KR100241586B1 - Pressurized transparent apparatus with a foaming composition containing nonionic and amphoteric surfactants - Google Patents

Abstract

The novel pressurized transparent devices containing stable, transparent, very soft foam cosmetic compositions pressurized by hydrocarbon gas do not contain C monohydric alcohols and include nonionic and amphoteric surfactants. The composition is useful for gentle and effective skin cleansing and cosmetic removal.

Description

Pressurized transparent devices for foamable compositions containing nonionic and amphoteric surfactants

The present invention relates to a novel pressurizing device comprising a composition, in particular a cosmetic or skin composition and in particular a composition for cleaning and removing makeup.

The user expects that the cosmetic removal composition will be able to remove all kinds of cosmetics, namely lipsticks, powders, eye shadows, foundations, etc. cleanly and smoothly without damaging the skin. Cleansing the skin is very important for face protection. It should be as effective as possible that fat residues such as excess sebum, daily cosmetics, especially cosmetic residues, and especially water-free, "waterproof" products accumulate in the skin layer and block the pores of the skin. Appear in acne form. Common cosmetic removal is generally in the form of gels, lotions or creams. However, the consumer is waiting for a new type of product, which at the same time can be more aesthetic and pleasant. To meet these expectations, new cosmetic removers and cleaners for the skin have appeared in the form of transparent pressurization devices containing foamable, single phase, transparent, fine and cosmetic removal compositions.

Compositions for topical application in single phase and stable, transparent, foamable, pressurized bottles are especially known in US Pat. No. 3,719,752. These compositions comprise a surfactant and a propellant gas in a hydroalcoholic medium. The alcohol is preferably a C ₁ -C ₃ monohydric alcohol. However, the use of alcohols, especially ethanol, in such compositions poses a risk of flammability. As a result, attempts have been made to avoid the use of C ₁ -C ₃ monohydric alcohols in facial cleansing compositions.

WO95 / 05796 also consists of a hydrocarbon propellant gas and an aqueous concentrate (including α-olefinsulfonate salts, betaines and alkylpolyglucosides) and is a single phase composition, which is a fluid contained in a transparent bottle (1 Is a non-alcohol). However, such a device is not disadvantageous: in particular the composition it contains is not stable over time, in particular a halo of agglomerates of suspensions in the composition appears in storage. Since the pressurized bottle is transparent, such instability is not accepted by the consumer.

EP-676188 describes a similar device comprising a single phase composition (without monohydric alcohol), which is a fluid, consisting of a propellant gas and an aqueous concentrate. The propellant gas comprises a mixture of dimethyl ether and hydrocarbon gas, and the aqueous concentrate contains a surfactant and additionally a coupling agent. It is also known that dimethyl ether is a flammable gas with a very low flash point. Thus, its use increases the risks associated with pressurization devices both in the production site and in the case of users of such devices.

Canadian patent CA-1002256 describes a uniform, transparent pressurization system, which can be used to dispense transparent aqueous cosmetic products, including cosmetic removal products. The use of triethanolamine salts of acyl lactylic acid as surfactants results in a system in which the propellant gas is completely dissolved in the water phase.

US Pat. No. 3,840,465 describes a transparent pressurization system comprising a transparent composition which is free of alcohol and is foamed. Such compositions typically contain an aqueous solution of an anionic foaming surfactant, where the liquid propellant is dispersed by a second surfactant that is soluble in the propellant and not soluble in water.

The compositions described in all these documents and used to cleanse the skin consist essentially of anionic surfactants that destroy the skin's hydro-lipid membrane and make the skin clean but rough.

Thus, surprisingly, the Applicant is a very soft, foaming, stable, transparent cosmetic pressurized with a C ₁ -C ₃ monohydric alcohol-free hydrocarbon gas, which is based on a nonionic surfactant and may comprise one or more amphoteric surfactants. A new device containing the composition has been found.

The present invention is a pressurization device suitable for decomposing foam when the dispensing head is moved, comprising: Composition B comprises a mixture of a surfactant selected from nonionic surfactants and amphoteric surfactants, A pressurization device comprising:

(i) a pressurized bottle with a dispensing head, (ii) a single phase transparent composition contained in the bottle and comprising:

A-0.5-10 wt% propellant gas, B-90-95 wt% aqueous composition.

