KR100499932B1 - The construction materials and method manufacture mortar of drainage firing Urethan - Google Patents

The construction materials and method manufacture mortar of drainage firing Urethan Download PDF

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KR100499932B1
KR100499932B1 KR10-2002-0047193A KR20020047193A KR100499932B1 KR 100499932 B1 KR100499932 B1 KR 100499932B1 KR 20020047193 A KR20020047193 A KR 20020047193A KR 100499932 B1 KR100499932 B1 KR 100499932B1
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weight
urethane
agent
mixed
polyol
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KR20040014027A (en
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허정웅
규수 이 제스파
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허정웅
규수 이 제스파
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 탄성이 강하고 내마모성, 내약품성, 내노화성을 갖는 우레탄 방수몰타르 제조방법에 관한 것으로서, The present invention relates to a urethane waterproof mortar manufacturing method having a strong elasticity, wear resistance, chemical resistance, aging resistance,

더욱 상세하게는 메틸렌디이소시안에이트(MDI) 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합된 프리폴리머 우레탄 A제와, 다기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 첨가제 7.0중량%를 혼합한 우레탄 B제를 1:1로 혼합하는 복합 우레탄을 제조하는 공정과;More specifically, prepolymer urethane A, in which 50% by weight of methylene diisocyanate (MDI) and 50% by weight of polyol having a molecular weight of 2,000 to 4,000 g / mol are mixed, 80% by weight of a polyfunctional polyol mixture, 3.0% by weight of amines, A process for producing a composite urethane in which a urethane B agent in which 10% by weight of pigment and 7.0% by weight of an additive is mixed is mixed 1: 1;

상기 혼합 제조된 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량% 혼합하여서된 우레탄 발포 방수 몰타르 제조방법으로서, 다리 상판 슬래브 및 교각, 옹벽, 건축물 바닥 및 옥상 슬래브, 폐수처리장, 쓰레기 처리장, 수영장 바닥 등의 콘크리트 구조물 보수 및 보강공사 또는 방수처리를 간단 용이하게 시공함과 동시에 견고하게 시공함으로서 관리 및 보수비용을 절감할 수 있도록 한 것이다.50% by weight of the prepared composite urethane, 30% by weight sand, 20% by weight of CO 2 as a urethane foam waterproof mortar manufacturing method, bridge top slab and pier, retaining wall, building floor and rooftop slab, wastewater treatment plant, waste treatment plant , The construction and reinforcement work or waterproofing of concrete structures such as swimming pool floor can be easily and at the same time firmly constructed to reduce management and repair costs.

Description

우레탄 발포 방수 몰타르 제조방법 및 건축부재{The construction materials and method manufacture mortar of drainage firing Urethan}The construction materials and method manufacture mortar of drainage firing Urethan}

본 발명은 탄성이 강하고 내마모성, 내약품성, 내노화성을 갖는 우레탄 방수몰타르 제조방법에 관한 것으로서, 더욱 상세하게는 우레탄 수지와 모래로 이루어진 방수 몰타르 또는 우레탄수지, 모래, 유리 섬유봉, 탄소 섬유봉 등으로 이루어진 방수 몰타르를 제조하여 균열된 건축구조물, 신축건물의 방수제로 사용할 수 있도록 함으로서 시공이 간단 용이하고 방수가 완벽한 방수몰타르 제조방법 및 건축부재에 관한 것이다. The present invention relates to a urethane waterproof mortar manufacturing method having a strong elasticity, wear resistance, chemical resistance, aging resistance, more specifically, waterproof mortar or urethane resin made of urethane resin and sand, sand, glass fiber rods, carbon fiber rods, etc. The present invention relates to a method for manufacturing a waterproofing mortar and a building member, which is simple and easy to construct and perfect for waterproofing, by manufacturing a waterproof mortar made of cracks to be used as a waterproofing agent for a cracked building structure or a new building.

종래에는 사용중인 콘크리트 건축구조에 균열이 발생하여 보수작업을 할 경우 시멘트와 모래, 물을 혼합한 몰타르를 사용하거나 시멘트와 물을 혼합한 시멘트 풀을 사용하였으나 몰타르의 경우 파손된 부분의 공간부를 메우는 용으로는 가능하나 균열이 된 부분 또는 슬래브의 방수처리로는 불가능할 뿐만 아니라 기존의 구조물과 접합이 잘 이루어지지 않는 문제점이 있으며, 시멘트 풀의 경우 균열된 부분의 메움 작업은 어느 정도 효과를 볼 수 있으나 이 역시 기존의 구조물과 시멘트 풀의 양생 후 강도의 차이에 의하여 접합부가 균열되는 문제점이 있었다.Conventionally, when repairing due to cracks in the concrete building structure being used, mortar mixed with cement, sand, and water was used or cement paste mixed with cement and water was used. Although it is possible to use it, but it is not possible to waterproof the cracked part or the slab, and there is a problem that it is difficult to join the existing structure.In the case of cement paste, filling the cracked part may have some effect. However, this also had a problem in that the joint cracks due to the difference in strength after curing of the existing structure and cement paste.

