KR100418633B1 - Manufacture glue of using charcoals and negativer ion and zeolite - Google Patents

Manufacture glue of using charcoals and negativer ion and zeolite Download PDF

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Publication number
KR100418633B1
KR100418633B1 KR1020020076756A KR20020076756A KR100418633B1 KR 100418633 B1 KR100418633 B1 KR 100418633B1 KR 1020020076756 A KR1020020076756 A KR 1020020076756A KR 20020076756 A KR20020076756 A KR 20020076756A KR 100418633 B1 KR100418633 B1 KR 100418633B1
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South Korea
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powder
zeolite
adhesive
charcoal
stirring
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KR1020020076756A
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Korean (ko)
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박세환
최명부
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최명부
박세환
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks

Abstract

PURPOSE: A method for preparing an adhesive is provided, to obtain an anion-deodorizing effect and an electromagnetic wave-screening effect by using an artificial zeolite and an anion charcoal compound. CONSTITUTION: The method comprises the steps of adding 100 g of an aluminum powder to 1,000 ml of a sodium hydroxide solution (pH 13) with stirring and removing the gas generated, adding 10 g of sodium silicate with stirring, and drying the obtained one at a temperature of 100 deg.C to prepare an artificial zeolite powder; and adding 100 g of the artificial zeolite, 200 g of the charcoal powder of Quercus serrata obtained by heating Quercus serrata at a high temperature of 1,000 deg.C, 100 g of a nickel powder and 50 g of a tourmaline powder to 1,000 ml of a water-soluble acryl binder solution to prepare an adhesive.

Description

인조제오라이트와 음이온 숯화합물을 이용한 접착제 제조{Manufacture glue of using charcoals and negativer ion and zeolite}Manufacture glue of using charcoals and negativer ion and zeolite

본 발명은 접착제의 제조방법에 관한 것으로서, 보다 상세히 설명하면 숯이 가지고 있는 조습작용, 다공성, 연마성, 전기적 특성, 항균성과 또한 인조제오라이트가 가지고 있는 탈취효과 음이온이 가지고 있는 기능과 숯가루와 금속분말 화합물의 유해전자파 차단 기능을 갖는 접착제의 제조방법에 관한 것이다.본발명은 현대 건축자재인 나무 목제, 벽지도료 접착제에는 유해성 화공약품을 사용하여 인체에 미치는 유해성이 매우 크다고 보고되고 있고 또한 세멘트 바닥이나 벽면에는 알카리염 등으로 전위를 상실하여 양이온으로 이루어져 있다, 또한 단열제를 사용하여 내부 공기와 외부공기를 완전 차단하여 실내 공기가 양이온으로 오염되면서 벽면에는 습기 등이 차서 겔로 현상이 생기고 곰팡이 등이 서식하게 되며 비위생적이다.The present invention relates to a method for preparing an adhesive, and in more detail, the humidity, porosity, abrasiveness, electrical properties, antibacterial properties of charcoal, and deodorizing effect of artificial zeolite have an anion and charcoal powder and metal The present invention relates to a method for producing an adhesive having a harmful electromagnetic wave blocking function of a powder compound. The present invention is reported to have a very harmful effect on the human body by using harmful chemicals in wood, wallpaper and paint adhesives, which are modern building materials. On the wall, it is made of cations by losing potential with alkali salts. Also, the inside air and outside air are completely blocked by using a heat insulator, and indoor air is contaminated with cations. Is inhabited and unsanitary.

본 발명은 이러한 문제점을 해결하기 위하여, 숯이 가지고 있는 기능과 음이온이 인체에 미치는 좋은점을 이용하여 참나무를 1000도 고온에 구워진 백탄가루와 대량 음이온 발생물질인 전기석 분말을 사용하면서 특히 탈취효과가 우수한 인조제오라이트를 제조하여 사용하고 특히 참나무 숯가루와 유해전자파를 차단할 수 있도록 닉켈분말과 비철금속 분말은 숯과 같이 합성하여 접착제와 합성하고 벽면에나 바닥에 도포했을 때 금속이 가지고 있는 +이온과 숯이 가지고 있는 수많은 다공질 인 -이온이 유해전자파를 흡착할 수 있도록 한 접착제의 제조방법을 제공하는 것이 본 발명이 이루고자 하는 기술적 과제인 것이다.In order to solve this problem, the deodorizing effect is particularly used while using white charcoal powder baked at 1000 degrees high temperature and tourmaline powder which is a large amount of anion generating material by using charcoal function and anion which is good for human body. Nickel powder and non-ferrous metal powder are synthesized like charcoal, combined with adhesive, and applied to the wall or floor, so that the + ion and charcoal that metal has It is a technical task of the present invention to provide a method for producing an adhesive that allows numerous porous phosphorus-ions to adsorb harmful electromagnetic waves.

