KR100605090B1 - A synthetic marble and a preparation method thereof - Google Patents

A synthetic marble and a preparation method thereof Download PDF

Info

Publication number
KR100605090B1
KR100605090B1 KR1020050127000A KR20050127000A KR100605090B1 KR 100605090 B1 KR100605090 B1 KR 100605090B1 KR 1020050127000 A KR1020050127000 A KR 1020050127000A KR 20050127000 A KR20050127000 A KR 20050127000A KR 100605090 B1 KR100605090 B1 KR 100605090B1
Authority
KR
South Korea
Prior art keywords
marble
unsaturated polyester
pearl
polyester resin
wax
Prior art date
Application number
KR1020050127000A
Other languages
Korean (ko)
Inventor
최용준
Original Assignee
최용준
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
Application filed by 최용준 filed Critical 최용준
Priority to KR1020050127000A priority Critical patent/KR100605090B1/en
Application granted granted Critical
Publication of KR100605090B1 publication Critical patent/KR100605090B1/en
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=37184571&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR100605090(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0453Ornamental plaques, e.g. decorative panels, decorative veneers produced by processes involving moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • B44F9/04Designs imitating natural patterns of stone surfaces, e.g. marble
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06Unsaturated polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/06Unsaturated polyesters

Abstract

판넬과 그 한쪽면 상에 불포화폴리에스테르 수지, 펄 및 왁스 이루어진 대리석 문양/패턴 색상층으로 이루어지고, 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석 및 그 제조방법에 관한 것이다.The present invention relates to an artificial marble composed of a marble pattern / pattern color layer composed of an unsaturated polyester resin, pearl and wax on one side of the panel, and having a variety of appearances and luxurious textures such as natural marble, and a method of manufacturing the same.
인조대리석, 판넬 Artificial Marble, Panel