상기의 방법 이외로는 합성수지 실리콘을 주입하여 균열부분을 보수하는 경우가 있으나 이는 보수공사 초기에는 완벽한 접합이 이루어지나 외기의 온도에 약하므로 시간이 지날 수록 점성이 떨어져 재시공해야 하는 문제점 등이 있었다. In addition to the above method, the cracks may be repaired by injecting synthetic resin, but this may be a perfect joint at the beginning of repair work, but it may be weak in the temperature of the outside air, and thus, the viscosity may have to be rebuilt over time.

또한 기존의 다른 예로는 도로시공시 지반침하를 방지하기 위한 방수시트로서 산업폐기물인 폴리우레탄 폼을 재생처리 하여 폴리우레탄쉬트를 얻고 이 쉬트에 고무화아스팔트를 접착하여 고무화아스팔트층을 형성한 다음 그 위에 이 형 필름을 적층시킨 폴리우레탄 방수적층 쉬트가 있었으나, 이러한 종래의 폴리우레탄 방수적층 쉬트는 아스팔트의 온도변화에 따른 상태의 변화 즉 점도의 변화 때문에 장기간이 경과하면 점성이 없어져 경화되고 경화된 아스팔트 층은 온도변화에 따라 팽창과 수축이 되풀이되는 과정에서 접착성이 극히 불량한 폴리에치렌필름층 사이에 간극을 발생시키고 또 박막의 폴리에치렌필름은 시공전의 작업 부주의 몰탈시공시 돌이나 이물질이 혼입되면 표면손상이 쉽게 올 수 있으므로 간극과 필름의 파손은 방수기능을 저하시킨다.In addition, another existing example is a waterproof sheet for preventing ground subsidence during road construction to obtain a polyurethane sheet by recycling polyurethane foam, which is an industrial waste, and to form a rubberized asphalt layer by adhering rubberized asphalt to the sheet. Although there was a polyurethane waterproof laminated sheet in which the mold film was laminated thereon, such a conventional polyurethane waterproof laminated sheet had a viscous property after a long period of time due to the change of state according to the temperature change of asphalt, that is, the viscosity, so that the cured and cured asphalt In the process of repeated expansion and contraction due to temperature change, the layer generates gaps between the layers of polyethylene films which are extremely poor in adhesion, and the polyethylene films of thin films are mixed with stones or foreign substances during mortality during careless work before construction. Surface damage can easily occur. Lowers.

또한 이와 같은 방수쉬트는 쉬트 접착후 그 위에 필히 몰탈 시공이 있어야 하는바 바닥 방수시공시는 몰탈시공작업이 용이하나 벽면 방수시공시는 미끄러운 포리에치렌의 표면 때문에 벽돌을 쌓거나 거푸집을 설치해야 하는 등 시공작업이 극히 번거운 문제점이 있었다.In addition, such a waterproof sheet must be mortar-coated on top of the sheet after bonding. It is easy to mortar the floor during waterproofing, but when waterproofing the wall, it is necessary to stack bricks or form the mold due to the slippery surface of poriethiene. Such construction work was extremely troublesome.

본 발명은 이와 같은 문제점을 감안한 것으로서, 우레탄 수지와 모래 및 CO2가스를 혼합하여 우레탄 방수 몰타르를 제공하여 콘크리트 구조물의 방수와 보수공사및 방수공사를 간단 용이하게 시공하고 보수 관리비용을 최소화 할 수 있도록 함을 목적으로 한 것이다.In view of the above problems, the present invention provides a urethane waterproofing mortar by mixing urethane resin with sand and CO 2 gas, thereby easily and easily constructing and repairing a concrete structure, and waterproofing and minimizing maintenance and management costs. It is for the purpose of making it possible

이와 같은 목적을 갖는 본 발명은 복합 우레탄 수지, 모래등을 유리 섬유봉이나 탄소 섬유봉 사이에 노즐로 분사시공 또는 우레탄수지, 모래로 이루어진 방수 몰 타르를 노즐로 분사하여 시공할 수 있으며 또한 일정한 형틀에 충진시켜 건축부재를 성형함으로서 탄성이 강하고 내마모성, 내약품성, 내노화성을 갖는 우레탄 방수 몰 타르 또는 건축부재를 제공함을 특징으로 한다. The present invention having the above object can be applied by spraying a composite urethane resin, sand, etc. with a nozzle between a glass fiber rod or a carbon fiber rod, or spraying a waterproof mortar made of urethane resin and sand with a nozzle. It is characterized by providing a urethane waterproof mortar or building member having a strong elasticity, wear resistance, chemical resistance, aging resistance by molding the building member by filling in.

이하 본 발명의 제조방법을 상세히 설명하면 다음과 같다.Hereinafter, the manufacturing method of the present invention will be described in detail.

