JPS6383200A - Detergent for glass - Google Patents
Detergent for glassInfo
- Publication number
- JPS6383200A JPS6383200A JP23080686A JP23080686A JPS6383200A JP S6383200 A JPS6383200 A JP S6383200A JP 23080686 A JP23080686 A JP 23080686A JP 23080686 A JP23080686 A JP 23080686A JP S6383200 A JPS6383200 A JP S6383200A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- glass
- acid
- abrasive
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims description 29
- 239000003599 detergent Substances 0.000 title 1
- 239000012459 cleaning agent Substances 0.000 claims description 26
- 150000001412 amines Chemical class 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 description 25
- -1 window frames Chemical class 0.000 description 22
- 238000004140 cleaning Methods 0.000 description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- 229910044991 metal oxide Inorganic materials 0.000 description 11
- 150000004706 metal oxides Chemical class 0.000 description 11
- 235000013162 Cocos nucifera Nutrition 0.000 description 9
- 244000060011 Cocos nucifera Species 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 5
- 229940043264 dodecyl sulfate Drugs 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 4
- 239000005357 flat glass Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 239000003082 abrasive agent Substances 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000002594 fluoroscopy Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- HANWHVWXFQSQGJ-UHFFFAOYSA-N 1-tetradecoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCCCCCC HANWHVWXFQSQGJ-UHFFFAOYSA-N 0.000 description 1
- VICLBIYQLBCEJV-UHFFFAOYSA-N 2-(ethylamino)ethane-1,1-diol Chemical compound CCNCC(O)O VICLBIYQLBCEJV-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- URLJMZWTXZTZRR-UHFFFAOYSA-N sodium myristyl sulfate Chemical compound CCCCCCCCCCCCCCOS(O)(=O)=O URLJMZWTXZTZRR-UHFFFAOYSA-N 0.000 description 1
- 229960000776 sodium tetradecyl sulfate Drugs 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、表面に焼き付けたチタン等の金属薄膜や金属
酸化薄膜によって太陽放射エネルギーを反射するように
してあり、建物の窓ガラスとして多用される熱線反射ガ
ラスの汚れを除去する場合に用いられる洗浄剤に関する
。[Detailed Description of the Invention] [Field of Industrial Application] The present invention reflects solar radiation energy by a thin metal film such as titanium or a thin metal oxide film baked on the surface, and is widely used as window glass for buildings. The present invention relates to a cleaning agent used to remove stains from heat-reflecting glass.
この熱線反射ガラスは、太陽放射エネルギー、つまり、
熱線の反射によって室内の冷房負荷を低減できるととも
に、ハーフミラ−効果によって建物のデザイン性の向上
やプライバシーの確保に寄与できるため、近年、窓ガラ
スとして多用されるようになってきた。This heat-reflecting glass absorbs solar radiant energy, that is,
In recent years, it has become widely used as window glass because it can reduce the cooling load indoors by reflecting heat rays, and its half-mirror effect can contribute to improving the design of buildings and ensuring privacy.
そのような熱線反射ガラス製の窓ガラスの汚れを除去す
るにあたって、従来では、その洗浄剤として、例えば各
種界面活性剤を含んだ一般のガラス用洗浄剤や食器用洗
浄剤、衣料用洗浄剤、クレンザ−１あるいは、酸化セリ
ウム等の研磨剤を用いていた。Conventionally, in order to remove stains from such heat-reflecting glass windows, the cleaning agents used include, for example, general glass cleaning agents containing various surfactants, dishwashing agents, clothing cleaning agents, Cleanser 1 or an abrasive such as cerium oxide was used.
しかし、前述した従来の洗浄剤によるときは、洗浄効果
が十分でなかったり、金属酸化薄膜を削り落としてしま
うという問題があった。However, when using the above-mentioned conventional cleaning agents, there are problems in that the cleaning effect is not sufficient or the metal oxide thin film is scraped off.
