JPWO2022054279A5 - - Google Patents
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- Publication number
- JPWO2022054279A5 JPWO2022054279A5 JP2022547362A JP2022547362A JPWO2022054279A5 JP WO2022054279 A5 JPWO2022054279 A5 JP WO2022054279A5 JP 2022547362 A JP2022547362 A JP 2022547362A JP 2022547362 A JP2022547362 A JP 2022547362A JP WO2022054279 A5 JPWO2022054279 A5 JP WO2022054279A5
- Authority
- JP
- Japan
- Prior art keywords
- secondary battery
- lithium secondary
- battery according
- electrolytic solution
- monovalent group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002904 solvent Substances 0.000 claims description 35
- 229910052744 lithium Inorganic materials 0.000 claims description 21
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 20
- 239000008151 electrolyte solution Substances 0.000 claims description 17
- -1 ether compound Chemical class 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000002033 PVDF binder Substances 0.000 claims description 6
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 239000011888 foil Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 claims 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- 239000004962 Polyamide-imide Substances 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000004760 aramid Substances 0.000 claims 1
- 229920003235 aromatic polyamide Polymers 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000007773 negative electrode material Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 229920002312 polyamide-imide Polymers 0.000 claims 1
- 229920001721 polyimide Polymers 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 description 14
- 229910052731 fluorine Inorganic materials 0.000 description 13
- 239000011737 fluorine Substances 0.000 description 13
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229910003002 lithium salt Inorganic materials 0.000 description 4
- 159000000002 lithium salts Chemical class 0.000 description 4
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 3
- FNUBKINEQIEODM-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoropentanal Chemical compound FC(F)(F)C(F)(F)C(F)(F)CC=O FNUBKINEQIEODM-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 3
- HCBRSIIGBBDDCD-UHFFFAOYSA-N 1,1,2,2-tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane Chemical compound FC(F)C(F)(F)COC(F)(F)C(F)F HCBRSIIGBBDDCD-UHFFFAOYSA-N 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- QKAGYSDHEJITFV-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)pentane Chemical compound FC(F)(F)C(F)(F)C(F)(OC)C(F)(C(F)(F)F)C(F)(F)F QKAGYSDHEJITFV-UHFFFAOYSA-N 0.000 description 1
- ZYAMKYAPIQPWQR-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-3-methoxypropane Chemical compound COCC(F)(F)C(F)(F)F ZYAMKYAPIQPWQR-UHFFFAOYSA-N 0.000 description 1
- WSRVRMMFFLGOBI-UHFFFAOYSA-N 1,1,1,5-tetrafluoro-3-methoxy-2-methylpentane Chemical compound FCCC(C(C)C(F)(F)F)OC WSRVRMMFFLGOBI-UHFFFAOYSA-N 0.000 description 1
- ZNBGTBKGFZMWKR-UHFFFAOYSA-N 1,1,2,2,3,3,4,4-octafluoro-5-(1,1,2,2-tetrafluoroethoxy)pentane Chemical compound FC(F)C(F)(F)OCC(F)(F)C(F)(F)C(F)(F)C(F)F ZNBGTBKGFZMWKR-UHFFFAOYSA-N 0.000 description 1