When the push button contour of the dispensing head is moved, the composition of the present invention is dispensed in the form of a cream that cleans without damaging the skin. The absence of anionic and cationic surfactants in the composition dispensed by these devices has the effect of obtaining a very soft product of blowing agent on the skin and mucous membranes (lips, inside the eyelids), and therefore, for cleaning and in the face, especially makeup Can be used to remove makeup.

The pressurization device used in the present invention is preferably transparent. Such bottles are known and commonly used by those skilled in the art, for example with reference to patent application W095 / 05796 for these bottles. They discovered a surprising feature of the present invention: a transparent emulsion with fluidity comparable to that of water can be seen through a bottle, which is stored in the form of a cream blowing agent via a dispensing means, as previously expected. Not in spray form. Means for dispensing in aerosol bottles known to those skilled in the art can be used. Dispensing bottles and means that can be used in the present invention are shown, for example, in patent application FR-95-12788.

The word "transparent" means that the composition can identify the printed letters of the newspaper placed behind the bottle through the containing bottle. This term means that a 10 cm thick sample of the composition has a maximum light transmittance of at least 4% at any wavelength between 200 nm and 800 nm.

More specifically, the present invention relates to the above pressurizing device, characterized in that the aqueous composition B comprises:

(a) at least one nonionic emulsifying surfactant, (b) at least one nonionic thickening surfactant, aqueous composition B preferably comprises from 1 to 25% by weight of at least one nonionic emulsifying surfactant .

Advantageously, aqueous composition B comprises 1 to 30% by weight of at least one nonionic thickening surfactant.

It is preferred to control composition B, and in particular to control the selection and percentage of thickener (s), which composition B has a Brookfield viscosity of 5 to 200 mPa s, preferably 10 to 150 mPa s. It is adjusted to have.

Any propellant gas known in such applications can be used in the device according to the invention. In particular, hydrocarbon gases such as propane, n-butane, isobutane and mixtures thereof, and fluorinated gases such as chlorodifluoromethane, dichlorodifluoromethane, difluoroethane, chlorodifluoroethane, dichlorotetrafluoro Roethane and the like, and mixtures thereof; Nitrogen, air and carbon dioxide may be mentioned and mixtures thereof may also be used as propellant gas in the present invention. Hydrocarbons containing 2 to 6 carbon atoms are preferably used in the present invention. In the composition of the present invention, it is preferable to contain 1.5 to 4% by weight of the propellant gas relative to the total weight of the composition.

The emulsifying surfactant that can be used in the present invention is preferably selected from those having an HLB balance of 12 to 18. The emulsifier of the HLB balance (hydrophilic-lipophilic balance) is calculated according to the following formula:

HLB = (100-L) / 5

Where L represents the percentage by weight of the lipophilic group relative to the weight of the entire molecule.

These surfactants are preferably selected from polyols containing 2 to 16 carbon atoms and products adding 1 to 200 moles of ethylene oxide or propylene oxide to partial esters of fatty acids containing 12 to 22 carbon atoms. Do. It is advantageous to select such products having a degree of esterification of 2 or less.

Nonionic thickening surfactants which may be used in the present invention are preferably selected from:

C ₁ -C ₆ alkanolamides of α-carboxyl C ₈ -C ₂₂ alkyl ether acids;

a product of adding 10 to 300 moles of ethylene oxide or propylene oxide to a partial ester of a polyol containing β-2 to 16 carbon atoms and a fatty acid containing 12 to 22 carbon atoms;

γ-polyoxyethylenated and / or polyoxypropyleneated and / or polyglycerolated C ₁₂ -C ₂₂ fatty alcohols;

C ₁₂ -C ₂₂ fatty esters of δ-polyoxyethylene and / or polyoxypropylene and / or polyglycerols;

ε- polyethylene glycol and / or polypropylene glycol block copolymers.

It is advantageous for the compositions according to the invention to comprise at least two thickening surfactants, each belonging to two different classes selected from the above thickener classes α-ε.

C ₁ -C ₆ alkanolamides of carboxy C ₈ to C ₂₂ alkyl ether acids represent the product corresponding to formula (I):

Wherein R represents an alkyl chain containing 8 to 30 carbon atoms, R 'represents an alkyl chain containing 1 to 6 carbon atoms, and Y represents an ethylenediyl or 1,3-propylenediyl radical , n is an integer from 0 to 100).

