JPWO2020061639A5 - - Google Patents
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- Publication number
- JPWO2020061639A5 JPWO2020061639A5 JP2021511629A JP2021511629A JPWO2020061639A5 JP WO2020061639 A5 JPWO2020061639 A5 JP WO2020061639A5 JP 2021511629 A JP2021511629 A JP 2021511629A JP 2021511629 A JP2021511629 A JP 2021511629A JP WO2020061639 A5 JPWO2020061639 A5 JP WO2020061639A5
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- organic phase
- rich
- cobalt
- extraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 211
- 229910052759 nickel Inorganic materials 0.000 claims description 103
- 239000012074 organic phase Substances 0.000 claims description 96
- 238000000034 method Methods 0.000 claims description 81
- 238000000605 extraction Methods 0.000 claims description 50
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 40
- 239000002904 solvent Substances 0.000 claims description 37
- 229940053662 nickel sulfate Drugs 0.000 claims description 36
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 229910017052 cobalt Inorganic materials 0.000 claims description 27
- 239000010941 cobalt Substances 0.000 claims description 27
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 27
- 241000080590 Niso Species 0.000 claims description 26
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims description 26
- 239000012141 concentrate Substances 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 23
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 18
- 239000013078 crystal Substances 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 238000000638 solvent extraction Methods 0.000 claims description 16
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 9
- 239000000908 ammonium hydroxide Substances 0.000 claims description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 9
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 8
- 235000019738 Limestone Nutrition 0.000 claims description 8
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 8
- -1 calcrete Chemical compound 0.000 claims description 8
- 239000000284 extract Substances 0.000 claims description 8
- 239000004571 lime Substances 0.000 claims description 8
- 239000006028 limestone Substances 0.000 claims description 8
- 239000001095 magnesium carbonate Substances 0.000 claims description 8
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 8
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 8
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 230000003472 neutralizing effect Effects 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- RRIWRJBSCGCBID-UHFFFAOYSA-L nickel sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O RRIWRJBSCGCBID-UHFFFAOYSA-L 0.000 claims description 3
- 229940116202 nickel sulfate hexahydrate Drugs 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 235000011149 sulphuric acid Nutrition 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 150000002923 oximes Chemical class 0.000 claims 1
- 239000002244 precipitate Substances 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 239000012527 feed solution Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2018903643A AU2018903643A0 (en) | 2018-09-27 | Method for preparing a high-purity hydrated nickel sulphate | |
| AU2018903643 | 2018-09-27 | ||
| AU2019901760 | 2019-05-23 | ||
| AU2019901760A AU2019901760A0 (en) | 2019-05-23 | Method for preparing a high-purity hydrated nickel sulphate | |