Description

인조대리석 및 그 제조방법{A Synthetic Marble and A Preparation Method Thereof}A Synthetic Marble and A Preparation Method Thereof}
도 1은 본 발명에 따른 인조대리석의 제조를 위해 블록킹 처리한 판넬의 사시도이다. 1 is a perspective view of a panel blocked for the manufacture of artificial marble according to the present invention.
도 2는 실시예 1에 따라 얻어진 인조대리석의 표면의 사진이다. 2 is a photograph of the surface of the artificial marble obtained in Example 1.
도 3은 실시예 2에 따라 얻어진 인조대리석의 표면의 사진이다. 3 is a photograph of the surface of artificial marble obtained in Example 2. FIG.
도 4는 실시예 3에 따라 얻어진 인조대리석의 표면의 사진이다. 4 is a photograph of the surface of artificial marble obtained in Example 3. FIG.
도 5는 실시예 4에 따라 얻어진 인조대리석의 표면의 사진이다. 5 is a photograph of the surface of artificial marble obtained in Example 4. FIG.
도 6은 실시예 5에 따라 얻어진 인조대리석의 표면의 사진이다. 6 is a photograph of the surface of artificial marble obtained in Example 5. FIG.
도 7은 실시예 6에 따라 얻어진 인조대리석의 표면의 사진이다. 7 is a photograph of the surface of artificial marble obtained in Example 6. FIG.
도 8은 본 발명에 따라 제조된 인조대리석 (블록킹 제거 전)의 절단면도이다. 8 is a cutaway view of an artificial marble (prior to blocking removal) made according to the present invention.
(도면의 주요 부분에 대한 부호의 설명)(Explanation of symbols for the main parts of the drawing)
1: 판넬 2: 블록킹 3: 블록킹 두께 4: 대리석 패턴/문양 색상층1: panel 2: blocking 3: blocking thickness 4: marble pattern / pattern color layer
본 발명은 인조대리석 및 그 제조방법에 관한 것으로, 보다 상세하게는 불포화폴리에스테르 수지, 펄과 왁스의 반응에 의하여 천연대리석과 같은 다양한 외관과 고급스러운 천연 질감을 갖는 인조대리석 및 그 제조방법에 관한 것이다.The present invention relates to an artificial marble and a method for manufacturing the same, and more particularly, to an artificial marble having a variety of appearances and high-quality natural texture, such as natural marble by the reaction of unsaturated polyester resin, pearl and wax, and a method for producing the same. will be.
석회암과 돌로마이트가 접촉변성작용이나 광역변성작용을 받아 재결정되어 형성되는 천연대리석은, 연마하면 특유의 다색무늬와 광택이 나타나 건축물의 내장 및 외장재로 사용되고 있다. 그러나 천연대리석으로 된 건축재는 그 두께가 보통 10mm 이상으로 부피와 중량이 크고 가격이 고가여서, 그 사용이 제한적이라는 문제점이 있었다. 그리하여 가격은 천연대리석보다 저렴하나, 천연대리석과 같은 느낌을 줄 수 있는 인조대리석을 제조하는 데 많은 노력이 기울여져 오고 있으나, 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석은 아직까지 개발되지 않고 있는 실정이다. Natural marble, which is formed by recrystallization after lime or dolomite is subjected to contact or wide-area metamorphism, has a unique multicolored pattern and gloss when polished, and is used as interior and exterior materials of buildings. However, the building material made of natural marble has a problem that its use is limited because its thickness is usually 10 mm or more, its volume, weight, and price are high. Thus, although the price is cheaper than natural marble, much effort has been made to manufacture artificial marble which can give a feeling like natural marble. However, artificial marbles with various appearances and luxurious textures such as natural marble are still developed. It's not happening.
이에 본 발명자는 불포화폴리에스테르 수지, 펄과 왁스를 사용함에 의해 천연대리석과 같은 다양한 외관과 고급스러운 질감을 가지면서 가공성이 우수하고 경량의 인조대리석을 개발하게 되어 본 발명을 완성하게 되었다. Accordingly, the present inventors have completed the present invention by developing an artificial marble having excellent processability and light weight while having various appearances and luxurious textures such as natural marble by using unsaturated polyester resin, pearl and wax.
본 발명의 목적은 판넬과 그 한쪽면 상에 불포화폴리에스테르 수지, 펄 및 왁스 이루어진 대리석 문양/패턴 색상층으로 이루어지고, 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석을 제공하는 것이다. It is an object of the present invention to provide an artificial marble composed of a marble pattern / pattern color layer consisting of unsaturated polyester resin, pearl and wax on a panel and one side thereof, and having various appearances and luxurious textures such as natural marble.
본 발명의 또 다른 목적은 천연대리석과 같은 다양한 외관과 고급스러운 질 감을 갖는 인조대리석의 제조방법으로, Another object of the present invention is a method of manufacturing artificial marble having a variety of appearance and luxurious texture, such as natural marble,
판넬의 상면의 가장자리를 블록킹 처리하여 원하는 도막 두께의 공간을 형성하는 단계; 상기 공간에, 불포화폴리에스테르 수지와 펄의 혼합물 및 왁스를 처리하는 단계; 경화시킨 후 가장자리의 블록킹을 제거하는 단계로 이루어지는 인조대리석 제조방법을 제공하는 것이다. Blocking the edge of the upper surface of the panel to form a space having a desired coating thickness; Treating the space with a mixture of unsaturated polyester resin and pearl and wax; To provide a method of manufacturing artificial marble comprising the step of removing the blocking of the edge after curing.
본 발명의 목적을 달성하기 위하여, 판넬과 판넬 한쪽면 상에 불포화폴리에스테르 수지, 펄 및 왁스로 이루어진 대리석 문양/패턴 색상층으로 이루어지는 천연 대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석이 제공된다. In order to achieve the object of the present invention, artificial marble having various appearances and luxurious textures, such as natural marble composed of a marble pattern / pattern layer of unsaturated polyester resin, pearl and wax, is provided on the panel and one side of the panel. do.
본 발명에서 판넬은 일반적으로 건축자재의 소재로 사용되는 MDF, 보드류, 아크릴, 하질의 대리석 및 백라이트 등의 판넬을 포함한다. 판넬의 크기나 두께에는 제한이 없으나, 제조상의 용이성을 고려하여 적절히 사용한다. In the present invention, the panel generally includes panels such as MDF, boards, acrylic, low-quality marble, and backlight, which are used as building materials. There is no limitation on the size or thickness of the panel, but it is appropriately used considering the ease of manufacture.