메틸렌디이소시안에이트(이하"MDI"라칭함) 50중량%에 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합되어 이루어진 프리폴리머 우레탄(이하 "우레탄 A제"라칭함)과, A prepolymer urethane (hereinafter referred to as "urethane A") formed by mixing 50% by weight of a polyol having a molecular weight of 2,000 to 4,000 g / mol with 50% by weight of methylene diisocyanate (hereinafter referred to as "MDI"),

다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%과 소포제, 표면강화제, 셀프레벨링제, 자외선방지제를 균등혼합한 첨가제 7.0중량%를 혼합한 베이스 수지(이하"우레탄 B제"라칭함)와, 상기 우레탄 A와 B제를 1:1비율로 혼합하는 복합 우레탄을 제조하는 공정과;Base resin mixed with 80% by weight of polybasic polyol mixture, 3.0% by weight of amines, 10% by weight of pigment, and 7.0% by weight of an additive mixed with an antifoaming agent, a surface hardening agent, a self-leveling agent and a sunscreen agent (hereinafter referred to as "urethane B") Latching), and a process for producing a composite urethane mixing the urethane A and B agent in a 1: 1 ratio;

상기 혼합 제조된 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량% 혼합하여서된 우레탄 발포 방수 몰타르 제조방법을 특징으로 한다.50% by weight of the prepared composite urethane, sand 30% by weight, CO 2 20% by weight, characterized in that the urethane foam waterproof mortar manufacturing method by mixing.

또한 본 발명의 다른 실시 예로서, 상기 혼합된 복합 우레탄 80중량%와 CO2 20중량% 혼합하여서 제조된 방수 몰타르를 특징으로 한다.In addition, another embodiment of the present invention, characterized in that the waterproof mortar prepared by mixing 80% by weight of the mixed composite urethane and 20% by weight of CO 2 .

상기와 같이 제조되는 본 발명의 방수몰타르에 의해 성형되는 건축부재 구조를 살펴보면 다음과 같다.Looking at the structure of the building member molded by the waterproof mortar of the present invention manufactured as described above are as follows.

MDI 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합된 우레탄 A제와, 다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 첨가제7.0중량%를 혼합한 우레탄 B제를 1:1로 혼합한 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량%로 혼합 분사시켜 패널(11)또는 블록(12)을 형성한 건축부재(10)를 특징으로 한다.50% by weight of MDI and 50% by weight of polyol having a molecular weight of 2,000 to 4,000 g / mol are mixed with the urethane A agent, 80% by weight of a polybasic polyol mixture, 3.0% by weight of amines, 10% by weight of pigment, and 7.0% by weight of additive. Characterized by the building member 10 in which the panel 11 or the block 12 was formed by mixing and spraying a mixture of 50% by weight, 30% by weight of sand, 20% by weight of CO 2 , and a mixture of 1 urethane B in a 1: 1 ratio. It is done.

상기 우레탄 B제 제조시 혼합되는 첨가제는 소포제, 표면강화제, 셀프레벨링제, 자외선방지제를 균등하게 1:1 혼합하여 우레탄 B제 총중량 대비 중 첨가제 7.0중량%를 혼합한다. The additives to be mixed during the preparation of the urethane B agent is an equally 1: 1 mixing of an antifoaming agent, a surface strengthening agent, a self-leveling agent, and a sunscreen agent, and mixes 7.0% by weight of the additive with respect to the total weight of the urethane B agent.

상기 첨가제는 거품제거와 제품성형시 표면건조 및 경도와 내화학성에 강하도록하고, 햇빛에 노출시 탈색, 점성력 약화를 방지하게 된다.The additives are resistant to surface drying and hardness and chemical resistance during foam removal and product molding, and to prevent discoloration and weakening of viscous force when exposed to sunlight.

또한 상기 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량%로 혼합된 패널(11) 중앙부에 유리 섬유봉(13)을 井형으로 설치한 것을 특징으로 한다.In addition, the glass fiber rod 13 is installed in the center portion of the panel 11 mixed with 50 wt% of the composite urethane, 30 wt% of sand, and 20 wt% of CO 2 .

이와 같이 구성된 본 발명은 복합 우레탄과 모래를 혼합하거나 또는 복합 우레탄만을 사용하여 방수 몰타르 또는 건축부재로 성형하게 되는데 이때 반드시 CO2를 혼합하여 발포하여 사용한다. In the present invention configured as described above, the composite urethane and sand are mixed or molded into a waterproof mortar or a building member using only the composite urethane. In this case, CO 2 must be mixed and foamed.

본 발명은 기존의 우레탄에 가스를 주입하여 발포된 우레탄과는 상이한 구성을 갖는 것입니다.The present invention is different from the urethane foamed by injecting gas into the existing urethane.

즉, 기존에는 통상적인 우레탄에 경화제와 가스를 주입하여 분사 발포하는 방식으로 식내장시 조형물 등을 만들었으나 이러한 발포 우레탄은 신축성이 전혀 없는 상태이기 때문에 외부의 충격에 쉽게 파손 되는 반면에 본 발명에서 사용되는 복합 우레탄은 강한 접착력과 탄성을 갖고 내마모성, 내약품성, 내노화성을 갖는 도록 하기 위해 MDI 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합된 프리폴리머 우레탄과, 다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 첨가제 7.0중량%를 혼합한 우레탄을 1:1로 혼합하는 복합 우레탄을 제조하였다.That is, in the past, moldings and the like were made by injecting a curing agent and a gas into a conventional urethane by injection foaming, but since the foamed urethane is not in a state of elasticity at all, it is easily damaged by external shocks, while in the present invention The composite urethane used is a prepolymer urethane in which 50% by weight of MDI and 50% by weight of polyol having a molecular weight of 2,000 to 4,000 g / mol are mixed in order to have strong adhesion and elasticity, and to have abrasion resistance, chemical resistance, and aging resistance, and polybasic polyol The composite urethane which mixed the urethane which mixed 80 weight% of mixtures, 3.0 weight% of amines, 10 weight% of pigments, and 7.0 weight% of additives by 1: 1 was prepared.

