JPS63502511A

JPS63502511A - Use of nitrogen-containing heterocycles to reduce water loss from plants and increase crop yields

Info

Publication number: JPS63502511A
Application number: JP50134387A
Authority: JP
Inventors: マニング，デイビツド・トレドウエイ; キヤピイ，ジエイムズ・ジヨセフ; ク−ク，アンソン・リチヤ−ド; シ−ズ，リチヤ−ド・エリク; ウ−，タイ−テ−; ロペス，アニハル; フイリツプス，ジエニフア−・リン; アウトカルト，ラツセル・ジエイムズ
Original assignee: ローヌ―プーラン・ネーデルランド・ベー・ベー
Priority date: 1986-01-23
Filing date: 1987-01-23
Publication date: 1988-09-22
Also published as: IE870163L; MA20926A1; DD254318A5; ZA87480B; PL263788A1; ES2004071A6; HUT45848A

Abstract

(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。 (57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention]

植物からの水　損　を減らし且つの収　を増　させるための窒素　有？素環　１　の１豆立且！皇１１乏丘光１本発明は、植物からの発散水分損失（ｔｒａｎｓｐｉｒａｔｉｏｎａｌ　１ｏｉｓ−ｔｕｒｅ　１ｏｓｓ）を減らし且つ作物の収率（ｃｒｏｐ、ｙｉｅｌｄ）を増大させるための窒素含有複素環化合物の使用に関する。本発明は、更に新規な窒素含有複素環化合物及びその製造方法にも関する。１豆立１１発散は、生存している組織から蒸気の形態で水が通過する等の公知の生理学的プロセスである。植物の発散の場合、水蒸気物の根糸による水性栄養素の吸収及び転流を促進している。気孔によって、植物組織と外部空気の間での必要な気体の交換が可能となる。植物の根によって吸収された水の総量のほんの約１％が植物の成長のために利用され、その他の水は植物の気孔を介して発散により大気中に放出されると考えられている。植物において極めて低い率の発散が必要な栄養素の運ｎ及び正常な植物の成長に必要であることが判明している。発散が完全に停止すると植物が害を被り、枯死する可能性が高いが、植物における発散率を最高４０〜５０％に減らしても植物には害はないと予想される。例えば、Ｕ、Ｓ、Ｐ、Ｎα４，０９４，８４５を参照されたい。植物からの発散による水分損失を減らすことは幾つかの理由で重要である。特に、乾燥気候の地帯では潅概用水の必要量が少なくτ済み、移植又は積荷中或いは気候が極めて冷たいときに植物が萎れる等の害を受けるのが防止され、成る環境下での水の圧迫が抑制される。前記した水の圧迫（ｗａｔｅｒ　５ｔｒｅｓｓ）は、発散率が植物による水の吸収率を越えたときに生ずる。水の圧迫は植物における水位及び膨圧が減るにつれて現れ、萎れる等の書が生じたり、ついには枯死に至◆ことさえあり得る。植物からの発散水分損失を減らすための各種方法が開発されテイル。例えば１１．ｓ、Ｐ、Ｎｏｓ、　４，０９４，８４５．４，３９７，６８１．３，８９０，１５８゜３．８４７，６４１．３，８２６，６７１．３，６７６．１０２．　ｊ、ｓ３９，３７３．３，３３９，９９０．　。３．１９９，９４４及びＥＰ　７３，７６０−８に記載されている。植物からの発散による水分損失を減らすべく使用されるとして上記特許明細ハク酸、低級有機酸の長鎖エステル、ポリイソシアネート、液体、１？　ＩＪテルペン類、ベンジルアルキルアンモニウム塩等が包含される。しかしながら、この物質を使用すると植物からの発散による水分損失が減るが、多くの物質は光合成、呼吸、細胞分裂等の他の植物プロセスに有害な影響を及ぼした。植物からの発散による水分損失を減らすために、２−クロロ　−４−エヂルアミノ　−６−イツプロビルアミノーｓ−トリアジン（アトラジン：ａｔｒａｚｉｎｅ　）を使用することも文献に記載されている。例えば、Ｇ、［１，Ｗｉｌｌｓら、Ｗｅｅｄｓ　１１：２５３−２５５（１９６３）及　びＪａｌｕｅＳＣ，Ｇｒａｈａｍら、’ｔｉｅｅｄ　５ｃｉｅｎｃｅ　１６：３８９−３９２（ｔ９６８）を参照されたい。しかしながら、発散防止剤としてアトラジンを使用すると、植物の光合成の光を必要とする反応、例えば光合成の電子輸送（ｅｌｅｃｔｒｏｎ　ｔｒａｎｓｐｏｒｔ；）の阻害及び植物の薬害が引き起される。従って、本発明の目的は、植物からの発散による水分損失を減らし、それによって土壌中の水分をより有効に利用するために成る種の窒素含有複素環化合物を使用する方法を提供する。本発明の別の目的は、作物の収率を増大させるために成る種の窒素含有複素環化合物を使用する方法を提供する。本発明の更に別の目的は、新規な窒素含有複素環化合物及びその製造方法を提供することにある。上記した目的並びにその他の目的は、以下の記載から当業者に明らかであろう。ル泗Ｊとｌ丞本発明は植物からの水分損失を減らすための方法に関し、植物表面に植物の光合成の電子輸送を実質的に阻害することなく植物表面からの水分損失を減らすに充分な有効量の式：％式％（式中、Ｒ１，Ｒ２及びＸの定義は後記する）の化合物を適用することからなる。本発明は作物の収率を増大させるための方法にも関し、作物に植物の光合成の電子輸送を実質的に阻害することなく作物の（式中、Ｒ１，Ｒ２及びＸの定義は後記する）の化合物を適用することからなる。本発明は更に新規な窒素含有複素環化合物及びその製造方法にも関する。詳細な説明上記した通り、本発明は、成る種の窒素含有複素環化合物を使用することにより植物からの水分損失を減らし且つ作物の収率を増大させるための方法に関する。詳しくは、本発明の植物からの発散による水分損失を減らし且つ作物の収率を増大させるための方法は、植物表面又は作物に植物の光合成の電子輸送゛　を実質的に阻害することなく植物表面からの水分損失を減らすか又は作物の収率を増大させるに充分な有効量の式：Ｒ１は単環式芳香族若しくは非芳香族環系、二環式芳香族若しくは非芳香族環系、多環式芳香族若しくは非芳香族環系及び架橋環系から選択された置換或いは未置換の炭素環式又は複素環式環系であって、前記環系は飽和でも不飽和でもよく、許容され得る置換基（Ｚ）は同一でも異なっていてもよく１個又はそれ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ、プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ。トリアルキルシリルオキシ、アリールジアルキルシリルオキシ。トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルフキンスルホニル、ボリハＯアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニルニル、アミノチオカルボニル。アルキルアミノチオカルボニル。ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒドロキシカルボニル及びその誘導塩９ホルムアミド、アルキル、アルコキシ、ポリハロアルキル、ポリハロアルコキシ、アルコキシカルボニル、＠換アミノ（この場合許容され得る置換基は同一でも異なっていてもよぐ１個又は２ｆ囚鋒ｉのプロパルギル、アニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカロアルキル力ルポニルアミノ．トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩，ホスホン酸及びその誘導塩，アルコキシカルボニルアミノ。アルキルアミノカルボニルオキシルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ，ポリハロアルキニル、ポリハロアルキニルオキシ。ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメヂル，アルコキシカルボニルヒドラゾツメチル、アルフキシイ挽若メチル。破換若しくは未置換のアリー°ルオキシイミノメチル、ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基、ハロアルキル、ハロアルケニル、ハロアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル、ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル、アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、アロイル、へロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルホニル、アリへロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、ハロアシルアミノ、アルコキシニルオキシ、シアナト、イソシアブト、イソチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルフキシ、シフルーｔルスル＊ニウム、−Ｘ、−Ｘ、−Ｘ−Ｒ、−Ｘ−Ｒ３゜Ｙ３Ｒ５であり、或いはＲ１は置換異原子又は置換炭素原子、或いは２個若しくはそれ以上の炭素原子又は異原子と以下の許容され得る置換基を組合せて含有する置換若しくは未置換の直鎖又は分岐鎖であって、前記′Ｒ置換基Ｚ）はり一でも異なっていてもよく１個またはそれ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ。プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ。トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルコキシスルホニル、ポリハロアルフキシスルホニル、ヒドロキシ、アミノ、アミツカボニル、アミノチオカルボニル、アルキルアミノチオカルボニル１．ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒドロ°キシカルボニル及びその誘導塩、ホルムアミド、アルキル。アルコキシ、ポリハロアルキル、ポリハロアルコキル、アルコアルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル。ボリハ０アルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アル、キルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩、ホスホン酸及びその誘導塩、アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニ゛ル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ、ボリハＯアルキニル、ポリハロアルキニルオキシ。ポジフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル、アルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチル、Ｗ！！換若くは未置換のアリールオキシイミノメチル、ヒドラゾツメチル、！換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドとアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル、ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、八ロアルキニルオキシ、ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルヶニルスルホニル、アルコキシスルホニル、アリールオギシスルホニル、プロパルギルオキシ、アロイル、へロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルボニル、アルキルアミノスルホニル、ジアルキルアミノスルボニル、アリールアミノスルホニル、カルボキシアルコキシ、カルボキシアルキルチオ、アルコキシカルボニルアルコキシ、アシルオキシ。へロアシルオキシ、ポリハロアシルオキシ、アロイルオキシ。アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロ°アルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、へロアジイソチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルボスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシボスフイノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アル、″］キシアルケニル。シアノアルコキシ、ジアルキルスルホニラｌ１．−Ｘ、−Ｘ。Ｙ３Ｒ５であり、〆は共有−重結合又は二重結合、置換若しくは未置換の異原子又は置換炭素原子、或いは２個若しくはそれ以上の炭素原子又は異原子と以下の許容され得る置換基（Ｚ）を組合せて含有する置換若しくは未置換の直鎖又は分岐鎖であって、前記置換基は同一でも異なっていてもよく１個またはそれ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル。アルコキシカル、ボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ、プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ、トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルコキシスルボニル、ポリハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル９アミノチオカルボニル、アルキルアミノチオカルボニルルアミノチオカルボニル、ニトロ、シアノ、ヒドロキシカルボニル及びその誘尋塩．ホルムアミド、アルキル、アルコキシ、′ポリハロアルキル、ポリハロアルコキル、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又はそれ以上のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ。ポリハロアルキルチオ、アルキルスルフ、イニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ボリハ０アルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩，ホスホンと及びその誘合塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ。アルキニル、ア゛ルキニルオキシ．ポリハロアルケニルオキシ。ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル，アルフキシ力ルポニルヒドラゾノメヂル，アルコキシイミノメチル、置換若しくは未置換のアリールオキシイミノメチル。ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基，ハロアルキル、ハロアルケニル、ハロアルキニル。アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリ−ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、へＯアルキニルチオ。ハロアルケニルスルホニル、ポリハロアルケニルスルホニル。アルコキシスルホニル、アリールオキシスルホニル、ブＯパルギルオキシ、アロイル、へロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホニル、カルボキシアルコキシ、カルボキシアルキルチオ、アルコキシカルボニルアルコキシ、アシルオキシ、八口アシルオキシ、ポリへ〇アシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、へロアシルアミノ、アルカルボニルオキシシクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ。アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ。ジアルキルスルホニウム、−Ｘ，−Ｘ．−Ｘ−Ｒ３。 −Ｘ−Ｒ３。Ｙ３Ｒ５であり、Ｒ２は単環式芳香液若しくは非芳香族環系．二環式芳香族若しくは非芳香族環系．多環式芳香族若しくは非芳香族環系及び架橋環系から選択された置換或いは未置換の少なくとも１個の窒素原子を有する複素環式環系であって、前記環系は飽和でも不飽和でもよく、許容され得る置換基（Ｚ）は同一でも異なっていてもよく１個又はそれ以上の水素，ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルジアルキルシリルオキシ、トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド。アルコキシスルホニル、ポリハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミゾ力ルポニル，アミノチオカルボニル、アルキルアミノチオカルボニル、ジアルキルアミノチオカルボニル、ニトロ、シアムヒドロキシ力ルポ禽びその誘導塩．ホハロアルフキシ，アルコキシカルボニル、置換アミノ（この場アルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ。ホニルアミノ，アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールジアルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ、ポリハロアルキニル，ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミカルバゾノメチル，アルフキシカルボニ１ルヒドラゾノメチル，アルコ置換若ミノメチル。置換若しくは未置換のアリールオキシイミノメチル、ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基．ハロアルキル。ハロアルケニル、ハロアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル、ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ。ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル，アルコキシスルホニル。アリールオキシスルホニル、プロパルギルオキシ、アロイル。ハロアシル、ポリ八ロアシル、アリールオキシカルボニル、アルチオ、アルコキシカルボニルアルコキシ、アシルオキシ、へロアシルオキシ、ポリ八ロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、八ロアルキルスルホニルオキシ，ボリハロアルキルスルホニルオキシ、アロイルアミノ、へロアシルアミノ、アルコキシカルボニルオキシ、アリールスルホニルアラチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム、−Ｘ、＝Ｘ。Ｙ３Ｒ５であり、Ｒ３は単環式芳香族若しくは非芳香族環系、二環式芳香族若しくは非芳香族環系、多環式芳行族若しくは非芳香族環系及び架橋環系から選択された置換或いは未置換の炭素環式又は複素環式環系であって、前記環系は飽和でも不飽和でもよく、許容され得る置換Ｗ　（Ｚ）は同一でも異会っていてもよく１個又はそれ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ、プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ。ハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル。ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒドロキシカルボ）嘆びその誘導塩、ホルムアミド、アルキル、アルコキシ、ポリハロアルキル、ポリハロアルコキシ、アルコキシカルボニル、置換アミノ（この場合許容され得る薇換基は同一でも異なっていてもよく１個又は２ｇＸ１軸のプロパルギル、アルコキシアル士ル、アルキルチオアルキル、アルキル、アルダニ１ル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルブオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩、ホスホン酸及びその誘導塩、アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ、ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミカルバゾノメチル、アルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチル、置換若しくは未置換のアリールオキシイミノメチル、ヒドラゾツメデル。置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基、ハロアルキル、ハロアルケニル、ハロアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル、ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル、アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、アロイル、へロアシル、ポリ八ロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールボニル゛アルコキシ、アシルオキシ、へロアシルオキシ、ポリ八ロアシルオキシ、アロイル、オキシ、アルキルスルホニルオキシ、アルケニルスルホニルオ・キシ、アリールスルホニルオキシ。ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、ハ“Ｏアシルアミノ、アルコキシカルオキシ、シアナト、イソシアナト、イソチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ。アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシボスフイノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム、−Ｘ、−Ｘ、−Ｘ−Ｒ３，−Ｘ−Ｒ３゜Ｙ３Ｒ５であり、或いはＲ３はＭ換異原子又は置換炭素原子、或いは２個若しくはそれ以上の炭素原子又は異原子と以下の許容され得る置換基（Ｚ）れ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルヶニルチオ、チオシアノ、プ［］／マルギルチオ、ヒドロキシイミノ、アルコキシイミノ。トリアルキルシリルオキシ、アリールジアルキルシリルオキシ。トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルコキシスルボニル、ポルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル、ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒトＯキシカルボニル及びその誘導塩、ホルムアミド、アルキル。アルコキシ、ポリハロアルキル、ポリハロアルコキル、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又は２＄ＳＪｊ！＝にのプロパルギル。アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル。ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルボン酸及びその誘導塩、ホスホン酸及びその誘導塩、アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ、ポリハロアルキニル。ポリハロアルキニルオキシ。ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル、アルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチル、Ｎ操者しくは未置換のアリールオキシイミノメチル、ヒドラゾツメチル、Ｗ検者しくは未Ｗ１換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基、ハロアルキル、ハロアルケニル、ハロアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル、ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ。ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル、アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、アロイル、へロアシル、ポリハロＺシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホニル、カルボキシアルコキシ、カルボキシアアルキルスルホニルオ′、キシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルフィニルオキシ、アロイルアミノ、へロアシルアミノ、アルコキシカルボニルオキシ、アリールスルフニルアミノ、アミノカルボニルオキシ、シアナト、イソシアナト。イソチオシアノ、シクロアルキルアミノ、トリアルキルアンモアルキルアミノ、アル・フキジアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル。シアノアルコキシ、ジアルキルスルホニウム、　−Ｘ　、　ｍ　Ｘ。 −Ｘ−Ｒ３，−Ｘ−Ｒ３゜Ｙ３Ｒ５であり、Ｙ、及びＹ４は夫々酸素又は硫黄であり、Ｙ２及びＹ３は夫々酸素、硫黄、アミノ又は共有結合であり、Ｒ４及びＲ５は夫々水素、置換若しくは未置換のアルキル。ポリハロアルキル、フェニル又はベンジルであって、許容され得る置換基（２）は同一でも異なっていてもよく１個又はそれ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ。゛プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ。トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルフキジスルホニル、ポリハロアルコキシスルホニル。ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルポール、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル。ジアルキルアミノチオカルボニル、ニトロ、シアン、ヒドロキキシ，ポリハロアルキル、ポリハロアルコキシ、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又はＺ　１’ＪＪ　斗毒のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキル、スルホニル、ポリハロアルキルスルホニル、アルキルカルボニルアミノ、アルキルカルボニルアミノ、ボリハＯアルキルスルホニルアミノ、ポリハロ感温，ホスホン酸及びその誘導塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ、ボリハＯアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル，アルコキシカルボニルヒドラゾツメチルキシイミノメチル、置換若しくは未置換のアリールオキシイミノメチル、ヒドラゾツメチル、置換若しくは未置換のアリール合したヒドロキシ基，ハロアルキル，ハロアルケニル、ハロアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキニル、ハロアルケニルオキシ、ハロアルキニルオキシ，ハロアルキニルチオ、ハロアルケニルスルホニル，ポリハロアルケニルスルホニル，アルコキシスルホニル、アリールオキシスルホニル、ブＯパルギルオキシ、アロイル、ハロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルホニル、アルハロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、へロアシルアミノ、アルコキシカルオキシ、シアナト、イソシアナト、イソチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ。アリール（アルキル）アミノ、アラアルキルアミン、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム、−Ｘ，−Ｘ．−Ｘ−Ｒ３．−Ｘ−Ｒ３。Ｙ３Ｒ５である）の化合物を適用することからなる。上記したアルキル含有部分は約１〜１００個若しくはそれ以上の炭素原子を含み、好ましくは約１〜３０個、より好ましくは約１〜２０個の炭素原子を含む。ポリサッカライド部分は最高約５０個の炭素原子を含む。式１に包含される化合物は全て満たされていない（ｕｎｆｉｔｔｅｄ）結合位置を持たない化合物であることを理解されたい。式１に包含される化合物に対して許容され得る置換基の場合置換基の原子価は特定の炭素原子又は異原子の結合能に適していなければならないととを理解されたい。式１のＲ及びＲ３に包含される単環式環系（ｍｏｎｏｃｙｃｌｉｃｒｉｎｇ　ｓｙｓｔｅｍｓ）は下記一般式２で表される。上記式中、Ｂ　は飽和又は不飽和炭素原子であり、Ａ１はＢ１と−緒になって０〜４個の二重結合又は０〜２個の三重結合を有する環系（ｃｙｃｌｉｃ　５ｙｓｔｅ＋ｅ）を形成する原子の環形成鎖（ｒｉｎｇ−ｆｏｒｍｉｎｇ　ｃｈａｉｎ）である。Ａ１が２〜１２個の炭素原子を含んでいてもよ（，１〜１１個の炭素原子とＮ、Ｏ，Ｓ、Ｐ若しくは他の異原子（ｈｅｔｅｒｏａｔｏｌｓ）から選択された１〜４四の異原子とを引合せて含んでいてもよく、４０の環形成異原子を含んでいてもよい。式１のＲ２°に包含される単環式環系は、少なくとも１個の窒素原子を有す、るＲ　及びＲ３の単環式環系である。環形成異原子が、芳香族及び脂肪族Ｎ−オキシドやスルフィニル、スルホ；ル、セレンオキシド及びホスフィンオキシト部分を含有する環系の場合の如く画素原子を担持（ｂｅａｒ）　シていてもよい。３個以上の環形成原子を含有するＢ　及びＡ１により形成される環に含まれる特定の炭素原子がカルボニル、チオカルボニル、ｖ１換若しくは未置換イミノ基又は賀挽若しくは未置換メチリデン基を担持していてもよい。Ｚで示される基は、２に関して定義されている多数の置換基の基から選択された１個又はそれ以上の置換基である。Ｂ１及ｉｎ９１１Ｑｌｌｂｌｌｌｒｓ）を含むときには、飽和炭素環（ｃａｒｂｏｃｙｃｌｅ）、即ちシクロプロピルでなければならない。Ｂ　及びＡ１により形成された環が５個以下の環形成員を含むときには、１個以上のり原子を含んでいてはならない。式１のＲ及びＲ３に包含される単環式環ＭＩＪ″ｌｔ１の例には次のものが包含される。なお、式中Ｚは前記と同義である。式１のＲ１及びＲ３に包含される二環式系は下記一般式３及び４により表される。上記式中、Ｂ２及びＢ３は夫々飽和若しくは不飽和炭素原子又は飽和窒素原子であり、Ａ　及びＡ３は夫々下記する原子の環形成鎖であり、２は２について定義した置換基の基から夫々選択された１ｇ又はそれ以上の置換基である。Ａ２及びＡ３の組合せが０〜５の二重結合と８２又はＢ３と組合ゼて含んでいもよい。Ａ２及びＡ３は、Ｂ２又はＢ３とは別個に１〜１１ｇの炭素原子を含んでいてもよく、１〜１０個の炭素原子と共にＮ、○。Ｓ、Ｐ若しくは他の異原子から選択された１〜３個の異原子を含んでいてもよく、１〜３個の環形成異原子を含んでいてもよい。環形成異原子が、芳香族及び脂肪族Ｎ−オキシドやスルフィニル、スルホニル、セレンオキシド及びホスフィンオキシト基を含有する環系の場合の如く酸素原子を担持（ｂｅａｒ）　シていてもよい。Ａ　及びＡ３に含まれる特定の炭素原子がカルボニル。チオカルボニル、ｌ若しくは未Ｉ磯イミノ基又はＩ挽若し、くは未Ｉ役メチリデン基を担持していてもよい。式１のＲ２に包含される二環式環系は、少なくとも１個の窒素原子を有するＲ　及びＲ３の二環式環系を包含する。式３及び４に包含される構造に関して、次のことに留意されたい。（ａ）　Ｂ　及びＢ　が共に窒素原子のときには、Ａ２及びＡ３の各々に含まれる環原子（ｒｉｎｇ　ａｔｏｍ）は３個より少なくてはならない。（ｂ）Ｂ３ではなくＢ２が窒素原子のときには、Ａ２及びＡ３の一方が少なくとも３個の環原子を含み、他方が少なくとも２個の環原子を含む。（Ｃ）基Ａ　及びＡ３の一方が３個より少ないｌ環原子を含むときには、他方は少なくとも３個の環原子を含み且″っ架橋末端（ｂｒｉｄｇｅｈｅａｄ　ａｔｏｍｓ）原子は飽和されていなければならない。（ｄ）ＭＡ　又はＡ３がカルボニル、ヂオカルボニル、イミノ又はメチリデンを担持する炭素原子を含むときには、Ｂ２及びＢ３と一緒になって少なくとも４員を有する環を形成しなければならない。（ｅ）環状（ａｎｎｕ　ｆａｒ）二重結合が式３及び４で表される２個の環のいずれかに対して外（ｅｘｏｃｙｃ　Ｉ　ｉ　ｃ　）にあるときには、少なくとも５員を含有プる環の内にあって且つ少なくとも５員を含有す結合しているどきには、基Ａ　又はＡ３は１個の二重結合を含有し、架橋末端原子は不飽和であると理解されたい。Ｒ１及びＲ３について定義された二環式環系がスピロ環式環系であってもよく、式３及び４の融合二環式構造に限定されない。スピロ環式環系（ｓｐｉｒｏｃｙｃｌｉｃ　ｒｉｎｇ　５ｙｓｔｅａ＋ｓ）は飽和若しくは不飽和の炭素環式又は複素環式でもよく、前記した１個又は式１のＲ１及びＲ３に包含される二環式環構造の例には次のものが含まれる。式１のＲ及びＲ２に包含される二環以上の多環式環系は下記一般式５．６．７及び８により表される。上記式中、Ｂ４．Ｂ５．Ｂ６及びＢ７．は夫々飽和若しくは不飽の原子と共に０〜２個の二重結合を含み得る原子の環形成鎖である。基２は、Ｚについて定義した置換基の基の中から選択された１個又はそれ以上の置換基である。Ａ４．Ａ５．Ａ６及びＡ７の環形成元素は、Ｂ４．Ｂ５，８６及びＢ１とは別個に１〜１１個の炭素原子を含んでいてもよく、１〜１０個の炭素原子と共にＮ、Ｏ，Ｓ、Ｐ若しくは他の異原子から選択された１〜３個の異原子を含んでいてもより、１〜３個の異原子を含んでいてもよい。環形成異原子が、芳香族Ｎ−オキシドやスルフィニル、スルホニル、セレンオキシド及びホスフィンオキシト基を含有する環系の場合の如く酸素原子を担持していてもよい。八〇は時には結合とし°て定義され得る。Ａ４、Ａ５．Ａ６及びＡ７に含まれる特定の炭素原子が１個又はそれ以上のカルボニル、チオカルボニル、ｆｆｉ換若挽若は未ｗ換イミノ基を担持していてもよい。構造式８に関して、基Ｂ、Ｂ９及びＢ１゜は夫々飽和若しくは不飽和炭素原子又は飽和窒素原子である。基８１１は飽和若しくは不飽和炭素原子、窒素原子又はリン原子である。Ａ８゜Ａ　及びＡ　は基Ｂ　、Ｂ　、Ｂ　及びＢ１１のうちの１ｇと共（−〇〜２ｇｆＡの二重結合を含み得る原子の環形成鎖である。Ａ８．、Ａ、及びＡ１０の環形成元素は、Ｂ８．Ｂ９．Ｂｌｏ及び選択された１〜３個の異原子を含んでいてもよく、２〜３個のインオキシド基を含有する環系の場合の如く酸素原子を担持しくは未置換イミノ基を担持していてもよい。Ｒ及、びＲ３について定義された多環式環系がスピロ環式環系であってもよく、式５，６．７及び８の融合多環式溝道に駆足されない。スピロ環式環系は飽和若しくは不飽和の炭素環式又は複素環式でもよく、前記した１個又はそれ以上の置換ＷＺで置換されていてもよい。 “　式１のＲ２に包含される多環式環系には少なくとも１個の窒素原子を有するＲ　及びＲ３の多環式環系が含まれる。式１のＲ及びＲ３に包含される多環式環１８造の例には次のものが包含される。式１のＲ１及びＲ３に包含される架橋二環式環構造は下記一般式９．１０及び１１で表される。原子又は窒素原子であり、基Ａ　、Ａ　及びＡ　は夫々Ｂ１２及Ａ、１．Ａ１２及びＡ１３の環形成元素は、Ｂ１２及びＢ１３とは別個に１〜１１個の炭素原子を含んでいてもよく、１〜１０個の炭素原子と共にＮ、Ｏ，Ｓ、Ｐ若しくは他の異原子から選択された１〜３ｍの異原子を含んでいてもよく、１〜３個の異原子を含んでいてもよい。但し、基Ａ　、Ａ　及びＡ１３のうちの１個が単きには基Ａ１１．Ａ１２及びＡ１３は少なくとも２個の飽和環形成原子を含んでいなければならない。環形成異原子が、スルフィニル、スルホニ”ル、セレンオキシド及びホスフィンオキシト部分の場合の如り酸素原子を担持していてもよい。Ａ１１．Ａ１２及びＡ１３に含まれる特定の炭素原子が１個又はそれ以上のカルボニル、チオカルボニル、置換若しくは未置換イミノ基を担持していてもよい。式１のＲ２に包含される架橋二環式環系には少なくとも１個の窒素原子を有するＲ　及びＲの架橋二環式環系が含まれる。式１のＲ１及びＲ３に包含される架橋二環式環構造の例には次のものが包含される。鮫類又は直鎖の炭素鎖であっても、炭素原子及び異原子の両方を含む飽和若しくは不飽和の分岐鎖又は直鎖であっても、飽和若しくは不飽和の分岐鎖又は直鎖の異原子類であってもよい。Ｘの特定の異原子桐造がスルホニル、スルフィニル、Ｎ−オキシド及びホスフィンオキシト部分を含有する基の場合の如く酸素原子を担持していてもよい。Ｘの特定の異原子成分が前記した如き１個又はそれ以上のは換基Ｚを担持していてもよい。Ｘに係わる特定の炭素原子がカルボニル、チオカルボニル、置換若しくは未置換イミノ、置換若しくは未置換アルキリデン又は前記した如き１個又はそれ以上の置換基Ｚを担持していてもよい。置換基Ｘに包含される構造の例辷は次のものが含まれる。上記式中、ｍは０〜８の値であり、ｎは０〜２の値であり、Ｒ８，Ｒ９，Ｒ１゜及びＲ１１は夫々水素、置換若しくは未置換アルキル、ポリハロアルキル、〈ニル又はベンジルであり、ここで許容され得る置換基は２につい、′Ｃ定義した通りである。式１が広範囲の窒素含有複素雪化合物を包含することは容易に理解されよう。植物からの発散による水分損失を減らし且つ作物の収率を高めるために使用゛され得る式１の範囲内の窒素含衣　１４−ＣＩ　ＯＣｊ　ＣＩ４　−　Ｆ　ＯＣＪＩ　ＣＩ２・　４−Ｃ烏　ＯＣｔ　ＣＩ４　−　ｃＨ，ＯＣＪ　ＣＪＩ４　−　ＣＨ３００Ｃｔ　ＣＩ３．４−ＣＪＩ、　ＯＣＩ　ＣＩ２、　３−Ｃノｘ　ＯＣ１ｌ　Ｃ１２，５−ＣＩ２　０　ＣＪＩ　ＣＩ３−ＣＩ　ＯＣｔ　ＣＩ　□ ２−　Ｃｊ　ＯＣＩ　ＣＩ３、　５−Ｃノｘ　ＯＣＩ　ＣＩ４　−　ＣＦ、　ＯＣｔ　ＣＩ４　−　ＣａＨｓＯ−’　ＯＣｊ　ＣＩ２　−　ＮＯ，ＯＣＩ　ＣＩ３−Ｎｏｔ　ＯＣｊ　ＣＪ４　−　Ｎｏ、　ＯＣ，ｔ　ＣＩ２、　４−Ｃｔ、　Ｏｃｔ　ＯＣＨ３表　１（続き）３　−　ＣＮ　ＯＣＩ　ＣＩ４−ＣＩ　ＯＦ　Ｒ４−ＣＮ　ＯＣｔ　ＣＩ２．６−ＣＩ、　ＯＣｔ　ＣＩ４−Ｃｏ、ＣＨ，ＯＣｔ　Ｃ□ ４−　ＣＨ２Ｃｏ、ＣＨ，ＯＣｔ　ＣＩ４−　Ｃ，）らＣｏ　−ＯＣｔ　ＣＩ４−　ＣＨ，Ｃｏ　−ＯＣｔ　ＣＩ２、　３．　４．　５−ＣＩ、　ＯＣＩ　ＣＩ２、　３．　４．　５．　６−ＣＩ、　ＯＣｔ　ＣＩ４−（ＣＨｌ）、Ｃ−ｏ　ｃｔ　ＣＩ４−ＣＨ，Ｓ−ＯＣｊｌ　ＣＩ４−（Ｃ，Ｈ，）、Ｃ−ｏ　ｃノ　ＣＩ、　３．４−ＯＣＲ２０−ＯＣＩ　ＣＩ３−ＣＨ，Ｃ０ＮＨ−ＯＣＪＩ　Ｃ７ｌ３−ＣＨ，Ｏ−ＯＣＩ　ＣＩ４−　Ｃ，）−〇）−〇−ＯＣｔ　Ｃ１表　１（続き）４−（Ｃ，Ｈ，ＣＨ（ＣＨ，）Ｏ−）　ＯＣｔ　ＣＩ３、　４．　５−（ＣＨｌ）ｍ　ＯＣｊ　ＣＩ３、　５”（ＣＨ，）、−４−Ｂｒ　ＯＣｊ　ＣＩ２−Ｂｒ −４−Ｃｊ　ＯＣｊ　Ｃ１゜４−０＝ＣＨ−ＯＣｔ　ＣＩ４−ｎ−Ｃ４ＨｇＯ−ＯＣＩ　ＣＩ４−　ｎ　−ＣｙＨｔｓｏ−ＯＣｔ　ＣＩ４−Ｃｊ−５，６−（Ｃ）ら）４−　ＯＣｔ　ＣＩ３−　（ＣＨｌ）、Ｎ−ＯＣｔ　ＣＩ４−　（ＣＩに−Ｎ　＝Ｎ−）　ＯＣｔ　ＣＩ２、　４−ＣＪＩ−６−ＣＯＯＨＯ（Ｊ　Ｃ１４−ＣａＨａ　ＯＣｔ　Ｃ）３−Ｆ　ＯＣｊ　ＣＩ２、　４−Ｃｊ、　ＯＢｒ　Ｂｒ表　１（続き）堤、−≦１２ダを峙もｂ８他ワシ生汀デ）−゛　ｏｃノ　ＣＩ２−ＣＨ５０−４ −７リル　ＯＣＩ　ＣＩ２、　４−ＣＩ、　ＯＣノ　ＣＨ。２、　４−ＣＪ、　ＯＢｒ　Ｏ（。３ｉ４−（ＣＨ＝ＣＨ−ＣＨ＝ＣＨ）−０ｃＪ２Ｃノ２．３−　（ＣＨＪｉ−ＯＣＩ　Ｃ）２、　３−（ＣＨ，）４−４−Ｃｊｔ　ＯＣＩ　ＣＩ２．３−（ＣＨ＝Ｃ１（− ＣＨ＝ＣＨ）−０ＣＩ　ＣＩ２．３−（ＣＨ＝ＣＨ−ＣＨ＝ＣＨ）−４−Ｃノー　〇Ｃ！　ＣＩ２．３−（ＣＨ＝ＣＨ−ａ−ｉ＝ＣＨ）−４−ＣＨ３０ｏ　ｃノ　ＣＩ２．６−ＣＩ、　Ｓ　Ｃｔｔ　ＣＩ４−ＣＨ，Ｓ　Ｃｊｔ　ＣＩ２、　４−ＣＩ２　Ｓ　ＣＩ　０１表　１（続き）４−Ｃノー２−ＣＨ（ＣＨ，）Ｃ，Ｈ，ＯＣｔ　ＣＩ２−ＣＨ３−４−（４−Ｃ）− ２−ＢｒＣｓＨ４０）−５−ＣＪｌ　ＮＨＣＪ　ＣＩ４−Ｎｏ、　ＮＨＢｒ　Ｂｒ表　１（続き）３−　ｎ　−０４）ＬＩＯＱ　ＣＪ　ＣＪ゛３−Ｃ，Ｈ，−ＣＨ，Ｏ−ＯＣｔ　ＣＩ４−　（４−（ＣｓＨｓＣＨｚＯ）−（）　ｃｔｔ　ｃｔＣ，Ｉ（、ＣＨ，０３− ２−１３ｒ　ＯＣｔ　Ｃ）２−　ＣＨ，０−４−ＣＨＯＯＣｊｔ　ＣＩ２、　３（ＣＨ，）、−ＮＨＣＩ　Ｃｊｔ２、　３−Ｏ−Ｃ（ＣＨ３）！０−　ＯＣｊｔ　ＣＩ３−　ＣＨ，＝ＣＨＣＨ，Ｏ−０’　ＣＩ　ＣＩ３−ＣＩＣＨ２ＣＨ２Ｏ−ＯＣｚ　ＣＩ３−ＣＨ，ＳＯ，−０−ＯＣｔ　ＣＩ２−ＣＨ，０−ＯＣｊｔ　ＣＩ２−　ｎ　−ＣｙＨｌ、Ｏ−ＯＣＩ　Ｃ１表　１（続き）゛２−Ｃ，Ｈ，ＣＨ，０−ＯＣｔ　ＣＩ２−　ｎ−Ｃ，Ｐ−〇−４−Ｂｒ　ＯＣ２Ｃｊｔ２−　ｉ　−Ｃ，Ｈ７０−３− ＣＪ　ＯＣｔ　ＣＩ２−Ｃ，Ｈ３ＳＯ２−０−ＯＣｊｔ　Ｃ１ｚ−ＢｒＣＨ，ＣＨ２−ＯＣｔ　ｃｔ２−ＣＨ，＝Ｃ（ＣＨ，）ＣＨ，−ＯＣＪ　Ｃ７表　１（続き）４−ＨＯＯＣＩ　ＣＩ３−ＨＯＯＣＩ　ＣＩ２−）（００Ｃ）　ＣＩ４−（ｉ−ＣａＨ２）−０’　ＣＪ　Ｃ□３−Ｃ２Ｈ，−ＯＣｔ　ＣＩ３−（ＣＨｌ）、Ｃ−ＯＣＩ　ＣＩ２−ｎ−０４Ｆら−ＯＣＪ　Ｃｊｌ２２−５ｅｅ−Ｃ４Ｈ−ＯＣｊｌ　ＣＩ２−ＣＪ　−４−ｎ−Ｃ１Ｈ７０ＣＪ　Ｃｊｌ２−Ｃ，Ｈ，−４−Ｂｒ　ＯＣｊｌ　ＣＩ３、３−（ＣＨ＝ＣＨ−ＣＨ＝ＣＨ）−表　１（続き）表　１（続き）４−ｎ−Ｃ４ＨｇＳ　−０’　ＣＩ　ＣＩ２−　ｉ　−Ｃ，Ｈ，Ｓ−ＯＣｔ　ＣＩ３−ｎ−Ｃ７Ｈ，、Ｓ−ＯＣＪ　ＣＩ４−ＨＣ＝ＣＣＨ，０−ＯＣｔ　ＣＩ３−ＨＣ＝ＣＣＨ，Ｏ−ＯＣｔ　ＣＩ２−ＨＣＣＩＣＨ，Ｏ−ＯＣＩ　ＣＩ４−（Ｃ，Ｈ，ＳＣＨ，Ｏ）−０Ｃｔ　ＣＩ３−　（Ｃ，Ｈ，ＳＣＨ，Ｏ）−０Ｃｔ　ＣＩ２−　（Ｃ，Ｈ，ＳＣＨ，Ｏ）−０Ｃｔ　Ｃｒ表　１（続き）代表的窒素含有複素環化合物３、．５−　（ＣＨ，Ｏ）、　ＯＣｊｌ　ＣＩ３、５−（Ｃ，Ｈ，ＣＨ，Ｏ）、　ＯＣｔ　ＣＩ３．５−（ＣＨｓＣｏ、）、　ＯＣＪ　Ｃ１１２、６−（ＱＨｓＯ）＊　ＯＣｔ　ＣＩ２−Ｃ，Ｈ，−ＯＣｊｌ　ＣＩ３−Ｃ，Ｈ，−ＯＣｔ　ＣＩ３−Ｃ，Ｈ，−００Ｃｔ　ＣＩ２−Ｃノー４−Ｂｒ　ＯＣｊ　ＣＩ２−Ｃｊ−４−Ｆ　ＯＣＩ　ＣＩ２．４−Ｆ、　ＯＣｊｌ　ＣＪｔ表　１（続き）２−Ｆ−４−Ｃノー　□　Ｃｔ　ＣＪ２−ＮＯ，−３−０２Ｈ，ＮＨＣＪ　ＣＪ２、　４−（ＮＯ２）２　ＮＨＣｊｌ　、Ｃノ２、　３．４−ＣＪ、　ＮＨＣＪ　Ｆ２−ＣＨ，０−ＣＨ，−ＮＨＦ　Ｆ３−（４−ＣノーＣ，Ｈ４０）　ＮＨＦ　Ｆ２、　３−（ＣＨ，５Ｏ２）、　ＮＨＣＪ　ＣＪ４−（２−Ｃｉ−４−ＢｒＣ，Ｈ４）　ＮＨＣｔ　Ｃ１ｚ２−Ｃノー４−ｎ−Ｃ，Ｈ３Ｏ−ＯＣＪ　ＣＪ２表　１（続き）代表的窒素含有複素環化合物Ｙ′２４＝（ｃｐ−ｃ６Ｈ４−ｓｏ２−ｏ−＞　ｏ　Ｃ，ｚ　Ｃｊｌ表　１（続き）３−ＣＨ，ＣＯ−ＯＣＪ　ＣＪ２−Ｂｒ７３−ｎ−Ｃ４Ｉ（ｅＯ−ＯＣＪ　Ｃ）２−ＣＨ，０−４−（ＣＨ，）３Ｃ−ＯＣｊ　ＣＪ４−Ｃ，Ｈ，ＣＨ＝ＣＨＣ０−ＯＣＪ　Ｃｊｌ２、　６−ＣＪ、−４−Ｎｏ２　０　Ｃｔ　ＣＪ４−ＣＯＮＨ，ＯＣｊｌ　ＣＪ３−　Ｃ，Ｈ，ＮＨＣＯ−ＯＦ　Ｆ４−　Ｃ０ＮＨＮＨ，ＯＣＪ　Ｃｔ４−ＣＨ＝Ｃ（ＣＮ）、　ＯＣｔ　Ｃｔ表　１（続き）２−ＣＨ，Ｏ−４００ノ　ＣノＣＨ，Ｃ（ＮＯ，）＝ＣＨ− ４−ＣＨ，Ｓｏ□　ｏｃノ　ＣＪ２−　ＣＨ，−４−Ｃｊｌ　−ＯＣｊｌ　ＣＪ２−ＣＨ，Ｃｊｌ−４−ＮＯ２０ＣＪ　ＣＪ２−ＣｔＨｇ−４−Ｎｏ２　０　Ｃｊｌ　Ｃｊｌ４−Ｎｏ、　Ｓ　ＣＪ　ＣＪ４−　（ＣＨ，）、Ｃ−Ｓ　ＣＪ　ＣＪ２．４−ＣＪ、−５−ＣＨ，、Ｓ　ＣＪ　ＣＪ２、　３　（ＣＨ＝ＣＨ−ＣＨ＝ＣＨ）−Ｓ　Ｃ７Ｃｔ４−ｃｓＨ８Ｏ− Ｓ　ＣＪ　ＣＪ２、　４−ＣＪ２　Ｓ　Ｆ　Ｆ２．４−ＣＪ２　Ｓ　Ｂｒ　Ｂｒ３．５−Ｃｊｌ２　Ｓ　Ｃｔ　Ｃｔ３−Ｃ，Ｈ，Ｏ−Ｓ　Ｆ　Ｉ２．４−ＣＪ、　ＯＦ　Ｆ２、　４−ＣＪ２　０　Ｂｒ　Ｂｒ表　１（続き）３．５−ＣＪ２　０　ＣＪ　ＣＪ３−Ｃ，Ｈ，Ｏ−ＯＦ　’ｌ３−（４−ＣノーＣ，Ｈ，Ｃｏ−）　Ｓ　（Ｊ　Ｃ）２−Ｎｏ、　Ｓ　ＣＪ　ＣＪ３−（４−ＣノーＣ，Ｈ，Ｃｏ−）　ＯＣｊ！　ＣＪ２−ＮＯ□　’　ｏｃノ　ＣＪ３−ＣｓＨｘｓＯ−Ｓ　−ＣＪ　ＣＪ２、　３．５−（Ｃ，Ｈ，）、−Ｓ　Ｃ１，０１表　１（続き）４−（Ｈ，Ｎ−Ｃ０ＣＨ，−）　ＯＣＪ　ＣＪ４−Ｃ０２（ＣＨ２）、、ＣＨ３０ＣＪ　Ｃｓ４−（Ｈ２ＮＣ−ＮＨ−）　ＯＣＪ　Ｃノ２．４−Ｃｊ！、−５− ＣＨ，ＯＣｊ　ＣＪ２−Ｃノー４−ＮＯ□　ＯＣｔ　ＣＪ２−ＣＨ２０Ｈ−４−Ｃｊ　ＮＨｃｉ　ＣＪ２−ＣＨ２ＯＣＨ３ＮＨＣＪ　ＣＪ２−ＣＨ，Ｃｏ−４−ＣＪ　ＮＨＣＪ　ＣＪ２−Ｃ，Ｈｓ　ＯＣｊ　０１表　１（続き）代表的窒素含有複素環化合物表　１（続き）表　１（続き）Ｏ表　１（続き）表　２（続き）２．４−Ｃ，ｔｔ、　−ＯＣｊ　Ｐ（＝Ｏ）（ＯＣ２Ｈｓ）ｉ２、　４−Ｃｊ２　０　０ノ　ＯＣＨ，ＣＦ。２、　４−Ｃｊ、　ＯＣｊ！　ＣＮ２．４−Ｃｊ！２　０　Ｃｊ　ＳＣＭ。ＨＯＣｊ　ＣＣノ。２．４−Ｃｊ！２　０　ＣＪＬ　ＣＨ３ＣＯ−２，４−Ｃｊ２　０　Ｃｊ　ＣＨ３Ｃ０ＣＨ，−２、４−Ｃｊ、　ＱＣノ　ＣＦ。２、　４−Ｃｊ、　ＯＣｔ　ＣＨ３５ｏ。２、　４−Ｃｊ、　ＱＣノ　−５ＣＥＮ２、　４−Ｃ１ｚ　ＯＣｊ　Ｈ表　２（続き）３−Ｎｏ、　ＯＣｊ　Ｈ２、４−Ｃｊ、　ＯＣｊ　−（、：ＣＨ２，４−Ｃｊ２　０　Ｃ）　−ＣＨ＝ＣＨ。３−Ｎｏ、　ＯＣｊ　−Ｃ：ＣＨ２、４−Ｃ１２’ｏ　Ｆ　−Ｃ−１：ＣＨ２、４−ｃｊ！　ＯＣｔ　ＣＨＦ。２、　４−Ｃｊ、　ＯＣｊ！’　Ｃ０ＮＨ。２、　４−Ｃｊ、　ＯＣｊ　、ＣＨ，ＣＯ□Ｃ，Ｈ。２、　４−　Ｃｔ、　ＯＦ　−Ｎ（ＣＨｌ）！２．４−Ｃｊ！、　ＯＣｊ　−Ｐ（＝Ｏ）（ＱＣ，Ｈ，）。２、　４−Ｃｊ、　ＯＣｊ　−〇ＣＣＮ２−ＣＨｌ−４（２−Ｂｒ−ＮＨＣ，Ｃ。４−Ｃ）−〇、Ｈ３０）２−Ｃｊ　ＮＨＣｔ　ＣＮ２、　４−Ｃｊ、　ＱＣノ　−Ｐ（＝Ｏ）（ｏｃ、）（、）ｚ表　２（続き）２、　４−Ｃｊ、　ＮＨＣｔ　ＣＮ２、　４−Ｃｊ、　ＯＦ　ＣＨ１３’−Ｃ，Ｈ，Ｏ−０、Ｆ’　Ｃ，Ｈ。３−Ｎｏ、　ＮＨＦ　ＣＨ。３−　（ｎ−ＣｓＨｌｓ）−０Ｃｔ　ＣＮ表　２（続き）代表的窒素含有複素環化合物表　２（続き）表　２（続き）２、　３−　（ＣＨ＝ＣＨＣＨ＝ＣＨ）　’　ＯＣＪ　ＯＣＨ，ＣＦ３２．４− ＣＪ２　ＯＣノ　Ｃ２Ｈ３Ｏ代表的窒素含有複素環化合物２、４−Ｃ烏　ＯＣＮ　ＣＨ３２、４−ＣＪ２　０ＣＮＨ２、４−Ｃ烏　ＯＮｏ、　Ｈ２、４−ＣＪ、　ＯＣ０Ｇ（、Ｃ）　Ｈ２、４−ＣＪ２　０　ＣＮ　ＣＮ４−　Ｃ，Ｈ，０００ＣＨ，ＣＦ、０ＣＲ２０Ｆ３４−ＣＪ゛　０　００（２ＣＦ、０ＣＲ２ＣＦ。４−Ｂｒ’　Ｓ　ＯＣＦ、　ＯＣＦ。２．３−（ＣＨ＝ＣＨ−ＣＨ＝ＣＨ）−Ｓ　ＣＣノ、　ＣＣノ。３．４−　（ＣＨ２）４　０　ＣＦ３　ＣＦ！３、　５−ＣＪ２　０　０ＳＯ２ＣＨ３０ＳＯ２ＣＨ３３−ＮＯ□　００ＳＯ２ＣＦ、０８Ｏ２ＣＦ。３−　Ｃ，Ｈ２ＣＯ’　ＮＨ０８０２ＣＦ、０８０．ＣＦ３３、４−（ＣＨ＝ＣＨ−ＣＨ＝ＣＨ）　−００ＳＯ，ＣＨ３ｃ、Ｍ。４−　ＣＨ，Ｓ　ＯＣＮ　０８０２ＣＨ。４　＋　Ｃ，Ｈ，ＮＨ０ＣＯＣＨ，０ＣＯＣＨ。３、４−Ｃノ２０ＳＯ２ＣＨ１Ｓ０２ＣＨ３Ｘ１−　″　″　−−−−−−− ＪトＩ憂工工工＝工に工ニ■憂 −Ｘ　ＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯｅＥ ′　工　工　工　工　エ　工　工　国　工　閃　工　閃　工　工　（ＪＣＪＣＪトマトエに３（冨工ヱ工工工エエ８匡工ゾ１．ａ　、　Ｅ：ｌ：工工工１（ｂ６エ８エマ１エエ：ｌ：：ｅｆｌ：：Ｅｆｌｆｌ：ｅＥＥ：ｅＥｋ−１６易乙乙、５５，５５５乙Ｉ　ＩＩ川用エ＊：ｅ：ｃ工工；工３エエ　工工工ミＭ１００ＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯ−、’ １５５Ｈ５５５５憂エエヨエＪ３剖乙工：！：０：に工工工工；二工国置ミヱ工工ｒ１エエエご工ご工８工８エエエ工工ごごごジｌ０ＩＩωＣＩＯｃａ　ＣＯｃｏ　ｃａ　ｃｏωＩ韓０＝ωずト；に＝＝＝憂会藁２二＝　エマ１８１＝＝＝３−工；藁りご　需用Ｑ　−ＣｆＪ　Ｏｘω　０胃り寥η　０曝ｏ　ｏ鰯　。蕩ｃａｃａｃａｃｏｗＯ′Ｏ′Ｏ′５川　ご　ミ　工　エ　工　工　子３３、Ｏｌ　１’１＞　ＵｕｕＵＱｕｌ−＋ｔ−＋ｕｕｔ−’Ｃ，＋ｕ□　ＣＪミａ８８８”ｅ３８ −．３８δ８８８　８；＋＝’＝ｇ＝ｇｇｇ＝＝＝　＝ ζ苫８こごご８８苫。−０゜ぐしｏａｇｉｇｇｇ８ｇ８ｇゾ＋：ご工ｉ−エ１憂工；ズ１−・・−・−〜−−−−−〜・−−−ずｌＯＯＯＯＯ１００ＯＯＯＯＯＯｅ４’ｃｏＣＱｃｏｃｏｔ。ス■＝閃工：Ｉ：工ミ工工ｌ（工冒工ヱエ工工千ｇ：会会工閃工３．　Ｅ　Ｅ匡工工工ヱゴ −Ｈ’、ＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯＯ；ｌ：Ｉ：＝工＝工０：工ご；＝エエエエ表　７代表的窒素含有複素環化合物ＨＨＨＨＨＩ　Ｃｏ　ＨＨＨＣ１ＨＨＩ　Ｃｏ　ＨＣＬ　ＨＣ１ＨＨＩ　Ｃｏ　ＨＨＣＬ　ＣＬ　ＨＨＩ　Ｃｏ　ＨＨＣＬ　ＨＨＨＩ　Ｃｏ　Ｈ、ＨＢｒ　ＨＨＨＩ　Ｃｏ　ＨＨＨＢｒ　ＨＨＩ　Ｃｏ　ＨＨＦ　Ｆ　ＨＨＩ　Ｃｏ　ＨＨＨＩ　ＨＨＩ　Ｃｏ　ＨＦ　ＨＣ１ＨＨＩ　Ｃｏ　ＨＨＨＣＨ３ＨＨＩ　Ｃｏ　ＨＨＣＨ３ＨＨＨＩ　Ｃｏ　ＨＣＨ３ＨＨＨＨＩ　Ｃｏ　ＨＨＨ佇プロピツレ　ＨＨＩ　Ｃｏ　ＨＨＨｌ−かル　ＨＨＩ　Ｃｏ　ＨＯＣＨ３ＨＨＨＨＩ　Ｃ０ＨＨ０ＣＨ３ＨＨＨＩ　Ｃｏ　ＨＨＨＣＣＨ３ＨＨＩ　Ｃｏ　Ｈ表　７　（続き）ＨＣＦ３Ｉ（ＨＨＩ　Ｃ０ＨＨＨＣＦ３　ＨＨＩ　Ｃｏ　ＨＨＯＣＦ３ＨＨＨＩ　Ｃ０ＨＨＨ０ＣＦ３ＨＨＩ　Ｃｏ　ＨＨＨ０ＣＦ２ＨＨＨＩ　Ｃｏ　ＨＨＨ０ＣＦ２Ｃ１ＨＨＩ　Ｃｏ　ＨＨＮＯ２ＨＨＨＩ　Ｃ０ＨＨＨＮｏ２ＨＨＩ　Ｃｏ　ＨＨＣＮＨＨＨＩ　Ｃ０ＨＨＨＣＮ　ＨＨＩ　Ｃｏ　ＨＨＨ５ｏ２ＣＨ３ＨＨＩ　Ｃｏ　ＨＨＨＳｏ□ＫＣＨ３）２ＨＨＩ　Ｃｏ　ＨＨＨ５ＣＨ３ＨＨＩ　Ｃｏ　ＨＨＨＨＨＨＩ　Ｃｏ　ＣＨ３Ｉ　ＨＣ１ＨＨＩ　Ｃｏ　ＣＨ２Ｃｌ　ＲＣＬ　ＨＨＩ　Ｃ０ＣＨ５ＨＨＣＨ３Ｉ　ＨＩ　Ｃｏ　ＣＨ３Ｉ　Ｈ００（３ＨＨＩ　Ｃｏ　ｃＩ（３表　７　（続き）ＨＮｏ２ＨＨＨＩ　Ｃｏ　ＣＨ３Ｉ　ＣＮ　ＨＨＨＩ　Ｃｏ　ＣＨ３Ｉ　ＨＣＦ３　ＨＨＩ　Ｃｏ　ＣＨ３Ｉ　ＨＨＨＨＯＣ０ＣＨ５ＨＨｃｔ　ＨＨＯＣＯＣＨ３Ｃ１ＨｃｔＨＨＯ−Ｃ０ＣＨ５ＨＣｔＨＨＨＯ−Ｃ０ＣＨ５ＨＨ０ＣＨ３ＨＨＯ−Ｃ０ＣＨ５ＨＨ’ＣＨ３ＨＨＯ−Ｃ０ＣＨ５ＨＨ５ＣＨ３ＨＨＯＣ０ＣＨ５ＨＨＣＦ３　ＨＨＯ−Ｃ０ＣＨ５ＨＨ０ＣＦ２ＨＨＨＯ−Ｃ０ＣＨ５ＨＨ０ＣＦ２ＣＬ　ＨＨＯ−Ｃ０ＣＨ５ＨＮｏ２ＨＨＨＯ−Ｃ０ＣＨ５ＨＣＮ　ＨＨＨＯ−Ｃ０ＣＨ５ＨＨＨＨＨＯ−Ｃ０ＣＦ５ＣＬ　ＨＣＬ　ＨＨＯ−Ｃ０ＣＦ３表　７　（続き）代表的窒素含有複素環化合物ＨＨＨＨＨＩＣ８ＨＣ１ＨＣＬ　ＨＨＩ　Ｃ３ＨＨＨＨ’ＨＨＩ　５ｏ２ＨＨＨＣＬ　ＨＨＩ　５ｏ２ＨＣＬ　ＨＣ１ＨＨＩ　５ｏ２ＨＣＯ２ＣＨ３ＨＨＨＨ’　１　５ｏ２ＨＨＨＣＨ３ＨＨＩ　ＳＯ２ＨＨＨ０ＣＨ３ＨＨ１５ｏ２ＨＨ０ＣＨ３ＨＨＨＩ　Ｓｏ□　ＨＮｏ２ＨＨＨＨＩ　Ｓｏ□　ＨＨＣＮ　ＨＨＨ１５ｏ２ＨＨＨＣＦ３ＨＨＩ　５ｏ２ＨＨＨＨＨＨＯ５Ｏ２ＣＨ３ＨＨＣＬ　ＨＨＯ５Ｏ２ＣＨ３Ｃ４ＨＣＬ　ＨＨＯ５Ｏ２ＣＨ３ＨＨＣＨ３Ｉ　ＨＯ５Ｏ２ＣＨ３ＨＨ０ＣＨ３ＨＨＯ５Ｏ２ＣＨ３ＨＨＣＦ３ＨＨＯ５ｏ２ＣＨ３表　７　（続き）ＨＣＮ　ＨＨＨＯ−５Ｏ２ＣＨ３ＨＨＮＯ２Ｈ、ＨＯ−５Ｏ２ＣＨ３ＨＨＨＨＨＯ−５ｏ２ＣＦ３表　８ＨＨＨＨＨＨＨＣＬ　ＨＨＣｌ　ＨＣＬ　ＨＨＨＣＬ　ＨＨＨＨＣＬ　ＣＬ　ＨＨＨＨＢｒ　ＨＨＨＨＦ　ＨＨＨＨＣＦ３ＨＨＨＨＣＨ３Ｉ　ＨＨ０ＣＲ３ＨＨＨＨＨＯＣＨ３ＨＨＨＨＥｒ：Ｈ３ＨＨＨ，ＮＯ２ＨＨＨＨＨＮｏ２ＨＨＨＣＮ　ＨＨＨ表　８　（続き）ＨＨ５Ｏ２ＣＨ３ＨＨＨＨＮ（Ｃ亀）ｚ　ＨＨＨ、ＨＣ０２ＣＨ３ＨＨＯＨＨＨＣＨ３Ｉ表　９ＨＨＣ１ＨＨＮＨＯＨＣＬ　ＨＣＬ　ＨＨＮＨＯＨＨＨＣＨ３ＨＨＮＨ’ＯＨＨＨ０ＣＨ３ＨＨＮＨＯＨＨＨＣＦ３ＨＨＮＨＯＨＨＨ５ＣＨ３ＨＨＮＨＯＨＨＨｓｏｚ、ｃＨ３ＨＨＮＨＯＨＨＨＨＨＨＮＨＳ　Ｈｃｔ　ＨＣ１ＨＨＮＨＳ　ＨＨＨＨＨＨＯＯＨＣＬ　ＨＣＬ　ＨＨＯＯＨＨＨＣＨ３Ｉ　ＨＯＯＨＨＨＯＣＨ３ＨＨＯＯＨＨＨＣＦ３ＨＨＯＯＨＨＮｏ２ＨＨＨＯＯＨＨＣＮ　ＨＨＨＯＯＨＨＨＨＨＨＯＳ　Ｈ表　９　（続き）代表的窒素含有複素環化合物ＣＬ　ＨＣＬ　ＨＨＯＳ　Ｈ表　工ＯＣ１ＨｃｔＨＨ−重結合Ｃｔ、ＨＨＨＨ−重結合ＨＣＬ　ＨＨＨ−重結合Ｉ（Ｉ（ＣｔＨＨ−重結合ＨＨＢｒ　ＨＨ−重結合ＦＨＨＨＨ−重結合ＨＦＨＨＨ−重結合ＨＨＦ　ＨＨ−重結合ＨＨＩ　ＨＨ−重結合ＣＨ３ＨＨＨＨ−重結合ＨＣＨ３ＨＨＨ−重結合ＨＨＣＨ３ＨＨ−重結合ＨＨイソプロピル　ＨＨ−重結合ＨＨｔ−ブチル　ＨＨ−重結合０ＣＨ３ＨＨＨＨ−重結合ＨＯＣＨ３ＨＨＨ−重結合ＨＨ０ＣＨ３ＨＨ−重結合表　１０　（続き）ＨＣＦ３ＨＨＨ−重結合ＨＨＣＦ３　ＨＨ−重結合ＨＨ０ＣＦ２ＨＨＨ−重結合ＨＨ０ＣＦ２ＣＬ　ＨＨ−重結合ＣｔＣｔＣＩ　ＣＬ　ＣＬ　−重結合Ｆ　Ｆ’　Ｆ　Ｆ　Ｆ　−重結合ＨＮｏ２ＨＨＨ−重結合Ｉ（ＨＮ０２Ｉ（Ｉ（−重結合ＨＣＮＨＨＨ−重結合ＨＨＣＮ　ＨＨ−重結合ＨＨ５ＣＨ３ＨＨ−重結合ＨＨＳｏ□ＣＨ３ＨＨ−重結合ＨＨＮ（ＣＨ３）２ＨＨ−重結合ＨＨｃｏ２α３ＨＨ−重結合ＨＨＨＨＨＣＨ２Ｃｌ　ＨＣＬ　ＨＨＣＨ３Ｉ　Ｃ１ＨＨＨＣＨ３Ｉ　Ｃ１Ｃ１ＨＨＣＨ２表　１０　（続き、）ＨＨＢｒ　ＨＨＣＨ３Ｉ　Ｆ　ＨＨＨＣＨ３Ｉ　ＨＦ　ＨＨＣＨ２Ｆ　）！　Ｃ１Ｈ）Ｉ　ＣＨ３Ｉ　Ｎｏ□　ＨＨＨＣＨ３Ｉ　ＣＮ　ＨＨＨＣＨ２ ′ＨＨＯＣＨ３ＨＨ′　ＣＦ３Ｉ（ＣＩ（３Ｈ１（ＨＣＨ３Ｉ　ＨＣＨ３Ｉ　ＨＣＨ３Ｉ　Ｉ（５ＣＨ３ＨＨｃＨ２ＨＨ５ｏ２ＣＨ３ＨＨＣＨ３Ｉ　！（Ｎ（ＣＨ３）２　ＨＨＣＨ３Ｉ　ＨＨＨＨＣＨＣＮＨＨＣ１ＨＨＣＨＣＮＣＬ　ＨＣＬ　ＨＨＣＨＣＮＨＨＣＨ３Ｉ　ＨＣＨＣＮＨＨ０ＣＨ３ＨＨＣＨＣＮＨＨＮｏ２ＨＨＣＨＣＮ表　１０（続き）ＨＨＣＦ３ＨＨＣＨＣＮ）Ｉ　ＨＨＨＨＣＨＣＯ２ＣＨ３Ｃ２ＨＣ２ＨＨＣＨＣ０２ＣＨ３Ｉ（ＨＨＨＨ−Ｃ＝Ｃ− １（Ｈｃｔ　ＨＨ−ｃ＝ｃ− ｃｔ　Ｈｃｔ　ＨＨ−ｃ＝＝ｃ− ＨＨＣＨ３Ｉ　Ｈ−Ｃ２Ｃ− ＨＨ０ＣＨ３Ｈ）ｔ　−Ｃ−ＥＣ− ）Ｉ　ＨＣＦ３ＨＨ−Ｃ＝Ｃ− ＨＮｏ２　ＨＨ）Ｉ　−ｃ＝：ｃ− ＨＣＮ　ＨＨＨ−Ｃ＝Ｃ− ＨＨＨＨＨ−ＣＨ＝ＣＨ− ＨＨＣ１ＨＨ−ＣＨ＝ＣＨ− Ｃ１ＨＣ１ＨＨ−ＣＨ＝ＣＨ−。ＨＨＣＦ３ＨＨ−ＣＨ＝ＣＨ− ＨＨＣＨ３Ｉ　Ｈ−ＣＨ＝ＣＨ− ＨＨＯＣＨ３ＨＨ−ＣＨ＝ＣＨ− 表　１０（続き）ＨＮＯ，）Ｉ　）Ｉ　Ｉ（−ＣＨ＝ＣＨ−Ｉ（ＣＮ　ＨＨＨ−ＣＨ＝ＣＨ− Ｈ）！　ＨＨＨＣＨ２Ｃ− 表　１０（続き）表　１０（続き）ＨＨＱＣ６Ｈ５ＨＨ−Ｃ（ＣＨ３）２−Ｂｒ　ＨＢｒ　ＨＨ−ｃｇ　Ｃ２Ｈ５）　−ＨＨ−０−ＣＨ２−０−Ｈ−ｃ（ｃｚ２）−−ＣＨ＝ＣＨ−α−ＣＨ−ＨＨＨ−重結合Ｈ−ＣＨＨＨ−ＣはＣＨ−ＨＨ−重結合ＨＮＯ２１（ＨＨ−重結合ＨＨＣ６Ｈρ−ＨＥ　−重結合ＨＣ６Ｈ５０−ＨＨＨ−重結合ＨＨＣ６Ｈ３ＨＨ−重結合表１０（続き）Ｃ，Ｈ，−ＨＨＨＨ−重結合 −ＣＨ＝ＣＨ−ＣＨ＝ＣＨ−Ｃ２Ｈ，ＯＨＨ−重結合ＨＨＣＨ３ＨＨ−重結合ＨＣＩ　ＣＩ　ＨＨ−重結合表　１１Ｈフェニル　−Ｃ（Ｃｕ、）−Ｎｏ−Ｃｔ　ＣＩ２．６−ＣＩ２　フェニル　− ＣＨ＝ＮＯ−ＣＩ　ＣＩ２．４−Ｃｊｌ２　フェニル　−ＣＨ＝ＮＯ−Ｃｉ　ＣＩ４−ＮＯ，フェニル　−ＣＨ＝ＮＯ−ＣＩ　Ｃ７２−ＣＨ５０−４−ＣｓＨｘｔＯフェニル　−ＣＨ−Ｎｏ−ＣＩ　ＣＩ４−ＣＩ　フェニル　−Ｃ０ＣＨ−Ｎｏ−ＣＩ　ＣノＨフェニル　−Ｇ（２ａＮ［Ｈ２Ｃ（＝ＮＯ−Ｃ１ｔ　ＣＩ４− ＣＩ　フェニル　−５ＣＨ２Ｃ（ＣＨｌ）−ＮＯ−Ｃｊｌ　ＣＩ４−ＣＩ　フェニル　−５Ｏ２Ｇ（２Ｃ（ＣＨ３）−ＮＯ−Ｃ７！　ＣノＨフェニル　Ｓｅ　ＣＩ　ＣＩ２．４−Ｃｊｌ　フェニル　Ｓｅ　Ｃｚ　Ｃｊｌ４−Ｂｒ　フｘ＝ル　Ｓｅ　ＣＩ　ＣＩ２−Ｃｊｌ−５−ＣＮ　フェニル　−ＰＯ（ＯＣＨ３）−Ｃｊｌ　ＣＩ３．４−（ＣＨｓ）ｚ　フェニル　−ＰＨ（−０）−Ｆ　ＦＨフェニル　−０− ＰＯ（ＯＣ）（３）−ＣＪ　ＣノＨフェニル　５ｉ（ＣＨ３）、−ＣＩ　ＣＩ４ −Ｃ，Ｈ，Ｃ０ＮＨ−フェニル　−ＮＨ−８Ｑ□−ＣＩ　Ｃノ表１１（続き）４−ＣＪ　フェニル　−ＣＥＣ−Ｆ　Ｆ２．４−ＣＪ　フェニル　−〇＝Ｃ−Ｆ　０ＣＨ３Ｈフェニル　−Ｃ＝Ｃ−ＣＪ　ｏＣＨ，ＣＦ。Ｈ２−ピリジニル　−Ｃ＝Ｃ−ＣＪ　ＣＪ３−Ｎｏ２　２−ピリジニル　−０（＝ＣＨ−（ｃｌｓ）　Ｃ７！　ＣＪ３−Ｎｏ２　２−ピリジニル　＝ＣＨ＝ＣＨ −（ｔｒａｎｓ）　ＣＪｔ　Ｃｉ３、４．５−（ＣＨり、フェニル　−ＣＯ−Ｃｔ　ＱＣ，Ｈ。３−ＣＪ　フェニル　−〇〇−Ｉ　Ｉ表１１（続き）５−ＣｓＨ，Ｏ−１−ナフチル　−ＮＨＯ−（Ｊ　ＣＪ２．４−Ｃｊ！、　フェニル　−８−８−ＣＪ　Ｃ）Ｈフェニル　−５−８−　Ｃ７ＩＣノ２−Ｆ−３−ＣＪ　フェニル　−５−Ｓ−ＣＪ　ＣＪ２．３−（ＣＨ＝Ｇ（ＣＨ＝ＣＨ）−フｘニル−、Ｉ結合Ｃｊ！　ＣＮ５−Ｎｏ、　フェニル　一重結合　Ｃｔ　ＣＮ４−Ｃ，Ｈ，フｘニルー３ｉ結合　（Ｊ　ＣＮ２−Ｃ１１）ｘニル− 重結合０−ＣＥＥｃＨＨフェニル　一重結合　ＣＪ　ＣＣノ。２．３−（ＣＨ＝ＣＨＣＨ＝ＣＨ）−７ｘニル−３ｉ結合Ｃ４！　ＣＨ３５Ｏρ −表１１（続き）：Ｌ　４．５−（ＣＨ３）、　７ｘ＝ル　一重結合Ｃｔ　ＣＨ３Ｓ０，０−Ｈフェニル　一重結合　Ｃｔ　ＣＦ、ＣＨ，０２−Ｃ，Ｈ，７μル　一重結合　ＦＦ４−ＣＨ３フェニル　一５Ｏ２ＮＨＣＯＮＨ−Ｃｔ　ＣＪ２−ＣＩ！　フェニル　−８Ｏ，ＮＨＣＯＮＨ−ＣＪ　ＣＪＩ３−Ｎｏ、　フェニル　＝ＣＨ，Ｃ０Ｃ）ら−Ｃｔ　ＣＪ４−Ｃ，Ｈ，Ｏフェニル　−ＩＣＨ，ＣＯＣＨ２−ＣＪ　Ｃ１表１１（続き）Ｈフェニル　一重結合　００（、ＣＦ、ＣＨ２へＨ１−ナフチル　一重結合　０圧蓼玖　αす２止Ｈ１−ナフチル　一重結合　Ｃル　ＣＮＨ）ｘ＝ル　−ＣＥＣ −σＨ，ＣＦ、αＢ２ｃＦｓＨ１−ナフチル　一重結合　ＣＮ　ＣＮ３−　Ｃ，Ｈ，フェニル　一重結合　ＣＮ　ＨＨ７エユヤ　＝ＣＨ，Ｎ＝Ｑ（Ｃ−Ｃ−Ｃ）　ＣノＨ７エユル　−Ｇ（２ＮＨＣＨ２Ｃ−Ｃ−Ｃ）　Ｃノ表１１（続き）２．４−ＣＩ２　フェニル　一０ＣＨ２ＣＨ２０−ＣＩ　Ｃ，、！２．４−ＣＪ２　フェニル−０ＣＨ２−ＣＩ　ＣＪ１２．４−Ｃ石　フェニル　−０ＣＨ（ＣＨｌ）−Ｃｉ　Ｃ□２．４−　ＣＪ２　７ｘ＝ルーＱＣ（ＣＨｘ）ｚ　−Ｃ−’ 　ＣＪ２．４−ＣＪ２　７ｘニル−０ＣＨ２０−ＣＪ　Ｃ２表　１２０ＣＲ３０ＣＨ３１０ＣＨ２ＣＨ３０ＣＨ２ＣＨ，１フエニル　ＯＣＨ３１フエニル　フェニル　０表　１３ＣＨ８ＣＨ３ＣルＣＨ３ＣＨ８ｔ−ブチルフェニル　ＣＨ３ＣＨ。表　１４代表的窒素含有複素環化合物ＣＨ３（ＣＨ２）１ＢＣＦ２ＣＦ２０−　ＣＩ　ＣＮＣＨ３０−（ＣＨ，ＣＨ２０）７ＣＨ２Ｃ＝Ｃ−ＣＩ　ＯＣＨ，ＣＦ。表１４（続き）代表的窒素含有複素環化合物００ＣＨ。表　１５代表的窒素含有複素環化合物ｙ′２４ｙ／、　ｘ’、ｌｙ′２６ｙ′！７ｙらＣＨ。表　１５（続き）ｙ’ｔｎ　Ｙ’２Ｓ　Ｘ’ｌｌ　ｙ’ａ　ｙ′Ｉ？Ｙ’２１１Ｃ１Ｃ１Ｎ　Ｈ，Ｃ１Ｃ１ＣｔＣｔＮ　ＣＨ３ＣＯＣ１ＣＬＣＩ　ＣＺ　Ｎ　ＣＨ３ＳＯ２−ＣＬ　ＣＬｃｔ　ｃｔ　ｓ　ｃｔ　ｃｔｃｔ　ｃｔ　＝ｓ−ｓ−ｃｔ　ｃｔｃｔ　ｃｔ　−ＮＨ−ＮＨ−ｃｔ　ｃｔＣｌ　Ｃ１−Ｎ＝Ｎ−ＣＬ　ＣＬｃｔ　ｃｔ　−重結合　ｃｔ　ｃｔｃｔ　ｃｔ　ｏ　−ｃｔ　ｃｔＣｌ　Ｃ１−ＣＨ，ＣＨ−ＣＬ　Ｃ１表　１５（続き）代表的窒素含有複素環化合物ｃｔ　ｃｔ　３ｐ＝ｏ　ＱＣ２Ｈ５ｃｔ　ｃｔ表　１６代表的窒素含有複素環化合物表　１６（続き）表　１６（続き）代表的窒素含有複素環化合物表　１６（続き）代表的窒素含有複素環化合物表　１６（続き）代表的窒素含有複素環化合物表　１６（続き）代表的窒素含有複素環化合物Ｒ’ｔｓ　Ｙ’２９　￥′ｓ０表　１６（続き）ＩＣ＝　ｃ　−ｃｔ　ｃｔｔ表　１６（続き）代表的窒素含有複素環化合物表　１６（続き）代表的窒素含有複素環化合物 −ＣＨ二ＣＨＣＮ　ＣＬ　ＣＬ −ＣＨ＝ＣＨＣＯＣＨ３Ｃ１（Ｊ −ＣＨ＝ＣＨＣＯ２Ｃ２Ｈｓ　Ｃ１Ｃ１−Ｃｏ２Ｃ６Ｈ５ｃｔ　ｃｔ −ＮＨＣＯＣ２Ｈ５ｃｔ　ｃｔＣＨ３ＳＯ２ＮＨ−ｃｔ　ｃｔ −ＣＨ２ＣＮ　Ｃ１Ｃ１表　１７代表的窒素含有複素環化合物表　１７（続き）表　１７（続き）代表的窒素含有複素環化合物表　１７（続き）表　１７（続き）代表的窒素含有複素環化合物表　１７（続き）代表的窒素含有複素環化合物表　１７（続き）代表的窒素含有複素環化合物表　１７（続き）表　１７（続き）表　１８代表的窒素含有複素環化合物２一ピリジニル　一重結合　Ｃノ　Ｃノ３−ピリジニル　ＯＣｔ　Ｃノ表１８（続き）表１８（続き）表１８（続き）表１８（続き）表１８（続き）表１８（鍔話）表１８（続き）クレ＼ＡＩＪ＼Ｒソし一ノ代表的窒素含有複素環化合物表１８（続き）表　１９代表的窒素含有複素環化合物表１９（続き）表　２０（ＣＨｓ）ｓＳｉ　Ｃｊ　ＣノＣ８にＯ−Ｃｊ　Ｃ１ＣＨ３ＮＨ−ＣＨ（ＣＨ，）−Ｃｊ　ＣＪ（Ｃ８υ、Ｃ（ＯＨ）　−Ｃ４ＣノＣＨ，＝ＣＨ−０−ＣＪ　ＣＪ（ＣＨ３）、ＮＣＨ２−ＣＪ　ＣＪ（ＣＨ３）ｉｓｉＯｃＨ，−Ｃｔ　ＣＪ表２０（続き）ＣＨ，ＯＣＨ，−Ｃｊｌ　ＣノＣＨ，５ＣＨ２−ＣＩ　ＣノＣＨ２＝ＣＨ−ＣＩ　ＣＪＨ２ＨＣ：＝Ｃ（ＣＨ２）、　−Ｃ７ＩＣＪＨＣ＝Ｃ（ＣＨ２）、　−Ｃ７ＣｊＩＣノーＣＨ２−Ｃｔ　ＣｊｌＢｒ−ＣＨ２−ＣＩ　ＣノＨＯ−ＣＨ，−ｃｉ　ｃノＣＨ，０−ＣＨ＝ＣＨ−Ｃ＊　Ｃｔ表２０（続き）ＨＯ（ＣＨ２”）ｚ　−ＣＩ　ＣＩＣ２Ｈ，ＣＨ（ＯＨ）−ＣＩ　ＣノＨ２ＮＣＨ，−Ｃｐ　ＣＩ（ＣＨｌ）、ＮＣＲ２−（Ｊ　Ｃ）（ＣｚＨ５’）２ＮＣＩ（ｚ　−Ｃｊｔ　Ｃ）ＨＣ＝ＣＣＨ，−ＮＨ−ＣＨ２− ＣＩ　ＣＩ（ＨＣＥ：ＣＣＨ，）２Ｎ−ＣＨ２−ＣＩ　Ｃノ表２０（続き）ＨＯ，Ｃ−ＣＩ　ＣノＨＣＩ　ＣＩｎ−Ｃ１Ｈ７−ＣＩ　ＣＩ（ＣＨ３）３Ｃ’−ＣＪ　、　Ｃ１表　２１代表的窒素含有複素環化合物 −ＮコＣＣ１２ｃｔ　ｃｔ −８ＣＨ３ＣＬ　ＣＬ −ＣＨ＝ＮＯ）Ｉ　ＣＬ　ＣＬ −ＮＨＣＯＣＨ３ｃｔ　ｃｔ −ＮＨＣＯＣＨ３ｃｔ　ｃｔ −ＣＨ＝ＣＨＣＮ　Ｃ１ＣＬ −ＣＨ＝ＣＨＣ０ＣＨ５ＣＬ　Ｃ１ −ＮＨＣＯＣＨ３ＣＬ　ＣＬ −Ｎ（ＣＨ２Ｃ４）２ｃｔ　ｃｔ −ＣＨ３５Ｏ２ＮＨ−ＣＬ　ＣＬ（ＣＨ３）２Ｎ−Ｃ１Ｃ１（ＣＨｌ）２Ｎ　−ｃｔ　（ＣＨ３）２Ｎ　−（ＣＨ３）２ＣＨＯ−Ｂｒ　Ｂｒ（ＣＨ３）２Ｃ＝ＮＯ−ｃｔ　ｃｔ表　２２２−ＣＨ３−４−Ｃ６Ｈ４０−フェニル　ｓ　ｃｔ　Ｈｃｔ４−Ｃ６Ｈ５−フェニル　ＯＨＢｒ　Ｂｒ４−ＣＬ　フェニル　ＯＦ　−ＣＨ二ＣＨＣＨミＨ−２，４−ＣＩ２　７ｘニル　ｏ　ＣＬ　−ＣＨ＝ＣＨ−ＣＨ＝ＣＨ−Ｈフエ請　ｏ　ｃｔ　ｃｔ　ｃｔ表　２３２．４−Ｃ１２７！＝ル　ＯＣｔ　ＨＨ２，４−Ｃ４ｚ　フェニル　ＯＣ１ＣＨ３Ｈ２、４−ＣＩ２　フェニル　ｏ　ｃｔ　ｃｔ　Ｈ３，５−ＣＬ２　フェニル　ＯＦ　Ｆ　Ｈ４〜Ｃｔ　フェニル　ｓ　ｃｔ　ｃｔ　Ｈ３，４−ＣＬ２　フェニル　ＯＢｒ　Ｂｒ　Ｈ３，５−Ｃ２２フェニル　ｏ　ｃｔ　ｃｔ　ｃｔ２．４ −Ｃ１２フェニル　ｏ　ｃｔ　ｃｔ　ｃｔＨ１−ナフチル　ＯＣＬ　ＣＩ　ＣＩ４−ｃａＨｓｏ−フェニル　ｓ　ｃｔ　ｃｔ　ｃｔＨフェニル　ｏ　ｃｔ　ｃｔ　ｃｔ表　２４代表的窒素含有複素環化合物Ｙ’４＠　Ａ’６　Ｘ’１６　Ｙ’４９　Ｙ’５０　Ｙ’Ｕ３　＝　５−Ｃ４７：１−二ｋ　ＯＣＩ　ＣＩ　Ｃ１４−Ｎｏ□　７！二／ｌｚ　ＯＣ１ＣＬ　ＣＩ２．４−ＣＩ２　フｘ、＝ｘ　ｏ　ｃｔ　ｃｔ　ｃｔ４−Ｎｏ□　フェニル　ＯＦ　Ｆ　Ｆ４−ＮＯ２フェニル　ＯＢｒ　Ｂｒ　Ｂｒ３−Ｃ６Ｈ５０−７：Ｘ−ニル　Ｓ　Ｃ１ＣＬ　Ｃ１−Ｈフェニ／Ｌ／　ＣＨ２Ｃ１ＣＩ　ＣＨ３表　２５代表的窒素含有複素環化合物Ｙ’５２　Ａ’７　Ｘ’１７　ｙ’ｓ３　Ｙ’Ｓ４　ｙ’５ｓ４（ＣＨ３ＣＨ（ＣＯ２ＣＨ２ＣＨ３）−）　７：ｒ−ニル　ＯＣｌ　ＨＣＩＨフｘニル　−ＣＨ２ＣＨ２−ＣＬ　ＣＬ　ＣＬＨ７！−ＪＬｌｏ　Ｃ７Ｃ２Ｃｔ表　２６Ｙ’ｓｓ　Ａ’８　Ｘ’１８　Ｙ’Ｓ７　Ｙ’ｇ　Ｙ’Ｋｓ３−ＣＬ　フェニル　ＯＣＬ　ＨＨ２，４−Ｃ１ｚ　フェニル　ＯＣＬ　ＨＨ３，４−ＣＬｚ　フェニル　ＯＣ１Ｃ１Ｈ４−ＣＬ　フェニル　ｓ　ｃｔ　ｃｔ　ｃｔ３．４−（ＣＨ３）２　フェニル　□　ｐ　Ｆ　ＦＨ１−ナフチル　ＯＢｒ　Ｂｒ　Ｂｒ２．４−Ｃ４ｚ　フェニル　ｏ　ｃｔ　ｃｔ　Ｈ表　２７代表的窒素含有複素環化合物ｙ／、　４　Ｘτ９　ｙ’ｓｏ　ｙ’ｓｉ　ｙＩ６□２．４−Ｃ１２フェニル　ｏ　ｃｔ　Ｈｃｔ４−Ｃ４−Ｃ６Ｈ４０−フェニル　ＯＨｃｔ　ｃｔ２−ｃａ３ −４−ｃｔ　フェニル　Ｓ　Ｃ１ＨＣ１表　２８代表的窒素含有複素環化合物Ａ’ｌＯ−Ｘ’２ＯＡ’ｌｌ　Ｙ’６３　Ｙ’６４表　２８（続き）代表的窒素含有複素環化合物Ａ’１Ｏ−Ｘ’２０　Ａ’ｌｌ　Ｙ’ａ３Ｙ’６４表　２８（続き）代表的窒素含有複素環化合物Ａ’ＩＯ”Ｘ’２ＯＡ’ｕ　Ｙ’６３　Ｙ’６４表　２８（続き）表　２８（続き）代表的窒素含有複素環化合物Ａ’ｔｏｅ′２ｏ　Ａ’ｌｌ　Ｙ’６３　Ｙ’６４夷　９只　ｒ誹央）代表的窒素含有複素環化合物代表的窒素含有複素環化合物表　２８（続き）表　２９（続き）表　２９Ａ’ｔｚ−ｘ’ｔ　ｙ’ａｓ　ｙ’ａｓ　Ｒ’１６　ｒ’６−（２’、４’−Ｃ／４Ｃ６Ｈ３０−）　２−ＣＬ　４−Ｃ１３，５−Ｈ２０５−（４’−ＣＺＣ６）１４−０−）　２−ＣＬ　４−ＣＬ　３−Ｈ−６−ＣｌＯ２−Ｃ６Ｈ５０−２ −Ｃ１６−Ｃ１３、５−Ｈ２Ｏ２（４’−Ｃ６Ｈ５０−Ｃ６Ｈ４０−）　２−Ｆ　４−Ｆ　３．５−Ｈ２０６−（２’、４’（０２Ｎ）ｚｃａＨ３ＮＨ−：ｌ　２−Ｆ　、４−、Ｆ　３−Ｈ−５−ＣＨ３０４−（４’−Ｃ１ｃｓＨ４Ｓ−）　２−Ｆ　６−Ｆ　３　、５−Ｈ２０５−Ｃ６Ｈ５ＣＨ２−２−Ｃ１４−Ｃ１３，６−Ｈ２０４−（１−す７トオキシ）　２−Ｆ　６−Ｃ１３，５−Ｈ２０４（２ ’、６’−ＣＱ−４’−ピリジ詠−５−）２−ｃｔ　６−ｃｚ　３．５−Ｈ２０６−（４’−Ｃ６Ｈ，０−Ｃ６Ｈ４ＣＨ２−）　２−Ｆ　３−Ｆ　４．５−Ｈ２Ｏ２−（２’、　４’−Ｃ４Ｃ６Ｈ３０−）　２−Ｃ１３−ＣＬ　４−Ｈ１４− （４’−Ｃ６Ｈ５０−Ｃ６Ｈ４０−）　２−Ｆ　６−Ｆ　３，５−Ｉ（２１６（３’１４’１５′−Ｂｒ３Ｃ６Ｈ２Ｍ（−）　２−Ｆ　５−Ｆ　３　、４−Ｈ２１６−Ｃ６Ｈ５−０−２−ＣＬ　−３−Ｎ）２−４．５−Ｈ２０４−（３’、　ｓ’−ｃｚ４Ｃ６Ｈ３Ｓ　）　２−Ｆ　３−ＣＮ　５　、６−）！２０４−Ｃ２ ’、　４’−Ｃ／４Ｃ６Ｈ３０−）　２−Ｃ６−ｆｙｃｃ１３−３．５−Ｈ２０５−（３’−Ｃ６Ｈ５Ｏ−Ｃ６Ｈ４０−）　２−ｃｔ　６−ｃｔ　３−ｃｃｔ３ −４−Ｈ。代表的窒素含有複素環化合物表　３１Ｈフェニル　ｏ　ｃｔ　ＣＬ２．４−Ｃｔｚ　フェニルｏ　ｃｚ　Ｃｔ３．５−Ｃ１２フェニル０ｃＬｃｔ４−Ｂｒ　７ＺニルＯＣ１Ｃ１３−ＮＯ２フェニルｓ　ｃｔ　Ｃｔ２−ＣＮ　７：ｒ：、二ｋ　ＯＣ１ＣＬ４−（４’−ｃｚｃ６Ｈ４ｏ　）　フェニル　ｏ　ｃｔ　Ｃｔ４−ＣＬ　フェニル　ＮＨＦ　Ｆ５−ｃｚ）Ｉ、　２−ピリジル　ＮＨｃｔ　ｃｔＨ１−ナフチル　ｏ　Ｃｔ　Ｃｔ４−Ｃ１フェニｋ　ＣＨ２ｃｔＣｔ２．４−Ｃ１２フェニル　一重結合　ｃｔＣｔＨフェニル−（三Ｃ−ｅｔ　ｃｔ特特開昭６３５０２５１１　（１２６）代表的窒素含有複素環化合物２　、４−　ＣＺｚ　フェニルｏ　ｃｔ　Ｃｔ３．５−Ｃ４ｚ　フェニル　ｏ　ｃｔ　Ｃｔ４−Ｎｏ２　フェニル　ｏ　ｃｔ　ｃｔ４！−ＣＮ　フェニル　ｏ　ｃｔ　Ｃｔ３．５−Ｃ６２フェニル゛　Ｓ　ｃｔ　Ｃｔ４−Ｃ２１−ナフチル　ｏ　ｃｔ　Ｃｔ３−Ｃ６Ｈ５０７！ニルＮＨＣ１ＣＬＨフェニル　ｏ　ｃｔ　Ｃｔ２．４−Ｃ１２フェニル　ＮＨｃｔ　Ｃｔ４−（４’−ＣｔＣ６Ｈ４０）　フェニル　ｏ　ｃｔ　Ｃｔ４−ＣＬ　フェニル　ＣＨ２Ｃ１Ｃ１表　３２（続き）２．４−Ｃ／、２　フェニル　一重結合　ｃｔ　ｃｔＨフェニル　−ＣＥ−Ｃｔ　Ｃ１表　３３Ｈフェニルｏ　ｃｔ　Ｃｔ２．４−Ｃ１２フェニル　□　Ｃ４Ｃ１３，５−ＣＬ２　フェニル　ｏ　ｃｔ　Ｃｔ４−　ＮＯ２フェニル　ｏ　ｃｔ　Ｃｔ４−ＣＮ　フェニル　ｏ　ＣＬ　ＣＬ３．５−Ｃ１２フェニル　ｓ　ｃｔ　Ｃｔ４−ｃｔ　１−す７Ｆ＃　ＯＣ１ＣＬ３−Ｃ６ＨｓＯ−フェニル　ＮＨｃｔ　Ｃｔ２．４−Ｃ１ｚ　フェニル　ＮＨＣ１Ｃ１表　３３（続き）４（４′−Ｃ４Ｃ，Ｈ４０）　フェニル０Ｃ４ｃｔ４−Ｃ１フェニル　ＣＨ２Ｃｌ　Ｃ１２，４−Ｃ７２フェニル　一重結合　ｃｔ　ｃｔＨフェニル　−ｃ＝ｃ−ｃｔ　ｃｔ表　３４３．５−Ｃ１２フェニル　ｏ　ｃｔ　ｃｔ２．４−Ｃ２２フェニル　ＮＨｃｔ　ｃｔ２．４−ＣＬ２　フェニル　ｏ　ｃｔ　ｃｔ３−Ｃ６Ｈ６Ｏフェニル　Ｎｕ　ｃｔ　ｃｔ２．６−Ｃ１２フェニル　−Ｇμ史−　ｃｔ　ｃｔ３．５−Ｃ１２フェニル　ｓ　ｃｔ　ｃｔ２−ＮＯ２フェニル　ｍ　ｃｔ　ｃｔ２．３−（ＣＨ２）４　フェニル　ｏ　ｃｔ　ｃｔ３．５−ｃｔ２　フェニル　Ｓ　Ｂｒ　Ｂｒ２−ｃｚ−２，３−（ＣＨ２）、　−フｘ＝ルｏ　ｃｔ　ｃｔ４ −（４’〜Ｃ５Ｈｓ　Ｏ−Ｃｓ　Ｈ４）〜　フェニル　ｏ　ｃｔ　ｃｔ表　３４（続き）Ｈ１−ナフチル　０　０Ｓ０２ＣＨ３０ＳＯ２ＣＨ３２，４−Ｃ１ｚ　フェニル　Ｏ０ＣＨ２ＣＦ３　００（２ＣＦ３表　３４（続き）２．４−ｆ：１２　フェニル　ＯＣＬ　ＯＣＨ３’４−ＣＬ　フェニル　ＯＣＬ　ＣＮ２．４．５−ＣＬ３　フェニル　ＯＣＬ　５０２ＣＨ３４−ＣＦ３　７−１−　ニルＯ０ＣＨ２ＣＦ３　ＣＣＨ２ＣＦ３３−ＣＮ　フェニル　Ｏ０ＣＨ２ＣＦ３　ＣＬ３−ｃ６Ｈ５ｏ　フェニル　Ｑ　ＣＨ３Ｓ−ＣＬ３１４１５−（ＣＨ３）３−　フェニル　ｏ　ｃ　ｃｔ３ｃｔ３、．５．Ｃ４２フェニル　ＯＣＨ３０− ｃｔ３．５−Ｃ１２フェニル　ｏ　ｃｔ　ＣＨ３０−２，４−ＣＬ２　フェニル　Ｓ　Ｆ　（ＣＨ，）２Ｎ−４−ｃａＩ（ｓｏ−フェニル　ＯＮｏ２Ｃ１４−ＣＨ３Ｓ−フェニル　ｏ　ｃｔ　ｃｔ２　＋　４−　Ｆ２　フェニル　ｏ　ｃｔ　ｃｔ表　３５表３５（続き）ＣＪ　ＣＪ　Ｎ　ＨＣノ　Ｃ１表３５（続き）Ｃｔ　ＣＪ　−ＮＨ−ＮＨ−−−Ｃｔ　ＣノＣｊ　ＣＪ　−Ｎ＝Ｎ−、−ＣＪ　ＣノＣノ　ＣＪ　−Ｓ−−−ＣＪ　ＣｔＣノ　ＣＪ　−５ｏ２　−−　ＣＪ　ＣノＣｊ　Ｃｊ！　−重結合　−一　ＣＪ　ＣノＣノ　Ｃｔ　−８−８−−−ＣＪ　ＣノＣノ　ＣＪ　−〇−−−Ｃｊ！　ＣノＣｊ　ＣＪ　−Ｃ＝Ｃ−−−ＣＪ　ＣノＣｔ　ＣＪ　−Ｃ−ＮＨ− 表３５（続き）Ｙ’、、２　Ｙ’、、　Ｘ２．　Ｆｔ′１．　Ｙ’、４　Ｙへ。Ｃｔ　ＣＪ　Ｎ　ＣＨ３ＣＯ−Ｃｔ　Ｃノ表３５（続き）Ｃｔ　ＣＪ　Ｎ　ｎ−Ｃ４Ｈｅ−Ｃｊ！　ＣノＣ！　ＣＪ　Ｎ　ＣＨ，＝ＣＨＣＨ，−ＣＪ　ＣノＣｔ　Ｃｐ　Ｎ　ＣＨ３０７ＣＯ−Ｃ，ｇ　ＣｐＣノ　ＣＪ　Ｎ　ＣＨｚＳＯ２−Ｃｊ！　ＣノＣ！　Ｃ１Ｎ　ＣＦ、Ｓ０２−　ＣＪ　ＣノＣｔ　ＣＪ　Ｐ　ＣＪ　Ｃｐ　ＣノＣノ　Ｃｔ　Ｐ　ＱＣ２Ｈ，ＣＪ　ＣノＣＪ　ＣＪ　Ｐ＝ＯＣｊ！　Ｃｊ！　Ｃ／１表３５（続き）表３５（続き）ＣＪ　Ｃｔ　Ｐ＝ＯＣＨ３０−ＣＪ　ＣＪ表３５（続き）代表的窒素含有複素環化合物表３５（続き）代表的窒素含有複素環化合物表３５（続き）表　３６Ｈｎ　−Ｃ７Ｈ１５０−ＨＨＯＨｎ　−ＣｅＨｓ９−　ＨＨ０表３６（続き）表３６（続き）表３６（続き）表３６（続き）表３６（続き）表３６（続き）ＨＣＨ，ＣＨ，（ＣＨ，’）ｓｃＨ２−ＣＪ　Ｃ４０表　・３７代表的窒素含有複素環化合物Ｈフェニル　ＯＣ！４−ＣＬ　フェニル　ＯＣＡ２　＋　４−Ｃ１２フェニル０ｃｔ３−ＣＮ　７：ｒ−二ｋ　ＯＣ／ｌ。２．４−（ＣＨ３）２　フェニル□　ｃｔ２−ＣＨ３−４−ＣＬ　７　エニｋ　ＯＣ１４−Ｃ６）１５０−　７−１−ニル０　、Ｃ／。３−Ｃ，ＨｓＣＨ２０−フェニル　０ｃｔ３．５−ＣＬ２　フェニル　ＯＣＡ２．４．５−Ｂｒ３　フェニル　Ｓ　Ｃｌ２．４−Ｃ１２７！ニルＳ　Ｃ／＝３−（４−ｃｚ−ｃ６Ｈ４）　−７ｘ　二ｐｖ　ｓ　ｃｔ４−Ｃ１フェニル　ＮＨＣ１４−ＣＬ　フェニル　ＮＨＦ３１４１５（ＣＨ３）３　フェニル　ＮＨＦ３−Ｃ６Ｈ５Ｏ−フェニル　ＮＨＦ３−Ｎｏ２　フェニル　ＯＦ３　ｒ　４−　ＣＡ２７　：”　二／ｌ／　ＣＨ２ＣＬ表　３７（続き）代表的窒素含有複素環化合物Ｈフェニル　一重結合　ｃｔ４（Ｃ６Ｈ５０）−フェニル　、−重結合　Ｆ４−ＣＦ３　フェニル　−Ｃ０ＮＨ−ｃｔ３−Ｃ１フェニル　−ｃ＝’ｅ−ｃｔＨ’１−ナフチル　ＯＣＬ４−Ｃ１・　１−ナフチル　ＯＣＬ５．６．７．８−Ｈ４１−ナフチル　ＯＦ６−ＣＨ３３−ピリジニル　０Ｆ３−Ｃ１’４−ピリジニル　ＯＣ６５−ＣＬ　２−チェニル　Ｏ，ＣｔＨ２−す７チル　ｏ　ｃｔ２．４−Ｃ１２７Ｌ二ｋ　−ＣＨ２０−Ｃ１表　３８Ｈフェニル　ＯＣｔＨフェニル　Ｓ　ＣＬ４−ＣＬ　フェニルＱ　（：：Ｃ３，５−Ｃ１２フェニル　ｓ　ｃｔ４−Ｃ，Ｈ３Ｏ−７！　二／Ｌ、　ＯＣ４２＋４−Ｂｒ２’　７　：ｒ−二／Ｌｚ　Ｓ　Ｃ４４−ＣＨ３フェニルＯＦ３−（４−ｃｚ−ｃ６ａ４ｏ）　７！ニルＯＣ１３−Ｃ６Ｈ５０−７：ｒ−、ニルｈＦ（ＣＬ３−Ｃ６Ｈ５０−フェニル　Ｎ［（Ｆ２．４−Ｃ１２フェニルＣＨ２ｃｔ２　＋　４　＋　５−　、Ｃ４３フェニル　一重結合ｃｔ４−ＣＨ３０−フェニル　一重結合　Ｃ３，５−（ＣＨ３０）２　フェニｋ　ＯＣｌ２−Ｂｒ　−４− Ｃ１フェニル　ＯＢｒ３−Ｃ１−４−ＣＨ，ＣＨ２Ｏ７にｋ　−ＣＨ２ＣＨ２− Ｃｌ３−ＣＨ５ＣＨ２０−４−ＣＨ３フｘ二ｈ　−ＣＯＮＨ−ＣＬＨ１−ナフチル　ＯＣＬ表　３８（続き）代表的窒素含有複素環化合物Ｈ２−ナフチ化　、ＯＣ４５−ＣＨ３ＣＨ２３−ピリジちル　→伍−Ｆ４−Ｂｒ　２−チェちル　ｏ　′ｃｔ４−ＣＨ３２−チアゾリル　一重−ＦＨフェニル　−ｃ＝ｃ−ｃｔ２．４−Ｃ１２７！二／Ｌｚ　−ＣＨ２０−ＣＬＨフェニル−ＣＨ２０−Ｃ１５，６，７，８−Ｈ４１−ナフチ／Ｌ’　Ｏｃｔ３＋４＋５−ｃｚ３　フェニル　ＣＨ２Ｂｒ表　３９代表的窒素含有複素環化合物Ｒ’ｌｌｌ　Ａ’１８　Ｘ’２９Ｙ’９０Ｈフェニル　０ｃｔ２．４−Ｃ１２フェニル　ＯＣｌ２．６−Ｃ１，フェニルｏＣ４３−Ｃ，Ｈ，Ｏ−フェニル　ＯＣＬ４−Ｃ６Ｈ５ＣＨ，−フェニル　ＯＣＬ３．４−（ＣＨ３）２　フェニル　ｓ　ｃｔ：Ｌ５−Ｃｌ２　フエニ／Ｌ／Ｓ　ｃｔ４−（４−ｃｚｃｓａ４ｏ）−フェニル　Ｓ　Ｃｌ２．４−（ＣＨ３０）ｚ　フェニル　ｏ　ｃｔ３．４−ＯＣＨ２０−フェニル　ＯＣｌ２．３−ＯＣＨ２０−フェニル　ＮＨＦ４−Ｃ１フェニル　Ｍ（Ｆ３−ＮＯ！　フェニル　０Ｆ２−Ｎｏ２　フェニル　ＯＣＬ３−ＣＨ３ＣＨ２−フェニル　ＯＣｔＨフェニル　ＣＨ２Ｃ１Ｈフェニル　一重結合　ｃｔ：３＋５−Ｂｒ２　フェニル　一重結合　ｃｔ表　３９（続き）代表的窒素含有複素環化合物Ｒ’１８　Ａ’１８　Ｘ’２９　Ｙ’３０２−ＣＨ３−４−Ｃ１７エニ／ｌ＜　ＣＨ２０Ｃｌ３−ＣＬ　フェニル　ＣＨ２Ｂｒ゛４−Ｃ１フェニル　ＣＨ２ＯＢｒＨ１−ナフチル　ＯＣＺＨ２−ナフチル　ＯＣＬ４−Ｃ１１−ナフチル　ＯＣＬ４−ＣＨ３２−ピリジニル　ＯＣｔＨ３−ピリジニル　０Ｆ５−Ｃ１２−チェ請　ＯＣＬ第５−ＣＨ３３−イシ隊すゾリル　ＮＨＦＨフェニル　−ｃ＝ｃ−ｃｔ２．５−Ｃ１２フェニル　Ｑ　Ｂｒ表　４０代表的窒素含有複素環化合物ｕ／、、　Ｘ’ＸＩ　ｚ／ＩＺ’２　Ｙ’９１　Ｙ’９２（ＣＨ３）　、ＣＨ３Ｈ２ＣＨ２−−重結合　０　０　ＣＬ　ＣｌＣＨ２”ＣＨＣＨ２−−を給０　０　ＣＩ　ＣＩＨＣ：＝ＣＣＨｚ　−−Ｎ結合　ｏ　ｏ　ｃｔ　ｃｔＨＯ−’ＭＪ給ｏ　ｏ　ｃｔ　ｃｔ表　４０（続き）Ｒ’１９　、　Ｘ’３０　ｚ′ｌｚ／２Ｙ’９１　Ｙ’９２（ＨＯＣＨ２）３Ｃ −−影給ｏ　Ｏｃｔ（？ｔＣＨ３０ＣＨ２ＣＨ２−−ｆｉ　ＯＯＣ１Ｃｌ５−ブロモ−２−チアゾリル　−１結合　ｏ　ｏ　ｃｔ　ｃｔ表　４０　（続き）代表的窒素含有複素環化合物Ｒ’１９　Ｘ’３０　ｚ／□ｚ′２ｙ’、！Ｙ’９２２−ピリ：）ニル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ５−ブロモ−２−ピリジニル　一重結合　ｏ　ｏ　ＣＩ　Ｃ１６’−メチル−４−ヒ’ｊ’Ｅ”二／’　−重結合０　０　ＣＩ　ＣＩ２ −ベンズイミダゾリル　−１徘吉合　ｏ　ｏ　ｃｔ　ｃｔ２−（２−インドリル）エチル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ２−チェ二ルカーボオキサミド　一重結合ｏ　ｏ　ｃｔ　ｃｔ表　４０（続き）代表的窒素含有複素環化合物Ｒ’１９　Ｘ’ＸＩ　ｚ／ｌｚ／２ｙ’ｓｔ　Ｙ’９２２−ペンズオキナゾリル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ２−ベンゾチアゾリル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ３−ビリジ訪メチル　−１エ吉合　０　０　ｃｔ　ＣＩ２−ピリジニルメチル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ４−ピリジニルメチル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ３−７エ、二Ｊレー２−ブロー！−Ａ／　−１顛昭＠　ＯＯＣＬ　Ｃ１表　４０　（続き）代表的窒素含有複素環化合物Ｒ’１９　Ｘ’３０　ｚ′ｌｚ／２Ｙ’９１　Ｙ’９２フェニルエチニル　一重結合　ｏ　ｏ　ｃｔ　ｃｔ４−トリルη祢？　−重結合　ｏ　ｏ　ｃｔ　ｃｔ３ −フェニルブロム　一重結合　ｏ　ｏ　ｃｔ　ｃｔフェニル　一重結合　０ＯＦＦ表　４０（続き）代表的窒素含有複素環化合物２−フエ請エチル　一重結合　０　０　Ｂｒ　Ｈベンゼンスルホニル　一重結合ｏ　ＯＣＨ３ｃｔベンジル　一重結合　０　０　Ｃ１ＢｒＣ２Ｈ，−重結合　０　０　、Ｆ　ｃｔシクロヘキシル　一重結合　００Ｆ　ｃｔシクロヘキシル　一重結合　００ＦＨ表　４０（続き）代表的窒素含有複素環化合物Ｒ’、９　ｘ’３ｏ　ｚ′１ｚ′２ｙ’ｓｔ　Ｙ’９２ｎ−Ｃ３Ｈ７−重結合　０　０　Ｂｒ　Ｈ４−メチル−２〜チアゾリル　−ＮＨ−００Ｃ４（：ｔ４−クロロ−２−ベンゾチアゾリル　−ＮＨ−００ｃｔ　ｃｔ表　４０（続き）代表的窒素含有複素環化合物Ｒ’１９　、ｘ′３ｏＺＳ　Ｚ１２Ｙ’９１　Ｙ’９２３−メチル−５−イソす γシリ＃　−ＮＨ−００ｃｚ　ｃｔ５−ブロモ−３−イソ子アゾリル　−ＮＨ− ００ｃｔ　ｃｔ３．５−７メチルー２ゼリミジニシ　−ＮＨ−００ｃｔ　ｃｔ表　４０（続き）代表的窒素含有複素環化合物Ｒ’１９　Ｘ’ＸＩ　Ｚ’ｔ　Ｚ’ｚ　Ｙ’ｓｌＹ′９ｚ２−チェニル　−ＣＨ２−００ｃｔ　ｃｔ２−メトキシフエちル　−ＮＨ−Ｓ　Ｓ　Ｃ１Ｈ表　４０（続き）Ｒ’１９　Ｘ’３Ｄ　Ｚ’ｔ　Ｚ’ｚ　Ｙｓｘ　Ｙ’９２３．４−ジクロロフエちル　−ＮＨ−Ｓ　Ｓ　ｃｔ　ｃｔ７ｚ＝ルーＣＨ２−Ｓ　Ｓ　ＣｔＣ１４−り０（：ｌフェニル　−ＣＨ２−Ｓ　Ｓ　ＣＺ　ＣＨ３３−メチル−４−クロロフエちル　一１凛断ｆ；　ＳＳＢ、　）ｌフェニル　−ＣＨ２−００Ｂｒ　ＣＬ２−フリル　−ＣＨ２−ＣＭ３Ｎ　ＯＣＬ　Ｃ１表　４０　（続き）代表的窒素含有複素環化合物Ｒ’１９　Ｘ’３゜　ｚ′ｌｚ′２Ｙ’９１　Ｙ’９□３−クロロフェニル　− Ｎ（ＣＨ３）−００ｃｔ　Ｈ表　４１Ｒ’２０　Ｘ’３１　Ｚ’（ｙ、　Ｙ’９４　ｙ’ｓｓ２．４−ジクロロフエちル　一重結合　ｓ　ｃｔ　ｃｔ　ｃｔ２．４−ジクロロフェニル　一重結合　ＣＨ２ｃｔ　ｃｔ　ｃｔフェニル　一重結合　ＣＨ２Ｆ　Ｆ　Ｆ２．４−ジクロロフエ、ちル　一重結合　ＮＨＨＨＢｒ４−クロロフェニル　一重結合　ＮＨｃｔ　ｃｔ　ｃｔ表　４１（続き）代表的窒素含有複素環化合物ｎ／、　Ｘ／３、Ｚ’３　Ｙ′９３Ｙ６４　Ｙ′９ｓ２．４−ジクロロフェニル　一重結合　、　ＮＨｃｔ　ｃｔ　ｃｔフェニル　−ｃｕ２ｃＨ２−ｏ　ｃｔ　ｃｔ　ｃｔフｘ二ｙ　−ＣＨ２−Ｓ　ｃｔ　ｃｔ　ｃｚ。 −ｙｘ二ｚ　−ＣＨ（ＣＨ３）−０ｃｔ　ｃｔ　ｃｔフｘ二ｋ　−ＣＨ２−ＯＣＬ　Ｃ４Ｃｌフェニル　−ＣＨ＝ＣＨ−Ｏｃｔ　ｃｔ　ｃｔ表　４１（続き）代表的窒素含有複素環化合物Ｒ＆　Ｘ’３１　Ｚ’ｓ　Ｙ’＊ｓ　Ｙ’！）４　Ｙ’９５フェニル　−ｃ＝：ｃ−，ｏ　ｃｔ　ｃｔ　ｃｔフェニル　−ＳＯ℃）−ｏ　ｃＬ　ＣＬ　ＣＡフ： ”二ｋ　−５Ｏ２−ＯＣＡ　ＣＬ　ＣＡ２−クロロフェニル　−ＣＨ２−ＮＨｃｔ　ｃｔ　ｃｔｌ−ナフチルメチル　一重結合　ｏ　ｃｔ　ｃｔ　ｃｔ表　４１（続き）代表的窒素含有複素環化合物Ｒ’２０　ｘ’ａｔ　ｚ′ＩＹ６３Ｙ’９４　Ｙ気フェニル　一重結合　ＯＨＣ１Ｃｔシクロヘキシル　一重結合　ｏ　ｃｔ　ｃｔ　ｃｔｎ−ブチル　一重結合　ｏ　ｃｔ　ｃｔ　ｃｔ４−フェノキシフェニル　一重結合　ｏ　ｃｔ　ｃｔ　ｃｔ表　４１（続き）代表的窒素含有複素環化合物Ｒ’２０　Ｘ’３１　ｚ′３Ｙ’９３　Ｙ’９４　ｙ’ｔｓ３−フェノキシフエちル　−６合　ｏ　ｃｔ　ｃｔ　ｃｔでシクロヘキシル　−ｍ合ＯＨＨＢｒシクロヘキシル　一重結合　０ＦＦＦフエニル　−ＣＨｚ　−ＯＨＨＢｒＨ−重結合　Ｑ　Ｂｒ　Ｂｒ　０８Ｏ２ＣＨ３Ｈ−重結合　ＯＨＨ０８Ｏ２ＣＨ３表　４１（続き）Ｒ’２０　Ｘ’３１　Ｚ’３　Ｙ’ｅｓ　Ｙ’ｓ＜　Ｙ’ｅｓＨ−重結合　ＯＣＨ３Ｈ０ＳＯ２ＣＨ３フエニル　一重結合　ＯＢ　ｒ　Ｂｒ　０８Ｏ２ＣＨ３フｘ　二／ｌ／　−重結合　Ｑ　ＨＣＣＨ３０ＳＯ２ＣＨ３フエニル　一重結合　ＯＨＣＣＣＣＨ３０ＳＯ２ＣＨ３シクロヘキシル　一重結合　ｏ　ｃｔ　ｃｔ　ｏｓｏ□ＣＨ３フェニル　一重結合　ＯＣＬ　Ｃ１ＣＮ表　４１（続き）代表的窒素含有複素環化合物Ｒ’２０　Ｘ’３１　２′ＩＹ’９３　Ｙ’９４　ｙ’ｅｓＨ−重結合　ｏ　ｃｔ　ｃｔ　０Ｐ（＝ＳＸＣＣ２Ｈ，）。フェニル　一重結合　ｏ　ｃｔ　ｃｔ　５ＣＨ３２，４−ジクロロフエ？　−重結合　ｏ　ｃｔ　ｃｔ　ｃＦ’３フェニル　一重結合　ｏ　ｃｔｃｔ　ＣＣ２Ｈ３（ＣＣＣＣＨ２）２ＮＣＨ２−−重結合　ｏ　ｃｔ　ｃｔ　ｃｔ表　４１（続き）Ｒ’２０　Ｘ’３１　ｚ／３Ｙ’９３　Ｙ’９４　Ｙ’９５４−七一トリ＝Ｊレメチプレ　−１腓吉合　ｏ　ｃｔ　ｃｔ　ｃｔ４−アミノフエちル　一重結合　ｏ　ｃｔ　ｃｔ　ｃｔ４−ニトロフェニル　一重結合　ｏ　ｃｔ　ｃｔ　ｃｔ表　４１（続き）Ｒ’２０　、Ｘ′ｌｌＺ’ｌ　Ｙ’９３　Ｙ’９４　Ｙ’９Ｓフェニル　一重結合　０　、ＣＬ　ＣＬ　Ｂｒ７　ｘ　二、ＴＩ／　−重結合　Ｏ５ＣＨ２ＣＱＮＨＮＨＣＳＮＨ２ＨＣ１ＣＨ３−重結合　ＯＦ　ＦＦ表４１（続き）３−クロロ−２−ピリジニル　ＣＨ，ＯＣｔ　ＣＪ　０２−ベンゾチアゾリル　一重結合　ＯＣｔ　Ｃｔ　Ｃｔ５−クロロ−２−チェニル　ＣＨ（Ｑ（３）−０（Ｊ　Ｃ）　ＣＪ２−フリル　ＣＨ２ＯＣｊ！　Ｃｊ！　６１表　４２２−メトキシフｘ　ニル　−ＮＨ−ＣＪ　ＨＨＣ１３−トリフルオロメチルフェニル　−ＣＨ，−ＣＪ　ＨＣｔ　Ｈ２，４−ジクｏロフェニｈ　−ＣＨ２−Ｂｒ　ＨＨＨ７ｘ　ニル−ＣＨ（ＣＨ，）−Ｂｒ　Ｂｒ　ＨＨ３−フルオロフェニル　一重結合Ｂｒ　Ｂｒ　ＨＨシクロヘキシル　一重結合　ＣＪ　Ｈ（Ｊ　Ｈ表４２（続き）フェニル　−Ｃ０ＮＨ−Ｂｒ　ＨＢｒ　Ｈシクロヘキシル　−ＣＨ，−Ｂｒ　ＨＢｒ　Ｈｎ−プロピル−ＣＨ，−Ｂｒ　ＨＢｒ　Ｈ２−りｏｏ７ｚニル　−ＮＨ −ＨＨＢｒ　Ｂｒフェニル　−ＣＨ，−ＨＨＣｔ　Ｃノフェニル　−ＣＨ２−ＨＢｒ　Ｂｒ　Ｈ２−メトキシフェニル　−ＣＨ２−ＨＢｒ　Ｂｒ　Ｈ表４２（続き）ＲＳ１Ｘ′３□　Ｙ’、、Ｙ％、Ｙｔ８Ｙ％。