불포화폴리에스테르 수지는 건축자재에 사용되며, 경화시 일정 두께의 도막을 형성할 수 있는, 통상의 2액형 또는 3액형 불포화폴리에스테르 수지가 사용될 수 있으며, 논왁스 타입의 불포화폴리에스테르 수지가 바람직하다. 또한 경도, 치수안정성, 수축률 및/또는 광택과 같은 물성의 개량을 위해 변형된 불포화폴리에스테르 수지도 사용가능하다. Unsaturated polyester resin is used in building materials, a conventional two-component or three-component unsaturated polyester resin can be used, which can form a coating film of a certain thickness upon curing, non-wax type unsaturated polyester resin is preferred. . Unsaturated polyester resins may also be used to improve physical properties such as hardness, dimensional stability, shrinkage and / or gloss.
펄은 통상 가구용 도료에 미려한 색상을 창출하기 위해 첨가되는 안료의 일종으로, 창출되는 색상에 따라서 진주펄, 황금펄, 동펄, 은펄 등이 있다. 본 발명에서는 1종 이상의 펄이 사용되는데, 사용되는 펄의 종류와 안료 혼합비에 따라 다 양한 색상의 대리석 표면이 창출될 수 있다. Pearl is usually a kind of pigment added to create a beautiful color in furniture paints, there are pearl pearl, golden pearl, copper pearl, silver pearl and the like depending on the color generated. In the present invention, one or more pearls are used, and marble surfaces of various colors may be created according to the type of pearls used and the pigment mixing ratio.
왁스는 가구용 왁스가 사용될 수 있다. 바람직하게는 물을 용제로 하고 실리콘유를 주성분으로 하는 왁스를 사용할 수 있다. Wax may be used for furniture wax. Preferably, water-based solvents and silicone oil-based waxes can be used.
일반적으로 왁스는 불포화폴리에스테르 수지와는 상용성 (compatibility)이 없어서 불포화폴리에스테르 수지 도료를 건축자재에 사용시에 사전의 왁스처리가 금기시되어 왔다. 그러나 본 발명에 의해, 불포화폴리에스테르 수지에 왁스를 점적 적용(drop application) 하면, 왁스 방울 주변에서 불포화폴리에스테르 수지와의 반응이 일어나면서 예상치 못한 천연대리석과 같은 다양하면서도 고급스러운 외관 (모양/무늬/색상)를 가진 인조대리석이 형성됨이 확인되었다. In general, wax has no compatibility with unsaturated polyester resins, and therefore, prior wax treatment has been contraindicated when unsaturated polyester resin paints are used in building materials. However, according to the present invention, when a drop application is applied to an unsaturated polyester resin (drop application), the reaction with the unsaturated polyester resin occurs around the wax drop, and various and luxurious appearances like unexpected natural marble (shape / pattern / Color) artificial marble was formed.
본 발명에 따른 인조대리석에서 불포화폴리에스테르 수지 100 중량부에 펄 0.1 ~ 2.5 중량부 및 왁스 0.01 ~ 0.2 중량부로 포함되는 것이 바람직하다. In the artificial marble according to the present invention, 100 parts by weight of unsaturated polyester resin is preferably contained in 0.1 to 2.5 parts by weight of pearl and 0.01 to 0.2 parts by weight of wax.
펄이 0.1 중량부 미만이거나 2.5 중량부 초과하면 고급스러운 문양/색상의 대리석이 형성되기 어렵다. 왁스가 0.01 중량부 미만이거나 0.2 중량부 초과하면 또한 고급스러운 문양/색상의 대리석이 형성되기 어렵다. If the pearl is less than 0.1 parts by weight or more than 2.5 parts by weight, it is difficult to form a luxurious pattern / colored marble. If the wax is less than 0.01 part by weight or greater than 0.2 part by weight, it is also difficult to form a luxurious pattern / colored marble.
또한 본 발명에 따른 인조대리석에는 필요에 따라서, 일반적으로 도료에 사용되는 적색, 황색등 기타 안료가 추가로 포함될 수 있다. 원하는 대리석의 색상농도에 따라 안료의 첨가량이 달라질 수 있으나, 일반안료는 불포화폴리에스테르 수지 100 중량부에 대해, 0.001 ~ 0.05 중량부로 포함되는 것이 바람직하다. 일반안료가 0.001 중량부 이하면 안료의 효과를 발휘하기 어렵고 0.05 중량부 초과하면 너무 진한색의 대리석 문양/색상이 형성될 수 있다. In addition, the artificial marble according to the present invention may further include other pigments, such as red, yellow, etc., which are generally used in paints as needed. The amount of the pigment may vary depending on the color of the desired marble, but the general pigment is preferably included in an amount of 0.001 to 0.05 parts by weight based on 100 parts by weight of the unsaturated polyester resin. If the pigment is 0.001 parts by weight or less, it is difficult to exert the effect of the pigment, and if it exceeds 0.05 parts by weight, too dark marble pattern / color may be formed.
본 발명의 또 다른 목적을 달성하기 위하여, 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석의 제조방법으로, In order to achieve another object of the present invention, as a method of manufacturing artificial marble having a variety of appearance and luxurious texture, such as natural marble,
i) 판넬의 상면의 가장자리를 블록킹 처리하여 원하는 도막 두께의 공간을 형성하는 단계; i) blocking the edge of the upper surface of the panel to form a space having a desired coating thickness;
ii) 상기 공간에, 불포화폴리에스테르 수지 100 중량부에 펄 0.1 ~ 2.5 중량부 및 왁스 0.01 ~ 0.2 중량부를 처리하는 단계; ii) treating 0.1-2.5 parts by weight of pearl and 0.01-0.2 parts by weight of wax to 100 parts by weight of unsaturated polyester resin in the space;
iii) 경화시킨 후 가장자리의 블록킹을 제거하는 단계로 이루어지는 인조대리석 제조방법을 제공하는 것이다. iii) to provide a method of manufacturing artificial marble comprising the step of removing the blocking of the edge after curing.
본 발명에 따른 제조방법에서, 판넬, 불포화폴리에스테르 수지, 펄 및 왁스는 상기에서 정의된 바와 같다. In the production process according to the invention, the panels, unsaturated polyester resins, pearls and waxes are as defined above.
단계 i)에서 블록킹 처리는, 도 1에 도시된 바와 같이, 판넬 상면에 도막이 형성될 수 있는 공간(틀)이 마련되도록, 판넬의 상면의 가장자리를 접착테이프나 목재 쫄대 등의 수단으로 처리하는 것이다. 블록킹의 두께는 원하는 도막의 두께에 상응하도록 하며, 바람직하게는 1~10mm 이다. 1mm 이하이면 도막의 두께가 너무 얇게 되어 문양이 흐리게 나타나게 되며, 10mm를 초과하면 대리석 문양/패턴층에 크랙이 발생할 수 있다. In step i), the blocking process is to process the edge of the upper surface of the panel by means such as adhesive tape or wood chock, so that a space (frame) in which the coating film can be formed is provided on the upper surface of the panel as shown in FIG. . The thickness of the blocking should correspond to the thickness of the desired coating film, preferably 1-10 mm. If it is less than 1mm, the thickness of the coating film is too thin, the pattern is blurred. If it exceeds 10mm, cracks may occur in the marble pattern / pattern layer.