이와 같이 이루어지는 본 발명의 제조 공정에 따른 실시 예를 상세히 설명하기로 한다.Embodiments according to the manufacturing process of the present invention made as described above will be described in detail.

제1공정: 우레탄 AFirst Step: Urethane A

MDI 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합된 프리폴리머로서, 제조시 반응속도에 특히 주의해야 하는데 100∼200RPM으로 MDI를 교반하면서 폴리올(polyol)을 서서히 주입하면서 온도 45℃를초과 하지 않도록 한다.Prepolymer mixed with 50% by weight of MDI and 50% by weight of polyol with a molecular weight of 2,000 to 4,000 g / mol. Particular attention should be paid to the reaction rate in the preparation.The temperature is slowly infused with polyol while stirring MDI at 100 to 200 RPM. Do not exceed ℃.

상기 폴리올(polyol)을 주입하여 2 시간의 교반한다. 상기 MDI를 교반할 때는 질소가스 분위기에 진행시켜 공기중의 수분 유입을 막도록 한다.The polyol is injected and stirred for 2 hours. When stirring the MDI to proceed to the nitrogen gas atmosphere to prevent the inflow of moisture into the air.

삭제delete

이를 좀더 구체적으로 살펴보면, 폴리올을 크게 두 가지로 나누면 polyether polyol과 polyester polyol로 나눌 수 있는데 최근에는 80~90%정도로 주로 polyether polyol이 많이 쓰여지고 있다. 또한 polyether polyol은 알칼리 촉매하에서 에틸렌 옥사이드와 프로필렌 옥사이드를 중합시켜 만든다. 개시제로서는 낮은 분자량의 di,polyfunctional 알코올 또는 아민이 사용된다. In more detail, the polyol can be divided into two broadly divided into polyether polyol and polyester polyol. Recently, the polyether polyol is mainly used as 80 ~ 90%. Polyether polyols are also made by polymerizing ethylene oxide and propylene oxide under alkali catalysts. As the initiator, low molecular weight di, polyfunctional alcohols or amines are used.

Polyester polyol의 경우에는 di,polycarboxylic acid를 축중합하거나 이들의 anhydride와 di,polyalcohol를 축중합해서 얻는다. 가장 일반적인 polyester polyol은 Adipic acid또는 phthalic anhydride와 탄소 2~6개 정도 포함하고 있는 Diglycol과 같은 oligoether diols또는 glycerol또는 trimethylol propane과 같은 triols과의 반응으로 얻어지며 elastomers나 연질폼, 경질폼 등에 많이 쓰인다. Polyester polyols are obtained by polycondensation of di, polycarboxylic acids or condensation of anhydrides with di, polyalcohols. The most common polyester polyols are obtained by reaction with oligoether diols such as adipic acid or phthalic anhydride and diglycol containing 2 to 6 carbon atoms, or triols such as glycerol or trimethylol propane, and are widely used in elastomers, soft foams and rigid foams.

Polyether polyol은 상대적으로 점도 편차가 적게 생산 할 수 있습니다. 폴리머 폴리올은 polyether polyol에 solid가 분산되어 있는 것을 말하며, 폼의 경도를 높이는데 사용된다.Polyether polyols can produce relatively low viscosity variations. Polymer polyols are solids dispersed in polyether polyols and are used to increase the hardness of foams.

따라서 본 발명은 MDI 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%를 교반 혼합하여 프리폴리머를 제조하고, 프리폴리머 제조시 반응속도에 주의하면서 100∼200RPM으로 MDI를 교반하는 동시에 온도 45℃에서 폴리올(polyol)을 서서히 주입하여 우레탄 A제를 제조하게 된다.Therefore, the present invention is prepared by preparing a prepolymer by stirring and mixing 50% by weight of MDI and 50% by weight of polyol having a molecular weight of 2,000 to 4,000 g / mol, and while stirring the MDI at 100 to 200 RPM while paying attention to the reaction rate when preparing the prepolymer, the temperature is 45 ° C. Injecting a polyol (polyol) slowly to prepare a urethane A.

제2공정: 우레탄 B제 제조Second Step: Manufacture of Urethane B

상기 제1공정에서 우레탄 B제를 제조하여 준비한 다음 다기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 첨가제 7.0중량%를 혼합하여 우레탄 B제를 제조한다. 상기 피그먼트(pigment)는 안료의 영문표기이며, 무기계로서 자외선에 의해 탈색되지 않은 것이며, 그 색상은 현장 조건에 따라 달라지는 것이므로 어느 한가지 색상에는 한정되지 않는다.The urethane B agent is prepared and prepared in the first step, and then the urethane B agent is prepared by mixing 80% by weight of the polyfunctional polyol mixture, 3.0% by weight of amines, 10% by weight of pigment, and 7.0% by weight of an additive. The pigment (pigment) is the English mark of the pigment, is an inorganic system is not bleached by ultraviolet light, the color is not limited to any one color because the color depends on the site conditions.

