KR100815315B1 - A manufacturing process of an artificial basalt stone - Google Patents

A manufacturing process of an artificial basalt stone Download PDF

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KR100815315B1
KR100815315B1 KR1020060065851A KR20060065851A KR100815315B1 KR 100815315 B1 KR100815315 B1 KR 100815315B1 KR 1020060065851 A KR1020060065851 A KR 1020060065851A KR 20060065851 A KR20060065851 A KR 20060065851A KR 100815315 B1 KR100815315 B1 KR 100815315B1
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stone
styropol
powder
porous
artificial
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KR20080006741A (en
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민홍식
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민홍식
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/061—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances by melting out
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/10—Clay
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/14—Minerals of vulcanic origin
    • C04B14/16—Minerals of vulcanic origin porous, e.g. pumice
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04—Macromolecular compounds
    • C04B16/08—Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/28—Polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40—Porous or lightweight materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54—Substitutes for natural stone, artistic materials or the like
    • C04B2111/542—Artificial natural stone
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80—Optical properties, e.g. transparency or reflexibility
    • C04B2111/802—White cement

Abstract

본　발명은　다공질의　화산석과　같은　인조석의　재현　및　조성물에　관한　것으로　특히　스티로폴을 제외하고는 원적외선 방사율이 많은 중에도 중량이 경량인 송이석분과 현무암석분에 맥반석분말, 일라이트분말, 황토분말, 백시멘트, 스티로풀의 혼합비를 30:25:10:5:5:15:10의 중량비로 한 것에 리그닌산 칼슘이 10Wt%함유된 물로 반죽함으로서 벽이나 옹벽에 미장하듯이 타설하거나 적당한 두께로 시공하거나 거푸집과 형틀 없이 조성물로 형성하여 24시간 경과되어 경화된 다음 화염을 통해 혼합된 스티로폴을 용융시켜 공기중에 확산 제거함으로서 성형물을 얻으며，　이와　같이　얻어진　조성물은 다공질이며 경량의 화산석과 같은 인조석을 얻는다.　따라서　이와 같이 얻어지는 인조석은 무공해는 물론 폐기물을 재 이용한다는 점에서 유용함은 물론 조경석으로　또는　미관상의　용기로서 다양하게　이용할　수　있는 효과가 있다．The present invention is concerned with the reproduction and composition of artificial tide, such as porous volcanic rocks.In particular, except for styropol, it is a light weight pineite, basalt powder, clay powder, white cement, white cement powder and basalt rock powder, even in the case of high far-infrared emissivity. The mixing ratio of styropool is 30: 25: 10: 5: 5: 15: 10 and kneaded with water containing 10Wt% of calcium lignate. It is formed into a composition without forming a mold and cured for 24 hours, and then the styropol mixed through the flame is melted to be diffused and removed in the air to obtain a molding. The obtained composition is a porous and lightweight volcanic stone artificial stone. Therefore, the artificial stone obtained as described above is useful in that it reuses waste as well as pollution-free, and also has various effects as a landscape stone or as an aesthetic container.

송이석분, 화산석, 스티로폴, 현무암석, 백시멘트, 일라이트, 황토석, 원적외선.    Pine stone, volcanic stone, styropol, basalt, white cement, illite, ocher, far infrared.

Description

다공질의 화산석을 재현한 인조석의 조형물과 그 제조방법{A manufacturing process of an artificial basalt stone}Sculpture of artificial stone that reproduces porous volcanic stone and its manufacturing method {A manufacturing process of an artificial basalt stone}