단계 ii)의 구성성분의 처리에서, 기본적으로 불포화폴리에스테르 수지와 펄은 혼합하고, 왁스는 점적 적용한다. 구체적으로는, ① 판넬 상의 상기 공간에 왁스를 점적 적용한 후, 불포화폴리에스테르 수지와 펄의 혼합물을 첨가하거나; ② 불포화폴리에스테르 수지와 펄의 혼합물에 왁스를 혼합하여 판넬 상의 공간에 첨가 하거나; ③ 먼저 판넬 상의 공간에 불포화폴리에스테르 수지와 펄의 혼합물을 첨가한 후, 왁스를 점적 적용하거나; 또는 ④ 판넬 상의 상기 공간에 일부 왁스를 점적 적용한 후, 불포화폴리에스테르 수지와 펄의 혼합물을 첨가한 후, 다시 나머지 왁스를 점적 적용한다.In the treatment of the components of step ii), basically the unsaturated polyester resin and pearl are mixed and the wax is applied dropwise. Specifically, (1) after dropwise applying wax to the space on the panel, a mixture of unsaturated polyester resin and pearl is added; ② the wax is mixed with a mixture of unsaturated polyester resin and pearl and added to the space on the panel; ③ first, a mixture of unsaturated polyester resin and pearl is added to the space on the panel, and then wax is applied dropwise; Or (4) After applying some wax to the space on the panel, adding a mixture of unsaturated polyester resin and pearl, and then applying the remaining wax again.
도 2 ~ 도 5에서와 같이, ① ~ ④의 처리과정에 따라 상이한 문양과 패턴의 인조대리석 외관이 형성될 수 있다.2 to 5, the artificial marble appearance of different patterns and patterns can be formed according to the processing of ① ~ ④.
단계 ii)에서, 필요에 따라서, 불포화폴리에스테르 수지와 펄의 혼합물에 안료가 색상에 따라 추가로 포함될 수 있다. 안료는 상기에서 정의된 바와 같은 안료가 사용될 수 있다. 안료가 추가로 포함된 경우는, 도 6 및 도 7에서와 같이 더 다양한 색상을 띤 인조대리석의 외관이 형성될 수 있다. In step ii), if necessary, pigments may additionally be included in the mixture of unsaturated polyester resins and pearls depending on the color. As the pigment, a pigment as defined above may be used. In the case where the pigment is additionally included, the appearance of more various colors of artificial marble may be formed as shown in FIGS. 6 and 7.
단계 iii)에서는, 단계 ii)에서 판넬 상의 공간에 형성된 도막이 경화되도록 상온에서 1 ~ 24시간 방치한 후, 완전 경화되면 가장자리의 블록킹을 제거하여 인조대리석을 완성한다. In step iii), the coating film formed in the space on the panel in step ii) is left to stand at room temperature for 1 to 24 hours, and when completely cured, the artificial marble is completed by removing the blocking of the edge.
필요에 따라서, 단계 i) 전에, 판넬의 상면을 신나로 한번 닦아내는(천에 묻혀서) 처리를 하면 불포화폴리에스테르 수지와 판넬과의 접착성이 더 양호하게 된다. 신나는 통상적으로 가구용 폴리신나를 사용한다. If necessary, prior to step i), the treatment of wiping off the upper surface of the panel with thinner once (with a cloth) results in better adhesion between the unsaturated polyester resin and the panel. Exciting usually uses polycinna for furniture.
또한, 필요에 따라서, 단계 iii) 후에, 생성된 인조대리석의 표면을 연마하거나, 불포화폴리에스테르 수지로 코팅함에 의한 광택을 위한 가공처리가 추가될 수 있다. 연마는 통상 페이퍼 가공한다. 코팅의 경우는 통상적인 필름 코팅지로 코팅을 하거나, 본 출원인의 특허출원 제2005-2011호에 기재된 바와 같이, 인조대리 석 면과 이형제가 도포된 유리판 사이에 불포화폴리에스테르 수지를 주입하고 서로 밀착시킨 후, 수지가 경화된 후에 유리판을 분리하면 고광택의 코팅이 형성될 수 있다. Also, if necessary, after step iii), a surface treatment may be added for polishing by polishing the surface of the resultant artificial marble or coating with an unsaturated polyester resin. Polishing is usually paper processing. In the case of coating, coating is performed with a conventional film coating paper, or as described in the applicant's patent application No. 2005-2011, insulated unsaturated polyester resin between the artificial surrogate asbestos and the glass plate to which the release agent is applied and closely adhered to each other. Then, after the resin is cured, the glass plate may be separated to form a high gloss coating.
상기와 같이 완성된 인조대리석은 제품화 시에 블록킹되었던 판넬 가장자리부분을 컷팅할 수 있다. The finished artificial marble as described above can cut the panel edge portion that was blocked at the time of commercialization.
하기 실시예들에 기초하여 본 발명에 따른 인조대리석의 제조방법을 더 구체적으로 설명하나, 본 발명이 이들로 한정하고자 하는 것은 아니다. Based on the following examples, a method of manufacturing artificial marble according to the present invention will be described in more detail, but the present invention is not intended to be limited thereto.
실시예Example
실시예Example 1 One
가로 1,500mm, 세로 910mm, 두께 40mm의 MDF 판넬의 상면의 가장자리 모두를 폭이 50mm인 마스킹 테이프로 블록킹 처리하여 공간의 높이가 3mm가 되도록 만든다. 형성된 공간에 왁스((주)오공) 2g을 점적 적용한 후, 불포화폴리에스테르 수지 (신광페인트) 18kg과 진주펄 (Merck) 60g과 황금펄 (Merck) 30g을 혼합한 혼합물 3.6kg으로 대리석 문양/패턴층을 형성한 후, 상온에서 24시간 경화시키고 마스킹 테이프를 제거하여 인조대리석을 완성하였다. 완성된 인조대리석의 표면의 사진을 도 2로 나타내었다. All edges of the top surface of the MDF panels 1,500 mm wide, 910 mm long and 40 mm thick are blocked with 50 mm wide masking tape to make the space 3 mm high. After 2g of wax (poor) was applied to the formed space, a marble pattern / pattern was made with a mixture of 18kg of unsaturated polyester resin (shingwang paint), 60kg of pearl pearl (Merck) and 30g of golden pearl (Merck). After the layer was formed, the artificial marble was completed by curing at room temperature for 24 hours and removing the masking tape. The photo of the surface of the finished artificial marble is shown in FIG.
실시예Example 2 2