すなわち、窓ガラスの汚れは、空気中の塵埃や煤煙ある
いは建物表面からの溶出物によるものであり、その成分
を調べてみると、珪酸類、アルカリ類、油脂や油脂エス
テル、イオウ化合物などが含まれている。そして、水や
一般の洗浄剤などを使用した場合には、上記汚れのうち
、油脂や油脂エステル、イオウ化合物等は除去できるが
、珪酸類、アルカリ類の除去は難しく、また、酸化セリ
ウム等の研磨剤を使用した場合には、ガラス表面にコー
ティングされた金属酸化薄膜をも一緒に除去してしまう
のである。In other words, stains on window glass are caused by dust and soot in the air, or elution from the building surface, and an examination of the components reveals that they include silicic acids, alkalis, oils and fats, oil esters, and sulfur compounds. It is. When using water or a general cleaning agent, it is possible to remove oils and fats, oil esters, sulfur compounds, etc., but it is difficult to remove silicates and alkalis, and it is difficult to remove silicates and alkalis, and cerium oxide, etc. When an abrasive is used, the thin metal oxide film coated on the glass surface is also removed.
そして、上記問題は、建物の外壁面にコンクリートやモ
ルタル１（ＰＣパネルや煉瓦、タイルなどの目地材も含
む）が使用されている場合に特に発生しているものであ
った。The above-mentioned problem particularly occurs when concrete or mortar 1 (including joint materials for PC panels, bricks, tiles, etc.) is used on the exterior wall of a building.
本発明は、上記の点に着口して成されたものであって、
ガラス表面にコーティングされた金属酸化薄膜の性能を
劣化させることなく汚れを除去することができるガラス
用洗浄剤を提供することを目的とするものである。The present invention has been achieved based on the above points, and
The object of the present invention is to provide a cleaning agent for glass that can remove dirt without deteriorating the performance of the metal oxide thin film coated on the glass surface.
本発明に係るガラス用洗浄剤は、Ａ成分として水溶性の
有機酸０．５〜５．０重量％と、Ｂ成分として研磨剤１
０．０〜８０．０重量％と、Ｃ成分として−Ｉ’ＩＱ式
（１）で示されるアミンオキシド１．０〜２５．０重量
％と、Ｄ成分として一般式（２）で示される陰イオン界
面活性剤１．０〜１０．０重量％と、Ｅ成分として一般
式（３）で示される非イオン界面活性剤１．０〜１０．
０重量％とを必須成分とすることを特徴とする。The glass cleaning agent according to the present invention contains 0.5 to 5.0% by weight of a water-soluble organic acid as the A component and 1% by weight of an abrasive as the B component.
0.0 to 80.0% by weight, 1.0 to 25.0% by weight of an amine oxide represented by the -I'IQ formula (1) as the C component, and an amine oxide represented by the general formula (2) as the D component. 1.0 to 10.0% by weight of an ionic surfactant and 1.0 to 10.0% by weight of a nonionic surfactant represented by the general formula (3) as component E.
It is characterized by having 0% by weight as an essential component.
Ｒ＋ Ｏ（ＣＩＩｚＣＩＩｚＯ）ｎｌｃＨｚｃＩ（ｚ
Ｎ−Ｏｎｌ−・−・（１）１？３
Ｒ＋ ０ （ＣＩｌｚＣＨｚＯ）ｎｚｓＯＪ
−・・・（２１Ｒ，−０−（ＣＩｌ□ＣＩｌ□Ｏ
） ｎ３Ｈ・・・・・・（３）（ただし、Ｒ１は炭素数
８〜２６の炭化水素、Ｒ２、Ｒ３は炭素数１〜３の炭化
水素基あるいはヒドロキシアルキル基であり、それぞれ
同一でも異なっていても良（、ｎｌ” Ｏ〜１０． ｎ
ｚ ＝ Ｏ〜５゜ｎユニ１〜５０である。）
その作用及び効果は次の通りである。R+ O(CIIzCIIzO)nlcHzcI(z
N-Onl-・-・(1)1?3 R+ 0 (CIlzCHzO)nzsOJ
-...(21R, -0-(CIl□CIl□O
) n3H...(3) (However, R1 is a hydrocarbon having 8 to 26 carbon atoms, R2 and R3 are a hydrocarbon group having 1 to 3 carbon atoms or a hydroxyalkyl group, and each may be the same or different. It's good (, nl" O ~ 10. n
z=O~5°nuni1~50. ) Its functions and effects are as follows.