３−メトキシフェニル　−ＣＨ２−Ｃ７ＩＣＪ　ＨＨ３−フルオロフェニル　− ＣＨ２−Ｃｉ　Ｃｔ　ＨＨ。３−ブロモフェニル　−ＣＨ，−ＣＪ　ＨＨＨ２−ｒ−ト＊シフＺ二ｋ　−ＮＨ −ＣＪ　（Ｊ　ＨＨｎ−プロピル−ＣＨ，−ＣＪ　ＨＣＪ　Ｈ２−フリル　−ＣＨ２−Ｂｒ　ＨＢｒ　Ｈ表４２（続き）２−ノルボルニル　一重結合　ｃｚ　ＨＢｒ　Ｈ３−ヒリシニル−Ｎ（ＣＨ３） −Ｆ　ＨＨＣｉ３．５−ジクロロフェニル　−ＣＩ（２ＣＨ２−Ｃ１ＣＪ！　Ｃ）　０１表　４３ＨＣＨ，ＣＨ，ＨＣＨ，ＣＨ，ＣＨ２Ｃ２Ｈｓｎ　−（：、Ｈ，ＣＨ，ＣＨ。ベンジル、　ＣＨ，Ｃ）Ｉ、　Ｈ３−クロロベンジル　ＣＨ，Ｃ０ＣＨ。フェニル　ＨＨ４−りｏ　ｏ　７ｚニルｎ　−Ｃ，Ｈ，ＣＨ３フェノキシ　ＣＨ３ＣＮ、　Ｈフェノキシ　ＣＨ３ＣＮ、　ＣＯＣ，Ｈ。１−ナフチル　ＣＨ，ＣＨ。表４３（続き）２．４−ジクロロフェノキシ　（：）（、ＯＣＲ。３−ピリジュルメチル　ＣＨ，ＣＨ，ｃｏ、Ｃ２）（。４−クロロチェニルオキシ　ＯＨＨ表１〜４３にリストした特定の化合物は、本発明に従って植物からの発散による水分損失を減らし且つ作物の収率を増大させるべく使用される窒素含有複素環（式）化合物の一例であると理解されたい。本発明はこれら化合物の使用のみに限定される１ｆＬると解釈されるべきではなく、むしろ本発明は上記式１に瞥耐ｖ素含有複素環化合物全てを含む。本発明の新規な窒素含有複素環化合物は下記する幾つかの式％式％Ｒ２４は置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ１ｏｃ、ｔｏ、Ｓ、Ｓｏ、ＳＯ２，ＮＨ，−ＣＨ２０−。 −ＣＨＳ−、−ＣＨ（ＯＨ３）Ｏ−、−ＣＨ（ＣＮ）Ｏ−。 −ＣＨ−Ｎｏ−、−Ｃ（ＣＨ３）　−Ｎｏ−。 −ＣＨ２ＣＨ２０−、−０Ｈ２ｃ、ｔ−＋２−、−Ｃミｃ−。 −ＣＨ２Ｓｏ−、−ＣＨ２ＳＯ２＋、−ｏｃｔ−＋２０Ｈ２０−。 ’−ＣＨ（アルキル）−ヌは一〇〇ＮＨ−であり、ｊは０又は１の値であり、ａは２〜４の値であり、Ｘ１９は同一でも異なっていてもよくハロゲン、アルキル、シアノ、ボリハロア ′ルキル、アルコキシ、ポリハロアルコキシ。アルキルチオ、アルキルスルフィニル、アルキルスルホニル。ニドＯ，アシル又はポリハロアルキルスルホニルである。但し、（１）２と４．２と６，２と３及び３と４から選択された少な（とも２個の環位置対（ｒｉｎｇ　ｐｏｓｉｔｉｏｎ　ｐａｉｒｓ）は同一または異なるハロゲンで置換されている：（ｉｉ）原位置２．４・及び６が塩素で置換されており、ｊが００値であり且つＸ　がＳＯのときには、Ｒ２４は未置換フ讐ニルでない；（ｉｉｉ）原位置２．３及び５が塩素で置換されており、ｊが１の値であり且つＸ１０がＳのときには、Ｒ２４は未置換フェニルでない：Ｒ２５はＨ＆若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ１１はｏ、Ｓ、Ｓｏ、８０２．ＮＨ，ＣＨ２，−ｉｆ共有結合。 −ＣＨ２０−、−ＣＨ２Ｓ−、７：Ｃ１−１（ＣＩ−１３）ｏ−。 −ＯＨ（ＣＮ）０−、−ＣＨ−Ｎｏ−。 −Ｃ（ＯＨ３）−Ｎｏ−、−０Ｈ２ｃ！−１２０−。 −ＣＨ２ＣＨ２−ニーｃ＝ｃ−，−ａＨ２ｓｏ−。 −ＣＨ２Ｓｏ。−、−０ＣＨ２Ｇ）−１２０−。 −Ｃ）ｌ　（アルキル）−又は−〇０Ｎ）−１−であり、ｂは２〜３の値であり、Ｘ２０は同一でも異なっていてもよくハロゲン、アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリハロアルコキシ。アルキルチオ、アルキルスルフィニル、アルキルスルホニル。ニトロ、アシル又はポリハロアルキルスルホニルである。但し、Ｘ２０の２から選択された少なくとも２個の環位置対は！１０ゲンである。上記式中、Ｒ２６は置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ　はＯ，Ｓ、Ｓｏ、Ｓｏ２．ＮＨ，ＣＨ２，−重共有結合。 −ＣＨ（ＯＮ）Ｏ−、−ＣＨ−Ｎｏ−。 −Ｃ（ＯＨ３’）−Ｎｏ−、−ＣＨ，、ＣＨ２０−。 −ＣＨ２ＣＨ２−、−Ｃ＝Ｃ−、−ＣＨ２Ｓｏ−。 −ＣＨ２Ｓ０２−、−０ＣＩ−１２０８２０−。Ｙ２３は水素、ハロゲン、アルキル、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、シアノ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニドＯ，アシル又はポリハロアルキルスルホニルである。上記式中、Ｒ２７は置換若しくは未ＨＩＴｈのフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ１３はｏ、Ｓ、Ｓｏ、Ｓｏ２．ＮＨ，ｃ＋２．−１共１結合。 −ＣＨＯ−、−ＣＨＳ−、τＣＨ（ＣＨ３’ＩＯ−。 −ＣＨ（ＣＮ）Ｏ−、−Ｃ）ｌ−Ｎｏ−。 −Ｃ（ＣＨ３）−Ｎｏ−、−ＣＨ２ＣＨ２０−。 −ＣＨ２ＣＨ２−、−Ｃ＝Ｃ−、−ＣＨ２Ｓｏ−。 −ＣＨＳｏ　二、−ＯＣＨＣＨ２０−。 −ＣＨ（アルキル）−又は−〇〇ＮＨ−であり、Ｙ２４はハロゲンであり１、Ｙ２５及びＹ２６は夫々水素、ハロゲン、アルキル、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、シアノ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ。アシル又はポリハロアルキルスルホニルである。但し、Ｙ　及びＹ２６の少なくとも一方はハロゲンであり、Ｙ２４”　２５及びＹ２６が塩素であり且つＸ１３がＯのときにはＲ２７は未置換フェニルでない上記式中、Ｒ２８は置換若しくは未置換のフェニル、１−又は２−ナフチル又は、ヘテロアリールであり、Ｘ、４はｏ、Ｓ、Ｓｏ、Ｓｏ２．ＮＨ，ＣＨ２，−重共有結合。 −ＣＨＯ−、−ＣＨ，２Ｓ−、−ＣＨ（ＣＨ３）０−。 −ＣＨ（ＣＮ）Ｏ−、−ＣＨ−Ｎｏ−。 −Ｃ（ＣＨ）−Ｎｏ−、−ＣＨ２ＣＨ２０−。 −ＣＨ２ＣＨ２＋、−Ｃ＝Ｃ−、−ＣＨ２Ｓｏ−。、−ＣＨ２８０２−、−０ＣＩ−１２０Ｈ２０−。 −ＣＨ（アルキル）−又は−〇〇ＮＨ−であり、Ｙ　及びＹ２８は夫々ハロゲンであり、Ｙ２９は水素、ハロゲン、アルキル、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、シアノ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アシル又はポリハロアルキルスルホニルである。Ｒ２９は置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ１５は０．ｓ、ｓｏ、ｓｏ２．ＮＨ，ＯＨ２，−重共有結合。 −Ｃ（ＣＨ３）−Ｎｏ−、−ＣＨ２Ｃ）−１２０−。 −〇８２０Ｈ２−，−Ｃ讐Ｃ−、−ＣＨ，２Ｓｏ−。 −ＣＨ２ＣＨ２＋、−０ＣＨ２ＣＨ２０−。 −ＣＨ（アルキル）−又は−〇〇ＮＨ−であり、Ｙ３゜、Ｙ３１及びＹ３２は夫々水素、ハロゲン、アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アシル又はポリハロアルキルスルホニルである。但し、Ｙ２Ｏ”　３１及びＹ３２の少なくとも２個はハロゲンである。上記式中、Ｒ２Ｏは置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、 ×１６はＯ，Ｓ、Ｓｏ、Ｓｏ２．ＮＨ，ＣＨ２，−重共有結合。 −ＣＨ２０−、−ＣＨ２Ｓ−、−ＣＨ（ＣＨ３）０−。 −ＣＨ（ＯＮ）Ｏ−、−ＣＨ−Ｎｏ−。 −Ｃ（ＣＨ＞　’＝ＮＯ−、−ＣＨ）ＣＨ２０−１一０Ｈ２ＣＨ２−、−ＣミＣ −、−ＣＨ２Ｓｏ−。 −０Ｈ２Ｓ０２−、−０ＣＩ−１２０Ｈ２０−。 −ＣＨ（アルキル）−又は−〇〇ＮＨ−であり、ＹＢ２．ＹＢ２及びＹＢ２は夫々水素、ハロゲン、アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アシル又はポリハロアルキルスルホニルである。但し、（ｉ）　ＹＢ２．　ＹＢ２及びＹＢ２の少なくとも２個はハロゲンである：（ａｔ）ｙ　及びＹＢ２の両方が塩素であり且つ×１６がＯのとぎには、Ｒ２Ｏは未置換フェニルでない；（ｉｉｉ）　Ｙ　及びＹＢ２の両方が塩素であり且つＸ　がＯのときには、Ｒ２Ｏは未置換フェニル又は４−メトキシフェニル、でない：ｄは０〜４の値であり、ｅは１又は２の値であり（但しｄ＋ｅは５より大きくない）、Ｒ３１は同一でも異なっていてもよく、置換若しくは未置換のアリール（但しＲ３１が２−又は４ −アリールのときにはｄはＯでない）、アルアルキル（但しＲ３１がＲ−アルアルキルのときにはｄは０でない）、アルコキシ、シクロアルコキシ、アリールオキシ、アルアルコキシ（但しＲ３１が４−アルアルコキシのときにはｄはＯでない）、アリールアリールオキシ、アルアルコキシアルアルキル、アリールアルアルコキシ、アリールオキシアルアルキル、アリールオキシアルキル、アリールオキシアリールオキシ、アルアルコキシアルアルコキシ、アリールオキジアルコキシ、アルキルチオ、アルケニルチオ、アリールチオ、アルアルキルチオ、アリールチオアルアルキル、アリールスルホニルアリールスルホニル、アルキルアミノ、ジアルキルアミノ、アシルオキシ、アロイルオキシ、アルコキシカルボニルオキシフェニルアゾ（但し×１□は０又はＳである）、ナフチルアゾ又は隣接する炭素原子と結合して５員環又は６員環を形成する一ＯＣＨ　Ｏ−又は−ＯＣＨ２ＣＨ２０−であり、ＹＢ２は同一でも異なっていてもよくハロゲン、アルキル、アルケニル、アルキニル、隣接する炭素原子と結合して６員環を形成する一ＣＨ −ＣＨＣＨ−ＣＨ−、−（ＣＨ　）　、ニトロ。シアノ、ハロアルキル又はポリハロアルキルであり、×１７はＯ，Ｓ，ＮＨ，Ｃ）（２．−ＣＨ２　０−、−ＣＨ２。Ｓ−又は−〇ＣＨ２０Ｈ２０−であり、Ｙ３７はハロゲンであり、ＹＢ２はハロゲン、アルコキシ、アルキルチオ、アルキルスルホニル、ポリハロアルコキシ、ポリハロアルキル、シアノ、ニトロ、置換若しくは未買換アリールチオ、アリールオキシ又はアリールスルホニルである。ｆは０〜５の値であり、Ｒ３２は同一でも異なっていてもよくハロゲン、アルキル、アルケニル、アルキニル、ポリハロアルキル、シアノ、ニトロ。アルキルアミノ、ジアルキルア二）、アルコキシ、ポリハロアルコキシ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アシル。ＣＯ２　（アルキル＞、ＣＯＮＨ（アルキル）、ＣＯＮ（アルキル）　、’ＳＯ　Ｎ（アルキル）　、アルキルカルボニルオキシ。アルコキシカルボニルオキシ、置換若しくは未置換のアリールオキシ、アリールチオ、アリールスルホニル又はアロイルであり、Ｘ　はＯ．Ｓ，ＣＨ２，−重共有結合又は−Ｃ編Ｃ−であり、ＹＢ２はハロゲン、ポリハロアルコキシ、ポリハロアルキル。シアノ、アルキルスルホニル、アルキルスルホニルオキシ、ポリハロアルキルスルホニル又はポリハロアルキルスルホニルオキシであり、Ｙ２Ｏはハロアルキル、ポリハロアルキル、アルコキシ（但し×１８はＳでも一重共有結合でもない）、ポリハロアルコキシ。い）、アルキルスルホニル、ニトロ、シアル゛コキシホスフィニル又はトリアルキルアンモニウムである。上記式中、Ｙ４１は同一でも異なっていてもよくハロゲンであり、Ｙ４２は同一でも異なっていてもよくハロゲン、アルコキシ。アルキルチオ又はポリハロアルコキシであり、Ｘ１ｇハｏ、　シチ’Ａ−，−Ｐ　（−０）　（０−７）Ｌｔキル）−２、−Ｐ（アルキル）−、−Ｐ（０−アルキル）−、スルフィニル。スルホニル、チオスルフィニル、−重共有結合、カルボニル。アミノカルボニルアミノ、アミノオキサリルアミノ、アミノカルボニルアルキレンカルボニルアミノノ、置換若しくは未置換のオキシアリールオキシ（但し１．３−アリーレンビス（オキシ）は少なくとも１個の置換基で置換されている）、オキシアリールアルキルアリールオキシ、第４シアルオキシ又はオキシアリールアリールオキシである。ｓ３上記式中、Ｙ５２及びＹ５３は夫々ハロゲンであり、ハロアルキル、シアノ、ニトロ、アミノ、アルキルア°ミノ、ジアルキルアミノ、アルコキシ、ポリハロアルコキシ、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ポリハロ、アルキルスルホニル、アルコキシカルボニル、アルキルアミノカルボニル、アミノカルボニル、ジアルキルアミノカルボニル。ジアルキルアミノスルホニル、アルキルアミノスルホニル、アミノスルホニル、アルキルカルボニル、ジアルコキシアルキル。アルキルカルボニルオキシ、アルキルカルボニルアルキルアミノ、隣接プる炭素原子と結合して６員環を形成する一ＣＨ−ＣＨＣＨ−ＣＨ−、置換もしくは未置換のアリール。アルアルキル、アリールオキシ、アリールチオ、アリールスルホニル又はアルアルコキシであり、ｘ２ｏは一ＣＨ（アルキル）　Ｏ−、　−〇　（アルキル）２０−。 −ＯＣＨ２＋，−ＣＨ２０−、　−〇Ｈ２＋。 −Ｃ　（ハｃｌ’ン）２　、−ＯＣＨ２　０−、−ＯＣＨ２　ＣＨ２　０−。又は−Ｃ−Ｃ−　＜但しＱは少なくとも１の値である）；−ＯＣＩ−１　（アルキル）　−、　−ＱＣ　＜アルキル）２。 −、ＯＣＨ　（フルキＡ，）Ｏ−、−ＱＣ　（７）Ｉｉキル）　２０−。 −ＯＣＨ　（アルキル）ＣＨ２０−。ｌ−ＯＣＩ−１　（アルキル）ＣＨ（アルキル）Ｏ−。 ’−ＣＨ　（アルキル）ＣＨ（アルキル）−。 −ＣＨ　（アルキル）−、−Ｃ（アルキル）２−。 −ＣＨ２ＣＨ２０−、−ＯＣＨ２ＣＨ２＋。 −ＣＨ　（アルキル）ＣＨ２０−、−ＣＨ２ＣＨ２−。 −ＣＨ　（ＣＮ）Ｏ−、−Ｃ　（フルーｔ／Ｌ，）（ＣＮ）Ｏ−。 −ＣＨ　（ポリハロアルキル）Ｏ−、−Ｃ　（ＣＮ）−Ｎｏ−。 −Ｃ（ＮＨアシキル）−Ｎｏ−。一Ｃ［Ｎ（アルキル）２］−Ｎｏ−。 −Ｃ（Ｓ’−アルキル）−Ｎｏ−。 −Ｃ　（０−フルーｔル）　”Ｎｏ−、　−ＳＣ　（−０）　Ｏ　。 −ＮＨＣ　（−０）Ｏ−、−Ｎ　（７／ｌ，キ／Ｌ，）Ｃ　（−０）Ｏ−。 −ＣＨ　（フルキル）Ｓ　（０７’，＋，ーｓ　（０）　ｈＣＨ２＋。 −ＱＣ　（−Ｓ）、Ｓ−、−Ｃ　（−０）Ｓ−。 −Ｃ　（−Ｓ）　−Ｓ−、−ＮＨ’（７Ａ４＝／ｌ，）Ｃ　（−０）Ｓ−。 −ＳＯ３Ｍ　（アルキル）−、−ＣＯＮＨ−。 −ＳＣ　（−０）ＮＨ−、−ＮＨＳ０２ＮＨ−。 −Ｎ（アルキル）ＳＯ２Ｍ゛（アルキル）−。 −Ｎ　（７Ｊｔｔ＊ル）ＳＯ２ＮＨ−。 −ＮＨＳ０２Ｎ　（７Ａ，ｌ）−、−Ｃ　（０−フルーｔ−Ａ，）−Ｎ−。 −Ｃ（Ｓ−アルキル）”Ｎ　、−ＣＨ　ＣＡｏゲン）−。 −Ｃ（アルキル）（ハロゲン’）−、−ＣＨ　（ＣＮ）＋。 −Ｃ（アルキル）（ＣＮ）−、−ＮＨ　（アルキル）ＮＨ−。 −ＮＨ−Ｎ　（アルキル）−；−ＮＨ−ＮＨ−又は−Ｎ−Ｎ−（但しＲ３３はニトロではない）ニーＣ　（−０）　−、　−Ｃ．（−０）　Ｃ　（−０）　−。 −ＣＨ（０−７／Ｌ、キ／ｌ、）−、−ＣＨ２０（−０）−。 −Ｃ（−０）ＣＨ２，−ＣＩ−１（７／ｌ、ｔ／Ｌ、）Ｃ（＝Ｏ）−。 −Ｃ（＝Ｏ）　ＣＨ（アルキル）、−ＣＨ−ＣＨ−。 −Ｃ（アルキル）−ＣＨ−、−ＣＨ−Ｃ（アルキル）−１−Ｃ（アルキル）−Ｃ（アルキル）−２−Ｃ（−０）ＣＨ−ＣＨ−。 −Ｐ（Ｙ　）（Ｙ４じアルキル）−１置換若しくは未置換の−Ｐ　（Ｙ　）　（Ｙ４ジアリール）又はアリーレン（ａｒｙｌｅｎｅ）　、　−３ｉ　（ハロゲン）２−９−８ｉ（アルキル）２−２ −ＱＣ（−０）　Ｎ　（アルキル）−１−ＯＣＨ２０（−０）Ｎ　（アルキル） −２１−Ｎ（アルキル）ＣＯＮ（アルキル）−１−ＱＣ（−０）ＮＨ−、−ＮＨＣＯＮＨ−。 −８ｏ２ＮＨＣ（−０）ＮＨ−又は−ＮＨＣ（−８）ＮＨ（但しＱは少なくとも１の値である）；ｈは０〜２の値であり、Ｒ３４はアシル、アルキ“ルスルホニル。ポリハロアルキル、ポリハロアシル、ポリハロアルキルスルボニル又は置換若しくは未置換のアロイル又はアリールスルボニルであり、Ｙ４３及びＹ４４は夫々０又はＳである。、Ｒ３５はイソオキサゾール、イソチアゾール、ピラゾール、イミダゾール、　１，２．４−トリアゾール、　１，２．４−オキサジアゾール。１．３．４−オキサジアゾール、　１，２．４−チアジアゾール、　１，３．４ −チアジアゾール、オキサゾール、チアゾール、ベンゾピラゾール。ベンズイミダゾール、ベンズオキサゾール、ベンゾチアゾール。インドール、ピロール、フラン、チオフェン、ベンゾフラン。１ベンゾチオフエン、ピリジシ、ピリミジン、ピリダジン、　１，３゜５−トリアジン、　１，２．４−）−リアジン、キノリン、イソキノリン。キナゾリン、フタラジン、ベンゾピリダジン、ベンゾピラジン。カルバゾール、ジベンゾフラン、ジベンゾチオフェン、ベンゾキサジン、フタルイミド、ベンゾピラン、ジベンゾピリジン。ピリドピリジン、ピラゾロピリミジン、テトラヒドロピリミジンジオン、クマリン、ピペリジン、モルホリン、テトラヒドロフラン、テトラヒドロチオフェン、ビロリヅン、チオモルホリン、ピペリジン−２−オン、ピペリジン−２，６−ジオン、２．５−ピロリジンジオン、３−モルホリン、２−オキソヘキサメチレンイミン。２−オキソテトラメチ、レンイミン、１−ピラゾリン、２−ピラゾリン。ピラゾリジン、２−イミダゾリジノン、２−イミダゾリジンチオン。２．４−イミダゾリジンジオン、１．２−オキサチオラン、１，３−オキサジノン、２１１−ピラン−２−オン、　４日−ピラン−４−オン、　２Ｈ−とラン− ２−チオン、　４Ｈ−ピラン−４−チオン、テトラヒドロピラン。テトラヒトＯチオビラン、７−オキサビシクロ［２，２，月へブタン。１−アザビシクロ［２，２，１］ヘプタン、オキセタン、クマリン、１゜３−ジオキサン、１．４−ジオキサン及び１，３−ジオキソランから選択された置換若しくは未置換の複素環式環系であり、Ｘ２１はｏ、ｓ又はＮＨであり（但し、Ｘ２１がＮＨのときにはＲ３５はピリジンでなく、且つＸ２１がＳのときにはＲ３５は未置換ベンゾチアゾールでない）、Ｙ４５及びＹ２Ｏは夫々ハロゲンである。又は上記式中、Ｒ３７及びＲ３８は夫々ハロゲン、ニトロ、シアノ、ポリハロアルキル、ポリハロアルコキシ、１アルキルスルボニル、ポリハロアルキルスルホニル、アシル、 °アルコキシカルボニル、ポリハロアルキルスルホニル又はＲ３９−Ｘ２２−であり（但しＲ３７及びＲ３９は置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ２２はｏ、ｓ、ｓｏ、ｓｏ　、ＣＨ、−１共有結合。 −ＣＨ，、Ｏ−、−ＣＨ２Ｓ−、−ＣＨ（ＣＨ３”）Ｏ−。 −ＣＨ（ＯＮ）Ｏ−、−ＣＨ−Ｎｏ−。 −Ｃ（ＣＩ−１３＞　−Ｎｏ−、−〇８２ＣＨ２ｏ−’。 −ＣＨ２ＣＨ２−、−Ｃ＝Ｃ−。 −ＣＨ２Ｓｏ−、、−ＣＨ３ＳＯ４，−、−０ＣＨ２Ｃ）−１２０−。キル、アルキルスルホニル、アルケニル、アルキニル、アルコキシカルボニル；置換若しくは未置換のアリール、アルアルキル、アリールオキシ、アリールアミノ、アロイル又はアリールスルホニルである）。但し、（ｉ）　Ｂ　がＲ−Ｎ＜、Ｒ３９−アルキル−Ｎ＜。Ｒ３９−Ｃ（−０）Ｎ＜、Ｒ−３ｏ　Ｎ＜、Ｒ３ｇ−０−Ｎ＜又はＲ３ｇ　ＮＨ −Ｎ＜のとぎには、Ｒ及びＲ３８の両方がＲ３９”−Ｘ２２−以外である；（ｉｔ）３　がＲＮ　＜　、　Ｒ３９−アルキル−Ｎ＜。又はＲ３ｇ　ＮＨＮ＜以外のときには、Ｒ３７及びＲ３８の一方がＲ３９−Ｘ２２−である：（ｉｉｉ）式（ｘｉｉｉ）においてＲ及びＹ　の両方が塩素であり且つＸ２２が一重共有結合のときには、Ｒ３９は未置換フェニルでない：又はＲ及びＲは夫々ハロゲン又はＲ４３’２３−であり（但しＲ４３は置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ２３ｃ、ｔｏ、Ｓ、Ｓｏ、Ｓｏ２．ＣＨ２，−重共有結合。 −ＣＨ２０−、−ＣＨ２Ｓ−、−ＣＨ（ＣＨ３’）Ｏ−。 −ＣＨ（ＣＮ）Ｏ−、、−ＣＨ−Ｎｏ−。 −Ｃ（ＣＨ３）−Ｎｏ−、−ＣＨ２，ＣＨ２０−。 −ＣＨ２ＣＨ２−、−Ｃ＝Ｃ−。 −ＣＨ２Ｓｏ−、−ＣＨ２Ｓｏ、−、−０ＣＨ２ＣＨ２０−。 −ＣＨ（アルキル）−又は−〇〇ＮＨ−であり、Ｂ１５はＯ，Ｓ、ＮＨ又はＮＲ４４である（ここで、Ｒ４４はアルキル、アルキルスルホニル、ポリハロアルキルスルボニル、アルケニル、アルキニル、アルコキシカルボニル：置換若しくは未置換のアリール、アルアルキル、アリールオキシ、アリールアミノ、アロイル又はアリールスルホニルである）。但し、Ｂ１５がＲ４３−Ｎ〈、Ｒ４３−アルキル−Ｎ＜。Ｒ４３−Ｃ（−０）Ｎ＜、Ｒ４３−８０２Ｎ＜、Ｒ４３−０−Ｎ＜”１５がＲ４３−Ｎ＜、Ｒ４３−アルキル−Ｎ＜。Ｒ４３−Ｃ（−０）Ｎ＜、Ｒ４３−８ｏ２Ｎ＜、Ｒ４３−０−Ｎ＜又はＲ４３− ＮＨ−Ｎ＜のときには”４１及びＲ４２の一方がＲ４３−Ｘ２３−である。又は４Ｊ上記式中、Ｒ４５，Ｒ４６，Ｒ４□及びＲ４８は夫々水素、ハロゲ乙ニトロ。シアノ、ポリハロアルキル、ポリハロアルコキシ、アルキルスルホニル、ポリハロアルキルスルホニル、アシル、アルキルチオ、アルキル、アルコキシ、アルキルスルフィニル又はＲ４９−Ｘ　２じであり（但しＲ４５−Ｒ４６，Ｒ４□及びＲ４８の一個はＲ４９Ｘ２４　ｒｔｏ’）且ツＲ４５，Ｒ４６，Ｒ４□及Ｔｆ　Ｒ４ｇ　ハ必ず２個以下の水素、アルキル又はアルコキシを含む）、Ｒ４９は置換若しくは未置換のフェニル、１−又は２−ナフチル又はヘテロアリールであり、Ｘ２４ｔ；ｔｏ、Ｓ、Ｓｏ、Ｓｏ□、ＣＨ２，−重共有結合。 −ＣＨ２０−、−ＣＨ２Ｓ−、−引−（（ＣＨ３）Ｏ−。 −ＣＨ（ＯＮ）Ｏ−、−ＣＨ−Ｎｏ−。 −Ｃ（Ｃ）（３）−Ｎｏ−、−ＣＨ２ＣＨ２０−。 −ＣＨＣＨ２−、−Ｃ荘Ｃ−。 −Ｃ）−１２Ｓｏ−、−ＣＨ２８０２−、−０ＣＨ２ＣＨ，Ｏ−。！−ＣＨｃアルキル）−又は−〇〇ＮＨ−であり、Ｙ４８はハロゲンであり、８１６はｏ、ｓ又はＮＨである。上記式中、は未置換の炭素環式（ｃａｒｂｏｃｙｃｌｉｃ）又は複素環式環系であり、これらは飽和でも不飽和でもよく、Ｂ１７は一〇Ｈ−Ｎ−、−Ｎ−ＣＨ−、−ＣＨ＝ＣＨ−。 −Ｃｏ−、−３ｏ２−、−ＣＨ２Ｃｏ−、−ＣＯＣＨ２−。 −ＣＯＮＨ−、−ＮＨＣＯ−、−３ｏ２ＮＨ−。 −ＮＨ３Ｏ２−、−５ｏ２Ｎ　（アルキル）−１−Ｎ（アルキル”）Ｃｏ２＋、 −ｏｓｏ２−、−０３−、−Ｎ＜。 −ＮＨ−、−Ｎ　（アルキル）−、−ＯＣＨ、−３ＣＨ２゜−ＮＨＣＨ２，−Ｎ　（７Ａ、−Ｊル）ＣＨ２、−８ＣＯ−。 −０ＣＨ２−、−０ＣＯ−、−ＣＨ，、−、−ＣＨ２０Ｈ２−又は−３ＣＨＣｏ −であり（但しＢ１７が−ｃｏ−であり且っＹ５４及びＹ５５は夫々ハロゲンである。Ｒ５１は単環式芳香族若しくは非芳香族環系、二環式芳香族若しくは非芳香族環系、多環式芳香族若しくは非芳香族環系及び架橋環系から選択゛された置換又は未置換の炭素環式又は複素環式環系であり、これらは飽和でも不飽和でもよく、Ｂ１８は＝ＣＨ−Ｎ−、−Ｎ−ＣＨ−、−ＣＨ−ＣＨ−。 −Ｃｏ−、−３ｏ２−、−ＣＨ２Ｃｏ−、−ＣＯＣＨ２−。 −ＣＯＮＨ−、−ＮＨＣＯ−、−８○２ＮＨ−。 −ＮＨ８Ｏ２＋、−ｓｏ、、Ｎ　＜フルキル）−１−Ｎ　＜フルキル）Ｃｏ２− 、−０３Ｏ２−、−Ｃ８−、−Ｎ＜。 −ＮＨＣＨ２，−Ｎ　（アルキル＞　ｃｉ−＋２．−５ｃｏ−。 −ＯＣＨ−、−０ＣＯ−、−ＣＨ−、−ＣＨＣＨ２−又は−３ＣＨ，、Ｃｏ−であり、Ｂ　は−ＣＨ２−又は−ＣＨ（アルキル）−であり、１は０又は１の値であり、上記式中、Ｂ　は−ＣＨ２Ｃ（ＣＨ３）２ＳＣＨ２−１＝ＣＨＣＨ−Ｃ（ＣＨ３）０ＣＨ２ −。＝ＣＨ２ＣＨ２ＳＣＨ２ＣＨ（ＣＨ３）＋。 −ＣＨＯＨＳＣＨＣＨ−、−ＣＨ２５ＣＨ２ＣＯ−。 −ＣＯＣＨ２Ｃ（Ｃ＋５）２ＣＨ２Ｃ〇−２−ＣＨＣＨ２ＣＨ（Ｃ６Ｈ５）ＯＨ２Ｃｏ−。 −ＣＯＮＨ（ＣＨ）ＣＨＣＨ２０−。 −ＣＯＣ（ＣＨ３）２ＮＨＣＯ−。 −ＣＨ２ＣＨ２Ｎ（０６Ｈ５）ＣＨ２ＣＨ２−１−ＣＨ２Ｎ　（Ｃ６Ｈ５）　ＣＨ２ＣＨ２−。 −ＣＨ２ＣＥ（２Ｃト１　（Ｃ６Ｈ５）　ＣＨ２ｃ　Ｈ２−。 −Ｃｏ　（’ＣＨ２）　３Ｃｏ−、−Ｃｏ　（ＯＨ２）　２Ｃｏ−。 −ＣＯＣ（ＣＨ３）２Ｃ（ＣＨ３）２Ｃｏ−′。 −Ｇｏ　（ＣＨ２）　４Ｇｏ−、−Ｇｏ　（ＣＨ２）　５Ｇｏ−。 −Ｇｏ　（、、ＣＩ（、）５ＣＨ２＋、−ｃｏ　（ＣＨ２）　４ＣＨ，、＋。 −ＣＯ（ＣＨ２）　３ＣＨ２＋、−ｃｏ　（ＣＨ２）２　ＣＨ２−。 −〇〇〇、Ｈ２ＳＣＨ，，Ｇｏ−。 −ＣＯＣ８２Ｎ　（Ｒ５２）ＣＨ２Ｃｏ−。 −ＣＯＣＨ２０ＣＨ，Ｃｏ−、−ＣＯＣＨ２ＳＣ８−。 −ＣＯＣＨ−ＣＨ−Ｎ＝ＣＨ−。＝ＣＨ２ＣＨ（Ｃ６＋５）ＣＨ２−Ｎ−ＣＨ−１；を−Ｃ０２−ＣＨ２ＣＨ２− であり、Ｒ５２は水素、アルケニル又は置換若しくは未置換のアリール又はアルカアリールであり、Ｙ５８及びＹ５９は夫々ハロゲンである。ＹＩＩ上記式中、Ｒ５３は置換若しくは未置換のシクロアルケニル、シクロアルカジェニル、シクロアル力トリエニル、ごシクロアルキル、ピシクＯアルカジェニル、トリシクロアルキルニル、トリシクロアルケニル又はトリシクロアルカジェニルであり、許容され得る置換基は同一でも異なっていてもよく１個又はそれ以上のアルキル、ハロゲン、ハロアルキル、ポリハロアルキル、アルコキシ、アルキルチオ、アルキルスルホニル。ポリハロアルコ゛キシ、ニトロ、シアノ、アシル、アロイル、アリール、アルコキシカルボニル、アルコキシカルボニルオキシ。オキソアシルオキシ；畝・は隣接の炭素原子と結合して５員環又は６員環を形成する一〇　Ｈ　＝　Ｃ　Ｈ　Ｃ　Ｈ　−　Ｃ　Ｉ−１−又は−ＣＨ−ＣＨＣＨ，２−であり、Ｙ　及びＹ６１は夫々ハロゲンであり、Ｘ　は０，Ｓ．ＮＨ．ＣＩ−１２，−ＣＨ２０−又は−重共有結合である。上記式中、Ｒ５４は同一でも異なっていてもよく１個又はイれ以上の水素。ハロゲン、アルキル、アリール、アルアルキル、アルケニル。アルキニル、ポリハロアルキル、ＮＨ２．ＮＨ（アルキル）。Ｎ（アルキル）２，アルコキシ、ポリハロアルコキシ、アルキルチオ、アルキルスルフィニル、アルキルスルボニル、アルアルコキシ、ＣＯ２アルキル、ＣＯＮＨ　（アルキル）。ＣＯＮＨ　、ＣＯＮ　（７ＭＬ，−１＝ル）　、Ｓｏ２Ｎ　（フル＊／Ｌ，）２。ＳＯ２ＮＨ（アルキル）、＄０２ＮＨ２．アシル。ｃｏ　ｃｏ−アルキル）２　、アシルオキシ。アシル−ＣＯＮ　（アルキル）或いは隣接の炭素原子と結合して、置換若しくは未置換の６員環を形成する２、３−（−ＣＨ−ＣＨＣＨ−ＣＨ−）。３、４−（−ＣＨ−ＣＨＣＨ−ＣＨ−）、２．３−（ＣＩ−１２）　４−又は３．４−（ＣＨ２）　４であり、Ｘ　は○．Ｓ，Ｓｏ，Ｓｏ２，ＣＨ２，ー重共有結合。一ＣＨ　２　０−、　−ＣＨ　２　Ｓ−、　−ＣＨ　（ＣＨ　３　’）　Ｏ−。 −ｃＨ　（ＣＮ）Ｏ−、−ＣＨ−Ｎ，Ｏ−。 −Ｃ　（ＣＨ３）−Ｎｏ−、−ＣＨ２ＣＨ２０−。 −ＣＨ２ＣＨ，−、−Ｃ−Ｃ−、−ＣＨ２Ｓｏ−。 −ＯＣＨ　ＣＨ　−１は一ＯＣＨ２−ｒあり、Ｙ　及びＹ５１は同一でも異なっていてもよくハロゲンである。上記式中、Ｒ６８は置換若しくは未置換のフェニル又は１−又は２−ナフチルであり、 ×２７は一〇Ｈ（アルキル）０−、−Ｃ（アルキル＞２０−。 −ＯＣＨ２−、−Ｃ　（ハロゲン）２．−ＯＣＨ２　０−。 −ＯＣＨ　ＣＨ　Ｏ−、−ＣＨ２０−、−Ｃ＝Ｃ−。一ＯＣＨ　（７Ａ，キル）−、−ＱＣ（アルキル）２。 −ＯＣＨ　（アルキル）Ｏ−、−ＱＣ　（アルキル）２０−。 −ＯＣＨ　（フルキＪ）ＣＨ２０−。 −ＯＣＨ　（フルキル）ＣＨ　（フル＋ル）Ｏ−。 −ＣＨ（アルキル）ＣＨ（アルキル）−。 −ＣＨ（アルキル）−、−Ｃ（アルキル）２−。 −ＣＨ　２　０Ｈ　２　０　−　、−ＱＣ８　２　Ｇ）（　２　−。 −ＣＨ　Ｃ７）Ｉｉキル”）ＣＨ２　０−、　ＣＨ２　ＣＨ２　＋。 −ＣＨ（ＣＮ）Ｏ−、　−〇　（７／ｌ，キ／Ｌ，）（ｑＮ）Ｏ−。 −ＣＨ　（ボｕハｏ７Ａｔ＊ＩＩｔ）Ｏ＋，−ｃ　（ＣＮ）−Ｎｏ−。 −Ｃ（ＮＨアシルル）−Ｎｏ−。一．Ｃ［Ｎ＜アルキル）２コーＮｏ−。 −Ｃ　（Ｓ−アルキル）−Ｎｏ−。 −Ｃ　（０−７Ａ４ル）−Ｎｏ−、　−ＳＣ　（−０）Ｏ−。二ＮＨＣ　（−０）Ｏ−、−Ｎ　（フルキ／Ｌ，）　Ｃ　（−０）　Ｏ−。Ｓｏ，Ｓｏ２，−ＣＨ２Ｓ　（０）ｈ−。ＣＨ　（フルーｔル）Ｓ　（０）ｈ　＋，　Ｓ　（０）　ｈＣＨ２　＋。 −ＱＣ　（−Ｓ）Ｓ−、−Ｃ　（−０）Ｓ−。 −Ｃ　（−Ｓ）　−Ｓ−、　−ＮＨ　（７／Ｌ，−１＝Ａ，）　Ｃ　（−０）　Ｓ−。 −Ｏ　（Ｃ−０）Ｓ−、−Ｎ　（アルキル）　＋，　−Ｎ　（Ｒ３４）　−。 −ＳＯ２ＮＨ−、−Ｓｏ２Ｎ　（７／ｌ，キル）＋，ーＣＯＮＨ−。 −ＣＯＮ　（７／１４／Ｌ，）−、−ＳＣ　（−０）Ｎ　（７／Ｌ，キル）−。 −３Ｃ（＝Ｏ’）’　ＮＨ−、−ＮＨ８Ｏ２ＮＨ−。 −Ｎ（アルキル）Ｓ０２Ｎ（アルキル）−１−Ｎ（アルキル’）ｓｏ２ＮＨ−。 −ＮＩ−ＩＳＯ２Ｎ（アルキル）−、−〇（０−アルキル）　−Ｎ　−。 −ＮＨ−Ｎ　（アルキル）−ニーＮＨ−ＮＨ−，−Ｎ＝’Ｎ−−Ｃ（−０）　− 、−Ｃ（＝Ｏ）　Ｃ（−０）　−。 −、ＣＨ（０−アルキル）−、−ＣＨ２０（＝Ｏ）−。 −Ｃ（−０）ＣＨ２，−ＣＨ（アルキル’）　Ｃ（−０）　−。 −Ｃ（−０）　ＣＨ（アルキル）、’−ＣＨ−ＣＨ−。 −Ｃ＜アルキル）−ＣＨ−、−ＣＨ−Ｃ（アルキル）−１−Ｃ（アルキル）−Ｃ（アルキル）−２−Ｃ（−０）ＣＨ−ＣＨ−。 −Ｐ（Ｙ　）（Ｙ４４−アルキル）−２置換若しくは未置換の−Ｐ　（Ｙ　）　（Ｙ４ジアリール）又はアリーレン、−８ｉ（ハロゲン）２−、−３ｉ（アルキル）２−１−ＯＣ（−０）　Ｎ　（アルキル）−１−ＯＣＨ２０（＝○）Ｎ（アルキル）−１−Ｎ（アル４ル）ＣＯＮ　（アルキル）−；−ＱＣ（−０）ＮＨ− 、−ＮＨＣＯＮＨ−。 −８ｏ２ＮＨＣ（−０）ＮＨ−、−ＮＨＣ（−３）ＮＨ。ポリハロアルキル、ポリ八ロアシル、ポリハロアルキルスルホニル又は置換若しくは未置換のアロイル又はアリールスルホニルであり、Ｙ４３及びＹ４４は夫々０又はＳである）、Ｚ　及びｚ２は夫々Ｏ，Ｓ、Ｃ１〜Ｃ８デルキリデン、置換若しくは未置換のベンジリデン、ＮＨ又はＮＲ”（ここでＲ″はアルキル、アリール、アルアルキル、アルケニル又は、アルキニルである）であり、Ｙ６７及びＹ６８は同一でも異なっていてもよく水素、ハロゲン。アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリ八０アルコキシ、ハロアルキル、アルキルヂオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アリール、ポリハロアルキルスルホニル、アルキルアミノ、ジアルキルアミノ、アシルアミノ、アシルオキシ、アルキルスルホニルオキシ、アリールスルホニルオキシ、アルケニルスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、ホスホノ又はホスフィノである。上記式中、Ｒ６９は置換若しくは未置換のフェニル又は１−又は２−ナフチルであり、 ×２８はＮＨ，ＣＨ２又は共有結合であり、ｚ３及びＺ４は夫々Ｏ，Ｓ、Ｃ１〜Ｃ８アルキリデン、置換若しくは未置換のベンジリデン、Ｎ）−１又はＮＲ”（ここでＲｒｎはアルキル、アリール、アルアルキル、アルケニル又はアルキニルである）であり、ＹＢ２及びＹ７゜は同一でも異なっていてもよく水素、ハロゲン。アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリハロアルフキシ、ハロアルキル、アルキルチオ、アルキルスルフィニル、アルキルス“ルホニル、ニトロ、アリール、ポリハロアルキルスルホニル、アルキルアミノ、ジアルキルアミノ、アシルルスルホニルオキシ、ポリハロアル１ルスルホニルオキシ、ホＲ７０はイソオキサゾール、イソチアゾール、ピラゾール、イミダゾール、　１，２．４−トリアゾール、　１，２．４−オキサジアゾール。１．３．４−オキサジアゾール、　１，２．４−チアジアゾール、　１，３．４ −チア１ジアゾール、オキサゾール、チアゾール、ベンゾピラゾール。ベンズイミダゾール、ベンズオキサゾール、ベンゾチアゾール。インドール、ビロール、フラン、チオフェン、ベンゾフラン。５．ζ駆Ｑベンゾチオフェン、ピリジン、ピリミジン、ピリダンノ、　１，３゜５−トリアジン、　１，２．４−トリアジン、キノリン、イソキノリン。キナゾリン、フタラジン、ベンゾピリダジン、ベンゾピラジン。カルバゾール、ジベンゾフラン、ジベンゾチオフェン、ベンゾキサジン、フタルイミド、ベンゾビラン、ジベンゾピリジン。ピリドピリジン、ピラゾロピリミジン、テトラヒドロピリミジンジオン、会元母 →＃ピペラジン、モルホリン、テトラヒドロフラン、テトラヒドロチオフェン、ピロリダン、チオモルホリン、ピペリジン−２−オン、ピペリジン−２，６−ジオン、２，５−ピロリジンジオン、３−モルホリン、２−オキソヘキサメチレンイミン。２−オキソテトラメチレンイミン、１−ピラゾリン、２−ピラゾリン。ピラゾリジン、２−イミダゾリジノン、２−イミダゾリジンチオン。２．４−イミダゾリジンジオン、１，２−オキサチオラン、１．３−オキサチオラン、１．３−オキサチアン、１，４−オキサチアン、　２（１Ｈ）−ビラジノン、　２Ｈ−ピラン−２−オン、　４Ｈ−ビラン−４−゛オン、　２Ｈ−ピラン −２−チオン、　４Ｈ−ビラン−４−チオン、テトラヒドロピラン。テトラヒド口ブオビラン、７−オキサビシクロ［２，２，１］へブタン。、７−アザビシクロ［２，２，１］へブタン、オキセタン、クマリン、１゜３− ジオキサン、１，４−ジオキサン及び１，３−ジオキソランから選択された置換若しくは未置換の飽和若しくは不飽和の芳香族又は非芳香族複素環式環系であり、 −ＣＨ（アルキル）Ｓ　（０）　ｈ−、−３（０）　ｈＣＨ２−。Ｘ　は−ＣＨ（アルキル）Ｏ−、−Ｃ（アルキル）２０−。 −ＯＣＨ−、−ＣＨＯ−、−ＣＨ２−、共有結合。 −Ｃ（ハロゲン＞２．−０ＣＨ２０−。 −ＯＣＨ，２ＣＨ２０−、−Ｃ冨Ｃ−。 −ＯＣＨ（アルキル）−、−ＱＣ（アルキル）２゜−ＯＣＨ（アルキル）Ｏ−、 −ＯＣ（アルキル）２０−。 −ＯＣＨ（アルキル）ＣＨ２０−。 −ＯＣＨ（アルキル）ＯＨ（アルキル）Ｏ−１−ＣＨ（アルキル）ＣＨ（アルキル）−１−ＣＨ（アルキル）−、−Ｃ（アルキル）２−１−ＯＨＣＨＯ−、−ＯＣＨＣＨ２−。 −ＣＨ＜フル＊ル＞　ＣＨＯ−、−ＣＨ２ＣＨ２＋。 −ＣＨ（ＣＮ）０−、−Ｃ，（アルキル）（ＯＮ）Ｏ−。 −ＣＨ（ポリハロアルキル）Ｏ−、−Ｃ（ＣＮ）−Ｎｏ−。 −Ｃ（ＮＨアシキル）＝ＮＯ−。 −Ｃ［Ｎ　（アルキル＞２３−Ｎｏ−。 −〇（Ｓ−アルキル）−Ｎｏ−。 −Ｃ（０−アルキル）−Ｎｏ−、−３Ｃ（−０）Ｏ−。 −ＮＨＣ（−０）Ｏ−、−Ｎ　＜フルキル）Ｃ（−０）Ｏ−。Ｓｏ、Ｓｏ２．−ＣＩ−１２３（０）ｈ−。 −Ｃ（アルキル）−Ｃ（アルキル）−２−ＱＣ（−３）Ｓ−、−Ｃ（＝Ｏ）Ｓ− 。 −Ｃ（−０）ＣＨ＝ＣＨ−。Ｒ″′はアルキル、アリール、アルアルキル、アルケニル文はアルキニルである）であり、 ”７１及びＹ７２は同一でも異なっていてもよく水素、ハロゲン。アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、ハロアルキル、アルキルチオ、アルキルスルフィキルスルホニル、アミノ、アルキルアミノ、ジアルキルアミノ。アシルアミノ、アシルオキシ、アルキルスルホニルオキシ、アリールスルホニルオキシ、アルタニルスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルボニルオキシ、アルコキシカルボニルノカルボニル、ジアルキルアミノカルボニル、ジアルキルアミノスルホニル、アルキルアミノスルホニル、アミノスルホニル。ジアルコキシアルキル、アリールスルホニル、ホスホノ又はホスフィノである。上記式中、Ｒ７１’ま置換若しくは未置換のアルキル、アルケニル、アルキニル、シクロアルキル、シクロアルケニル、シクロアルカシェアルケニル、ビシクロアルカジェニル、トリシクロアルキル。６社会占ｗー芸一４トリシクロアルケニル又はトリシクロアルカジェニルであり、一ＯＣ＋−１　＋，ーＣＨ　Ｏ−、−ＣＨ２−、共有結合。一Ｃ（ハロゲン）　、−ＯＣＨ２０−。一ＯＣト１（アルキル −ＯＣＨ　（７／ｌ／キ／ｌ／）ＣＨ２０−。 −ＯＣＨ　（アルキ／ｌ／）ＣＨ　（７／ｌ／−ｔ／ｌ／）Ｏ−。 −ＣＨ　（アルキル）ＣＨ（アルキル）−。 −ＣＨ（アルキル）−、−、Ｃ（アルキル）２−。 −ＣＨ２ＣＨ２０−、−ＯＣＨ２ＣＨ２−。 −ＣＨ　（アルキル’）ＣＨ　Ｏ−、−ＣＨ　ＣＨ２−。一ＣＨ　（ＣＮ）Ｏ−、−Ｃ　（アルキル）（ＯＮ）Ｏ−。 −ＣＨ（ポリハロアルキル）Ｏ−、−Ｃ　（ＣＮ）−Ｎｏ−。 −Ｃ　（ＮＨアルコキシ−Ｎｏ−。 −Ｃ［Ｎ（アルキル）２１−Ｎｏ−。 −Ｃ（Ｓ−アルキル）−ＮＯ−。一Ｃ（０−アルキル）−Ｎｏ−、−ＳＣ　（＝Ｏ）Ｏ−。 −ＮＨＣ　（−０）Ｏ−、−Ｎ　（アルキル）Ｃ　（＝Ｏ）Ｏ−。Ｓｏ．Ｓｏ２．−ＣＨ２Ｓ　（０）、−、　−ＣＨ　（アルキル）Ｓ（０）ｈ− 、−８　（０）　ｈＣＨ２＋。 −ＱＣ　（−Ｓ）Ｓ−、−Ｃ　（−０）Ｓ−。 −Ｃ　（−８）−Ｓ−、−ＮＨ　（アルキル）Ｃ　（−０）Ｓ−。 −、０　（Ｃ−０）Ｓ−、−ＮＨ−、−Ｎ　（アルキル）−。 −Ｎ　（Ｒ３４）＋，ーｓｏ２ＮＨー，ーＳｏ２Ｎ　（アルキル）−。 −ＣＯＮＨ−、−ＣＯＮ　（アルキ１ル）−。 −ＳＣ　（−０）Ｎ　＜フル＊ル）−’，ーＳＣ　（−０）ＮＨ−。 −ＮＨＳＯ２ＮＨ−。一Ｎ（アルキル）Ｓ０２Ｎ（アルキル）−。 −Ｎ（アルキル）ＳＯ２ＮＨ−。一ＮＨＳＯ　Ｎ（アルキル）−、−Ｃ（０−アルキル）＝Ｎ−。一Ｃ　（Ｓ−アルキル）＝Ｎー，ーＣ）Ｉ　（ハロゲン）−。 −Ｃ（アルキル）（ハロゲン）　−、−Ｃ）Ｉ　（ＯＮ）−。 −Ｃ（アルキル）（ＣＮ）−、−ＮＨ　（アルキル）　Ｎ　Ｈ　−　。 −ＮＨ−Ｎ　（アルキル）−　ニーＮＨ−ＮＨ−．−Ｎ−Ｎ−−Ｃ　（＝Ｏ）　 −、−Ｃ　（−０）Ｃ　（−０）−。 −ＣＨ　（０−アルキル）−、−ＣＨ２０　（−０）−。 −Ｃ　（−０）ＣＨ２．−ＣＨ　（アルキル）　Ｃ　（＝Ｏ）　−。 −Ｃ　（−０）　ＣＨ　（アルキル）、−ＣＨ−ＣＨ−。 −Ｃ（アルキル）−ＣＨ−、−ＣＨ−Ｃ　（アルキル）−、−Ｃ（アルキル）− Ｃ（アルキル）−。 −Ｃ　（−０）ＣＨ−ＣＨ−。一Ｐ　（Ｙ４３）　（Ｙ４じアルキル）−。置換若しくは未置換のーＰ（Ｙ　）　（Ｙ４，−アリール）又はアリーレン，− Ｓｉ（ハロゲン）−、−Ｓｉ（アルキル）２−。一ＯＣ　（−０）　Ｎ　（アルキル）−。 −ＯＣＨ２Ｃ　（＝Ｏ）Ｎ　（アルキル）−。 −Ｎ（アルキル）ＣＯＮ（アルキル）−；−ＱＣ　（−０）ＮＨ−、−ＮＨＣＯＮＨ−。 −Ｓｏ２ＮＨＣ　（−０）ＮＨ−、−Ｎ）（Ｃ　（−Ｓ）ＮＨ。ｈは０〜２の値であり、Ｒ３４はアシル、アルキルスルホニル。ポリハロアルキル、ポリハロアシル、ポリハロアルキルスルホニル或いは置換若しくは未置換の７０イル又はアリールスルホニルであり、Ｙ４３及びＹ４４は夫々Ｏ又はＳである）、Ｚ７及びＺｉは夫々Ｏ，Ｓ、Ｃ１〜Ｃ８アルキリデン、置換若しくは未置換のベンジリデン、ＮＨ又はＮＲ”（ここでＲｒｔｔはアルキル、アリール、アルアルキル、アルケニル又はアルキニルである）であり、Ｙ７３及びＹ７４は同一でも異なっていてもよく水素、ハロゲン。アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリハロアルコキシ、ハロアルキル、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アリール、ポリハロアル４；ルスルホニル、アルキルアミノ、ジアルキルアミノ、アシルアミノ、アシルオキシ、アルキルスルホニルオキシ、アリフルスルホニルオキシ、アルケニルスルホニルオキシ、ハロアルキルスルホニルオキシ又はポリハロアルキルスルホニルオキシである。 −ＣＨ２ＣＨ−Ｃ（ＣＨ３）０ＣＨ２−。 −ＣＨＣＨ２５ＣＨ２ＣＨ（ＣＨ３°）−２−ＣＯＣＨ２Ｃ（ＣＨ３）２ＣＨ２Ｃ０−１−ＣＯＣＨ２０）−１（Ｃ６Ｈ５）ＣＨ２Ｇｏ−。 −〇〇ＮＨ（０６Ｈ５）ＣＨ２ＣＨ２０−２−ＣＯＣ（ＣＨ３）２Ｎｈｃｏ−。 −ＣＨ２ＣＨ２Ｎ（Ｃ６Ｈ５）ＣＨ２ＣＨ２−１−ＣＨ２Ｎ（Ｃ６Ｈ５）φＨ２ｃＨ２−２−ＣＨ２ＣＨ２ＣＨ（０６Ｈ５）ＣＨ２ＣＨ２−２−Ｃｏ　（ＣＨ２）３Ｇｏ−、−〇〇　（ＣＨ２）２ｃｏ−。 −ＣＨＣＨ２ＣＨ（ＣＨ３）ＣＨ２Ｃｏ−。 −ＣＯＣ）Ｉ　（ＣＨ３）ＣＨ２Ｃｏ−。 −ＣｏＣ（ＣＨ３）２０Ｈ２ｃｏ−０ −ＣＯＣ（ＣＨ−１３）２　Ｃ（ＣＨ３）　２Ｃｏ−。 −Ｃｏ　（ＣＨ）　Ｇｏ−、−Ｇｏ　（ＣＨ２’）　５Ｃｏ−。 −Ｃｏ　（ＣＨ２）５ＣＨ２−、−Ｃｏ　（引−１２）４ＣＨ２−。 −Ｇｏ　（ＣＨ２）３ＣＨ２−、−Ｃｏ　（ＣＨ２）２Ｃ１−１２−。 −ＣＯＣＨ２ＳＣＨ２Ｃｏ−。 −ＣＯＣＨ２Ｎ　（Ｒ５２）ＣＨ２Ｃｏ−。 −ＣＯＣＨ２０ＣＨ２Ｃｏ−、−ＣＯＣＨ２ＳＣ８−。 −ＣＯＣＨ−ＣＨ−Ｎ−ＣＨ−。 −ＣＨＣＨ（Ｃ６Ｈ５）ＣＨ２−Ｎ−ＣＨ−又は−ＣＯ２−ＣＨ２ＣＨ２−であり、ここでＲ５２は水素、アルケニル又は置換若しくは未置換のアリール又はアルカアリールであり、Ｚ　及びＺ　は夫々Ｏ，Ｓ、Ｃ〜Ｃ８アルキリデン、置換若しくは未置換のベンジリデン、ＮＨ又はＮＲ”（ここでＲｒｓはアルキル、アリール、アルアルキル、アルケニル又はアルキニルである）であり、Ｙ　及びＹ７６は同一でも異なっていてもよく水素、ハロゲン。アルキル、シアノ、ポリハロアルキル、アルコキシ、ポリ八日アルコキシ、ハロアルキル、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アシル、ポリハロアルキミノ、アシルオキシ、アルキルスルホニルオキシ、アリールスルホニルオキシ、アルケニルスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、ホスホノ又はホスフィノである。上記式中、Ｒ７２は置換若しくは未置換のフェニル或いは１−又は２−ナフチルであり、 ×３１は一０ＣＨ２＋、−ＣＨ２−、共有結合。 −Ｃ（ハロゲン＞　、−ＣＭ：Ｃ−。 −ＯＣＨ（アルキル）−、−ＱＣ（アルキル）２゜−ＣＨ（アルキル）ＣＨ（アルキル）−９−ＣＨ（アルキル）、−、−Ｃ（アルキル）２−１Ｓｏ　、−ＣＨ５（０）ｈ−。 −ＣＨ（アルキル）Ｓ　（０）　１＋、　−ｓ　（０）　ｈＣｌ−１２−。 −ＣＨ（ハロゲン）−、−〇（アルキル）（ハロゲン）−１−ＣＨ（ＣＮ）−、 −Ｃ（アルキル）（ＣＮ）−。 −Ｃ（＝Ｏ）−、−ＣＨ（０−アルキル）−９−ＣＨ２Ｏ（−〇）−、−Ｃ（＝Ｏ）ＣＨ２゜−ＣＨ（アルキル）　Ｃ（−０）　−。 −Ｃ（＝Ｏ）　ＣＨ（アルキル）、−ＣＨ−ＣＨ−。 −Ｃ（アルキル）−ＣＨ−、−ＣＨ＝Ｃ（アルキル）−１−Ｃ（アルキル）−Ｃ（アルキル）−１−Ｃ（＝Ｏ）ＣＨ−ＣＨ−、アリーレン。 −８ｉ（ハロゲン）、、　−、−８ｉ　（アルキル）２−９ｈは０〜２の値である）、２　はｏ、ｓ、ｃ　−ｃ８アルキリデン、置換若しくは装置換のベンジリデン、ＮＨ又はＮＲ”（ここでＲＩＭはアルキル、アリール、アルアルキル、アルケニル又はアルキニルである）であり、Ｙ　、Ｙ　及びＹ２Ｏは同一でも異なっていてもよく水素、ハ０ゲン、アルキル、ヒドロキシ、シアノ、ポリハロアルキル。゛アルコキシ、ポリハロアルコキシ、ハロアルキル、アルキルチオ、アルキルスルフィニル、アルキルスルホニル、ニトロ、アシル、ポリハロアルキルスルホニル、アルキルアミノ、アミノ。ジアルキルアミノ、アシルアミノ、アシルオキシ、アルキルスルホニルオキシ、 ′°アリールスルホニルオキシ、アルケニルスルキルスルホニルオキシ、ホスホノ又はホスフィノである。ノ、アルキルアミノ、ジアルキルアミノ又はアシルアミノではあり得ず、Ｙ　及びＹ　が同じハロゲンのときにはＹ２Ｏが水素又はヒト０キシではあり得ない。上記式中、Ｒ７３はイソオキサゾール、イソチアゾール、ピラゾール、イミダゾール、　１，２．４−ｔ−リアゾール、　１，２．４−オキサジアゾール。１．３．４−オキサジアゾール、　１，２．４−チアジアゾール、　１，３．４ −チアジアゾール、オキサゾール、チアゾール、ベンゾピラゾール。ベンズイミダゾール、ベンズオキサゾール、ベンゾチアゾール。インドール、ビロール、フラン、チオフェン、ベンゾフラン。５−トリアジン、　１，２．４−トリアジン、キノリン、イソキノリン。キナゾリン、フタラジン、ベンゾピリダジン、ベンゾピラジン。カルバゾール、ジベンゾフラン、ジベンゾチオフェン、ベンゾキサジン、フタルイミド、ベンゾビラン、ジベンゾピリジン。ピリドピリジン、ピラゾロピリミジン、テトラヒドロピリミジンジオン、−一一二一ビペ”リジン、モルホリン、テトラヒドロフラン、テトラヒトロチオフ・エン、ビロリヅン、チオモルホリン、ピペリジン−２−オン、ピ°ベリジンー２．６−シオン、２，５−ピロリジンジオン、３−モルホリン、２−オキソヘキサメチレンイミン。２−オキソテトラメチレンイミン、１−ピラゾリン、２−ピラゾリン。、ピラゾリジン、２−イミダゾリジノン、２−イミダゾリジンチオン。２．４−イミダゾリジンジオン、１．２−オキサチオラン、１．３−オキサチオラン、１，３−オキサチアン、１，４−オキサチアン、　２（ＩＨ）−ビラジノン、　２８−ビラン−２−オン、　４Ｈ−ビラン−４−オン、　２Ｈ−ビラン− ２−ヂオン、４１１−ビランー４−チオン、テトラヒドロビラン。テトラヒドロチオビラン、７−オキサゾールｏ　［２，２，１１へブタン。７−アザビシクロ［２，２，１３へブタン、オキセタン、クマリン、１゜３−ジオキサン、１，４−ジオキサン及び１．３−ジオキソランから選択された置換若しくは未置換の飽和若しくは不飽和の芳香族又は非芳香族複素環式環系であり、 ×３２は一〇〇Ｈ２＋、−ｃ＋２＋、共有結合。 −Ｃ＜ハロゲン＞　、−Ｃ＝Ｃ−。 −ＯＣＨ（アルキル）−、−ＱＣ（アルキル）２゜−ＣＨ（アルキル）ＣＨ（アルキル）−１−ＣＨ（アルキル）−、−Ｃ（アルキル）２−９−ＯＣＨ２ＣＨ２ −、−ＣＨ２ＣＨ２−、Ｓｏ、−３−。Ｓｏ２．−ＣＨ，２Ｓ　（０）ｉ　−。ＣＨ（フルキル）Ｓ　（０）　ｈ　、−３（０）１．ＣＨ２＋。 −ＣＨ（ハロゲン）−、−Ｃ（アルキル）　（ハロゲン）−２−ＣＨ（ＣＮ）− 、−Ｃ（アルキル）（ＣＮ）−。 −Ｃ（−０）＋、　−ＣＨ（０−アルキル）−１−ＣＨ，、Ｃ（−０）＋、−ｃ　（−０）ＣＨ２゜−ＣＨ（アルキル）　Ｃ（−０）　−。 −Ｃ（−０）　ＣＨ（アルキル）、−ＣＨ−ＣＨ−。 −Ｃ（アルキル）−ＣＨ−、−ＣＨ−Ｃ（アルキル）−１゜−Ｃ（アルキル）− Ｃ（アルキル）−１−Ｃ（−０）ＣＨ−ＣＨ−、アリーレン。 −８１（ハ［］グン＞２−、−３ｉ＜アルキル）２−−Ｃ１ｌ−Ｃ（アルキル） − りは０〜２の値である）、２　はＯ，Ｓ、Ｃ１〜Ｃ８アルキリデン、置換若しくは装置換のベンジリデン、ＮＨ又はＮＲ”（ここでＲＪＩＩはアルキル、アリール、アルアルキル、アルケニル又はアルキニルである）であり、Ｙ　、Ｙ　及びＹＢ２は同一でも異なっていてもよく水素、八０ゲン、アルキル、ヒドロキシ、シアノ、ポリハロアルキル。アルコキシ、ポリハロアルコキシ、ハロアルキル、アルキルナ１オ、アルキルスルフイニル、アルキルスルホニル、ニトロ、アシル、ポリハロアルキルスルホニル、アルキルアミノ、アミン。ジアルキルアミノ、アシルアミノ、アシルオキシ、アルキルスルホニルオキシ、アリールスルホニルオキシ、アルケニルスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、ホスホノ又はホスフィノである。上記式中、Ｒ７４は置換若しくは未置換のアルキル、アルケニル、アルキニル、シクロアルキル、シクロアルケニル、シクロアルカジェニル、シクロアル力トリエニル、ごシクロアルキル、ビシクロアルケニル、ビシクロアルカジェニル、トリシクロアルキル。゛、−トリシクロアルケニル又はトリシクロアルカジェニルであり、Ｘ　は−０ＣＨ２−、−’ＣＨ２−，共有結合。 −Ｃ（ハロゲン）　、−ＣミＣ−９ −ＱＣ）−１（アルキル）−、−ＱＣ（アルキル）２゜−ＣＨ（アルキル）ＣＨ（アルキル）−２Ｓｏ２．−ＣＨ２３（０）　ｈ−。 −ＣＨ（アルキル）Ｓ　（０）　ｈ−、−８（０）　ｈＣＨ２＋。 −ＣＨ（ハロゲン）−、−Ｃ（アルキル）　（ハロゲン）−２−ＣＨ（ＣＮ）＋、−ｃ　（７）Ｌ、キル）（ＣＮ）−。 −Ｃ（−０）−、−ＣＨ（０−アルキル）−２−ＣＨ２Ｏ（−０）−、−Ｃ（− ０）ＣＨ２゜−ＣＨ（アルキル）　Ｃ（−０）　−。 −Ｃ（−０）ＣＨ＜フル＊ル）、−ＣＨ−ＣＨ−。 −Ｃ（７／Ｌ、＊／ｌ、）　−ＣＨ−’、　−ＣＨ−Ｃ（７／Ｌ、−１−／Ｌ、）ニー。 −Ｃ（アルキル）−Ｃ（アルキル）−２−Ｃ（−０）ＣＩ−１−ＣＨ−、アリーレン２−３ｉ（ハロゲン）２　、Ｓｉ（アルキル）２−１Ｚ１３はＯ，Ｓ；　Ｃ１〜Ｃ８アルキリデン、置換若しくは未置換のベンジリデン、Ｎ）］又はＮＲ” （ここでＲｔｎはアルキル、アリール、アルアルキル、アルケニル又はアルキニルである）であり、ＹＢ２．ＹＢ２及びＹＢ２は同一でも異なっていてもよく水素、ハロゲン、アルキル、ヒドロキシ、シアン、ポリハロアルキル。アルコキシ、ポリハロアルコキシ、ハロアルキル、アルキルチオ。アルキルスルフィニル、アルキルスルボニル、ニトロ、アシル、ポリハロアルキルスルホニル、アルキルアミノ、アミノ。ジアルキルアミノ、アシルアミノ、アシルオキシ、アルキルスルホニルオキシ、アリールスルホニルオキシ、アルケニルスルホニルオキシ、ハロアルキルスルホニルオキシ又はポリハロアルキルスルホニルオキシである。上記式（ｉ）〜（ｘｘｘ　ｉ　）において許容され得る置換基→は同一でも異なっていてもよく１個又はそれ以上の水素、ハロゲン。アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ。ボリハＯアルケニルチオ、チオシアノ、プロパルギルチオ９．ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオ°キシ、アリールジアルキルシリルオキシ、トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルス史ルフ７ミド、アルキシスルホニル、ポリハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル、ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒドロギシ力ルボニル及びその銹感温、ホルムアミド、アルキル、アルコキシ、ポリハロアルキル、ポリハロアルコキシ、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又は２個のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル。アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩、ホスホン酸及びその誘導塩°、アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル。アルキニルオキシ、ポリハロアルケニルオキシ、ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル、アルコキシカルボニルヒドラゾツメチル挽若しくは未置換のアリールオキシイミノメチル、ヒドラゾツメチル、置換若しくは未置換“のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒトＯキシ基。キル、アリールスルフィニル、アリールスルホ÷ル，ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ，ハロアルキニルオキシ、ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル、アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、７０イル、へロアシル、ポリ八ロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノアルコキシ。ルポキシアルキルチオ，アルコキシカルボニルアルコキシ、アシルオキシ、ハロアシルオキシ、ポリ八ロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、ハロアシルアミノ、アルコキシカルボニルオキシ、アリーソシアナト．イソチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノヂオイル．アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム、−Ｘ．−Ｘ．−Ｘ−Ｒ３．− Ｘ−Ｒ３。Ｙ３Ｒ５である。上記式中、、ＹＢ２．ＹＢ２．ＹＢ２．Ｙ６５及びＹＢ２は同一でも異なっていてもよくハロゲンであり、Ｒ１は単環式芳香族若しくは非芳香族環系，二環式芳香族若゛シクは非芳香族環系．多環式芳香族若しくは非芳香族環系及び架橋環系から選択された置換或いは未置換の炭素環式又は複素環式環系であって、前記環系は飽和でも不飽和でもよく、許容され得る置換基は同一でも異なっていてもよく１個又はそれ以上の水素，ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルオキシ、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ，チオシアノ。プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールシアル（キルシリルオキシ。ドリアリールシリルオキシ、ホルムアミジノ、アルキルスルフ幸アミド、ジアルキルスルファミド、アルキシスルホニル、ポリハロアルコキシスルホニル２ヒドロキシ、アミノ、アミノカルジアルキルアミノチオカルボニル、ニトロ、シア、）、ヒドロキシカルボ、ミ９〆びその誘導塩、ホルムアミド、アルキル、アルコキシ、ポリハロアルキルも異なっていてもよく１個又は２個のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル；ハロアルケニル又はポリハロアルケニルである）、アルキルヂオ，ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ、ボリハＯアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩。ホスホン酸及びその誘導塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシキシアルキニル、アルキニルオキシ、ポリハロアルケニルオキシ。ポリハロアルキニル、ポリハロアルキニルオキシ，ポリフルオロアルカノールル，アルコキシカルボニルヒドラゾツメチルノメチル、置換若しくは未置換のアリールオキシイミノメチル。ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリザラカライドと縮合したヒドロキシ基，ハロアルキル、ハロアルケニル、ハロアルキニル。アルコキシアルキル、アリールオキシ、アラアルコキシ、アリ・−ルチオ，アラアルキルチオ、アルキルチオアルキル、アリー゛ルヂオアルキル，アリールスルフィニル、アリールスルホニル。ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ。、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル。アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、アロイル、ハロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホキシ、アシルオキシ、へロアシル第４シ，ポリ八ロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルギルスルホニルオキシ、アロイルアミノ、ハロアシルアミノ、アル戸キシカルボニルオキシ。トウイソシアナト、イソチオシアノ、シクロアルキルアミノ。トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミン、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ。ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコ、キシアルケニル、シアノアルコキシ、ジアルキルスルホニウム。 −Ｘ，−Ｘ，−Ｘ−Ｒ３．−Ｘ−Ｒ３。Ｙ３Ｒ５であり、或いはＲ１は置換異原子又は置換炭素原子、或いは２個若しくはそれ以上の炭素原子又は異原子と以下の許容され得る置換基を組合せて含有する置換若しくは未買換の直鎖又は分岐鎖であって、前記置換基は同一でも異なっていてもよく１個またはそれ以上の水素，ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルヂオ，ポリハロアルケニルチオ、ナオシアノ，ブ０／マルギルチオ，ヒト０キシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールシアル４ニルシリルオキシ、ト、リアリールシリルオキシ、ボルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルコキシスルボニル、ポリハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル。ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒドロキシカルボニル及びその誘導塩、ホルムアミド、アルキル、アルコキシ、ポリハロアルキル、ポリハロアルフキル、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又は２個のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル。ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルセルボニルアミノ。ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノキルシリル、トリアリールシリル、スルホン酸及びその３７　３１塩。ホスホン酸及びその訓導塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ。アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ。ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノル．アルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチ“ル．買挽若しくは未買換のアリールオキシイミノメチル。ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾノロキシ基，ハロアルキル゛，ハロアルケニル、ハロアルキニル。アルコキシアルキル、７１ノールオキシ、アラアルコキシ、アリールチオ、アラアルキルｆオ，アルキルチオアルキル、アリ−ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ。ハロアルケニルスルホニル、ボリハＯアルケニルスルホニル。アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、アロイル、°ハロアシル、ポリ八ロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホニル、カルボキシアルコキシ、カルボキシアルキルチオ、アルシ，ポリハロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、へロアシルアミノ、アルカルボニルオキシシクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ。アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ。ジアルキルスルホニウム、−Ｘ．−Ｘ。Ｙ３Ｒ５であり、Ｘは共有−重結合又は二重結合、置換若しくは未置換の異原子又は口換炭素原子、或いは２個若しくはそれ以上の炭素原子又は異原子と以ｒの許容され得る置換基を組合せて含有°する置換若しくは未置換の直鎖又は分岐鎖であって、前記置換基は同一でも異なっていてもよく１個またはそれ以上の水素，ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ボリハロアルケニルヂオ，チオシアノ、プロパルギルチオ。ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ、トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルコキシスルホニル、ポリハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル、ジアルキルアミノチオカルボニル、ニトロ、シアノ、ヒドロキシカルボニル及びそのｌｉ！塩，ホルムアミド、アルキル、アルコキシ、ポリハロアルキル、ポリハロアルコキル、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又は２個のプロパルギル、アルコキシアルキル。アルキルチオアルキル、アルキル、アルケニル、ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリ八口アルキルチオ、アル４−ルスルフィニル、ポリハロアルキルスルフィニル、アルギルスルホニル、ボリハＤアル４− ルスルホニル。アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルびそのｍ　Ｓ塩、アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル。アルキニルオキシ、ポリハロアルケニルオキシ、ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオ［］アルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル，アルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチル、置換若しくは未買換のアリールオキシイミノメチル、ヒドラゾツメチル、ｎ挽若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基。ハロアルキル、ハロアルケニル、ハロアルキニル、アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ′。アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル、ハロアルキルスルフィニル．ハロアルＡニルスルホニル、ハロアルケニルオキシ，ハロアルキニルオキシ、ハロアルキニルチオ、ハロアルケニルスルホニル、ポリハロアルケニルスルホニル。アルコキシスルボニル、アリールアミノスルホニル、プロパルギルオキシ、アロイル、へロアシル、ポリ八ロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル。ジアルキルアミノスルホニル、アリールアミノスルホニル、力Ｊレボキシアルコキシ、カルボキシアルキルチオ、アルコキシカルボニルアルコキシ、アシルオキシ、ハロアシルオキシ、ポリハロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ９アリールスルホニルオキシ。ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、ハロアジルアミノ、アルコキシカルオキシ、シアナト、イソシアナト、イソチオシアノ、シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ。アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、“アルキルアミノアルコキシ、ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム、−Ｘ，−Ｘ，−Ｘ＝Ｒ３．−Ｘ−Ｒ３。Ｙ３Ｒ５であり、或いはＲ３６は単環式芳香族若しくは非芳香族環系，二環式芳香族若系であって、前記環系は飽和でも不飽和でもよく、許容され得る置換基は同一でも異なっていてもよく１個又はそれ以上の水素，ハロゲン、アルキルカルボニル、アルキルカルボニルアル４；ル，アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ，チオシアノ、プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ、ドリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド。アルキルアミンカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル：゛アルキルアミノチオカルボニル、ジアルポトにびその＝ｓ犯ホルムアミド、アルキル、アルコキシ。ポリハロアルキル、ポリハロアルコキシ、アルコキシカルボニル、＠換アミノ（この場合許容され得る置換基は同一でも異なルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル。スルホン酸及びそのＭ　１１塩，ホスホン酸及びその誘導塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシシ、アルケニル、ポリハロアルケニル、アルケニルオキシ、アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ、ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノールアルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチル、置換若しくは未置換のアリールオキシイミノメチル、ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基，ハロアルキル、ハロアルケニル、ハロアルキニル，アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリール・スルフィニル、アリールスルホニル。ハロアルキルスルフィニ°ル，ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ。ハロアルケニルスルホニル、ボリハＯアルケニルスルホニル。アルコキシスルホニル、アリールオキシスルホニル、プロパルギルオキシ、アロイル、ハロアシル、ポリ八ロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホキシ、アシルオキシ、ハロアシルオキリ，ポリへロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルトリアルキルアンモニウム，アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ。ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスル小ニウム。、−Ｘ，−Ｘ，−Ｘ−Ｒ３，−Ｘ−Ｒ３。Ｙ３Ｒ５であり、或いはＲ３は単環式芳香族若しくは非芳香族環系，二環式芳香族若しくは非芳香族環基，多環式芳香族若しくは非芳香族環系及び架橋環系から選択された置換或いは未置換の炭素環式又は複素°上の水素，ハロゲン、アルキルカルボニル、アルキルカルボニ・ルアルキル，アルコキシカルボニルアルキルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ。プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ。ハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル。ジアルキルアミノチオカルボニルシカルポ憂嘴びそのＭＨＩ塩．ホルムアミド、アルキル、アルコキシ、ポリハロアルキルルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又は２個のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル。ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ−ポリハロアルキルスルホニルアミノ、ボリハＯアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩。ホスホン酸及びそのＴＡ　ｌ塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル，アルケニルオキシ。アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ。ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル、アルフキシカル゛ボニルヒドラゾツメデル、アルコキシイミノメチル、置換若しくは未置換のアリールオキシイミノメチル。ヒドラゾツメデル、置換若しくは未置換のアリールヒドラゾツメデル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基、ハロアルキル、ハロアルケεル、ハロアルキニル。アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル。ハロアルキルスルフィニル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ。ハロアルケニルスルホニル、ポリハロアルケニルスルホニル。アルコキシスルホニル、アリールオキシカルボニル、プロパルギルオキシ、アロイル、ハロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホキシ、アシルオキシ、へロアシルオキシ、ポリハロアシルオキシ、アロイルオキシ、アルキルスルホニルオキシ、アルケニルスルホニルオキシ、アリールスルホニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、ハ［Ｊアシｌレアミノ、アルコキシカルボニルオキシアリールスルホニルアミノ、アミノカルボニルオキシ、シアナト、イソシアブト、イソチオシアノ、シクロアルキルアミノ。トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ、アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ。ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム。Ｙ３Ｒ５であり、或いはＲ３は置換異原子又は置換炭素原子、或いは２個若しくはそれ以上の炭素原子又は異原子と以下の許容され得る置換基を組合せて含有する置換若しくは未置換の直鎖又は分岐鎖であって、前記置換基は同一でも異なっていてもよく１個またはそれ以上の水素．ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシ力ルポニルアルキルヂオ，ポリハロアルケニルチオ、チオシアノ、プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ、トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルコキシスルホニル、ポリハロアルコキシスルホニル、ヒドロキシ、アミノ、アミノカルボニル、アルキルアミノカルボニル、ジアルキルアミノカルボニル、アミノチオカルボニル、アルキルアミノチオカルボニル。ジ？ルキルアミノチオ力ルボニル，ニトロ、シアン、ヒト０キシカルボニル及びその誘Ｓ塩．ホルムアミド、アルキル、アル゛　フキシ．ポリハロアルキル、ポリハロアルコキル、アルコキシ、カルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよく１個又は２個のプロパルギル、アルコキシアルキル、アル４ルチオアルキル，アルキル、アルケニル。ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリへ〇アルキルスルフィニ“ル，アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスル本ニルアミノ、アルキルカルボニキル力ルポニルアミノ，トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩。ホスホン酸及びその誘導塩，アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ。アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ。ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミ力ルバゾノメチル，アルフキシ力ルポニルヒドラゾノ°メチル、アルコキシイミノメチル、置換若しくは未Ｈａのアリールオキシイミノメチル。ヒドラゾツメデル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基，ハロアルキル；ハロアルケニル、ハロアルキニル。アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールヂオ，アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリールスルフィニル、アリールスルホニル。ハロアルキルスルフィニル、八ロアルキルスルホニル，ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ。ハロアルケニルスルホニル、ポリハロアルケニルスルボニル。アルコキシスルホニル、アリールオキシスルボニル、プロパルギルオキシ、アロイル、ハロアシル、ポリハロアシル、アリールオキシカルボニル、アミノスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルボニル、カルボキシアルコキシ、カルボキシアルキルチオ、アルコキシカルボニルアルコキシ、アシルオキシ、へロアシルオキシ、ポリハロアシルオキシ、アロイルオキシ、アルキルスルボニルオキシ、アルケニルスルホニルオキシ、アリールスルボニルオキシ、ハロアルキルスルホニルオキシ、ポリハロアルキルスルホニルオキシ、アロイルアミノ、へロアシルアミノ、アルフキシカルボニルオキシ、アリールスルホニルアミｌ、アミノカルボニルオキシ、シアナト、イソシアナト、イソチオシアノ。シクロアルキルアミノ、トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミノ、アラアルキルアミノ。アルコキシアルキルホスフィニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシホスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アリールオキシアミノ、アリールオキシイミノ、オキソ、チオノ、アルキルアミノアルコキシ、ジアルキルアミノアル凸キシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ。ジアルキルスルホニウム、−Ｘ、−Ｘ。Ｙ３Ｒ５であり、Ｙｌ及びＹ４は夫々酸素又は硫黄であり、Ｙ２及びＹ３は夫々酸素、硫黄、アミノ又は共有結合であり、Ｒ４及びＲ５は夫々水素或いは置換若しくは未置換のアルキル、ポリハロアルキル、フェニル又はベンジルであり、許容され得る買換基は同一でも異なっていてもよく１個又はそれ以上の水素、ハロゲン、アルキルカルボニル、アルキルカルボニルアルキル、アルコキシカルボニルアルキル、アルコキシカルボニルアルキルチオ、ポリハロアルケニルチオ、チオシアノ、プロパルギルチオ、ヒドロキシイミノ、アルコキシイミノ、トリアルキルシリルオキシ、アリールジアルキルシリルオキシ、トリアリールシリルオキシ、ホルムアミジノ、アルキルスルファミド、ジアルキルスルファミド、アルキルスルホニル、ボリハニル、アルキルアミノカルボニル、ジアルキルアミノ力ルボニ）し　・シカルボ号≦び°その誘導塩、ホルムアミド、アルキル、アルコキシ、ポリハロアルキル、ポリハロアルコキシ、アルコキシカルボニル、置換アミノ（この場合許容され得る置換基は同一でも異なっていてもよ（１個又は２個のプロパルギル、アルコキシアルキル、アルキルチオアルキル、アルキル、アルケニル。ハロアルケニル又はポリハロアルケニルである）、アルキルチオ、ポリハロアルキルチオ、アルキルスルフィニル、ポリハロアルキルスルフィニル、アルキルスルホニル、ポリハロアルキルスルホニル、アルキルスルホニルアミノ、アルキルカルボニルアミノ、ポリハロアルキルスルホニルアミノ、ポリハロアルキルカルボニルアミノ、トリアルキルシリル、アリールジアルキルシリル、トリアリールシリル、スルホン酸及びその誘導塩。ホスホン酸及びそのｆｆ１ｌ塩、アルコキシカルボニルアミノ、アルキルアミノカルボニルオキシ、ジアルキルアミノカルボニルオキシ、アルケニル、ポリハロアルケニル、アルケニルオキシ。アルキニル、アルキニルオキシ、ポリハロアルケニルオキシ。ポリハロアルキニル、ポリハロアルキニルオキシ、ポリフルオロアルカノール、シアノアルキルアミノ、セミカルバゾノメチル、アルコキシカルボニルヒドラゾツメチル、アルコキシイミノメチル、置換若しくは未置換のアリールオキシイミノメチル。ヒドラゾツメチル、置換若しくは未置換のアリールヒドラゾツメチル、モノ−、ジー或いはポリサッカライドと縮合したヒドロキシ基、ハロアルキル、ハロアルケニル、ハロアルキニル。アルコキシアルキル、アリールオキシ、アラアルコキシ、アリールチオ、アラアルキルチオ、アルキルチオアルキル、アリールチオアルキル、アリ−、ルスルフィニル、アリールスルボニル。ハロアルキルスルフィニ°ル、ハロアルキルスルホニル、ハロアルケニルオキシ、ハロアルキニルオキシ、ハロアルキニルチオ。ギルオキシ、アロイル、ハロアシル、ポリハロアシル、アリールオキシカルボニル、アミンスルホニル、アルキルアミノスルホニル、ジアルキルアミノスルホニル、アリールアミノスルホキシ、アシルオキシ、へロアシルオキシ、ボ□リハ「１アシルオｔニジ、アロイルオキシ、アルキルスルボニルオキシ、アルウニルスルホニルオキシ、アリールスルボニルオキシ、ハロアルキルスルホニルオキシ９ポリハロアルキルスルボニルオキシ、アロイルアミノ９ハロアシルアミノ、アルコキシカルボニルオキシ。ト、イソシアナト、イソチオシアノ、シクロアルキルアミノ。トリアルキルアンモニウム、アリールアミノ、アリール（アルキル）アミン１．アラアルキルアミノ、アルコキシアルキルホスフ、イニル、アルコキシアルキルホスフィノチオイル、アルキルヒドロキシボスフィニル、ジアルコキシホスフィノ、ヒドロキシアミノ、アルコキシアミノ、アラアルキルアミノ、アリ−。ルオキシイミノ、第４ソ、チオノ、アルキルアミノアルコキシ。ジアルキルアミノアルコキシ、アルコキシアルコキシ、アルコキシアルケニル、シアノアルコキシ、ジアルキルスルホニウム。 −Ｘ、−Ｘ、−Ｘ−Ｒ３，−Ｘ−Ｒ３゜従来方法に従って製造され得、多くは各種供給業者（ＳＬＩＩ＋ＤＩ　＋ｅｒ）から市販されているであろう。本発明方法に使用され得る上記式（ｉ）〜（ｘｘｘ　ｉ　ｉ　ｉ　）の新規な窒素含有複素環化合物は、下記する如き当業者に公知の各種従来方法に従って適当な出発物質を反応させて製造することができる。（以下余白）式（ｉ）の新規な窒素含有゛複素環化合物は、次の一般的な反応式に従って製造され得る。置換ピリジン類を製造するための上記した一般的な反応は反応条件も含めて、例えばＨｅｒｔｅｌＪｌ、Ｅ、、Ｔｈｅ　Ｃｈｅｍｉｓｔｒｙ　ｏｆ　Ｈｅｔｅｒｏ−ｃｙｃｌｉｃ　Ｃｏｍｐｏｕｎｄｓ、　Ｐｙｒｉｄｉｎｅ　ａｎｄ　Ｄｅｒｉｖａｔｉｖｅｓ−Ｐａｒｔ　２］ａｌｏ−ｐｙｒｉｄｉｎｅｓ、ｐ、３５１．　Ｉｎｔｅｒｓｃｉｅｎｅｅ、　Ｗｉｌｅｙ、Ｎｅｗ　Ｙｏｒｋ（１９６１）に記載されている。２，４．６−ドリクロロビリジンの如き中間体はＵ、　Ｓ、　Ｐ、　３．８３０．８２０に記載されている。式（１）の新規な化合物を製造するための他の方法は、Ｆｕ３ＨＪ、Ｃ，Ｊｄｙａｎｃｅｄ　ＯｒｇａｎｉｃＣｈｅｍｉｓｔｒｙ、ｐ、１２４．　Ｗｉｌｅｙ、　Ｎｅｗ　Ｙｏｒｋ（１９５０）及び０ｃｈｉａｉ、Ｅ、、Ａｒｏ−ｍａｔｉｃ　Ａｍ１ｎｅ　０ｘｉｄｅｓ、ｐ、２１．　Ｅｌｓｅｖｉｅｒ、　Ｎｅｗ　Ｙｏｒｋ（１９６７）に記載されている。式（ｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ，Ｘｂ及びＹ２８は前記と同義である。菫２５　１１・換ピラジン類を製造するだめの上記した一般的な反応は反応条件も含めて、例えばｕ、　ｓ、　ｐ、４，２５４，１２５に記載されている。式（ｉｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ，Ｘ、ＹＹ　及びＹ２３は前記と同義で２６　１２　２１’　２２あり、Ｙ４９はハロゲンである。２−置換ピリミジン類を製造するための上記した一般的な反応は反応条件も含めて、例えばＨｕｒｓｔ、Ｄ、Ｔ、、　Ａｎ　Ｉｎｔｒｏｄｕｃｔｉｏｎ　ｔｏ　ｔｈｅ　ＣｈｅＩＩｌｉｓｔｒｙ　ａｎｄ　８ｉｏｃｈｅｍｌｓｔｒｙ　ｏｆ　Ｐｙｒｉｍｉｄｉｎｅｓ、Ｐｕｒｉｎｅｓ　ａｎｄ　Ｐｔｅｒｉｄｉｎｅｓ、　ｐｐ、４９−５３゜Ｗｉｌｅｙ、　Ｎｅｗ　Ｙｏｒｋ（１９８０）に記載されている。Ｙ　及びＹ２３がアルギルチオである中間体はＥｉｌｉｎｇｓ４ｃｌｄ、　Ｈ，及び５ｃｈｅｖｃｒＩｌｌａｎｎ。Ｈ，、Ｃｈｅｍ、　Ｂｅｒ、、−υ）Ｏ，ｐ、１８７４−１８９１（１９６７）に記載されている。Ｒａｍｂｒｙ−Ｈｕｌｌピリミジン合成の如き式（ｉｉｉ）の新規な化合物を製造するための弛の方法は、Ｂｒｏｗｎ、　Ｄ、　Ｊ、、　Ｔｈｅ　Ｐｙｒｉｍｉｄｉｎｅｓ；Ｔｈｅ　Ｃｈｅｍｉｓｔｒｙ　ｏｒ　Ｈｅｔｅｒｏｃｙｃｌｉｃ　Ｃｏｍｐｏｕｎｄｓ、　ｐｐ、９８．１６９−１７０゜１６６、　Ｉｎｔｅｒｓｃｉｃｎｃｅ、　Ｗｉｌｅｙ、　Ｎｅｗ　Ｙｏｒｋ（１９６０）、／に記載されている。式（ｉｖ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ２□、×１３．Ｙ２４．Ｙ２５．Ｙ２６及びＹ４９は前記と同義である。４−置換ピリミジン類を製造するための上記した一般的な反応は反応条件も含めて、例えばＪＯ３＋■ａ、　Ｔ、ら、５ａｎｋｙ。にｅｎｋｙｕｓｈｏ　Ｎｅｗｐｏ、　３２．　ＤＩ）、　１１４−１２０（１９８０）に記載されティる。式（Ｖ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ２８，×１４．Ｙ２□、Ｙ２８及ヒＹ２９ハ前記ト同義テある。反応条件も含めた５−置換ピリミジン類を製造するための上記した一般的な反応及び中間体の製造は、例えばＦｉ’ｅｓｅｒ、　Ｌ。Ｆ、及びＦｉｅｓｅｒ、　Ｈ，、Ｏｒｇａｎｉｃ　Ｃｈｅｍｉｓｔｒｙ、　ｐ、３１０．　Ｈｅａｔｈ。Ｂｏｓｔｏｎ（１９７２）／並びにＢｒｏｗｎ、　Ｄ、　Ｊ、、　Ｔｈｅ　Ｐｙｒｉｍｉｄｉｎｅｓ；　ＴｈｅｌＣｈｅｍｉｓｔｒｙ　ｏｆ　Ｈｅｔｅｒｏｃｙｃｌｉｃ　Ｃｏｍｐｏｕｎｄｓ、　ｐｐ、５０．１６６、　Ｉｎｔｅｒ−ｓｃｉｅｎｃｅ、　Ｗｉｌｅｙ、　Ｎｅｗ　Ｙｏｒｋ（１９６２）に記載されている。式（Ｖ＋）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。同義である。反応条件も含めた３−置換ピリダジン類を製造するための上記した一般的な反応及び中間体の製造は、例えばＪｏｊｉｍａ、　ｒ、ら、ＡＯｒｉｃ、　Ｂｉｏｌ、ＣｈｅＩｌｌ、、　３２．　（１１）、　１３７６−１３８１（１９６８）並びにＥｉｌｉｎｇｓｆｅ！ｄ、　Ｈ，及びＳｃｈｅｖｅｒｍａｎｎ、　Ｈ，、Ｃｈｅｍ。Ｂａｒ、　、　１００　、　ｔ８７４−１８９１（１９６７）に記載されている。式（ｖｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ３゜’　×１６”３３”３４”３５及び”４９は前記と（１９６８）に記載されている。