가로 1500mm, 세로 910mm, 두께 40mm의 MDF 판넬의 상면의 가장자리 모두를 폭이 50mm인 마스킹 테이프로 블록킹 처리하여 공간의 높이가 3mm가 되도록 만든 다. 형성된 공간을 폴리신나(신광페인트)를 묻힌 천으로 문질러 닦는다. 그리고 나서 형성된 공간에, 불포화폴리에스테르 수지 (신광페인트) 18kg과 진주펄 (Merck) 60g과 동펄 (Merck) 30g을 혼합하고 왁스((주)오공) 10g을 추가로 혼합한 혼합물 3.6kg으로 대리석 문양/패턴 층을 형성한 후, 상온에서 24시간 경화시키고 마스킹 테이프를 제거하여 인조대리석을 완성하였다. 완성된 인조대리석의 표면의 사진을 도 3으로 나타내었다.All edges of the upper surface of the MDF panel with 1500mm width, 910mm height and 40mm thickness are blocked by 50mm width masking tape to make the space height 3mm. The formed space is rubbed with a cloth moistened with polycinna. Then, in the space formed, 18 kg of unsaturated polyester resin (shingwang paint), 60 g of pearl pearl (Merck) and 30 g of copper pearl (Merck) were mixed, and 3.6 g of a mixture of 10 g of wax (Ogpo) was further added. After the pattern layer was formed, it was cured at room temperature for 24 hours and the masking tape was removed to complete the artificial marble. A photograph of the surface of the finished artificial marble is shown in FIG. 3.
실시예Example 3 3
가로 1500mm, 세로 910mm, 두께 40mm의 MDF 판넬의 상면의 가장자리 모두를 폭이 50mm인 마스킹 테이프로 블록킹 처리하여 공간의 높이가 3mm가 되도록 만든다. 형성된 공간에, 불포화폴리에스테르 수지 (신광페인트) 18kg과 진주펄 (Merck) 60g과 동펄 (Merck) 30g을 혼합한 혼합물을 3.6kg 첨가한 후, 왁스((주)오공) 2g을 점적 적용하여 대리석 문양/패턴층을 형성하고, 상온에서 24시간 경화시키고 마스킹 테이프를 제거하여 인조대리석을 완성하였다. 완성된 인조대리석의 표면의 사진을 도 4로 나타내었다. All edges of the top surface of the MDF panels 1500mm wide, 910mm wide and 40mm thick are blocked with 50mm wide masking tape to make the space 3mm high. To the formed space, 3.6 kg of a mixture of 18 kg of unsaturated polyester resin (shingwang paint), 60 g of pearl pearl (Merck), and 30 g of copper pearl (Merck) was added, followed by dropwise application of 2 g of wax (Ogpo) Co., Ltd. A pattern / pattern layer was formed, cured at room temperature for 24 hours, and the masking tape was removed to complete the artificial marble. The photo of the surface of the finished artificial marble is shown in FIG.
실시예Example 4 4
가로 1500mm, 세로 910mm, 두께 40mm의 MDF 판넬의 상면의 가장자리 모두를 폭이 50mm인 마스킹 테이프로 블록킹 처리하여 공간의 높이가 3mm가 되도록 만든다. 형성된 공간에, 왁스((주)오공) 4g중 2g를 점적 적용한 후, 불포화폴리에스테르 수지 (신광페인트) 18kg과 진주펄 (Merck) 60g과 황금펄 (Merck) 50g을 혼합한 혼합물 3.6kg을, 상기 공간에 첨가하고, 다시 나머지 왁스를 점적 적용하여 대리석 문양/패턴 층을 형성한 후, 상온에서 24시간 경화시키고 마스킹 테이프를 제거하였다. 그리고 나서, 생성된 인조대리석과 이형제((주)현대)가 도포된 유리판 사이에 불포화폴리에스테르 수지(신광페인트) 2kg를 주입하고 서로 밀착시킨 후, 수지가 경화된 후에 유리판을 분리하여 고광택의 코팅이 형성하여 인조대리석을 완성하였다. 완성된 인조대리석의 표면의 사진을 도 5로 나타내었다. All edges of the top surface of the MDF panels 1500mm wide, 910mm wide and 40mm thick are blocked with 50mm wide masking tape to make the space 3mm high. 2 g of 4 g of wax (Okupo) was applied dropwise to the formed space, and then 3.6 kg of a mixture of 18 kg of unsaturated polyester resin (shingwang paint), 60 g of pearl pearl (Merck) and 50 g of golden pearl (Merck) was mixed. After adding to the space, the remaining wax was applied dropwise to form a marble pattern / pattern layer, and then cured at room temperature for 24 hours and the masking tape was removed. Then, 2 kg of unsaturated polyester resin (shingwang paint) was injected between the resultant artificial marble and the glass plate coated with the release agent (Hyundai Co., Ltd.), and then adhered to each other. After the resin was cured, the glass plate was separated to coat high gloss. This formation completed the artificial marble. The photo of the surface of the finished artificial marble is shown in FIG.
실시예Example 5 5
불포화폴리에스테르 수지와 펄의 혼합물에 적색안료(Merck) 1g을 추가로 첨가한 것을 제외하고는, 실시예 4와 동일하게 행하여 인조대리석을 제조하였고, 완성된 인조대리석의 표면 사진을 도 6으로 나타내었다. Artificial marble was prepared in the same manner as in Example 4, except that 1 g of a red pigment (Merck) was further added to the mixture of the unsaturated polyester resin and pearl, and the surface photo of the finished artificial marble is shown in FIG. 6. It was.
실시예Example 6 6
불포화폴리에스테르 수지와 펄의 혼합물에 적색안료(Merck) 1g을 추가로 첨가한 것을 제외하고는, 실시예 4와 동일하게 행하여 인조대리석을 제조하였고, 완성된 인조대리석의 표면 사진을 도 7로 나타내었다. A synthetic marble was prepared in the same manner as in Example 4, except that 1 g of a red pigment (Merck) was further added to the mixture of the unsaturated polyester resin and pearl, and a surface photograph of the finished artificial marble is shown in FIG. 7. It was.
도 2 ~ 도 7의 본 발명에 따른 인조대리석의 표면 사진에서 확인할 수 있듯이, 본 발명의 제조방법에 의하면 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석의 제조가 가능함을 알 수 있다. As can be seen from the surface photo of the artificial marble according to the present invention of Figures 2 to 7, it can be seen that according to the manufacturing method of the present invention, it is possible to manufacture artificial marble having various appearances and luxurious textures such as natural marble.
본 발명에 의하면 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석을 얻을 수 있다. 또한 본 발명에 의한 인조대리석은 천연대리석에 비하 여 경량이면서 가공성이 뛰어나서, 차세대 대리석으로 건축 내외장재 및 가구 상판자재로 사용될 수 있다. 구체적으로는 값비싼 천연대리석의 대체물로서, 식탁, 장롱, 탁자, 서랍장 등의 가구 상판, 외장용재, 주방 상판, 벽체나 화장실, 세면 상판 실내인테리어 등에 사용가능하다.According to the present invention, it is possible to obtain artificial marble having various appearances and luxurious textures such as natural marble. In addition, the artificial marble according to the present invention is light and excellent in processability compared to natural marble, it can be used as interior and exterior building materials and furniture roofing material as the next generation marble. Specifically, it can be used as a substitute for expensive natural marble, such as furniture tops such as dining tables, chests, tables, and chests of drawers, exterior materials, kitchen tops, walls, toilets, and washbasin interiors.