| PCT/AU2019/051044 WO2020061639A1 (en) | 2018-09-27 | 2019-09-26 | Method for preparing a high-purity hydrated nickel sulphate |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2022502564A JP2022502564A (ja) | 2022-01-11 |
| JP2022502564A5 JP2022502564A5 (https=) | 2023-06-29 |
| JPWO2020061639A5 true JPWO2020061639A5 (https=) | 2023-06-29 |
| JP7459060B2 JP7459060B2 (ja) | 2024-04-01 |
Family
ID=69949184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021511629A Active JP7459060B2 (ja) | 2018-09-27 | 2019-09-26 | 高純度水和硫酸ニッケルを調製するための方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11993520B2 (https=) |
| EP (1) | EP3856941A4 (https=) |
| JP (1) | JP7459060B2 (https=) |
| KR (1) | KR102820068B1 (https=) |
| CN (1) | CN112840049B (https=) |
| AU (1) | AU2019348192B2 (https=) |
| CA (1) | CA3110398C (https=) |
| WO (1) | WO2020061639A1 (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7360091B2 (ja) * | 2019-12-27 | 2023-10-12 | 住友金属鉱山株式会社 | 溶媒抽出方法およびコバルト水溶液の製造方法 |
| JP7348130B2 (ja) * | 2020-04-24 | 2023-09-20 | Ｊｘ金属株式会社 | 金属含有溶液中のマグネシウムイオン除去方法及び、金属回収方法 |
| US10995014B1 (en) | 2020-07-10 | 2021-05-04 | Northvolt Ab | Process for producing crystallized metal sulfates |
| CN114134341B (zh) * | 2020-09-04 | 2023-01-13 | 苏州博萃循环科技有限公司 | 一种含镍钴锰的料液中镍钴锰的回收方法 |
| CN116745236A (zh) | 2020-11-03 | 2023-09-12 | 哈茨有限公司 | 用于结晶金属硫酸盐的处理工艺 |
| PH12023551304A1 (en) | 2020-11-12 | 2023-11-20 | Hatch Ltd | Processes and methods for production of crystallized metal sulfates |
| CN112553478A (zh) * | 2020-12-02 | 2021-03-26 | 金川集团镍盐有限公司 | 一种氢氧化镍钴硫酸体系快速浸出的方法 |
| KR20230145474A (ko) | 2021-02-18 | 2023-10-17 | 해치 리미티드 | 리튬 및 배터리 화학물질 생성 시 황산나트륨 부산물 가공 |
| JP7832303B2 (ja) * | 2021-07-29 | 2026-03-17 | ユミコア | 金属を分離するための結晶化方法 |
| KR102601662B1 (ko) * | 2022-01-20 | 2023-11-10 | 포항공과대학교 산학협력단 | 2 서킷 공정에 의한 양극재용 고순도 니켈/코발트 혼합용액 제조방법 |
| CN115058597B (zh) * | 2022-06-30 | 2024-06-04 | 盛隆资源再生（无锡）有限公司 | 一种含钙、铁、钴、镍的电镀污泥的回收处理方法 |
| WO2024073810A1 (en) * | 2022-10-07 | 2024-04-11 | Igo Limited | Method for preparing high-purity mixed nickel and cobalt sulphate |
| WO2024213973A1 (en) * | 2023-04-11 | 2024-10-17 | Bactech Environmental Corporation | A process for treating a material containing iron and sulphur |
| US12286360B2 (en) * | 2023-07-26 | 2025-04-29 | Pt Qmb New Energy Materials | Cobalt-manganese sulfate solution from low nickel matte |
| WO2025020125A1 (zh) * | 2023-07-26 | 2025-01-30 | 青美邦新能源材料有限公司 | 一种低冰镍制备电池级硫酸镍钴锰晶体的方法 |
| JP2025530957A (ja) | 2023-08-25 | 2025-09-19 | コリア・ジンク・カンパニー・リミテッド | ニッケルを含有する原料からニッケル酸化物を回収するためのオールインワンニッケル製錬方法 |
| AU2024213150B2 (en) | 2023-08-25 | 2025-06-26 | Kemco | All-in-one nickel recovering method for nickel metal recovery from raw materials containing nickel |
| JP2025530955A (ja) | 2023-08-25 | 2025-09-19 | コリア・ジンク・カンパニー・リミテッド | ニッケルを含有する原料からニッケル水酸化物を回収するためのオールインワンニッケル製錬方法 |
| JP2025530958A (ja) | 2023-08-25 | 2025-09-19 | コリア・ジンク・カンパニー・リミテッド | ニッケルを含有する原料から硫酸ニッケル水溶液を製造する方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3276863A (en) | 1964-01-21 | 1966-10-04 | Gen Mills Inc | Separation of nickel and cobalt values using alpha-hydroxy oximes |
| US3869257A (en) * | 1972-08-17 | 1975-03-04 | Int Nickel Co | Production of nickel sulfate |
| NL169958C (nl) * | 1977-03-09 | 1982-09-16 | Stamicarbon | Werkwijze voor het selectief extraheren van metaalionen uit waterige oplossingen daarvan. |