제3공정: 복합 우레탄제조3rd step: composite urethane

상기 우레탄 A제와 우레탄 B제를 각각 제조한 후에는 A와 B의 우레탄 비율이 1:1로 혼합되도록 하여 복합 우레탄을 제조하게 된다.After the urethane A agent and the urethane B agent are respectively prepared, the urethane ratio of A and B is mixed in a ratio of 1: 1 to prepare a composite urethane.

상기 제1공정과 제2공정에서 제조된 A,B제 우레탄과 이를 혼합하여 제조된 복합우레탄은 모두 액체(수지)과정에서 실시된다.The A and B urethanes prepared in the first step and the second step and the composite urethane prepared by mixing them are all carried out in a liquid (resin) process.

제4공정: 방수 몰타르 제조 4th process: manufacturing waterproof mortar

상기와 같이 제조된 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량% 혼합하여서된 우레탄 발포 방수 몰타르(80)를 제조하게 되는 데, 혼합하는 과정은 일 측에 도 5와 같이 일 측에 우레탄 A제와 우레탄 B제를 수용하는 탱크(20)(20')를 구비하고 각각의 우레탄은 전기히터(30)를 거쳐 송출펌프(40)(40')에 의하여 믹싱 분사노즐(50)로 공급된다. 상기 분사노즐 일측에는 CO2 가스와 모래를 구비한 호퍼(60)가 설치되어 분사노즐(50)의 스위치를 개구시키면 송출펌프(40)(40')의 압력에 의하여 우레탄 A제와 우레탄 B제가 분사되는 동시에 CO2 가스와 모래가 사이폰작용에 의하여 분사되도록 할 수 도 있으며 필요에 따라서 모래가 내장되는 호퍼(60) 일측에 펌프(41)를 설치하여 분사노즐로 공급을 원활히 하도록 한다.50% by weight of the composite urethane prepared as described above, sand 30% by weight, CO 2 20% by weight to prepare a urethane foam waterproof mortar 80 by mixing, the mixing process is one side as shown in Figure 5 on one side And a tank 20, 20 'for accommodating the urethane A agent and the urethane B agent, and each urethane is mixed by the discharge pumps 40 and 40' by the discharge pumps 40 and 40 'through the electric heater 30. Is supplied. One side of the injection nozzle is provided with a hopper 60 having CO 2 gas and sand. When the switch of the injection nozzle 50 is opened, the urethane A agent and the urethane B agent are formed by the pressure of the delivery pumps 40 and 40 '. At the same time, the CO 2 gas and sand may be injected by the siphon action, and a pump 41 is installed at one side of the hopper 60 in which sand is embedded, so as to smoothly supply the spray nozzle.

이때 분사되는 우레탄 A,B와 모래, CO2 가스의 비률은 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량%로 분사노즐에서 믹싱된 후 분사되면 분사된 액체는 우레탄 방수 몰타르(80)가 된다.At this time, the ratio of urethane A, B, sand, and CO 2 gas is 50% by weight of composite urethane, 30% by weight of sand, and 20% by weight of CO 2. )

상기 우레탄 A제와 우레탄 B제는 각각의 용기에서 각각 압축된 공기의 힘에 의해 노즐로 이송되는데, 이때, 이송로의 관이 같은 규격이므로 자연히 1 : 1의 비율로 노즐에서 만나 분사된다.The urethane A agent and the urethane B agent are respectively transferred to the nozzle by the force of compressed air in each container. At this time, since the pipes of the transfer path are the same size, they are naturally sprayed from the nozzle at a ratio of 1: 1.

제5공정: 방수 몰타르 발포 시공5th process: waterproof mortar foaming construction

상기 제1공정 내지 제4공정에 의하여 제조된 본 발명의 우레탄 방수 몰타르는 터널 내부에 균열이 발생되어 누수가된 경우 누수 되는 부분에 분사노즐로 우레탄 방수 몰타르를 분사시키면 균열된 부분에 우레탄 방수 몰타르가 견고하게 달라붙어 이탈됨 없이 방수가 이루어진다.The urethane waterproofing mortar of the present invention prepared by the first step to the fourth process is urethane waterproofing mortar in the cracked portion when spraying the urethane waterproofing mortar with a spray nozzle to the leaked portion when the crack is leaked inside the tunnel Is firmly attached and is waterproof without leaving off.

상기 분사노즐에 의하여 분사되는 우레탄 방수 몰타르는 CO2 가스가 혼합되어 분사되므로 우레탄이 발포되면서 균열부 또는 시공부위에 접착된 후 건조되면 견고하게 균열부를 메우게 되므로 방수와 동시에 보수공사를 마무리하게 된다.The urethane waterproof mortar sprayed by the spray nozzle is mixed with CO 2 gas and sprayed, so urethane is foamed and adhered to the crack or construction site, and when dried, the crack is firmly filled with the crack. .

이와 같이 실시되는 본 발명은 균열된 부분의 내측면 또는 외측면에만 방수몰타르를 분사시켜 접착시키더라도 접착력이 강하므로 별도의 방수공사를 할 필요 없이 견고하게 방수 처리된다. The present invention is carried out in this way, even if the injection by spraying the waterproof mortar only on the inner surface or the outer surface of the cracked portion is strong adhesion because it does not need a separate waterproof construction.

