JPWO2022094706A5 - - Google Patents
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- Publication number
- JPWO2022094706A5 JPWO2022094706A5 JP2023527332A JP2023527332A JPWO2022094706A5 JP WO2022094706 A5 JPWO2022094706 A5 JP WO2022094706A5 JP 2023527332 A JP2023527332 A JP 2023527332A JP 2023527332 A JP2023527332 A JP 2023527332A JP WO2022094706 A5 JPWO2022094706 A5 JP WO2022094706A5
- Authority
- JP
- Japan
- Prior art keywords
- calcium
- impurities
- feedstock
- metal sulfate
- leach solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012535 impurity Substances 0.000 claims 80
- 238000000034 method Methods 0.000 claims 73
- 229910052751 metal Inorganic materials 0.000 claims 71
- 239000002184 metal Substances 0.000 claims 71
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 62
- 239000011575 calcium Substances 0.000 claims 62
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 58
- 239000000243 solution Substances 0.000 claims 58
- 229910052791 calcium Inorganic materials 0.000 claims 56
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 46
- 239000011777 magnesium Substances 0.000 claims 46
- 229910052749 magnesium Inorganic materials 0.000 claims 46
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 37
- 229910052744 lithium Inorganic materials 0.000 claims 37
- -1 basic metal salts Chemical class 0.000 claims 24
- 238000002386 leaching Methods 0.000 claims 21
- 229910052728 basic metal Inorganic materials 0.000 claims 18
- 239000012452 mother liquor Substances 0.000 claims 18
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 15
- 238000005342 ion exchange Methods 0.000 claims 15
- 238000000638 solvent extraction Methods 0.000 claims 15
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 13
- 229910001634 calcium fluoride Inorganic materials 0.000 claims 12
- 239000003153 chemical reaction reagent Substances 0.000 claims 12
- 239000003795 chemical substances by application Substances 0.000 claims 12
- 239000000463 material Substances 0.000 claims 12
- 239000007864 aqueous solution Substances 0.000 claims 10
- 238000002425 crystallisation Methods 0.000 claims 9
- 230000008025 crystallization Effects 0.000 claims 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 8
- 238000004519 manufacturing process Methods 0.000 claims 8
- 238000011144 upstream manufacturing Methods 0.000 claims 8
- 230000002378 acidificating effect Effects 0.000 claims 6
- 238000000605 extraction Methods 0.000 claims 6
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical class [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims 6
- 239000007800 oxidant agent Substances 0.000 claims 6
- 230000001376 precipitating effect Effects 0.000 claims 6
- 238000005201 scrubbing Methods 0.000 claims 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims 6
- 239000002904 solvent Substances 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- 239000011260 aqueous acid Substances 0.000 claims 4
- 229940044175 cobalt sulfate Drugs 0.000 claims 4
- 229910000361 cobalt sulfate Inorganic materials 0.000 claims 4
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims 4
- 229910000000 metal hydroxide Inorganic materials 0.000 claims 4
- 150000004692 metal hydroxides Chemical class 0.000 claims 4
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 3
- 229910021583 Cobalt(III) fluoride Inorganic materials 0.000 claims 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 3
- 235000019738 Limestone Nutrition 0.000 claims 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims 3
- 239000003463 adsorbent Substances 0.000 claims 3
- YCYBZKSMUPTWEE-UHFFFAOYSA-L cobalt(ii) fluoride Chemical compound F[Co]F YCYBZKSMUPTWEE-UHFFFAOYSA-L 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 238000007599 discharging Methods 0.000 claims 3