For example, R can be selected from stearyl, oleyl, ricinole, linoleyl, lauryl, myristyl, capryl and palmityl radicals or can be selected from C ₈ -C ₂₂ alkyl radicals. R 'can be selected from, for example, methyl, ethyl, n-propyl, isopropyl, t-propyl, isopropyl, t-butyl and n-hexyl radicals.

Among the partial esters of polyols which may be used in the present invention, in particular glycols, glycerol and sugars such as glucose, fructose, maltose, ribose, arabinose, xylose, lixoose, ribulose, xylose, Mention may be made of alloses, altroses, mannose, gulose, galactose, sucrose and sorbitol.

The following products may, for example, be mentioned among the thickening surfactants which can be used in the present invention: castor oil, monoethanolamide of carboxylic alkyl (C ₁₃ , C ₁₅ ) ether acid (2 EO), carboxylic ether Monoethanolamide of acid (50 EO), oxyethylenated (200 EO) tallow mono- and diglycerides, oxyethylenated (82 EO) tallow mono- and diglycerides, oxyethylenated (78 EO) copra mono- And diglycerides, stearic acid and hydroxystearic acid triglycerides (40 EO), polyethylene glycol monostearate (100 EO), polyglycerolated (3.5 mole) dodecanediol alcohol, oxyethylenated (250 EO) 2-octyldo Decanol, oxyethylenated (100 EO) stearyl alcohol, oxyethylenated (50 EO) oleyl alcohol, polyethylene glycol (50 EO) dioleate, oxyethylenated (200 EO) glycerol palmitate, oxyethylenated (160 EO) Sorbitan Tree Sourceate, oxy-ethylenated (200 EO) sorbitan triisostearate, polyethylene glycol (150 EO) stearate, oxyethylated (120 EO) methylglucose dioleate, oxyethylenated (150 EO) pentaerythritol Tetrastearate, polyethylene glycol (55 EO) dioleate, polyethylene glycol (300 EO) undecylenate and polyethylene glycol (150 EO) distearate.

The following products may be mentioned among the polyoxy alkylenated polyol esters which can be used, for example, as emulsifying surfactants: oxyethylenated (7 EO) glycerol monodecylenate, oxyethylenated (15 EO) glycerol monostearate , Oxyethylenated (20 EO) glycerol monolaurate, oxyethylenated (20 EO) glycerol dilaurate, oxyethylenated (4 EO) diglycerol stearate, oxyethylenated (7 EO) glycerol cocoate, oxyethylene Pyrrolidone carboxylate of glycerol monoisostearate, oxyethylenated (20 EO) glycerol monostearate, oxyethylenated (30 EO) glycerol monostearate, oxyethylenated (4 EO) di Glycerol Stearate, Oxyethylated (30 EO) Copra Mono- and Diglycerides, Oxyethylated (40 EO) Sorbitan Lanoleate, Oxyethylated (20 EO) Rubitano monooleate, oxyethylenated (20 EO) sorbitan trioleate, oxyethylenated (20 EO) sorbitan monopalmitate, oxyethylenated (20 EO) sorbitan monostearate, oxyethylenated (20 EO) sorbitan monolaurate, oxyethylenated (20 EO) sorbitan undecylenate, oxyethylenated (18 EO) sorbitan undecylenate, oxyethylenated (6 EO) sorbitan hexastearate, oxyethylenated (44 EO) sorbitan monolaurate, oxyethylenated (30 EO) sorbitan tetraoleate, oxyethylenated (4 EO) sorbitan monostearate, oxyethylenated (40 EO) sorbitan oleate, oxyethylene Sulfonated (4 EO) sorbitan, monolaurate, oxyethylenated (10 EO) sorbitan monolaurate, oxyethylenated (40 EO) sorbitan tetraoleate, oxyethylenated (3 EO) butylglucoside cocoate , Oxypropyleneated (20 PO) Methylglucoside distearate, oxyethylenated (20 EO) methylglucoside monolaurate, oxyethylenated (20 EO) methylglucose benzoate, oxyethylenated (1.4 EO) caster and sucrose triglyceride ester, oxyethylene Sulfur (2 EO) casters and sucrose triglyceride esters, oxyethylenated (20 EO) methylglucose sesquistearate, oxyethylenated (20 EO) methylglucose distearate, oxyethylenated (4 EO) butanediol monostearate, Oxyethylenated (50 EO) polyethylene glycol monostearate, polyethylene glycol distearate, polyethylene glycol (8 EO) myristate, polyethylene glycol (8 EO) monostearate, polyethylene glycol (20 EO) monostearate, polyethylene glycol (6 EO) laurate, polyethylene glycol (8 EO) distearate, poly Ethylene glycol (8 EO) dilaurate, polyethylene glycol (8 EO) monooleate, tetraethylene glycol diheptanoate, polyethylene glycol (8 EO) dioleate, polypropylene glycol (26 EO) oleate, polyethylene glycol (30 EO) dipolyhydroxystearate (6 hydroxy), polyethylene glycol (40 EO) stearate and polyethylene glycol (8 EO) dilaurate.