또한 상기와 같이 이루어지는 보수공사는 터널내부 뿐만 아니라 옹벽, 건축물, 하수종말처리장, 쓰레기 처리장의 침출수 누출방지 등으로 사용할 수 있게된다.In addition, the repair work made as described above can be used not only inside the tunnel, but also for preventing leachate leakage from retaining walls, buildings, sewage treatment plants, and waste disposal plants.

또한 건축물, 터널 내부등 전체적으로 전면 보수공사를 할 경우에는 보수공사하고자 하는 부분에 유리 섬유봉을 井형으로 설치한 후 20㎜두께로 우레탄방수 몰타르를 분사시켜 접착층을 형성함으로서 터널 내부 보수공사등을 간단하게 시공할 수 있게 된다.In addition, in the case of the overall renovation work such as the building and the inside of the tunnel, install the fiberglass rods on the part to be renovated in the form of 井 and spray the urethane waterproof mortar with a thickness of 20mm to form the adhesive layer to repair the inside of the tunnel. It is easy to construct.

상기 우레탄 방수 노즐에서 분사되는 분사과정을 간략하게 설명하면, 먼저 우레탄 A제와 우레탄 B제는 각각의 탱크(20)(20')에 구비된 펌프(42)(42')에 의해 전기히터(30)로 펌핑된다. 상기 전기히터(30)에서는 110℉∼120℉의 온도로 가열된 후 송출펌프(40)에 의하여 각각의 통로를 통하여 분사노즐(50)에서 CO2 가스와 모래가 혼합되어 분사되어 발포된다.Briefly describing the spraying process sprayed from the urethane waterproofing nozzle, the urethane A agent and the urethane B agent are first electric heaters (pumps 42 and 42 'provided in the respective tanks 20 and 20'). 30). In the electric heater 30 is heated to a temperature of 110 ° F to 120 ° F and then the CO 2 gas and sand is mixed by the injection nozzle 50 through the respective passages by the delivery pump 40 is injected and foamed.

또한 도면 부호중 90은 CO2가스 탱크이다.In addition, reference numeral 90 denotes a CO 2 gas tank.

상기 터널공사시 우레탄 방수 몰타르를 20㎜의 두께로 형성하는 것은 내부에 설치되는 유리 섬유봉이 6㎜가 교차되어 12mm의 두께를 형성함으로 이를 매몰하고 터널내벽의 완전한 방수가 이루어지도록 하는 동시에 내부의 건축 제한 높이에 따른 공간부가 줄어들지 않는 범위에서 최대한 효과를 얻을 수 있도록 한 것이다. Forming the urethane waterproof mortar with a thickness of 20mm during the tunnel construction means that the glass fiber rods installed therein intersect 6mm to form a thickness of 12mm, so that it is buried and complete waterproofing of the inner wall of the tunnel is achieved. It is to achieve the maximum effect in the range that the space part according to the limit height does not decrease.

또한 본 발명은 상기와 같이 균열된 부분, 판손된 부분을 분사노즐로 직접 분사시켜 시공을 할 수 있지만, 일정한 형상을 갖는 형틀 내에 분사시켜 건축 부재를 형성할 수 있다.In addition, the present invention can be constructed by directly injecting the cracked portion, the damaged portion with a spray nozzle as described above, it can be sprayed in a mold having a predetermined shape to form a building member.

즉, 건축용 패널, 보도블록, 타일, 내외장재 패널의 형상을 갖는 형틀을 제작하여 분사노즐로 우레탄 방수 몰타르를 분사시켜 채우면 건축부재를 성형할 수 있게 된다.That is, the building member can be molded by forming a mold having the shape of a building panel, a sidewalk block, a tile, and an interior and exterior panel by spraying and filling urethane waterproof mortar with a spray nozzle.

상가 분사노즐은 작업을 마무리한 후에는 인측에 연결된 솔벤트 펌프를 이용하여 분사노즐 내부를 청소하여 노즐부가 막히는 것을 방지하게 된다.After finishing the work, the spray nozzle cleans the inside of the spray nozzle using a solvent pump connected to the inside to prevent the nozzle part from being blocked.

본 발명의 우레탄 방수 몰타르로 건축부재의 방수 및 방습성, 유연성 및 신축성, 내마모성 등을 갖는 물성표를 살펴보면 다음의 표와 같다.Looking at the physical properties of the urethane waterproofing mortar of the present invention having a waterproof and moisture-proof, flexibility and elasticity, wear resistance and the like of the building member as shown in the following table.

이상의 /표1에서 알 수 있듯이 본 발명의 방수몰타르는 마모지수 : 15, 접착강도 : >1.000(70.3㎏/㎡), 신장율 : 70%, 경도 : 85, 열노화 : 70℃(30일) 통과, 충격강도 : 크랙무, 투습성 : 0.038, 항파열 : 250PSI, 인장강도 : 1360PSI으로서 상당히 우수한 물성을 갖는 것을 알 수 있으며,As can be seen from Table 1 above, the waterproof mortar of the present invention has a wear index: 15, adhesive strength:> 1.000 (70.3㎏ / ㎡), elongation: 70%, hardness: 85, heat aging: 70 ° C (30 days). , Impact strength: crackless, moisture permeability: 0.038, anti-rupture: 250PSI, tensile strength: 1360PSI.