式（ｖｉｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。反応式８上記式中、Ｙ　、Ｙ　’Ｙ　Ｙ　ｄ、ｅ、Ｒ３１及び×１７３６　３７１　３８・　４９゜は前記と同義である。反応条件も含めた置換１，３．５−１−リアジン類を製造するための上記した一般的な反応及び中間体の製造は、例えばドイツ特許９５２，４７８．　Ｉｌ、Ｓｊ）、２，８２４，８２３　、　Ｋｏｏｐｓａｎ、　Ｈ。ら、Ｒｅｃ、　Ｔｒａｙ、　Ｃｈｉｎ、、　７８．９６７−９８０　（ｉ９５９）、　Ｄｒａｂｅｋ、　Ｊ、及び５ｋｒＯｂａｌ、　Ｍｌ、　Ｃｈｅ＋＋＋、　Ｚｖｅｓｔｉ、、　１７．　（７）、　４８２−４８７（１９６３）、旧「ｔ。Ｒｏら、Ｈｅ１ｖ、　Ｃｈｉｎ、＾ｃｔａ、　３３．１３ＧＳ（１９５０）並びにドイツ特許１．０７６．６９６に記載されている。式（ｖｉｉｉ）の新規な化合物を製造及びＣｈａｋｒａｂａｒｔｉ、　Ｊ、に。ら、Ｊ、　’Ｃｈｅｆｆｉ、　Ｓａｃ、　８６１（１９７４）　ニ記載されている。式に従って製造され得る。艮灸人上上記式中、Ｒ３□、ｆ。×１８．Ｙ３９．Ｙ４ｏ及びＹ４９は前記と同義である。反応条件も含めた置換１，３．５−）・リアジン類を製造するための上記１ノだ一般的な反応及び中間体の製造は、例えばＵ、Ｓ、Ｐ、３，３１６，２６４　上記ｎすれテイル。２．４−シ’ｙ　ｏ　ロー６−（ジェトキシホスフィニル） −１，３，５−トリアジンの如き中間体は日本特許７４４６６３５に記載されている。式（ｉｘ）の新規な化合物を製造するｔ−メ（７）　他（Ｆ）　方法は、Ｈｅｎｄｏｚａ、　Ｃ，Ｅ、ら、Ｊ、　Ａｇ、　Ｆｏｏｄ　Ｏ−ｈｅｍ、、。１９、　（１）、　４ｌ−４５（１９７２）に記載されている。式に従って製造され得る。上記式中、Ｙ４１”　４□、Ｙ４９及び×１９は前記と同義である。反応条件も含めたビス−１，３，５−トリアジン類を製造するための上記した一般的な反応及び中間体の製造は、上記した式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似している。式（ｘｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ’　”　×２０−　Ｙ５２．Ｙ５３及びＹ４９は前記と同義である。反応条件も含めた置換１，３．５−ｔ−リアジン類を製造するための上記した一般的な反応及び中間体の製造は、上記した式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似している。式（ｘｉ）の新規な化合物を製造するための他の方法は、Ａ１１ｅｉ＋、　Ｃ，Ｆ、　Ｈ，及びＣｏｎｖｅｒｓｅ、　Ｓ、、　Ｏｒｇ、　Ｓｙｎ、　Ｃｏ１１．、　Ｖｏｌ。１、２２６−２２７．υ、Ｓ、Ｐ、１，９１１，６８９．Ｂｅ５Ｓｉｅｒｅ−Ｃｈｒｅｔｉｅｎ、　Ｌ及び５ｅｒｎｅ、　Ｈ，、Ｂｕｌｌ、　Ｓｏｃ、　Ｃｈｔｍ、　Ｆｒａｎｃｅ、（６）、　Ｐａｒｔ　２．２０３９−２０４６（１９７３）、　日本特１２８，１０１．８本特許２８，１００．日　本　特　許２８．０９８　、日本特許９１５５．Ｌｏｅｗ、　Ｐ、及び−ｅｉｓ、　Ｃ，Ｄ４．　Ｊ、　Ｈｅｔｅｒ。ｃｙｃｌｉｃ　Ｃｈｅｗ、、　１３．８２９−８３３（１９７６）並びにＲｉｃｈｔｅｒ、　Ｇ、　Ｈ，。Ｔｅｘｔｂｏｏｋ　ｏｆ　Ｏｒｇａｎｉｃ　Ｃｈｅｍｉｓｔｒｙ、　ｐ、４８６．　Ｗｉｌｅｙ、　Ｎｅｗ　Ｙｏｒｋ（１９６７）に記載されている。式（Ｘｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ、Ｘ　、Ｙ　、Ｙ　及びＹ４９は前記と同義で３５、２１　４５　４６ある。反応条件も含めた複素環式置換１，３．５−トリアジン類を製造するための上記した一般的な反応及び中間体の製造は、上記した式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似２４０（１９５８）並びに英国特許９０８．３５２に記載されている。式（ｘｉｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得６゜上記式中、Ｒ３□、Ｒ３８，Ｂ１４及びＹ４７は前記と同義である。Ｂｅｒ、、２４　、４９５（１８９１）、　Ａｄｅｍｂｒｉ、　Ｇ、及びＴｅｄｅｓｃｈ、ｉ、　Ｐ、、Ｂｕｌｌ。Ｊ、　Ｂ、ら、Ｊ、　Ｈｅｄ、　Ｃｈｅｗ、、　２０．　（７）、　９３４−９３９（１９７７）に記載されている。式（ｘｉｖ）の新規な窒素含有複素環化合物は、次の一般的な反′応式に従って製造され得る。般的な反応及び中間体の製造は、’Ｐａｈａｎａｙａｋ、　Ｂ、　Ｋ、、　Ｊ、　Ｉｎｄ。に記載されている。式（ｘｉｖ）の新規な化合物を製造するための他の方法は、Ｔｒｉｐａｔｈｉ、　Ｈ，ら、Ａｇｒｉｃ、　Ｂｉｏｌ、　ＣｈｅＩｌｌ、、　３７．１３７５（１９７３）並　び　にｙｏｕｎｇ、　Ｔ、　Ｅ、及びＡｍ５ｔｕｔｚ、　Ｅ、　Ｄ、、　Ｊ、、　Ａｍｂｅｒ。Ｃｈｅｍ、　Ｓｏｃ、　７３．４７７３−４７７５（１９５１）に記載されている。式（ＸＶ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。般的な反応及び中間体の製造は、５ｅｌｉａ＋、　Ｈ，及びＳｅ１１ｍ、　Ｈ。Ｂｕｌｌ、　Ｓｏｃ、　ＣｈｉＩｌ、　Ｆｒａｎｃｅ、　１２１９−１２２０（１９６７）に記載されている。式（ｘｖｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。反応式１６上記式中、Ｒ４１，Ｒ４□−”’１５及びＹ４９は前記と同義である。反応条件も含めた置換１，３．４−アゾール類を製造するための上記量体は英国特許９１３，９１０に記載されている。式（ＸＶ＋＋）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ４５，Ｒ４６−Ｒ４７’　Ｒ４８’　８１６及びＹ４８は前記と同義である。反応条件も含めた置換ベンゾアゾール類を製造するための上記した一般的な反応及び中間体の製造はＨｕｇｅｒｓｈｏｆｒＡ、、　Ｃｈｅｗ、　Ｂｅｒ、、　３６．３１２１−３１３４（１９０３）並びにＹｏｕｎｇ、　Ｔ、　Ｅ、及びＡｍ５ｔｕｒｚ、　Ｅ、Ｄ、、　Ｊ、　Ａｗｅｒ、　Ｃｈｅｌｌ、　Ｓｏｃ、、　７３．４７７３−４７７５（１９５１）に記載されている。式（ｘｖｉｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ４５，Ｒ４６，Ｒ４□、Ｒ４８，８１６及びＹ４８は前記と同義である。反応条件も含めた１換ベンゾイソオキサゾール類を製造するための上記した一般的な反応及び中間体の製造は、Ｃｏｍｐｒｅｈｅｎｓｉｖｅ　Ｈｅｔｅｒｏｃｙｃｌｉｃ　Ｃｈｅｍｉｓｔｒｙ、　Ｖｏｗ、　１６．　ｐ、　５８゜Ｐｅｒｇａｍｏｎ　Ｐｒｅｓｓ、　Ｎｅｗ　Ｙｏｒｋ（１９８４）に記載されている。式（ＸｉＸ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ５ｏ、Ｂ１□、“Ｙ５４．Ｙ５５及びＹ４８は前記と同義である。反応条件も含めた置換１，３．５−トリアジン類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似している。式（ｘｉｘ）の新規な化合物を製造するための他の方法は、Ｂｅｅｃｈ。Ｈ，Ｆ、、　Ｊ、　Ｃｈｅｗ、　Ｓｏｃ、、（Ｃ）、　４６６−４７２（１９６７）に記載されている。式（ＸＸ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ５１，８１ｇ、Ｂ１９”　５６”　５７及びＹ４９は前記と同義である。反応条件も含めた置換１，３．Ｓ−トリアジン類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ｖＨｉ）の化合物を製造するために使用される方法と類似している。式（ｘｘ　ｉ　）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｂ２ｏ、Ｙ５８．Ｙ５゜及びＹ４９は前記と同義である。式（ｘｘ　ｉ　ｉ　）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。 Reduce water loss from plants and to increase the income of Is there nitrogen? Elementary ring 1 One bean standing! Emperor 11 Hosooka Hikari 1 The present invention deals with transpirational water loss from plants. s-ture (1oss) and crop yield (crop, yield). Relating to the use of nitrogen-containing heterocyclic compounds to increase The present invention is further novel. The present invention also relates to nitrogen-containing heterocyclic compounds and methods for producing the same. 1 mame stand 11 Escape is a known physiological process such as the passage of water in the form of vapor from living tissues. It is a process. In the case of plant transpiration, absorption of aqueous nutrients by phreatic root threads and Promoting translocation. Stomata allow for the transfer of necessary gases between the plant tissue and the external air. Exchange becomes possible. Only about 1% of the total amount of water absorbed by plant roots is absorbed by plants. water is used for growth, and other water is released into the atmosphere by transpiration through the stomata of plants. It is believed that it will be released. Very low rates of transpiration in plants are necessary for the transport of nutrients and for normal plant growth. It turns out that it is necessary. If transpiration stops completely, plants will be damaged and die. Although it is likely that plants will is not expected to cause any harm. For example, see U, S, P, Nα4,094,845. I want to be illuminated. Reducing water loss through transpiration from plants is important for several reasons. especially , in areas with dry climates, the amount of irrigation water required is small, and during transplanting or loading or An environment where plants are prevented from suffering damage such as withering when the climate is extremely cold. The pressure of water below is suppressed. Water 5tress mentioned above occurs when the rate of transpiration exceeds the rate of water uptake by the plant. Water pressure affects plants It appears as the water level and turgor pressure decreases, causing signs such as withering, and eventually withering. It is even possible to reach ◆. Various methods have been developed to reduce transpiration water loss from plants. For example 11 ．． s, P, Nos, 4,094,845. 4,397,681. 3,890, 158°3. 847,641. 3,826,671. 3,676. 102. j , s39,373. 3,339,990. . 3. 199,944 and EP 73,760-8. from plants The above patent specifies succinic acid as being used to reduce water loss due to transpiration. Long chain ester of organic acid, polyisocyanate, liquid, 1? IJ terpenes, Ben Included are dylalkyl ammonium salts and the like. However, using this substance This reduces water loss through transpiration from plants, but many substances are lost during photosynthesis, respiration, and cellular processes. It had deleterious effects on other plant processes such as division. 2-chloro-4-edylamide to reduce water loss due to transpiration from plants. -6-Itupropylamino-s-triazine (atrazin) The use of e) is also described in the literature. For example, G. [1, Wills et al., Weeds 11:253-255 (196 3) and Jalu SC, Graham et al. 16:389-392 (t968). However, when atrazine is used as an anti-emission agent, it reduces the light of photosynthesis in plants. Required reactions, such as photosynthetic electron transport rt;) inhibition and phytotoxicity of plants. It is therefore an object of the present invention to reduce water loss due to transpiration from plants and thereby using a species of nitrogen-containing heterocyclic compound to make more effective use of moisture in the soil. Provide a method for using Another object of the invention is the nitrogen-containing heterocyclization of seeds to increase crop yields. A method of using the compound is provided. Yet another object of the present invention is to provide a novel nitrogen-containing complex An object of the present invention is to provide a ring compound and a method for producing the same. For the above purposes and other purposes The objectives will be clear to those skilled in the art from the following description. Le J and L J The present invention relates to a method for reducing water loss from plants. sufficient to reduce water loss from the plant surface without substantially inhibiting the electron transport of the plants. Effective amount formula:% formula% (In the formula, the definitions of R1, R2 and X are given below) . The present invention also relates to a method for increasing the yield of crops, in which the crop is charged with electricity for plant photosynthesis. (wherein R1, R2 and X are defined later) ). The present invention also relates to novel nitrogen-containing heterocyclic compounds and methods for producing the same. detailed description As mentioned above, the present invention provides that by using nitrogen-containing heterocyclic compounds of The present invention relates to a method for reducing water loss from plants and increasing crop yield. Specifically, the present invention reduces water loss due to transpiration from plants and increases crop yield. The method for increasing the amount of electron transport for plant photosynthesis on the surface of plants or crops is to substantially increase the Reduce water loss from the plant surface or increase crop yield without inhibiting an effective amount of the formula: R1 is a monocyclic aromatic or non-aromatic ring system; Aromatic or non-aromatic ring systems, polycyclic aromatic or non-aromatic ring systems and bridged ring systems a substituted or unsubstituted carbocyclic or heterocyclic ring system selected from The system may be saturated or unsaturated, and the permissible substituents (Z) may be the same or different. optionally one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonyl Rubonylalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkyl Kylthio, polyhaloalkenylthio, thiocyano, propargylthio, hydroxy Shiimino, alkoxyimino. trialkylsilyloxy, aryldialkylsilyloxy. Triarylsilyloxy, formamidino, alkylsulfamide, dialkyl Rusulfamide, Alfkinsulfonyl, Boliha O alkoxysulfonyl, Hydo Roxy, amino, aminocarbonyl, alkylaminocarbonyl Nyl, aminothiocarbonyl. Alkylaminothiocarbonyl. dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and Its derived salts 9 formamide, alkyl, alkoxy, polyhaloalkyl, polyhalogen loalkoxy, alkoxycarbonyl, @substituted amino (in which case permissible substitutions) The groups may be the same or different, and may be one or two propargyl, anyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloal Killthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkyls sulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkyl Caroalkyl luponylamino. trialkylsilyl, aryldialkylsilyl triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivatives Salt, alkoxycarbonylamino. alkylaminocarbonyloxylbonyl xy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkyl Quinyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloal Quinyloxy. Polyfluoroalkanol, cyanoalkylamino, semi-rubazonomedyl, a Rukoxycarbonyl hydrazotumethyl, alphoxycarbonyl hydrazotumethyl. bankruptcy or Unsubstituted aryloxyiminomethyl, hydrazotumethyl, substituted or unsubstituted aryl hydrazotumethyl, mono-, di- or polysaccharide Hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy Alkyl, aryloxy, aralkoxy, arylthio, aralkylthio , alkylthioalkyl, arylthioalkyl, arylsulfinyl, aryl lsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloa lekenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenyl Sulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryl Oxysulfonyl, propargyloxy, aroyl, heroacyl, polyhaloacyl aryl, aryloxycarbonyl, aminosulfonyl, aryloacyloxy, aryloxycarbonyl, Loyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ali lsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy Honyloxy, aroylamino, haloacylamino, alkoxynyloxy, Anato, isocybuto, isothiocyano, cycloalkylamino, trialkyl ammonium, arylamino, aryl(alkyl)amino, araalkyla mino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxya Mino, alkoxyamino, aryloxyamino, aryloxyimino, oxyamino So, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alco xyalkoxy, alkoxyalkenyl, cyanoalfoxy, cyfurusul *Nium, -X, -X, -X-R, -X-R3゜Y3R5, or R1 is a substituted heteroatom or a substituted carbon atom, or two or more carbon atoms or is a substituted or unsubstituted compound containing a combination of foreign atoms and the following permissible substituents: straight chain or branched chain, and the above 'R substituents Z) may be one or different; one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonyl Alkyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthio , polyhaloalkenylthio, thiocyano. Propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl Oxy, aryldialkylsilyloxy. Triarylsilyloxy, formamidino, alkylsulfamide, dialkyl Rusulfamide, alkoxysulfonyl, polyhaloalfoxysulfonyl, hydro Roxy, amino, amitsucarbonyl, aminothiocarbonyl, alkylaminothio Carbonyl 1. dialkylaminothiocarbonyl, nitro, cyano, hydro Cycarbonyl and its derivative salts, formamide, alkyl. Alkoxy, polyhaloalkyl, polyhaloalkokyl, alcoalkoxyalkyl alkyl, alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhalyl (roalkenyl), alkylthio, polyhaloalkylthio, alkylsulf Inil. Polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nyl, alkylsulfonylamino, al, kylcarbonylamino, polyhaloal Kylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivatives salts, phosphonic acids and their derivative salts, alkoxycarbonylamino, alkylamino Carbonyloxy, dialkylaminocarbonyloxy, alkenyl, polycarbonyloxy loalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloa alkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy. Podifluoroalkanol, cyanoalkylamino, semi-rubazonomethyl, alkanol alkoxycarbonylhydrazotumethyl, alkoxyiminomethyl, W! ! Younger and younger is unsubstituted aryloxyiminomethyl, hydrazotumethyl,! replaced or left unplaced aryl hydrazotumethyl, mono-, di- or polysaccharides and alkyl Nyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, arylthioalkyl, aryls Rufinyl, arylsulfonyl, haloalkylsulfinyl, haloalkyls ruphonyl, haloalkenyloxy, octoalkynyloxy, haloalkynylthio , haloalkenylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl Honyl, aryloxysulfonyl, propargyloxy, aroyl, herooxy polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alkyl aminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl, Carboxyalkoxy, carboxyalkylthio, alkoxycarbonylalco Oxy, acyloxy. Heroacyloxy, polyhaloacyloxy, aroyloxy. Alkylsulfonyloxy, alkenylsulfonyloxy, arylsulfonyl Oxy, halo°alkylsulfonyloxy, polyhaloalkylsulfonyloxy , aroylamino, heroadiisothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, araalky Ruamino, alkoxyalkylbosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxybosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, Al, ″]xyalkenyl. Cyanoalkoxy, dialkylsulfonyl l1. -X, -X. It is Y3R5, Ending with a covalent double bond, substituted or unsubstituted heteroatom, or substituted carbon atom , or two or more carbon atoms or heteroatoms and the following permissible substitutions: A substituted or unsubstituted straight chain or branched chain containing a combination of groups (Z), The substituents may be the same or different and contain one or more hydrogen, halogen, Alkylcarbonyl, alkylcarbonylalkyl. Alkoxycar, Bonylalkyl, Alkoxycarbonylalkylthio, Polyhalogen loalkenylthio, thiocyano, propargylthio, hydroxyimino, alco ximino, trialkylsilyloxy, aryldialkylsilyloxy, Realylsilyloxy, formamidino, alkylsulfamide, dialkyl Sulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydro xy, amino, aminocarbonyl, alkylaminocarbonyl, dialkylami Nocarbonyl9-aminothiocarbonyl, alkylaminothiocarbonylruamino Thiocarbonyl, nitro, cyano, hydroxycarbonyl and their dihydrogen salts. Hol Muamide, alkyl, alkoxy, 'polyhaloalkyl, polyhaloalkokyl, alkoxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) may contain one or more propargyl, alkoxyalkyl, alkyl Kylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalke ), alkylthio. Polyhaloalkylthio, alkylsulf, inyl, polyhaloalkylsulfini Alkylsulfonyl, Alkylsulfonyl, Boliha 0 Alkylsulfonyl, Alkylsulfonyl Mino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyh Roalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl , triarylsilyl, sulfonic acid and its derived salts, phosphones and their derived salts , alkoxycarbonylamino, alkylaminocarbonyloxy, dialkyl Aminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy . Alkynyl, alkynyloxy. Polyhaloalkenyloxy. polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semi-rubazonomethyl, alfoxyluponylhydrazo Nomedyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimide Nomethyl. hydrazotumethyl, substituted or unsubstituted arylhydrazotumethyl, mono-, Hydroxy group, haloalkyl, haloalkyl group condensed with di- or polysaccharide Kenyl, haloalkynyl. Alkoxyalkyl, aryloxy, araalkoxy, arylthio, araa Lukylthio, alkylthioalkyl, ary-haloalkylsulfinyl, haloar rukylsulfonyl, haloalkenyloxy, haloalkynyloxy, heoalkyl Nilthio. Haloalkenylsulfonyl, polyhaloalkenylsulfonyl. Alkoxysulfonyl, aryloxysulfonyl, pargyloxy, allo yl, heroacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl Nyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylami Nosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxyca Rubonylalkoxy, acyloxy, Yaguchi acyloxy, polyhenyl acyloxy , aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, Arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl Sulfonyloxy, aroylamino, heroacylamino, alcarbonyloxy Cycloalkylamino, trialkylammonium, arylamino, aryl (alkyl)amino, araalkylamino. Alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkoxyalkylphosphinyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, Alkoxyamino, aryloxyamino, aryloxyimino, oxo, thi Ono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxy Lukoxy, alkoxyalkenyl, cyanoalkoxy. dialkylsulfonium, -X, -X. -X-R3. -X-R3. It is Y3R5, R2 is a monocyclic aromatic liquid or a non-aromatic ring system. Bicyclic aromatic or non-aromatic ring systems ．． Substituted or unsubstituted polycyclic aromatic or non-aromatic ring systems and bridged ring systems. a heterocyclic ring system having at least one substituted nitrogen atom, said ring system being saturated; may be saturated or unsaturated, and the permissible substituents (Z) may be the same or different. one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonyl alkyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthi E, polyhaloaldialkylsilyloxy, triarylsilyloxy, form Amidino, alkyl sulfamide, dialkyl sulfamide. Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, and cyamic hydroxyl derivative salts. hohaloalufuki cy, alkoxycarbonyl, substituted amino (here alkyl, alkyl, alkenyl) (alkenyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhalo Alkylthio. Honylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino , polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkyl lucilyl, triaryldialkoxycarbonylamino, alkylaminocarbo Nyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalke Nyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyl Oxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkali Nol, cyanoalkylamino, semicarbazonomethyl, alfoxycarboni 1 Ruhydrazonomethyl, alco-substituted young minomethyl. Substituted or unsubstituted aryl Oximinomethyl, hydrazotumethyl, substituted or unsubstituted arylhydra Hydroxy group condensed with zotumethyl, mono-, di- or polysaccharide. C Roarkil. Haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, ara alkoxy, arylthio, araalkylthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyls Rufinil, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy. Haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl. Aryloxysulfonyl, propargyloxy, aroyl. Haloacyl, polyoctaloacyl, aryloxycarbonyl, althio, alkoxy Cycarbonyl alkoxy, acyloxy, herooacyloxy, polyoctoacyloxy xy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy cy, arylsulfonyloxy, octoalkylsulfonyloxy, polyhaloal Kylsulfonyloxy, aroylamino, heroacylamino, alkoxycarbo Nyloxy, arylsulfonylarathiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl(alkyl)amino, ara Lucylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphine Nothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydro Roxyamino, alkoxyamino, aryloxyamino, aryloxyimine No, oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Rusulfonium, -X, =X. Y3R5 and R3 is a substituent selected from monocyclic aromatic or non-aromatic ring systems, bicyclic aromatic or non-aromatic ring systems, polycyclic aromatic or non-aromatic ring systems and bridged ring systems. or an unsubstituted carbocyclic or heterocyclic ring system, wherein said ring system may be saturated or unsaturated, and the permissible substitutions W (Z) may be the same or different and include one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alco Oxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalke Nilthio, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino of. Haloalkoxysulfonyl, hydroxy, amino, aminocarbonyl, alkyl aminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkyl Kylaminothiocarbonyl. dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbo) Formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (in which case the permissible substituents may be the same or different), 1 or 2g x 1 axis of propargyl, alkoxyalkyl, , alkylthioalkyl, alkyl, aldanyl, haloalkenyl or is polyhaloalkenyl), alkylthio, polyhaloalkylbouo, alkylthio Rusulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhal loalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, Realkylsilyl, aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkylaminocarbonyloxy, Nyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazotumethyl, alkoxyimino Methyl, substituted or is unsubstituted aryloxyiminomethyl, hydrazotumedel. replaced or left unplaced aryl hydrazotumethyl, mono-, di- or polysaccharide Hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy alkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl, aryl lsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloa alkenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenyl sulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyloxy, aroyl, heroacyl, polyoctaloacyl aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylbonylalkoxy, acyloxy, heroacyloxy, polyoctaloacyloxy, aroyl, oxy, alkylsulfonyl Nyloxy, alkenylsulfonyloxy, arylsulfonyloxy. Haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroyl Amino, acylamino, alkoxycaroxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylammonium, aryl Ruamino. Aryl(alkyl)amino, araalkylamino, alkoxyalkylphosph alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, alkoxyalkylphosphinothioyl Nil, dialkoxybosphino, hydroxyamino, alkoxyamino, ary oxyamino, aryloxyimino, oxo, thiono, alkylaminoal koxy, dialkylaminoalkoxy, alkoxyalkoxy, alkoxyal kenyl, cyanoalkoxy, dialkylsulfonium, -X, -X, -X-R3, -X-R3゜Y3R5, or R3 is M-replaced heteroatom or substituted carbon atom, or 2 or more carbon atoms or is a heteroatom and the following permissible substituents (Z) more than hydrogen, halogen, alkyl carbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, Rukoxycarbonylalkylthio, polyhaloalganylthio, thiocyano, p[ ]/margylthio, hydroxyimino, alkoxyimino. trialkylsilyloxy, aryldialkylsilyloxy. Triarylsilyloxy, formamidino, alkylsulfamide, dialkyl Rusulfamide, alkoxysulfonyl, porbonyl, alkylaminocarbonyl , dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothio carbonyl, dialkylaminothiocarbonyl, nitro, cyano, human oxygen rubonyl and its derivative salts, formamide, alkyl. Alkoxy, polyhaloalkyl, polyhaloalkokyl, alkoxycarbonyl, substituted amino (in which case the permissible substituents may be the same or different, one or more is 2$SJj! = propargyl. Alkoxyalkyl, alkylthioalkyl, alkyl, alkenyl, haloal kenyl or polyhaloalkenyl), alkylthio, polyhaloalkylthio, alkylsulfinyl. Polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl Rusulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminoca Rubonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloa alkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalke Nyloxy, polyhaloalkynyl. Polyhaloalkynyloxy. Polyfluoroalkanol, cyanoalkylamino, semi-rubazonomethyl, alkoxycarbonylhydrazotumethyl, alkoxyiminomethyl, N-operated or unsubstituted aryloxyiminomethyl, hydrazotumethyl, W-substituted or unsubstituted arylhydrazotumethyl, mono-, di- or polysaccharides. condensed Hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy alkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl, aryl lsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloa lekenyloxy, haloalkynyloxy. Haloalkynylthio, haloalkenyl sulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryl oxysulfonyl, propargyloxy, aroyl, heroacyl, polyhalo Z sulfonyl , aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxyalco xy, carboxyalkylsulfonylo', xy, alkenylsulfonyloxy cy, arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloal Kylsulfinyloxy, aroylamino, heroacylamino, alkoxylic Bonyloxy, arylsulfnylamino, aminocarbonyloxy, cyanato, isocyanate. isothiocyano, cycloalkylamino, trialkylammoalkylamino, al-fukidialkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, aryloxyamino, aryloxy Imino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxy alkoxy, alkoxyalkenyl. Cyanoalkoxy, dialkylsulfonium, -X, mX. -X-R3, -X-R3゜Y3R5, Y and Y4 are oxygen or sulfur, respectively, and Y2 and Y3 are oxygen, sulfur, amino, respectively. or a covalent bond, and R4 and R5 are hydrogen, substituted or unsubstituted alkyl, respectively. Le. polyhaloalkyl, phenyl or benzyl, in which the permissible substituents (2) may be the same or different and contain one or more hydrogen, halogen, alkyl radicals; Rubonyl, alkylcarbonylalkyl, alkoxycarbonylalkylbonyl alkylthio, polyhaloalkenylthio, thiocyano. ゛Propargylthio, hydroxyimino, alkoxyimino, trialkyl silicate silyloxy, aryldialkylsilyloxy. Triarylsilyloxy, formamidino, alkylsulfamide, dialkyl Rusulfamide, alfkidisulfonyl, polyhaloalkoxysulfonyl. Hido Roxy, amino, aminocarbonyl, alkylaminocarpol, dialkylua Minocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl. dialkylaminothiocarbonyl, nitro, cyanogen, hydroxy, polyhaloa alkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (permissible in this case) The permissible substituents may be the same or different and may include one or more substituents such as propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alkyl, nyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhalyl Loalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfinyl Kyl, sulfonyl, polyhaloalkylsulfonyl, alkylcarbonylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhalo thermosensitive, phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminoca Rubonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloa alkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalke Nyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkynyl Lukanol, cyanoalkylamino, semi-rubazonomethyl, alkoxycarbo Nylhydrazotumethylximinomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazotumethyl, substituted or unsubstituted aryloxyiminomethyl xy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkyl ruthioalkynyl, haloalkenyloxy, haloalkynyloxy, haloalky Nylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, alco xysulfonyl, aryloxysulfonyl, pargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alhaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyl rusulfonyloxy, arylsulfonyloxyhaloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino, heroacylamino, arylsulfonyloxy, Lukoxycaroxy, cyanato, isocyanato, isothiocyano, cycloalkyl Ruamino, trialkylammonium, arylamino. Aryl(alkyl)amino, aralkylamine, alkoxyalkylphosph alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, alkoxyalkylphosphinothioyl Nyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, ary oxyamino, aryloxyimino, oxo, thiono, alkylaminoal koxy, dialkylaminoalkoxy, alkoxyalkoxy, alkoxyal Kenyl, cyanoalkoxy, dialkylsulfonium, -X, -X. -X-R3 ．． -X-R3. Y3R5) It consists of applying a compound of. The alkyl-containing moieties described above contain about 1 to 100 or more carbon atoms. , preferably about 1 to 30 carbon atoms, more preferably about 1 to 20 carbon atoms. Po The saccharide moiety contains up to about 50 carbon atoms. Compounds encompassed by formula 1 are all compounds with no unfitted bonding positions. I hope you understand that. Permissible Substituent Fields for Compounds Included in Formula 1 The valency of the synthetic substituent must be appropriate for the binding capacity of the particular carbon atom or foreign atom. I hope you understand that. Monocyclic ring systems included in R and R3 of formula 1 systems) is represented by the following general formula 2. In the above formula, B is a saturated or unsaturated carbon atom, and A1 and B1 together are 0 A ring system with ~4 double bonds or 0 to 2 triple bonds (cyclic 5ys ring-forming chain of atoms forming te+e) ). A1 may contain 2 to 12 carbon atoms (, 1 to 11 carbon atoms). Select from atoms and N, O, S, P or other heteroatols may contain 1 to 44 heteroatoms, and 40 ring-forming heteroatoms. May contain. The monocyclic ring system encompassed by R2° in formula 1 has at least one nitrogen atom. It is a monocyclic ring system of R and R3. Ring-forming heteroatoms include aromatic and aliphatic N-oxides, sulfinyl, sulfol; pixel elements, such as in the case of ring systems containing selenium oxide and phosphine oxyto moieties. It may also carry a child. Characteristics contained in the ring formed by B and A1 containing three or more ring-forming atoms carbonyl, thiocarbonyl, v1-substituted or unsubstituted imino group or may carry an unsubstituted methylidene group. The group denoted by Z is selected from a number of substituent groups defined for 2 One or more substituents. B1 and in911Qllbllllrs) When used, it must be a saturated carbocycle, i.e. cyclopropyl. Must be. If the ring formed by B and A1 contains 5 or less ring members and must not contain more than one glue atom. Examples of the monocyclic ring MIJ″lt1 included in R and R3 of Formula 1 include the following: be done. In addition, Z in the formula has the same meaning as above. The bicyclic system encompassed by R1 and R3 in Formula 1 is represented by the following general formulas 3 and 4. . In the above formula, B2 and B3 are saturated or unsaturated carbon atoms or saturated nitrogen atoms, respectively. , A and A3 are respectively ring-forming chains of atoms shown below, and 2 is defined for 2. 1 g or more substituents each selected from the above substituent groups. A2 and The combination of A3 may include 0 to 5 double bonds in combination with 82 or B3. A 2 and A3 may contain 1 to 11 g of carbon atoms separately from B2 or B3. N, ○ with 1 to 10 carbon atoms. May contain 1 to 3 heteroatoms selected from S, P or other heteroatoms , may contain 1 to 3 ring-forming heteroatoms. Ring-forming heteroatoms include aromatic and aliphatic N-oxides, sulfinyl, sulfonyl, an oxygen atom, as in ring systems containing selenium oxide and phosphine oxyto groups; It may be carried. Specific carbon atoms contained in A and A3 is carbonyl. thiocarbonyl, l or non-I isoimino group, or I-ground or non-I role methylide It may also carry a linkage group. The bicyclic ring system encompassed by R2 in formula 1 is R having at least one nitrogen atom. and R3 bicyclic ring systems. Regarding the structures encompassed by Formulas 3 and 4, note the following. (a) When B and B are both nitrogen atoms, each of A2 and A3 contains There must be no fewer than 3 ring atoms. (b) When B2 is a nitrogen atom instead of B3, one of A2 and A3 is at least also contains 3 ring atoms and the other contains at least 2 ring atoms. (C) When one of the groups A and A3 contains fewer than 3 l-ring atoms, the other contain at least three ring atoms and have a bridgehead ato ms) Atoms must be saturated. (d) MA or A3 is carbonyl, diocarbonyl, imino or methylidene When containing supported carbon atoms, together with B2 and B3 at least 4 members must form a ring with . (e) cyclic (annu far) double bond between two rings represented by formulas 3 and 4; When it is exocyc Iic, at least in a ring containing at least 5 members, and when bonded to a ring containing at least 5 members; means that group A or A3 contains one double bond and the bridge terminal atom is unsaturated. I want to be understood. The bicyclic ring system defined for R1 and R3 may be a spirocyclic ring system, Not limited to fused bicyclic structures of formulas 3 and 4. spirocyclic ring system clic ring 5ystea+s) is a saturated or unsaturated carbocyclic or A bicyclic ring which may be heterocyclic and is included in one or R1 and R3 of formula 1 as described above. Examples of structures include: The polycyclic ring system of two or more rings included in R and R2 of Formula 1 is represented by the following general formula 5. 6. 7th grade and 8. In the above formula, B4. B5. B6 and B7. are 0 with saturated or unsaturated atoms respectively A ring-forming chain of atoms that may contain ~2 double bonds. Group 2 is defined for Z one or more substituents selected from among the substituent groups listed above. A4. A5. The ring-forming elements of A6 and A7 are B4. Separate from B5, 86 and B1 may contain 1 to 11 carbon atoms, and together with 1 to 10 carbon atoms, N, Even if it contains 1 to 3 different atoms selected from O, S, P or other different atoms Furthermore, it may contain 1 to 3 different atoms. The ring-forming heteroatom is aromatic N-oxy Sid, sulfinyl, sulfonyl, selenium oxide and phosphine oxyto groups It may also carry an oxygen atom, as in the case of containing ring systems. Eighty is sometimes a combination It can be defined as follows. A4, A5. The specific carbon atom contained in A6 and A7 is 1 One or more carbonyl, thiocarbonyl, ffi-converted or unconverted imino It may also carry a group. With respect to structural formula 8, groups B, B9 and B1° are each a saturated or unsaturated carbon atom or is a saturated nitrogen atom. Group 811 is a saturated or unsaturated carbon atom, a nitrogen atom, or It is a phosphorus atom. A8゜A and A are of the groups B, B, B and B11 It is a ring-forming chain of atoms that may contain a double bond of 1g and (-0 to 2gfA). A8. , A, and A10 are ring-forming elements B8. B9. Blo and selected one Ring systems containing 2 to 3 inoxide groups, which may contain ~3 heteroatoms It may carry an oxygen atom or an unsubstituted imino group as in the case of . The polycyclic ring system defined for R and R3 may be a spirocyclic ring system, Equations 5 and 6. It is not driven by the fused polycyclic grooves of 7 and 8. Spirocyclic ring systems are saturated young or unsaturated carbocyclic or heterocyclic, containing one or more of the above-mentioned substituents. It may be replaced with WZ. “The polycyclic ring system included in R2 of Formula 1 has at least one nitrogen atom. Polycyclic ring systems of R and R3 are included. Examples of polycyclic rings included in R and R3 of Formula 1 include the following. The bridged bicyclic ring structure included in R1 and R3 of Formula 1 is represented by the following general formula 9. 10 and 1 It is represented by 1. atoms or nitrogen atoms, and groups A, A, and A are B12 and A, 1. A12 and the ring-forming element of A13 has 1 to 11 carbon atoms separately from B12 and B13. may contain 1 to 10 carbon atoms as well as N, O, S, P or other May contain 1 to 3m heteroatoms selected from heteroatoms, 1 to 3 heteroatoms May contain. However, one of the groups A, A, and A13 is not a single group. A11. A12 and A13 must contain at least two saturated ring-forming atoms. Must be. Ring-forming heteroatoms include sulfinyl, sulfonyl, selenium oxide, and phosphine. It may also carry an oxygen atom as in the case of an oxyto moiety. A11. A12 and One or more specific carbon atoms contained in A13 are carbonyl, thiocarboxylic may carry a substituted or unsubstituted imino group. The bridged bicyclic ring system encompassed by R2 in Formula 1 has at least one nitrogen atom. R and bridged bicyclic ring systems of R are included. Examples of bridged bicyclic ring structures included in R1 and R3 of Formula 1 include the following: Ru. Saturated or straight carbon chains containing both carbon atoms and heteroatoms is an unsaturated branched chain or a straight chain; It may be a different atom. Certain heteroatoms of X include sulfonyl, sulfinyl, N-oxide and phosphine. It may also carry an oxygen atom, as in the case of groups containing an oxyto moiety. X's Even if a particular heteroatomic component carries one or more substituents Z as described above, good. The specific carbon atom related to X is carbonyl, thiocarbonyl, substituted or unsubstituted imino, substituted or unsubstituted alkylidene or one or more as mentioned above The above substituent Z may be supported. Examples of structures encompassed by substituent X include the following. In the above formula, m is a value of 0 to 8, n is a value of 0 to 2, and R8, R9, R1° and R11 are hydrogen, substituted or unsubstituted alkyl, polyhaloalkyl, or benzyl, and the permissible substituents here are It is. It will be readily appreciated that Formula 1 encompasses a wide range of nitrogen-containing heterosnow compounds. Plant Used to reduce water loss due to transpiration from plants and increase crop yields. Nitrogen coating within the range of formula 1 to obtain 1 4-CI　OCj　CI 4-F OCJI CI 2. 