All products used in the present invention are commercially available:

C ₁ -C ₆ alkanolamides of carboxylic C ₈ -C ₂₂ alkyl ether acids are for example sold by Henkel (trade name: Comperlan) or by Chem Y (trade name: Aminol);

Products of adding ethylene oxide or propylene oxide to partial esters of polyols and fatty acids are for example sold by BASF ™ (Cremophor) or Amerchol ™ (Glucamate).

Polyoxyethylenated and / or polyoxypropyleneated and / or polyglycerolated C ₁₂ -C ₂₂ fatty acids are for example sold by ICI (trade name: Brij);

C ₁₂ -C ₂₂ fatty acid esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerols are sold, for example, by ICI (trade name: Myrj);

Polyethylene glycol and / or polypropylene glycol block polymers are sold, for example, by ICI (Synperonic).

The present invention preferably relates to said pressurization device, characterized in that the aqueous composition B comprises:

(a) 2-15% by weight of at least one nonionic emulsifying surfactant, (b) 2-15% by weight of at least one nonionic thickening surfactant.

The composition of the present invention preferably comprises from 3 to 10% by weight of at least one thickening surfactant, as defined above. In practice, the amount of thickener used is adjusted to satisfy the above viscosity range. Excess compound in this form results in significant thickening of the composition of the present invention, which then becomes difficult to dispense as an aerosol. Too small amounts will threaten the stability of the composition.

It is advantageous for composition B to further comprise at least one alkylpolyglucoside as a nonionic surfactant. This alkylpolyglucoside preferably represents 0.01 to 10% by weight of B.

The aqueous composition B preferably further comprises at least one amphoteric surfactant in an amount ranging from 0.01 to 15% by weight of B, more preferably 1 to 5% by weight of B.

According to a preferred composition, B comprises:

1-25% by weight of at least one nonionic emulsifying surfactant,

1-30% by weight of at least one nonionic thickening surfactant,

0.01 to 10% by weight of at least one alkylpolyglucoside,

0.01-15% by weight of at least one amphoteric surfactant.

Composition B may comprise up to about 98% water. Water usually means pure demineralized water. However, all or part of the water used in Composition B may optionally be selected from mineral water or thermal water. Typically, mineral water is suitable for consumption, but hot water is not always so. Each of these waters contains in particular dissolved minerals and oligoelements. These waters are known to be used for the purpose of special treatments, such as loss or hydration of the skin and treatment of some form of skin, depending on the specific oligoelements and minerals they contain. Mineral water or hot water will refer to an aqueous and / or mineral solution of oligoelements prepared from natural minerals or hot water and natural minerals or hot water rich in mineral components and / or additionally oligoelements, and purified (demineralized or distilled) water.

Natural hot water or mineral water used in the present invention is, for example, Vittel water, Vichy basin water, Uriage water, Roche Posay water, Bourboule water, Engien Number of Enghien-les-Bains, Number of Saint Gervais-les-Bains, Number of Neris-les-Bains, Number of Allevar-les-Bains , Digne, Maizieres, Neirac-les-Bains, Lons-le-Saunier, Les Eaux Bonnes water, Rocheforrt water, Saint Christau water, Fumades water, Tercis-les-bains water and Avene water Can be.