- YQQHEHMVPLLOKE-UHFFFAOYSA-N 1,1,2,2-tetrafluoro-1-methoxyethane Chemical compound COC(F)(F)C(F)F YQQHEHMVPLLOKE-UHFFFAOYSA-N 0.000 description 1
- HBRLMDFVVMYNFH-UHFFFAOYSA-N 1-ethoxy-1,1,2,2-tetrafluoroethane Chemical compound CCOC(F)(F)C(F)F HBRLMDFVVMYNFH-UHFFFAOYSA-N 0.000 description 1
- DMECHFLLAQSVAD-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoropropane Chemical compound CCOC(F)(F)C(F)C(F)(F)F DMECHFLLAQSVAD-UHFFFAOYSA-N 0.000 description 1
- YDHBUMSZDRJWRM-UHFFFAOYSA-N 2-cyano-n-cyclopentylacetamide Chemical compound N#CCC(=O)NC1CCCC1 YDHBUMSZDRJWRM-UHFFFAOYSA-N 0.000 description 1
- ZKNHDJMXIUOHLX-UHFFFAOYSA-N 2-ethoxy-1,1,1-trifluoroethane Chemical compound CCOCC(F)(F)F ZKNHDJMXIUOHLX-UHFFFAOYSA-N 0.000 description 1
- PCTQNZRJAGLDPD-UHFFFAOYSA-N 3-(difluoromethoxy)-1,1,2,2-tetrafluoropropane Chemical compound FC(F)OCC(F)(F)C(F)F PCTQNZRJAGLDPD-UHFFFAOYSA-N 0.000 description 1
- OYOKPDLAMOMTEE-UHFFFAOYSA-N 4-chloro-1,3-dioxolan-2-one Chemical compound ClC1COC(=O)O1 OYOKPDLAMOMTEE-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910013098 LiBF2 Inorganic materials 0.000 description 1
- 229910015720 LiNi0.85Co0.12Al0.03O2 Inorganic materials 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910006095 SO2F Inorganic materials 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N methyl pentane Natural products CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- ZDCRNXMZSKCKRF-UHFFFAOYSA-N tert-butyl 4-(4-bromoanilino)piperidine-1-carboxylate Chemical compound C1CN(C(=O)OC(C)(C)C)CCC1NC1=CC=C(Br)C=C1 ZDCRNXMZSKCKRF-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2020/034710 WO2022054279A1 (ja) | 2020-09-14 | 2020-09-14 | リチウム２次電池 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPWO2022054279A1 JPWO2022054279A1 (https=) | 2022-03-17 |
| JPWO2022054279A5 true JPWO2022054279A5 (https=) | 2023-05-25 |
| JP7565624B2 JP7565624B2 (ja) | 2024-10-11 |
Family
ID=80631462
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022547362A Active JP7565624B2 (ja) | 2020-09-14 | 2020-09-14 | リチウム２次電池 |
| JP2022547394A Active JP7486230B2 (ja) | 2020-09-14 | 2021-05-17 | リチウム２次電池 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022547394A Active JP7486230B2 (ja) | 2020-09-14 | 2021-05-17 | リチウム２次電池 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20230246239A1 (https=) |
| EP (2) | EP4213267A4 (https=) |
| JP (2) | JP7565624B2 (https=) |
| KR (2) | KR102894179B1 (https=) |
| CN (2) | CN116018696B (https=) |
| WO (2) | WO2022054279A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102874125B1 (ko) * | 2020-11-13 | 2025-10-20 | 테라와트 테크놀로지 가부시키가이샤 | 리튬 이차 전지 |
| JPWO2023100767A1 (https=) * | 2021-11-30 | 2023-06-08 | ||
| JP7770231B2 (ja) * | 2022-03-31 | 2025-11-14 | 本田技研工業株式会社 | リチウム金属電池用電解液 |
| JP2024067441A (ja) * | 2022-11-04 | 2024-05-17 | トヨタ自動車株式会社 | リチウム金属二次電池およびその充放電方法 |