Claims (7)

  1. 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석의 제조방법으로, As a manufacturing method of artificial marble having a variety of appearance and luxurious texture, such as natural marble,
    i) 판넬의 상면의 가장자리를 블록킹 처리하여 원하는 도막 두께의 공간을 형성하는 단계; ii) 상기 공간에, 불포화폴리에스테르 수지 100 중량부에 펄 0.1 ~ 2.5 중량부 및 왁스 0.01 ~ 0.2 중량부를 처리하는 단계; iii) 경화시킨 후 가장자리의 블록킹을 제거하는 단계로 이루어지고, i) blocking the edge of the upper surface of the panel to form a space having a desired coating thickness; ii) treating 0.1-2.5 parts by weight of pearl and 0.01-0.2 parts by weight of wax to 100 parts by weight of unsaturated polyester resin in the space; iii) hardening and then removing the blocking of the edges,
    여기서 단계 ii)에서의 처리는 ① 왁스를 점적 적용한 후, 불포화폴리에스테르 수지와 펄의 혼합물을 첨가, ② 불포화폴리에스테르 수지와 펄의 혼합물에 왁스를 혼합하여 첨가, ③ 불포화폴리에스테르 수지와 펄의 혼합물을 첨가한 후 왁스를 점적 적용, 및 ④ 일부 왁스를 점적 적용한 후, 불포화폴리에스테르 수지와 펄의 혼합물을 첨가하고 다시 나머지 왁스를 점적 적용으로 이루어지는 군에서 선택되는 하나로 행해지는 것인 제조방법. Here, the treatment in step ii) is performed by (1) applying a wax dropwise, then adding a mixture of unsaturated polyester resin and pearl, (2) mixing and adding wax to a mixture of unsaturated polyester resin and pearl, and (3) of unsaturated polyester resin and pearl. After the addition of the mixture, the wax is applied dropwise, and ④ some wax is applied dropwise, and then a mixture of unsaturated polyester resin and pearl is added, and the remaining wax is applied to one selected from the group consisting of drop application.
  2. 제 1항에 있어서, 단계 ii)에서 상기 혼합물에 안료가 0.001 ~ 0.05 중량부가 추가로 첨가되는 것인 제조방법. The method according to claim 1, wherein 0.001 to 0.05 parts by weight of a pigment is further added to the mixture in step ii).
  3. 제 1항에 있어서, 단계 i) 이전에, 판넬의 상면을 신나로 닦아내는 처리 단계를 포함하는 것인 제조방법. The method according to claim 1, comprising a processing step of wiping the top surface of the panel with a thinner before step i).
  4. 제 1항에 있어서, 단계 iii) 후에, 생성된 인조대리석의 표면을 연마, 필름코팅지로 코팅 또는 불포화폴리에스테르 수지로의 코팅에 의한 가공처리 단계를 추가로 포함하는 것인 제조방법. The process according to claim 1, further comprising, after step iii), processing the surface of the resulting artificial marble by polishing, coating with a film coated paper or coating with an unsaturated polyester resin.
  5. 제 1항 내지 제 4항중 어느 한 항에 따른 제조방법에 의해 제조된, 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석. Artificial marble having various appearances and luxurious textures, such as natural marble, prepared by the manufacturing method according to any one of claims 1 to 4.
  6. 판넬과 그 한쪽면 상에 불포화폴리에스테르 수지 100 중량부에 대해, 펄 0.1 ~ 2.5 중량부 및 왁스 0.01 ~ 0.2 중량부로 이루어진 대리석 문양/패턴층으로 이루어지고, 천연대리석과 같은 다양한 외관과 고급스러운 질감을 갖는 인조대리석.It consists of a marble pattern / pattern layer consisting of 0.1 to 2.5 parts by weight of pearl and 0.01 to 0.2 parts by weight of wax, with respect to 100 parts by weight of unsaturated polyester resin on the panel and one side thereof. Artificial marble having a.
  7. 제 6항에 있어서, 상기 대리석 문양/팬턴층이 추가로 안료를 0.001 ~ 0.05 중량부로 포함하는 것인 인조대리석.The artificial marble according to claim 6, wherein the marble pattern / panton layer further comprises 0.001 to 0.05 parts by weight of the pigment.
KR1020050127000A 2005-12-21 2005-12-21 A synthetic marble and a preparation method thereof KR100605090B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020050127000A KR100605090B1 (en) 2005-12-21 2005-12-21 A synthetic marble and a preparation method thereof