The cosmetic or skin compositions of the present invention may additionally contain auxiliaries customary in the art, such as preservatives, antioxidants, fragrances, blockers, colorants and hydrophilic or lipophilic agents.

Skin preparations include anti-aging agents, anti-wrinkle agents, hydrating or wetting agents, depigmenting agents, preparations for free radicals (oxygen radical species), nutrients, protective agents, restructuring agents, hardeners, anti-acne agents, peeling agents, emollients, or And other agents for the treatment of skin such as filamentous fungal disease, dermatitis, psoriasis, and the like. Depending on their nature, these agents can be used in conventional ratios, for example 0.01 to 10% by weight relative to the total weight of the composition.

α-hydroxy acids (glycolic acid, lactic acid, malic acid, citric acid and similar acids) may be more particularly anti-acne, anti-aging, anti-wrinkle, hydrating and releasing agents.

Sulfite may be mentioned, for example, as an antioxidant.

The following examples are intended to illustrate the invention but not to limit it.

Compositions B1-B16 were prepared according to the data in Table I. These compositions are then placed in a pressurized bottle with a dispensing head into which pressurized gas is introduced. The whole is stirred to obtain a uniform mixture of the initial two phases. The device is evaluated in Table 1.

In Table I:

All amounts are expressed in weight percent of the active substance relative to the total amount of the composition.

Sodium N-cocoylaminodoethyl, N-ethoxycarboxymethylglycinate amphoteric surfactants are "Miranol C2M" (trade name, manufactured by Rhone Poulenc), "Plantaren 2000" (trade name, manufactured by Henkel), alkyl (C ₈ / C ₁₀ / C ₁₂ / C ₁₄ / C ₁₆ 29/37/23/9/2) polyglucoside, "Tween 20" is oxyethylenated (20 EO) sorbitan monolaurate (nonionic Surfactants) (ICI sold). Except for Lucas water, the water used in the examples is demineralized water.

After evaluating the viscosity mPa s of the aqueous compositions B ₁ to B ₁₆ , these aqueous compositions were packaged in a transparent pressurized bottle by introducing 97% by weight of the composition and 3% by weight of isobutane into the bottle. After several months of storage at room temperature, the transparency and stability of these pressurization devices are continuously measured.

The viscosity is expressed in mPa s. Viscosity is measured at 25 ° C. with the aid of Brookfield viscosity at which the speed of the Roto module (Module 1) is fixed at 5 rpm.

Transparency is indicated by +, 0 or-(+ = transparent, 0 = halo,-= turbid),

-Stability is expressed as 0 or 1 (1 = stable, 0 = unstable).

Each thickener is represented by T ₁ to T ₁₀ :

T ₁ : copra acid monoethanolamide

T ₂ : caster oil

T ₃ : oleyl alcohol EO (50 EO)

T ₄ : stearic acid amide (C ₁₆ / C ₁₈ 30/70) (50 EO)

T ₅ : methylglucoside dioleate (120 EO)

T ₆ : oxyethylenated (160 EO) sorbitan triisostearate

T ₇ : polyglycerolated (3.5 mol) dodecanediol alcohol

T ₈ : PEG (100 EO) monostearate

T ₉ : block polymer of polyoxyethylene and polyoxypropylene (EO / PO / EO 98/67/98)

T ₁₀ : oxyethylenated (200 EO) palm glycerides and oxyethylenated (70 EO) copra glycerides (80/20)

T ₁₁ : oxyethylenated (60 EO) cetylstearyl (C ₁₆ / C ₁₈ ) alcohol ether of myristyl glycol.

All compositions except B ₃ are transparent and do not exhibit halo at the time of manufacture or after several months of storage. Example B ₃ is not included in the present invention.

TABLE 1a

TABLE 1b

Claims (30)