또한 본 발명의 우레탄 발포 방수 몰타르를 폐수처리장, 쓰레게처리장, 내 약품성 바닥재, 수영장 내부 라이닝, 지하주차장 및 천장에 사용하기 위한 내화학성을 시험한 결과 다음의 표2와 같은 결과를 얻었다.In addition, the urethane foam waterproof mortar of the present invention was tested for chemical resistance for use in wastewater treatment plants, waste treatment plants, chemically resistant flooring, pool linings, underground parking and ceilings, the results are shown in Table 2.

A: 침윤 21℃ 168시간에서 이상무, B: 침윤 24℃ 168시간에서 이상무, N:사용을 권하지 않음을 나타낸 것임.A: No abnormality at 168 hours of infiltration 21 ° C, B: No abnormality at 168 hours of infiltration 24 ° C, N: Not recommended for use.

상기 표2에서 알 수 있듯이 본 발명은 질산 70%와 크실렌을 제외하고는 나머지 화학약품에서 내화학성이 상당히 양호함으로 나타남을 알 수 있다.As can be seen from Table 2, the present invention can be seen that the chemical resistance is very good in the remaining chemicals except for 70% nitric acid and xylene.

본 발명의 우레탄 발포 방수 몰타르는 상기 표 1과 표2에서 알 수 있듯이 점착력이 강한 동시에 내화가성을 갖게 되므로 보강공사 및 보수공사를 한 부분 또는 시공한 건축자재가 쉽게 이탈되거나 파손되지 않고 오래 지속될 수 있다. Urethane foam waterproof mortar of the present invention, as can be seen in Table 1 and Table 2, because it has a strong adhesive strength and fire resistance, it can be long-lasting without removable or damaged construction materials that are part or construction of reinforcement and repair work easily have.

이와 같이 된 본 발명은 터널, 다리 상판 슬래브 및 교각, 옹벽, 건축물 바닥 및 옥상 슬래브, 폐수처리장, 쓰레기 처리장, 수영장 바닥 등의 콘크리트 구조물 보수공사 및 보강공사와 방수처리를 간단 용이하게 시공함과 동시에 견고하게 시공함으로서 관리 및 보수비용을 절감할 수 있게된 효과를 갖는다. The present invention thus achieved a simple and easy construction and reinforcement and waterproofing of concrete structures, such as tunnels, bridge deck slabs and piers, retaining walls, building floors and rooftop slabs, wastewater treatment plants, waste disposal plants, pool floors, etc. By constructing firmly, it is possible to reduce the management and maintenance costs.

도1은 본 발명의 방수몰타르 제조 공정도.1 is a process for producing a waterproof mortar of the present invention.

도2a,2b는 본 발명의 방수몰타르에 의해 제조된 건축부재 사시도.Figure 2a, 2b is a perspective view of the building member produced by the waterproof mortar of the present invention.

도3은 본 발명의 방수몰타르에 의해 제조된 건축부재 단면구성도.Figure 3 is a cross-sectional view of the building member produced by the waterproof mortar of the present invention.

도4a, 4b는 본 발명의 방수몰타르로 시공된 방수구조물 예시도.Figure 4a, 4b is an exemplary view illustrating a waterproof structure constructed of waterproof mortar of the present invention.

도5는 본 발명의 방수 몰타르를 분사 발포 시공하는 분사노즐 구성도.5 is a configuration of a spray nozzle for spraying foaming mortar of the present invention.

<도면의 주요 부분에 대한 부호 설명><Description of the symbols for the main parts of the drawings>

10:건축부재 11:패널10: building member 11: panel

12:블록 13:유리 섬유봉12: Block 13: glass fiber rod

20,20':탱크 30:전기히터20,20 ': Tank 30: Electric Heater

40:송출 펌프 50:분사노즐40: delivery pump 50: injection nozzle

60:호퍼 70:솔벤트 펌프60: Hopper 70: solvent pump

80:방수 몰타르 90:CO2탱크80: waterproof mortar 90: CO 2 tank

Claims (5)