본 발명은 다공질의 화산석을 재현한 인조석의 조형물과 그 제조방법에 관한 것으로 종래 공개특허 1984년 제8312호에 의하면, 각종 건축물이 완공된 후 공원 조성이나 정원을 조경함에 있어 나무와 자연석을 많이 사용하나 가격이 비싸고 중량이 무거우며, 사용자가 필요로 하는 모형체의 자연석을 발굴하기 힘들어 이를 시정하기 위하여 입지 조건에 맞는 인조석을 사용하여 조경의 효과를 높이고 사용자의 경제적 부담을 줄이기 위하여 시멘트의 응고성과 PS스치로폴 발포입자의 용해성을 이용하여 성형처리한 후 열이나 유성에 녹여내어 발포 입자의 기포를 이용함으로서 돌의 모형을 나타내도록 하는 것이 알려져 있다. The present invention relates to a sculpture of artificial stone that reproduces a porous volcanic stone and a method of manufacturing the same. According to Korean Patent Laid-Open No. 8312, 1984, after a variety of buildings are completed, a lot of trees and natural stones are used in park construction or gardening. However, due to the high price and heavy weight, it is difficult to find the natural stone of the model required by the user.In order to correct this problem, the artificial solid stone suitable for the location conditions is used to enhance the effect of landscaping and reduce the economic burden on the user. It is known to form a model of stone by using the solubility of the PS Styropol foamed particles, and then dissolving it in heat or oil and using bubbles of the foamed particles.

그러나 상기 인용된 공개특허에 있어서는 구체적인 방법에 관하여는 공개된 바가 없다. 또 공개특허 1986년 제8107호에는 포리에스텔 액상수지와 탈크파우더 및 지당을 혼합한 후 경화제를 교반하여 결착제를 조성하고 이와 같이 조성된 결착제를 기판표면에 도포한 다음 그 위에 회색 자연석 분말 및 흑색 자연석 분말이 혼 합된 분말을 도포하여 표면이 인조 화강석과 같이하여 인조 화강석을 제조함이 알려져 있으며，　또한　공개특허　2000년　제72274호에　의하면，콘크리트조직을 형성하는　소재로서　미세한　석분과　시멘트，색소가　첨가된　물，파쇄된　스티로폴입자 등으로　이들을　모두　포함　교반과정을　거친다음　모형틀에　주입시켜　일정시간동안　응고시키고　응고된　콘크리트 성형체를　틀에서　분리시켜　표면에　응집된　몰타르　피막이　모형체의　표피층에　형성된　피막을　제거하고 그　위에　용해제를　도포하면，　스티로폴입자들의　용해작용을　통해　콘크리트성형체의　외부층에　무수한　공동화　현상을　갖춤으로서　다공질　용암석의　형태와　유사한　면모를　갖추도록 함이　알려져　있다．　그러나　상기와　같은　용해제를　도포함으로서　발생되는　용해된　공해물질에　대한　대비책이　요구된다.그러함에도　상기와　같은 방법으로는 형성된　조형물의　무게가　무거우며 경제적이지 못한 점이 있다. 그리고 표면만이 자연석으로 표현되나 화산석과 같은 다공질의 가벼운 자연석을 재현 할 수는 없다. However, in the above-mentioned cited patents, no specific method is disclosed. In addition, Korean Patent No. 8007 No. 1007 discloses a mixture of polyester liquid resin, talc powder, and liquor sugar, followed by stirring a curing agent to form a binder, and applying the binder formed on the surface of the substrate to the gray natural stone powder and It is known to manufacture artificial granite by applying powder mixed with black natural stone powder, and the surface is like artificial granite. Also, according to Korean Patent Publication No. 2000274 of 72274, it is a material that forms a concrete structure. After adding all of the particles with crushed styropol particles, etc., the mixture is stirred and injected into the mold to solidify for a certain period of time, and then the solidified concrete molded body is separated from the mold. Remove the film and melt on top of it The application of the agent is known to bring about a number of cavitation phenomena in the outer layer of the concrete molding through the dissolution of the styropol particles, thus providing a shape similar to that of the porous lava rock. However, there is a need for countermeasures against dissolved pollutants generated by the inclusion of such dissolutions. Nevertheless, in the same manner as described above, the weight of the formed body is heavy and uneconomical. And only the surface is represented by natural stone, but it is impossible to reproduce the porous light natural stone like volcanic stone.