水溶性の有機酸０．５〜５．０重量％と、研磨剤１０．
０〜８０．０重量％と、上記一般式（１）で示されるア
ミンオキシド１．０〜２５．０重量％と、上記一般式（
２）で示される陰イオン界面活性剤１．０〜１０．０多
項％と、上記一般式（３）で示される非イオン界面活性
剤１．０〜１Ｏ００重量％とを必須成分としているので
、アミンオキシド類、陰イオン界面活性剤、非イオン界
面活性剤の成分により、ガラス表面との接触を良くして
洗浄効果を高めることができるとともに、水溶性の有機
酸の成分により、汚れの分解効果を上げることができ、
さらに、研磨剤の成分により、化学的に落とせない汚れ
を除去することができる。0.5-5.0% by weight of a water-soluble organic acid and 10% by weight of an abrasive.
0 to 80.0% by weight, 1.0 to 25.0% by weight of the amine oxide represented by the above general formula (1), and the above general formula (
Since the essential components are 1.0 to 10.0% by weight of the anionic surfactant represented by 2) and 1.0 to 1000% by weight of the nonionic surfactant represented by the above general formula (3), The components of amine oxides, anionic surfactants, and nonionic surfactants improve the cleaning effect by improving contact with the glass surface, and the water-soluble organic acid component improves dirt decomposition effects. can raise
Furthermore, the components of the abrasive can remove stains that cannot be removed chemically.
そして、上記水溶性の有機酸の含有量が０．５重量％未
満の場合には、酸としての汚れの分解効果が低下し、５
．０重量％を超える場合には濃度増加の割には分解効果
が増加せず、むしろ窓枠等の金属を侵食して好ましくな
い。また、研磨剤の含有量が１０．０重量％未満の場合
には、研磨力が弱く汚れを落とす効果が低下し、８０．
０重量％を超える場合には、洗浄剤の流動性が低下して
研磨力を著しく低めることになる。さらに、アミンオキ
シドの含有量が１．０重量％未満の場合には、洗浄効果
が低く 、２５．０重量％を超える場合には、後の洗浄
残りが多くなって、掃除効果を低下させるとともに、そ
れ以上含有量を増加してもさほど顕著な洗浄効果が得ら
れないのである。また、上記陰イオン界面活性剤の含有
量が１．０重量％未満の場合では、浸透力及び親水力の
効果がうすく、洗浄効果が低くなり、１０．０重量％を
超える場合には、上記アミンオキシドの場合と同様に使
用後の泡切れの問題や洗浄効果が低いという問題がある
。さらに、非イオン界面活性剤の含有量が１．０重量％
未満の場合でも、上記陰イオン界面活性剤と同様に洗浄
効果が低くなり、１０．０重量％を超える場合には、使
用後の泡切れの問題や添加効果が低いという問題がある
。If the content of the above-mentioned water-soluble organic acid is less than 0.5% by weight, the effect of decomposing dirt as an acid decreases,
．． If it exceeds 0% by weight, the decomposition effect will not increase in proportion to the increase in concentration, but rather it will corrode metals such as window frames, which is undesirable. Furthermore, if the content of the abrasive is less than 10.0% by weight, the abrasive power will be weak and the dirt removal effect will be reduced, resulting in 80.
If it exceeds 0% by weight, the fluidity of the cleaning agent will decrease and the polishing power will be significantly lowered. Furthermore, if the content of amine oxide is less than 1.0% by weight, the cleaning effect will be low, and if it exceeds 25.0% by weight, there will be a lot of residue left after washing, which will reduce the cleaning effect and reduce the cleaning effect. , even if the content is increased further, no significant cleaning effect can be obtained. In addition, if the content of the anionic surfactant is less than 1.0% by weight, the effects of penetrating power and hydrophilic power will be weak, and the cleaning effect will be low; if the content exceeds 10.0% by weight, the above-mentioned Similar to the case of amine oxide, there are problems with foam running out after use and poor cleaning effect. Furthermore, the content of nonionic surfactant is 1.0% by weight.
Even if the amount is less than 10.0% by weight, the cleaning effect will be low as with the anionic surfactant, and if it is more than 10.0% by weight, there will be problems such as foam breakage after use and a low addition effect.