메틸렌디이소시안에이트(MDI) 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합되어 이루어진 프리폴리머 우레탄 A제와, 다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 소포제, 표면강화제, 셀프레벨링제, 자외선방지제가 균등하게 혼합된 첨가제 7.0중량%를 혼합한 우레탄 B제를 1:1비율로 혼합하는 복합 우레탄을 제조하는 공정과;50% by weight of methylene diisocyanate (MDI) and 50% by weight of a polyol having a molecular weight of 2,000 to 4,000 g / mol, a prepolymer urethane A, 80% by weight of a polybasic polyol mixture, 3.0% by weight of amines and pigment 10 A process for producing a complex urethane in which the urethane B agent, in which a weight ratio, an antifoaming agent, a surface hardening agent, a self-leveling agent, and a sunscreen agent is evenly mixed, is mixed at a ratio of 1: 1 by weight; 상기 혼합 제조된 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량% 혼합하는 공정으로 이루어진 것을 특징으로 하는 우레탄 발포 방수 몰타르 제조방법.50% by weight of the prepared composite urethane, sand 30% by weight, CO 2 20% by weight of the urethane foam waterproof mortar manufacturing method comprising the step of mixing. 메틸렌디이소시안에이트(MDI) 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합되어 이루어진 프리폴리머 우레탄 A제와, 다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 소포제, 표면강화제, 셀프레벨링제, 자외선방지제가 균등하게 혼합된 첨가제 7.0중량%를 혼합한 우레탄 B제를 1:1비율로 혼합하는 복합 우레탄을 제조하는 공정과;50% by weight of methylene diisocyanate (MDI) and 50% by weight of a polyol having a molecular weight of 2,000 to 4,000 g / mol, a prepolymer urethane A, 80% by weight of a polybasic polyol mixture, 3.0% by weight of amines and pigment 10 A process for producing a composite urethane in which the urethane B agent is mixed in a 1: 1 ratio by weight, an antifoaming agent, a surface strengthening agent, a self-leveling agent, and an 7.0 wt% additive which is evenly mixed with a sunscreen; 상기 혼합 제조된 복합 우레탄 80 중량%와 CO2 20중량%를 혼합하는 공정으로 이루어진 것을 특징으로 하는 우레탄 발포 방수 몰타르 제조방법.Process for producing polyurethane foam waterproof mortar which is characterized by being a step of mixing the mixture of 80% by weight of the prepared urethane compound and CO 2 20% by weight. MDI 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합되어 이루어진 프리폴리머 우레탄 A제와, 다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 소포제, 표면강화제, 셀프레벨링제, 자외선방지제가 균등하게 혼합된 첨가제7.0중량%를 혼합한 우레탄 B제를 1:1로 혼합시켜서 된 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량%를 형틀에 혼합분사시켜 패널(11)이 이루어진 것을 특징으로 하는 우레탄 발포 방수 건축부재.50% by weight of MDI and 50% by weight of polyol having a molecular weight of 2,000 to 4,000 g / mol, prepolymer urethane A, 80% by weight of polybasic polyol mixture, 3.0% by weight of amines, 10% by weight of pigment, antifoaming agent and surface hardening agent 50% by weight, 30% by weight of sand and 20% by weight of CO 2 were mixed in a mold by mixing urethane B in a 1: 1 ratio of an additive, which was evenly mixed with a self-leveling agent and a sunscreen. Urethane foam waterproof building member, characterized in that the panel 11 is made by spraying. 제3항에 있어서,The method of claim 3, 상기 패널은, 복합 우레탄 50 중량%, 모래 30중량%, CO2 20중량%로 혼합된 패널(11) 중앙부에 유리 섬유봉(13)을 井형으로 설치한 것을 특징으로 하는 우레탄 발포 방수 건축부재.The panel is a urethane foamed waterproof building member, characterized in that the glass fiber rod 13 is installed in the center of the panel 11 mixed with 50% by weight of the composite urethane, 30% by weight, CO 2 20% by weight. . MDI 50중량%와 분자량 2,000∼4,000g/mol의 폴리올 50중량%가 혼합되어 이루어진 프리폴리머 우레탄 A제와, 다염기성 폴리올 혼합물 80중량%, 아민류 3.0중량%, 피그먼트 10중량%, 소포제, 표면강화제, 셀프레벨링제, 자외선방지제가 균등하게 혼합된 첨가제7.0중량%를 혼합한 우레탄 B제를 1:1로 혼합시켜서 된 복합 우레탄 80중량%와 CO2 20중량%가 혼합되어 패널을 이루고, 상기 패널 중앙부에는 유리 섬유봉(13)이 설치된 것을 특징으로 하는 우레탄 발포 방수 건축부재.50% by weight of MDI and 50% by weight of polyol having a molecular weight of 2,000 to 4,000 g / mol, prepolymer urethane A, 80% by weight of polybasic polyol mixture, 3.0% by weight of amines, 10% by weight of pigment, antifoaming agent and surface hardening agent , 80% by weight of the composite urethane B and 20% by weight of CO 2 mixed with a 1: 1 ratio of the urethane B mixed with a 7.0% by weight of the self-leveling agent, a sunscreen additive evenly mixed to form a panel, the panel Urethane foam waterproof building member, characterized in that the glass fiber rod 13 is installed in the center.
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KR101156460B1 (en) * 2011-10-28 2012-06-18 (주)에이엠지그룹건축사사무소 This construction method using mortar and elastic
KR102155884B1 (en) 2020-07-09 2020-09-16 대영산업 주식회사 Manufacturing method and construction member of urethane foam waterproof mortar

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KR100500160B1 (en) * 2002-08-22 2005-07-11 허정웅 The method and equipment operation mortar of drainage firing Urethan
KR100896503B1 (en) * 2007-07-03 2009-05-08 주식회사 이파엘지종합특수방수 Non-solvent type Urethanes which is used to upper membranous of inorganic elastic waterproof
KR200454231Y1 (en) * 2008-09-05 2011-06-23 박영복 The electricty mat

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* Cited by examiner, † Cited by third party
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KR101156460B1 (en) * 2011-10-28 2012-06-18 (주)에이엠지그룹건축사사무소 This construction method using mortar and elastic
KR102155884B1 (en) 2020-07-09 2020-09-16 대영산업 주식회사 Manufacturing method and construction member of urethane foam waterproof mortar

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