따라서 본 발명은 상기와 같은 단점을 보완하면서도 화산석과 유사한 다공질의 가벼운 자연석을 제공하기 위하여는 종래 포트랜트시멘트(Portland Cement)대신 원적외선 방출량이 예를들어 0.922μn이며 방사에너지가 3.55x102(W/m2.μm,37℃)(한국원적외선응용평가연구원 시험성적임) 크고 무게가 가벼운 송이석분과 현무암석분 및 맥반석분말, 운모점토광물의 하나인 일라이트분말 에 황토분말과 백시멘트 그리고 폴리스틸렌수지를 넣어 다공질의 기포 프라스틱으로 된 스티로폴(Styropor)을 혼합하며，상기　혼합물을　반죽하여 성형시키기에 알맞도록 하기 위해 첨가되는　물의　양에　비해　10Wt%의 리그닌산칼슘이 함유된 결합제 용액을 첨가하여 얻어지는 용액으로 반죽하여 얻어진　모르탈을　타설이나 바르기 용이하도록 한 것을 벽이나 옹벽에 미장을 하듯이 적당한 두께로 시공하거나 도자기의 초벌구이를 형성하듯 형상을 만들어 일정시간 경과되어 응고 되고 경화되면 부러시를 이용하여 표면에 형성된 얇은 피막을 제거하고 상기 스티로폴이 용융되는 정도의 화염을 표면에 가하면, 스티로폴이 용출되어 그 공간에 공동이 생성됨으로서 더욱 가볍고 경량의 다공성의 화산암과 같은 형상의 인조석의 조형물을 얻게된다.Therefore, the present invention is to compensate for the above disadvantages, but to provide a light natural stone of porous similar to volcanic stone, far infrared emission amount is 0.922μn instead of the conventional Portland Cement, for example, the radiation energy is 3.55x10 2 (W / m 2 .μm, 37 ℃) Styropor, which is made of porous foam plastic, is mixed, and a solution obtained by adding a binder solution containing 10 Wt% of calcium lignate to the amount of water added to make the mixture suitable for kneading and molding the mixture. Make the mortar obtained by kneading so that it is easy to pour and apply mortar like plastering on walls or retaining walls. When it is applied to a thickness or forms a ceramic ware, it forms a shape and solidifies and hardens after a certain period of time. If a thin film formed on the surface is removed by using a brush, and a flame is applied to the surface, the styropol is melted. Elution results in the formation of cavities in the space, resulting in a lighter, lighter, porous volcanic rock-like artifact.

따라서 본 발명에 의하면 거푸집이나 형틀이 없이도 임의의 조성물을 재현할 수 있다.Therefore, according to the present invention, any composition can be reproduced without a formwork or a mold.

상기에서 설명되는　송이암이나 현무암, 맥반석등의 분말의 직경은 0.1∼2mm정도 되는것을 사용하며, 스티로폴의 지름은 0.2∼10mm의 크기가 좋다． 상기에서 첨가되는 각종 석분이나 스티로폴의 크기를 제한함은 그 이하이거나 그 이상일 경우 완성된 조성물의 강도와 재현된 자연석의 모양에 지장을 초래하는 것이며, 배합 비는 다음과 같다.The above-mentioned powders such as rock clusters, basalt and elvan have a diameter of about 0.1 to 2 mm, and the diameter of the styropole is preferably 0.2 to 10 mm. Limiting the size of the various stone powder or styropol added in the above is less or more than that will cause the strength of the finished composition and the shape of the reproduced natural stone, the mixing ratio is as follows.

송이석분 : 현무암석분 : 맥반석분 : 일라이트분말 : 황토분말 : 백시멘트 : 스티로폴의 배합비는 다음과 같다.Songyiseok powder: basalt rock powder: elvan powder powder: illite powder: ocher powder: white cement: Styropol.