4-C Crow OCt CI 4-cH, OCJ CJI 4-CH300Ct CI 3. 4-CJI, OCI CI 2, 3-Cnox OC1l C1 2,5-CI2 0 CJI CI 3-CI OCt CI □ 2- Cj OCI CI 3, 5-Cnox OCI CI 4 - CF, OCt CI 4 - CaHsO-' OCj CI2 - NO, OCI CI 3-Not　OCj　CJ 4 - No, OC, t CI 2, 4-Ct, Oct OCH3 Table 1 (continued) 3-CN OCI CI 4-CI OFR 4-CN　OCt　CI 2. 6-CI, OCt CI 4-Co, CH, OCt C□ 4-　CH2Co, CH, OCt　CI4-　C,) et al. Co　-OCt　CI 4-CH,Co-OCtCI 2, 3. 4. 5-CI, OCI CI2, 3. 4. 5. 6-C I, OCt CI4-(CHl), Coct CI 4-CH, S-OCjl CI 4-(C,H,), C-oc-CI, 3. 4-OCR20-OCI CI 3-CH,C0NH-OCJI C7l3-CH,O-OCI CI 4-　C,)-〇)-〇-OCt　C1 Table 1 (continued) 4-(C,H,CH(CH,)O-) OCt CI3, 4. 5-(CHl )m　OCj　CI3,　5”(CH,),-4-Br　OCj　CI2-Br -4-Cj OCj C1゜ 4-0=CH-OCt CI 4-n-C4HgO-OCI CI 4-n-CyHtso-OCtCI4-Cj-5,6-(C) et al.) 4- OCt CI3- (CHl), N-OCt CI 4- (-N to CI = N-) OCt CI2, 4-CJI-6-COOH O (J C14-CaHa OCt C) 3-F OCj CI 2, 4-Cj, OBr Br Table 1 (continued) Tsutsumi, facing −≦12 da also b8 and other wasibu te de) −゛　ocノ　CI2-CH50-4 -7 Lil OCI CI2, 4-CI, OCCH. 2, 4-CJ, OBr O(. 3i4-(CH=CH-CH=CH)-0cJ2Cノ2. 3- (CHJi-O CI　C) 2, 3-(CH,)4-4-Cjt OCI CI2. 3-(CH=C1(- CH=CH)-0CI CI2. 3-(CH=CH-CH=CH)-4-Cno 〇C! CI2. 3-(CH=CH-a-i=CH)-4-CH30o cノ CI2. 6-CI, S Ctt CI 4-CH, S Cjt CI 2, 4-CI2 S CI 01 Table 1 (continued) 4-C no 2-CH(CH,)C,H,OCt CI2-CH3-4-(4-C )− 2-BrCsH40)-5-CJl NHCJ CI4-No, NHBr B r Table 1 (continued) 3-n-04) LIOQ CJ CJ゛3-C,H,-CH,O-OCt CI4- (4-(CsHsCHzO)-() ctt ctC, I(, CH, 03- 2-13r　OCt　C) 2-CH, 0-4-CHOOCjt CI2, 3(CH,), -NHCI Cjt2, 3-O-C(CH3)! 0-OCjt CI3-CH,=CH CH, O-0' CI CI3-CICH2CH2O-OCz CI3-CH, SO, -0-OCt CI 2-CH,0-OCjt CI 2-n-CyHl, O-OCI C1 Table 1 (continued)゛ 2-C,H,CH,0-OCt CI 2-n-C,P-〇-4-Br　OC2Cjt2-　i　-C,H70-3- CJ　OCt　CI2-C,H3SO2-0-OCjt　C1z-BrCH,C H2-OCt ct 2-CH,=C(CH,)CH,-OCJ C7 Table 1 (continued) 4-HOOCI CI 3-HOOCI CI 2-) (00C) CI 4-(i-CaH2)-0' CJ C□3-C2H, -OCt CI 3-(CHl), C-OCI CI 2-n-04F et al-OCJ Cjl 22-5ee-C4H-OCjl CI2-CJ -4-n-C1H70CJ Cjl2-C,H,-4-Br　OCjl　CI3,3-(CH=CH-CH= CH) - Table 1 (continued) Table 1 (continued) 4-n-C4HgS -0' CI CI2-i -C,H,S-OCtC I3-n-C7H,, S-OCJ CI 4-HC=CCH,0-OCt CI 3-HC=CCH, O-OCt CI 2-HCCICH, O-OCI CI 4-(C,H,SCH,O)-0Ct CI3- (C,H,SCH,O)-0 Ct CI2- (C, H, SCH, O)-0Ct Cr Table 1 (continued) Representative nitrogen-containing heterocyclic compounds 3. 5-(CH,O), OCjl CI3, 5-(C,H,CH,O), OCt CI3. 5-(CHsCo,), OCJ C112, 6-(QHs O) * OCt CI2-C, H, -OCjl CI 3-C,H,-OCt CI 3-C,H,-00Ct CI 2-C no 4-Br　OCj　CI 2-Cj-4-F OCI CI 2. 4-F, OCjl CJt Table 1 (continued) 2-F-4-C No □ Ct CJ 2-NO, -3-02H, NHCJ CJ2, 4-(NO2)2 NHCjl , C-2, 3. 4-CJ, NHCJ F 2-CH, 0-CH, -NHF　F 3-(4-C No C, H40) NHF F2, 3-(CH,5O2), N HCJ CJ4-(2-Ci-4-BrC, H4) NHCt C1z2-C -4-n-C, H3O-OCJ CJ2 Table 1 (continued) Representative nitrogen-containing heterocyclic compounds Y′2 4=(cp-c6H4-so2-o-> o C,z Cjl Table 1 (continued) 3-CH, CO-OCJ CJ 2-Br73-n-C4I (eO-OCJ C)2-CH,0-4-(CH,) 3C-OCj　CJ4-C,H,CH=CHC0-OCJ　Cjl2, 6-C J, -4-No2　0　Ct　CJ4-CONH,OCjl　CJ 3- C, H, NHCO-OF 4-　C0NHNH,OCJ　Ct 4-CH=C(CN), OCt Ct Table 1 (continued) 2-CH, O-400 no C no CH,C(NO,)=CH- 4-CH, So□ocノCJ 2-CH,-4-Cjl-OCjl CJ2-CH,Cjl-4-NO20 CJ　CJ2-CtHg-4-No2　0　Cjl　Cjl4-No,　S　C J　CJ 4- (CH,), C-S CJ CJ2. 4-CJ, -5-CH,, S CJ CJ2, 3 (CH=CH-CH=CH)-S C7Ct4-csH8O- S　CJ　CJ 2, 4-CJ2 S F F 2. 4-CJ2 S Br Br 3. 5-Cjl2 S Ct Ct 3-C, H, O-S F I 2. 4-CJ, OFF 2, 4-CJ2 0 Br Br Table 1 (continued) 3. 5-CJ2 0 CJ CJ 3-C,H,O-OF'l 3-(4-C No C, H, Co-) S (J C) 2-No, S CJ C J 3-(4-C no C, H, Co-) OCj! CJ2-NO□’ocノ C.J. 3-CsHxsO-S -CJ CJ 2, 3. 5-(C,H,),-S C1,01 Table 1 (continued) 4-(H,N-C0CH,-)　OCJ　CJ4-C02(CH2),,CH3 0CJ Cs4-(H2NC-NH-) OCJ Cno2. 4-Cj! , -5- CH, OCj　CJ2-CNo4-NO□　OCt　CJ 2-CH20H-4-Cj NHci CJ2-CH2OCH3NHCJ CJ 2-CH, Co-4-CJ NHCJ CJ2-C, Hs OCj 01 Table 1 (continued) Representative nitrogen-containing heterocyclic compounds Table 1 (continued) Table 1 (continued) O Table 1 (continued) Table 2 (continued) 2. 4-C, tt, -OCj P (=O) (OC2Hs) i2, 4-Cj2 　0　0ノ　OCH, CF. 2, 4-Cj, OCj! CN 2. 4-Cj! 2　0　Cj　SCM. HOCj CCノ. 2. 4-Cj! 2　0　CJL　CH3CO-2,4-Cj2　0　Cj　CH 3C0CH, -2, 4-Cj, QCノCF. 2, 4-Cj, OCt CH35o. 2, 4-Cj, QCノ-5CEN2, 4-C1z OCj H Table 2 (continued) 3-No, OCj H 2,4-Cj,　OCj　-(,:CH2,4-Cj2　0　C)　-CH=C H. 3-No, OCj-C:CH 2,4-C12'oF-C-1:CH2,4-cj! OCt CHF. 2, 4-Cj, OCj! '　C0NH. 2, 4-Cj, OCj, CH, CO□C, H. 2, 4-Ct, OF-N(CHl)! 2. 4-Cj! ,　OCj　-P (=O) (QC, H,). 2, 4-Cj, OCj-〇CCN2-CHl-4(2-Br-NHC,C . 4-C)-〇, H30) 2-Cj NHCt CN 2, 4-Cj, QCノ-P(=O)(oc,)(,)z Table 2 (continued) 2, 4-Cj, NHCt CN 2, 4-Cj, OF CH1 3'-C, H, O-0, F' C, H. 3-No, NHF CH. 3- (n-CsHls)-0Ct CN table 2 (continued) Representative nitrogen-containing heterocyclic compounds Table 2 (continued) Table 2 (continued) 2, 3- (CH=CHCH=CH)' OCJ OCH, CF32. 4- CJ2 OCノ C2H3O Representative nitrogen-containing heterocyclic compounds 2, 4-C Crow OCN CH3 2,4-CJ2　0CNH 2, 4-C Crow ONo, H 2, 4-CJ, OC0G (, C) H2, 4-CJ2 0 CN CN 4-　C,H,000CH,CF,0CR20F34-CJ゛　0　00(2C F, 0CR2CF. 4-Br' S OCF, OCF. 2. 3-(CH=CH-CH=CH)-S CC, CC. 3. 4- (CH2) 4 0 CF3 CF! 3, 5-CJ2 0 0 SO2 CH30SO2CH33-NO□ 00SO2CF, 08O2CF. 3-C,H2CO' NH0802CF, 080. CF33,4-(CH=C H-CH=CH)-00SO,CH3c,M. 4-CH, S OCN 0802CH. 4 + C, H, NH0COCH, 0COCH. 3, 4-Cノ20SO2CH1S02CH3X1-　''　　---- J to I yuko koko = ko to ko ni ■uu -X　OOOOOOOOOOOOOOOOOOeE '　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　 to Matoe ni 3 (Tomiko Eko Koko Ee 8 Kaku Zo1. a, E:l:Ef. lfl:eEE:eEk-16Ek-16I, 55,555I II River E*:e: c engineering; 155H5555 Yueeeyoe J3 Anatomy Worker:! : 0: ni construction construction; Work r1 Eeeee work gogogogo 8 work 8eeee work gogogoji l0IIωCIOca COc o ca coωI 0=ωzut; ni===yuukaiwara22=e Ma181===3-works; straw rig demand For Q - CfJ Ox ω 0 stomach ri η 0 exposure o o sardine. cacacacow O'O'O'5 River Gomi Koko 33 , Ol　1'1 ＞　UuuUQul-+t-+uut-'C, +u□ CJ Mi a888"e38 −． 38δ888 8;+=’=g=ggg==== ζtom8 kogogo88 toma. -0° Gushi oagiggg8g8g zo+: work i-e 1 work; 1-・・-・−〜−−−−−〜・−−zulOOOOOO100OOOOOOOOe 4’coCQcocot. S■=Senkou: I: Koumi Koukou l (Kobu Kou ee Koukou 1000 g: Kai Kai Kou Koukou 3. 　E　E匡 Kokokoego -H', OOOOOOOOOOOOOOOOOOOOO;l:I:=Work=Work0:Work; = Eeeee Table 7 Representative nitrogen-containing heterocyclic compounds HHHHHI　Co　H HHC1HHI Co H CL　HC1HHI　Co　H HCL CL HHI Co H HCL　HHHI　Co　H , HBr　HHHI　Co　H HHBr　HHI　Co　H HF　F　HHI　Co　H HHI　HHI　Co　H F　HC1HHI　Co　H HHCH3HHI Co H HCH3HHHI Co H CH3HHHHI　Co　H HH Tamapropitsure HHI Co H HHL-Cal HHI Co H OCH3HHHHI C0H H0CH3HHHI Co H HHCCH3HHI Co H Table 7 (continued) HCF3I (HHI C0H HHCF3 HHI Co H HOCF3HHHI C0H HH0CF3HHI CoH HH0CF2HHHI CoH HH0CF2C1HHI CoH HNO2HHHI C0H HHNo2HHI CoH HCNHHHHI C0H HHCN　HHI　Co　H HH5o2CH3HHI Co H HHSo□KCH3)2HHI Co HHH5CH3HHI Co H HHHHHI Co CH3 I HC1HHI Co CH2 Cl　RCL　HHI　C0CH5 HHCH3I HI Co CH3 I H00 (3HHI Co cI (3 Table 7 (continued) HNo2HHHI Co CH3 I CN HHHI Co CH3 I HCF3 HHI Co CH3 IHHHHOC0CH5 HHct HHOCOCH3 C1HctHHO-C0CH5 HCtHHHO-C0CH5 HH0CH3HHO-C0CH5 HH’CH3HHO-C0CH5 HH5CH3HHOC0CH5 HHCF3 HHO-C0CH5 HH0CF2HHHO-C0CH5 HH0CF2CL　HHO-C0CH5HNo2HHHO-C0CH5 HCN　HHHO-C0CH5 HHHHHO-C0CF5 CL　HCL　HHO-C0CF3 Table 7 (continued) Representative nitrogen-containing heterocyclic compounds HHHHHHIC8H C1HCL HHI C3H HHH’HHI 5o2H HHCL HHI 5o2H CL　HC1HHI　5o2H CO2CH3HHHH’ 1 5o2HHHCH3HHI SO2H HH0CH3HH15o2H H0CH3HHHI So□H No2HHHHI So□H HCN HHH15o2H HHCF3HHI 5o2H HHHHHO5O2CH3 HHCL　HHO5O2CH3 C4HCL　HHO5O2CH3 HHCH3I HO5O2CH3 HH0CH3HHO5O2CH3 HHCF3HHO5o2CH3 Table 7 (continued) HCN　HHHO-5O2CH3 HHNO2H, HO-5O2CH3 HHHHHO-5o2CF3 Table 8 HHHHH HHCL　HH Cl　HCL　HH HCL HHH HCL CL HH HHBr　HH HHF HH HHCF3HH HHCH3I H H0CR3HHH HHOCH3HH HHEr:H3HH H,NO2HHH HHNo2HH HCN HHH Table 8 (continued) HH5O2CH3HH HHN (C turtle)z HH H, HC02CH3HH OHHHCH3I Table 9 HHC1HHNHOH CL　HCL　HHNHOH HHCH3HHNH’OH HH0CH3HHNHOH HHCF3HHNHOH HH5CH3HHNHOH HHsoz,cH3HHNHOH HHHHHNHS H ct　HC1HHNHS　H HHHHHHOOH CL　HCL　HHOOH HHCH3I HOOH HHOCH3HHOOH HHCF3HHOOH HNo2HHHOOH HCN HHHOOH HHHHHOS H Table 9 (continued) Representative nitrogen-containing heterocyclic compounds CL　HCL　HHOS　H Table work O C1HctHH-heavy bond Ct, HHHH-heavy bond HCL HHH-heavy bond I(I(CtHH-heavy bond HHBr　HH-heavy bond FHHHH-heavy bond HFHHH-heavy bond HHF　HH-heavy bond HHI　HH-heavy bond CH3HHHH- double bond HCH3HHH-heavy bond HHCH3HH-heavy bond HH isopropyl HH-heavy bond HHt-butyl HH-heavy bond 0CH3HHHH- double bond HOCH3HHH-heavy bond HH0CH3HH-heavy bond Table 10 (continued) HCF3HHH-heavy bond HHCF3 HH-heavy bond HH0CF2HHH-heavy bond HH0CF2CL HH-heavy bond CtCtCI　CL　CL　-Double bond F　F’　F　F　F　-Double bond HNo2HHH-heavy bond I(HN02I(I(- double bond HCNHHH-heavy bond HHCN　HH-heavy bond HH5CH3HH-heavy bond HHSo□CH3HH-heavy bond HHN(CH3)2HH-heavy bond HHco2α3HH-heavy bond HHHHHCH2 Cl　HCL　HHCH3 I C1HHHCH3 I C1C1HHCH2 Table 10 (continued) HHBr　HHCH3 IF HHHCH3 I HF HHCH2 F)! C1H)I CH3 I No□HHHCH3 I CN HHHCH2 'HHOCH3HH' CF3 I(CI(3H1(HCH3) I HCH3I HCH3 I I (5CH3HHcH2 HH5o2CH3HHCH3 I! (N(CH3)2 HHCH3 IHHHHCHCN HHC1HHCHCN CL　HCL　HHCHCN HHCH3I HCHCN HH0CH3HHCHCN HHNo2HHCHCN Table 10 (continued) HHCF3HHCHCN ) I HHHHCHCO2CH3 C2HC2HHCHC02CH3 I(HHHH-C=C- 1 (Hct　HH-c=c- ct Hct HH-c==c- HHCH3I H-C2C- HH0CH3H)t -C-EC- )I HCF3HH-C=C- HNo2 HH) I -c=:c- HCN HHH-C=C- HHHHH-CH=CH- HHC1HH-CH=CH- C1HC1HH-CH=CH-. HHCF3HH-CH=CH- HHCH3I H-CH=CH- HHOCH3HH-CH=CH- Table 10 (continued) HNO,)I)II(-CH=CH-I(CNHHH-CH=CH- H)! HHHCH2C- Table 10 (continued) Table 10 (continued) HHQC6H5HH-C(CH3)2-Br HBr HH-cg C2H5) -HH-0-CH2-0-H-c(cz2)--CH=CH-α-CH-HH H-heavy bond H-CHHH-C is CH-HH-heavy bond HNO21 (HH-heavy bond HHC6Hρ-HE-heavy bond HC6H50-HHH-heavy bond HHC6H3HH-heavy bond Table 10 (continued) C, H, -HHHH- double bond -CH=CH-CH=CH-C2H,OHH-heavy bond HHCH3HH-heavy bond HCI CI HH-heavy bond Table 11 H phenyl-C(Cu,)-No-Ct CI2. 6-CI2 phenyl- CH=NO-CI CI2. 4-Cjl2 phenyl-CH=NO-Ci C I4-NO, phenyl-CH=NO-CI C72-CH50-4-CsHx tO phenyl -CH-No-CI CI4-CI phenyl -C0CH-N o-CI　CノHphenyl　-G(2aN[H2C(=NO-C1t　CI4- CI phenyl -5CH2C(CHl)-NO-Cjl CI4-CI phe Nyl-5O2G(2C(CH3)-NO-C7! CnoH phenyl Se C I CI 2. 4-Cjl phenyl Se Cz Cjl4-Br I CI2-Cjl-5-CN phenyl-PO(OCH3)-Cjl CI 3. 4-(CHs)z phenyl -PH(-0)-F FH phenyl -0- PO(OC)(3)-CJ CnoH phenyl 5i(CH3), -CI CI4 -C,H,C0NH-phenyl -NH-8Q□-CI C Table 11 (continued) 4-CJ phenyl-CEC-F F2. 4-CJ phenyl-〇=C-F 0CH3H phenyl -C=C-CJ oCH, CF. H2-pyridinyl -C=C-CJ CJ3-No2 2-pyridinyl -0( =CH-(cls) C7! CJ3-No2 2-pyridinyl=CH=CH -(trans) CJt Ci3, 4. 5-(CH, phenyl-CO-C t　QC,H. 3-CJ phenyl-〇〇-I Table 11 (continued) 5-CsH, O-1-naphthyl-NHO-(J CJ2. 4-Cj! , Fe Nyl -8-8-CJ C)H phenyl -5-8- C7IC 2-F-3-CJ phenyl-5-S-CJ CJ2. 3-(CH=G(CH =CH)-fxnyl-, I bond Cj! CN5-No, phenyl single bond Ct　CN4-C,H, F x Nyl-3i bond (J　CN2-C11) x Nyl- Heavy bond 0-CEEcHH phenyl single bond CJ CC no. 2. 3-(CH=CHCH=CH)-7xnyl-3i bond C4! CH35Oρ -Table 11 (continued) :L 4. 5-(CH3), 7x=L single bond Ct CH3S0,0-H chain phenyl single bond Ct CF, CH, 02-C, H, 7 μl single bond FF 4-CH3 phenyl-5O2NHCONH-Ct CJ2-CI! phenyl -8O, NHCONH-CJ CJI3-No, phenyl =CH, C0C )ra-Ct　CJ4-C,H,Ophenyl　-ICH,COCH2-CJ　C1 Table 11 (continued) H phenyl single bond 00 (, CF, to CH2 H1-naphthyl single bond 0 Pressure pressure αsu2stopH1-naphthyl single bond Cl CNH) x=ru -CEC -σH, CF, αB2cFsH1-naphthyl single bond CN CN3-C, H, phenyl single bond CN HH7 Eyuya =CH, N=Q (C-C-C) C-H7 Eyul-G (2NHCH2C-C-C) C-Table 11 (continued) 2. 4-CI2 phenyl-10CH2CH20-CI C,,! 2. 4-CJ 2 Phenyl-0CH2-CI CJ12. 4-C stone phenyl -0CH (C Hl)-Ci　C□2. 4-CJ2 7x=LouQC(CHx)z-C-' CJ2. 4-CJ2 7x Nil-0CH20-CJ C2 Table 12 0CR30CH31 0CH2CH30CH2CH,1 Phenyl OCH31 Phenyl Phenyl 0 Table 13 CH8CH3C CH3CH8t-butyl Phenyl CH3CH. Table 14 Representative nitrogen-containing heterocyclic compounds CH3(CH2)1BCF2CF20- CI CNCH30-(CH,CH2 0)7CH2C=C-CI OCH, CF. Table 14 (continued) Representative nitrogen-containing heterocyclic compounds 00CH. Table 15 Representative nitrogen-containing heterocyclic compounds y'24y/, x', ly'26y'! 7y et al. CH. Table 15 (continued) y’tn Y’2S X’ll y’a y’I? Y’211C1C1N H, C1C1 CtCtN CH3COC1CL CI CZ N CH3SO2-CL CLct ct s ct ct ct ct = s-s-ct ct ct　ct　-NH-NH-ct　ctCl　C1-N=N-CL　CL ct ct - double bond ct ct ct ct o - ct ct Cl　C1-CH,CH-CL　C1 Table 15 (continued) Representative nitrogen-containing heterocyclic compounds ct ct 3p=o QC2H5ct ct table 16 Representative nitrogen-containing heterocyclic compounds Table 16 (continued) Table 16 (continued) Representative nitrogen-containing heterocyclic compounds Table 16 (continued) Representative nitrogen-containing heterocyclic compounds Table 16 (continued) Representative nitrogen-containing heterocyclic compounds Table 16 (continued) Representative nitrogen-containing heterocyclic compounds R'ts Y'29 ¥'s0 Table 16 (continued) IC=　c　-ct　ct t Table 16 (continued) Representative nitrogen-containing heterocyclic compounds Table 16 (continued) Representative nitrogen-containing heterocyclic compounds -CH2CHCN CL CL -CH=CHCOCH3C1(J -CH=CHCO2C2Hs C1C1-Co2C6H5ct ct -NHCOC2H5ct ct CH3SO2NH-ct ct -CH2CN　C1C1 Table 17 Representative nitrogen-containing heterocyclic compounds Table 17 (continued) Table 17 (continued) Representative nitrogen-containing heterocyclic compounds Table 17 (continued) Table 17 (continued) Representative nitrogen-containing heterocyclic compounds Table 17 (continued) Representative nitrogen-containing heterocyclic compounds Table 17 (continued) Representative nitrogen-containing heterocyclic compounds Table 17 (continued) Table 17 (continued) Table 18 Representative nitrogen-containing heterocyclic compounds 2-pyridinyl single bond Cno Cno 3-pyridinyl OCt Cno Table 18 (continued) Table 18 (continued) Table 18 (continued) Table 18 (continued) Table 18 (continued) Table 18 (Tsubawa) Table 18 (continued) Kure＼AIJ＼R Soshiichino Representative nitrogen-containing heterocyclic compounds Table 18 (continued) Table 19 Representative nitrogen-containing heterocyclic compounds Table 19 (continued) Table 20 (CHs)sSi　Cj　Cノ C8 to O-Cj C1 CH3NH-CH(CH,)-Cj　CJ(C8υ, C(OH)　-C4Cノ CH,=CH-0-CJ CJ (CH3), NCH2-CJ CJ (CH3) isiOcH, -Ct CJ Table 20 (continued) CH, OCH, -Cjl　Cノ CH,5CH2-CI　Cノ CH2=CH-CI　CJ H2 HC:=C(CH2), -C7ICJHC=C(CH2), -C7CjI C no CH2-Ct Cjl Br-CH2-CI　Cノ HO-CH, -ci cノ CH,0-CH=CH-C*Ct Table 20 (continued) HO(CH2”)z-CI CI C2H,CH(OH)-CI　Cノ H2NCH, -Cp CI (CHl), NCR2-(JC) (CzH5')2NCI(z-CjtC)HC=CCH, -NH-CH2- CI CI (HCE:CCH,)2N-CH2-CI C Table 20 (continued) HO,C-CI　Cノ HCI CI n-C1H7-CI CI (CH3)3C'-CJ, C1 Table 21 Representative nitrogen-containing heterocyclic compounds -Nco CC12ct ct -8CH3CL CL -CH=NO)I CL CL -NHCOCH3ct ct -NHCOCH3ct ct -CH=CHCN　C1CL -CH=CHC0CH5CL C1 -NHCOCH3CL CL -N(CH2C4)2ct ct -CH35O2NH-CL CL (CH3)2N-C1C1 (CHl)2N -ct (CH3)2N -(CH3)2CHO-Br Br (CH3)2C=NO-ct ct Table 22 2-CH3-4-C6H40-phenyl sct Hct4-C6H5-phenyl Nyl OHBr Br4-CL phenyl OF -CH2CHCHmiH-2, 4-CI2 7x Nyl o CL -CH=CH-CH=CH-H ct ct ct Table 23 2. 4-C127! =ru　OCt　HH2,4-C4z　phenyl　OC1CH 3H2,4-CI2 phenyl oct ct H3,5-CL2 phenyl OF　F　H4〜Ct　Phenyl　s　ct　ct　H3,4-CL2　Fe Nyl OBr Br H3,5-C22 phenyl o ct ct ct2. 4 -C12 phenyl o ct ct ctH1-naphthyl OCL CI CI 4-caHso-phenyl s ct ct ctH phenyl o ct ct ct Table 24 Representative nitrogen-containing heterocyclic compounds Y’4 @ A’6 X’16 Y’49 Y’50 Y’U3 = 5-C47 :1-2k OCI CI C14-No□ 7! 2/lz OC1CL CI 2. 4-CI2 Fu x, = x o ct ct ct 4-No□ Phenyl O F　F　F 4-NO2 phenyl OBr Br Br3-C6H50-7:X-nyl S C1CL C1-H Phenyl/L/CH2C1CI CH3 table 25 Representative nitrogen-containing heterocyclic compounds Y’52 A’7 X’17 y’s3 Y’S4 y’5s4 (CH3CH( CO2CH2CH3)-) 7:r-nyl OCl HCIH fxnyl-CH 2CH2-CL CL CLH7! -JLlo　C7C2Ct Table 26 Y’ss A’8 X’18 Y’S7 Y’g Y’Ks3-CL Phenyl OCL HH 2,4-C1z phenyl OCL HH3,4-CLz phenyl OC1C 1H4-CL phenyl s ct ct ct3. 4-(CH3)2 Phenyl Ru　□　p　F　FH1-Naphthyl　OBr　Br　Br 2. 4-C4z phenyl o ct ct H table 27 Representative nitrogen-containing heterocyclic compounds y/, 4 Xτ9 y’so y’si yI6□2. 4-C12 phenyl o ct Hct4-C4-C6H40-phenyl OHct ct2-ca3 -4-ct phenyl S C1HC1 Table 28 Representative nitrogen-containing heterocyclic compounds A'lO-X'2OA'll Y'63 Y'64 Table 28 (continued) Representative nitrogen-containing heterocyclic compounds A'1O-X'20 A'll Y'a3Y'64 Table 28 (continued) Representative nitrogen-containing heterocyclic compounds A’IO”X’2OA’u Y’63 Y’64 Table 28 (continued) Table 28 (continued) Representative nitrogen-containing heterocyclic compounds A'toe'2o A'll Y'63 Y'64 9 only r.) Representative nitrogen-containing heterocyclic compounds Representative nitrogen-containing heterocyclic compounds Table 28 (continued) Table 29 (continued) Table 29 A'tz-x't y'as y'as R'16 r'6-(2', 4'-C /4C6H30-) 2-CL 4-C13,5-H205-(4'-CZC6 )14-0-) 2-CL 4-CL 3-H-6-ClO2-C6H50-2 -C16-C13, 5-H2O2 (4'-C6H50-C6H40-) 2-F 4-F 3. 5-H206-(2', 4'(02N)zcaH3NH-:l 2-F, 4-, F 3-H-5-CH304-(4'-C1csH4S-) 2-F 6-F 3, 5-H205-C6H5CH2-2-C14-C13, 6-H204-(1-su7toxy) 2-F 6-C13,5-H204(2 ',6'-CQ-4'-pyridine-5-)2-ct 6-cz 3. 5-H20 6-(4'-C6H,0-C6H4CH2-) 2-F 3-F 4. 5-H2 O2-(2', 4'-C4C6H30-) 2-C13-CL 4-H14- (4'-C6H50-C6H40-) 2-F 6-F 3,5-I (216( 3'14'15'-Br3C6H2M(-) 2-F 5-F 3, 4-H2 16-C6H5-0-2-CL-3-N)2-4. 5-H204-(3', s'-cz4C6H3S) 2-F 3-CN 5, 6-)! 204-C2 ', 4'-C/4C6H30-) 2-C6-fycc13-3. 5-H20 5-(3'-C6H5O-C6H40-) 2-ct 6-ct 3-cct3 -4-H. Representative nitrogen-containing heterocyclic compounds Table 31 H phenyl o ct CL 2. 4-Ctz phenyl ocz Ct3. 5-C12 phenyl 0cLct 4-Br 7Z Nil OC1C1 3-NO2 phenyl s ct Ct 2-CN 7:r:, 2k OC1CL4-(4'-czc6H4o) Fe Nyl o ct Ct4-CL phenyl NHF F 5-cz) I, 2-pyridyl NHct ctH1-naphthyl o Ct C t 4-C1 Phenic CH2ctCt 2. 4-C12 phenyl single bond ctCtH phenyl-(3C-et ct JP-A-63502511 (126) Representative nitrogen-containing heterocyclic compounds 2, 4-CZz phenyl o ct Ct3. 5-C4z phenyl o ct Ct4-No2 phenyl o ct ct4! -CN phenyl o ct Ct3. 5-C62 phenyl S ct Ct4-C21-naphthyl o ct Ct3-C6H507! Nil NHC1CL H phenyl o ct Ct 2. 4-C12 phenyl NHct Ct4-(4'-CtC6H40) Fe Nyl o ct Ct4-CL phenyl CH2C1C1 Table 32 (continued) 2. 4-C/, 2 phenyl single bond ct ctH phenyl -CE-Ct C1 Table 33 H phenyl o ct Ct 2. 4-C12 phenyl □ C4C13,5-CL2 phenyl o ct Ct4- NO2 phenyl o ct Ct4-CN phenyl o CL C L 3. 5-C12 phenyl s ct Ct4-ct 1-s7F# OC1CL 3-C6HsO-phenyl NHct Ct2. 4-C1z phenyl NHC 1C1 Table 33 (continued) 4(4'-C4C, H40) Phenyl 0C4ct4-C1 Phenyl CH2C l　C1 2,4-C72 phenyl single bond ct ctH phenyl -c=c-ct ct Table 34 3. 5-C12 phenyl o ct ct2. 4-C22 phenyl NHct ct2. 4-CL2 phenyl o ct ct3-C6H6O phenyl Nu ct ct2. 6-C12 phenyl - Gμ history - ct ct3. 5-C12 Phenyl s ct ct2-NO2 phenyl m ct ct 2. 3-(CH2)4 phenyl o ct ct3. 5-ct2 phenyl S　Br　Br2-cz-2,3-(CH2), -fux=ruoct　ct4 -(4'~C5Hs O-Cs H4)~Phenyl o ct ct table 34 (continuation) H1-naphthyl 0 0S02CH30SO2CH32,4-C1z phenyl O0CH2CF3 00 (2CF3 table 34 (continued) 2. 4-f:12 phenyl OCL OCH3'4-CL phenyl OCL CN 2. 4. 5-CL3 Phenyl OCL 502CH34-CF3 7-1- Nyl O0CH2CF3 CCH2CF33-CN Phenyl O0CH2CF3 CL3-c6H5o Phenyl Q CH3S-CL31415-(CH3) 3-phenyl oc ct3ct3,. 5. C42 phenyl OCH30- ct3. 5-C12 phenyl o ct CH30-2,4-CL2 phenyl S F (CH,)2N-4-caI (so-phenyl ONo2C14-C H3S-phenyl o ct ct 2 + 4- F2 phenyl o ct ct table 35 Table 35 (continued) CJ　CJ　N　HCノ　C1 Table 35 (continued) Ct　CJ　-NH-NH---Ct　CノCj　CJ　-N=N-, -CJ　 C no C no CJ -S---CJ Ct CノCJ　-5o2　--　CJ　CノCj　Cj! - Double bond - 1 CJ C no C no Ct -8-8---CJ C no C no CJ -〇---Cj!　 C no Cj　CJ　-C=C---CJ　CノCt　CJ　-C-NH- Table 35 (continued) Y',,2 Y',,X2. Ft'1. Y', 4 Go to Y. Ct CJ N CH3CO-Ct C Table 35 (continued) Ct CJ N n-C4He-Cj! C no C! CJ N CH,=CHC H, -CJ　CノCt　Cp　N　CH307CO-C,g　CpCノ　CJ　 N　CHzSO2-Cj! C no C! C1N CF, S02-CJ CnoC t CJ P CJ Cp Cノ CノCt　P　QC2H, CJ　CノCJ　CJ　P=OCj! Cj! C. /1 Table 35 (continued) Table 35 (continued) CJ Ct P=OCH30-CJ CJ Table 35 (continued) Representative nitrogen-containing heterocyclic compounds Table 35 (continued) Representative nitrogen-containing heterocyclic compounds Table 35 (continued) Table 36 Hn-C7H150-HHO Hn-CeHs9-HH0 Table 36 (continued) Table 36 (continued) Table 36 (continued) Table 36 (continued) Table 36 (continued) Table 36 (continued) HCH, CH, (CH,')scH2-CJ C40 table ・37 Representative nitrogen-containing heterocyclic compounds H phenyl OC! 4-CL phenyl OCA 2 + 4-C12 phenyl 0ct 3-CN 7: r-2k OC/l. 2. 4-(CH3)2 Phenyl□ct2-CH3-4-CL 7 Enik OC14-C6)150-7-1-nyl0, C/. 3-C,HsCH20-phenyl 0ct3. 5-CL2 phenyl OCA 2. 4. 5-Br3 phenyl S Cl2. 4-C127! Nil S C/= 3-(4-cz-c6H4)-7x 2 pv s ct4-C1 phenyl N HC1 4-CL phenyl NHF 31415(CH3)3 Phenyl NHF3-C6H5O-phenyl NHF 3-No2 Phenyl OF 3r 4-CA27:”2/l/CH2CL table 37 (continued) Representative nitrogen-containing heterocyclic compounds H phenyl single bond ct 4(C6H50)-phenyl, -double bond F4-CF3 phenyl -C0N H-ct3-C1 phenyl -c='e-ct H'1-naphthyl OCL 4-C1・1-naphthyl OCL 5. 6. 7. 8-H41-naphthyl OF6-CH33-pyridinyl 0F 3-C1'4-pyridinyl OC6 5-CL 2-chenyl O, Ct H2-su7 chill o ct 2. 4-C127L 2k-CH20-C1 table 38 H phenyl OCt H phenyl S CL 4-CL Phenyl Q (::C 3,5-C12 phenyl s ct 4-C,H3O-7! 2/L, OC42+4-Br2' 7:r-2/L z　S　C44-CH3phenyl OF 3-(4-cz-c6a4o) 7! Nyl OC13-C6H50-7: r-, di hF(CL3-C6H50-phenyl N[(F 2. 4-C12 phenylCH2ct 2 + 4 + 5-, C43 phenyl single bond ct4-CH30-pheny single bond C3,5-(CH30)2 phenyl OCl2-Br-4- C1 phenyl OBr3-C1-4-CH, CH2O7 k -CH2CH2- Cl3-CH5CH20-4-CH3fu x 2h -CONH-CLH1-naphthi Le OCL Table 38 (continued) Representative nitrogen-containing heterocyclic compounds H2-naphthylation, OC4 5-CH3CH23-pyridityl → 5-F4-Br 2-chechyl o'c t 4-CH32-thiazolyl single-F H phenyl -c=c-ct 2. 4-C127! 2/Lz -CH20-CLH phenyl-CH20-C1 5,6,7,8-H41-naphthi/L' Oct3+4+5-cz3 phenyl CH2Br table 39 Representative nitrogen-containing heterocyclic compounds R’llll A’18 X’29Y’90H Phenyl 0ct 2. 4-C12 phenyl OCl 2. 6-C1, phenyl oC4 3-C,H,O-phenyl OCL 4-C6H5CH,-phenyl OCL3. 4-(CH3)2 phenyl s ct:L5-Cl2 feni/L/S ct4-(4-czcsa4o)-feni Nil S Cl2. 4-(CH30)z phenyl o ct3. 4-OCH2 0-phenyl OCl2. 3-OCH20-phenyl NHF4-C1 phenyl M(F 3-NO! Phenyl 0F 2-No2 Phenyl OCL 3-CH3CH2-phenyl OCt H phenyl CH2C1 H phenyl single bond ct :3+5-Br2 phenyl single bond ct table 39 (continued) Representative nitrogen-containing heterocyclic compounds R'18 A'18 X'29 Y'302-CH3-4-C17 en/l< CH20Cl3-CL phenyl CH2Br ゛4-C1 phenyl CH2OBr H1-naphthyl OCZ H2-naphthyl OCL 4-C11-naphthyl OCL 4-CH32-pyridinyl OCt H3-pyridinyl 0F 5-C12-Ce OCL No. 5-CH33-isozolyl NHFH phenyl -c=c-ct 2. 5-C12 phenyl Q Br Table 40 Representative nitrogen-containing heterocyclic compounds u/,, X'XI z/IZ'2 Y'91 Y'92 (CH3), CH3 H2CH2--heavy bond 0 0 CL ClCH2" CHCH2-- is supplied 0 0 CI CIHC:=CCHz--N bond o o ct ctHO-'MJ Supply o o ct ct Table 40 (continued) R'19, X'30 z'lz/2Y'91 Y'92 (HOCH2) 3C --Shadow feed o Oct(?tCH30CH2CH2--fi OOC1Cl5-b Lomo-2-thiazolyl-1 bond o o ct ct table 40 (continued) Representative nitrogen-containing heterocyclic compounds R'19 X'30 z/□z'2y',! Y'922-pyri:)nyl single bond Combined o o ct ct5-bromo-2-pyridinyl single bond o o CI C16'-Methyl-4-H'j'E"2/'-Double bond 0 0 CI CI2 -Benzimidazolyl -1 Wakiyoshiai o o ct ct2-(2-indolyl ) Ethyl single bond o o ct ct2-chenylcarbooxamide single Combined o o ct ct table 40 (continued) Representative nitrogen-containing heterocyclic compounds R’19 X’XI z/lz/2y’st Y’922-penzoquinazolyl Single bond o o ct ct2-benzothiazolyl single bond o o c t ct3-pyridinyl-1-yoshiai 0 0 ct CI2-pyridinyl Methyl single bond o o ct ct 4-pyridinylmethyl single bond o o ct ct 3-7 e, 2 J Ray 2-Blow! -A/-1 顛昭＠OOCL Table C1 40 (continued) Representative nitrogen-containing heterocyclic compounds R'19 X'30 z'lz/2Y'91 Y'92 phenylethynyl single Combine o o ct ct4-trill η? - Heavy bond o o ct ct3 -Phenylbrome single bond o o ct ct phenyl single bond 0OF F Table 40 (continued) Representative nitrogen-containing heterocyclic compounds 2-ethyl single bond 0 0 Br H benzenesulfonyl single bond o OCH3ct benzyl single bond 0 0 C1BrC2H, - double bond 0 0, F ct cyclohexyl single bond 00F ct cyclohexyl one Heavy bond 00FH Table 40 (continued) Representative nitrogen-containing heterocyclic compounds R', 9 x'3o z'1z'2y'st Y'92n-C3H7- heavy bond 0 0 Br H4-methyl-2-thiazolyl-NH-00C4 (:t4-k Rolo-2-benzothiazolyl-NH-00ct ct table 40 (continued) Representative nitrogen-containing heterocyclic compounds R'19, x'3oZS Z12Y'91 Y'923-methyl-5-isosu γSili# -NH-00cz ct5-bromo-3-isoton azolyl -NH- 00ct ct3. 5-7 Methyl-2 Zerimidinishi-NH-00ct ct table 40 (continued) Representative nitrogen-containing heterocyclic compounds R'19 X'XI Z't Z'z Y'slY'9z2-chenyl -CH 2-00ct ct2-methoxyphethyl-NH-S S C1H table 40 ( continuation) R’19 X’3D Z’t Z’z Ysx Y’923. 4-dichlorophene Chiru -NH-S S ct ct 7z = Lou CH2-S S CtC1 4-ri0(:l phenyl-CH2-S S CZ CH33-methyl-4-k Rolofuechiru 11 dignified f; SSB,) l phenyl -CH2-00Br C.L. 2-Frills -CH2-CM3N OCL C1 Table 40 (continued) Representative nitrogen-containing heterocyclic compounds R'19　X'3゜　z'lz'2Y'91　Y'9□3-chlorophenyl- N(CH3)-00ct H table 41 R'20 X'31 Z' (y, Y'94 y'ss2. 4-dichlorophene single bond s ct ct ct2. 4-dichlorophenyl single bond C H2ct ct ct phenyl single bond CH2F F F2. 4-dichloro Hue, chile single bond NHHHBr4-chlorophenyl single bond NHct ct ct table 41 (continued) Representative nitrogen-containing heterocyclic compounds n/, X/3, Z'3 Y'93Y64 Y'9s2. 4-dichlorophenyl Single bond, NHct ct ct phenyl -cu2cH2-o ct ct ct fu x 2y -CH2-S ct ct cz. -yx2z -CH(CH3)-0ct ct ctfux2k -CH2-OC L C4Cl phenyl -CH=CH-Oct ct ct table 41 (continued) Representative nitrogen-containing heterocyclic compounds R & X’31 Z’s Y’*s Y’! )4 Y'95 phenyl -c=: c-,o ct ct ct phenyl-SO℃)-o cL CL CAfu: "2k -5O2-OCA CL CA2-chlorophenyl -CH2-NHc t ct ctl-naphthylmethyl single bond o ct ct ct table 41 (continuation) Representative nitrogen-containing heterocyclic compounds R'20 x'at z'IY63Y'94 Y phenyl single bond OHC 1Ct Cyclohexyl single bond o ct ct ctn-butyl single bond o ct ct ct 4-phenoxyphenyl single bond o ct ct ct table 41 (continued) Representative nitrogen-containing heterocyclic compounds R'20 X'31 z'3Y'93 Y'94 y'ts3-phenoxyphene Chill - 6 o ct ct ct and cyclohexyl - m OHHBr Cyclohexyl single bond 0FFF Phenyl-CHz-OHHBr H-heavy bond Q Br Br 08O2CH3H-heavy bond OHH08O2CH 3 Table 41 (continued) R’20 X’31 Z’3 Y’es Y’s< Y’esH-heavy bond OC H3H0SO2CH3 Phenyl single bond OB r Br 08O2CH3 x 2/l/- double bond Q HCCH30SO2CH3 phenyl single bond OHCCCCH30SO2CH3 cyclohexyl single bond o ct ct oso CH3 phenyl single bond OCL C1CN table 41 (continued) Representative nitrogen-containing heterocyclic compounds R'20 X'31 2'IY'93 Y'94 y'esH-heavy bond o c t ct 0P (=SXCC2H,). Phenyl single bond o ct ct 5CH32,4-dichlorophene? -heavy Bond o ct ct cF’3 phenyl single bond o ctct CC2H 3 (CCCCH2)2NCH2-- double bond o ct ct ct table 41 (continued) tree) R'20 X'31 z/3Y'93 Y'94 Y'954-71 tri = J Le Methipre -1 Oct ct ct 4-aminophethyl single bond o ct ct ct 4-nitrophenyl single bond o ct ct ct table 41 (continued) R'20, X'llZ'l Y'93 Y'94 Y'9S phenyl single bond Coupling 0, CL CL Br7 x 2, TI/-poly bond O5CH2CQN HNHCSNH2HC1CH3- double bond OF FF Table 41 (continued) 3-chloro-2-pyridinyl CH, OCt CJ 02-benzothiazolyl Single bond OCt Ct Ct5-chloro-2-chenyl CH(Q(3)-0 (JC) CJ2-Frill CH2OCj! Cj! Table 61 42 2-Methoxyf x Nyl-NH-CJ HHC13-trifluoromethylphene Nyl -CH, -CJ HCt H2,4-dichlorophenyh -CH2-Br HHH7x Nyl-CH(CH,)-Br Br HH3-fluorophenyl Single bond Br Br HH Cyclohexyl Single bond CJ H (JH Table 4 2 (continued) Phenyl -C0NH-Br HBr H cyclohexyl -CH, -Br H Br　Hn-propyl-CH, -Br　HBr　H2-rioo7zyl　-NH -HHBr Br phenyl -CH, -HHCt C no Phenyl -CH2-HBr Br H2-methoxyphenyl -CH2-HB r　Br　HTable 42 (continued) RS1X'3□Y', Y%, Yt8Y%. 3-methoxyphenyl -CH2-C7ICJ HH3-fluorophenyl - CH2-Ci Ct HH. 3-bromophenyl -CH, -CJ HHH2-r-to*SchiffZ2k -NH -CJ (J HHn-propyl-CH, -CJ HCJ H2-furyl -C H2-Br　HBr　HTable 42 (continued) 2-norbornyl single bond cz HBr H3-hyricinyl-N(CH3) -F HHCi3. 5-dichlorophenyl-CI(2CH2-C1CJ!C ) 01 table 43 HCH,CH,H CH, CH, CH2C2Hs n-(:, H, CH, CH. Benzyl, CH, C) I, H 3-chlorobenzyl CH, C0CH. Phenyl HH 4-rio　o　7znyln　-C,H,CH3phenoxy　CH3CN,　H Phenoxy CH3CN, COC, H. 1-Naphthyl CH, CH. Table 43 (continued) 2. 4-Dichlorophenoxy (:) (, OCR. 3-Pyridulmethyl CH, CH, co, C2) (. 4-chlorochenyloxy OHH Certain compounds listed in Tables 1-43 are derived from plant emanation according to the present invention. Nitrogen-containing heterocycles used to reduce water loss and increase crop yields Formula) is to be understood as an example of a compound. The invention is limited to the use of these compounds only. 1fL defined Rather, the present invention provides that the above formula 1 is combined with a v-containing heterocyclic compound. Including everything. The novel nitrogen-containing heterocyclic compounds of the present invention have the following formulas: R24 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X1oc, to, S, So, SO2, NH, -CH20-. -CHS-, -CH(OH3)O-, -CH(CN)O-. -CH-No-, -C(CH3) -No-. -CH2CH20-, -0H2c, t-+2-, -Cmic-. -CH2So-, -CH2SO2+, -oct-+20H20-. '-CH (alkyl)-nu is 100NH-, j is a value of 0 or 1, a has a value of 2 to 4, X19 may be the same or different; halogen, alkyl, cyano, borihaloa 'alkyl, alkoxy, polyhaloalkoxy. Alkylthio, alkylsulfinyl, alkylsulfonyl. Nido O, acyl or polyhaloalkylsulfonyl. however, (1) 2 and 4. A small number selected from 2 and 6, 2 and 3, and 3 and 4 (both with two ring positions) Ring position pairs may be the same or different halogen is replaced with: (ii) Original position 2. 4 and 6 are replaced with chlorine, j is 00 value, and When X is SO, R24 is not unsubstituted phenyl; (iii) Original position 2. 3 and 5 are replaced with chlorine, j has a value of 1, and When X10 is S, R24 is not unsubstituted phenyl: R25 is H & or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X11 is o, S, So, 802. NH, CH2, -if covalent bond. -CH20-, -CH2S-, 7:C1-1(CI-13)o-. -OH(CN)0-, -CH-No-. -C(OH3)-No-, -0H2c! -120-. -CH2CH2-nee c=c-, -aH2so-. -CH2So. -, -0CH2G) -120-. -C)l (alkyl)- or -〇0N)-1-, and b has a value of 2 to 3. , X20 may be the same or different; halogen, alkyl, cyano, polyhaloa alkyl, alkoxy, polyhaloalkoxy. Alkylthio, alkylsulfinyl, alkylsulfonyl. Nitro, acyl or polyhaloalkylsulfonyl. However, at least two ring position pairs selected from 2 of X20! It is 10 gen . In the above formula, R26 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X is O, S, So, So2. NH, CH2, - heavy covalent bond. -CH(ON)O-, -CH-No-. -C(OH3')-No-, -CH,, CH20-. -CH2CH2-, -C=C-, -CH2So-. -CH2S02-, -0CI-120820-. Y23 is hydrogen, halogen, alkyl, polyhaloalkyl, alkoxy, polyhalo Alkoxy, cyano, alkylthio, alkylsulfinyl, alkylsulfony yl, nidoO, acyl or polyhaloalkylsulfonyl. In the above formula, R27 is substituted or unHITh phenyl, 1- or 2-naphthyl or hetero is an aryl, X13 is o, S, So, So2. NH, c+2. -1 co-one bond. -CHO-, -CHS-, τCH(CH3'IO-. -CH(CN)O-, -C)l-No-. -C(CH3)-No-, -CH2CH20-. -CH2CH2-, -C=C-, -CH2So-. -CHSo2, -OCHCH20-. -CH (alkyl)- or -〇〇NH-, Y24 is halogen and 1 , Y25 and Y26 are hydrogen, halogen, alkyl, polyhaloalkyl, alkyl, respectively. koxy, polyhaloalkoxy, cyano, alkylthio, alkylsulfinyl, Alkylsulfonyl, nitro. Acyl or polyhaloalkylsulfonyl. however, At least one of Y and Y26 is halogen, and Y24''25 and Y26 is chlorine and X13 is O, R27 is not unsubstituted phenyl In the above formula, R28 is substituted or unsubstituted phenyl, 1- or 2-naphthyl, or heteroa is a reel, X, 4 are o, S, So, So2. NH, CH2, - heavy covalent bond. -CHO-, -CH,2S-, -CH(CH3)0-. -CH(CN)O-, -CH-No-. -C(CH)-No-, -CH2CH20-. -CH2CH2+, -C=C-, -CH2So-. , -CH2802-, -0CI-120H20-. -CH (alkyl)- or -〇〇NH-, and Y and Y28 are each halogen and Y29 is hydrogen, halogen, alkyl, polyhaloalkyl, alkoxy, Polyhaloalkoxy, cyano, alkylthio, alkylsulfinyl, alkyl Sulfonyl, nitro, acyl or polyhaloalkylsulfonyl. R29 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X15 is 0. s, so, so2. NH, OH2, - heavy covalent bond. -C(CH3)-No-, -CH2C)-120-. -〇820H2-, -CenC-, -CH,2So-. -CH2CH2+, -0CH2CH20-. -CH (alkyl)- or -〇〇NH-, and Y3゜, Y31 and Y32 are husband Hydrogen, halogen, alkyl, cyano, polyhaloalkyl, alkoxy, polyhalogen loalkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, tro, acyl or polyhaloalkylsulfonyl. however, At least two of Y2O''31 and Y32 are halogens. In the above formula, R2O is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, ×16 is O, S, So, So2. NH, CH2, - heavy covalent bond. -CH20-, -CH2S-, -CH(CH3)0-. -CH(ON)O-, -CH-No-. -C(CH＞　'=NO-, -CH)CH20-1-0H2CH2-, -CmiC -, -CH2So-. -0H2S02-, -0CI-120H20-. -CH(alkyl)- or -〇〇NH-, YB2. YB2 and YB2 are husbands Hydrogen, halogen, alkyl, cyano, polyhaloalkyl, alkoxy, polyhalogen loalkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, tro, acyl or polyhaloalkylsulfonyl. however, (i) YB2. At least two of YB2 and YB2 are halogens: (a t) If both y and YB2 are chlorine and ×16 is O, then R2O is unresolved. Not substituted phenyl; (iii) When both Y and YB2 are chlorine and X is O, R2 O is not unsubstituted phenyl or 4-methoxyphenyl; d has a value of 0 to 4; , e has a value of 1 or 2 (however, d+e is not greater than 5), and R31 is the same may be different, substituted or unsubstituted aryl (provided that R31 is 2- or 4- - when aryl, d is not O), aralkyl (provided that R31 is R-ara (d is not 0 when alkyl), alkoxy, cycloalkoxy, aryl xy, aralkoxy (however, when R31 is 4-aralkoxy, d must be O) ), arylaryloxy, aralkoxyaralkyl, arylaria Rukoxy, aryloxyaralkyl, aryloxyalkyl, arylo xyaryloxy, aralkoxyaralkoxy, aryloxydialkoxy cy, alkylthio, alkenylthio, arylthio, aralkylthio, ary ruthioaralkyl, arylsulfonylarylsulfonyl, alkylamino , dialkylamino, acyloxy, aroyloxy, alkoxycarbonyloxy xyphenylazo (where x1□ is 0 or S), naphthylazo or adjacent -OCH O- or -OCH2 that combines with a carbon atom to form a 5- or 6-membered ring CH20-, and YB2 may be the same or different and represent halogen, alkyl, alkenyl, alkynyl, one CH that combines with adjacent carbon atoms to form a 6-membered ring -CHCH-CH-, -(CH), nitro. cyano, haloalkyl or polyhaloalkyl, x17 is O, S, NH, C ) (2. -CH2 0-, -CH2. S- or -〇CH20H20-, Y37 is halogen, YB2 is halogen, alkoxy, alkylthio, alkylsulfonyl, polyhalo Alkoxy, polyhaloalkyl, cyano, nitro, substituted or unsubstituted aryl thio, aryloxy or arylsulfonyl. f is a value of 0 to 5, R32 may be the same or different and represent halogen, alkyl, alkenyl, alkyl Nil, polyhaloalkyl, cyano, nitro. alkylamino, dialkylamino), alkoxy, polyhaloalkoxy, alkyl ruthio, alkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nil, Asil. CO2 (alkyl>, CONH (alkyl), CON (alkyl), 'SO N (alkyl), alkylcarbonyloxy. alkoxycarbonyloxy, substituted or unsubstituted aryloxy, aryl thio, arylsulfonyl or aroyl, X is O. S, CH2, - heavy covalent bond or -C edition C-, YB2 is halogen , polyhaloalkoxy, polyhaloalkyl. Cyano, alkylsulfonyl, alkylsulfonyloxy, polyhaloalkyl sulfonyl or polyhaloalkylsulfonyloxy, Y2O is haloalkyl, polyhaloalkyl, alkoxy (However, ×18 is also S (not a heavy covalent bond), polyhaloalkoxy. ), alkylsulfonyl, nitro, sialkoxyphosphinyl or trial It is kylammonium. In the above formula, Y41 may be the same or different and is a halogen, and Y42 may be the same or different. Also suitable for halogen and alkoxy. Alkylthio or polyhaloalkoxy, X1ghao, Citi'A-, -P (-0) (0-7)Ltkyl)-2, -P(alkyl)-, -P(0-alkyl)-2, -P(alkyl)-, -P(0-alkyl) Kill)-, sulfinyl. Sulfonyl, thiosulfinyl, -heavy covalent bond, carbonyl. Aminocarbonylamino, aminooxarylamino, aminocarbonylalkylene carbonylamino Substituted or unsubstituted oxyaryloxy (provided that 1. 3-Arylenbis (oxy) is substituted with at least one substituent), oxyarylal Kylaryloxy, quaternary sialoxy or oxyarylaryloxy Ru. s3 In the above formula, Y52 and Y53 are each a halogen, including haloalkyl, cyano, nitro, and amino. , alkylamino, dialkylamino, alkoxy, polyhaloalkoxy, Alkylthio, alkylsulfinyl, alkylsulfonyl, polyhalo, alkyl rusulfonyl, alkoxycarbonyl, alkylaminocarbonyl, aminocarbonyl Bonyl, dialkylaminocarbonyl. dialkylaminosulfonyl, alkylaminosulfonyl, aminosulfonyl, Alkylcarbonyl, dialkoxyalkyl. Alkylcarbonyloxy, alkylcarbonylalkylamino, adjacent carbon 1CH-CHCH-CH-, substituted or unsubstituted, that combines with atoms to form a 6-membered ring replacement aryl. Aralkyl, aryloxy, arylthio, arylsulfonyl or ara Lukoxy, x2o is 1CH (alkyl)O-, -〇　(alkyl)20-. -OCH2+, -CH20-, -〇H2+. -C (hacl'n) 2, -OCH2 0-, -OCH2 CH2 0-. or -C-C-<where Q has a value of at least 1); -OCI-1 (Al Kill) -, -QC <Alkyl)2. -, OCH (Fulki A,) O-, -QC (7) Ii Kill) 20-. -OCH (alkyl)CH20-. l-OCI-1 (alkyl)CH(alkyl)O-. '-CH (alkyl) CH (alkyl)-. -CH(alkyl)-, -C(alkyl)2-. -CH2CH20-, -OCH2CH2+. -CH (alkyl)CH20-, -CH2CH2-. -CH (CN)O-, -C (Flue t/L,) (CN)O-. -CH (polyhaloalkyl)O-, -C (CN)-No-. -C(NHacyl)-No-. 