その結果、上記のようにして研磨剤、界面活性剤及び酸
から成る組み合わせ効果により、洗浄効果を上げること
ができ、既知処方で除去できなかったＰＣパネルからの
エフロレフセンス等をはじめとして、珪酸類、アルカリ
類の汚れが、ガラス表面の金属酸化薄膜に傷を付けたり
、削り落とすことなく、容易に取れるようになった。加
えて、酸として水溶性有機酸を使用しているので、ガラ
ス周辺の建築部材などへの腐蝕の悪影響がないことはも
ちろん、清掃作業が主として屋外で実施されることから
人体への安全性を損なうことがなくて、洗浄剤が囲りに
飛散し易い屋外での窓ガラスの掃除に有用である。As a result, due to the combination effect of the abrasive, surfactant, and acid as described above, the cleaning effect can be increased, and silicic acid can be removed, including efflorescence from PC panels that could not be removed with known formulations. It is now possible to easily remove stains from metal oxides and alkalis without damaging or scraping the thin metal oxide film on the glass surface. In addition, since a water-soluble organic acid is used as the acid, there is no negative effect of corrosion on building materials around the glass, and since the cleaning work is mainly carried out outdoors, it is safe for the human body. It does not cause any damage and is useful for cleaning window glass outdoors where the cleaning agent is likely to be scattered around.
以下本発明の詳細な説明する。 The present invention will be explained in detail below.
前記水溶性の有機酸としては、例えば酢酸、プロピオン
酸、酪酸、シュウ酸、コハク酸、マレイン酸、乳酸、り
んご酸、酒石酸、グリコール酸、クエン酸、アスパラギ
ン酸、グルタミン酸等を使用することができる。As the water-soluble organic acid, for example, acetic acid, propionic acid, butyric acid, oxalic acid, succinic acid, maleic acid, lactic acid, malic acid, tartaric acid, glycolic acid, citric acid, aspartic acid, glutamic acid, etc. can be used. .
また、研磨剤としては、炭酸カルシウム、りん酸カルシ
ウム、炭酸マグネシウム、タルク、けいそう土、珪石、
長石、石英等を使用することができる。研磨剤の粒度は
小さいもの程好ましいが、洗浄効果などを考えると、通
常１〜５０μｍ程度のものが好ましい。また、研磨剤は
、モース硬度で１〜７のものが好ましい。なぜなら、硬
度がモース硬度で１未満の場合には、研磨効果に乏しく
、モース硬度７を超える場合には、金属酸化薄膜に傷を
付は易いからである。In addition, as abrasives, calcium carbonate, calcium phosphate, magnesium carbonate, talc, diatomaceous earth, silica stone,
Feldspar, quartz, etc. can be used. The smaller the particle size of the abrasive, the more preferable it is, but in consideration of the cleaning effect, etc., it is usually preferable to have a particle size of about 1 to 50 μm. Further, the abrasive is preferably one having a Mohs hardness of 1 to 7. This is because when the hardness is less than 1 on the Mohs scale, the polishing effect is poor, and when it exceeds 7 on the Mohs scale, the metal oxide thin film is easily damaged.
従って、例えば酸化アルミニウムを含有する研磨剤のよ
うな硬度の高いものは金属酸化薄膜に傷を付けるために
好ましくない。Therefore, highly hard abrasives such as aluminum oxide-containing abrasives are undesirable because they damage the metal oxide thin film.
さらに、前記Ｃ，Ｄ、Ｅ成分として示した式ｆｌ） 、
（２１、（３）におけるＲｏは、炭素数８〜２６の炭
化水素基、またＲ２及びＲ１は炭素数１〜３の炭化水素
基あるいはヒドロキシアルキル基であり、それぞれ同一
でも異なっていても良い。Furthermore, the formula fl) shown as the C, D, and E components,
(21, Ro in (3) is a hydrocarbon group having 8 to 26 carbon atoms, and R2 and R1 are a hydrocarbon group or hydroxyalkyl group having 1 to 3 carbon atoms, and each may be the same or different.