30 : 25 : 10 : 5 : 5 : 15 : 10이다.30: 25: 10: 5: 5: 15: 10.

한편, 상기와 같은 배합비로 되는 혼합물을 반죽하여 성형하기 위해서는 물에 10Wt%의 리그린산 칼슘이 함유된 결합제 용액으로 반죽하는 것이다. 상기와 같은 리그닌산 칼슘이 함유된 결합제는 일종의 풀(糊劑)의 작용을 하여 입자 상호간 응결시키는 성질이 있고 통상적으로 펄프 생산중에 발생되는 폐액에서 생성되는 것이며 따라서 펄프 생산중 그대로 하수에 방출하면 공해의 원인이 되는 것이다.On the other hand, in order to knead and shape the mixture of the above compounding ratio is to knead with a binder solution containing 10Wt% calcium ligrate in water. The binder containing calcium lignate as described above has a property of condensation between particles by acting as a kind of grass, and is generally produced in waste liquid generated during pulp production. Therefore, it is polluted when released into sewage during pulp production. Will cause.

또한 종래 콘크리트 제품은 알카리의 용출(일명 석화)에 의해 강도가 저하하는 경년변화를 일으키는 폐단이 있는바 본 발명에 의하면, 첨가되는 리그린산 칼슘이 함유된 결합제 용액을 본 발명과 같이 일라이트석분을 혼용 사용함으로서 상호간에 수화작용을 일으켜 결착이 공고하여 종래와 같은 알카리 성분의 용출이 전혀 없어 경년변화를 일으키지 않게 된다는 것을 알게 됐다.In addition, according to the present invention, a conventional concrete product has a pulmonary end causing a change in strength due to the elution of alkali (also called calcification). According to the present invention, a binder solution containing calcium ligrate to be added is added as in the present invention. By using a mixture of hydration effect between each other and the binding is confirmed that there is no leaching of the alkaline components as in the prior art, it has been found that does not cause secular change.

뿐만이 아니라 사용되는 용수에 염분이 있는 경우 종래 응고된 구조가 약해지거나 응고하지 않는 불편이 있었으나 상기한 리그닌산 칼슘이 함유된 용액을 사용함으로서 바닷물을 이용한 건축물이나 구조물을 건조할 수도 있음으로서 어떠한 조건하의 물도 임의로 사용할 수 있음을 알게 되었고 첨가되는 리그닌산 칼슘의 양에따라 응고 반응시간을 조절할 수 있어서 최단 1∼2분에서 최대 7일 까지 목적과 예산에 따라 반응 속도를 조절할 수 있는바 본 발명에서는 24시간의 작업 공정을 감안한 것이다. In addition, if there is salt in the water used, the coagulated structure is inconvenient to be weakened or not coagulated, but by using a solution containing calcium lignate as described above, it is also possible to dry a building or structure using seawater under certain conditions. It was found that water can also be used arbitrarily and the coagulation reaction time can be adjusted according to the amount of calcium lignate added, so that the reaction rate can be adjusted according to the purpose and budget from the shortest 1 to 2 minutes up to 7 days. Given the working process of time.

또, 본 발명에서 스티로폴을 용출시키기 위한 화염으로는 천연가스이거나 응축 프로판가스(LPG)와 같은 압축가스 분사용 램프 또는 전기 발열선을 사용할 수도 있으며, 용적이 작은 형태의 용기와　같은　조형물은 스티로폴이 용융되는 온도 이상 즉 120℃정도 이상 되는　로(爐)에 넣음으로서 스티로폴이　용융 기화되어　공기 중에 발산시킴으로서　다공질의 형상을 갖는 조형물을 얻을 수가 있음을 알 수 있었다. 이와 같은 화염에 의한 스티로폴의 용융시 유의할 점은 발생되는 유독가스의 발생에 유의해야 한다는 점이다. In addition, in the present invention, the flame for eluting styropol may be a natural gas, a lamp for injection of compressed gas such as condensed propane gas (LPG), or an electric heating wire. It was found that the molded article having a porous shape can be obtained by fusion of the styropol into the air by putting it in a furnace at a temperature of about 120 ° C. or more, that is, about 120 ° C. or more. It is important to pay attention to the generation of toxic gas generated when melting Styropol due to such a flame.