1C[N(alkyl)2]-No-. -C(S'-alkyl)-No-. -C (0-Fruit) "No-, -SC (-0) O. -NHC (-0)O-, -N (7/l, Ki/L,)C (-0)O-. -CH (Full Kill) S (07', +, -s (0) hCH2+. -QC (-S), S-, -C (-0)S-. -C (-S) -S-, -NH' (7A4=/l,)C (-0)S-. -SO3M (alkyl)-, -CONH-. -SC (-0)NH-, -NHS02NH-. -N(alkyl)SO2M゛(alkyl)-. -N (7Jtt*ru)SO2NH-. -NHS02N (7A, l)-, -C (0-flut-A,)-N-. -C(S-alkyl)"N, -CHCAogen)-. -C(alkyl)(halogen')-, -CH(CN)+. -C(alkyl)(CN)-, -NH(alkyl)NH-. -NH-N (alkyl)-; -NH-NH- or -N-N- (However, R33 is nitrogen Not Toro) ni -C (-0) -, -C. (-0) C (-0) -. -CH(0-7/L, Ki/l,)-, -CH20(-0)-. -C(-0)CH2, -CI-1(7/l, t/L,)C(=O)-. -C(=O) CH (alkyl), -CH-CH-. -C(alkyl)-CH-, -CH-C(alkyl)-1-C(alkyl)-C (Alkyl)-2-C(-0)CH-CH-. -P(Y　)(Y4dialkyl)-1 Substituted or unsubstituted -P (Y) (Y4 diaryl) or arylene (a rylene), -3i (halogen) 2-9-8i (alkyl) 2-2 -QC(-0)N(alkyl)-1-OCH20(-0)N(alkyl) -21-N(alkyl)CON(alkyl)-1-QC(-0)NH-, -NH CONH-. -8o2NHC(-0)NH- or -NHC(-8)NH (where Q is at least h is a value of 0 to 2, R34 is acyl, alkyl sulfonyl Le. Polyhaloalkyl, polyhaloacyl, polyhaloalkylsulfonyl or substituted is unsubstituted aroyl or arylsulfonyl, and Y43 and Y44 are each 0 or S. , R35 is isoxazole, isothiazole, pyrazole, imidazole, 1, 2. 4-triazole, 1,2. 4-Oxadiazole. 1. 3. 4-oxadiazole, 1,2. 4-thiadiazole, 1,3. 4 -thiadiazole, oxazole, thiazole, benzopyrazole. Benzimidazole, benzoxazole, benzothiazole. Indole, pyrrole, furan, thiophene, benzofuran. 1benzothiophene, pyridine, pyrimidine, pyridazine, 1,3゜5-tri Azin, 1, 2. 4-)-Ryazine, quinoline, isoquinoline. Quinazoline, Phthalazine, Benzopyridazine, Benzopyrazine. Carbazole, dibenzofuran, dibenzothiophene, benzoxazine, phthal imide, benzopyran, dibenzopyridine. Pyridopyridine, pyrazolopyrimidine, tetrahydropyrimidinedione, kumali piperidine, morpholine, tetrahydrofuran, tetrahydrothiophene, Viloridun, thiomorpholine, piperidin-2-one, piperidine-2,6-di On, 2. 5-pyrrolidinedione, 3-morpholine, 2-oxohexamethylene Imin. 2-oxotetramethy, lenimine, 1-pyrazoline, 2-pyrazoline. Pyrazolidine, 2-imidazolidinone, 2-imidazolidinethione. 2. 4-imidazolidinedione, 1. 2-oxathiolane, 1,3-oxazino 211-pyran-2-one, 4th-pyran-4-one, 2H- and ran- 2-thione, 4H-pyran-4-thione, tetrahydropyran. Tetrahyto-O-thiobilane, 7-oxabicyclo[2,2,mohebutane. 1-azabicyclo[2,2,1]heptane, oxetane, coumarin, 1゜3-di Oxane, 1. a substituted compound selected from 4-dioxane and 1,3-dioxolane; or an unsubstituted heterocyclic ring system, and X21 is o, s or NH (provided that X When 21 is NH, R35 is not pyridine, and when X21 is S, R3 5 is not an unsubstituted benzothiazole), Y45 and Y2O are each halogen. or In the above formula, R37 and R38 are halogen, nitro, cyano, polyhaloalkyl, polyhalogen, respectively. loalkoxy, 1 alkylsulfonyl, polyhaloalkylsulfonyl, acyl, °Alkoxycarbonyl, polyhaloalkylsulfonyl or R39-X22- Yes (However, R37 and R39 are substituted or unsubstituted phenyl, 1- or 2-na phthyl or heteroaryl, X22 is o, s, so, so, CH, -1 covalent bond. -CH,, O-, -CH2S-, -CH(CH3'')O-. -CH(ON)O-, -CH-No-. -C(CI-13>-No-, -082CH2o-'. -CH2CH2-, -C=C-. -CH2So-, -CH3SO4,-, -0CH2C)-120-. Kyl, alkylsulfonyl, alkenyl, alkynyl, alkoxycarbonyl; Substituted or unsubstituted aryl, aralkyl, aryloxy, arylami aroyl or arylsulfonyl). however, (i) B is RN<, R39-alkyl-N<. R39-C(-0)N<, R-3o N<, R3g-0-N< or R3gNH -N<, both R and R38 are other than R39''-X22-; (it) 3 is RN<, R39-alkyl-N<. Or when R3g is other than NHN<, one of R37 and R38 is R39-X2 2- is: (iii) In formula (xiii), both R and Y are chlorine, and X22 is When a single covalent bond, R39 is not unsubstituted phenyl; or R and R are each halogen or R43'23- (provided that R43 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl, X23c, to, S, So, So2. CH2, - heavy covalent bond. -CH20-, -CH2S-, -CH(CH3')O-. -CH(CN)O-, -CH-No-. -C(CH3)-No-, -CH2,CH20-. -CH2CH2-, -C=C-. -CH2So-, -CH2So, -, -0CH2CH20-. -CH (alkyl)- or -〇〇NH-, and B15 is O, S, NH or NR 44 (where R44 is alkyl, alkylsulfonyl, polyhaloalkyl) rusulfonyl, alkenyl, alkynyl, alkoxycarbonyl: substituted or Unsubstituted aryl, aralkyl, aryloxy, arylamino, aroyl or arylsulfonyl). however, B15 is R43-N<, R43-alkyl-N<. R43-C(-0)N<, R43-802N<, R43-0-N<”15 is R4 3-N<, R43-alkyl-N<. R43-C(-0)N<, R43-8o2N<, R43-0-N< or R43- When NH-N<, one of "41 and R42" is R43-X23-. or 4J In the above formula, R45, R46, R4□ and R48 are hydrogen and halogen nitro, respectively. Cyano, polyhaloalkyl, polyhaloalkoxy, alkylsulfonyl, polyhalogen loalkylsulfonyl, acyl, alkylthio, alkyl, alkoxy, alkyl rusulfinil or R49-X2 (however, R45-R46, R4□ and One of R48 is R49X24 rto') and R45, R46, R4□ and Tf R4g must contain 2 or less hydrogen, alkyl or alkoxy), R49 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl , X24t; to, S, So, So□, CH2, - heavy covalent bond. -CH20-, -CH2S-, -u-((CH3)O-. -CH(ON)O-, -CH-No-. -C(C)(3)-No-, -CH2CH20-. -CHCH2-, -CsoC-. -C) -12So-, -CH2802-, -0CH2CH,O-. ! -CHc alkyl)- or -〇〇NH-, and Y48 is a halogen, 816 is o, s or NH. In the above formula, is an unsubstituted carbocyclic or heterocyclic ring system, which may be saturated or unsaturated, B17 is 10H-N-, -N-CH-, -CH=CH-. -Co-, -3o2-, -CH2Co-, -COCH2-. -CONH-, -NHCO-, -3o2NH-. -NH3O2-, -5o2N(alkyl)-1-N(alkyl")Co2+, -oso2-, -03-, -N<. -NH-, -N (alkyl)-, -OCH, -3CH2゜-NHCH2, -N (7A, -J)CH2, -8CO-. -0CH2-, -0CO-, -CH,, -, -CH20H2- or -3CHCo - (however, B17 is -co- and Y54 and Y55 are each halogen) be. R51 is a monocyclic aromatic or non-aromatic ring system, a bicyclic aromatic or non-aromatic ring substitutions selected from systems, polycyclic aromatic or non-aromatic ring systems and bridged ring systems; unsubstituted carbocyclic or heterocyclic ring systems, which may be saturated or unsaturated; B18 is =CH-N-, -N-CH-, -CH-CH-. -Co-, -3o2-, -CH2Co-, -COCH2-. -CONH-, -NHCO-, -8○2NH-. -NH8O2+, -so,, N　<furkyl)-1-N　<furkyl)Co2- , -03O2-, -C8-, -N<. -NHCH2, -N (alkyl>ci-+2. -5co-. -OCH-, -0CO-, -CH-, -CHCH2- or -3CH,, Co- can be, B is -CH2- or -CH(alkyl)-, 1 is a value of 0 or 1, In the above formula, B is -CH2C(CH3)2SCH2-1=CHCH-C(CH3)0CH2 −. =CH2CH2SCH2CH(CH3)+. -CHOHSCHCH-, -CH25CH2CO-. -COCH2C(C+5)2CH2C〇-2-CHCH2CH(C6H5)OH 2Co-. -CONH(CH)CHCH20-. -COC(CH3)2NHCO-. -CH2CH2N (06H5) CH2CH2-1-CH2N (C6H5) C H2CH2-. -CH2CE (2C to 1 (C6H5) CH2c H2-. -Co ('CH2) 3Co-, -Co (OH2) 2Co-. -COC(CH3)2C(CH3)2Co-'. -Go (CH2) 4Go-, -Go (CH2) 5Go-. -Go (,,CI(,)5CH2+,-co(CH2)4CH,,+. -CO(CH2)3CH2+, -co(CH2)2CH2-. -〇〇〇, H2SCH,,Go-. -COC82N (R52) CH2Co-. -COCH20CH, Co-, -COCH2SC8-. -COCH-CH-N=CH-. =CH2CH(C6+5)CH2-N-CH-1; -C02-CH2CH2- and R52 is hydrogen, alkenyl, substituted or unsubstituted aryl, or alkaryl and Y58 and Y59 are each halogen. YII In the above formula, R53 is substituted or unsubstituted cycloalkenyl, cycloalkagenyl, cyclo Loal trienyl, cycloalkyl, cycloalkyl, tricyclo alkylnyl, tricycloalkenyl or tricycloalkagenyl; The permissible substituents may be the same or different and include one or more alkyl groups, Halogen, haloalkyl, polyhaloalkyl, alkoxy, alkylthio, alkyl Killsulfonyl. Polyhaloalkoxy, nitro, cyano, acyl, aroyl, aryl, alco oxycarbonyl, alkoxycarbonyloxy. Oxo Acyloxy; ridge is a group that combines with adjacent carbon atoms to form a 5- or 6-membered ring. 〇　H　=　C　　　C　H　-　C　I-1- or -CH-CHCH,2- can be, Y and Y61 are each halogen, and X is 0, S. N.H. CI-12,-C H20- or -heavy covalent bond. In the above formula, R54 may be the same or different and is one or more hydrogen atoms. Halogen, alkyl, aryl, aralkyl, alkenyl. Alkynyl, polyhaloalkyl, NH2. NH (alkyl). N(alkyl)2, alkoxy, polyhaloalkoxy, alkylthio, alkyl Sulfinyl, alkylsulfonyl, aralkoxy, CO2alkyl, CON H (alkyl). CONH, CON (7ML, -1=L), So2N (Full*/L,)2 . SO2NH (alkyl), $02NH2. Asil. co co-alkyl)2, acyloxy. Acyl-CON (alkyl) or bonded to adjacent carbon atoms, substituted or 2,3-(-CH-CHCH-CH-) forming an unsubstituted 6-membered ring. 3, 4-(-CH-CHCH-CH-), 2. 3-(CI-12) 4- or 3 ．． 4-(CH2) is 4, X is ○. S, So, So2, CH2, - heavy covalent bond. 1 CH 2 0-, -CH 2 S-, -CH (CH 3') O-. -cH (CN)O-, -CH-N,O-. -C (CH3)-No-, -CH2CH20-. -CH2CH,-, -C-C-, -CH2So-. -OCH　CH　-1 has one OCH2-r, Y and Y51 are the same or different It is often halogen. In the above formula, R68 is substituted or unsubstituted phenyl or 1- or 2-naphthyl, ×27 is 10H (alkyl) 0-, -C (alkyl>20-). -OCH2-, -C (halogen)2. -OCH2　0-. -OCH CH O-, -CH20-, -C=C-. -OCH (7A, kyl)-, -QC (alkyl)2. -OCH (alkyl)O-, -QC (alkyl)20-. -OCH (Furuki J) CH20-. -OCH (furkyl) CH (fur + le) O-. -CH(alkyl)CH(alkyl)-. -CH(alkyl)-, -C(alkyl)2-. -CH 2 0H 2 0 -, -QC8 2 G) (2 -. -CH C7) Ii kill") CH2 0-, CH2 CH2 +. -CH(CN)O-, -〇　(7/l,ki/L,)(qN)O-. -CH (Bouhao7At*IIt)O+, -c (CN) -No-. -C(NHacyl)-No-. one. C[N<alkyl)2coNo-. -C (S-alkyl)-No-. -C (0-7A4) -No-, -SC (-0)O-. 2NHC (-0) O-, -N (Fulki/L,) C (-0) O-. So, So2, -CH2S (0)h-. CH (Fruit) S (0) h +, S (0) hCH2 +. -QC (-S)S-, -C (-0)S-. -C (-S) -S-, -NH (7/L, -1=A,) C (-0) S-. -O (C-0)S-, -N (alkyl) +, -N (R34) -. -SO2NH-, -So2N (7/l, kill)+, -CONH-. -CON (7/14/L,)-, -SC (-0)N (7/L, kill)-. -3C(=O')' NH-, -NH8O2NH-. -N(alkyl)SO2N(alkyl)-1-N(alkyl')so2NH-. -NI-ISO2N(alkyl)-, -〇(0-alkyl)-N-. -NH-N (alkyl)-NH-NH-, -N='N--C(-0)- , -C(=O) C(-0)-. -, CH(0-alkyl)-, -CH20(=O)-. -C(-0)CH2, -CH(alkyl')C(-0)-. -C(-0) CH (alkyl), '-CH-CH-. -C<alkyl)-CH-, -CH-C(alkyl)-1-C(alkyl)-C (Alkyl)-2-C(-0)CH-CH-. -P(Y)(Y44-alkyl)-2 substituted or unsubstituted -P(Y) (Y4 diaryl) or arylene, -8i (halogen) 2-, -3i (alkyl) )2-1-OC(-0)N(alkyl)-1-OCH20(=○)N(a (alkyl)-1-N(alkyl)-;-QC(-0)NH- , -NHCONH-. -8o2NHC(-0)NH-, -NHC(-3)NH. Polyhaloalkyl, polyoctaloacyl, polyhaloalkylsulfonyl or substituted is unsubstituted aroyl or arylsulfonyl, and Y43 and Y44 are each 0 or S), Z and z2 are respectively O, S, C1-C8 delkylidene, substituted or unsubstituted benzylidene, NH or NR'' (where R'' is alkyl, ali or aralkyl, aralkyl, alkenyl or alkynyl), Y67 and Y68 may be the same or different and are hydrogen or halogen. Alkyl, cyano, polyhaloalkyl, alkoxy, poly80alkoxy, halo Alkyl, alkyldio, alkylsulfinyl, alkylsulfonyl, nitro , aryl, polyhaloalkylsulfonyl, alkylamino, dialkylamino , acylamino, acyloxy, alkylsulfonyloxy, arylsulfony oxy, alkenylsulfonyloxy, haloalkylsulfonyloxy, poly Haloalkylsulfonyloxy, phosphono or phosphino. In the above formula, R69 is substituted or unsubstituted phenyl or 1- or 2-naphthyl, ×28 is NH, CH2 or a covalent bond, and z3 and Z4 are respectively O, S, C1~ C8 alkylidene, substituted or unsubstituted benzylidene, N)-1 or NR''( where Rrn is alkyl, aryl, aralkyl, alkenyl or alkynyl ) and YB2 and Y7° may be the same or different and are hydrogen and halogen. Alkyl, cyano, polyhaloalkyl, alkoxy, polyhaloalfoxy, halo Alkyl, alkylthio, alkylsulfinyl, alkylsulfonyl, nito b, aryl, polyhaloalkylsulfonyl, alkylamino, dialkylami No, acyl sulfonyloxy, polyhaloalyl sulfonyloxy, hoR70 isoxazole, isothiazole, pyrazole, imidazole, 1,2. 4-triazole, 1,2. 4-Oxadiazole. 1. 3. 4-oxadiazole, 1,2. 4-thiadiazole, 1,3. 4 -Thia1 diazole, oxazole, thiazole, benzopyrazole. Benzimidazole, benzoxazole, benzothiazole. Indole, virol, furan, thiophene, benzofuran. 5. ζdrive Q Benzothiophene, pyridine, pyrimidine, pyridanno, 1,3゜5-tria Jin, 1, 2. 4-triazine, quinoline, isoquinoline. Quinazoline, Phthalazine, Benzopyridazine, Benzopyrazine. Carbazole, dibenzofuran, dibenzothiophene, benzoxazine, phthal imides, benzobiranes, dibenzopyridines. Pyridopyridine, pyrazolopyrimidine, tetrahydropyrimidinedione, Kaigenmo → #piperazine, morpholine, tetrahydrofuran, tetrahydrothiophene, Pyrrolidane, thiomorpholine, piperidin-2-one, piperidin-2,6-di one, 2,5-pyrrolidinedione, 3-morpholine, 2-oxohexamethylene Imin. 2-oxotetramethyleneimine, 1-pyrazoline, 2-pyrazoline. Pyrazolidine, 2-imidazolidinone, 2-imidazolidinethione. 2. 4-imidazolidinedione, 1,2-oxathiolane, 1. 3-Oxathio Ran, 1. 3-oxathiane, 1,4-oxathiane, 2(1H)-bilazino 2H-pyran-2-one, 4H-bilan-4-one, 2H-pyran -2-thione, 4H-bilane-4-thione, tetrahydropyran. Tetrahydrobuobilane, 7-oxabicyclo[2,2,1]hebutane. , 7-azabicyclo[2,2,1]hebutane, oxetane, coumarin, 1°3- Substitution selected from dioxane, 1,4-dioxane and 1,3-dioxolane or an unsubstituted saturated or unsaturated aromatic or non-aromatic heterocyclic ring system; , -CH(alkyl)S(0)h-, -3(0)hCH2-. X is -CH(alkyl)O-, -C(alkyl)20-. -OCH-, -CHO-, -CH2-, covalent bond. -C (halogen>2. -0CH20-. -OCH, 2CH20-, -CtomiC-. -OCH(alkyl)-, -QC(alkyl)2゜-OCH(alkyl)O-, -OC(alkyl)20-. -OCH(alkyl)CH20-. -OCH(alkyl)OH(alkyl)O-1-CH(alkyl)CH(alkyl) )-1-CH(alkyl)-, -C(alkyl)2-1-OHCHO-, -O CHCH2-. -CH<full*ru> CHO-, -CH2CH2+. -CH(CN)0-, -C, (alkyl)(ON)O-. -CH(polyhaloalkyl)O-, -C(CN)-No-. -C(NHacyl)=NO-. -C[N (alkyl>23-No-). -〇(S-alkyl)-No-. -C(0-alkyl)-No-, -3C(-0)O-. -NHC(-0)O-, -N<furkyl)C(-0)O-. So, So2. -CI-123(0)h-. -C(alkyl)-C(alkyl)-2-QC(-3)S-, -C(=O)S- . -C(-0)CH=CH-. R″′ is alkyl, aryl, aralkyl, alkenyl is alkynyl ) and ``71 and Y72 may be the same or different and are hydrogen or halogen. Alkyl, cyano, polyhaloalkyl, alkoxy, polyhaloalkoxy, halo Alkyl, alkylthio, alkylsulfikylsulfonyl, amino, alkyl Amino, dialkylamino. Acylamino, acyloxy, alkylsulfonyloxy, arylsulfonyl Oxy, altanylsulfonyloxy, haloalkylsulfonyloxy, polyh loalkylsulfonyloxy, alkoxycarbonyl Nocarbonyl, dialkylaminocarbonyl, dialkylaminosulfonyl, a Lucylaminosulfonyl, aminosulfonyl. Dialkoxyalkyl, arylsulfonyl, phosphono or phosphino. In the above formula, R71' Substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloa Alkyl, cycloalkenyl, cycloalkashalkenyl, bicycloalkaje Nyl, tricycloalkyl. 6 Social Dictionary - Geiichi 4 Tricycloalkenyl or tricycloalkagenyl , 1OC+-1+, -CHO-, -CH2-, covalent bond. 1C (halogen), -OCH20-. 1OCto1(alkyl -OCH (7/l/ki/l/) CH20-. -OCH (alkyl/l/)CH (7/l/-t/l/)O-. -CH(alkyl)CH(alkyl)-. -CH(alkyl)-, -, C(alkyl)2-. -CH2CH20-, -OCH2CH2-. -CH (alkyl')CH O-, -CH CH2-. 1CH (CN)O-, -C (alkyl) (ON)O-. -CH (polyhaloalkyl)O-, -C (CN)-No-. -C (NH alkoxy-No-. -C[N(alkyl)21-No-. -C(S-alkyl)-NO-. 1C(0-alkyl)-No-, -SC (=O)O-. -NHC (-0)O-, -N (alkyl)C (=O)O-. So. So2. -CH2S (0), -, -CH (alkyl)S (0)h- , -8 (0) hCH2+. -QC (-S)S-, -C (-0)S-. -C(-8)-S-, -NH(alkyl)C(-0)S-. -, 0 (C-0)S-, -NH-, -N (alkyl)-. -N (R34)+, -so2NH-, -So2N (alkyl)-. -CONH-, -CON (alkyl)-. -SC (-0)N <full*ru)-', -SC (-0)NH-. -NHSO2NH-. 1N(alkyl)S02N(alkyl)-. -N(alkyl)SO2NH-. -NHSO N(alkyl)-, -C(0-alkyl)=N-. 1C (S-alkyl)=N-, -C)I (halogen)-. -C(alkyl)(halogen)-, -C)I(ON)-. -C(alkyl)(CN)-, -NH(alkyl)NH-. -NH-N (alkyl)-niNH-NH-. -N-N--C (=O) -, -C (-0)C (-0)-. -CH (0-alkyl)-, -CH20 (-0)-. -C (-0)CH2. -CH (alkyl) C (=O) -. -C (-0) CH (alkyl), -CH-CH-. -C(alkyl)-CH-, -CH-C(alkyl)-, -C(alkyl)- C (alkyl)-. -C (-0)CH-CH-. 1P (Y43) (Y4 dialkyl)-. Substituted or unsubstituted -P(Y) (Y4, -aryl) or arylene, - Si(halogen)-, -Si(alkyl)2-. 1OC (-0) N (alkyl)-. -OCH2C (=O)N (alkyl)-. -N(alkyl)CON(alkyl)-;-QC (-0)NH-, -NHCO NH-. -So2NHC (-0)NH-, -N) (C (-S)NH. h has a value of 0 to 2, and R34 is acyl or alkylsulfonyl. Polyhaloalkyl, polyhaloacyl, polyhaloalkylsulfonyl or substituted or unsubstituted 70yl or arylsulfonyl, and Y43 and Y44 are each is O or S), Z7 and Zi are respectively O, S, C1-C8 alkylidene, substituted or unsubstituted benzylidene, NH or NR” (where Rrtt is alkyl , aryl, aralkyl, alkenyl or alkynyl), Y73 and Y74 may be the same or different and are hydrogen or halogen. Alkyl, cyano, polyhaloalkyl, alkoxy, polyhaloalkoxy, halo Alkyl, alkylthio, alkylsulfinyl, alkylsulfonyl, nitro , aryl, polyhaloal 4; rusulfonyl, alkylamino, dialkylami No, acylamino, acyloxy, alkylsulfonyloxy, aryfursulfonyloxy Nyloxy, alkenylsulfonyloxy, haloalkylsulfonyloxy or It is polyhaloalkylsulfonyloxy. -CH2CH-C(CH3)0CH2-. -CHCH25CH2CH(CH3°)-2-COCH2C(CH3)2CH2 C0-1-COCH20)-1(C6H5)CH2Go-. -〇〇NH(06H5)CH2CH20-2-COC(CH3)2Nhco-. -CH2CH2N(C6H5)CH2CH2-1-CH2N(C6H5)φH2 cCH2-2-CH2CH2CH (06H5) CH2CH2-2-Co (CH2 )3Go-, -〇〇　(CH2)2co-. -CHCH2CH(CH3)CH2Co-. -COC)I (CH3)CH2Co-. -CoC(CH3)20H2co-0 -COC(CH-13)2C(CH3)2Co-. -Co (CH) Go-, -Go (CH2') 5Co-. -Co(CH2)5CH2-, -Co(CH2)4CH2-. -Go (CH2)3CH2-, -Co (CH2)2C1-12-. -COCH2SCH2Co-. -COCH2N (R52)CH2Co-. -COCH20CH2Co-, -COCH2SC8-. -COCH-CH-N-CH-. -CHCH(C6H5)CH2-N-CH- or -CO2-CH2CH2- the law of nature, Here, R52 is hydrogen, alkenyl, substituted or unsubstituted aryl, or alkyl is an aryl, Z and Z are respectively O, S, C-C8 alkylidene, substituted or unsubstituted ben Zylidene, NH or NR” (where Rrs is alkyl, aryl, aralkyl , alkenyl or alkynyl), Y and Y76 may be the same or different and are hydrogen and halogen. Alkyl, cyano, polyhaloalkyl, alkoxy, polyoctoalkoxy, halo Alkyl, alkylthio, alkylsulfinyl, alkylsulfonyl, nitro , acyl, polyhaloalkimino, acyloxy, alkylsulfonyloxy, acyl Rylsulfonyloxy, alkenylsulfonyloxy, haloalkylsulfony oxy, polyhaloalkylsulfonyloxy, phosphono or phosphino . In the above formula, R72 is substituted or unsubstituted phenyl or 1- or 2-naphthyl, ×31 is -CH2+, -CH2-, covalent bond. -C(halogen>, -CM:C-. -OCH(alkyl)-, -QC(alkyl)2゜-CH(alkyl)CH(alkyl)-, -QC(alkyl)2゜-CH(alkyl)CH(alkyl) (alkyl)-9-CH (alkyl), -, -C(alkyl)2-1So, -CH 5(0)h-. -CH (alkyl)S (0) 1+, -s (0) hCl-12-. -CH(halogen)-, -〇(alkyl)(halogen)-1-CH(CN)-, -C(alkyl)(CN)-. -C(=O)-, -CH(0-alkyl)-9-CH2O(-〇)-, -C(= O) CH2°-CH(alkyl)C(-0)-. -C(=O) CH (alkyl), -CH-CH-. -C(alkyl)-CH-, -CH=C(alkyl)-1-C(alkyl)-C (Alkyl)-1-C(=O)CH-CH-, arylene. -8i (halogen), -, -8i (alkyl) 2-9h is a value between 0 and 2. ), 2 is o, s, c-c8 alkylidene, substituted or device-exchanged benzylidene, NH or NR” (where RIM is alkyl, aryl, aralkyl, alkenyl) or alkynyl), Y, Y and Y2O may be the same or different and represent hydrogen, halogen, alkyl , hydroxy, cyano, polyhaloalkyl. ゛Alkoxy, polyhaloalkoxy, haloalkyl, alkylthio, alkyls Rufinil, alkylsulfonyl, nitro, acyl, polyhaloalkylsulfonyl alkylamino, amino. dialkylamino, acylamino, acyloxy, alkylsulfonyloxy, ´°Arylsulfonyloxy, alkenylsulfonyloxy, phospho or phosphino. It cannot be alkylamino, dialkylamino or acylamino, When Y and Y are the same halogen, Y2O can be hydrogen or human oxy do not have. In the above formula, R73 is isoxazole, isothiazole, pyrazole, imidazole, 1 ,2. 4-t-lyazole, 1,2. 4-Oxadiazole. 1. 3. 4-oxadiazole, 1,2. 4-thiadiazole, 1,3. 4 -thiadiazole, oxazole, thiazole, benzopyrazole. Benzimidazole, benzoxazole, benzothiazole. Indole, virol, furan, thiophene, benzofuran. 5-triazine, 1,2. 4-triazine, quinoline, isoquinoline. Quinazoline, Phthalazine, Benzopyridazine, Benzopyrazine. Carbazole, dibenzofuran, dibenzothiophene, benzoxazine, phthal imides, benzobiranes, dibenzopyridines. Pyridopyridine, pyrazolopyrimidine, tetrahydropyrimidinedione, -11 21 Bipe” lysine, morpholine, tetrahydrofuran, tetrahydrothiophene Viloridun, thiomorpholine, piperidin-2-one, piperidin-2. 6-Sion, 2,5-pyrrolidinedione, 3-morpholine, 2-oxohexame Tirenimine. 2-oxotetramethyleneimine, 1-pyrazoline, 2-pyrazoline. , pyrazolidine, 2-imidazolidinone, 2-imidazolidinethione. 2. 4-imidazolidinedione, 1. 2-oxathiolane, 1. 3-Oxathio Ran, 1,3-oxathiane, 1,4-oxathiane, 2(IH)-bilazino 28-Biran-2-one, 4H-Biran-4-one, 2H-Biran- 2-dione, 411-bilane-4-thione, tetrahydrobilane. Tetrahydrothiovirane, 7-oxazole o [2,2,11 hebutane. 7-Azabicyclo[2,2,13-butane, oxetane, coumarin, 1゜3-di Oxane, 1,4-dioxane and 1. Substituted group selected from 3-dioxolane or an unsubstituted saturated or unsaturated aromatic or non-aromatic heterocyclic ring system, ×32 is 100H2+, -c+2+, covalent bond. -C<halogen>, -C=C-. -OCH(alkyl)-, -QC(alkyl)2゜-CH(alkyl)CH(alkyl)-, -QC(alkyl)2゜-CH(alkyl)CH(alkyl) (alkyl)-1-CH(alkyl)-, -C(alkyl)2-9-OCH2CH2 -, -CH2CH2-, So, -3-. So2. -CH, 2S (0)i -. CH (Full Kill) S (0) h, -3 (0) 1. CH2+. -CH(halogen)-, -C(alkyl)(halogen)-2-CH(CN)- , -C(alkyl)(CN)-. -C(-0)+, -CH(0-alkyl)-1-CH,, C(-0)+, -c (-0) CH2°-CH (alkyl) C(-0)-. -C(-0) CH (alkyl), -CH-CH-. -C(alkyl)-CH-, -CH-C(alkyl)-1゜-C(alkyl)- C(alkyl)-1-C(-0)CH-CH-, arylene. -81(ha[]gun>2-, -3i<alkyl)2--C1l-C(alkyl) − is a value between 0 and 2), 2 is O, S, C1-C8 alkylidene, substituted or device-exchanged benzylidene, NH or NR” (where RJII is alkyl, aryl, aralkyl, alke nyl or alkynyl), Y, Y and YB2 may be the same or different and represent hydrogen, octogen, alkyl , hydroxy, cyano, polyhaloalkyl. Alkoxy, polyhaloalkoxy, haloalkyl, alkylna-1o, alkyls Rufinyl, alkylsulfonyl, nitro, acyl, polyhaloalkylsulfonyl alkylamino, amine. dialkylamino, acylamino, acyloxy, alkylsulfonyloxy, Arylsulfonyloxy, alkenylsulfonyloxy, haloalkylsulfonyloxy Nyloxy, polyhaloalkylsulfonyloxy, phosphono or phosphino. Ru. In the above formula, R74 is substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloal Kyl, cycloalkenyl, cycloalkagenyl, cycloaltrienyl, Cycloalkyl, bicycloalkenyl, bicycloalkagenyl, tricycloa Lukiru. ゛, -tricycloalkenyl or tricycloalkagenyl, X is -0CH2-, -'CH2-, covalent bond. -C (halogen), -CmiC-9 -QC)-1(alkyl)-, -QC(alkyl)2゜-CH(alkyl)CH (Alkyl)-2So2. -CH23(0) h-. -CH (alkyl)S (0) h-, -8 (0) hCH2+. -CH(halogen)-, -C(alkyl)(halogen)-2-CH(CN)+ , -c (7)L, kill) (CN)-. -C(-0)-, -CH(0-alkyl)-2-CH2O(-0)-, -C(- 0) CH2°-CH (alkyl) C(-0)-. -C(-0)CH<ful*ru), -CH-CH-. -C(7/L, */l,) -CH-', -CH-C(7/L, -1-/L, )knee. -C(alkyl)-C(alkyl)-2-C(-0)CI-1-CH-, ary Ren 2-3i (halogen) 2, Si (alkyl) 2-1Z13 is O, S; C 1-C8 alkylidene, substituted or unsubstituted benzylidene, N)] or NR" (where Rtn is alkyl, aryl, aralkyl, alkenyl or alkynyl) ) and YB2. YB2 and YB2 may be the same or different and may be hydrogen, halogen, or alkyl. Kyl, hydroxy, cyan, polyhaloalkyl. Alkoxy, polyhaloalkoxy, haloalkyl, alkylthio. alkylsul Finyl, alkylsulfonyl, nitro, acyl, polyhaloalkylsulfonyl , alkylamino, amino. dialkylamino, acylamino, acyloxy, alkylsulfonyloxy, Arylsulfonyloxy, alkenylsulfonyloxy, haloalkylsulfonyloxy Nyloxy or polyhaloalkylsulfonyloxy. The permissible substituents → in the above formulas (i) to (xxx i) may be the same or different. May contain one or more hydrogen, halogen. Alkylcarbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl Kyl, alkoxycarbonylalkylthio. Boliha O alkenylthio, thiocyano, propargylthio9. Hydroxyimino , alkoxyimino, trialkylsilyloxy, aryldialkylsilyl Oxy, triarylsilyloxy, formamidino, alkylsulfamide, Dialkyrus history 7mido, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy , amino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl Rubonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkyl Aminothiocarbonyl, nitro, cyano, hydroxycarbonyl and their rust temperature sensitivity , formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy cy, alkoxycarbonyl, substituted amino (in which case the permissible substituents are the same) may also be different, with one or two propargyl, alkoxyalkyl, alkyl Kylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalke ), alkylthio, polyhaloalkylthio, alkylsulfinyl, Polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nil. Alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl Rusulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl , aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts , phosphonic acid and its derivative salts °, alkoxycarbonylamino, alkylamino Carbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhalo Alkenyl, alkenyloxy, alkynyl. Alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhalo Alkynyloxy, polyfluoroalkanol, cyanoalkylamino, semi-alkylamino Rubazonomethyl, alkoxycarbonylhydrazotumethyl Ground or unsubstituted aryloxyiminomethyl, hydrazotumethyl, substituted or or unsubstituted arylhydrazotumethyl, mono-, di- or polysaccharide Human Ooxy group fused with do. Kyl, arylsulfinyl, arylsulfol, haloalkylsulfinyl , haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, loalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl , alkoxysulfonyl, aryloxysulfonyl, propargyloxy, 7 0yl, heroacyl, polyoctaloacyl, aryloxycarbonyl, aminosul Honyl, alkylaminoalkoxy. Lupoxyalkylthio, alkoxycarbonylalkoxy, acyloxy, halo Acyloxy, polyoctaloacyloxy, aroyloxy, alkylsulfonyloxy xy, alkenylsulfonyloxy, arylsulfonyloxy, haloalkyl Sulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino, halo Acylamino, alkoxycarbonyloxy, arysocyanato. isothiosia No, cycloalkylamino, trialkylammonium, arylamino, aryl (alkyl)amino, araalkylamino, alkoxyalkylphosphini Alkoxyalkyl phosphinodioil. Alkylhydroxyphosphinyl , dialkoxyphosphino, hydroxyamino, alkoxyamino, aryl oxyamino, aryloxyimino, oxo, thiono, alkylaminoalkoxy cy, dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkeni cyanoalkoxy, dialkylsulfonium, -X. -X. -X-R3. − X-R3. It is Y3R5. In the above formula, , YB2. YB2. YB2. Y65 and YB2 may be the same or different. Rogen, R1 is a monocyclic aromatic or non-aromatic ring system, bicyclic aromatic or R1 is a non-aromatic ring system. Substituted or selected from polycyclic aromatic or non-aromatic ring systems and bridged ring systems An unsubstituted carbocyclic or heterocyclic ring system, which ring system may be saturated or unsaturated. The permissible substituents can be the same or different and contain one or more hydrogen atoms. , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonyloxy, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano. Propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl Oxy, arylsial (kylsilyloxy). doarylsilyloxy, formamidino, alkyl sulfur group Amides, dialkylsulfamides, alkylsulfonyls, polyhaloalkoxys sulfonyl 2-hydroxy, amino, aminocardialkylaminothiocarbonyl, nitro, shea,), hydroxycarbo, derivative salts of mi-9, formamide, a alkyl, alkoxy, polyhaloalkyl may also be different, with one or two propargyl, alkoxyalkyl, alkyl Kylthioalkyl, alkyl, alkenyl; haloalkenyl or polyhaloalke ), alkyldio, polyhaloalkylthio, alkylsulfinyl, Polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nyl, alkylsulfonylamino, alkylcarbonylamino, boliha O alkyl Rusulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl , aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts . Phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Bonyloxy Kishi Alkynyl, alkynyloxy, polyhaloalkenyloxy. Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol Alkoxycarbonylhydrazotumethylnomethyl, substituted or unsubstituted Ryloxyiminomethyl. hydrazotumethyl, substituted or unsubstituted arylhydrazotumethyl, mono-, Hydroxy group, haloalkyl, haloalkyl group condensed with di- or polyzaracalide Kenyl, haloalkynyl. Alkoxyalkyl, aryloxy, aralkoxy, ary-ruthio, ara Alkylthio, alkylthioalkyl, arydioalkyl, arylsul Finyl, arylsulfonyl. haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, Haloalkynyloxy, haloalkynylthio. , haloalkenylsulfonyl, polyhaloalkenylsulfonyl. Alkoxysulfonyl, aryloxysulfonyl, propargyloxy, allo yl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl Nyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylami Nosulfoxy, acyloxy, quaternary heroacyl, polyoctatyloacyloxy, alloacyl yloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ary sulfonyloxy, haloalkylsulfonyloxy, polyhaloargylsulfonyloxy Nyloxy, aroylamino, haloacylamino, altoxycarbonyloxy . Toisocyanate, isothiocyano, cycloalkylamino. trialkylammonium, arylamino, aryl(alkyl)amine, a alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphos finothioil, alkylhydroxyphosphinyl, dialkoxyphosphino, Hydroxyamino, alkoxyamino, aryloxyamino, aryloxy imino, oxo, thiono, alkylaminoalkoxy. dialkylaminoalkoxy, alkoxyalkoxy, alco, xyalkenyl , cyanoalkoxy, dialkylsulfonium. -X, -X, -X-R3. -X-R3. Y3R5, or R1 is a substituted heteroatom or a substituted carbon atom, or two or more carbon atoms or is a substituted or unsubstituted compound containing a combination of foreign atoms and the following permissible substituents: Straight chain or branched chain, the substituents may be the same or different, and may contain one or more substituents. More hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl , alkoxycarbonylalkyl, alkoxycarbonylalkyldio, polyha loalkenylthio, naocyano, b0/margylthio, human0 ximino, al Koxiimino, trialkylsilyloxy, arylsial4ylsilyloxy , t, realylsilyloxy, boramamidino, alkylsulfamide, dia Rukylsulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, Hydroxy, amino, aminocarbonyl, alkylaminocarbonyl, dialkyl Ruaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl. dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and Derivative salts thereof, formamide, alkyl, alkoxy, polyhaloalkyl, polyhalogen loalfkyl, alkoxycarbonyl, substituted amino (in which case permissible substitutions The groups may be the same or different and may include one or two propargyl, alkoxyal Kyl, alkylthioalkyl, alkyl, alkenyl. haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloal Killthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkyls sulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkyl Servonylamino. Polyhaloalkylsulfonylamino, polyhaloalkylcal Bonylamino Kylsilyl, triarylsilyl, sulfonic acid and its 37 and 31 salts. Phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Bonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloal Kenyl, alkenyloxy. Alkynyl, alkynyloxy, polyhaloalkenyloxy. polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylaminol. Alkoxycarbonylhydrazotumethyl, alkoxy Iminomethyel. Aryloxyiminomethyl that has been purchased or not redeemed. hydrazotumethyl, substituted or unsubstituted arylhydrazonoloxy group, haloar Alkyl, haloalkenyl, haloalkynyl. Alkoxyalkyl, 71-noloxy, araalkoxy, arylthio, ara Alkyl f-o, alkylthioalkyl, ary-haloalkylsulfinyl, halo Alkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloal Quinylthio. Haloalkenylsulfonyl, bolihaO alkenylsulfonyl. Alkoxysulfonyl, aryloxysulfonyl, propargyloxy, allo yl, °haloacyl, polyoctaloacyl, aryloxycarbonyl, aminosul Honyl, alkylaminosulfonyl, dialkylaminosulfonyl, aryla Minosulfonyl, carboxyalkoxy, carboxyalkylthio, alkyl, poly Lihaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyl Sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy , polyhaloalkylsulfonyloxy, aroylamino, heroacylamino, a carbonyloxy Cycloalkylamino, trialkylammonium, arylamino, aryl (alkyl)amino, araalkylamino. Alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkoxyalkylphosphinyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, Alkoxyamino, aryloxyamino, aryloxyimino, oxo, thi Ono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxy Lukoxy, alkoxyalkenyl, cyanoalkoxy. dialkylsulfonium, -X. -X. Y3R5, X is a covalent double bond, a substituted or unsubstituted heteroatom, or a substituted carbon atom , or two or more carbon atoms or heteroatoms and the permissible substitutions of r A substituted or unsubstituted straight chain or branched chain containing a combination of groups, wherein the The substituents may be the same or different and contain one or more hydrogen, halogen, or alkyl Kylcarbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl , alkoxycarbonylalkylthio, polyhaloalkenyldio, thiocyano, Propargylthio. Hydroxyimino, alkoxyimino, trialkylsilyloxy, aryldi Alkylsilyloxy, triarylsilyloxy, formamidino, alkyl Sulfamide, dialkyl sulfamide, alkoxysulfonyl, polyhaloal Coxysulfonyl, hydroxy, amino, aminocarbonyl, alkylaminoca Rubonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylamino Notiocarbonyl, dialkylaminothiocarbonyl, nitro, cyano, hydro xycarbonyl and its li! salt, formamide, alkyl, alkoxy, poly Haloalkyl, polyhaloalkokyl, alkoxycarbonyl, substituted amino (this The permissible substituents may be the same or different and include one or two propal Gill, alkoxyalkyl. Alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloa rukenyl), alkylthio, poly-yakuchi alkylthio, al-4-rusulfi Nyl, polyhaloalkylsulfinyl, argylsulfonyl, boliha D al 4- Rusulfonyl. Alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfur Honylamino, polyhaloalkylcarbonyl bisono m S salt, alkoxycarbo Nylamino, alkylaminocarbonyloxy Kenyl, polyhaloalkenyl, alkenyloxy, alkynyl. Alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhalo Alkynyloxy, polyfluor[]alkanol, cyanoalkylamino, semi Rubazonomethyl, alkoxycarbonylhydrazotumethyl, alkoxyimino Methyl, substituted or unpurchased aryloxyiminomethyl, hydrazotumethyl , ground or unsubstituted arylhydrazotumethyl, mono-, di- or polysaccharide Hydroxy group fused with charride. Haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, ary ruoxy, aralkoxy, arylthio′. aralkylthio, alkylthioalkyl, arylthioalkyl, aryls Rufinyl, arylsulfonyl, haloalkylsulfinyl. haloal-A-nil Sulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthi E, haloalkenylsulfonyl, polyhaloalkenylsulfonyl. alkoxys rubonyl, arylaminosulfonyl, propargyloxy, aroyl, heroa sil, polyoctaloacyl, aryloxycarbonyl, aminosulfonyl, alkyl Ruaminosulfonyl. dialkylaminosulfonyl, arylaminosulfonyl, levoxyalco xy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy cy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfur Honyloxy, alkenylsulfonyloxy 9arylsulfonyloxy. Haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroyl Amino, haloazilamino, alkoxycaroxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylammonium, aryl amino. Aryl(alkyl)amino, araalkylamino, alkoxyalkylphosph alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, alkoxyalkylphosphinothioyl Nyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, ary oxyamino, aryloxyimino, oxo, thiono, alkylamino alkoxy, dialkylaminoalkoxy, alkoxyalkoxy, alkoxy Lukenyl, cyanoalkoxy, dialkylsulfonium, -X, -X, -X=R 3. -X-R3. Y3R5, or R36 is a monocyclic aromatic or non-aromatic ring system, a bicyclic aromatic young system, and The ring system may be saturated or unsaturated, and the permissible substituents may be the same or different. Often one or more hydrogen, halogen, alkylcarbonyl, alkylcarboxylate nylal4;ru, alkoxycarbonylalkyl, alkoxycarbonylalkyl ruthio, polyhaloalkenylthio, thiocyano, propargylthio, hydroxy imino, alkoxyimino, trialkylsilyloxy, aryl dialkyloxy Ryloxy, doarylsilyloxy, formamidino, alkylsulfami Do. Alkylamine carbonyl, dialkylaminocarbonyl, aminothiocarbonyl Le: ゛Alkylaminothiocarbonyl, dialpotonibisono = s-formamide , alkyl, alkoxy. Polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, @substituted amino ( In this case, the permissible substituents are the same or different alkenyl or polyhaloalkenyl groups. ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhalylthio loalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfur Honylamino, polyhaloalkylcarbonylamino, trialkylsilyl, ali dialkylsilyl, triarylsilyl. Sulfonic acid and its M11 salt, Phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Bonyloxy cy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkyl Nyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkyl Nyloxy, polyfluoroalkanol Alkoxycarbonylhydrazotumethyl, alkoxyiminomethyl, substituted or is unsubstituted aryloxyiminomethyl, hydrazotumethyl, substituted or unsubstituted aryl hydrazotumethyl, mono-, di- or polysaccharide Hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy Alkyl, aryloxy, aralkoxy, arylthio, aralkylthio , alkylthioalkyl, arylthioalkyl, aryl sulfinyl, Lyrsulfonyl. Haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy , haloalkynyloxy, haloalkynylthio. Haloalkenylsulfonyl, bolihaO alkenylsulfonyl. Alkoxysulfonyl, aryloxysulfonyl, propargyloxy, allo yl, haloacyl, polyoctaloacyl, aryloxycarbonyl, aminosulfonyl Nyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylami Nosulfoxy, acyloxy, haloacyloxy, polyheroacyloxy, alloyloxy yloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ary Rusulfonyloxy, haloalkyltrialkylammonium, arylamino , aryl(alkyl)amino, araalkylamino, alkoxyalkylphos finyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosph vinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, ali alkylamino, aryloxyimino, oxo, thiono, alkylamino Lukoxi. dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, Cyanoalkoxy, dialkyl sulfonium. , -X, -X, -X-R3, -X-R3. Y3R5, or R3 is a monocyclic aromatic or non-aromatic ring system, a bicyclic aromatic or non-aromatic ring group , substituted or unsubstituted selected from polycyclic aromatic or non-aromatic ring systems and bridged ring systems. Substituted carbocyclic or heterohydrogen, halogen, alkylcarbonyl, alkyl carbonylalkyl, alkoxycarbonylalkylbonylalkylthio, Lihaloalkenylthio, thiocyano. Propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl Oxy, aryldialkylsilyloxy. Haloalkoxysulfonyl, hydroxy, amino, aminocarbonyl, alkyl Aminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkyl Kylaminothiocarbonyl. dialkylaminothiocarbonyl MHI salt of Shikarupo Yuubiko. Formamide, alkyl, alkoxy, polyhalo alkyl Rubonyl, substituted amino (in which case permissible substituents may be the same or different) Often one or two propargyl, alkoxyalkyl, alkylthioalkyl , alkyl, alkenyl. haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloal Killthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkyls sulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkyl Carbonylamino-polyhaloalkylsulfonylamino, polyhaloalkylcal Bonylamino, trialkylsilyl, aryldialkylsilyl, triaryl Silyl, sulfonic acid and its derived salts. Phosphonic acid and its TA salt, alkoxycarbonylamino, alkylamino Carbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhalo Alkenyl, alkenyloxy. Alkynyl, alkynyloxy, polyhaloalkenyloxy. polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semi-rubazonomethyl, alphoxycarbonylhydra Zotumedel, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl. hydrazotumedel, substituted or unsubstituted aryl hydrazotumedel, mono-, Hydroxy group, haloalkyl, haloalkyl group condensed with di- or polysaccharide Kel, haloalkynyl. Alkoxyalkyl, aryloxy, araalkoxy, arylthio, araa Lukylthio, alkylthioalkyl, arylthioalkyl, arylsulfy Nyl, arylsulfonyl. haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, Haloalkynyloxy, haloalkynylthio. Haloalkenylsulfonyl, polyhaloalkenylsulfonyl. Alkoxysulfonyl, aryloxycarbonyl, propargyloxy, allo yl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl Nyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylami nosulfoxy, acyloxy, herooacyloxy, polyhaloacyloxy, alloacyloxy yloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ary sulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy Nyloxy, aroylamino, H[Jacylleaamino, alkoxycarbonyl xyarylsulfonylamino, aminocarbonyloxy, cyanato, isocyanate Buto, isothiocyano, cycloalkylamino. trialkylammonium, arylamino, aryl(alkyl)amino, a alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphos finothioil, alkylhydroxyphosphinyl, dialkoxyphosphino, Hydroxyamino, alkoxyamino, aryloxyamino, aryloxy imino, oxo, thiono, alkylaminoalkoxy. dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, Cyanoalkoxy, dialkylsulfonium. Y3R5, or R3 is a substituted heteroatom or a substituted carbon atom, or two or more carbon atoms or is a substituted or unsubstituted compound containing a combination of foreign atoms and the following permissible substituents: Straight chain or branched chain, the substituents may be the same or different, and may contain one or more substituents. More hydrogen. halogen, alkylcarbonyl, alkylcarbonylalkyl , alkoxycarbonylalkyl, alkoxycarbonylalkyldio, polyh loalkenylthio, thiocyano, propargylthio, hydroxyimino, alco ximino, trialkylsilyloxy, aryldialkylsilyloxy, Realylsilyloxy, formamidino, alkylsulfamide, dialkyl Sulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydro xy, amino, aminocarbonyl, alkylaminocarbonyl, dialkylami Nocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl. Ji? rukylaminothiocarbonyl, nitro, cyanide, human oxycarbonyl and That temptation salt. Formamide, alkyl, alfoxy. Polyhaloalkyl, po Lihaloalkokyl, alkoxy, carbonyl, substituted amino (in this case acceptable The substituents may be the same or different and may include one or two propargyl, alkoxy, Sialkyl, aruthioalkyl, alkyl, alkenyl. haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloal Kylthio, alkylsulfinyl, polyh〇alkylsulfinyl, alkyl Sulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkyl carbonyl, luponylamino, trialkylsilyl, aryl dialkyl Lyle, triarylsilyl, sulfonic acids and their derivative salts. Phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Bonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloal Kenyl, alkenyloxy. Alkynyl, alkynyloxy, polyhaloalkenyloxy. polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semi-rubazonomethyl, alfoxyluponylhydrazo methyl, alkoxyiminomethyl, substituted or un-Ha aryloxy Minomethyl. hydrazotumedel, substituted or unsubstituted arylhydrazotumethyl, mono-, Hydroxy group fused with di- or polysaccharide, haloalkyl; haloalkyl Kenyl, haloalkynyl. Alkoxyalkyl, aryloxy, aralkoxy, aryldio, araa Lukylthio, alkylthioalkyl, arylthioalkyl, arylsulfy Nyl, arylsulfonyl. haloalkylsulfinyl, octoalkylsulfonyl, haloalkenyloxy, Haloalkynyloxy, haloalkynylthio. Haloalkenylsulfonyl, polyhaloalkenylsulfonyl. Alkoxysulfonyl, aryloxysulfonyl, propargyloxy, allo yl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl Nyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylami Nosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxyca Rubonylalkoxy, acyloxy, heroacyloxy, polyhaloacyloxy , aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, Arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl Sulfonyloxy, aroylamino, heroacylamino, alphoxycarbonyl Oxy, arylsulfonyl amyl, aminocarbonyloxy, cyanato, iso Cyanato, isothiocyano. Cycloalkylamino, trialkylammonium, arylamino, aryl (alkyl)amino, araalkylamino. Alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkoxyalkylphosphinyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, Alkoxyamino, aryloxyamino, aryloxyimino, oxo, thi Ono, alkylaminoalkoxy, dialkylaminoalconvexoxy, alkoxy Lukoxy, alkoxyalkenyl, cyanoalkoxy. Dialkylsulfonium, -X, -X. It is Y3R5, Yl and Y4 are oxygen or sulfur, respectively, and Y2 and Y3 are oxygen, sulfur, or amino, respectively. or a covalent bond, and R4 and R5 are each hydrogen or a substituted or unsubstituted atom. alkyl, polyhaloalkyl, phenyl or benzyl, which are acceptable substitutable groups. may be the same or different and may contain one or more hydrogen, halogen, or alkyl carbon. carbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, alkylcarbonylalkyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, Coxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, propane lugylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy , aryldialkylsilyloxy, triarylsilyloxy, formamidi , alkyl sulfamide, dialkyl sulfamide, alkyl sulfonyl, Rihanyl, alkylaminocarbonyl, dialkylaminocarbonyl) Cicarbo ≦ and its derived salts, formamide, alkyl, alkoxy, polyhalo Alkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (in this case The permissible substituents can be the same or different (one or two propargyl , alkoxyalkyl, alkylthioalkyl, alkyl, alkenyl. haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloal Killthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkyls sulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkyl carbonylamino, polyhaloalkylsulfonylamino, polyhaloalkylcal Bonylamino, trialkylsilyl, aryldialkylsilyl, triaryl Silyl, sulfonic acid and its derived salts. Phosphonic acid and its ff1l salt, alkoxycarbonylamino, alkylamino Carbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhalo Alkenyl, alkenyloxy. Alkynyl, alkynyloxy, polyhaloalkenyloxy. polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo trimethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimide Nomethyl. hydrazotumethyl, substituted or unsubstituted arylhydrazotumethyl, mono-, Hydroxy group, haloalkyl, haloalkyl group condensed with di- or polysaccharide Kenyl, haloalkynyl. Alkoxyalkyl, aryloxy, araalkoxy, arylthio, araa Rukylthio, alkylthioalkyl, arylthioalkyl, ary, Rusulf ynyl, arylsulfonyl. Haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy , haloalkynyloxy, haloalkynylthio. Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarboni aminesulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl arylaminosulfoxy, acyloxy, herooacyloxy, 1 acyloxy, aroyloxy, alkylsulfonyloxy, alunils sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy9 Polyhaloalkylsulfonyloxy, aroylamino 9 haloacylamino, al Coxycarbonyloxy. isocyanato, isothiocyano, cycloalkylamino. Trialkylammonium, arylamino, aryl(alkyl)amine1. araalkylamino, alkoxyalkyl phosph, inyl, alkoxyalkyl Phosphinothioyl, alkylhydroxybosphinyl, dialkoxyphosphine No, hydroxyamino, alkoxyamino, aralkylamino, ary. ruoxiimino, quaternary, thiono, alkylaminoalkoxy. dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, Cyanoalkoxy, dialkylsulfonium. -X, -X, -X-R3, -X-R3゜Can be produced according to conventional methods, and in many cases each It will be commercially available from seed suppliers (SLII+DI+er). The present invention Novel nitrogen-containing complexes of the above formulas (i) to (xxx　i　i　i　) that can be used in the method Barocyclic compounds can be prepared from appropriate starting materials according to various conventional methods known to those skilled in the art, such as those described below. It can be produced by reacting substances. (Margin below) The novel nitrogen-containing heterocyclic compound of formula (i) can be prepared according to the following general reaction scheme: can be done. The general reactions described above for producing substituted pyridines, including reaction conditions, are as follows: For example, HertelJl, E., The Chemistry of Heter o-cyclic Compounds, Pyridine and Der tivatives-Part 2] alo-pyridines, p, 351. Interscienee, Wiley, New York (1961) Are listed. 2,4. Intermediates such as 6-drichloropyridine are U, S, P, 3. 830. 820. To produce a new compound of formula (1) Another way to do this is by Fu3HJ, C, Jdanced OrganicCh emistry, p, 124. Wiley, New York (1950) and 0chiai, E,, Aro-matic Am1ne Oxides, p , 21. Described in Elsevier, New York (1967) Ru. The novel nitrogen-containing heterocyclic compounds of formula (ii) are prepared according to the following general reaction scheme: can be done. In the above formula, R, Xb and Y28 have the same meanings as above. Sumire 25 11・ The general reaction described above for producing converted pyrazines, including the reaction conditions, is based on the following example: Bau, s, p, 4,254,125. The novel nitrogen-containing heterocyclic compound of formula (iii) can be prepared according to the following general reaction scheme: can be built. In the above formula, R, X, YY and Y23 have the same meanings as above, 26 12 21' 22 Yes, and Y49 is halogen. The above method for producing 2-substituted pyrimidines General reactions, including reaction conditions, are described by Hurst, D., T., An I. ntroduction to the Che II listry and 8 iochemlstry of Pyrimidines, Purines a nd Pteridines, pp, 49-53゜Wiley, New Y ork (1980). Where Y and Y23 are argylthio Interbody Eilings 4cld, H, and 5chevcrIllann. H,, Chem, Ber, -υ) O, p, 1874-1891 (1967) It is described in. Preparation of new compounds of formula (iii) such as Rambry-Hull pyrimidine synthesis A relaxed method for building is described by Brown, D. J., The Pyrimi dines；The Chemistry or Heterocyclic Compounds, pp, 98. 169-170゜166, Inters Cicnce, Wiley, New York (1960), / ing. The novel nitrogen-containing heterocyclic compound of formula (iv) can be prepared according to the following general reaction scheme: can be done. In the above formula, R2□, ×13. Y24. Y25. Y26 and Y49 have the same meaning as above be. The general reaction described above for producing 4-substituted pyrimidines is based on the reaction conditions. Including, for example, JO3+■a, T, et al., 5anky. ni enkyusho Newpo, 32. DI), 114-120 (19 80). The novel nitrogen-containing heterocyclic compound of formula (V) is prepared according to the following general reaction scheme: It can be done. In the above formula, R28,×14. Y2□, Y28, and Y29 have the same meaning as above. anti The above-mentioned general reaction and reaction conditions for producing 5-substituted pyrimidines, including reaction conditions. The preparation of intermediates and intermediates is described, for example, by Fi'eser, L. F., and Fieser, H., Organic Chemistry, p. 310. Heath. Boston (1972)/and Brown, D. J., The Py rimidines; ThelChemistry of Heterology clic Compounds, pp, 50. 166, Inter-sci ence, Wiley, New York (1962). The novel nitrogen-containing heterocyclic compound of formula (V+) is prepared according to the following general reaction scheme: can be done. are synonymous. The above-mentioned procedure for producing 3-substituted pyridazines including reaction conditions General reactions and preparation of intermediates are described, for example, by Jojima, r. et al., AOric , Biol, CheIll, , 32. (11), 1376-1381 ( 1968) and Eilingsfe! d, H., and Schevermann. ,　H,,Chem. Bar, 100, t874-1891 (1967) . The novel nitrogen-containing heterocyclic compound of formula (vii) can be prepared according to the following general reaction scheme: can be built. In the above formula, R3゜' × 16"33"34"35 and "49 are as above (1968 )It is described in. The novel nitrogen-containing heterocyclic compound of formula (viii) can be prepared according to the following general reaction scheme: can be manufactured. Reaction formula 8 In the above formula, Y, Y'Y, Y d, e, R31 and ×1736 371 38 ・　49゜ has the same meaning as above. Substitution 1, 3 including reaction conditions. 5-1-Production of riazines The above-mentioned general reactions and preparation of intermediates for ,478. Il, Sj), 2,824,823, Koopsan, H. et al., Rec, Tray, Chin, 78. 967-980 (i959 ), Drabek, J, and 5krObal, Ml, Che+++, Zvesti, 17. (7), 482-487 (1963), formerly “t. Ro et al., He1v, Chin, ^cta, 33. 13GS (1950) line up German patent 1. 076. 696. Novel formulation of formula (viii) Preparation of compounds and Chakrabarti, J. et al., J.’Cheffi , Sac, 861 (1974). can be manufactured according to the formula. Moxibustion person In the above formula, R3□, f. ×18. Y39. Y4o and Y49 have the same meanings as above . Substitution 1, 3 including reaction conditions. 5-) The above step 1 for producing riazine However, common reactions and intermediate preparations include, for example, U, S, P, 3,316,264. The above nth tail. 2. 4-shi’y　o　low 6-(jethoxyphosphinyl) Intermediates such as -1,3,5-triazine are described in Japanese Patent No. 7446635. There is. The method (7) and others (F) for producing the novel compound of formula (ix) is as follows: Hendoza, C, E, et al., J, Ag, Food O-hem,. 19, (1), 4l-45 (1972). can be manufactured according to the formula. In the above formula, Y41''4□, Y49 and x19 have the same meanings as above. The above steps for producing bis-1,3,5-triazines including reaction conditions The general reaction and preparation of intermediates are as described above for the preparation of the compound of formula (viii). It is similar to the method used for The novel nitrogen-containing heterocyclic compound of formula (xi) can be prepared according to the following general reaction scheme: can be done. In the above formula, R'''×20-Y52. Y53 and Y49 have the same meanings as above . Substitution 1, 3 including reaction conditions. The above-mentioned method for producing 5-t-lyazines General reactions and intermediate preparations produce compounds of formula (viii) as described above. is similar to the method used for For producing a novel compound of formula (xi) Other methods include A11ei+, C, F, H, and Converse, S ,, Org, Syn, Co11. , Vol. 1, 226-227. υ, S, P, 1,911,689. Be5Siere-C hretien, L and 5erne, H,, Bull, Soc, Cht m, France, (6), Part 2. 2039-2046 (1973 ), Japan Special Edition 128, 101. 8 patents 28,100. Japanese patent license 28. 0 98, Japanese Patent No. 9155. Loew, P, and -eis, C, D4. J. , Heter. cyclic Chew,, 13. 829-833 (1976) and Ric hter, G, H,. Textbook of Organic Chemistry, p, 486 ．． Wiley, New York (1967). The novel nitrogen-containing heterocyclic compound of formula (Xii) can be prepared according to the following general reaction scheme: can be built. In the above formula, R, X, Y, Y and Y49 have the same meanings as above and are 35, 21, 45 46 be. Heterocyclic substitution including reaction conditions 1, 3. For producing 5-triazines The above-described general reaction and preparation of intermediates for the above-described compound of formula (viii) 240 (1958) as well as British Patent 90 8. 352. The novel nitrogen-containing heterocyclic compound of formula (xiii) can be prepared according to the following general reaction scheme: Can be manufactured 6゜ In the above formula, R3□, R38, B14 and Y47 have the same meanings as above. Ber, 24, 495 (1891), Adembri, G., and Ted. esch,i,P,,Bull. J, B, et al., J, Hed, Chew, 20. (7), 934-9 39 (1977). The novel nitrogen-containing heterocyclic compound of formula (xiv) can be prepared according to the following general reaction formula: can be manufactured. General reactions and preparation of intermediates are described in 'Pahanayak, B., K., J. Ind. It is described in. Another method for preparing novel compounds of formula (xiv) is Tripathi, H., et al., Agric, Biol, Chell. 37. 1375 (1973) and young, T, E, and Am5t utz, E, D,, J,, Amber. Chem, Soc, 73. 4773-4775 (1951) Ru. The novel nitrogen-containing heterocyclic compound of formula (XV) can be prepared according to the following general reaction scheme: can be done. General reactions and preparation of intermediates include 5elia+, H, and Se11m, H. Bull, Soc, Chill, France, 1219-1220 ( 1967). The novel nitrogen-containing heterocyclic compound of formula (xvi) can be prepared according to the following general reaction scheme: can be built. Reaction formula 16 In the above formula, R41, R4□-"'15 and Y49 have the same meanings as above. Substitution 1, 3 including reaction conditions. The above polymers for producing 4-azoles are manufactured in the UK. It is described in Patent No. 913,910. The novel nitrogen-containing heterocyclic compound of formula (XV++) can be prepared according to the following general reaction formula: can be manufactured. In the above formula, R45, R46-R47' R48' 816 and Y48 are the same as above. It is righteousness. The above-mentioned method for producing substituted benzazoles including reaction conditions. General reactions and preparation of intermediates are described by Hugershofr A., Chew, Be. r,, 36. 3121-3134 (1903) and Young, T.E. , and Am5turz, E, D,, J, Awer, Chell, So c,, 73. 4773-4775 (1951). The novel nitrogen-containing heterocyclic compound of formula (xviii) can be prepared according to the following general reaction formula: It can be manufactured by In the above formula, R45, R46, R4□, R48,816 and Y48 have the same meanings as above. be. The above-mentioned procedure for producing 1-substituted benzisoxazoles including reaction conditions. The general reaction and production of intermediates are described in Comprehensive Heter cyclic Chemistry, Vow, 16. p, 58°Pe Described in rgamon Press, New York (1984) . The novel nitrogen-containing heterocyclic compound of formula (XiX) can be prepared according to the following general reaction scheme. can be built. In the above formula, R5o, B1□, "Y54. Y55 and Y48 have the same meanings as above. Substitution 1, 3 including reaction conditions. The above-mentioned general method for producing 5-triazines The reaction and production of intermediates used to produce the compound of formula (viii) above are similar to the method used. Others for producing the novel compound of formula (xix) The method is Beech. H, F,, J, Chew, Soc,, (C), 466-472 (196 7). The novel nitrogen-containing heterocyclic compound of formula (XX) can be prepared according to the following general reaction scheme: can be done. In the above formula, R51,81g, B19''56''57 and Y49 have the same meanings as above. be. Substitution 1, 3 including reaction conditions. The above for producing S-triazines The general reaction and preparation of intermediates are as follows: similar to the method used in The novel nitrogen-containing heterocyclic compound of formula (xxi) can be prepared according to the following general reaction formula: It can be manufactured by In the above formula, B2o, Y58. Y5° and Y49 have the same meanings as above. The novel nitrogen-containing heterocyclic compound of formula (xx　i　i　) can be expressed by the following general reaction formula: Therefore, it can be manufactured.

【え盃ム上記式中、Ｒ５３，Ｘ２５−”　６０．Ｙ６１及びＹ４９は前記と同義である。反応条件も含めた置換１，３．５−トリアジン類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似しているつ式（ｘｘ　ｉ　ｉ　＋　）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ５４、Ｘ２６”　５０及びＹ５１は前記と同義である。反応条件も含めたヘキサヒドロ−１，３，５−ｊ−リアジン類を製造するための上記した一般的な反応及び中間体の製造は、例えばＨｅｙｅｒｓ、　Ａ、　１．ら、Ｊ、　Ａｍｅｒ、　Ｃｈｃｖ、　Ｓｏｃ、、９１．７６３（１９６９）に記載されている。適当な中間体の製造は、上記式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似している。式（ｘｘｉｖ）の新規な窒素含有複素環化合物は、次の一般的な反９式に従って製造され得る。上記式中、Ｒ，ＸＺ、Ｚ、Ｙ６□及びＹ６８は前記と６８　２７・　１２、めの上記した一般的な反応及び中間体の製造は、例えば日本特許７５，１１７，９２９に記載されている。式（ｘｘｉｖ）の新規な化合物を製造するための他の方法は、Ｕ、Ｓ、Ｐ、３，１２９，２２５並びに日本特許７５．１３２，１２９に記載されている。式（ＸＸＶ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。式（ｘｘｖｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ７ｏ、×２９．゛ｚ５．Ｚ６．Ｙ７１及ＣＦ　Ｙ　７２　ハ前記と同義である。反応条件も含めた置換マレイミド類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ＸＮＶ）の化合物を製造するために使用される方法と類似している。式（ｘｘｖｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ、Ｘ　、Ｚ　、Ｚ８．Ｙ７３及びＹ７４は前記と同義である。反応条件も含めた置換マレイミド類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ｘｘｉｖ）゛の化合物を製造するために使用される方法と類似している。式（ｘｘｖｉｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｂ　２１．Ｚ　ｇ　、　Ｚ　１０’　Ｙ　７５及Ｕ　Ｙ　７６ＧｉｌｔＪ　記ト同’ａテある。反応条件も含めた置換マにイミド類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ｘｘｉｖ）の化合式（ｘｘｉｘ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。ある。適当なハロゲン化剤には、例えばＰＣＮ　５．ＰＯＣｊ　３゜反応及び中間体の製造は、例えばＹｕｋｉ　Ｇｏｓｅｉ　Ｋａｇａｋｕ　ＫｙｏｔａｉＳｈｉ　２ｇ、　（４）、　４６２−４６３（１９７０）に記載されている。式（ＸＸｉＸ）の新規な化合物を製造するための伯の方法は、’／ａｋｕｇａｋｕ　Ｚａｓｓｈｉ８６、　（１２）、　１１６８−１１７２（１９６６）、Ａｃｔａ　Ｄｏｔ、　Ｐｈａｒ＋＋＋、３６．　（３）、　３０１−３０６（１９７９）、　Ｕ、Ｓ、Ｐ、２，９６３，４７７、日本特許６，８２２，３０９．Ｏｒｇ、　Ｐｒｅｐ。Ｐｒｏｃｅｄ、　Ｉｎｔ、　１７．　（２）、　１０７−１１４（１９８５）、　Ａｒｌ１１．に旧ｒａ、　Ｚｈ、　２１゜（６）、５１５−５２０（１９６８）並びにドイツ特許１，９４８，５５０に記載されている。式（ＸＸＸ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。周れである。反応条件も含めたＥ換ビリダジノン類を製造するための上記した一般的な反応及び中間体の製造は、上記式（ｘｘｉｘ）の化合物を製造するために使用される方法と類似している。式（ＸＸＸｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。上記式中、Ｒ７４，Ｘ３３，２１３−Ｙ８３．ＹＢ２及びＹ８５は前記と同義である。反応条件も含めた置換ビリダジノン類を製造する。ための上記した一般的な反応及び中間体の製造は、上記式（ｘｘｉｘ）の化合物を製造するために使用される方法と類似している。式（ＸＸＸｉｉ）の新規な窒素含有複素環化合物は、次の一般的な反応式に従って製造され得る。ＲｌＸ−Ｈ＋Ｙ４ｇ−Ｒ３６→　Ｒ１−Ｘ−Ｒ３６上記式中、Ｒ１，Ｘ、　Ｒ’ ３６及びＹ４９は前記と同義である。反応条件も含めた置換非対象化合物類を製造するための上記した一般的な反応及び中間体の製造は、適当な出発物質を用いて上記式（ｖｉｉｉ）の化合物を！ＩＩ造するために使用される方法と類似し上記式中、Ｒ１”　６２．Ｙ６３．ＹＢ２．ＹＢ２”　６６及びＸは前記と同義である。反応条件も含めた置換シクロホスファゼン類を製造するための上記した一般的な反応及び中間体の製造は、適当な出発物質を用いて上記式（ｖｉｉｉ）の化合物を製造するために使用される方法と類似している。上記した方法に加えて、式１に包含される窒素含有？！１素環化合物の製造に使用される他の方法が例えば以下に示す刊行物に記載されている。イタリー特許５８９．５４３．イタリー特許５８８゜２８０、英国特許８７２，３１３．カナタ特許６５９，６１０．　ＰＣＴ出ＩＪ　ＡＵ８１１０００４６、　Ｕ、Ｓ、Ｐ、３，２０３，５５０　、　Ｕ、Ｓ、Ｐ、　３，９３１，１６５゜ｔｌ、　Ｓ、　Ｐ、２，７２０，４８０．　Ｕ、Ｓ、Ｐ、　４，０３８，１９７．　ｔｌ、ｓ、Ｐ、　３，６８２，９０３゜Ｕ、Ｓ、Ｐ、　３，７７５，４０６．　Ｕ、Ｓ、Ｐ、　３，９３２，１６７、　ｔｌ、ｓ、Ｐ、　４，３９０，５３８゜Ｕ、Ｓ、Ｐ、　３，３６１，７４６．　Ｕ、Ｓ、Ｐ、　４，４１４，２２１．　Ｕ、Ｓ、Ｐ、　４，２３７，１２７゜ｕ、ｓ、ｐ、３，９５１，９７１及Ｕ　ｔｌ、ｓ、　Ｐ、３，９７３．９４７：式１を有する発散防止（ａｎｔｉｔｒａｎｓｐｉｒａｎｔ）化合物は、植物及び作物の水使用１（発散率）を有意に減少させると同時に水蒸気（ｍｏｉｓｔｕｒｅ　ｖａｐｏｒ）損失に対する植物葉表面の耐性（拡散耐性：ｄｉｆｆｕｓｉｖｅ　ｒｅｓｉｓｔａｎｃｅ）を高めることが知見された。更に、本発明で使用される発散防止化合物は、光合成の光要求反応（ｌｉｇｈｔ−ｒｅｑｕｉｒｉｎｇ　ｒｅａｃｔｉｏｎｓ）を実質的に阻害せず、生育植物に対して実質的な植物薬害を示さず、且つ同様な条件手での未、処理作物に比べて、特に植物が水分圧迫状態（ｌＩｌｏｆｓｊＬＩｒ（！　５ｔｒｅｓｓＣＯｎｄｉｔｉＯｎＳ）を被る地域において作物収率を増大させるのに役立つ。本発明で使用される発散防止化合物は、成る発達期間例えば生育期間植物及び作物の水使用量を抑制することによって例えば生殖期間に未使用の水を利用することが可能となる。上記した如く気孔は植物葉表面の上皮における微細な開孔であり、これを介して葉内部の細胞間空間と大気との間で気体の交換が行なわれる。式１を有する発散防止化合物は植物の気孔は光合成の電子流に対して実質的な悪影響を及ぼさないと推定される。植物における光合成反応は、光−要求反応即ち明反応と光−不要求反応即ち暗反応とからなる。暗反応は通常、二酸化炭素を必要とする。暗反応は二酸化炭素に加えて、光反応により産生、提供される化学エネルギー及び還元力を必要とする。通常、植物の光合成には２種の光−要求反応が関与しており、これらの反応は便宜的に光化学系工及び光化学系■と称される。例え、ば、５ａｌｉｓｂｕｒｙ、　Ｆ、　Ｂ、及びＲｏｓｓ、　Ｃ，Ｌ、　Ｐｌａｎｔ　Ｐｈｙｓｉｏｌｏｏｙ、ｐ。１３１−１３５（１９７８）を参照されたい。これらの光化学系は電子伝達鎖（ｅ＋ｅｃｔｒｏｎ　ｔｒａｎｓｐｏｒｔ　ｃｈａｉｎ）によって相互に関連しており、暗反応に対して還元力と化学エネルギーを提供する。これらの光化学系の一方若しくは両方が阻害されると光合成が悪影響を受け、植物が損害を受けたり枯死したりさえする。本発明で使用される発散防止化合物は全く若しくは実質的に全く光化学系１又は光化学系■を阻害しないことが判明した。対照的に、除草剤アトラジンは光合成の光反応、特に電子伝達鎖を実質的に阻害することが公知である。例えば、′Ｊａｃｈｅｔｔａ。Ｊ、　Ｊ、及びＲａｄｏｓｅｖｉｃｈ、　Ｓ、　Ｒ，、Ｗｅｅｄ　５ｃｉｅｎｃｅ　２９：３７−４３（１９８１）を参照されたい。前記した除草阻害（ｈｅｒｂｉｃｉｄａｌ　１ｎｈｉｂｉｔｉｏｎ）によって葉内部に二酸化炭素が蓄積され、気孔が塞がれる。例えば、Ｓｍ１ｔｈ、Ｄ、及びＢｕｃｈｈｏｌｔｚ、に、　Ｐ、、　Ｐｌａｎｔ　ｐｈｙｓｉｏ＋ｏａｙ　３９：５７２−５７８（１９６４）を参照されたい。従って、本発明で使用される化合物の発散防止活性とは異なり、アトラジンの発散防止活性はその除草活性と関連している。本明細書において、光合成の電子伝達が実質的に阻害されないことは光合成の電子伝達が全く若しくは殆んど阻害されないことを意味する。本明細書において、窒素含有複素環化合物の植物からの水分損失を減するための有効量とは、植物の光合成の電子伝達を実質的に阻害することなく植物からの発散による水分損失を減するに十分な化合物の発散防止有効ｆｆｉ　（ａｎｔｉｔｒａｎｓｐｉｒａｔｉｏｎａｌｌｙｅｒｒｅｃｔｉｗｅ　ａ＋１ｏｕｎｔ）を意味する。同様に、窒素含有複素環化合物の植物収率を増大させるための有効量とは、植物の光合成の電子伝達を実質的に阻害することなく植物の収率を増大させるａｍｏｕｎｔ）を意味する。何れにおいても、化合物の有効量は使用される化合物の種類、処理すべき作物の種類、環境及び気象条件等に応じて広範囲で変更可能である。但し、化合物の使用」は植物の光合成の電子伝達を実質的に阻害したり、植物に対して実質的な薬害（例えば菓が焼ける。白化する。１！ｌ死する）を与える聞ではない。一般的に、以下により詳しく記載する如く化合物は１アール当り化合物的０．２５〜１５ボンドの濃度で植物及式１を有する窒素含有複素環化合物は、当業者に公知の各種慣用方法に従って使用され得る。活性成分として化合物を含有する組成物は、通常液体若しくは固体のキャリア及び／又は希釈剤を含む。濃厚物は、これら化合物の１種をアセトン、キシレン、ニトロベンゼン、シクロヘキサノン又はジメチルホルムアミドの如き非植物毒性（ｎｏｎｐｈｙｔｏｔｏｘｔｃ）溶媒を用いて溶解させ、適当な表面活性乳化及び分散剤を用いて水に活性成分を分散させて製造される。分散及び乳化剤の種類及び使用量は、組成物の性質及び薬剤の活性成分を分散させる能力に応じて設定される。通常、山によって植物に適用後の活性成分が再乳化したり植物から洗い落ちることがないように活性成分をスプレーに所望通りに分散させつつ、出来るだｌツ少聞の薬剤を使用することが望ましい。ノニオン、アニオン又はカチオン性分散及び乳化剤、例えばアルキレンオキシドとフェノールの縮合生成物、有機酸、アルキルアリールスルホネート、複合エーテルアルコール、第４アンモニウム化合物等が使用される。水和性粉末若しくは微粉組成物を作成するときにはミ活性成分を適当に分割された固体キャリア例えばクレー、タルク、ベントナイト、ケイ藻±、フラー上等の内部及びその上に分散させる。水和性粉末を作成するときには、上記した分散剤及びリグノスルホネー１−を包含させてもよい。本発明における活性成分の所要色は、処理すべぎ１アール当り　１〜２００ガロン又はそれ以上の液体キャリア及び／又は希釈剤、約５〜５００ボンドの不活性の固体キャリア及び／又は希釈剤に適用され得る。液体Ｓ厚物における濃度は通常約５〜９５重量％であり、固体製剤における濃度は約０゜５〜９０重量％である。一般的用途における効果的なスプレー又は微粉は１アール当り約０．１〜１００ボンド、好ましくは約０，２５〜１５ボンド、より好ましくは約０，５〜５ボンドの活性成分を含む。本発明を実施する際に有用な製剤（ｆＯｒｌｌＬＩＩａｔ＋ｏ１１）は、活性成分′の活性を減じたり処理すべき植物に害を与えない限り、安定化剤のような他の任意成分又は他の生物学的に活性な化合物を含んでいてもよい。伯の生物学的に活性な化合物には、例えば１種若しくはそれ以上の殺虫剤７除草剤、殺菌剤、殺線虫剤。殺ダニ剤、植物生長調節剤又は他の公知の化合物が包含される。各成分の公知の目的又は他の目的に応じて前記化合物を組合せて使用してもよく、相乗効果を期待することもできる。好ましくは、式１を有する発散防止化合物を水圧迫が実質的に全く若しくは殆んどない状態下、或いは平均的若しくは正常な生育状態下で植物及び作物に適用される。化合物の好ましい適用条件は実質的な土壌水分損失の前である。特定の理論に縛、られるつもりはないが、発散防止化合物を適用すると処理植物若しくは作物における水の最小総必要量（ｍｉｎｉｍｕｗ＋　ｔｏｔａｌ　ｗａｔｅｒｒｅｑｕｉｒｅｍｅｎｔｓ）が減少するのではなく、前記化合物の適用により処理植物及び作物による水の利用がより有効に行なわれるものと推定される。発散防止効果は所与の植物又は作物の塊゛長に必要な水の総量を減するのではなく（特定の作物では潅概により節水が実施され得る）、前記発散防止効果により同様な条件下での未処理作物に比べて８１両及び降雨が全く若しくは殆んどない場合の処理作物の収率を増大させることができる。又、式１を有する発散防止化合物は好ましくは、葉内部の飽和大気圧と葉周囲の大気圧との水蒸気圧差がかなり大きい状態下で植物及び作物に適用する。前記状態には、大気の湿度が低い場合。葉における光／熱負荷が高い場合及び空気の移動速度が速い場合が包含される。、特に、式１を有する発散防止化合物を植物に例えば植物の生育段階で適用すると、植物により利用（消費）される水の旦を約１〜６週間に亘り抑υｌすることができ、よって他の発達期間例えば重要な生”殖生育期間（ｒｅｐｒｏｄｕｃｔｔｖｅ　ｇｒｏｗｔｈ　ｐｈａｓｅ）に土壌中の利用可能な水の保存ｍはより多くなる。このように土壌水分が保存されると、重要な発達期間例えば生殖生育期間中植物組織内における水分の不足を最小限に抑えることができ、従って作物の収率を高めることができる。本発明で使用される発散防止化合物を植物の生殖生育期間に適用しても、同様の結果を得ることができる。通常、式１を有する発散防止化合物は、特に乾燥気候地域の潅概水の必要量を少なくするために、移植又は積荷中成いはひどい寒冷気候のときに植物を立枯れや他の損害から保護するために及び上記した如き成る種の環境下での水の圧迫（ｗａｔｅｒＳｔｒ８ＳＳ）を緩和するために有用である。前記化合物は農業、園芸及び関連分野で有用であり、冬枯れを防止すべく草木例えば非落菓性観賞潅木、常緑樹、８１木等に適用することも可能である。冬枯れの主な原因は、路面が凍つ物を、新鮮さを保ち且つ水滴（ｎｅｅｓ＋ｅ　ｄｒｏｐ）を遅らすために他の観賞植物例えばバラや他の花、クリスマスツリー等に適用することも可能である。更に、発散防止化合物は夏の熱気や移植のショックを解消若しくは最小限に抑えるべく使用され得る。上記したことに加えて、式１を有する発散防止化合物は作物例えば小麦やオート麦における葉の病気（ｆｏｌｉａｒ　ｄｉｓｅａｓｅｓ）を二】ントロールするためにも使用されることが判明した。例えば、＾ｗａｎｔ　Ｇａｒｄｅｎｅｒ、　Ｖｏｌ、１８．　Ｎｏ、１．　Ｎｏｖｅｍｂｅｒ、　１９８５を参照されたい。この文献には、発散防止剤を菌病をコントロールすべく使用する旨が記載されている。本明細占において、植物とは一般に農業若しくは園芸作物。観賞植物及び芝生を意味する。本発明方法に従“つて式１を有する発散防止化合物により処理され得る植物の例には、コーン。綿、サツマイモ、ジャガイモ、アルフ？ルフ７．小麦、ライムギ、高地米（ｕｐｌａｎｄ　ｒｉｃｅ）　、大麦、オート麦、モロコシ、ドライビーンズ、大豆、サトウダイコン、ヒマワリ、タバコ、トマト、カノラ（ｃａｎｏｌａ）、落葉性果実類、柑橘類、紅茶、コーヒー。オリーブ、パイナツプル、ココア、バナナ、サトウキビ、ギネアアブラヤシ、草木性花壇用植物、？１１木、芝生、装飾用植物。常緑樹、ｓｌ木、花等が包含される。本明細書において、作物とは一般に上記した農業若しくは園芸作物を意味する。本明細書において、移植されたストックとは一般にタバコ、トマト、ナス、キュウリ、レタス、ストロベリー、草木性花壇用植物、？１木、ＩＩ木の苗等を意味する。本発明の発散防止化合物は、植物からの水分損失を減じ且つ作物の収率を高める。前記化合物は、発散防止効果又は収率増大効果を得るのに十分な量を使用したときにも極めて安全であり、植物の光合成の電子伝達を阻害することもないし植物を焦がしたり若しくは傷つけることもない。また、前記化合物は、雨による流出（ｗａｓｈ−ｏＨ）を含めた風化、紫外線による分解、酸化又は水分の存在下での加水分解に対して耐性を示すか、又は少なくとも活性成分の所望の発散防止特性を著しく低下させたあろう前記分解、酸化及び加水分解に対して耐性を示す。所望により活性成分の混合物を使用してもよく、又活性成分と前記した如き他の生物学的に活性の化合物若しくは成分との組合せを使用してもよい。以下、本発明の実施例を示す。（以下余白）２．４−ジクロル−６−（４−メチルフェニルチオ−１３５−ト１　ジ゛艮Ｌアセトン２００ｄ中に塩化シアヌル１８．４ｇ（０，１モル）を含有する溶液中へ、０〜５℃の温度で冷却しながらかつ磁気攪拌しながらアセトン５０ｄ中に４ −メチルチオフェノール１２．４９　（０，１モル）と２，６−ルチジン１０．７９　（０，１モル）とを含有する溶液を添加した。した。得られた混合物を２時間にわたり磁気攪拌し、！温まで加温しかつ沈澱した２、６−ルチジン塩酸塩をＰ別し、かつアセトンで洗浄した。次いで、Ｐ液を合して氷上に注ぎ込み、かつ得られた沈澱固体を濾過によって集めた。この固体を１１００ａの１０固体をヘキサンから２回再結晶して、５ｇの粗生成物を得た。この物質をさらに減圧昇華により精製して１．１６ＳＦ　（０，００４モル）の純粋な２，４−ジクロル−６−（４−メチルフェニルチオ）−１，３，５−トリアジンを得、これは１１２〜１１４℃の融点を有した。生成物の元素分析は次の通りであった：分　析：　Ｃ１ｏＨＩ　Ｃ１２Ｎ３　Ｓ計算値：　Ｃ，４４，１３：　Ｈ，２，５９：　Ｎ、　１５．４４実測値；　Ｃ，４４，２４：　Ｈ，２，６１：　Ｎ、　１５．３４この化合物を以下化合物１と称する。実施例工に用いたと同様な方法で他の化合物を製造した。植物からの水分損失を減少させるため後記の実施例で使用する化合物２〜３６の構造および分析データを下記表Ａに示す。化合物１８はＨａｙｂｒｉｄｇｅ　Ｃｈｅａ＋１ｃａｌ　Ｃｏｍｐａｎｙ、Ｌｉｍ１ｔｅｄ、Ｔｒｅｖｉｌｌｅｔ、Ｔｉｎ−ｔａｇｅｌ、　Ｃｏｒｎｗａｌｌ、英国から得たものであり、ヘキサンから３回再結晶化させた。表　Ａ代表的窒素含有複素環化合物 ◆　島　ｊ　かセ＾　−− 表　Ａ　（続き）ｉ」旌ｌ見含有複素環化合物表　Ａ　（続き）虹紅Ｚ久１に長ユＬユニえ文旦±ユ土り土上上玉上上上±１乏分　析　：　Ｃ９Ｎ３　Ｃ１４Ｎ３０計算値：　Ｃ，３４，７６：　Ｈ，０，９７；　Ｎ、　１３．５１実測値：　Ｃ、３４，３０：　Ｈ、０，８９：　Ｎ　、　１３．８０この化合物を以下化合物３１と称する。Ｕ−亘−−１実施例■に用いたと同様な方法で他の化合物を製造した。植物からの水分損失を減少させるため後記の実施例で使用する化ｌ工代表的窒素含有複素環化合物哀−１二？Ｉ　Ｖ２−゛　ロルー４６−ピス　２°４°−ジクロルフェノキシ”）　−１，３，５ −Ｅ火ヱえ之ユ１１アセトン１００ｄ中に塩化シアヌル９．２ｇ（０，０５モル）を含有する溶液中へ、０〜５℃の温度で冷却しながらかつ磁気攪拌しながら、ｓ、１５ｇ（０，０５モル）の２．４−ジクロルフェノールと７．２５９（ｏ、ｏｓモル）６炭酸カリウムとを添加した。これらの成分を、０〜５℃の反応温度を維持するような速度で添加した。この混合物を氷上に注ぎ込み、かつ得られた固体沈澱物を濾過によって集め、ｉｏｏ、１の１０％水酸化ナトリウム水溶液および次いで水で洗浄した。乾燥後、固体をヘキサンから再結晶化させた。最初の結晶分をヘキサンから２回再結晶化させて、１６５〜１６８℃の融点を有する２−クロル−４，６− ビス（２°、４−ジクロルフェノ４；シ）−１，３，５−トリアジン２．０ｇ（０，００５モル）を得た。生成物の元素分析は次の通りである：分　析　二　０１５Ｈ６０１５Ｎ３０□計算値：　Ｃ，４１，１８：　Ｈ，１，３８：　Ｎ、　９．６０実測値：　Ｃ，４１，４１；　Ｈ，０，９６：　Ｎ、　９．８にの化合物を以下化合物４６と称する。衷−」Ｌ一旦−ｖｉ２．４−ジクロル−６−（３°５°−ジクロルフェノキシ−１３５−トＩ　ジンの製造アセトン１５Ｉｄ中ニ３，５−ジクｏルア　ｘ　／　−）ＬｔＳ：２４’Ｊ　（０，０３２モル）を含有する０〜５℃の温度まで冷却された溶液へ２．６−ルチジン３．４５９　（０，，０３２モル）を添加し、次いでアセトン１８５ａ！！中の塩化シアヌル５．９３ｇ（０，０３２モル）の溶液を添加した。塩化シアヌル／アセトン溶液を滴加しながら、０〜５℃の反応温度を維持した。供給を完了した後、攪拌を約θ℃の温度で１時間続け、次いで混合物を室温まで加温した。ルチジン塩酸塩を濾過によって除去し、かつＰ液を木炭（ｃｈａｒｃｏａｌ）で処理し、セライトを通して濾過した。アセトン溶液から減圧下で溶剤を除去し、残留物をトルエン中に溶解させた。この溶液を０．５Ｍ　Ｎａ０Ｈ（２回）、次いで水によって洗浄し、ＨｇＳＯ４で脱水しかつ減圧蒸発させて粗製固体生成物９．１ｇを得た。ヘキサンからの再結晶および減圧昇華により、１０９〜１１１ ℃の融点を有する純粋な２．４−ジクロル−６−（３°、５−ジクロルフェノキシ）−１，３，５−トリアジン１．０ｇ（０，００３モル）を得た。生成物の元素分析は次の通りであった：分　析　：　Ｃ９Ｎ３　Ｃ１４ＯＮ３計粋値：　Ｃ，３４，７６：　Ｈ，０，９７；　Ｎ、　１３．５１実測値：　Ｃ，３４，４１：　Ｈ，０，９０：　Ｎ、　１３．３３この化合物を以下化合物４７と称する。実　施　例　■ ４．６−ジク０ルー２−（３’−９メチルアミノ入エノキシ）一旦１士士」−アジンおよび６−クロル−２，４−ビス−（３−ジメチルアミノフェノキシ）−１，３，５−トリアジンの１遺乾燥テトラヒドロフラン１００ｄ中にＮａＨ（油中５０％）４．２９（０，０９モル）を含有する懸濁物へ、乾燥テトラヒドロフラン２００ｄ中に３−（Ｎ、１４−ジメチルアミノ）フェノール１０．０ｇ（０，０７モル）を含有する溶液を４℃の温度で滴加した。この混合物を′ｇ温まで加温し、添加漏斗に移し、かつ乾燥テトラヒドロフラン１００ｔｆＪ中に塩化シアヌル１３．４ｇ（０，０７モル）を含有する溶液中へ０℃で滴加した。この混、合物を０℃にて３時間攪拌し、蒸発させかつ残留物を熱ＣＨ２Ｃｌ２で抽出した。このＣＨ２Ｃｌ２溶液を蒸発させ、かつ残留物をヘキサン中の５％ＥｔＯＡＣを用いるＦｌｏｒｉｓｉ　ＩＯ上でのフラッシュカラムクロマトグラフィーで精製し、ＥｔＯΔＣ−ヘサキンから再結晶化させた後に　１３４〜１３６．５℃の融点を有する６−クロル−２，４−ビス−（３゛−ジメヂルアミノフエノキシ） −１，３，５−１−リアジン１．７０９（０，００４モル）と油状物としての４．６−ジクロル−２−（３°−ジメヂルアミノフェノキシ）−１，３，５−ｉ− リアジン０．６５９　（０，００２モル）とを得た。これら２種の生成物の元素分析は次の通りであった：分　析　：　Ｃ１１Ｈ１ｏＣ１２Ｎ４０計算値：　Ｃ，４６，３４：　Ｈ，３，５３：　Ｎ、　１９．６５　；Ｃｊ　、　２４．８７実測値：　Ｃ，４８，６９：　Ｈ，３，７４：　Ｎ、　１７．１７　：Ｃρ、　２０．８８この化合物を以下化合物４８と称する。　分　析　：ＣＨＣｊ！Ｎ５０２計算値：　Ｃ，５９，１４ニド１．５．２２：　Ｎ、　１８．１５　：０、８．２８：　Ｃ１、９，１９実測値：Ｃ，ケ８．５２　：　Ｈ，５，０４；　Ｎ、　１７．８５　；０、８．９０：　Ｃ１１ｌ、　９．４にの化合物を以下化合物４９ど称する。釆−！Ｊ　Ｖｌ４．６−ジクロル−２−（４’−ブロモ−３゛、５−ジメチルフェノキシ−１３，５−１−リアジンの製− アセトン８（７中に塩化シアヌル９．２ｇ（０，０５モル）を含有する溶液へ、アセトン１０Ｉｄ中に溶解させた２、６−ルチジン５．８ｄを一６０℃の温度で添加した。次いで、アセトン３０ｄ中の４−ブロモ−３，５−ジメチルフェノール１０．０９　（０，０５モル）の溶液を添加し、その間−６０℃の温度を維持した。この混合物を一６０℃にて１時間および室温にて３０分間攪拌し、次いで濾過し、沈澱物をアセトンで洗浄した。Ｐ液を氷上に注ぎ込み、かつ得られた沈澱物を吸引ＦＡによって集めた。粗生成物を水洗し、かつ熱ヘキサンから結晶化させて、１４９〜１５１．”Ｃの融点を有する４、６−ジクロル−２−（４’− ７０モー３゛、５−ジメチルフェノキシ）−１，３，５−トリアジン１．４９ｙ　（０，００４モル）を桃−母色結晶として得た。この生成物の元素分析は、次の通りであった：分　析：　Ｃ１１Ｈ８Ｂ　ｒＣ１２Ｎ３０計算値：　Ｃ，３７，８６：　Ｈ，２，３１：　Ｎ、　１２．０４実測値：　Ｃ，３８，６３：　Ｈ，２，４７；　Ｎ、　１１．５５この化合物を以下化合物５０と称する。：ｔｊＬ−刊一一一バ実施例■で用いたと同様な方法で他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物５１〜６１の構造および分析データを下記表Ｃに示す。化合物６１を製造するには、酸受容体として２，６−ルチジンの代りにトリイソプロパツールアミンを使用した。表　Ｃ代表的窒素含有複素環化合物ＣＩ表　Ｃ（続き）代表的窒素含有複素環化合物ＣＩＣＩ施　例　Ｘ４．６−ジクロル−２−（２’−フェニルフェノキシ−１，３，５−トリアジン曵１１アセトン１００−中に塩化シアヌル１０．８３　ｇ＜０．０６モル）を含有する磁気攪拌された溶液中へ、アセトン１００ｄ中にトリイソプロパツールアミン１１．２４　ｇ（０，０６モル）を含有する溶液を一７０℃の温度で添加した。次いで、アセトン１００ｄ中の２−フェニルフェノール１０．０ｇ（０，０６モル）の溶液を一７０℃の温度ｐ滴加した。この混合物を空温で１時間攪拌し、Ｅ過しかつＰ液を氷水上へ注ぎ込んだ。蒸発によってアセトン溶剤を除去した後、得られた混合物を水とＣＨ２Ｃｌ２との間に分配させ、有機層を分離し、無水Ｎａ２ＳＯ４で脱水しかつ蒸発させた。残留生成物をシリカタルを用いるフラッシュカラムクロマトグラフィーによって精製し、かつヘキサン中の５％酢酸エチルで溶出させて、４，６−ジクロル−２−（２°−フェニルフェノキシ）−１，３，５−ｔ−リアジン６．０ｙ　（０，０２モル）を油状物として得た。この生成物の元素分析は次の通りであった：分　析二　ＣＨＣ１２Ｎ３０計算値：　Ｃ，５６，６３：　Ｈ，２，８５：　Ｎ、　１３．２１　：ＣＩ　、　２２．２９実測値：　Ｃ，５５，６５：　Ｈ，２，９９：　Ｎ、　１３．４６　：Ｃｊ　、２４．１８実施例■と同様な方法で２−クロルアニリン４．６３ｇ（０，０４モル）と塩化シアヌル６．６９９　（０，０４モル）とを２．６−ルチジン３．８９　ｇ（０，０４モル）の存在下に反応させ、ただし供給時間の終りに冷却浴を除去しかつ攪拌混合物を空温まで加温した。ルチジン塩酸塩を戸別した後、Ｐ液から減圧下でアセトン溶剤を除去し、得られた固体をヘキサンとベンゼンとの混合物から結晶化させた。生成物の最初の回収分は、１５３〜１５６℃の融点を有する２゜４ −ジクロル−６−（２’−クロルフェニルアミノ）−１，３，５−トリアジン１．１９　（０，００４モル）であった。生成物のＭＮＲ分析は次の通りであった：ＮＭＲ（ＣＤＣ１３）　；　７．０−８．３５　ｐａｍ（複合マルチプレット、芳香族およびＮＨ）この化合物を以下化合物６３と称する。２４−ジクロル−６−４°−クロルフェニルアミノ）−１，３，５−１−リアジＺ立見】実施例Ｘｌと同様な方法で４−クロルアニリン６．９４ＳＦ　（’０．０５モル）と塩化シアヌル１０．０４　ｇ（０，０５モル）と２，６−ルチジン５．８３ｇ（０，０５モル）とをアセトン溶液中で反応させた。供給を完結した後、反応混合物を０℃の温度で約１時間攪拌し、次いで空温にて約１６時間攪拌した。水洗および乾燥すると、１８１〜１８４℃の融点を有する２、４−ジクロル−６− （４−クロルフェニルアミノ）−１，３，５−ト’Ｊ７シン１４．０ｇ（０，０５−ＥＪＬｚ）　ヲ’Ｒｔニー。生成物（７）ＮＭＲ分析は次の通りであった：１３ＣＨＨＲ（ｄ６アセトン）　１７１．３８．１６５．２９．１３６．７４．１３０．５６゜１２９．７２．１２３．７９　ｐｐｍ。この化合物を以下化合物６４と称する。ノ）−１，３，５−１−リアジンの製造アセトン（１２０ＩＩｄ！、）中に塩化シフ　ヌ）ｔｔ　（５，０ｇ、０．０３モル）を含有する０℃の温度の攪拌溶液へ、アセトン（２００ｒｄ　）中に２．６−ルチジン（３，１５ｍ、０．０３モル）と１−アミノ−５，６，７，８−テトラヒドロナフタレン（３，９７ｇ、０．０３モル）とを含有する溶液を滴加した。０℃にて２時間後、反応混合物を空温まで加温し、かつ１時間攪拌した。この反応混合物を濾過し、Ｐ液をシリカゲルを通して濾過しかつアセトンで洗浄して、２，４−ジクロル−６−（５’。６゛、７°、８′−テトラヒドロナフチル−１°−アミノ）−１，３，５−トリアジンを１５８〜１６２℃の融点を有する固体（７，０ｇ、０．０２モル）として得た。生成物の元素分析は次の通りであった：分　析　：　Ｃ１３Ｈ１２Ｃｊ！２　Ｎ４計算値：　Ｃ，５２，８９；　Ｈ，４，１０：　Ｎ、　１８．９８実測値：　Ｃ，５３，０３；　）−１，４，０６：　Ｎ、　１８．８９この化合物を以下化合物６５と称する。Ｚユ１】アセトン３００ｉ中に塩化シアヌル２０ｇ（０，１１モル）を含有する溶液へ、アセトン２００Ｉｄ、中にｐ−ニトロアニリン１ｓ、ｏｇ（０，Ｎモル）を含有する♂液とア七トンＩＱＯｄ中に２．６−ルチジン１２．６１ｄｃｏ、ｉｉＮモルを含有する溶液とを添加した。得られた混合物を窒素雰囲気下で室温にて約１６時間攪拌した。次いで混合物を濾過し、Ｐ液を氷水上に注ぎ込み、得られた沈澱物を回収して５．６ｇの粗生成物を得た。この粗生成物をアセトン−トルエンから再結晶化させて４．６−ジク［］ルー２−（４−ニトロフェニルアミツー− １，３，５−トリアジン３．７２ｇ（０，０１モル）を２４０℃の融点（分解）を有する黄色固体として得た。この生成物の元素分析は次の通りであった。分　析　：　Ｃ９Ｈ５Ｎ５０２　Ｃ１２計算＠　：　Ｃ，３７，７９：　Ｈ，１，７６：　Ｎ、　２４．４８　：０、１１．１９　；　Ｃｊ　、　２４．７９実測値：　Ｃ，３ｇ、０４　；　Ｈ，２，０１；　Ｎ、　２４．２０　；０、１１．１４　：　ＣＮ　、　２３．７４この化合物を以下化合物６６と称する。実　施　例　Ｘｖ（と乏二ｒｏ−ｔ−二又」Ｌ二≦Σｐコしし＝ムヱ」エリニＬム立−ｔ−ＩＪ乙２こｎＣＨ２ＣＮ２３００−中に実施例ｘｒｖで製造した４、６−ジクロル−２−（４ −ニトロフェニルアミノ）−１，３，５−トリアジン６００Ｒｇ（０，００２モル）を含有する溶液へ、Ｈｅｒガスをｖ温にて４時間バブリングさせた。得られた混合物を冷凍機内に約４８時間貯蔵し、かつＣＨＣ１２から分離した油をデカンデージョンで集めた。この油をＣＨ２Ｃｌ２（３×２０ｆｆｉ＋！）で洗浄し、次いでトルエンから再結晶化させてｓｏｏＩＩｒｇ（ｏ、　００２モル）の４．６−ジプロモー２−（４°−ニドＯフエニ冗アミノ）−１，３，５−トリアジンを黄色固体として得た。この生成物の元素分析は次の通りであった：計算値：　Ｃ，２８，８１：　Ｈ，ｉ、３４：　Ｎ、　１８．６７実測ｉｉｉ　：　Ｃ，２９，８５：　Ｈ，２，ン５　：　Ｎ　、　１８．８５この化合物を以下化合物６１と称する。２旦１１実施例Ｘｖと同様な方法で４．６−ジクロル−２−（４’−クロルフェニルアミノ）−１，３，５−トリアジンを臭化水素と反応させて、１９７．５〜２００℃ の融点を有する４、６−ジプロモー２−（４°−クロルフェニルアミノ）−１，３，５−トリアジンを得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ９Ｈ５Ｎ４　Ｃｊ！　Ｂｒ２計算値：　Ｃ，２９，６６：　Ｈ，１，３９：　Ｎ、　１５．３８　：Ｃ４）　、　９．７３：　Ｂ　ｒ　、　４３．８５実測値：　Ｃ，２９，４９：　Ｈ，１，４８Ｎ、　１５．１９　：Ｃ１ｌ　、　９．３６；　Ｂ　ｒ　、　４３．４０この化合物を以下化合物６８と称する。２−４−クロルフェニルアミノ）−４，６−ジフルオロ−１，３，５−トリアＺｚ立ｌ】トルエン１２０ｄ中に弗化シアヌル１６．２１　ｇ（０，１２モル）を含有する攪拌溶液へ、−１０℃〜０℃の温度で冷却しながら、トルエン１２０ｄ中の４− クロルアニリン１２．７５　（ｊ　（０，１０モル）の溶液を２時間かけて添加した。次いで、この混合物を室温で１５分間かつ５０℃の温度で３０分間攪拌した。濾過後、Ｐ液を溶剤の回転減圧蒸発によって半分の容積まで減少させた。結晶粗生成物（１２，６ｇ）を濃縮溶液から分離し、かつ濾過および乾燥の後にトルエンから再結晶化させて、２−（４°−クロルフェニルアミノ）−４，６−ジフルオＯ−１，３，５−トリアジン６．３ｇ（０，０３モル）を融点１４４〜１４１℃の白色結晶として得た。この生成物のＮＭＲ分析は次の通りであった。：１３ＣＮＭＲ（ｄ６アセトン）６１７７．０９（ＩＩ）、　１６８．２１（１１）。１３０．７５，１２９．７５，１２４．１２ｐｐｍ。この化合物を以下化合物６９と称する。１　Ｘ■ ４−クロル−６−ヨーニー２−（２’　４−ジクロルフェノキシ）−１，３，５ −トアセトン６０ｍｅ中に４，６−ジクロル−２−（２’、４°−ジクロルフェノキシ）−１，３，５−トリアジン６．０ｇ（０，０２モル）を含有する懸濁物へ、アセトン６０ｄ中にＮ　ａ　！　５．８ｇ（０，０４モル）を含有する溶液を添加した。得られた混合物を攪拌しかつ９０℃の温度まで密封壜内で６時間加熱した。次いで混合物を濾過し、Ｐ液を蒸発させて９．２ｇの固体を得、かつ４０７の塩化メチレンをこの固体に添加し、次いで懸濁物を濾過した。Ｐ液を蒸発させ、かつ残留物を９０℃にて減圧下に１０時間昇華させた。次いで温度を１６０〜１９０℃まで上昇させかつ２．０ｇのオフホワイト色の固゛体を冷フ水から再結晶化させて１．０ｇ（０，００２モル）の４−クロル−６−ヨー１５５〜１５８℃の白色固体として得た。こめ生成物の元素分析は次の通りであった：分　析　：　ＣＨＣ１３■　Ｎ３０計算値：　Ｃ，２６，８４：　Ｈ，０，７５：　Ｎ　、　１０．４４；１　、３１．５４（”：ＩＩ　１ｇ７ｎ ■　、３０．６１この化合物を以下化合物７０と称する。実　施　例　Ｘ■ 実施例■と同様な方法で製造した２、４−ジクロル−６−（２°、４°−ジクロルフェニルアミノ）−１，３，５−トリアジン４．０９　（０，０１モル）を、２００ｄのトルエンに溶解させた。還流混合物中へＨＢｒガスを５時間・にわたり連続バブリングさせた。この反応混合物を変温まで冷却し、かつ窒素ガスをこの混合物中にバブリングさせて全ての過剰のＨＢｒを除去した。次いで反応混合物を蒸発乾固させ、残留物をＣＨ２Ｃｊ！２／ヘキサンから再結晶させて１．９７ｇ（０，００５モル）の４，６−ジプロモー２−（２°、４°−ジクロルフェノキシ）−１，３，５−トリアジンを融点１７４〜１１６℃の銀灰色結晶として得た。この生成物の元素分析は次の通りであった：分　析：　ＣＨＢｒ　Ｃ１２Ｎ３　。計算値：　Ｃ，２７，００：　Ｈ，０，７５：　Ｎ、　１０．５０　：Ｃ！　、　１７．５０実測値：　Ｃ，２７，４１：　Ｈ，０，６５：　Ｎ、　１０．０１　：この化合物を以下化合物１１と称する。アセトン１５０ｄ中に弗化シアヌル３．９１ｇ（０，０３モル）を含有する攪拌溶液へ、３．７２ｇ（０，０３モル）の４−クロルフェノールと３、ｉｏｇ（０，０３モル）の２．６−ルチジンとの混合物を０℃の温度で滴加した。約１６時間攪拌した後、反応混合物を氷上に注ぎ込んで油状物を分離させた。この油状物をエーテル中に溶解させ、０．５Ｎ　ＮａＯＨ１次いで水により洗浄し、かつ脱水した。蒸発させて白色固体を得、これをヘキサンから再結晶化させかつ減圧昇華させて、８１〜８２．５℃の融点を有する２−（４−クロルフェノキシ）−４，６−ジフルオロ−１，３，５−トリアジン０゜４７ｇ（０，００２モル）を得た。この生成物の元素分析は次の通りであった：分　析：　ＣＨＣＩ　ＦＮ３０４計算値：　Ｃ，４４，７４：　Ｈ，１，６７：　Ｎ、　１７．３９実測値：　Ｃ，４４，８０：　Ｈ，１，７２：　Ｎ、　１７．２３この化合物を以下化合物７２と称する。実　施　例　Ｘ−夏２−フルオロ−４，６−ビス−（４°−クロルフェノキシ）−１，３５−トリアアセトン１５ｄ中に４−クロルフェノール３．７２！７　（０，０３モル）と２．６−ルチジン３．１０ｓｐ　（０，０３モル）とを含有する混合物へ、磁気攪拌しながらかつ０〜５℃の温度に冷却しながらアセトン１８５〆中に弗化シアヌル３．９１ｉ７を含有する溶液を添加した。０〜５℃の温度で１時間攪拌した後、混合物を室温にて約７０時間攪拌した。次いで混合物を攪拌しかつ還流下で約２８時間加熱し、室温まで冷却しかつ氷上に注ぎ込んで固体を得た。この固体を水洗し、トルエン中に溶解させかつ得られた溶液を順次に０．５ＮＮ　ａ　０　＋１と水とで洗浄し、次いでＨりＳＯ４で脱水しがっ減圧下に蒸発させた。得られた固体をヘキサンから再結晶化させて、１４９〜１５０℃の融点を有する２− フルオロ−４，６−ビス＝（４−クロルフェノキシ゛）−１，３，５−１−リアジンの最初の回収分１．２０ｇ（０，００３モル）を得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１５Ｈ８Ｎ３０２　Ｃ１２Ｆ　。計算値：　Ｃ，５１，１５：　Ｈ，２，２９：　Ｎ　、　１１．９３　：Ｆ、５．３９実測値：　Ｃ，５１，２０：　Ｈ，２，２１：　Ｎ、　１１．８９　；Ｆ、５．１にの化合物を以下化合物７３と称する。実　施　例　ＸＸＩ２．４−ジクロル−６−（４−ｓｅｅ−ブチルオキシフェノキシ）−１，３，５ −１−リアジンの製造Ａ　：　４−（ＳｅＣ−ブチルオキシ）フエ、／−ルの製造窒素雰囲気下で５００−の丸底フラスコ中へＮａ０Ｈ（２，９１ｇ。０．０１モル）と１２５−の１：１水／ジオキサン（脱気したもの）とを導入した。ＮａＯＨの全部が溶解した後、ハイドロキノン（４，０ｇ、　０．０４モル）を添加し、得られた溶液は直ちに暗褐色に変化した。この時点で、ジオキサン５ｄ中に溶解させた２−ヨードブタン＜４．１５ｍ、　０．０４モル）を添加し、かつ混合物を室温にて７２時間攪拌し、次いで１０＄ＨＣｊ水溶液で約２のｌ）Ｈまで酸性化させた。この水溶液をＥｔＯＡｃ　（２ｘ１５０〆）で抽出しかつ抽出物を合して水、飽和ＮａＣｌ！で洗浄し、脱水しくＨｏ２Ｏ３）、かつ減圧濃縮して粗生成混合物を得た。この混合物をフラッシュクロマトグラフィーにより精製して、受口のジアルキル化生成物と２．３１９　（０，０１モル）の４ −（ｓｅａ−ブチルオキシ）フェノールと出発ハイドロキノンとを順次溶出させた。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ（ＣＤＣＲ３）：δ０．９５　（ｔ、　３Ｈ，Ｊ−７Ｈｚ＞　、　１．２９（ｄ、　３Ｈ，Ｊ＝６Ｈｚ）　、　１．２９−１．４０　（ｍ、　２Ｈ）　、　４．１２　（ｓｅｘｔｅｔ。Ｈ，Ｊ−６Ｈ２）、　６．３５（ｂｒ　ｓ、ＩＨ）、　６．７２（Ｓ、４Ｈ）　Ｉ）Ｉ）ｍ温度計と添加漏斗と窒素入口とを装着したｉ　ｏｏｉの３ツ首丸底フラスコ中へ、アセトン２０ｄ中に溶解された塩化シアヌル（２，２２ｇ、　０．０１モル）を添加した。０〜５℃の温度まで冷却した後、Ａで製造した４−（ｓｅｃ−ブチルオキシ）フェノール（２，０９゜０．０１モル）と２．６−ルチジン（１，４０ｍ、　０．０１モル）とをアセトン２０ｄ中に溶解させた溶液を滴下漏斗を介し徐々に滴加した。反応物の温度をこの添加のｗＡＯ〜５℃に維持した。次いで反応混合物を室温にて１６時間攪拌した。この時間の後、反応混合物をセライトパッドで濾過し、かつパッドをアセトンで洗浄した。氷水を添加し、かつ沈澱した油状物を、ＥｔＯＡＣで抽出した。ＥｔｏＡＣ層を水洗し、脱水しくＨ（ＩｓＯ４）かつ濃縮して褐色の半固体を得た。この粗生成物をシリカ上でのフラッシュクロマトグラフィーにより精製しく溶出剤：１０％ＥｔＯＡＣ／ヘキサン）　、２．４３ｇ（ｏ、ｏｏａモル）の２．４−ジクロル −６−（４’−５ｅｃ−ブチルオキシフェノキシ）−１，３，５−トリアジンを融点５２．０〜５５．０℃の淡褐色結晶として得た。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１３Ｈ１３Ｃｊ！２　Ｎ３０゜計算値：　Ｃ，４９，７０；　Ｈ，４，１７：　Ｎ、　１３．３７　；実測値：　Ｃ，５０，２６：　Ｈ，４，５１：　Ｎ、　１３．