A pressurization device suitable for dispensing foam when the dispensing head is moved, comprising: Composition B comprises a mixture of a surfactant selected from nonionic surfactants and amphoteric surfactants, Including pressurization device: (i) a pressurized bottle with a dispensing head, (ii) a single phase transparent composition comprising: A-0.5-10 wt% propellant gas, B-90-95 wt% aqueous composition. The apparatus of claim 1 wherein the pressurized bottle is transparent. The device of claim 1 or 2, wherein the aqueous composition B comprises: (a) at least one nonionic emulsifying surfactant, (b) at least one nonionic thickening surfactant. The device of claim 1, wherein the aqueous composition B comprises 1 to 25% of at least one nonionic emulsifying surfactant. The device of claim 1, wherein the aqueous composition B comprises 1-30% of at least one nonionic thickening surfactant. The device of claim 1, wherein composition B has a Brookfield viscosity of 5 to 200 mPa s. The device of claim 1, wherein composition B comprises 1.5 to 4% propellant gas. The device according to claim 1, wherein the gas is selected from hydrocarbon gases containing 2 to 6 carbon atoms. 4. The device of claim 3, wherein the emulsifying surfactant is selected from those having an HLB balance of 12-18. The emulsifying surfactant according to claim 3, wherein 1 to 200 moles of ethylene oxide or propylene oxide are added to the partial ester of the polyol containing 2 to 16 carbon atoms and the fatty acid containing 12 to 22 carbon atoms. Apparatus characterized in that it is selected from the product. The apparatus of claim 10 wherein the emulsifying surfactant has an esterification degree of 2 or less. The device of claim 3, wherein the thickening surfactant is selected from: 10 to 10 partial esters of C ₁ -C ₆ alkanolamides of α-carboxyl C ₈ -C ₂₂ alkyl ether acids, polyols containing 2 to 16 carbon atoms and fatty acids containing 12 to 22 carbon atoms At least one selected from products adding 300 moles of ethylene oxide or propylene oxide, γ-polyoxyethylenated, polyoxypropyleneated and polyglycerolated C ₁₂ -C ₂₂ fatty alcohols, δ-polyoxyethylene, poly At least one selected from C ₁₂ -C ₂₂ fatty esters of oxypropylene and polyglycerol, at least one selected from ε- polyethylene glycol and polypropylene glycol block copolymers. The device of claim 12, wherein the aqueous composition B comprises at least two thickening surfactants, each belonging to two different classes selected from the thickener classes α-ε. 14. The polyol according to any one of claims 10 to 13, wherein the polyol is glycol, glycerol, glucose, fructose, maltose, ribose, arabinose, xylose, lixoose, ribulose, xylose, Apparatus characterized in that it is selected from allose, altrose, mannose, gulose, galactose, sucrose and sorbitol. The thickening surfactant according to claim 3, wherein the thickening surfactant is castor oil, monoethanolamide of carboxylic alkyl (C ₁₃ , C ₁₅ ) ether acid (2 EO), monoethanolamide of carboxylic ether acid (50 EO), oxy Ethyleneated (200 EO) tallow mono- and diglycerides, oxyethylenated (82 EO) tallow mono- and diglycerides, oxyethylenated (78 EO) copra mono- and diglycerides, stearic acid and hydroxystearic acid Triglycerides (40 EO), polyethylene glycol monostearate (100 EO), polyglycerolated (3.5 mole) dodecanediol alcohol, oxyethylenated (250 EO) 2-octyldodecanol, oxyethylenated (100 EO) ste Aryl alcohol, oxyethylenated (50 EO) oleyl alcohol, polyethylene glycol (50 EO) dioleate, oxyethylenated (200 EO) glycerol palmitate, oxyethylenated (160 EO) sorbitan triisostearate, oxyethylene Tues (200 EO) Sorbitant Lysostearate, polyethylene glycol (150 EO) stearate, oxyethylenated (120 EO) methylglucose dioleate, oxyethylenated (150 EO) pentaerythritol tetrastearate, polyethylene glycol (55 EO) dioleate, Device selected from polyethylene glycol (300 EO) undecylenate and polyethylene glycol (150 EO) distearate. 