이하 본 발명을 실시예에 따라 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to Examples.

이하 설명하는 석분은 직경이　0.1∼2mm크기의 것을 의미하며, 송이석분 30Wt%,　현무암석분 25Wt%, 맥반석분 10Wt%, 일라이트분말 5Wt%, 황토분말 5Wt%, 백시멘트 15Wt％에，입자의　크기가　0.1∼10mm크기로　분쇄된　스티로폴 10Wt%를 혼합하고, 상기　혼합물을 혼련하는１단계의　공정과，　Stone powder described below means having a diameter of 0.1 to 2mm, and is composed of 30Wt% of pine stone powder, 25Wt% of basalt stone powder, 10Wt% of elvan rock powder, 5Wt% of illite powder, 5Wt% of ocher powder, and 15Wt% of white cement. A one-step grinding step of mixing 10 wt% of styropol that is ground into a size of 0.1 to 10 mm and kneading the mixture;

상기　1단계의　공정에　의해　얻어진　혼합물을 반죽으로하기 위해　첨가되는　물의　양에　비해　약10Wt％의　리그닌산 칼슘이 함유된 액상의 결합제를 용액으로 반죽하는 2단계의　공정과，　A two-step kneading step of kneading a liquid binder containing about 10 Wt% calcium lignate with a solution compared to the amount of water added in order to knead the mixture obtained by the first step;

상기．2단계의　공정에　의해　얻어진　반죽된　모르탈을　벽이나　옹벽　또는　벽면에　적당한　두께로　시공하여　24시간정도　경과되면　응고되고，　응고된　표면을　브러시로　표면의　얇은　피막을　제거하는　3단계공정과，The above-described three-step process and the step of removing the thin film on the surface by brushing the hardened surface after applying the plaster mortar obtained by the two-step process to the appropriate thickness on the wall, retaining wall or wall for 24 hours. ，

상기　제3단계　공정에　의해　피막이　제거된　표면에　액화가스의 분사용램프 등으로　화염을　방사하여　스티로폴을　용융제거함으로서　다공질이　성형된 인조석의　조형물을　얻는다．In the third step, the flame is sprayed onto the surface from which the coating is removed to spray a liquefied gas into the molten gas to melt and remove the styropole, thereby obtaining a molded article made of porous artificial stone.

또한　상기 제2단계의 공정으로 얻어진 모르탈로는　옹벽이나　벽면이　아닌 초벌구이와　같은　용기와 같은 조형물을 만드는 경우 응고되는 시간이 빠르므로 조형할 형체를 거푸집이나 형틀 없이 임의 형상 등으로　모형을 만들수가 있으며, 만들어진 초벌구이 용기의 표면에　상기　제2공정에서　얻어진　모르탈로　표면처리　할　수도　있으며，　모형이　작은　경우　로 내에　넣어　스티로폴을　용융　소각하고　기화시켜 로 밖의 공기중에　발산시킴으로서　다공질의　인조　화산암의 조형물을 얻는다.　　In addition, the mortalo obtained by the second step process can be solidified in the case of making moldings such as pottery vessels, such as retaining walls or wall surfaces, so that the molds to be molded can be formed into arbitrary shapes without form or mold. In addition, the surface of the prepared roasting vessel can be surface treated with mortar obtained in the second process.If the model is small, it can be put into the furnace to melt and burn the styropol to give off the air in the furnace to obtain the artificial artificial volcanic rock.