- 239000010440 gypsum Substances 0.000 claims 3
- 229910052602 gypsum Inorganic materials 0.000 claims 3
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 3
- 239000004571 lime Substances 0.000 claims 3
- 239000006028 limestone Substances 0.000 claims 3
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 claims 3
- 239000012528 membrane Substances 0.000 claims 3
- 239000002244 precipitate Substances 0.000 claims 3
- 238000007670 refining Methods 0.000 claims 3
- 235000013024 sodium fluoride Nutrition 0.000 claims 3
- 239000011775 sodium fluoride Substances 0.000 claims 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims 2
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims 2
- 239000005708 Sodium hypochlorite Substances 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims 2
- 229940099596 manganese sulfate Drugs 0.000 claims 2
- 235000007079 manganese sulphate Nutrition 0.000 claims 2
- 239000011702 manganese sulphate Substances 0.000 claims 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims 2
- 229940053662 nickel sulfate Drugs 0.000 claims 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229940043430 calcium compound Drugs 0.000 claims 1
- 150000001674 calcium compounds Chemical class 0.000 claims 1
- 150000001868 cobalt Chemical class 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 150000002696 manganese Chemical class 0.000 claims 1
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 150000002815 nickel Chemical class 0.000 claims 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202063109227P | 2020-11-03 | 2020-11-03 | |
| US63/109,227 | 2020-11-03 | ||
| PCT/CA2021/051557 WO2022094706A1 (en) | 2020-11-03 | 2021-11-03 | Treatment process for crystallizing a metal sulfate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2023551108A JP2023551108A (ja) | 2023-12-07 |
| JP2023551108A5 JP2023551108A5 (https=) | 2024-11-12 |
| JPWO2022094706A5 true JPWO2022094706A5 (https=) | 2024-11-12 |
Family
ID=81457479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2023527332A Pending JP2023551108A (ja) | 2020-11-03 | 2021-11-03 | 金属硫酸塩を結晶化するための処理方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US12441621B2 (https=) |
| EP (1) | EP4240879A1 (https=) |
| JP (1) | JP2023551108A (https=) |
| KR (1) | KR20230100733A (https=) |
| CN (1) | CN116745236A (https=) |
| AU (1) | AU2021376545A1 (https=) |
| CA (1) | CA3174158A1 (https=) |
| CL (1) | CL2023001276A1 (https=) |
| CU (1) | CU20230021A7 (https=) |
| WO (1) | WO2022094706A1 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH12023551304A1 (en) | 2020-11-12 | 2023-11-20 | Hatch Ltd | Processes and methods for production of crystallized metal sulfates |
| KR20230145474A (ko) | 2021-02-18 | 2023-10-17 | 해치 리미티드 | 리튬 및 배터리 화학물질 생성 시 황산나트륨 부산물 가공 |
| CN113321248B (zh) * | 2021-06-23 | 2024-05-03 | 湖南金源新材料股份有限公司 | 镍粉制备电子级硫酸镍的方法及结晶装置，以及结晶装置的控制方法 |
| JP7099592B1 (ja) * | 2021-06-25 | 2022-07-12 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| KR20240024618A (ko) * | 2022-08-17 | 2024-02-26 | 에스케이이노베이션 주식회사 | 황산 니켈 제조 방법 |
| WO2024055117A1 (en) * | 2022-09-16 | 2024-03-21 | Manganese X Energy Corp. | Process for the purification of manganese sulfate solutions and subsequent crystallization of high purity manganese sulfate monohydrate |
| US20240228310A1 (en) * | 2023-01-06 | 2024-07-11 | Lithium Nevada Corporation | Magnesium removal process |
| MX2024001254A (es) * | 2023-01-11 | 2024-02-14 | Korea Zinc Co Ltd | Metodo para producir una disolucion de sulfato del niquel para una bateria secundaria a partir de un catodo de niquel. |
| WO2024249268A2 (en) * | 2023-05-26 | 2024-12-05 | Energy Exploration Technologies, Inc. | Compositions and methods for extracting lithium from an aqueous solution |