4. The emulsifying surfactant according to claim 3, wherein the emulsifying surfactant is oxyethylenated (7 EO) glycerol monoundecenate, oxyethylenated (15 EO) glycerol monostearate, oxyethylenated (20 EO) glycerol monolaurate, oxyethylene Pyrrolidonecarbylated (20 EO) glycerol dilaurate, oxyethylenated (4 EO) diglycerol stearate, oxyethylenated (7 EO) glycerol cocoate, oxyethylenated (25 EO) glycerol monoisostearate Carboxylate, oxyethylenated (20 EO) glycerol monostearate, oxyethylenated (30 EO) glycerol monostearate, oxyethylenated (4 EO) diglycerol stearate, oxyethylenated (30 EO) copra mono- and Diglycerides, oxyethylenated (40 EO) sorbitan ranoleate, oxyethylenated (20 EO) sorbitan monooleate, oxyethylenated (20 EO) sorbitan trioleate, oxyethylenated (20 EO) sorbitan monopalmitate, oxyethylenated (20 EO) sorbitan monostearate, oxyethylenated (20 EO) sorbitan monolaurate, oxyethylenated (20 EO) sorbitan undecylenate, oxyethylenated (18 EO) sorbitan undecylenate, oxyethylenated (6 EO) sorbitan hexastearate, oxyethylenated (44 EO) sorbitan monolaurate, oxyethylenated (30 EO) sorbitan tetraoleate, oxy Ethylenated (4 EO) sorbitan monostearate, oxyethylenated (40 EO) sorbitan oleate, oxyethylenated (4 EO) sorbitan monolaurate, oxyethylenated (10 EO) sorbitan monolaurate, Oxyethylenated (40 EO) sorbitan tetraoleate, oxyethylenated (3 EO) butylglucoside cocoate, oxypropyleneated (20 PO) methylglucoside distearate, oxyethylenated (20 EO) methylglucoside Mono laulay , Oxyethylenated (20 EO) methylglucose benzoate, oxyethylenated (1.4 EO) caster and sucrose triglyceride ester, oxyethylenated (2 EO) caster and sucrose triglyceride ester, oxyethylenated (20 EO) methylglucose Quistearate, oxyethylenated (20 EO) methylglucose distearate, oxyethylenated (4 EO) butanediol monostearate, oxyethylenated (50 EO) polyethylene glycol monostearate, polyethylene glycol distearate, polyethylene glycol (8 EO) myristate, polyethylene glycol (8 EO) monostearate, polyethylene glycol (20 EO) monostearate, polyethylene glycol (6 EO) laurate, polyethylene glycol (8 EO) distearate, polyethylene glycol (8 EO) dilaurate, polyethylene glycol (8 EO) monooleate, tetraethylene Glycol diheptanoate, polyethylene glycol (8 EO) dioleate, polypropylene glycol (26 EO) oleate, polyethylene glycol (30 EO) dipolyhydroxystearate (6 hydroxy), polyethylene glycol (40 EO) stearate And polyethylene glycol (8 EO) dilaurate. The device of claim 1 or 2, wherein the aqueous composition B comprises: (a) 2 to 15 weight percent of at least one nonionic emulsifying surfactant, (b) 2 to 15 weight percent of at least one nonionic thickening surfactant. The device according to claim 1 or 2, wherein the aqueous composition B comprises 3 to 12% by weight of at least one nonionic emulsifying surfactant. The device according to claim 1 or 2, wherein the aqueous composition B has a Brookfield viscosity of 10 to 150 mPa. The device of claim 1 or 2, wherein the aqueous composition comprises 3 to 6 weight percent of at least one thickening surfactant. The device according to claim 1 or 2, wherein the aqueous composition B comprises at least one alkylpolyglucoside as a nonionic surfactant. The device according to claim 1 or 2, wherein the aqueous composition B comprises 0.01 to 15% by weight of at least one alkylpolyglucoside. The device according to claim 1 or 2, wherein the aqueous composition B comprises at least one surfactant. The device of claim 23, wherein the amphoteric surfactant is present in the aqueous composition B in an amount from 0.01 to 15 wt%. The device of claim 1 or 2, wherein B comprises: 1-25% by weight of at least one nonionic emulsifying surfactant, 1-30% by weight of at least one nonionic thickening surfactant, 0.01 to 10% by weight of at least one alkylpolyglucoside, 0.01-15% by weight of at least one amphoteric surfactant. The device of claim 1 or 2, wherein the composition comprises mineral or hot water. The device of claim 1 or 2, wherein the composition further comprises at least one auxiliary agent selected from preservatives, antioxidants, fragrances, blockers, colorants and hydrophilic or lipophilic agents. 3. The device of claim 1, wherein the composition additionally comprises at least one α-hydroxy acid. 4. The device according to claim 1 or 2, wherein the composition further comprises at least one antioxidant selected from sulfites. The device according to claim 1 or 2, wherein the composition is suitable for cleaning and protecting human skin.