| KR20250017537A (ko) * | 2023-07-27 | 2025-02-04 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 전해액 및 이를 포함하는 리튬 이차 전지 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010036577A1 (en) * | 1996-11-28 | 2001-11-01 | Kenji Nakane | Lithium secondary battery and cathode active material for ues in lithium secondary battery |
| KR100472513B1 (ko) * | 2002-11-16 | 2005-03-11 | 삼성에스디아이 주식회사 | 리튬 설퍼 전지용 유기 전해액 및 이를 채용한 리튬 설퍼전지 |
| JP2006120462A (ja) | 2004-10-21 | 2006-05-11 | Sanyo Electric Co Ltd | 非水電解質電池 |
| CN103947009B (zh) * | 2011-11-15 | 2016-03-09 | 帝人株式会社 | 非水系二次电池用隔膜及其制造方法以及非水系二次电池 |
| JP6107814B2 (ja) * | 2012-03-19 | 2017-04-05 | 三菱化学株式会社 | 非水系電解液及び非水系電解液電池 |
| US9812735B2 (en) * | 2013-08-21 | 2017-11-07 | Sekisui Chemical Co., Ltd. | Lithium ion secondary battery |
| KR102407139B1 (ko) * | 2015-05-20 | 2022-06-10 | 삼성전자주식회사 | 리튬금속전지 |
| SG11201810610XA (en) | 2016-06-08 | 2018-12-28 | Solidenergy Systems Llc | High energy density, high power density, high capacity, and room temperature capable "anode-free" rechargeable batteries |
| KR102115595B1 (ko) * | 2016-11-22 | 2020-05-26 | 주식회사 엘지화학 | 리튬이차전지용 전해질 및 이를 포함하는 리튬이차전지 |
| US11094966B2 (en) | 2017-03-02 | 2021-08-17 | Battelle Memorial Institute | High efficiency electrolytes for high voltage battery systems |
| US10472571B2 (en) | 2017-03-02 | 2019-11-12 | Battelle Memorial Institute | Low flammability electrolytes for stable operation of electrochemical devices |
| KR102160704B1 (ko) * | 2017-04-20 | 2020-09-28 | 주식회사 엘지화학 | 리튬 이차전지용 전해액 및 이를 포함하는 리튬 이차전지 |
| KR102115602B1 (ko) | 2017-06-21 | 2020-05-26 | 주식회사 엘지화학 | 리튬 이차전지 |
| CN107134592A (zh) * | 2017-06-27 | 2017-09-05 | 山东大学 | 一种氟代醚基锂电池用电解液及其制备方法 |
| KR102045472B1 (ko) * | 2017-11-21 | 2019-11-15 | 울산과학기술원 | 리튬 금속 이차전지용 전해액 |
| WO2019130994A1 (ja) | 2017-12-27 | 2019-07-04 | 帝人株式会社 | 非水系二次電池用セパレータ及び非水系二次電池 |
| KR102568793B1 (ko) * | 2018-01-05 | 2023-08-22 | 삼성전자주식회사 | 무음극 리튬금속전지 및 그 제조방법 |
| EP3579325B1 (en) * | 2018-06-07 | 2021-03-10 | Panasonic Intellectual Property Management Co., Ltd. | Lithium secondary battery |
| WO2020106762A1 (en) * | 2018-11-21 | 2020-05-28 | Battelle Memorial Institute | Electrolyte for stable cycling of rechargeable alkali metal and alkali ion batteries |
| EP3902052A1 (en) * | 2020-04-22 | 2021-10-27 | Solvay SA | Anode-less lithium battery |
-
2020
- 2020-09-14 JP JP2022547362A patent/JP7565624B2/ja active Active
- 2020-09-14 EP EP20953344.7A patent/EP4213267A4/en active Pending
- 2020-09-14 WO PCT/JP2020/034710 patent/WO2022054279A1/ja not_active Ceased
- 2020-09-14 KR KR1020237011368A patent/KR102894179B1/ko active Active
- 2020-09-14 CN CN202080104946.6A patent/CN116018696B/zh active Active
-
2021
- 2021-05-17 WO PCT/JP2021/018575 patent/WO2022054338A1/ja not_active Ceased
- 2021-05-17 KR KR1020237009222A patent/KR20230052935A/ko active Pending
- 2021-05-17 CN CN202180062247.4A patent/CN116195088A/zh active Pending
- 2021-05-17 EP EP21866299.7A patent/EP4213268A4/en active Pending
- 2021-05-17 JP JP2022547394A patent/JP7486230B2/ja active Active
-
2023
- 2023-03-08 US US18/119,000 patent/US20230246239A1/en active Pending
- 2023-03-08 US US18/118,948 patent/US20230246238A1/en active Pending
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