상기와 같이 본 발명은 탈취효과가 우수한 인조제오라이트를 제조하기 위하여 가성소오다용액(PH13) 300ml에 알미늄 100g을 합성용해 반응시켜 규산소오다 100g을 합성하여 반응시켜 건조한 분말 100g을 제조하여 참나무 숯가루 200g, 닉켈분말 100g, 전기석분말 50g을 합성 믹스하여 수용성아크릴접착제(고형분 40%)에 합성혼합하여 접착제를 제조하는 방법에 관한 것이다.상기와 같이 제조된 접착제는 세맨트 벽면이나 바닥에 도포하는 도포제로 사용할 수 있다.숯이 가지고 있는 수많은 다공질을 냄새로 흡착하고 세균을 흡착 살균하고 제습효과가 뛰어나므로 이를 사용하면서 벽면이나 천장, 바닥에는 전기가 흐르므로 전자파를 차단하기 위하여 비철금속분말을 참나무숯가루와 합성하여 사용하였다.일본교또대학 목질 연구소 이시하라 교수는 참나무를 1000도 고온에 구운 백탄은 통전성이 있고 수많은 다공질로 되어 있어 유해 전자파나 라돈을 흡착한다고 보고되어 있다.본 발명은 숯이 가지고 있는 음전하에 금속분말인 +이온을 합성하여 유해전자파를 차단한 기술이다.상기와 같이 본 발명의 기능성 접착제로 세맨트 벽면이나 바닥에 도포했을 때 기존세맨트 바닥에 전위가 상실된 것을 전위를 살려주면서 제습탈취, 향균, 음이온 효과를 있게 하여 오염된 공기를 정화시켜 실내 공기를 쾌적하게 하는 것이다.성문이화학사전(삼광인쇄사 1997년 2월 20일 인쇄 1073쪽)에는 전기석 (Tourmalin)은 화학조성의 일반식이 WX3B3Al3(AlSi209)3(O,OH,F)4로서 나타내어지는 (W=Na, Ca; X=Al, Fe,LI,Mg)광물, 6방결정계, 이극상, 보통은 기둥모양인데, 가끔 가늘고 길거나 바늘 모양이기도 하고, 드물게는 편평함, 더욱 드물계는 뿔면인것도 있다고 기재되어 있습니다.본 발명을 실시예를 통하여 보다 상세하게 설명하면 다음과 같다.실시예스덴비커 2000ml에 가성소오다용액(pH13)1000ml에 알루미늄 분말100g을 첨가하여 교반하면서 반응시켜 가스를 날려 보낸 다음, 규산소오다 100g을 투입시켜 교반하면서 반응시켜 건조기에 넣고 100℃로 가열 건조시켜 혼합하여 분말의 인조제오라이트를 제조한 다음, 상기 인조제오라이트 100g과 1000℃ 고온에 구워진 참나무 숯가루 200g, 닉켈분말 100g 및 전기석분말 50g을 수용성아크릴바인다 1000ml용액에 투입 혼합하여 접착제를 제조하였다.As described above, the present invention synthesizes 100 g of aluminum sodium hydroxide in 300 ml of caustic soda solution (PH13) in order to prepare artificial zeolite having excellent deodorizing effect, synthesizes 100 g of sodium silicate, and reacts to prepare dry powder 100 g, and oak charcoal powder. The present invention relates to a method for producing an adhesive by synthetically mixing 200 g, nickel powder 100 g, and tourmaline powder 50 g with a water-soluble acrylic adhesive (solid content 40%). The adhesive prepared as described above is a coating agent applied to Semant wall or floor. Adsorbs numerous pores of charcoal with smell, absorbs and sterilizes germs, and has excellent dehumidification effect. Electricity flows through walls, ceilings, and floors while using them. Ishihara, a professor of timber research at Nihon Kyoto University, White charcoal burned at high temperature has been reported to adsorb harmful electromagnetic waves and radon because it is electrically conductive and numerous porous materials. The present invention is a technique of blocking harmful electromagnetic waves by synthesizing + ion, which is a metal powder, on the negative charge of charcoal. When applied to the sement wall or floor with the functional adhesive of the present invention as described above, the potential of the potential loss on the bottom of the existing semantics while dehumidifying deodorizing, antibacterial, anion effect to clean the contaminated air to make the indoor air pleasant In the Dictionary of Chemicals (Samkwang Printing Co., Ltd., printed on February 20, 1997, p. 1073), tourmaline is represented by the general formula of chemical composition (WX3B3Al3 (AlSi209) 3 (O, OH, F) 4). = Na, Ca; X = Al, Fe, LI, Mg) mineral, hexagonal crystal system, bipolar, usually columnar, sometimes thin, long or needle-like, rarely flat, even rarer The present invention will be described in more detail with reference to the following examples. EXAMPLES 1000 ml of aluminum powder is added to 1000 ml of caustic soda solution (pH13) in 2000 ml of dens beaker and reacted with stirring while blowing gas. Next, 100 g of sodium silicate was added thereto, reacted with stirring, heated to 100 ° C., mixed to prepare artificial zeolite of powder, and then 100 g of artificial zeolite and 200 g of oak charcoal powder baked at 1000 ° C. high temperature and nickel powder. An adhesive was prepared by mixing 100 g and 50 g of tourmaline powder in 1000 ml of a water-soluble acrylic binder.