前記炭素数８〜２６の炭化水素基としては、オクチル、
２−エチルヘキシル、ノニル、デシル、ウンデシル、ド
デシル、トリデシル、テトラデシル、ヘプタデシル、ヘ
キサデシル、オクタデシル、アイコシル、オレイル、イ
ソバルミチル、イソステアリル、２−オクチルドデシル
、２−デシルテトラデシル、ブチルフェニル、ジブチル
フェニル、オクチルフェニル、ノニルフェニル、ドデシ
ルフェニル、ジノニルフェニル等を使用することができ
る。The hydrocarbon group having 8 to 26 carbon atoms includes octyl,
2-ethylhexyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, heptadecyl, hexadecyl, octadecyl, icosyl, oleyl, isobalmityl, isostearyl, 2-octyldodecyl, 2-decyltetradecyl, butylphenyl, dibutylphenyl, octylphenyl , nonylphenyl, dodecylphenyl, dinonylphenyl, etc. can be used.
また式（２）におけるＭとしては、ナトリウム、カリウ
ム、アンモニウム、モノエタノールアミン、ジェタノー
ルアミン、トリエタノールアミン等がある。Further, M in formula (2) includes sodium, potassium, ammonium, monoethanolamine, jetanolamine, triethanolamine, and the like.
特に好ましいアミンオキシドとしては、ドデシルジメチ
ルアミンオキシド、テトラデシルジメチルアミンオキシ
ド、ヤシアルキルジメチルアミンオキシド、ドデシルジ
ヒドロキジエチルアミンオキシド、ヤシアルキルジヒド
ロキジエチルアミンオキシド等がある。Particularly preferred amine oxides include dodecyl dimethyl amine oxide, tetradecyl dimethyl amine oxide, coconut dimethyl amine oxide, dodecyl dihydroxy diethyl amine oxide, and coconut dihydroxy diethyl amine oxide.
さらに、特に好ましい前記陰イオン界面活性剤としては
、ドデシル硫酸、テトラデシル硫酸、ヤシアルキル硫酸
、ポリオキシエチレン（２）ドデシル硫酸、ポリオキシ
エチレン（３）ドデシル硫酸、ポリオキシエチレン（２
）ヤシアルキル硫酸、ポリオキシエチレン（３） ヤシ
アルキル硫酸の各エステルのナトリウム、カリウム、ア
ンモニウム、モノエタノールアミン、ジエタノールアミ
ン、トリエタノールアミン塩がある。面前記（）内の数
字はエチレンオキシドの平均付加モル数を示す。Further, particularly preferred anionic surfactants include dodecyl sulfate, tetradecyl sulfate, coconut alkyl sulfate, polyoxyethylene (2) dodecyl sulfate, polyoxyethylene (3) dodecyl sulfate, polyoxyethylene (2) dodecyl sulfate, and polyoxyethylene (2) dodecyl sulfate.
) Coconut alkyl sulfate, polyoxyethylene (3) There are sodium, potassium, ammonium, monoethanolamine, diethanolamine, and triethanolamine salts of each ester of coconut alkyl sulfate. The numbers in parentheses above indicate the average number of moles of ethylene oxide added.
さらに、前記非イオン界面活性剤の好ましい例を挙げる
と、ドデシルアルコール、ヘキサデシルアルコール、オ
クタデシルアルコール、オレイルアルコール、ヤシアル
キルアルコール、牛脂アルキルアルコール、オクチルフ
ェノール、ノニルフェノールに約８〜２５モルのエチレ
ンオキシドを付加した非イオン界面活性剤がある。Furthermore, preferable examples of the nonionic surfactants include dodecyl alcohol, hexadecyl alcohol, octadecyl alcohol, oleyl alcohol, coconut alkyl alcohol, tallow alkyl alcohol, octylphenol, nonylphenol to which about 8 to 25 moles of ethylene oxide is added. There are nonionic surfactants.
上記各成分を含有する洗浄剤は、一般に、水に適当量、
好ましくは、２０〜４０重量％分散させた洗浄液として
用いられるのであって、それらを用いた掃除は、綿布な
どを用いて洗浄液でガラス表面を拭き上げ、水で洗浄し
た後、スクイージあるいは乾布で拭き上げを行うもので
ある。Cleaning agents containing each of the above components are generally prepared by adding an appropriate amount to water,
Preferably, it is used as a cleaning solution with a 20 to 40% by weight dispersion, and cleaning with this cleaning solution involves wiping the glass surface with the cleaning solution using a cotton cloth, washing it with water, and then wiping it with a squeegee or dry cloth. This is to raise the level.