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR1020050127000A KR100605090B1 (en) 2005-12-21 2005-12-21 A synthetic marble and a preparation method thereof
CN2006800016287A CN101090927B (en) 2005-12-21 2006-07-14 A synthetic marble and a preparation method thereof
PCT/KR2006/002774 WO2007073025A1 (en) 2005-12-21 2006-07-14 A synthetic marble and a preparation method thereof

Publications (1)

Publication Number Publication Date
KR100605090B1 true KR100605090B1 (en) 2006-07-28

Family

ID=37184571

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020050127000A KR100605090B1 (en) 2005-12-21 2005-12-21 A synthetic marble and a preparation method thereof

Country Status (3)

Country Link
KR (1) KR100605090B1 (en)
CN (1) CN101090927B (en)
WO (1) WO2007073025A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100792105B1 (en) 2006-04-17 2008-01-04 최용준 A Synthetic Marble Furniture Upper Plate and A Preparation Method Thereof
WO2008084948A1 (en) * 2007-01-09 2008-07-17 Lg Chem, Ltd. Artificial marble and preparation process thereof
KR100982609B1 (en) 2008-08-07 2010-09-15 김병열 Manufacturing Method of Artificial Marble Having Various Pattern And The Artificial Marble Thereby
KR101172836B1 (en) 2009-11-27 2012-08-10 최용준 A preparation method for a synthetic marble applicable to three dimensional figures
WO2020242012A1 (en) * 2019-05-31 2020-12-03 롯데케미칼 주식회사 Artificial marble
KR20210009008A (en) 2019-07-16 2021-01-26 김병열 Panel having various patterns and its manufacturing method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102718554A (en) * 2011-08-31 2012-10-10 崔容准 Improvement method for manufacturing artificial marble with various surface appearances and product thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03141144A (en) * 1989-10-25 1991-06-17 Matsushita Electric Works Ltd Molding of artificial marble
KR930021341A (en) * 1992-04-24 1993-11-22 최재석 Manufacturing method of artificial marble sanitary ware
KR20000073530A (en) * 1999-05-11 2000-12-05 문재희 The manufacturing method for a specially-coated marble
KR20050020100A (en) * 2003-08-21 2005-03-04 주식회사 엘지화학 Artificial marble having external appearance of mother-of-pearl and method of making the same
KR20050118361A (en) * 2004-06-14 2005-12-19 정진희 Scagliola marble using shell and production method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6157644A (en) * 1984-08-28 1986-03-24 Showa Highpolymer Co Ltd Unsaturated polyester resin composition
TW562783B (en) * 2001-11-06 2003-11-21 Nippon Catalytic Chem Ind Aritificial marble and producing method thereof
CN1363475A (en) * 2001-11-15 2002-08-14 郭旭清 Artificial carved stone as decoration