| US4108752A (en) | 1977-05-31 | 1978-08-22 | Diamond Shamrock Corporation | Electrolytic cell bank having spring loaded intercell connectors |
| US4541868A (en) * | 1983-07-22 | 1985-09-17 | California Nickel Corporation | Recovery of nickel and cobalt by controlled sulfuric acid leaching |
| US5399322A (en) * | 1992-10-15 | 1995-03-21 | Hazen Research, Inc. | Selective recovery of dissolved metals and preparation of metal salt products |
| US5855858A (en) | 1993-07-29 | 1999-01-05 | Cominco Engineering Services Ltd. | Process for the recovery of nickel and/or cobalt from an ore or concentrate |
| AUPN191395A0 (en) * | 1995-03-22 | 1995-04-27 | M.I.M. Holdings Limited | Atmospheric mineral leaching process |
| US6149885A (en) * | 1997-04-30 | 2000-11-21 | Sumitomo Metal Mining Co., Ltd. | Method for purifying a nickel sulfate solution by solvent extraction |
| US6231823B1 (en) * | 2000-03-27 | 2001-05-15 | Dynatec Corporation | Solvent extraction process for the separation of cobalt from nickel in aqueous sulphate-containing solutions |
| US6267800B1 (en) * | 2000-04-11 | 2001-07-31 | Sherritt International Corporation | Process for producing cobalt metal powder from nickel-cobalt sulphides |
| BRPI0507138A (pt) * | 2004-01-28 | 2007-06-19 | Commw Scient Ind Res Org | processo de extração por solvente para separação de cobalto e/ou nìquel de impureza em soluções de lixìvia |
| WO2006029439A1 (en) * | 2004-09-13 | 2006-03-23 | Canopean Pty. Ltd | Process for preparing nickel loaded organic extractant solution |
| EA013353B1 (ru) | 2005-10-03 | 2010-04-30 | Ототек Оюй | Способ переработки никельсодержащего сырьевого материала в выщелачивающем растворе на основе хлорида |
| DE102011089574B4 (de) * | 2011-12-22 | 2015-10-01 | Continental Automotive Gmbh | Elektrische Vorrichtung mit Filter zum Unterdrücken von Störsignalen |
| KR101191042B1 (ko) * | 2011-12-27 | 2012-10-15 | 강호길 | 니켈정광, 니켈매트로부터 고순도 황산니켈을 제조하는 방법 |
| US9481919B2 (en) * | 2012-02-14 | 2016-11-01 | Cerro Matoso Sa | Production of high grade nickel product |
| CN103224259A (zh) * | 2013-05-15 | 2013-07-31 | 大冶有色金属有限责任公司 | 一种粗硫酸镍精制并回收有价金属的方法 |
| US11149328B2 (en) * | 2013-11-01 | 2021-10-19 | Colorado School Of Mines | Method of leaching arsenic from ore comprising copper |
| CN105200235B (zh) * | 2015-07-27 | 2017-10-27 | 江西睿锋环保有限公司 | 从电镀污泥中回收有价金属制备阴极铜和电池级硫酸镍的方法 |
| JP6489378B2 (ja) * | 2016-06-20 | 2019-03-27 | 住友金属鉱山株式会社 | 硫酸ニッケルと硫酸コバルトの低塩素濃度混合水溶液の製造方法 |
| CN108002408B (zh) * | 2016-10-31 | 2021-06-04 | 湖南金源新材料股份有限公司 | 电池废料制备硫酸镍、锰、锂、钴及四氧化三钴的方法 |
| TWI667056B (zh) * | 2018-04-30 | 2019-08-01 | Chaoyang University Of Technology | 錯合反應協同溶劑萃取回收金屬之方法 |
| CN108570555A (zh) * | 2018-05-03 | 2018-09-25 | 北京矿冶科技集团有限公司 | 一种从镍钴富集物中直接生产电池级硫酸镍的方法 |
-
2019
- 2019-09-26 EP EP19866230.6A patent/EP3856941A4/en active Pending
- 2019-09-26 AU AU2019348192A patent/AU2019348192B2/en active Active
- 2019-09-26 CN CN201980063456.3A patent/CN112840049B/zh active Active
- 2019-09-26 JP JP2021511629A patent/JP7459060B2/ja active Active
- 2019-09-26 CA CA3110398A patent/CA3110398C/en active Active
- 2019-09-26 US US17/280,962 patent/US11993520B2/en active Active
- 2019-09-26 KR KR1020217011969A patent/KR102820068B1/ko active Active
- 2019-09-26 WO PCT/AU2019/051044 patent/WO2020061639A1/en not_active Ceased
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