１０　：この化合物を以下化合物７４と称する。実　施　例　ＸＸ■ 実施例Ｘ　ＸＩで用いたと同様な方法で他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で用いる化合物７５〜８３の構造および分析データを下記表りに示す。表　Ｄ代表的窒素含有複素環化合物Ｃρ Ｉ例　ＸＸＩＶ４−クロル−６−メチル−２−（２°、４°−ジクロルフェノキシ）−１３５− トリアジンの製造乾燥テトラヒドロフラン４００ｄ中に実施例■と同様に製造した２、４−ジクロル−６−（２°、４°−ジクロルフェノキシ）−１，３，５−１−リアジン５．０ｙ　（０，０２モル）を含有する溶液へ、エーテル中の臭化メチルマグネシウム２．１モル溶液５．９２を０℃の温度で摘加した。得られた混合物を窒素雰囲気下で室温にて約１８時間攪拌した。この混合物を濃縮し、かつ残留物をヘキサン中の１０１　ＥｔＯＡＣを用いるシリカゲル上でのフラッシュカラムクロマトグラフィーによって精製し、融点１０７〜１０８℃の４−クロル−６−メチル− ２−（２°、４°−ジクＯＪＬ／　７　ｘ　／キシ）−１，３，５−ｔ−ＩＪ　７ジン２．０ＯＳＦた：分　析　：　ＣＨＣ１３Ｎ３０計算値：　Ｃ，４１，３４：　Ｈ，２，０８：　Ｎ、　１４．４６　：（：、ｌｌｌ、　３６．６・１実測値：　Ｃ，４１，３５：　Ｈ，２，３９：　Ｎ、　１４．４６　：ＣＩ！、　３６．８５この化合物を以下化合物８４と称する。、施　例　ＸＸｖ４−ブロモ−６−メチル−２−（２°、４−ジクロルフェノキシ−１３５−トＣＨ２Ｃｌ２３００Ｉ＋ｌｉ！中に実施例ＸＸｒＶで製造した４−クロル−６−ダプルー２−（２’、４’−ジクロルフェノキシ）−１，３，５−ト□リアジンＺ２．０ｇ　：（０，００７モル）を含有する溶液中へ、乾燥ＨＢｒガスを３時間バブリングさせた。この混合物をπ温にて約１８時間静置した。次いで懸濁物を濾過し、かつ固体をＮ　ａ　ＨＣＯ３溶液とで脱水し、溶剤を蒸発させて１２３〜１２７℃の融点を有する４−ブロモ−６−メチル−２−（２° 、４°−ジクロルフェノキシ）−１，３，５−トリアジン０．７９　（０，００２モル）を得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１ｏＨ６ＢｒＣ１２Ｎ３０計算１　：　Ｃ，３５，８５：　Ｈ，１，８１：　Ｎ、　１２．５４　：Ｃｊ　、　２１．１７　；　Ｂ　ｒ　、　２３．８５実測値：　Ｃ，３６，２２：　Ｈ，２，１５：　Ｎ、　１２．４６　：Ｃ１ｌ　、　２２．００　；　３　ｒ　、　２１．２０この化合物を以下化合物８５と称する。 −ｖｒ’ ４−り〔１ルー６−メチル−２−（１−ナフトキシ）−１３，５−ト１アジンの至テトラヒドロフラン３００ＩＩｉ中に実施例■で製造した４、６−ジクロル−２ −（１−ナフトキシ）−１，３，５−トリアジン５．０９　（０，０２モル）を含有する４℃の溶液へ、テトラヒドロフラン２００ｄ中の２．７Ｍ臭化メチルマグネシウム７、０ｄを滴加した。得られた混合物を室温にて約１８時間攪拌し、次いで蒸発させた。残留物をヘキサン中の７％酢酸エチルを用いるシリカゲル上でのフラッシュカラムクロマトグラフィーによって精製し、（ＣＨ２Ｃ１２−ヘキサンから再結晶化した後）８０〜８３℃の融点を有する４−クロル−６−メチル−２−（１−ナフトキシ）−１，３，５−トリアジン２．０ｇ（０，００７モル）を得た。この生成物の元素分析は次の通りであった：分　析　：　ＣＨＣｌＮ３０計算値：　Ｃ，６１，８９：　Ｈ，３，７１：　Ｎ、　１５．４６　：（：、ｌ　、　１３．０５実測値：　Ｃ，６１，８６：　Ｈ，３，７２；　Ｎ、　１５．４６　：（：、ｌ　、　１３．０７この化合物を以下化合物８６と称する。 −例 ζ２」ノ一二（Ｘ上」ヨヨ慎ヨ左二Ｖ二乙久旦五≦Ｊｘ／土乏ユ」二り辷トリアジンの製造アセ１〜ン２００−中に２．４−ジクロル−６−（２’、４°−ジクロルフェノキシ）−１，３，５−トリアジン１０．０９　（０，０３モル）を含有する攪拌溶液へ、３．４９ｇ（０，０３モル）の２．６−ルチジンを０〜５℃の温度で添加した。この混合物へ、１．０３９　（０，０３モル）のメタノールを室温まで加温しながら滴加した。この混合物を５０℃まで加熱し、かつこの温度に約６時間維持し、次いで空温まで冷却し、かつ約６０時間攪拌した。ルチジン塩酸塩をＰ別し、溶剤を蒸発させかつ残留物をエーテル中に溶解させてＭＱＳＯ４で脱水した。この溶液をシリカカラム上でフラッシュクロマトグラフィーにかけ、ＣＨＣ１２／へ摩サン（９：　１　）で溶出させた。溶剤を蒸発させて３．１４９の結晶生成物を得、これをヘキサンから再結晶化させて８７〜８９℃の融点を有する２− クロル−４−メトキシ−６−（２’、４−ジクロルフェノキシ）−１，３，５− １−リアジンＬ８６９　（０，（１０６モル）を得た。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ６Ｃ１３Ｎ３０２計算値：　Ｃ，３８，６７：　Ｈ，１，９７；　Ｎ、　１３．７１　：実測値：　Ｃ，３８，９４：　Ｈ，２，ＯＱ：　Ｎ、　１４．０９　：この化合物を以下化合物８１と称する。実　施　例　ＸＸ■ 乾燥テトラヒト゛ロフラン３０ｄ中にＮａＨ（油中５０％）　１．０６ｇ（０，０２モル）を含有する攪拌懸濁物へ、乾燥テトラヒドロフラン１０ｄ中に２．２．２−１−リフルオロエタノール１．７２ｄ　（０，０１モル）を含有する溶液を４℃の温度で滴加した。この混合物を窒素雰下で添加漏斗に移し、かつ乾燥テトラヒドロフラン６０ｄ中の４゜６−ジクロル−２−フェニル−１，３，５−） −リアジン５．０ｇ（０，０２モル）の溶液へ室温にて滴加し、約１８時間攪拌し、次いで蒸発乾固させた。残留物をヘキサン中の２％　ＥｔＯＡｃを用いるシリカゲル上でのフラッシュカラムクロマトグラフィーにより精製して０，９ｇの粗生成物を得、これをＣＨ２Ｃｌ２−ヘキサンから再結晶化させて、９２〜９３ ℃の融点を有する４、６−ビス−（２°、２’、２°−トリフルオロエトキシ） −２−フェニル−１，３，５−トリアジン０．４８９　（０，００１モル）を白色プレートとして得た。この生成物の元素分析は次の通りであった：分　析　’　Ｃ１３Ｈ９Ｎ３　０２　Ｆ６計算値：　Ｃ，４４，２０：　Ｈ，２，５７；　Ｎ、　１１．８９　；Ｆ、３２．２７実測ｉ１１　：　Ｃ，４４，５１：　Ｈ，２，５７；　Ｎ、　１２．０３；Ｆ、３１．５にの化合物を以下化合物８８と称する。実　施　例　ｘｘｒｘ４−クロル−６−（２’、２°、２°−トリフルオロエトキシ）−２−フェニル −１，３，５−ｔ−リアジンの製実施例ＸＸ■からのカラムクロマトグラフィーのフラクションを調べたところ、１部は第２成分として４−クロル−６−（２°、２゛。２°−トリフルオロエトキシ）−２−フェニル−１，３，５−１−リアジンを含有すると同定された。これらを合しかつ溶出剤としてｌヘキサン中の１０％酢酸エチルを用いる製造用液体クロマトグラフィー（シリカゲル）によって精製し、３２０■（ｏ、　ｏｏｉモル）の４−り　”ロルー６−（２°、２°、２’−ｔ −リフルオロエトキシ）−２−フェニル−１，３゜５−トリアジンを油状物として得た。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１１Ｈ７Ｃ１１Ｆ３　Ｎ３０計算１ｍ　：　Ｃ，４５，６１：　Ｈ，２，４４：　Ｎ、　１４．５１　：ＣＩ　、１２．２４　：　Ｆ　、１９．６８実測値：　Ｃ，４５，４３：　Ｈ，２，４１：　Ｎ、　１４．４５；ＣＩ！　、１２．２８　：　Ｆ　、１８．０２この化合物を以下化合物８９と称する。トルエン１５０ｄ中に塩化シアヌル３６．９ｇ（０，０２モル）を含有プる攪拌溶液中へ、３３．２９　（０゜０２モル）の亜燐酸トリエチルを少しづつ添加した。発熱反応を、水浴中にて停止するまで冷却することによりコントロールした。この混合物を攪拌し、６０〜９０℃の温度にて約１８時間加熱した。トルエンを減圧下で除去し、かつ残留物をヘキサンで抽出した。セライトで濾過した後、２゜４−ジクロル−６−（ジェトキシホスフィニル）−１，３，５−ｔ−リアジンの粗生成物は次のＮＭＲスペクトルを示した：ＮＭＲ（ＣＤＣ１３）：６１．１５−１．６５１）Ｉ）ｉｔ（３Ｈ，ｔ、Ｃ１１３）。４．１６−４．７５（２１’ｌ、ｐｅｎｔｅｔ、　Ｃ１１２）この化合物を精製することなく以下の８で使用した。Ｂ：２−　〇ルー４−２゛４゛−ジクロルフェノキシ）−６−（ジェトキシボスフィニル）−１，３，５−ｔ−リアジンの製造Ａで製造した２、４−ジクロル− ６−（ジェトキシホスフィニル）−１゜３．５−トリアジン１ｏｇ　（０，０３５モル）をアセトン５０ｄ中に溶解させ、かつ得られた溶液を１０２ｇの氷と５４ｍの水との攪拌混合物へ１５分間かけて添加した。この攪拌懸濁物へ８％水酸化ナトリウム水溶液１８ｄ中に２．４−ジクロルフェノール５．７ｇ（０，０３２モル）を含有する溶液を添加した。この混合物を０〜５℃にて１時間攪拌し、次いで空温にてさらに１時間攪拌した。水をデカント除去し、有機残留物をエーテル中に溶解させかつ水洗し、脱水し、濾過しそして溶剤を蒸発させ、９．１ｇ（０，０２モル）の２−クロル−４−（２°、４−ジクロルフェノキシ）−６− （ジェトキシホスフィニル）−１，３，５−１−リアジンを油状残留物として得た。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１３Ｈ１３Ｃ１３Ｎ２０４　Ｐ計算値：　Ｃ，３７，８４；　Ｈ，３，１８：　Ｐ、　７．５１；Ｃｌ　、　２５．７８実測値；　Ｃ，３８，９３：　Ｈ，３，４３；　Ｐ、　７．３７；Ｃｌ　、　２５．３２この化合物を以下化合物９０と称する。施　例　ＸＸＸｌ２４−ジクロル−６−２′−カルボメトキシフェニルスルボニルアミノ）−１，３，５−ｔ−リアジンの製造トルエン１５０ｄ中の塩化シアヌル５．７ｇ（０，０３モル）と２−カルボメトキシベンゼンスルホンアミドのナトリウム塩７．１１ｇ（０，０３モル）との混合物を、空温にて２０分間攪拌した。次いでこの混合物を８０℃まで３時間加熱し、熱時に濾過し、かつＰ液をヘキサンで希釈して連部した。白色固体が沈澱し、これを吸引によって回収しかつ乾燥させて、２１２〜２１５℃の融点を有する２、４−ジクロル−６−（２−カルボメトキシフェニル辰ルポニルアミノ）−１，３，５−トリアジン３．０ｇ（０，００８モル）を得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１１Ｈ８Ｃ１２Ｎ４　Ｃ４ｓ計算値：　Ｃ，３６，３８：　Ｈ，２，２２：　Ｎ、　１５．４２実測値：　Ｃ，３８，３６：　ｌ−１，１，６３：　Ｎ、　１５．４２この化合物を以下化合物９１と称する。実　施　例　ＸＸＸｌ２−（２°、４−ジクロル−α−メチルベンジルオキシ）−４，（ｙ−ジクロル −１，３，５−トリアジンの製造窒素雰囲気下におけるアセトン５０ｄ中に塩化シアヌル１．４ｇ（０，０４モル）を含有する０℃まで冷却された溶液へ、７．６９（０，０４モル）の２．４− ジクロル−α−メチルベンジルアルコールと４．３ｇ（０，０４モル）の２，６ −ルチジンと２５ｄのアセトンとの混合物を滴加した。得られた暗赤色の反応混合物を０℃にて３０分間攪拌し、その間白色沈澱が生じた。Ｖ温での攪拌を２日間続けた。次いで沈澱物を濾過によって分離しかつＰ液を減圧下で濃縮した。未反応の塩化シアヌルをにｕｇｅｌｒｏｈｒ装置を用いて留去した（０．２５ｍＨｇ、５０〜７０℃）。次いで暗色残留物を、９：１ヘキサン−ＥｔＯＡｃ溶出剤を用いるシリカゲル上でのクロマトグラフにかけると５．０ｇの橙色油状物が得られ、これをＫｕｇｅｌｒｏｈｒ装置と拡散ポンプ（１０−’ａｍＨｃＩ　：　１２０℃）とを用いて無滴し、２．０ｇの無色固体を得た。ヘキサンから再結晶化させて１，４ｇ（０，００４モル）の２−（２°、４°−ジクロル−α−メチルベンジルオキシ）−４，６−ジクロル−１，３，５−トリアジンを融点９１．５〜９９．５℃の無色針状結晶として得た。この生成物の元素分析は次の通りであった：分　析：　０１１Ｈ７０１４Ｎ３　。計算値：　Ｃ，３８，９７：　）ｌ、　２．０８：　Ｎ、　１２．４０実測値：　Ｃ，３９，０２：　Ｈ，１，８２：　Ｎ、　１２．５８この化合物を以下化合物９２と称する。実施例ＸＸＸＩに用いたと同様な方法で他の化合物を製造した。合物９３〜９５の構造お°よび分析データを下記表Ｅに示す。ＩＩ −施　例　ｘｘｘｒｖ虹Ｌ２１刃邊プ芸Ｇ（乙 In the above formula, R53, and the production of intermediates used to produce the compound of formula (viii) above. Similar to the method used, novel nitrogen-containing heterocyclic compounds of formula (xx i i + ) can be prepared according to the following general reaction scheme. In the above formula, R54, The manufacture is described, for example, in Heyers, A. 1. et al., J. Amer, Chcv, Soc, 91.763 (1969). It is listed. The preparation of suitable intermediates is analogous to the methods used to prepare compounds of formula (viii) above. Novel nitrogen-containing heterocyclic compounds of formula (xxiv) can be prepared according to the following general formula. In the above formula, R, XZ, Z, Y6 and Y68 are the same as those mentioned above, and the above-mentioned general reaction and preparation of intermediates are described, for example, in Japanese Patent No. 75,117,929. Other methods for preparing novel compounds of formula (xxiv) are described in U, S, P, 3,129,225 and Japanese Patent No. 75,132,129. The novel nitrogen-containing heterocyclic compound of formula (XXV) can be prepared according to the following general reaction scheme. can be built. Novel nitrogen-containing heterocyclic compounds of formula (xxvi) can be prepared according to the following general reaction scheme. In the above formula, R7o, x29.゛z5. Z6. Y71 and CF Y72 C have the same meaning as above. The general reactions and intermediate preparations described above for preparing substituted maleimides, including reaction conditions, are similar to the methods used to prepare compounds of formula (XNV) above. The novel nitrogen-containing heterocyclic compound of formula (xxvii) can be prepared according to the following general reaction formula: It can be manufactured by In the above formula, R, X, Z, Z8. Y73 and Y74 have the same meanings as above. The general reactions and intermediate preparations described above for preparing substituted maleimides, including reaction conditions, are similar to the methods used to prepare compounds of formula (xxiv)'' above. The novel nitrogen-containing heterocyclic compound of formula (xxviii) can be prepared according to the following general reaction formula: It can be manufactured as follows. In the above formula, B21. Z g , Z 10' Y 75 and U Y 76 Gil tJ. The above-mentioned general reaction and intermediate production for producing imides including reaction conditions include the novel nitrogen-containing heterocyclic compound of formula (xx ix) of the above formula (xxiv). It can be prepared according to the following general reaction formula. be. Suitable halogenating agents include, for example, PCN 5. POCj 3゜reaction and medium The production of intermediates is described, for example, in Yuki Gosei Kagaku Kyotaishi 2g, (4), 462-463 (1970). Haku's method for preparing novel compounds of formula (X XiX) is described in Acta Dot, Phar+++, 36. (3), 301-306 (1979), U, S, P, 2,963,477, Japanese Patent 6,822,309. Org, Prep. Proced, Int, 17. (2), 107-114 (1985), Arl11. Ra, Zh, 21°(6), 515-520 (1968) and German Patent No. 1,948,550. The novel nitrogen-containing heterocyclic compound of formula (XXX) can be prepared according to the following general reaction scheme. can be built. It's around. The above-mentioned method for producing E-substituted pyridazinones including reaction conditions. The general reaction and preparation of intermediates are similar to the methods used to prepare compounds of formula (xxix) above. Novel nitrogen-containing heterocyclic compounds of formula (XXXi) can be prepared according to the following general reaction scheme. In the above formula, R74,X33,213-Y83. YB2 and Y85 have the same meanings as above. Substituted pyridazinones including reaction conditions are produced. The general reactions described above and the preparation of intermediates for are similar to the methods used to prepare compounds of formula (xxix) above. The novel nitrogen-containing heterocyclic compound of formula (XXXii) can be prepared according to the following general reaction formula: It can be manufactured by RlX-H+Y4g-R36→R1-X-R36 In the above formula, R1, X, R'36 and Y49 have the same meanings as above. Production of non-substituted compounds including reaction conditions The general reactions and intermediates described above for the preparation of compounds of formula (viii) above using appropriate starting materials are described above. Similar to the method used to build In the formula, R1"62.Y63.YB2.YB2"66 and X have the same meanings as above. The above steps for producing substituted cyclophosphazenes including reaction conditions The general reaction and preparation of intermediates are similar to the methods used to prepare compounds of formula (viii) above using appropriate starting materials. In addition to the methods described above, the nitrogen-containing ? ! Used in the production of monocyclic compounds Other methods that may be used are described, for example, in the publications listed below. Italian Patent 5 89.543. Italian patent 588°280, British patent 872,313. Kanata Patent 659,610. PCT Issue IJ AU81100046, U, S, P, 3,203,550, U, S, P, 3,931,165°tl, S, P, 2,720,480. U, S, P, 4,038,197. tl, s, P, 3,682,903°U, S, P, 3,775,406. U, S, P, 3,932,167, tl, s, P, 4,390,538°U, S, P, 3,361,746. U, S, P, 4,414,221. The antitranspirant compound having formula 1 is: Significantly reduces water use1 (transpiration rate) of plants and crops while simultaneously Tolerance (expansion) of plant leaf surfaces to moisture vapor loss It was found that this method increases diffusive resistance. Furthermore, the anti-emission compounds used in the present invention do not substantially inhibit the light-requiring reactions of photosynthesis and are effective in inhibiting growing plants. It shows no substantial phytotoxicity to plants and is comparable to untreated and treated crops under similar conditions. All of these are useful for increasing crop yields, especially in areas where plants are subject to water stress conditions. Anti-emission compounds used in plants reduce the amount of water used by plants and crops during developmental periods, e.g. during the growing period, thereby making it possible to utilize unused water, e.g. during the reproductive period. As mentioned above, stomata are minute openings in the epithelium on the surface of plant leaves, through which gas exchange takes place between the intercellular space inside the leaf and the atmosphere. It is presumed that the anti-emission compound having formula 1 does not have a substantial negative effect on the electron flow of photosynthesis in the stomata of plants. Photosynthetic reactions in plants include light-demanding reactions, or light reactions, and light-unrequiring reactions, or dark reactions. It consists of response. Dark reactions usually require carbon dioxide. In addition to carbon dioxide, dark reactions require the chemical energy and reducing power produced and provided by light reactions. Generally, two types of light-demanding reactions are involved in photosynthesis in plants, and these reactions are conveniently referred to as photosystems and photosystems. For example, 5Alisbury, F. B., and Ross, C. L., Plant Physiolooy, p. 131-135 (1978). These photosystems are interconnected by an electron transport chain, which provides reducing power and chemical energy for dark reactions. When one or both of these photosystems are inhibited, photosynthesis is adversely affected and plants are damaged or even die. It has been found that the anti-shedding compounds used in the present invention do not inhibit at all or substantially no photosystem 1 or photosystem. In contrast, the herbicide atrazine is known to substantially inhibit the light reactions of photosynthesis, particularly the electron transport chain. For example, 'Jachetta. See J. J., and Radosevich, S. R., Weed Science 29:37-43 (1981). Due to the herbicidal inhibition described above, carbon dioxide accumulates inside the leaves. This causes the stomata to become blocked. See, eg, Smlth, D., and Buchholtz, P., Plant Physio+oay 39:572-578 (1964). Therefore, the anti-emission activity of the compounds used in the present invention is different from that of the compounds used in the present invention. Therefore, the anti-shedding activity of atrazine is related to its herbicidal activity. In this specification Therefore, the fact that photosynthetic electron transport is not substantially inhibited means that photosynthetic electron transport is not inhibited at all or to a small extent. As used herein, an effective amount of a nitrogen-containing heterocyclic compound for reducing water loss from plants is defined as an effective amount of a nitrogen-containing heterocyclic compound to reduce water loss from plants without substantially inhibiting electron transfer during photosynthesis of plants. It means that the compound has anti-transpiratory effectiveness of a compound sufficient to reduce water loss due to dispersion. Taste. Similarly, an effective amount of a nitrogen-containing heterocyclic compound for increasing plant yield is one that increases plant yield without substantially inhibiting electron transport for photosynthesis in the plant. amount). In either case, the effective amount of the compound is It can be varied over a wide range depending on the type of compound, the type of crop to be treated, the environment and weather conditions, etc. However, the use of compounds does not substantially inhibit electron transport during photosynthesis in plants or cause substantial chemical damage to plants (for example, sweets burn, bleaching, or death). Generally, the compounds are 1-alpha, as described in more detail below. Nitrogen-containing compounds having the formula 1 are added to plants at a concentration of 0.25 to 15 bonds per compound. Barocyclic compounds can be used according to a variety of conventional methods known to those skilled in the art. active ingredients and Compositions containing compounds are usually prepared in a liquid or solid carrier and/or diluted. Contains diluent. Concentrates include one of these compounds in acetone, xylene, nitrobenzene, cyclo Dissolved in nonphytotoxic solvents such as hexanone or dimethylformamide and activated in water using appropriate surface-active emulsifying and dispersing agents. Manufactured by dispersing sex ingredients. The type and amount of dispersing and emulsifying agents used will depend on the nature of the composition and how the active ingredients of the drug are dispersed. It is set according to the ability to Usually the active ingredient is re-milked after being applied to the plant by the pile. It is advisable to use small quantities of the agent while still dispersing the active ingredient as desired in the spray so that it does not burn or wash off from the plant. Nonionic, anionic or cationic dispersing and emulsifying agents, such as alkylene oxides and phenols. Condensation products of organic acids, alkylaryl sulfonates, complex ether alcohols A quaternary ammonium compound, etc. are used. In preparing the wettable powder or fine powder compositions, the active ingredient is dispersed in and on a suitably divided solid carrier such as clay, talc, bentonite, diatomaceous algae, fuller, and the like. When preparing the wettable powder, the above-mentioned dispersant and lignosulfone 1- may be included. The required color of the active ingredient in the present invention is 1 to 200 gal per 1 area to be treated. or more of liquid carrier and/or diluent, about 5 to 500 bonds of inert solid carrier and/or diluent. The concentration of liquid S in thick material is Usually about 5-95% by weight, and the concentration in solid formulations is about 0.5-90% by weight. Ru. An effective spray or powder for general use is about 0.1 to 100 bonds per are, preferably about 0.25 to 15 bonds, more preferably about 0.5 to 5 bonds. Contains active ingredients. Formulation (fOrllLIIat+o11) useful in practicing the invention includes active ingredient Other optional ingredients such as stabilizers or other biologically active compounds may be included as long as they do not reduce the activity of the ingredient or harm the plants to be treated. Examples of biologically active compounds include one or more insecticides, herbicides, fungicides, and nematicides. Included are acaricides, plant growth regulators or other known compounds. The above compounds may be used in combination depending on the known purpose of each component or other purposes, and a synergistic effect can also be expected. Preferably, the anti-wicking compound having Formula 1 is applied to plants and crops under substantially no or little water stress or under average or normal growth conditions. It will be done. The preferred application conditions for the compound are before substantial soil water loss. specific theory Without wishing to be bound by theory, it is understood that the application of an anti-emission compound does not reduce the minimum total water requirements in the treated plant or crop; It is estimated that water will be used more effectively. Divergence prevention The stopping effect does not reduce the total amount of water required for the clump length of a given plant or crop; Water conservation can be achieved by irrigation for certain crops), and the above-mentioned transpiration prevention effect lowers the yield of treated crops compared to untreated crops under similar conditions and when there is no or little rainfall. can be increased. Also, the anti-emission compound having formula 1 preferably has a fairly large water vapor pressure difference between the saturated atmospheric pressure inside the leaf and the atmospheric pressure around the leaf. Apply to plants and crops under low conditions. The above condition includes when the atmospheric humidity is low. This includes cases where the light/heat load on the leaves is high and air movement speeds are high. , in particular, applying the anti-shedding compound having formula 1 to the plant, e.g. at the plant's growth stage. This can reduce the amount of water used (consumed) by plants for about 1 to 6 weeks, thereby reducing the amount of water available in the soil during other developmental periods, such as the important reproductive growth phase. The storage of available water m is more It becomes. When soil moisture is conserved in this way, critical developmental periods such as the reproductive growth period can be Water shortages within plant tissues can be minimized throughout the period, thus increasing crop yields. The anti-emission compound used in the present invention can be applied to reproductive plants of plants. Similar results can be obtained when applied during the growing season. Typically, anti-emission compounds having formula 1 reduce irrigation water requirements, especially in arid climate regions. In order to eliminate the need for transplantation or loading, maturing is used to protect plants from damping-off and other damage in severely cold climates, and to protect plants from water stress (w) in the environment for species such as those mentioned above. aterStr8SS). The compounds are useful in agriculture, horticulture and related fields, and can be used to protect plants from winter blight. For example, it can be applied to non-dropping ornamental shrubs, evergreen trees, 81 trees, etc. The main cause of winter blight is that frozen road surfaces are removed from other ornamental plants such as roses, other flowers, Christmas trees, etc. to keep them fresh and slow down water drop. It is also possible to use Additionally, anti-wicking compounds can be used to eliminate or minimize summer heat and transplant shock. In addition to the foregoing, it has been found that anti-shedding compounds having formula 1 can also be used to control foliar diseases in crops such as wheat and oats. For example, ^want Gardener, Vol, 18. No, 1. See November, 1985. This document describes the use of anti-emission agents to control fungal diseases. In this specification, plants generally refer to agricultural or horticultural crops. means ornamental plants and lawns. According to the method of the invention, an anti-emission compound having formula 1 Examples of plants that can be treated with products include corn. Cotton, sweet potato, potato, Alf? Ruff 7. Wheat, rye, upland rice, barley, oats, sorghum, dry beans, soybeans, sugar beets, sunflowers, tobacco, tomatoes, canola, deciduous fruits, citrus fruits, tea, coffee. Olive, pineapple, cocoa, banana, sugar cane, Guinea oil palm, grass Wooden flowerbed plants? 11 Trees, lawns, and ornamental plants. Includes evergreen trees, small trees, flowers, and the like. In this specification, crops generally refer to agricultural or horticultural crops. As used herein, transplanted stock generally refers to tobacco, tomatoes, eggplants, cucumbers, lettuce, strawberries, herbaceous bedding plants, etc. It means 1st tree, 2nd tree seedlings, etc. The anti-wicking compounds of the present invention reduce water loss from plants and increase crop yield. The compounds are extremely safe when used in amounts sufficient to provide an anti-shedding or yield-enhancing effect, and do not inhibit photosynthetic electron transport in plants, nor are they suitable for use in plants. It will not burn or damage anything. In addition, the compound may be washed away by rain. would have been resistant to weathering, including wash-oH, UV degradation, oxidation or hydrolysis in the presence of moisture, or at least would have significantly reduced the desired anti-shedding properties of the active ingredient. Resistant to said degradation, oxidation and hydrolysis. Mixtures of the active ingredients may be used if desired, or combinations of the active ingredients with other biologically active compounds or ingredients as described above. Examples of the present invention will be shown below. (Left below) 2.4-dichloro-6-(4-methylphenylthio-135-to-1) into a solution containing 18.4 g (0.1 mol) of cyanuric chloride in 200 d of acetone, 0 12.49 (0.1 mol) of 4-methylthiophenol and 10.79 (0.1 mol) of 2,6-lutidine in 50 d of acetone while cooling at a temperature of ~5° C. and stirring magnetically. The resulting mixture was stirred magnetically for 2 hours, warmed to ! warm and precipitated. The 2,6-lutidine hydrochloride was separated from P and washed with acetone. The P solutions were then combined and poured onto ice, and the resulting precipitated solid was collected by filtration. This solid was recrystallized twice from hexane to obtain 5 g of crude product. This material was further purified by vacuum sublimation to yield 1.16 SF (0,004 mol) of pure 2,4-dichloro-6-(4-methylphenylthio)-1,3,5-tri The azine was obtained, which had a melting point of 112-114°C. The elemental analysis of the product was as follows: Analysis: C1oHI C12N3S Calculated: C,44,13: H,2, 59: N, 15.44 Observed; C,44,24: H, 2,61: N, 15.34 This compound is hereinafter referred to as Compound 1. Other compounds were prepared in the same manner as used in the examples. The structures and analytical data for compounds 2-36 used in the Examples below to reduce water loss from plants are shown in Table A below. Compound 18 was obtained from Haybridge Chea+1cal Company, Limited, Trevillet, Tin-tagel, Cornwall, UK and was recrystallized three times from hexane. Table A Typical nitrogen-containing heterocyclic compounds - Table A (continued) i'' Heterocyclic compounds containing nitrogen Table A (continued) Analysis: C9 N3 C14N30 Calculated value: C, 34, 76: H, 0, 97; N, 13.51 Actual value: C, 34, 30: H, 0, 89: N, 13.80 This compound is hereinafter referred to as compound 31. U-Wataru--1 Other compounds were produced in the same manner as used in Examples. Chemical compounds used in the examples below to reduce water loss from plants Representative nitrogen-containing heterocyclic compounds Ai-12? I V 2-゛ Lorou 46-pis 2°4°-dichlorophenoxy”) -1,3,5 -E Fire 11 Contains 9.2 g (0.05 mol) of cyanuric chloride in 100 d of acetone 15 g (0.05 mol) of 2,4-dichlorophenol and 7.259 (0.05 mol) 6 s of 2,4-dichlorophenol are added into a solution of 2.4-dichlorophenol and 7.259 (o. Carbonated power lium was added. These components were added at such a rate as to maintain a reaction temperature of 0-5°C. It was added at a Pour the mixture onto ice and filter the resulting solid precipitate. It was collected and washed with ioo, 1 part of a 10% aqueous sodium hydroxide solution and then water. After drying, the solid was recrystallized from hexane. Is the first crystal component hexane? Recrystallized twice from ,005 mol) was obtained. The elemental analysis of the product is as follows: Analysis 2 015H6015N30 Calculated: C,41,18: H,1, 38: N, 9.60 Observed: C,41,41; H,0,96 :N, The compound of 9.8 is hereinafter referred to as compound 46. LtS: 24 'J (0,032 mol) into a solution cooled to a temperature of 0-5 °C. 3.459 (0,032 mol) of gin was added followed by 185 a! of acetone. ! A solution of 5.93 g (0,032 mol) of cyanuric chloride in the solution was added. cyanide chloride A reaction temperature of 0-5° C. was maintained while adding the solution/acetone solution dropwise. After the feeds were completed, stirring was continued for 1 hour at a temperature of about θ°C, and then the mixture was allowed to warm to room temperature. Lutidine hydrochloride was removed by filtration and the P solution was treated with charcoal and filtered through Celite. The solvent was removed from the acetone solution under reduced pressure and the residue was dissolved in toluene. This solution was diluted with 0.5M NaOH (2 times) and then Washed with water, dried over HgSO4 and evaporated under reduced pressure to yield 9.1 g of crude solid product. Recrystallization from hexane and vacuum sublimation yielded pure 2,4-dichloro-6-(3°, 5-dichlorophenox) with a melting point of 109-111 °C. 1.0 g (0,003 mol) of -1,3,5-triazine was obtained. source of product The elementary analysis was as follows: Analysis: C9N3 C14ON3 Calculated value: C, 34,76: H, 0,97; N, 13.51 Actual value: C, 34,41: H, 0,90 : N, 13.33 This compound is hereinafter referred to as compound 47. Example 4.6-diku0-2-(3'-9 methylamino-containing enoxy) 4.29 (0.09 mol) of NaH (50% in oil) in 100 d of dry tetrahydrofuran. ) into a suspension containing dry tetrahydrofurane. A solution containing 10.0 g (0.07 mol) of 3-(N,14-dimethylamino)phenol in 200 d of water was added dropwise at a temperature of 4°C. The mixture was warmed to 100 g, transferred to an addition funnel, and dissolved in 100 tfJ of dry tetrahydrofuran. It was added dropwise at 0° C. into a solution containing 13.4 g (0.07 mol) of Null. The mixture was stirred at 0° C. for 3 hours, evaporated and the residue extracted with hot CH2Cl2. The CH2Cl2 solution was evaporated and the residue purified by flash column chromatography on a Florisi IO using 5% EtOAC in hexanes. 6-chloro-2,4-bis-(3'-dimethylaminophenoxy)-1,3,5 having a melting point of 134-136.5°C after being prepared and recrystallized from EtOΔC-hesaquine. 1.709 (0,004 mol) of -1-riazine and 4.0 as an oil. 0.659 (0,002 mol) of 6-dichloro-2-(3°-dimedylaminophenoxy)-1,3,5-i-lyazine was obtained. The elemental analysis of these two products was as follows: Analysis: C11H1oC12N40 Calculated: C, 46,34: H, 3,53: N, 19.65; Cj, 24.87 Observed: C, 48,69: H, 3,74: N, 17.17: Cρ, 20.88 This compound is hereinafter referred to as compound 48. Analysis: CHCj! N502 Calculated value: C,59,14 1.5.22: N, 18.15: 0,8.28: C1,9,19 Actual value: C, 8.52: H,5,04; N , 17.85; 0, 8.90: C11l, The compound of 9.4 is hereinafter referred to as compound 49. Pot-! J Vl 4. Preparation of 6-dichloro-2-(4'-bromo-3',5-dimethylphenoxy-13,5-1-riazine) - 9.2 g (0.05 mol) of cyanuric chloride in acetone 8 (7) 5.8 d of 2,6-lutidine dissolved in 10 Id of acetone were added at a temperature of -60 °C to a solution containing 4-bromo-3,5-dimethylphenol in 30 d of acetone. A solution of 10.09 (0.05 mol) of mol was added while maintaining a temperature of -60°C. The mixture was stirred at -60° C. for 1 hour and at room temperature for 30 minutes, then filtered and the precipitate was washed with acetone. Pour the P solution onto ice and pour the resulting precipitate. The precipitate was collected by suction FA. The crude product was washed with water and crystallized from hot hexane to yield 149-151. 1.49y (0,004 mol) of 4,6-dichloro-2-(4'-70mo3',5-dimethylphenoxy)-1,3,5-triazine having a melting point of ``C'' is pink-base colored. Obtained as crystals. Elemental analysis of this product was as follows: Analysis: C11H8B rC12N30 Calculated: C, 37,86: H, 2, 31: N, 12.04 Observed: C, 38,63: H, 2,47; N, 11.55 This compound is hereinafter referred to as compound 50. Other compounds were produced in the same manner as used in the examples.From plants. The structures and analytical data for Compounds 51-61 used in the Examples below to reduce water loss are shown in Table C below. To prepare compound 61, 2,6-rutidium is used as the acid acceptor. Triisopropanolamine was used instead of amine. Table C Representative nitrogen-containing heterocyclic compounds CI Table C (continued) Representative nitrogen-containing heterocyclic compounds CI CI Example 11 1.24 g (0.06 mol) of triisopropanolamine 1 in 100 d of acetone into a magnetically stirred solution containing 10.83 g (0.06 mol) of cyanuric chloride in 100 d of acetone. The containing solution was added at a temperature of -70°C. Next Then, a solution of 10.0 g (0.06 mol) of 2-phenylphenol in 100 d of acetone was added dropwise at a temperature of -70 DEG C. The mixture was stirred at air temperature for 1 hour, filtered with E, and the P solution was poured onto ice water. After removing the acetone solvent by evaporation, the resulting mixture was partitioned between water and CH2Cl2, the organic layer was separated, dried over anhydrous Na2SO4 and evaporated. The residual product was purified by flash column chromatography on silica and eluted with 5% ethyl acetate in hexane to give 4,6-dichloro-2-(2°-phenylphenoxy)-1,3,5- 6.0y (0.02 mol) of t-lyazine was obtained as an oil. The elemental analysis of this product was as follows: Analysis 2 CHC12N30 Calculated: C, 56,63: H, 2,85: N, 13.21: CI, 22.29 Observed: C, 55 , 65: H, 2,99: N, 13.46: Cj, 24.18 2-chloroaniline 4.63 g (0.04 mol) and cyanuric chloride 6.699 (0,04 mol) in the presence of 3.89 g (0.04 mol) of 2,6-lutidine, except that at the end of the feeding period the cooling bath was removed and the stirred mixture was allowed to warm to air temperature. After lutidine hydrochloride was separated, the acetone solvent was removed from the P solution under reduced pressure, and the resulting solid was condensed from a mixture of hexane and benzene. crystallized. The first crop of product is 2.4-dichloro-6-(2'-chlorophenylamino)-1,3,5-triazine 1. 19 (0,004 mol). The MNR analysis of the product was as follows: NMR (CDC13); 7.0-8.35 pam (complex multiplet, aromatic and NH) This compound is hereinafter referred to as compound 63. 24-dichloro-6-4°-chlorophenylamino)-1,3,5-1-riadi chloride with 4-chloroaniline 6.94SF ('0.05 mol) in the same manner as in Example Xl. 10.04 g (0.05 mol) of cyanuric acid and 5.83 g (0.05 mol) of 2,6-lutidine were reacted in an acetone solution. After the feeds were completed, the reaction mixture was stirred at a temperature of 0° C. for about 1 hour and then at air temperature for about 16 hours. water When washed and dried, 14.0 g of 2,4-dichloro-6-(4-chlorophenylamino)-1,3,5-to'J7-syn (0,05-EJLz) with a melting point of 181-184 °C wo'Rtnee. Product (7) NMR analysis was as follows: 13CHHR (d6 acetone) 171.38.165.29.136.74.130.56°129.72.123.79 ppm. This compound is hereinafter referred to as compound 64. -) Preparation of -1,3,5-1-riazine A stirred solution containing (5.0 g, 0.03 mol) of chloride (5.0 g, 0.03 mol) in acetone (120IId!) to acetone. (200rd) in 2.6-lutidine (3.15m, 0.03 mole) A solution containing 1-amino-5,6,7,8-tetrahydronaphthalene (3.97 g, 0.03 mol) was added dropwise. After 2 hours at 0°C, the reaction mixture was warmed to ambient temperature and stirred for 1 hour. This reaction mixture was filtered, and the P solution was filtered through silica gel. 2,4-dichloro-6-(5'.6',7',8'-tetrahydronaphthyl-1'-amino)-1,3,5-trichloro-2,4-dichloro-6-(5'.6',7',8'-tetrahydronaphthyl-1'-amino)-1,3,5-tri- The azine was taken as a solid (7.0 g, 0.02 mol) with a melting point of 158-162°C. I got it. The elemental analysis of the product was as follows: Analysis: C13H12Cj! 2 N4 calculated value: C, 52,89; H, 4, 10: N, 18.98 actual Measured value: C, 53,03; )-1,4,06: N, 18.89 This compound is hereinafter referred to as compound 65. Zyu1] To a solution containing 20g (0.11 mol) of cyanuric chloride in acetone 300i, a male solution containing 1s, og (0,N mol) of p-nitroaniline in acetone 200Id, and a seventone 2.6-lutidine 12.61dco, iiN model in IQOd A solution containing 100 ml was added. The resulting mixture was stirred at room temperature under nitrogen atmosphere for about 16 hours. The mixture was then filtered, P solution was poured onto ice water, and the resulting precipitate The precipitate was collected to obtain 5.6 g of crude product. This crude product was recrystallized from acetone-toluene to obtain 3.72 g (0.01 mol) of 4,6-diq[]-2-(4-nitrophenylamino-1,3,5-triazine) at 240 g. Obtained as a yellow solid with melting point (decomposition) of °C. Elemental analysis of the product was as follows: Analysis: C9H5N502 C12 calculation @: C, 37, 79: H, 1, 76: N, 24.48:0, 11.19; Cj, 24.79 real Measured values: C, 3g, 04; H, 2,01; N, 24.20; 0, 11. 14: CN, 23.74 This compound is hereinafter referred to as compound 66. Example Xv (Topojiro-t-bimata"L2≦Σpkoshishi=mu"eliniLmu-t-IJOtsu 2kon CH2CN2300-4 produced in Example xrv, 6-dichloro-2-(4-nitrophenylamino)-1,3,5-triazine 600Rg (0,002mol) Her gas was bubbled into the solution containing 100 ml at v temperature for 4 hours. The resulting mixture was stored in a refrigerator for about 48 hours, and the oil separated from CHC12 was decanted. Collected at the auction site. This oil was washed with CH2Cl2 (3 x 20ffi+!) and then recrystallized from toluene to give 4.0% of sooIIrg (o, 002 mol). 6-dipromo2-(4°-nido-O-phenibroamino)-1,3,5-triazidi was obtained as a yellow solid. The elemental analysis of this product was as follows: Calculated: C, 28,81: H, i, 34: N, 18.67 Observed iii: C, 29,85: H, 2, 5: N, 18.85 This compound is hereinafter referred to as compound 61. 2dan11 4,6-dichloro-2-(4'-chlorophenylamine) was prepared in the same manner as in Example Xv. -1,3,5-triazine is reacted with hydrogen bromide to produce 4,6-dipromo-2-(4°-chlorophenylamino)-1,3,5 having a melting point of 197.5-200°C. - Triazines were obtained. The elemental analysis of this product was as follows: Analysis: C9H5N4 Cj! Br2 calculated value: C, 29,66: H, 1, 39: N, 15.38: C4), 9.73: Br, 43.85 Actual value: C, 29, 49: H, 1, 48 N, 15.19: C1l, 9.36; B r , 43.40 This compound is hereinafter referred to as compound 68. To a stirred solution containing 16.21 g (0.12 mol) of cyanuric fluoride in 120 d of toluene A solution of 4-chloroaniline 12.75 (j (0.10 mol)) in 120 d of toluene was added over 2 hours while cooling at a temperature of -10 °C to 0 °C. The mixture was then allowed to cool at room temperature. Stir for 15 minutes and at a temperature of 50°C for 30 minutes. Ta. After filtration, the P solution was reduced to half its volume by rotary vacuum evaporation of the solvent. Conclusion The crystalline crude product (12.6 g) was separated from the concentrated solution and, after filtration and drying, filtered. 