| WO2025179340A1 (en) * | 2024-02-27 | 2025-09-04 | Commonwealth Scientific And Industrial Research Organisation | A process for manganese purification |
| WO2025206012A1 (ja) * | 2024-03-26 | 2025-10-02 | 三菱マテリアル株式会社 | 金属硫酸塩結晶の製造方法および金属硫酸塩 |
Family Cites Families (27)
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|---|---|---|---|---|
| FR1597569A (https=) | 1968-10-21 | 1970-06-29 | ||
| FI68422C (fi) | 1983-10-21 | 1985-09-10 | Outokumpu Oy | Hydrometallurgiskt foerfarande foer behandling av klorider ochfluorider innehaollande raoaemnen av vaerdefulla metaller |
| JP4216626B2 (ja) * | 2003-03-20 | 2009-01-28 | 新日本製鐵株式会社 | ニッケル含有廃液スラッジからの硫酸ニッケルの回収方法 |
| JP4216657B2 (ja) * | 2003-06-26 | 2009-01-28 | 新日本製鐵株式会社 | ニッケル含有廃液スラッジからの硫酸ニッケルの回収方法 |
| CN102286661A (zh) * | 2011-08-25 | 2011-12-21 | 云南锡业集团（控股）有限责任公司 | 一种红土镍矿硫酸浸出直接电解的方法 |
| JP5904459B2 (ja) * | 2011-11-22 | 2016-04-13 | 住友金属鉱山株式会社 | 高純度硫酸ニッケルの製造方法 |
| CN102417982A (zh) * | 2011-11-29 | 2012-04-18 | 南通库博新材料有限公司 | 一种采用萃取方法去除钙和镁的方法 |
| CN102534223B (zh) * | 2012-01-09 | 2014-09-17 | 湖南邦普循环科技有限公司 | 一种从废旧锂离子电池中回收有价金属的方法 |
| US10522884B2 (en) | 2012-04-04 | 2019-12-31 | Worcester Polytechnic Institute | Method and apparatus for recycling lithium-ion batteries |
| US10266912B2 (en) * | 2012-11-07 | 2019-04-23 | Lixivia, Inc. | Processed slag and methods for producing same |
| CN103011296B (zh) * | 2012-12-07 | 2014-12-10 | 中信大锰矿业有限责任公司 | 以软锰矿粉做原料还原法生产高纯硫酸锰的方法 |
| PT3417082T (pt) * | 2016-02-18 | 2022-11-08 | Li Tech Pty Ltd | Recuperação de lítio a partir de minerais de fosfato |
| JP6613954B2 (ja) | 2016-02-25 | 2019-12-04 | 住友金属鉱山株式会社 | ニッケル水溶液の製造方法 |
| CN105712383A (zh) | 2016-04-22 | 2016-06-29 | 四川天齐锂业股份有限公司 | 利用萃取法除去富锂溶液中钙、镁杂质的方法 |
| CN108002408B (zh) * | 2016-10-31 | 2021-06-04 | 湖南金源新材料股份有限公司 | 电池废料制备硫酸镍、锰、锂、钴及四氧化三钴的方法 |
| US10246343B2 (en) | 2016-11-11 | 2019-04-02 | Rocher Manganese, Inc. | Processing of cobaltous sulpha/dithionate liquors derived from cobalt resource |
| CN107416908B (zh) * | 2017-05-27 | 2019-03-19 | 广东芳源环保股份有限公司 | 一种低成本制备高纯硫酸锰溶液的方法 |
| JP7253538B2 (ja) | 2017-09-28 | 2023-04-06 | リサイクレージ・リチオン・インコーポレーテッド | リチウムイオン電池リサイクル方法 |
| CN109055757B (zh) * | 2018-09-10 | 2020-04-03 | 吉首大学 | 一种回收电解锰或电解锌的阳极渣中二氧化锰和铅的方法 |
| EP3856941A4 (en) | 2018-09-27 | 2022-06-15 | IGO Limited | Method for preparing a high-purity hydrated nickel sulphate |
| CN109279667A (zh) | 2018-10-09 | 2019-01-29 | 金川集团股份有限公司 | 一种以氧化镍为原料生产电池级硫酸镍的方法 |
| EP3670686A1 (en) | 2018-12-21 | 2020-06-24 | A.C.N. 630 589 507 Pty Ltd | Battery recycling process |
| CN109734107A (zh) | 2018-12-28 | 2019-05-10 | 池州西恩新材料科技有限公司 | 一种锂电池废正极材料的资源化回收方法 |
| CN111233006A (zh) * | 2020-02-28 | 2020-06-05 | 上海晶宇环境工程股份有限公司 | 一种含有氯化钠的杂盐的处理方法及装置 |
| CN111411228B (zh) * | 2020-05-28 | 2021-08-10 | 中钢天源股份有限公司 | 一种从镍钴镁混合溶液中萃取分离镍、钴、镁的方法 |
| US10995014B1 (en) * | 2020-07-10 | 2021-05-04 | Northvolt Ab | Process for producing crystallized metal sulfates |
| CN113106257B (zh) * | 2021-04-12 | 2022-11-29 | 广东佳纳能源科技有限公司 | 锂电池废料的回收利用方法及其应用 |
-
2021
- 2021-11-03 CN CN202180083821.4A patent/CN116745236A/zh active Pending
- 2021-11-03 CA CA3174158A patent/CA3174158A1/en active Pending
- 2021-11-03 JP JP2023527332A patent/JP2023551108A/ja active Pending
- 2021-11-03 EP EP21887949.2A patent/EP4240879A1/en active Pending
- 2021-11-03 WO PCT/CA2021/051557 patent/WO2022094706A1/en not_active Ceased
- 2021-11-03 CU CU2023000021A patent/CU20230021A7/es unknown
- 2021-11-03 AU AU2021376545A patent/AU2021376545A1/en active Pending
- 2021-11-03 KR KR1020237018455A patent/KR20230100733A/ko active Pending
-
2022
- 2022-10-31 US US17/977,408 patent/US12441621B2/en active Active
-
2023
- 2023-05-03 CL CL2023001276A patent/CL2023001276A1/es unknown
-
2025
- 2025-09-11 US US19/325,776 patent/US20260070803A1/en active Pending
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