勿論、この洗浄剤は、熱線反射ガラスではない一般のガ
ラスの掃除にも使用できる。また、洗浄剤は、水で希釈
せずに、濡れた布あるいはスポンジに含ませて使用する
ことも可能である。Of course, this cleaning agent can also be used to clean ordinary glass other than heat-reflecting glass. Further, the cleaning agent can also be used by soaking it in a wet cloth or sponge without diluting it with water.
以下本発明の実施例及び比較例を挙げる。Examples and comparative examples of the present invention are listed below.
（実施例１）
クエン酸３．０重量％、けいそう±５５．０重量％、ド
デシルジメチルアミンオキシド７．０重量％、ドデシル
硫酸ナトリウム３．０重量％、ポリオキシエチレン（１
０）ノニルフェニルエーテル１０．０重量％、水２２．
０重量％を混合して洗浄剤を調製した。(Example 1) 3.0% by weight of citric acid, ±55.0% by weight of diatomaceous acid, 7.0% by weight of dodecyldimethylamine oxide, 3.0% by weight of sodium dodecyl sulfate, polyoxyethylene (1% by weight)
0) Nonylphenyl ether 10.0% by weight, water 22.
A cleaning agent was prepared by mixing 0% by weight.
（実施例２）
リンゴ酸１６５重量％、タルク６１．５重量％、ヤシア
ルキルジヒドロキジエチルアミンオキシド３．０重量％
、ポリオキシエチレン（２）ヤシアルキル硫酸ナトリウ
ム４．０重量％、ポリオキシエチレン（９）ヤシアルキ
ルエーテル７．０重量％及び水２３．０重量％を混合し
て洗浄剤を調製した。(Example 2) Malic acid 165% by weight, talc 61.5% by weight, coconut alkyldihydroxydiethylamine oxide 3.0% by weight
A cleaning agent was prepared by mixing 4.0% by weight of polyoxyethylene (2) sodium coconut alkyl sulfate, 7.0% by weight of polyoxyethylene (9) coconut alkyl ether, and 23.0% by weight of water.
（実施例３）
コハク酸１．０重量％、けいそう±５９．０重量％、ド
デシルジメチルアミンオキシド１０．０重量％、ポリオ
キシエチレン（３）ドデシル硫酸ナトリウム１０．０重
量％、ポリオキシエチレン（１５）ステアリルエーテル
２．０重量％及び水１８．０重量％を混合して洗浄剤を
調製した。(Example 3) Succinic acid 1.0% by weight, silica ±59.0% by weight, dodecyldimethylamine oxide 10.0% by weight, polyoxyethylene (3) sodium dodecyl sulfate 10.0% by weight, polyoxyethylene (15) A cleaning agent was prepared by mixing 2.0% by weight of stearyl ether and 18.0% by weight of water.
（実施例４）
酒石酸２．０重量％、けいそう±６６．０重量％、ドデ
シルジメチルアミンオキシド１５．０重量％、ポリオキ
シエチレン（３）ドデシル硫酸カリウム５．０重量％、
ポリオキシエチレン（１０）ミリスチルエーテル２．０
重量％及び水１０．０重量％を混合して洗浄剤を調製し
た。(Example 4) Tartaric acid 2.0% by weight, diatomaceous acid ±66.0% by weight, dodecyldimethylamine oxide 15.0% by weight, polyoxyethylene (3) potassium dodecyl sulfate 5.0% by weight,
Polyoxyethylene (10) myristyl ether 2.0
A cleaning agent was prepared by mixing % by weight and 10.0% by weight of water.
く比較例１〉 けいそう土と酸とを混合して洗浄剤とした。Comparative example 1> A cleaning agent was prepared by mixing diatomaceous earth and acid.
く比較例２ン 酸化セリウムだけを用いた。Comparative Example 2 Only cerium oxide was used.
く比較例３〉
研磨剤５３重量％、脂肪酸系非イオン界面活性剤６重量
％を含有する市販品へを用いた。Comparative Example 3 A commercially available product containing 53% by weight of abrasive and 6% by weight of fatty acid nonionic surfactant was used.
く比較例４〉
研磨剤２０重多筒、脂肪酸有機溶剤を含有する市販品Ｂ
を用いた。Comparative Example 4> Commercial product B containing 20-layer abrasive cylinder and fatty acid organic solvent
was used.