이상　설명한　바와　같이　본　발명에　의하면，공해물질인 폐 스티로폴이나 제지공장에서 폐기하는 펄프의 폐액인 리그닌산 칼슘을 수집하여 이를 이용하여 공해가　없는　다공질이며,　경량의　인조　조형　석재를　얻을　수　있고，　경량이면서도 외관이　화산암과　같은　모양의　자연석을　얻을　수가　있어서　조경은　물론　장식물로도　유용하게　이용할　수 있고, 재료 자체의 원적외선 발산에 의한 효과는 물론 무공해이며, 환경의 조건에 관계 없이 어디서나 작업이 가능한 등 아직까지 알려진바 없는 산업상 유용한 발명인　것이다．　　　As described above, according to the present invention, calcium lignate, which is a waste liquid of waste material such as waste styropol or paper pulp, is collected and used to obtain a pollution-free, porous and lightweight synthetic stone. In addition, the appearance of natural stone, such as volcanic rock, can be obtained, so that the landscaping can be usefully used as a decoration, and the effect of far-infrared radiation of the material itself is pollution-free, and it can be worked anywhere regardless of environmental conditions. It is an industrially useful invention that is not known until now.

Claims (3)

입자의 지름이 0.1∼2mm 크기의 송이석분 30Wt%와　현무암석분 25Wt%및　맥반석분　10Wt%,　일라이트분말 5Wt%, 황토분말 5Wt%, 백시멘트 15Wt%에, 입자의 크기가 0.2∼10mm의 스티로폴 10Wt%을　혼합하여　고르게 교반하는　제１단계의　공정과，Styropol with a particle size of 0.2 to 10 mm, with a particle size of 0.1 to 2 mm, 30 Wt% of pinestone, 25 Wt% of basalt and 10 Wt% of rock mass, 10 Wt% of clay powder, 5 Wt% of ocher powder, 5 Wt% of ocher powder, and 15 Wt% of cement. The first step of mixing 10Wt% and stirring it evenly, 상기　제1단계 공정에서　얻어진　혼합물에　10Wt％의　리그닌산 칼슘이 함유된 결합제로되는 물로　반죽하는　제２단계의　공정과，A second step of kneading with water comprising a binder containing 10 Wt% calcium lignate in the mixture obtained in the first step; 상기　제２단계의　공정으로　얻어진　모르탈로　벽면이나　옹벽에　일정　두께로　시공이나　타설하여　24시간　이상　응고시켜　표면을　브러시로　피막을 제거하는　제３단계의　공정과，The third step of removing the film with a brush by solidifying the surface of the mortar with the retaining wall or the retaining wall obtained in the second step to solidify for more than 24 hours. 상기　제３단계의　공정으로　피막이　제거된　표면을　화염에　의해　가열하여　스티로폴을　용융　제거하는 공정에 의해　다공질이며,　경량의　조형물을　얻는　것을　특징으로하는　다공질의　화산석을　재현하는　인조석의 조형물．In the third step, the surface of which the film has been removed is heated by flame to melt the styropol to remove the styropol, which is a porous and sculpted artificial stone that reproduces the porous volcanic stone. 상기　청구항１에　있어서，In claim 1 above, 제３단계의　공정에　의해　얻어진　조형물을　120℃정도　이상의　로　내에 넣어　스티로폴을　용융　기화하여 공기중에 발산시켜　다공질의　경량　조형물을 얻는 것을　특징으로하는　다공질의　화산석을　재현하는　인조석의　조형물　제조방법.The method of manufacturing artificial stone sculptures, which reproduces porous volcanic rocks, which is characterized by melting the vaporized styropol into the air by dissolving the sculptures obtained by the third step in a temperature of about 120 ° C or higher to obtain a porous lightweight stone sculpture. 삭제delete
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KR20050098417A (en) * 2004-04-07 2005-10-12 윤재화 Loess mortar composition for construction materials and coating method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2508267C1 (en) * 2013-02-19 2014-02-27 Юлия Алексеевна Щепочкина Crude mixture for making material imitating natural stone

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