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03141144A (en) * 1989-10-25 1991-06-17 Matsushita Electric Works Ltd Molding of artificial marble
KR930021341A (en) * 1992-04-24 1993-11-22 최재석 Manufacturing method of artificial marble sanitary ware
KR20000073530A (en) * 1999-05-11 2000-12-05 문재희 The manufacturing method for a specially-coated marble
KR20050020100A (en) * 2003-08-21 2005-03-04 주식회사 엘지화학 Artificial marble having external appearance of mother-of-pearl and method of making the same
KR20050118361A (en) * 2004-06-14 2005-12-19 정진희 Scagliola marble using shell and production method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100792105B1 (en) 2006-04-17 2008-01-04 최용준 A Synthetic Marble Furniture Upper Plate and A Preparation Method Thereof
WO2008084948A1 (en) * 2007-01-09 2008-07-17 Lg Chem, Ltd. Artificial marble and preparation process thereof
KR100975380B1 (en) * 2007-01-09 2010-08-11 (주)엘지하우시스 Artificial marble and preparation method thereof
US8063117B2 (en) 2007-01-09 2011-11-22 Lg Chem, Ltd. Artificial marble and preparation process thereof
KR100982609B1 (en) 2008-08-07 2010-09-15 김병열 Manufacturing Method of Artificial Marble Having Various Pattern And The Artificial Marble Thereby
KR101172836B1 (en) 2009-11-27 2012-08-10 최용준 A preparation method for a synthetic marble applicable to three dimensional figures
WO2020242012A1 (en) * 2019-05-31 2020-12-03 롯데케미칼 주식회사 Artificial marble
KR20210009008A (en) 2019-07-16 2021-01-26 김병열 Panel having various patterns and its manufacturing method
KR102222441B1 (en) 2019-07-16 2021-03-03 김병열 Panel having various patterns and its manufacturing method

Also Published As

Publication number Publication date
CN101090927B (en) 2010-09-15
WO2007073025A1 (en) 2007-06-28
CN101090927A (en) 2007-12-19

Similar Documents

Publication Publication Date Title
KR100605090B1 (en) A synthetic marble and a preparation method thereof
US7258897B1 (en) Process for producing an ornamental surface on a substrate
US20160075925A1 (en) Building material for forming an architectural surface covering and method for producing the same
KR100792105B1 (en) A Synthetic Marble Furniture Upper Plate and A Preparation Method Thereof
KR101438396B1 (en) Shell odorment manufacturing method and shell odorment manufactured by the same
KR20090034628A (en) Ornamental purpose board and the manufacture method to form built-in pattern on formica
JP2877664B2 (en) How to paint a decorative veneer
KR101087677B1 (en) A panel with mother-of-pearl and manufacturing method for the same
KR20190039369A (en) Decoration panel having natural materials and manufacturing method thereof
KR101171644B1 (en) A method making patterns for furniture
CN202577828U (en) Ultraviolet curing PVC film decorating board
KR101172836B1 (en) A preparation method for a synthetic marble applicable to three dimensional figures
US6531009B1 (en) Method and kit for making marble patterned glass articles
CN100497004C (en) Lacquerwork lamp unit making process
KR100982609B1 (en) Manufacturing Method of Artificial Marble Having Various Pattern And The Artificial Marble Thereby
JP2928969B2 (en) Manufacturing method of decorative board
KR20020014495A (en) Synthetic-stone board and manufacturing method of the same
KR100982782B1 (en) Decoration panel for furniture and manufacturing method thereof
KR20130133543A (en) Shell odorment manufacturing method and shell odorment manufactured by the same
CN102718554A (en) Improvement method for manufacturing artificial marble with various surface appearances and product thereof
CN1060069A (en) Producing technology for colour marble grain decorative plate
CN1081970A (en) Sand-adhered plate as decoration and method of manufacturing technology thereof
KR20090046595A (en) A method making patterns for furniture
TW403641B (en) The manufacture method of artifical jade panel
KR100468390B1 (en) A Process For Coloring Of Lacquer Face And Nacre

Legal Events

Date Code Title Description
A201 Request for examination
A302 Request for accelerated examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20120711

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20130530

Year of fee payment: 8

FPAY Annual fee payment

Payment date: 20150115

Year of fee payment: 9

FPAY Annual fee payment

Payment date: 20150810

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20160719

Year of fee payment: 11

FPAY Annual fee payment

Payment date: 20171121

Year of fee payment: 12

FPAY Annual fee payment

Payment date: 20180626

Year of fee payment: 13