く比較例５〉
研磨剤９０重量％、界面活性剤１．５重量％を含有する
市販品Ｃを用いた。Comparative Example 5> Commercial product C containing 90% by weight of abrasive and 1.5% by weight of surfactant was used.
く比較例６〉
研磨剤８７重量％、界面活性剤５重量％を含有する市販
品りを用いた。Comparative Example 6 A commercially available product containing 87% by weight of abrasive and 5% by weight of surfactant was used.
次に上記実施例及び比較例で示した洗浄剤について行っ
た汚れ除去試験と膜研削試験とを示す。Next, a stain removal test and a membrane grinding test conducted on the cleaning agents shown in the above Examples and Comparative Examples will be shown.
（汚れ除去試験）
洗浄剤を綿布に含ませ、水で除去できない汚れのついた
ガラスの表面に対して、荷重一定で所定の回数（１０回
）擦り、汚れの除去状態を目視によって判断した。汚れ
が付着した試験体としては、ＰＣパネルの汚れが付着し
たガラス、コンクリート汚れが付着したガラス、メタケ
・イ酸ソーダで人工的に表面を汚したガラス（１）、モ
ルタル液で人工的に表面を汚したガラス（２）について
行った。結果を第１表に示す。尚、第１表中○は汚れ落
ちが良好なことを示し、△は汚れ落ちにむらがあること
を示し、×は汚れ落ちが悪いことを示している。(Stain Removal Test) A cotton cloth was soaked in a cleaning agent and rubbed against the surface of a glass with stains that could not be removed with water a predetermined number of times (10 times) under a constant load, and the state of stain removal was visually judged. The test specimens with dirt on them include glass with PC panel dirt on it, glass with concrete dirt on it, glass whose surface was artificially stained with metal oxide and soda sulfate (1), and glass whose surface was artificially stained with mortar liquid. was carried out on the dirty glass (2). The results are shown in Table 1. In Table 1, ◯ indicates that stain removal is good, △ indicates that stain removal is uneven, and × indicates that stain removal is poor.
第１表
（膜研削試験）
所定濃度に希釈した洗浄剤を綿布に滴下しながら熱線反
射ガラス表面をその綿布で所定の回数（３００回）、一
定荷重（６００ｇ ＞かけて擦り、熱線反射ガラス表面
に形成されている金属酸化薄膜の傷付き具合を目視によ
って判断した。尚、熱線反射ガラスについては、酸化チ
タン系熱線反射ガラス（Ａ）と鉄、クロム、コバルト系
熱線反射ガラス（Ｂ）の２種について試験した。結果を
第２表に示す。Table 1 (Membrane Grinding Test) Drop a cleaning agent diluted to a predetermined concentration onto a cotton cloth and rub the surface of the heat-reflecting glass with the cotton cloth for a predetermined number of times (300 times) under a constant load (>600 g). The degree of damage to the metal oxide thin film formed on the metal oxide thin film was visually judged.As for the heat-reflective glass, two types of heat-reflective glass were used: titanium oxide-based heat-reflective glass (A) and iron, chromium, and cobalt-based heat-reflective glass (B). The results are shown in Table 2.
第２表
尚、第２表中Ｏは透視で傷が見えないことを示し、△は
透視で傷が見えることを示し、×は膜が削られているこ
とを示している。Table 2 In Table 2, O indicates that no scratches are visible under fluoroscopy, △ indicates that scratches are visible under fluoroscopy, and × indicates that the film is scraped.
上記第１表及び第２表の結果から、実施例の洗浄剤にお
いては、汚れの洗浄効果及び膜面に対する傷の付き防止
効果の両面で共に良好な結果が得られ、本発明に係るガ
ラス用洗浄剤は、熱線反射ガラス用の洗浄剤として優れ
ていることが確認された。From the results shown in Tables 1 and 2 above, the cleaning agents of the examples showed good results in both the dirt cleaning effect and the scratch prevention effect on the film surface. The cleaning agent was confirmed to be excellent as a cleaning agent for heat ray reflective glass.