상기와 같이 본 발명은 음이온과 숯이 가지고 있는 기능을 이용하여 세멘트 벽면이나 바닥제에 도포하여 현대건축 자재에 함유된 각종 유해 냄새를 잡아주고 특히 세맨트 바닥에서 내품는 알카리염을 흡착하고 전위를 상실한 세멘트에 음이온을 발생 시키면서 숯이 가지고 있는 기능을 우리 주거공간에 가깝게 접목시키면서 특히 유해전자파를 차단할 수 있도록 한 것이 특징이다.As described above, the present invention uses various functions of anion and charcoal to apply to the cement wall or floor to catch various harmful odors contained in modern building materials. While generating negative ions in the cement, the charcoal's function is close to our residential space, and especially it can block harmful electromagnetic waves.

Claims (1)

본 발명은 접착제의 제조방법에 있어서,The present invention provides a method for producing an adhesive, 가성소오다용액(pH13) 1000ml에 알루미늄 분말 100g을 첨가하여 교반하면서 반응시켜 가스를 날려 보낸 다음, 규산소오다 100g을 투입시켜 교반하면서 반응시켜 건조기에 넣고 100℃로 가열 건조시켜 혼합하여 분말의 인조제오라이트를 제조한다음, 상기 인조제오라이트 100g과 1000℃ 고온에 구워진 참나무 숯가루 200g, 닉켈분말 100g 및 전기석분말 50g을 수용성아크릴 바인다 1000ml 용액에 투입 혼합하여 제조함을 특징으로 하는 접착제의 제조방법.100 g of aluminum powder was added to 1000 ml of caustic soda solution (pH13), reacted with stirring to blow gas, and then 100 g of sodium silicate was added to react with stirring. After preparing a zeolite, 100 g of artificial zeolite and 200 g of oak charcoal powder baked at a high temperature of 1000 ° C., 100 g of nickel powder, and 50 g of tourmaline powder are added and mixed into a 1000 ml solution of water-soluble acrylic binder.
KR1020020076756A 2002-12-02 2002-12-02 Manufacture glue of using charcoals and negativer ion and zeolite KR100418633B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1303177C (en) * 2005-06-30 2007-03-07 周祖全 Anionic powder and anionic environmental protection adhesive
KR100951918B1 (en) 2010-02-04 2010-04-09 신성종합건축사사무소(주) Method of manufacturing finishing paiting materials for constructure
KR101629635B1 (en) * 2015-05-20 2016-06-21 신수연 The manufacturing method of a nano-silicagel composite and a ocher artificial zeolite composite for toxic spill prevention and the method of use them

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1303177C (en) * 2005-06-30 2007-03-07 周祖全 Anionic powder and anionic environmental protection adhesive
KR100951918B1 (en) 2010-02-04 2010-04-09 신성종합건축사사무소(주) Method of manufacturing finishing paiting materials for constructure
KR101629635B1 (en) * 2015-05-20 2016-06-21 신수연 The manufacturing method of a nano-silicagel composite and a ocher artificial zeolite composite for toxic spill prevention and the method of use them

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