Claims (1)
％と、Ｂ成分として研磨剤１０．０〜８０．０重量％と
、Ｃ成分として一般式（１）で示されるアミンオキシド
１．０〜２５．０重量％と、Ｄ成分として一般式（２）
で示される陰イオン界面活性剤１．０〜１０．０重量％
と、Ｅ成分として一般式（３）で示される非イオン界面
活性剤１．０〜１０．０重量％とを必須成分とすること
を特徴とするガラス用洗浄剤。 ▲数式、化学式、表等があります▼・・・・・・（１） Ｒ＿１−Ｏ−（ＣＨ＿２ＣＨ＿２Ｏ）＿ｎ＿２ＳＯ＿３
Ｍ・・・・・・（２） Ｒ＿１−Ｏ−（ＣＨ＿２ＣＨ＿２Ｏ）＿ｎ＿３Ｈ・・・
・・・（３） （ただし、Ｒ＿１は炭素数８〜２６の炭化水素基、Ｒ＿
２、Ｒ＿３は炭素数１〜３の炭化水素基あるいはヒドロ
キシアルキル基であり、それぞれ同一でも異なっていて
も良く、ｎ＿１＝０〜１０、ｎ＿２＝０〜５、ｎ＿３＝
１〜５０である。） ［２］前記研磨剤が、粒度１〜５０μｍのものである特
許請求の範囲第［１］項に記載のガラス用洗浄剤。 ［３］前記研磨剤が、モース硬度で１〜７のものである
特許請求の範囲第［１］項又は第［２］項に記載のガラ
ス用洗浄剤。[Scope of Claims] [1] 0.5 to 5.0% by weight of a water-soluble organic acid as the A component, 10.0 to 80.0% by weight of the abrasive as the B component, and a compound of the general formula ( 1.0 to 25.0% by weight of the amine oxide represented by 1) and general formula (2) as component D.
1.0 to 10.0% by weight of anionic surfactant represented by
and 1.0 to 10.0% by weight of a nonionic surfactant represented by general formula (3) as component E. ▲There are mathematical formulas, chemical formulas, tables, etc.▼・・・・・・(1) R_1-O-(CH_2CH_2O)_n_2SO_3
M... (2) R_1-O-(CH_2CH_2O)_n_3H...
...(3) (However, R_1 is a hydrocarbon group having 8 to 26 carbon atoms, R_
2, R_3 is a hydrocarbon group or hydroxyalkyl group having 1 to 3 carbon atoms, and may be the same or different, n_1 = 0 to 10, n_2 = 0 to 5, n_3 =
It is 1-50. ) [2] The glass cleaning agent according to claim 1, wherein the abrasive has a particle size of 1 to 50 μm. [3] The glass cleaning agent according to claim 1 or 2, wherein the abrasive has a Mohs hardness of 1 to 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23080686A JPS6383200A (en) | 1986-09-29 | 1986-09-29 | Detergent for glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23080686A JPS6383200A (en) | 1986-09-29 | 1986-09-29 | Detergent for glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6383200A true JPS6383200A (en) | 1988-04-13 |
Family
ID=16913567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23080686A Pending JPS6383200A (en) | 1986-09-29 | 1986-09-29 | Detergent for glass |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6383200A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04146997A (en) * | 1990-10-08 | 1992-05-20 | General Kk | Thermal head cleaning agent |
| WO1996030480A1 (en) * | 1995-03-27 | 1996-10-03 | Talc De Luzenac | Liquid scouring composition |
| EP1111038A1 (en) * | 1999-12-22 | 2001-06-27 | The Procter & Gamble Company | Scouring composition |
-
1986
- 1986-09-29 JP JP23080686A patent/JPS6383200A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04146997A (en) * | 1990-10-08 | 1992-05-20 | General Kk | Thermal head cleaning agent |
| WO1996030480A1 (en) * | 1995-03-27 | 1996-10-03 | Talc De Luzenac | Liquid scouring composition |
| FR2732354A1 (en) * | 1995-03-27 | 1996-10-04 | Talc De Luzenac | SCOURING COMPOSITION IN LIQUID OR CREAM FORM |
| EP1111038A1 (en) * | 1999-12-22 | 2001-06-27 | The Procter & Gamble Company | Scouring composition |
| WO2001046378A1 (en) * | 1999-12-22 | 2001-06-28 | The Procter & Gamble Company | Scouring composition |
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