2-(4°-chlorophenylamino)-4,6-di 6.3 g (0.03 mol) of fluoro-1,3,5-triazine were obtained as white crystals with a melting point of 144 DEG -141 DEG C. NMR analysis of this product was as follows. : 13CNMR (d6 acetone) 6177.09 (II), 168.21 (11). 130.75, 129.75, 124.12ppm. This compound is hereinafter referred to as compound 69. 1 to a suspension containing 6.0 g (0.02 mol) of Na! A solution containing 5.8 g (0.04 mol) was added. The resulting mixture was stirred and heated in a sealed bottle to a temperature of 90°C for 6 hours. It was hot. The mixture was then filtered, the P solution was evaporated to give 9.2 g of solid, and 407 methylene chloride was added to this solid, then the suspension was filtered. The P liquid was evaporated and the residue was sublimated at 90° C. under reduced pressure for 10 hours. The temperature was then raised to 160-190°C and 2.0 g of an off-white solid was recrystallized from cold water to give 1.0 g (0,002 mol) of 4-chloro-6-iodine. Obtained as a white solid at 155-158°C. The elemental analysis of the rice product was as follows: Analysis: CHC13N30 Calculated: C, 26,84: H, 0,75: N, 10.44; 1,3 1.54 ('':II 1g7n , 30.61 This compound is hereinafter referred to as compound 70.Example 4.09 (0.01 mol) of luphenylamino)-1,3,5-triazine were dissolved in 200 d of toluene. HBr gas was passed into the reflux mixture for 5 hours. Bubbling was carried out continuously. The reaction mixture was cooled to a variable temperature and nitrogen gas was removed. All excess HBr was removed by bubbling into the mixture. Then reaction mixture Evaporate to dryness and convert the residue to CH2Cj! 2/hexane to give 1.97 g (0,005 mol) of 4,6-dipromo-2-(2°,4°-dichlorophene). (Noxy)-1,3,5-triazine was obtained as silver gray crystals with a melting point of 174-116°C. The elemental analysis of this product was as follows: Analysis: CHBr C12 N3. Calculated values: C, 27,00: H, 0,75: N, 10.50: C! , 17.50 Actual value: C, 27,41: H, 0,65: N, 10.01: This compound The product is hereinafter referred to as compound 11. To a stirred solution containing 3.91 g (0.03 mol) of cyanuric fluoride in 150 d of acetone was added 3.72 g (0.03 mol) of 4-chlorophenol and 2.0 g (0.03 mol) of 3,iog (0.03 mol). The mixture with 6-lutidine was added dropwise at a temperature of 0<0>C. Approximately 16:00 After stirring for a while, the reaction mixture was poured onto ice to separate the oil. This oil was dissolved in ether, washed with 0.5N NaOH, then water, and desorbed. I watered it. Evaporation gave a white solid, which was recrystallized from hexane and evaporated under reduced pressure. 0.47 g (0.002 mol) of 2-(4-chlorophenoxy)-4,6-difluoro-1,3,5-triazine having a melting point of 81-82.5° C. was obtained. The elemental analysis of this product was as follows: Analysis: CHCI FN30 4 Calculated: C, 44,74: H, 1,67: N, 17.39 Observed: C, 44,80: H , 1,72: N, 17.23 This compound is hereinafter referred to as compound 72. EXAMPLE ．． To a mixture containing 3.10 sp (0.03 mol) of 6-lutidine Cyanuric fluoride in acetone 185 with stirring and cooling to a temperature of 0 to 5°C. A solution containing 3.91i7 was added. After stirring for 1 hour at a temperature of 0-5°C, the mixture was stirred at room temperature for about 70 hours. The mixture was then stirred and heated under reflux for about 28 hours, cooled to room temperature and poured onto ice to give a solid. The solid was washed with water, dissolved in toluene and the resulting solution was washed sequentially with 0.5 NN a 0 +1 and water, then dried over HSO4 and evaporated under reduced pressure. Obtained The solid obtained was recrystallized from hexane to give 2-fluoro-4,6-bis(4-chlorophenoxy)-1,3,5-1-rea having a melting point of 149-150°C. An initial recovery of 1.20 g (0,003 moles) of gin was obtained. Elemental content of this product The analysis was as follows: Analysis: C15H8N302 C12F. Calculated values: C, 51, 15: H, 2, 29: N, 11.93: F, 5. 39 Actual value: C, 51, 20: H, 2, 21: N, 11.89; F, 5.1 The compound is hereinafter referred to as compound 73. Example XXI Production of 2.4-dichloro-6-(4-see-butyloxyphenoxy)-1,3,5-1-riazine A: Production of 4-(SeC-butyloxy)fe,/-l Nitrogen Na0H (2.91 g. 0.01 mol) and 125 1:1 water/dioxane (degassed) were introduced into a 500 round bottom flask under atmosphere. Ta. After all of the NaOH was dissolved, hydroquinone (4.0 g, 0.04 mol) was added and the resulting solution immediately turned dark brown. At this point, 2-iodobutane (<4.15 m, 0.04 mol) dissolved in dioxane 5d was added and the mixture was stirred at room temperature for 72 h, then diluted with 10 $ HCj aqueous solution for approximately 2 l). Acidified to H. Extract this aqueous solution with EtOAc (2x150〆). Combine the two extracts with water and saturated NaCl! Wash with water, dehydrate (Ho2O3), and reduce The crude product mixture was obtained by pressure concentration. This mixture was subjected to flash chromatography. Further purification sequentially eluted the inlet dialkylated product, 2.319 (0.01 mol) of 4-(sea-butyloxy)phenol, and the starting hydroquinone. NMR analysis of this product was as follows: NMR (CDCR3): δ0.95 (t, 3H, J - 7Hz>, 1.2 9 (d, 3H, J = 6Hz), 1.29- 1.40 (m, 2H), 4.12 (sextet. H, J-6H2), 6.35 (br s, IH), 6.72 (S, 4H) I) I) m thermometer and addition funnel i ooi's three-necked round-bottom flap with a nitrogen inlet and Cyanuric chloride (2.22 g, 0.01 mole) dissolved in 20 d of acetone was added to the flask. After cooling to a temperature of 0 to 5°C, 4-(sec-butyloxy)phenol (2,09°0.01 mol) prepared in A and 2,6-rutidi (1.40 m, 0.01 mol) dissolved in 20 d of acetone was added dropwise. Add gradually via lower funnel. The temperature of the reaction was maintained at ~5°C wAO of this addition. Ta. The reaction mixture was then stirred at room temperature for 16 hours. After this time, the reaction mixture was filtered through a pad of Celite and the pad was washed with acetone. Ice water was added and the precipitated oil was extracted with EtOAC. The EtoAC layer was washed with water, dried with H(IsO4) and concentrated to give a brown semi-solid. The crude product was purified by flash chromatography on silica, eluent: 10% EtOAC/hexane), 2.43 g (o,ooa moles) of 2,4-dichloro-6-(4'-5ec-butyl). Oxyphenoxy)-1,3,5-triazine was obtained as pale brown crystals with a melting point of 52.0-55.0°C. The elemental analysis of this product was as follows: Analysis: C13H13Cj! 2 N30° Calculated value: C, 49,70; H, 4,17: N, 13.37; Actual value: C, 50,2 6: H, 4,51: N, 13.10: This compound is Referred to as compound 74 do. EXAMPLE XX EXAMPLE XX Other compounds were prepared in a manner similar to that used in XI. Structure of Compounds 75-83 used in Examples below to reduce water loss from plants The construction and analytical data are shown in the table below. Table D Representative nitrogen-containing heterocyclic compounds Cρ I Example XXIV Preparation of 4-chloro-6-methyl-2-(2°,4°-dichlorophenoxy)-135-triazine In 400 d of dry tetrahydrofuran as in the example 2,4-dichloro produced Ru-6-(2°,4°-dichlorophenoxy)-1,3,5-1-riazine5. Methylmagnesium bromide in ether to a solution containing 0y (0.02 mol) 5.92 ml of a 2.1 molar solution of M. The resulting mixture was placed in a nitrogen atmosphere. The mixture was stirred at room temperature under air for about 18 hours. Concentrate this mixture and convert the residue into hexafluoride. Purified by flash column chromatography on silica gel using 101 EtOAC in 4-chloro-6-methyl-2-(2°,4°-diqOJL/7x/xy), mp 107-108 °C. -1,3,5-t-IJ 7 Gin 2.0 OSF: Analysis: CHC13N30 Calculated value: C, 41, 34: H, 2, 08: N, 14.46: (:, l ll, 36. 6.1 Actual value: C, 41,35: H, 2,39: N, 14.46: CI!, 36.85 This compound is hereinafter referred to as compound 84., Example XXv 4-bromo-6-methyl -2-(2°, 4-dichlorophenoxy-135-toC 4-chloro-6-da prepared in Example XXrV in H2Cl2300I+li! Dry HBr gas was bubbled into a solution containing 2.0 g (0,007 mol) of Plue 2-(2',4'-dichlorophenoxy)-1,3,5-triazine Z for 3 hours. This mixture was allowed to stand at π temperature for about 18 hours. The suspension was then filtered and the solid was dried with NaHCO3 solution and the solvent was evaporated. 0.79 (0.00 2 mol) of 4-bromo-6-methyl-2-(2°,4°-dichlorophenoxy)-1,3,5-triazine having a melting point of 123-127°C. I got it. The elemental analysis of this product was as follows: Analysis: C1oH6BrC12N30 Calculation 1: C, 35, 85: H, 1, 81: N, 12.54: Cj, 21.17; Br, 23. 85 actual value: C, 36,22: H, 2,15: N, 12.46: C 1l, 22.00; 3 r, 21.20 This compound is hereinafter referred to as Compound 85. -vr' 4-di[1-6-methyl-2-(1-naphthoxy)-13,5-to-1azine 4,6-dichloro-2-(1- To a solution at 4 °C containing 5.09 (0.02 mol) of 2.7 M methyl bromide in tetrahydrofuran 200 d. 7.0 d of gnesium was added dropwise. The resulting mixture was stirred at room temperature for about 18 hours and then evaporated. The residue was purified by flash column chromatography on silica gel using 7% ethyl acetate in hexane (CH2C12-hexanes). 4-chloro-6-methylene with a melting point of 80-83 °C (after recrystallization from xane) 2.0 g (0,007 mole)-2-(1-naphthoxy)-1,3,5-triazine ) was obtained. The elemental analysis of this product was as follows: Analysis: CHCl N30 Calculated: C, 61,89: H, 3,71: N, 15.46: (:, l, 13.05 Observed) : C, 61, 86: H, 3, 72; N, 15.46 : (:, l, 13.07 This compound is hereinafter referred to as compound 86. - Example Left 2 V 2 otokutan 5 ≦ Jx/Doboyu” 2 ritake tria Production of gin 2,4-dichloro-6-(2',4°-dichlorophenol 3.49 g (0.03 mol) of 2,6-lutidine was added to a stirred solution containing 10.09 (0.03 mol) of 1,3,5-triazine added. To this mixture, 1.039 (0.03 mol) of methanol was added dropwise while warming to room temperature. Heat this mixture to 50°C and keep it at this temperature for about 6 hours. It was then cooled to air temperature and stirred for about 60 hours. Lutidine hydrochloride was separated from P, the solvent was evaporated and the residue was dissolved in ether and dried over MQSO4. The solution was flash chromatographed on a silica column, eluting with CHC12/Hemasan (9:1). Evaporate the solvent to form crystals of 3.149. A product was obtained which was recrystallized from hexane to give 2-chloro-4-methoxy-6-(2',4-dichlorophenoxy)-1,3,5-1 having a melting point of 87-89°C. -Ryazine L869 (0, (106 mol) was obtained. The elemental analysis of this product was as follows: Analysis: C1oH6C13N302 Calculated: C,38,67: H,1,97; N,13 .71: Actual value: C, 38, 94: H, 2, OQ: N, 14.09: This compound is hereinafter referred to as compound 81. Example XX NaH (50% in oil) in 30 d of dry tetrahydrofuran 1 A solution containing 1.72 d (0.01 mol) of 2.2.2-1-lifluoroethanol in 10 d dry tetrahydrofuran was added to a stirred suspension containing 0.06 g (0.02 mol) at 4°C. The mixture was transferred to an addition funnel under a nitrogen atmosphere and placed on a drying tube. Add dropwise at room temperature to a solution of 5.0 g (0.02 mol) of 4°6-dichloro-2-phenyl-1,3,5-)-riazine in 60 d of trahydrofuran and stir for about 18 hours. It was then evaporated to dryness. The residue was purified using 2% EtOAc in hexane. Purification by flash column chromatography on silica gel gave 0.9 g of crude product, which was recrystallized from CH2Cl2-hexane to give 4,6-bis-(2 0.489 (0,001 mol) of -2-phenyl-1,3,5-triazine Obtained as a color plate. The elemental analysis of this product was as follows: Analysis' C13H9N302 F6 Calculated: C,44,20: H,2,57; N, 11.89; F, 32.27 Observed i11: C , 44, 51: H, 2, 57; N, 12.03; F, 31.5 The compound is hereinafter referred to as compound 88. Example xxrx Preparation of 4-chloro-6-(2',2°,2°-trifluoroethoxy)-2-phenyl-1,3,5-t-riazine Column chromatography fractions from Example XX Upon investigation, it was found that part 1 contained 4-chloro-6-(2°, 2′.2°-trifluoroethoxy)-2-phenyl-1,3,5-1-riazine as the second component. was identified as having These were combined and purified by preparative liquid chromatography (silica gel) using 10% ethyl acetate in 1 hexane as eluent to give 320 (o, ooi mol) of 4-'Rorou 6-(2°, 2 °, 2'-t-lifluoroethoxy)-2-phenyl-1,3°5-triazine as an oil. I got it. The elemental analysis of this product was as follows: Analysis: C11H7C11F3 N30 Calc. 1m: C, 45,61: H, 2,44: N, 14.51: CI, 12.24: F, 19. 68 Actual value: C, 45, 43: H, 2, 41: N, 14.45; CI! , 12.28 : F , 18.02 This compound is hereinafter referred to as compound 89. To a stirred solution containing 36.9 g (0.02 mol) of cyanuric chloride in 150 d of toluene, 33.29 (0.02 mol) of triethyl phosphite was added little by little. Ta. The exothermic reaction was controlled by cooling in a water bath until it stopped. The mixture was stirred and heated at a temperature of 60-90°C for about 18 hours. Toluene was removed under reduced pressure and the residue was extracted with hexane. After filtering through Celite, 2゜4-dichloro-6-(jethoxyphosphinyl)-1,3,5-t-riadi The crude product showed the following NMR spectrum: NMR (CDC13): 61.15-1.651) I) it (3H,t, C113). 4.16-4.75 (21'l, pentet, C112) This compound was used in 8 below without purification. B: 2-〇ru4-2゛4゛-dichlorophenoxy)-6-(jethoxybos Production of 2,4-dichloro-6-(jetoxyphosphinyl)-1°3.5-triazine (0.035 mol) produced in step A It was dissolved in 50 ml of acetone and the resulting solution was added over 15 minutes to a stirred mixture of 102 g of ice and 54 ml of water. Add 8% hydroxy acid to this stirred suspension. A solution containing 5.7 g (0.032 mol) of 2,4-dichlorophenol in 18 d of aqueous sodium chloride solution was added. The mixture was stirred at 0-5°C for 1 hour and then at air temperature for a further 1 hour. Decant off the water and remove the organic residue. 9.1 g (0.02 mol) of 2-chloro-4-(2°,4-dichlorophenoxy)-6-( (jetoxyphosphinyl)-1,3,5-1-riazine was obtained as an oily residue. The elemental analysis of this product was as follows: Analysis: C13H13C13N204 P calculated: C, 37,84; H, 3,18: P, 7.51; Cl, 25.78 found; C, 38,93: H, 3,43; P, 7.37; Cl, 2 5.32 This compound is hereinafter referred to as compound 90. Example XXXl Preparation of 24-dichloro-6-2'-carbomethoxyphenylsulfonylamino)-1,3,5-tert-riazine 5.7 g (0.03 mol) of cyanuric chloride and 2-carbohydrate in 150 d of toluene A mixture with 7.1 1 g (0.03 mol) of the sodium salt of methoxybenzenesulfonamide was stirred at air temperature for 20 minutes. Then this mixture The mixture was heated to 80° C. for 3 hours, filtered while hot, and the P solution was diluted with hexane and serialized. A white solid precipitates, which is collected by suction and dried to give 2,4-dichloro-6-(2-carbomethoxyphene) having a melting point of 212-215°C. 3.0 g (0,008 mol) of 1,3,5-triazine (Nylthylponylamino) was obtained. The elemental analysis of this product was as follows: Analysis: C11H8C12N4 C4s Calculated: C,36,38: H,2,22: N, 15.42 Observed: C,38,36: l- 1,1,63: N, 15.42 This compound is hereinafter referred to as compound 91. Example XXXl Preparation of 2-(2°,4-dichloro-α-methylbenzyloxy)-4,(y-dichloro-1,3,5-triazine 1.4 g of cyanuric chloride in 50 d of acetone under nitrogen atmosphere 7.69 (0.04 mol) of 2,4-dichloro-α-methylbenzyl alcohol and 4.3 g (0.04 mol) of A mixture of 2,6-lutidine and 25d acetone was added dropwise.The resulting dark red reaction mixture The mixture was stirred at 0°C for 30 minutes during which time a white precipitate formed. Stirring at V temperature for 2 days It continued for a while. The precipitate was then separated by filtration and the P solution was concentrated under reduced pressure. Unreacted cyanuric chloride was distilled off using a gelrohr apparatus (0.25 mHg, 50-70°C). The dark residue was then chromatographed on silica gel using a 9:1 hexane-EtOAc eluent to give 5.0 g of an orange oil, which was chromatographed on a Kugelrohr apparatus and a diffusion pump (10-'am HcI: 120 ℃) to obtain 2.0 g of colorless solid. 1,4 g (0,004 mol) of 2-(2°,4°-dichloro-α-methylene) was recrystallized from hexane. Rubenzyloxy)-4,6-dichloro-1,3,5-triazine was obtained as colorless needle crystals with a melting point of 91.5-99.5°C. The elemental analysis of this product was as follows: Analysis: 011H7014N3. Calculated value: C, 38,97: )l, 2.08: N, 12.40 Actual value: C, 39,02: H, 1,82: N, 12.58 This compound is compounded below. It is called object 92. Other compounds were prepared in a manner similar to that used in Example XXXI. The structures and analytical data for compounds 93-95 are shown in Table E below. I I - Example xxxrv Rainbow L21 Blade Play G (Otsu

【Ｌ見旦旦ヨエ訴長じ」凍り二丘りと上ニアシンー２− イル）オキシムの製造Ａ：２．４−ジクロルベンズアルデヒドオキシムの製造０℃の温度まで冷却された水２ＯｍＱ中にヒドロキシルアミン塩酸塩８．８ｇ＜０．１３モル）を含有する溶液へ、１０．６ｇ（０，１３モル）のｌｌＫ１１Ｍナトリウムとエラノル５０ｍ１中の２．４−ジクロルベンズアルデヒド１４．７ｇ（０，０８モルλの溶液とを添加した。空温かつ窒素圧力下での攪拌を３．５時間続けた。次いで、この反応混合物を１５−の水で希釈しかつＣＨ２Ｃ１２（３ｘ１００　ｄ）で抽出した。有機層を合してＭｇＳＯ４で脱水し、かつ減圧下で濃縮して１５．７９の無色固体を得た。溶出剤としてジクロルメタンを用いるシリカゲル上でのクロマトグラフィーにより、１４．２９（０，０７モル）の２．４−ジクロルベンズアルデヒドオキシムを無色固体として得た。この物質のＮＭＲスペクトルは次の通りであった：ＮＭＲ（ＣＤＣｌ２）：δ　７．２１（ＩＮ、ｄｄ、Ｊ＝９．２ｌ−１ｚ）、　７．１０（ＩＨ，ｄ、Ｊ＝２Ｈ２）、７．７５（１）１．　ｄ。Ｊ−９Ｈｚ）、８．０９（ＩＨ，ｓ）、８．４９（１）１゜ｓ）　ｐｐｍ３　：　２，４−ジクロルベンズアル−ヒト０−（４，６−ジクロル−１３計上」ｊ−と＞−ユヨヱヒしまま＞ｆへ乳］施例ＸχＩに上記したと同様な手順を用いて塩化シアヌルと反応させた。この反応混合物を濾過して沈澱物を除去し、かつＰ液を氷上に注いで黄色固体を生成させた。この固体を分離しかつアセトン− 水から再結晶化させて２．１　ｇ　（０，００６モル）の２．４−ジクロルベンズアルデヒドＱ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）オキシムを融点１２４〜１２４．５℃の淡黄色針状結晶として得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１ｏＨ４Ｃ１４Ｋ４０計算値：　Ｃ，３５，５４：　Ｈ，［１９；　Ｎ、　１６．５８実測値：　Ｃ，３５，７２；　Ｈ，１，３５；　Ｎ、　１６．７４この化合物を以下化合物９６と称する。実　施　例　ｘｘｘｖアセトフェノンＱ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）ＬＬｚ人立見立１１トフェノンオキシムと塩化シアヌルとを実施例ｘｘｘ■の手順にしたがって反応させ、１２３〜１２５℃の融点を有するアセトフェノン０−（４，６−ジクロル−１，３，５−トリアジン−２−イル）オキシムを得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１１Ｈ８Ｃ１２Ｋ４０計算値：　Ｃ，４６，６７：　Ｈ，２，８５：　Ｎ、　１９．７９実測値：　Ｃ，４７，１０；　Ｈ，２，８０：　Ｎ、　１９．７７この化合物を以下化合物９７と称する。実　施　例　ＸＸＸＶＩ２．６−シクロルベンズアルデヒ゛Ｑ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）オキシムの製氷冷アセトン３００ｄ中へ、１８．９ｇ（０，１モル）の２，６−ジクロルベンズアルドキシムと１８．４ｇ、　（０，１モル）の塩化シアヌルとを添加した。得られた溶液のｐＨ値を５％重炭酸ナトリウム溶液の添加により６に維持した。３時間攪拌しかつｐＨ６に維持した後、結晶が沈澱し、これを吸引−過によって集め、１００ｍの２０％水性アセトンで３回洗浄しかつ減圧オーブン内で約１８時間にわたり６０℃で乾燥させて、１３４．９〜１３５．９℃の融点を有する２、６−ジクロルベンズアルデヒドＱ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）オキシム４．９２ｇ（０，０２モル）を得た。この生成物の元素分析は次の通りであった：分　析：　ＣＨＣ１４Ｋ４０計算値：　Ｃ，３５，５４：　Ｈ，１，１９；　Ｎ、　１６．５８実測ｍ　：　Ｃ，３５，７８；　Ｈ，１，０４：　Ｎ、　１６．４０この化合物を以下化合物９８と称する。実　施　例　ＸＸＸ■ Ｎ−’（２，４−ジクロルフェニル）−Ｎ’−（４，６−ジクロル−１，３，５ −トリアジシー２−イル）ヒドラジンの製造２．４−ジクロルフェニルヒドラジン４．３ｇ　（０，０２モル）を、実施例ＸＸＸＩで用いたと同様な方法で１２５ｄのＣＨＣ１２における２、６−ルチジン３．１１９　（０，０３モル）の存在下に塩化シアヌルｓ、ｅ４ｇ（０，０３′ ｆニル）で処理した。空温にて約１８時間攪拌した後、反応混合物を減圧下で濃縮し、かつ残留物をＣＨＣＪ！３から再結晶化させて３．４ｇ（０’、０１モル）のＮ−（２，４−ジクロルフェニル）−Ｎ’−（４，６−ジクロル−１，３，５−トリアジン−２−イル）とドラジンを融点１８５．０〜１９２．０℃（分解）の無色針状結晶として得た。この生成物の元素分析は次の通りである：分　析：Ｃｌ−（Ｃｌ４Ｎ３計算値：　Ｃ，３３，２６；　Ｈ，１，５５：　Ｎ　、　２１．５５実測値：　Ｃ，３２，８８：　Ｈ，１，６０：　Ｎ、　２０．７４この化合物を以下化合物９９と称する。実　施　例　ＸＸＸ■ Ｎ−２４−ジ　ロルフェニル）−Ｎ−（４，６−ジクロル−１，３，５−トリアン゛−２−イル　メタンスルホンアミドの製造ル）のトリエチルアミンと８０ｍの乾燥テトラヒドロフランとを含有する磁気攪拌された溶液へ、テトラヒト０フ５２１塩化メタンスルホニル１１．５９　（０．１モル）を含有する溶液を滴加した。白色沈澱物が添加につれて分離した。空温における攪拌を約１６時間続け、次いで混合物を４時間にわたり還流加熱させた。生成物を冷却により単離し、濾過して沈澱物を除去しかつ減圧下で濃縮して２１．６ｇの黄色固体を得た。９：１トルエン−酢酸エチル溶出剤を用いるシリカゲル上でのクロマトグラフィーにより、１．５ＳＦ　（０．００６モル）の２．４−ジクロルフェニル（メタン、スルホンアミド）を黄色固体として与えた。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ　（ＣＤＣｊ！３）：δ　３．１０（３Ｈ，ｓ）、　７．０（ＩＨ，　ｂｓ）。７、３７（１Ｈ，ｄｄ，Ｊ＝２．９Ｈ２）、　７．　５５（ＩＨ。ｄ，　Ｊ−２ｔｌｚ）、　７．　７１（ＩＨ，　ｄ，　Ｊ＝９Ｈｚ）ｐＨｍＢ：Ｎ−２４−ジクロルフェニル）−Ｎ−（４．６−ジクロル−１．３．５一実施例ＸＸＸＶＩに使用したと同様な手順を用いて、１．１５７（０．　００６モル）の塩化シアヌルを１．５ｇ（０．００６モル）の２，４−ジクロルフェニルメタンスルホンアミドと６７０■（０．００６モル）の２。６−ルチジンとで処理した。無色沈澱物を濾過によって分離し、かつＰ液を減圧下で濃縮して２．８！Ｊの黄色固体を得た。これを３：１ヘキサン−酢酸エチル溶出剤を用いるシリカゲル上でのフラッシュクロマトグラフにかけて１．６ｇの黄色固体を得た。トルエン−ヘキサンからの再結晶化により　１．０ｇ（０．００３モル）のＮ− （２．４−ジクロルフェニル）−Ｎ−（４．６−ジクロル−１．３．５−トリアジン−２−イル）メタンスルホンアミドを融点１４５〜１５７℃の２００ｑの斎伽黄色針状結晶を得た。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ　（ＣＤＣ１３）：δ　３．７４（３Ｈ，ｓ）、　７．１０−７．６８（３Ｈ。ｍ）　ｐｐｗ。１Ｒ　（ＣＨＣｊ！３　）　：１５４０，　１５９ＯａＩ＆１３Ｃ　ＮＨＲ　（ＣＤＣｊ３）　：δ１７１．６０，　１６５．４２，　１３６．９８，　１３４．　００。１３３、０８，　１３０．９７，　１３０．５１，　１２８．６４。４３、５０　ｐｐｍ。この化合物を以下化合物１００と称する。施　例　ｘｘｘｒｘ２−ベンジルオキシ−４．６−ジクロル−１．３．５−トリアジンの製０〜５℃ の温度まで冷却されたアセトン１５ｍｅ中のベンジルアルコール４．２２９　（０、０４モル）を含有する磁気攪拌された溶液へ４、１８ｇ（０．０４モル）の２．６−ルチジンを滴加し、次いでアセトン１８５ｄ中に塩化シアヌル７、２９　（０．０４モル）を含有する溶液を添加した。供給を完了した後、反応混合物を０℃にて約１時間攪拌し、次いで室温まで加温した。約２０℃に達するとルチジン塩Ｍ塩の沈澱物が分離し、これを戸別した。ｅ液を氷上に注ぎ込んで粗生成物を沈澱させた。この粗生成物を水洗しかつ脱水して５．７９ｇの物質を得た。ヘキサンから２回再結晶化させて、７８〜８１．５℃の融点を有する２−ベンジルオキシ−４，６−ジクロル−１、３．５−ｔ−リアジン０．４１　ｇ（０．００２モル）を得た。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ　（ＣＤＣｊ！　）：６　５．５５ｐｐｍ（２Ｈ，ｓ，ＣＨ２）　、　７．４６（５Ｈ，ｓ，芳香族）この化合物を以下化合物１０１と称する。施　例　ＸＬ１、２ｇ（０．０５モル）のマグネシウム屑と２０ｄのエーテルとを窒素雰囲気下で１００ｄの３ツ′首丸底フラスコに入れた。エーテル１５ｄ中に２，４−ジクロルベンジルクロライド９、７ｇ（０．０５モル）を含有する溶液２滴を添加して、反応を開始させた。この溶液の残部を次いで激しく可決させるように急速に添加した。上記のように作成したグリニヤール試薬を、３℃の温度まで冷却された９．２ＳＦ　（０．０５モル）の塩化シアヌルと１２５ｄのエーテルとの混合物へ滴加した。添加が進行するにつれて、７℃までの発熱と白色沈澱の生成とが観察された。室温にて攪拌を約１６時間続け、かつ得られた不均質混合物を濾過してマグネシウム塩を除去した。Ｐ液を水洗しかつ有！！！層をＭＧＳＯ４で脱水し、減圧下で濃．縮して１２．６９の黄色固体を得た。この物質４．０９を９＝１ヘキサン：　ＥｔＯＡＣ溶出剤を用いるシリカゲル上でのクロマトグラフにかけて、２．９ｇの生成物を得た。ヘキサンからの再結晶化により、１．７ｇ（０．００５モル）の２−（２°．４°−ジクロルベンジル）−４．６−ジクロル−１．３．５−トリアジンを融点１１０〜１１２、５℃の無色針状結晶として得た。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ５Ｃｉ４　Ｎ３計算！　：　Ｃ，３８，８７：　Ｈ，１，６３：　Ｎ、　１３．６０実測値：　Ｃ，３８，７１；　Ｈ，１，７０；　Ｎ、　１３．５１この化合物を以下化合物１０２と称する。実　施　例　ＸＬＩ２−（２″、４°−ジクロルフェニル）−４，６−ジクロル−１，３，５−ｔ− リアジンの製造実施例ＸＬに記載したと同様な方法で、１１．１ｇ（０，０４モル）の２，４− ジクロルヨードベンゼンからグリニヤール試薬を作成した。この試薬を、３℃の温度まで冷却された乾燥テトラヒドロフラン７Ｓｄ中に塩化シアヌル７．５ｇ（０，０４モル）を含む溶液へ滴加した。これにより８℃まで６発熱と白色固体の生成とが観察された。この反応混合物を空温にて７時間攪拌し、次いで３日間還流加熱させた。固体を濾過分離し、かつ黒色Ｐ液を減圧下で濃縮した。残留物をＥｔＯＡＣと水との間に分配させかつ有典層をＨｇＳＯ４で脱水し、濃縮して１４．９ｇの黒色固体を得た。未反応の塩化シアヌルの大部分を、Ｋｕｇｅｌｒｏｈｒ装置を用いて留去した。次いで残留物を９：１ヘキサン：　ＥｔＯＡｃ溶出剤を用いるシリカゲル上でのクロマトグラフにかけた。これにより５．４ｇの粗生成物が得られた。昇華（０，０５ａｎＨｇ、　８０〜８５℃）により２．０ｇ（０・００７モル）の２−（２“、４°−ジクロルフェニル）−４，６−ジクロル−１，３，５−１−リアジンを融点１１１〜１１５℃の無色固体として得た。この生成物の元素分析は次の通りであった：計算値：　Ｃ，３６，６５：：　Ｈ，１，Ｇ３：　Ｎ、　１４．２５実測値：　Ｃ，３４，２２：　Ｈ，０，９２：　Ｎ、　１３．２０この化合物を以下化合物１０３と称する。１．４０ｇ（０，０６モル）のマグネシウム屑を、乾燥窒素雰囲気下で添加漏斗を備えた５０ｄの反応フラスコ中にてエチルエーテル４Ｉｄに懸濁させた。ブロモベンゼン（９，４８ｇ、　０．０６モル）と約２１ｍのエーテルとをフラスコの添加漏斗に加え、かつ約２ｄのこの溶液をフラスコ中へ添加し、これを加温して反応を開始させた。残部のブロモベンゼン溶液を約１時間かけて加えることにより、還流速度を￥［ｊした。この混合物を空温にて約１６時間攪拌し、次いで還流下に加熱した。上記で作成したグリニヤール試薬を次いで注射器により乾燥滴下漏斗に移し、この滴下漏斗をベンゼンＩＳｄにおける塩化シアヌル８．１５９　（０，０４モル）の溶液を含有する攪拌された窒素パージ乾燥フラスコに取付け、これを３℃の温度まで冷却し。グリニヤール試薬溶液を攪拌しながら滴加し、かつ得られた混合物を空温まで４日間加温した。この反応混合物を５０１１１ｉ！の水で急冷しかつエーテルで抽出した後、有機層を脱水し、溶剤を蒸発除去して固体を得た。ヘキサンからの結晶化により、４．９１９（０，０２モル）の生成物の最初の回収分を得、これをシクロヘキサンから再結晶させ、次いで減圧昇華させて２．４ −ジクロル−６＝フェニル−１，３，５−トリアジンを融点１１７〜１１８℃の白色結晶物質として得た。この生成物の元素分析は次の通りであった：分　析：　Ｃｓ　Ｈｓ　Ｃ１ｚ　Ｎ３計算値：　Ｃ，４７，８０；　ｌ−１，２，２３：　Ｎ、　１８．５８実測値：　Ｃ，４７，５０；　ｌ−１，２，２６：　Ｎ、　１８．４９この化合物を以下化合物１０４と称する。実　施　例　ＸＬＩＩＩ２−（１−ナフチル）−４，６−ジクロル−１，３，５−トリアジンの製造０．６６ＳＦ　（０，０３モル）のマグネシウム屑に、乾燥テトラヒドロフラン５０ｊＩｉ！中に１−ブロモナフタレン３．７７ｍ　（０，０３モル）を含有する溶液を添加した。得られた混合物を室温にて２０分間攪拌した。１５０Ｉｄの乾燥テトラヒドロフランを加え、次いで混合物を室温にて窒素雰囲気下で１時間攪拌した。上記のように作成したグリニヤール試薬を添加漏斗に移し、かつ乾燥テトラヒトＯフラン３００１１Ｉ！！中に塩化シアヌル５，０９（０，０３モル）を含有する溶液へ空温にて滴加した。この混合物を３時間攪拌した後、溶剤を蒸発させて固体残留物を得、これを１０ＸＮａＯＨ水溶液とＥｔｚ０との間に分配させた。Ｅｔｚ　Ｏ層ン中の２０Ｘ　ＥｔＯＡｃを用いる製造用プレートクロマトグラフィー（シリカゲル）により精製して、１６０Ｒｇ（０，０００６モル）の２−（１−ナフチル）−４，６−ジクロル−１，３，５−）−リアジンを融点１６６〜１６７℃の黄色固体として得た。この生成物の元素分析は次の通りであった：分　析　：Ｃ１３８７０１２Ｎ３計算値：　Ｃ，５６，５４：　Ｈ，２，５６実測値：　Ｃ，５５，２７：　Ｈ，２，６２この化合物を以下化合物１０５と称する。エチルエーテルをテラヒドロフランの代りに溶剤として使用しかつグリニヤール試薬を還流エーテル中にて２−プロモーナフタレンから１．５時間かけて作成する以外は実施例ＸＬＩ［で用いたと同様な方法により、１９３〜１９４℃の融点を有する２−（２−ナフチル）−４，６−ジクロル−１，３，５−トリアジンを製造した。この生成物の元素分析は次の通りであった：分　析　二　０１３Ｈ７０１２Ｎ３計算値：　Ｃ，５６，５４：　Ｈ，２，５６：　Ｎ　、　１５．２２　：（：、ｌ　、　２５．６８実測値：　Ｃ，５４，４８：　Ｈ，２，６３：　Ｎ、　１４．５４　：ＣＲ，２７，９８この化合物を以下化合物１０６と称する。実　施　例　ＸＬＶ２−ベンジル−４，６−ジクロル−１，３，５−トリアジンの製造１．４０ｇ（０，０６モル）のマグネシウムと０．９１ｇ（０，０９モル）の塩化ベンジルとから作成したグリニヤール試薬を、実施例ＸＬ■で用いたと同様な方法により、８．１５ｇ（０，０４モル）の塩化シアヌルと反応させた。粗生成物（２，７０ｇ）を減圧昇華させ、次いで再び昇華させて８２〜８５℃の融点を有する純粋な２−ベンジル−４，６−ジクロル−１，３，５−トリアジン０．９９！ＩＦ　（０，００４モル）を得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１ｏＨ７Ｃ１２Ｎ３計算値：　Ｃ，５０，０２：　Ｈ，２，９４：　Ｎ、　１７．４９実測値：　Ｃ，４９，９０：　Ｈ，２，８５：　Ｎ、　１７．５７この化合物を以下化合物１０１と称する。実　施　例　ＸＬＶＩ２−（２°、４゛−ジクロルベンジルチオ）−４，６−ジクロル−１，３，５− ｔ−リ４．８９　（０，０６モル）のチオ尿素と１２．２９　（０，０６モル）の２．４−ジクロルベンジルクロライドと５０ｍのエタノールとの混合物を攪拌し、かつ窒素雰囲気下で４．５時間にわたり還流加熱させた。次いで、この反応混合物を冷却し、水５０ｄ中にＮ　ａ　Ｏ８６，２５９（０，１６モル）を含む溶液を滴加した。添加が完了した後、混合物を２時間加熱還流させ、その間これは黄色となった。室温における攪拌を２日間続けた。次いでエタノールを減圧下で除去し、かつ水性残留物をＣＨＣｊ！２　（６ｘ１００　＊）で抽出した。有は層を合してＭｇＳＯ４で脱水しかつ濃縮して、１２．１９（０，０６モル）の２，４−ジクロルベンジルメルカプタンをとび色の液体として得た。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ（ＣＤＣ１３）：６１．９０（ＩＨ，ｔ、　Ｊ＝８Ｈｚ）、　３．７９（２Ｈ。ｄ、Ｊ＝８Ｈｚ）、７．１８−７．３３（２１１，ｍ）。７．３３−７．４８（１）１．ｍ）ｐｐｍ。アセトン中に塩化シアヌル６．１（０，０３モル）を含有する溶液へ、Ａで作成した２、４−ジクロルベンジルメルカプタン６．７９（０，０３モル）を添加した。実施例ＸＸＸＩで用いたと同様な手順を使用して、生成物を作成した。この粗生成物を１：１ヘキサン−トルエン溶出剤を用いるシリカゲル上でのクロマトグラフにかけて、２．０ｇの耗生成物を得た。再結晶化により１．９ｇ（０，００６モル）の５５．５〜５８．５℃の融点を有する２−（２°、４°−ジクロルベンジルチオｌ−４，６−ジクロル−１，３，５−トリアジンを得た。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１゜Ｎ５　Ｃ１４Ｎ３　Ｓ計算値：　Ｃ，３５，２２；　Ｈ，１，４８：　Ｎ、　１２．３２実測値：　Ｃ，３５，５６：　Ｈ，１，６２；　Ｎ、　１２．４７この化合物を以下化合物１０８と称する。実　施　例　ＸＬＶＩ６−クロル−２，４−ビス−（２°、４°−ジクロルベンジルチオ）−１，３，５−ト誌ｌ−と２ぷり【造実施例ＸＬＶＩからの初期のクロマトグラフフラクションは２．３ｇの無色固体を含有しており、これをヘキサンから再結晶化させて７６．０〜８０．０℃の融点を有する２、４−ビス−（２°、４°−ジクロルベンジルチオ）−６−クロル −１，３，５−トリアジン２．２ｇ（ｏ：ｏｏａモル）を得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１７Ｈ１ｏＣ１５Ｎ３　Ｓ２計算値：　Ｃ，４１，０３：　Ｈ，２，０３：　Ｎ、　８．４４実測値：　Ｃ，４１，３５：　Ｈ，２，２５：　Ｎ、　８．９３（以下余白） −一２−（２’、４’−ジクロルフェネトキシ）−４，６−ジクロル−１，３５−ト１乙Ｚｚ五玉ＩＡ：虹（２１工Ｊ夕」」リシし乙／Ｌ、ｍユ亙（７）　ｌ’Ｊ上テトラヒドロフラン中のポラン−テトラヒドロフラン複合体の１Ｍ溶液１２４ｄを５００ｇ２の３℃首丸底フラスコに入れ、０℃の温度まで氷浴を用いて冷却した。テトラヒドロフラン１００　ｍｆ！。中に２．４−ジクロルフェニル酢酸１２．７！？　（０，０６モル）を含有する溶液を、５℃以下の温度を維持するような速度で滴加した。添加が進行するにつれてガス発生が観察された。添加終了後、無色混合物を１時間還流加熱させ、次いで空温にて約１６時間攪拌した。次いで反応混合物を１２５−のメタノールで処理した。溶剤を減圧下で除去し、残留物をニーデル中に溶解し、５χＮａＯＨ水溶液で洗浄した。有機層をＭｇＳＯ４で脱水、濃縮して、１２．７ｇ（０，０６６モル）の２．４−ジクロルフェネチルアルコールを無色油状物として得た。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ（ＣＤＣ１３）：６１．６２（ＩＨ，ｓ）、　２．９８（２１１，ｔ、Ｊ＝７Ｈ２）、　３．８８（２Ｈ，ｔ、Ｊ＝７Ｈ２）、　７．１０−７．４８（３Ｈ，Ｉｎ）　ｐｐｍＢ：２−２°４°−ジクロルフェネトキシ）−４，６−ジクＤルづ、３゜アセトン中に塩化シアヌル６．４５９　（０，０４モル）を含有する溶液を、実施例ＸＸＸＩで用いたと同様な手順により、Ａで作成した２、４−ジクロルフェネチルアルコール６．７ｇ（０，０４モル）で処理した。この粗生成物を１：１トルエン−ヘキサン溶出剤を用いるシリカゲル上でのクロマトグラフにかけた。得られた物質をヘキサンから再結晶化させて、２．２９　（０，００６モル）の２−（２’。４゛−ジクロルフエネトキシ）−４，６−ジクロル−１，３，５−トリアジンを融点１０６．５〜１０８℃の無色針状結晶として得た。この生成物の元素分析は次の通りであった：分　析　二　Ｃ１１Ｈ７Ｃ１４Ｎ３　。計算値：　Ｃ，３８，９７：　Ｈ，２，０８：　Ｎ、　１２．４０実測値：　Ｃ，３９，１４：　Ｈ，２，３５；　Ｎ、　１２．５４この化合物を以下化合物１１０と称する。実　施　例　ＸＬＩＸＮ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）−２，４−ジクロルベンズアミ゛の裂迭２．２ｇ（０，０１モル）の２，４−ジクロルベンゾイルクロライドと１．７９　（０，０１モル）の２−アミノ−４，６−ジクロルトリアジンと８゜ｄのアセトンとを含有する０℃の温度まで冷却された攪拌混合物へ、水４ｄ中にＮａ０８４００ｍｇを含有する溶液を添加した。このＮａ０）ｌ溶液を、４℃以下の温度を維持するような速度で添加した。攪拌を添加終了後３峙間にわたってＭ続した。次いＭに１ｓＯ４で脱水し、減圧下で濃縮しＣ３，６９の無色固体を得た。９：１ヘキサン−ＥｔＯＡＣ溶出剤を用いるフラツシコクロマトグラフィーにより、９００１Ｈｇの無色固体を得た。次いでこの物質をＣＨ２Ｃｌ２に溶解させ、飽和Ｎａ）（ＣＯ３水溶液で洗浄した。有機層をＭｑＳＯ４で脱水、回転蒸発器で濃縮した。残留物をトルエン−ヘキサンから再結晶化させて、１６２〜１６６℃の融点を有するＮ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）−２，４−ジクロルベンズアミド３００η（ｏ、　ｏｏｉモル）を得た。この生成物の元素分析は次の通りであった：分　析　：　ＣＨＣ１４Ｎ４０計算値：　Ｃ，３５，５４：　Ｈ，１，１９；　Ｎ、　１６．５８実測値：　Ｃ，３６，０３：　Ｈ，１，５４；　Ｎ、　１６．２３この化合物を以下化合物１１１と称する。叉−」Ｌ−皿一一」− Ｎ−（４，６−ジクロル−１，３，５−）−リアジン−２−イル）−２，４−ジクロル１０Ｍの３℃首丸底フラスコ中へ窒素雰囲気下で２ｏ〆（０，２１モル）の無水酢酸を加え、３℃の温度まで水浴を用いて冷却した。これへ１．３．５ｇ（０，０８モル）の２．４−ジクロルアニリンを少しづつ添加した。この混合物を空温にて１７時間攪拌した。生成した無色固体を濾過によって除去し、減圧オーブン内で乾燥して１６．５ｇ（０，０８モル）の２．４−ジクロルアセトアニリドを得た。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ（ＣＤＣｊ！３　”）：δ　２．２２（３Ｈ，ｓ）、　７．１８（ＩＨ，ｄｄ）。７．３４（ＩＨ，ｄ）、　７．４０−７．７８（１ｔｌ、ｂｓ）。８．２８（ＩＨ，ｄ）　＋１１１０１実施例ＸＬＩＸで用いたと同様な手順により、Ａで作成された２、４−ジクロルアセトアニリド６．０９　（０，０３モル）と塩化シアヌルｓ、５７　（０，０３モル）と　１２０１ｄｌのアセトンとを含有する混合物を、水１２＃Ｉｉ！中にＮ　ａ　ＯＨ１，１８ｙ　（０，０３モ／ｌｚ）　ヲ含有スル１液１’処理した。後処理により、１０．５ｇの無色油状物が得られ、これを９＝１ヘキサン− 酢酸エチル溶出剤を用いるシリカゲル上でのクロマトグラフにかけると、８．０９の黄色油状物が得られた。これは静置すると固化した。ヘキサンから再結晶化すると、融点１０６〜１０８．５℃を有するＮ−（４，６−ジクロル−１，３，５−トリアジン−２−イル） −２，４−ツク０ルアセトアニリドの無色プリズム結晶６．４ｇ（０，０２モル）が得られた。この生成物のＮＭＲ分析は次の通りであった：ＮＭＲ（ＣＤＣｊ！３’）：δ　２．８２（３Ｈ，ｓ）。７．１８（ＩＨ，ｄ、Ｊ＝９１１ｚ）。７．４５（１Ｈ，ｄｄ、Ｊ＝２．９Ｈ２）。７．６（ＩＨ，ｄ、Ｊ＝２Ｈｚ）ｐｐｍ。この生成物を以下化合物１１２と称する。実　施　例　ＬＩ２．４−ジクロル−６−フェニルエチニル−１，３，５−トリアジンの製造臭化エチルマグネシウム（２Ｍテトラヒドロフラン中溶液４９ｄ、０．１モル）へ、テトラヒドロフラン（５０ｄ　）中のフェニルアセチレン（１ｏｇ、０．１モル）を添加した。ベンゼン（６５ｄ）中の塩化シアヌル（１２ｇ、　０．０７モル）を２５℃以下の反応温度を維持しながら滴加した。６時間攪拌後、溶媒を蒸発させ、残留物をエーテルで抽出した。溶媒を蒸発させ、残留物をエーテルで粉砕して（ｔｒｉｔｕｒａｔｅｄ）、１．５ｇ（０，００６−Ｅ／Ｌ／　）　（７）２．４−シクロルー６−フェニルエチニルー１．３．５−１−リアジンを融点１２５〜１３１℃の黄色固体として１９だ。この生成物の元素分析は次の通りであ計算値：　Ｃ，５２，８３：　Ｈ，２，０２：　Ｎ、　１６．８０実測値：　Ｃ，５３，３７：　Ｈ，２，２８：　Ｎ、　１６．２５この化合物を以下化合物１１３と称する。オロエトキシ）−６−（フェニルエチニル）−１，３，５−トリアジンの製造実施例ＸＸ■およびＸＸ■で用いたと同様な方法により、２゜４−ジクロル−６ −フェニルエチニル−１，３，５−トリアジンを２．２．２−トリフルオロエタノールと反応させて、４８〜５１℃の融点を有する２−クロル−４−（フェニルエチニル）−６−（２°、２’、２’−トリフルオロエトキシ）−１，３，５− トリアジン及び６８〜７２℃の融点を有する２、４−ビス−（２°、２°、２− トリフルオロエトキシ）−６−（フェニルエチニル）−１，３，５−トリアジンが得られた。これら２種の生成物の元素分析は次の通りであった：２−Ｏルー４−フェニルエチニル−６−（２°、２’、２’−トリフルオロニジ −１３５−トリアジン分　析：　ＣＨＣＩ　Ｆ３　Ｎ３０計算値：　Ｃ，４９，７８：　Ｈ，２，２５：　Ｆ、　１８．１７実測値：　Ｃ，５０，９８；　Ｈ，２，４２：　Ｆ、　１７．１１この化合物を以下化合物１１４と称する。２．４−ビス−（２°、２°、２°−トリフルオロエトキシ−６−フェニルエチニル）−１，３，５−トリアジン分　析：　Ｃ１５Ｈ９Ｆ６　Ｎ３０２計算値：　Ｃ，４７，７６：　Ｈ，２，４０：　Ｎ、　１１．１４Ｆ、３０．２２実測値：　Ｃ，４８，４２：　Ｈ，２，３２：　Ｎ、　１１．２６Ｆ、２９．３３この化合物を以下化合物１１５と称する。実　施　例　Ｌｌｌｌ２−４−（フェニルアゾ）フェノキシ−４，６−ジクロル−１，３，５−トリ乙２之旦１１温度計と滴下漏斗と窒素入口とを装着した２５０Ｉｄの３ツ首丸底フラスコ中ヘアレトン３０ｄ中に溶解した塩化シアヌル（４，６７９，０，０３モル）を添加し、水浴中で０〜５℃の温度まで冷却した。滴下漏斗にアセトン３０ｄ中の４− フェニルアゾフエノール（５，０ｇ、　０．０３モル）と２，６−ルチジン（２，９１ａｅ、　０．０３モル）とを含有する溶液を充填し、この混合物を０〜５ ℃の反応温度を維持しながら滴加した。添加終了後、反応混合物を室温にて１６時間攪拌し、セライトパッドを通してＰ遇し、氷水（１４０ｍｌ！　）添加した。生成した沈澱物をブフナー漏斗で集めた。この沈澱物をＥｔＯＡｃに溶解させ、飽和ＮａＨＣＯ３及び水で洗浄し、脱水しくＭＱｓｏ４＞、ｌ縮した。粗生成物をヘキサン：ＣＨＣｊ３（２：　１　）から２回再結晶化させて、１６２．０〜１６４．０℃の融点を有する２−（４−（フェニルアゾ）フェノキシ】−４゜６−ジクロル−１，３，５−、トリアジン７５０η（０，００２モル）が得られた。この生成物の元素分析は次の通りであった：分　析　二　０１５Ｈ９Ｃ１２Ｎ５０　゛計算値：　Ｃ，５２，０４：　Ｈ，２，６２：　Ｎ、　２０．２３実測値：　Ｃ，５２，３７：　Ｈ，２，８２：　Ｎ、　２０．２０この化合物を以下化合物１１６と称する。実　施　例　し■ ２．２°−［１，３−フェニレンビス（オキシ１−ビス　４．６−ジクロル−１３５−）−リアジン　の郷造窒素入口と温度計と滴下漏斗とを装着した２５０ｄの３ツ首丸底フラスコ中ヘアセトン１００ｄ中に溶解した塩化シアヌル（１３，４６ｃｔ　、　０．０７モル）を添加し、水浴中で０〜５℃の温度まで６却した。アセトン１００ｄ中に溶解したレゾルシノール（４，０９，０，０４モル）と２．６−ルヂジン（８，５０ｍ、　０．０３モル）とを滴下漏斗に入れた。この溶液を徐々に、０〜５℃の反応温度を維持しながら滴加した。次いで反応混合物を空温にて１６時間攪拌した。この時点で、沈澱物をセライトパッドで濾過して除去した。Ｐ液へ氷水（１４０ｍ　＞を添加して得られた油状物をＥｔＯＡｃ（２Ｘ１５０　ｍ＞により水溶液から抽出した。有機層を合して、ＭｇＳＯ４で脱水、減圧濃縮した。この粗生成物をシリカ上でのフラッシュクロマトグラフィー（溶出剤５％　ＥｔＯ＾Ｃ／ヘキサン）により精製すると、２．８０ｇ（０，００７モル）の２．２’−［１，３−フェニレンビス（オキシ）］−ビス［４，６−ジクロル −１，３，５−）−リアジン］が１４５〜１４８℃の融点を有する白色固体として得られた。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１□Ｈ４Ｃ１４Ｎ６０２計算値：　Ｃ，３５，５０；　ｌ−１，０，９９：　Ｎ、　２０．７０実測値：　Ｃ，３５，０７；　Ｈ，０，９１：　Ｎ、　２０．４０この化合物を以下化合物１１７と称する。実　施　例　ＬＶ実施例Ｌ　ＩＶに用いたと同様な方法で他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で用いる化合物１１８〜１２１の構造および分析データを下記表Ｆに示す。ェ表−−−上一ＩＣ１実　施　例　ＬＶＩビス−（４，６−ジクロル−１一一一一一一一二し辷ＬＬＵじ仁−２−（Ａ、）７ｔｙＪ艮１温度計と滴下漏斗とを装着した２５０ｍの３ツ首九底フラスコ中へ、アセトン５〇−中に塩化シアヌル＜２．７８９．０．０２モル）を含む０〜５℃の温度まで冷却された溶液を添加した。２−アミノ−４，６−ジクロル−１，３□５−トリアジン（２，４８９、０，０２モル）を添加し、反応温度を０〜５℃にした。水６ｄ中のＮ　ａ　ＯＨ（０，６ＳＦ０．０２モル）を含む冷溶液を２０分間でゆっくり滴加した。次いで反応混合物を空温にて４時間攪拌後、４．５ｇのＮａ２ｃｏ３を溶解させた２５０ｍの氷水中へ注入した。この溶液を濾過して固体沈澱物（トリス［４，６−ジクロル−１，３，５−トリアジン−２−イル〕アミン）を除去し、Ｐ液を酸性化させた。白色沈澱物をブフナーＳ斗で集めた。得られた粉末結晶（１，５１ｇ）を２日間かけて昇華させると、２０４．０〜２０７、Ｏ ”Ｃの融点を有する純粋なビス−（０，００３モル）を得た。この生成物の元素分析は次の通りであった：分　析：　０６　ＨｃＩ！４　Ｎ６計算値：　Ｃ，２３，０３：　Ｈ，０，３２：　Ｎ、　３１．３３実測値：Ｃ，２２゜６７　：　Ｈ，１，２０：　Ｎ、　３０．６７この化合物を以下化合物１２２と称する。Ｎ、Ｍ−ビス（４，６−ジクロル−１，３，５−トリアジン−２−イル　−４− フルオロベンゼンアミンのＮ、Ｎ−ビス（４，６−ジクロル−１，３，５−トリアジン−２−イル）−４° −フルオロベンゼンアミンをＨａｙｂｒｉｄｇｅ　Ｃｈｅａ＋１ｃａｌ　Ｃｏｍｐａｎｙ。Ｌｉｍ１ｔｅｄ、　Ｔｒｅｖｉｌｌｅｔ、　Ｔｉｎｔａｇｅｌ、　Ｃｏｒｎｗａｌｌ、英国から入手し、トルエンから再結晶化させた。融点は２３１．０〜２３３．０℃と測定された。この化合物の元素分析は次の通りであった：分　析：　０１２Ｈ４０１４ＦＮ７計算値：　Ｃ，３５，４１；　Ｈ，０，９９：　Ｎ、　２４．０８実測値ζＧ、　３４．４１　：　Ｈ，１，０６：　Ｎ、　２３．８２この化合物を以下化合物１２３と称する。実　施　例　Ｌ■ Ｎ、Ｍ−ビス（４，６−ジクロル−１，３，５−トリアジン−２−イル）−３° −クロル−４°−フルオロベンゼンアミンの製造Ｎ、Ｎ−ビス（４，６−ジクロル−１，３□５−トリアジン−２−イル）−３゛−クロル−４゛−フルオロベンゼンアミンをＨａｙｂｒｉｄｇｅ　ＣｈｅｍｉｃａｌＣｏｍｐａｎｙ、　Ｌｉｍ１ｔｅｄ、　Ｔｒｅｖｉｌｌｅｔ、　Ｔｉｎｔａｇｅｌ、　Ｃｏｒｎｗａｌｌ、英国から入手し、トルエンから再結晶化させた。融点は２２８．５〜２２９゜５ ℃と測定された。この化合物の元素分析は次の通りであった：分　析：　Ｃｌ２Ｈ３Ｃ１５ＦＮ７計算ｆｆ１：　Ｃ，３２，６５：　ｌ−１，０，６８：　Ｎ、　２２．２１実測値：　Ｃ，３２，２１：　）ｌ、　０．８６：　Ｎ、　２１．６５この化合物を以下化合物１２４と称する。撹拌機と温度計と滴下漏斗と窒素入口とを装着した１　００ｍの３つ首丸底フラスコ中へ、テトラヒドロフラン２０ａｌ！中の塩化シアヌル（３，６８９，０，０２モル）を添加後、激しく撹拌し、−１５℃〜−１０℃の温度まで冷却した。水４ｄ中のヒドラジン水和物（１，９０ｇ、５５％ヒドラジン含有量、０．０３モル）を、・−１５℃〜−１０℃の反応温度を維持しながら滴下漏斗を介して徐々に添加した。添加終了後、反応混合物を０℃にて１５分間撹拌した。氷水（４０ｄ）を加え、水溶液をＥ　ｔＯＡｃ（２ｘ１００　ＩＩ！ｌ）で抽出し、抽出物をＭＱＳＯ４で脱水し、減圧濃縮すると、２．９２９　（０，００９モル）の２．２°、４，４°−テトラクロルヒドラゾ−１，３，５−トリアジンが微細な白色固体として得られた。これは２５０℃にて分解し始めた。生成物の元素分析は次の通りであった：分　析　二　０６　Ｈ２０１４Ｎ８計算値：　Ｃ，２１，９７：　Ｈ，０，６１：　Ｎ、　３４．１７実測値：　Ｃ，２３，６４：　Ｈ，１，３４：　Ｎ、　３６．２３隔膜と酸トラップへの出口と密栓とを設けた２５０ｄの３ツ首５−トリアジン（３，２０ｇ、０．０１モル）と１００ｄのＣＨＣｌ３とを添加した。水Ｓｏｄ中に°溶解した重炭酸ナトリウム（１，６４ｇ、０．０２モル）を添加した。この２相溶液をゆっくり攪拌して、相ＣＨＣｌ３層が均質かつ深赤色となるまで、すなわち約１５分間に少しずつバブリングさせた。この時点で０８０７３層を分離し、水洗し、脱水しくＮａ５０４）、減圧濃縮して橙色結晶をられた淡但色固体をＣＨＣｌ３から再結晶化させると、１８６．０〜１９０．０℃の融点を有する２、２°、４．４°−テトラフロラアゾ−１，３゜５−トリアジン２．１　ｇ　（０，００６モル）が得られた。この生成物の元素分析は次の通りであった：分　析二　０６　Ｃ１４Ｎａ　Ｉ計算値：　Ｃ，２２，１１：　Ｈ，０，００：　Ｎ、　３４．３８実測値：　Ｃ，２２，７８：　Ｈ，０，２８：　Ｎ、　３３．９８この化合物を以下化合物１２６と称する。有する０℃の溶液へ、アセトン（２５ｍ１！　）中に、温度を５℃以下に維持しながら２．６−ルチジン（３，１５ｄ、　０．０３モル）及び４−ビトロキシ− ３−メトキシベンズアルデヒド（４゜１２５９　、０．０３モル）を含有する溶液を滴加した。２時間攪拌後反応混合物を濾過し、溶液をシリカゲルで濾過し、アセトンで洗浄すると、６５０η（０，００２モル）の２．４−ジクロル−６− （４°−ホルミル−２°−メトキシフ゛　エノキシ）−１，３，５−トリアジンが融点１５６〜１５７．５℃の白色固体として得られた。この生成物のＮＭＲ分析は次の通りであり、た：’ＨＮＭＲ（ＣＤＣｊ　３）：δ３．８（ｓ、　３Ｈ）。７．２−７．７（ｇ＋、３旧。１０．０５（ｓ、　１ｔｎｐＤｌこの化合物を以下化合物１２７と称する。Ｉ　施　例　しＸＩ実施例ＬＸｒで用いたと同様な方法で他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１２８〜１３１の構造および分析デーダを下記表Ｇに示す。表　ＧＩＩＲ実　施　例　ＬＸｍ２．４−ジクロル−６−（５−タプルイソオキサ１リルー３−アミノ　−１３．５−トリアジンの製造アセトン（１００ｍ　）中に塩化シアヌル（ｓ、ｏｇ、０．０３モル）を含有する０℃の溶液へ、アセトン（５０ｄ）中に、５℃以下の温度を維持しながら２．６−ルチジン（３，１５ｄ、　０．０３モル）及び３−アミノ−５−メチルイソオキサゾール（２，６６９、０，０３モル）を含有する溶液を滴加した。２時間攪拌後、反応混合物を室温まで加温し、氷水２００ｄに注入した。混合物をＰ遇し、固体を乾燥し、クロロホルムから再結晶化させると、８００１１１ｆｆ　（０，００３モル）の２゜４−ジクロル−６−（５−メチルイソオキサシリル−３ °−アミノ）−１，３゜５−トリアジンガ融点１２８〜１３２℃の固体として得られた。この生成物の元素分析は次の通りであった：分　析　：　０７　Ｈ５Ｃ１２Ｎ５　。計算値：　Ｃ，３４，１７：　Ｈ，２，０５：　Ｎ、　２８．０６実測値：　Ｃ，３４，２４：　Ｈ，２，１１：　Ｎ、　２８．１５この化合ｐを以下化合物１３２と称する。実　施　例　ＬＸｒＶ虹紅Ｚ久且亙−６−（２−エユ乏且ルアミノ）　−１，３，５−トリアジンの■ アセトン（１４０ｄ　’）及び砕いた氷水（２００ａｅ　）中に塩化シアヌル（１８，４９，０，１モル）を含有する溶液へ、５℃以下の反応温度を維持しながらアセトン（６８ｄ　）中の２−アミノピリジン（９，４９，０，１モル）を滴加した。次いで、５℃以下の温度及び８．０以下のｐＨを維持しながら水酸化ナトリウム（２Ｎ溶液５０ｄ　、０．１モル）を添加した。この反応混合物を一過し、シリカゲル上でクロマトグラフにかけると、５９０Ｉｔｇ（０，００２モル）の２．４−ジクロル−６−（２−ピリジニルアミノ）−１，３，５−トリアジンが融点１７０〜１７２℃の橙色固体として得られた。この生成物の元素分析は次の通りであった：分　析　：　０８　Ｈ５０１２Ｎ５引算値：　Ｃ，３９，６９：　Ｈ，２，０８：　Ｎ、　２８．９３実測値：　Ｃ，３４，０８：　Ｈ，１，４７；　Ｎ、　２７．９２この化合物を以下化合物１３３と称する。アセトン（１２ｄ　’）中に２−アミノベンゾキサゾール（ｉ、ｏｇ、０．００７モル）及び塩化シアヌル（１，３８ｇ、０．００７モル）を含有する０℃の溶液へ、反応混合物の温度を１０℃以下に且つｐＨを６．５〜７．０に維持するような速度で５％水酸化ナトリウム溶液（３４ｍ）を添加した。添加終了後、反応混合物を濾過し、固体ｊ、３．５−トリアジンが２５０’Ｃより高い融点を有する白色固体として得られた。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１゜Ｎ５　Ｃ１２Ｎ５　。計算値：　Ｃ，４２，’５８　：　Ｈ，１，７９；　Ｎ　、　２４．８３実測値；　Ｃ，４１，６８：　Ｈ，１，７８；　Ｎ、　２３．５８この化合物を以下化合物１３４と称する。実　施　例　ＬＸＶｒ２．４−ジクロル−６−（４−キナゾリンオキシ）−１３５−トリアジンの“　１艷童アセトン（１１０ｍ）中に４−ヒドロキシキナゾリン（５ｇ、０．０３モル）及び塩化シアヌルＣＧ、３ｇ、０．０３モル）を含有する混合物へ、反応混合物の温度を１０”Ｃ以下に維持し且っｐ＋＋を６．５〜７．０に維持するような速度で２％水酸化ナトリウム溶液を添加した。添加終了後、反応混合物を空温まで加温し、約１６時間攪拌した。反応混合物を濾過し、固体をソックスレー抽出器に入れて環流クロロホルムで抽出した。溶媒を蒸発させ、シリカゲルクロマトグラフィーにかけると、１００ｗＩ（０，０００３モル）の２゜４−ジクロル−６− （４°−キナゾリンオキシ）−１，３，５−トリアジンが２５０℃より高い融点を有する固体として与えた。この生・威勢のＮＭＲ分析は次の通りであった：１ＨＮＭＲ（ＣＤＣｊ３’）：δ７．２−８．２１１１）Ｉｆ（５Ｈ，ｌ）。８．５　ｐｐｍ（ＩＨ，ｓ）この化合物を以下化合物１３５と称する。モル）及び塩化シアヌル（３９、０，０２モル）を含有する０℃の混合物へ、反応混合物の温度を１０℃以下に且つｐＨを６．５〜１８０に維持するような速度で２％水酸化ナトリウム溶液（１３０ｄ　）を添加した。添加終了後、反応混合物を冷凍機中に約１６詩間貯蔵し、固体生成物を濾過し、アセトンから再結晶化させた。固体をソックスレー抽出器に入れ、環流クロロホルムで約１６時間抽出した。溶媒を蒸発させると、３．７５９　（０，０１モル）の２−（２−カルバゾリルオキシ）−４，６−ジクロル−１，３，５−トリアジンが融点２４９〜２５６℃の固体として得られた。この生成物の元素分析は次の通りであった：分　析　：　０１５Ｈ８Ｃ１２Ｎ４０計　算　ｉｆｆ　：　Ｃ，５４，４０：　Ｈ，２，４４：　Ｎ　、１６．９２この化合物を以下化合物１３６と称する。 −施　例　ＬＸ■ ２４−ジクロ゛ルー６−４−２３−ジメチル−１−フェニル−３−ピラゾリ゛− ５−オン−アミノ　−１．３５−トリアジンの製造アセトン（２００ｍ　）及び砕いた氷水（２００ｄ　）中に塩化シアヌル（１８，４ｇ、＋　０．１モル）を含有する溶液へ、５℃以下の反応温度を維持しながらアセトン（１８０Ｉ！ｒＩｌ）中の４−アミノアンチピリン（２０，３ｇ、０．１モル）を滴加した。次いで温度を５℃以下に且つｐＨを８．０未満に維持しながら水酸化ナトリウム（２Ｎ溶液５０ｄ　。０．１モル）を添加した。この反応混合物を濾過し、Ｐ液を蒸発２．４−ジクロル−６−［４−（２，３−ジメチル−１−フェニル−３−ピラゾリン−５−オン −アミノ）　］−］１．３．５−トリアジが２５０　”Ｃより高い融点を有する白色固体として得られた。この生成物の元素分析は次の通りであった：分　析　：　Ｃ１４Ｈ１２Ｃ１２Ｎ２０計算値：　Ｃ，４７，８８：　Ｈ，３，４５：　Ｎ、　２３゜９３実測値；　Ｃ，４６，５７：　Ｈ，３，４９：　Ｎ、　２３．０５この化合物を以下化合物１３７と称する。る溶液へ、０〜４℃の温度まで冷却しながらアセトン２００ｄ中に！！濁させたカリウムフタルイミド２０．８９　（０，１モル）の懸濁物を添加した。得られた混合物を０〜４℃にて３時間攪拌後、室温にて約１６時間攪拌した。この混合物を濾過し、Ｐ液を氷水中に注入して裟澱させた。この混合物を濾過し、固体を減圧乾燥させて１７ｇの粗生成物を得た。この粗生成物をＣＨ２Ｃｌ２−ヘキサンから再結晶化させると、１７６〜１１１℃の融点を有する４、６−ジクロル− ２−（Ｎ−フタルイミド）’−１．３．５−トリアジン４．５ｇ（０，０２モル）を得た。この生成物の元素分析は次の通りであった：分　析：　Ｃ１１Ｈ４Ｃ１２Ｎ４０２計算値：　Ｃ，４４，９０：　Ｈ，１，３６実測値：　Ｃ，４５，０５：　Ｈ，１，９７この化合物を以下化合物１３８と称する。油中に３５重量％ＫＨ４，０２ＳＦ　（０，０４モル）を含有する懸濁物へ、１００−のテトラヒドロフランとテトラヒドロフラン中の３゜４．５．６−テトラクロルフタルイミド（１０，０ｇ、　０．０３モル）を含有する溶液とを４℃の温度で添加した。混合物を室温にて３０分間攪拌し、０℃まで冷却し、乾燥テトラヒドロフラン１５０ｄ中に塩化シアヌル６．４７９　（０，０４モル）を含有する溶液を添加した。この混合物を室温にて約１６時間攪拌し、濾過し、Ｐ液を氷水上質を熱Ｃ３Ｈ２Ｃ１２で抽出した。塩化メチレン溶液を空温まで冷却し、ヘキサンを添加して生成物を結晶化させた。濾過すると、７００ｑ　（０，００２モル）の４，６−ジクロル−２−（Ｎ−３，４，５，６−テトラクロルフタルイミド）−１，３，５ −）−リアジンが融点２９８〜３００℃の白色固体として得られた。この生成物のＩＲ分析は次の通りであった。Ｉ　Ｒ（ＫＢ　ｒ　）　：　１７４５．　１５１０．　１４００．　１３７０．　１３００及び１２３５α　。この化合物を以下化合物１３９と称する。友−」Ｌ−ニー　ＬＸＸＩ２−４゛６゛−ジクロル−１゛１３°、５’−１−リｌ乏クー２−イル）−１，２−ベンゾイソチアゾールー３（２Ｈけン　１．１−ジオシヒの製清２００ｍのアセトン中に　１００ｇ（０，０５４モル）の塩化シアヌルを、含有する溶液へ、１００ｍ１のアセト病】にｉｏｇ（０，０５４モル）のサッカリンを含む懸濁液を添加した。数分後混合物は均質となった。５．５〆（０，０５４モル）の２，６−ルチジンを添加後窒素雰囲気下空温で約１６時間攪拌した。懸濁液を濾過し、Ｐ液を蒸発させ、残留物をＣ１］　Ｃ！！２−ヘキサンから結晶化した。この固体を濾過し、Ｐ液を蒸発させると、残留物が得られた。残留物をＣＨ２Ｃ１２−ヘキサンから再結晶化すると、２．０ｇ（０，００６モル）の２−（４°、６°−ジクロル−１゛、３°、５°−トリアジン−２°−イル）−１，２−ベンゾイソチアゾール−３（２Ｈ）オン　１．１−ジオキシドが得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１゜Ｈ４０３ＣＩ２　Ｈ４Ｓ計算値：　Ｃ、３８，６０；　Ｈ，１，３０；　Ｎ、　１８．０１　：ＣＩ　、　２２．７９実測値；　Ｃ、３６，５９：Ｈｌｌ、４３：Ｎ、　１６．２７　：Ｃｊ）　、　２０．７１この化合物を以下化合物１４０と称する。茄　例　ＬＸＸｎ２４−’″　ロルー６−ト１　チルシリルエチニル−１，３，５−トリアジ２匹１上８０ｄのテトラヒドロフラン中に１４．４１１Ｉｉ！（０，１モル）のトリメチルシリルアセチレンを含む溶液に、−６０℃で臭化エチルマグネシウム（２Ｍテトラヒドロフラン溶液３５．４ｍ　）を添加した。溶液を空温まで加温し、２時間攪拌し、４０℃で１時間加熱した。溶液を室温まで冷却し、６５ｍ！のテトラヒドロフラン中に１２ｇ（０，０７モル）の塩化シアヌルを含む溶液に滴加した。空温で１時間後、溶媒を蒸発させ、残留物をエーテルで抽出した。エーテルを蒸発させ、残留物をシリカゲルクロマトグラフィーにかけると、１．２ｇ（０，００５モル）の２．４−ジクロル−６ −トリメチルシリ・ルエチニルー１．３．５−トリアジンが褐色の油状物として得られた。生成物の元素分析は次の通りであった：′分　析：Ｃ８Ｈｇ　Ｃｊ’ ２　Ｎ３　Ｓ　ｉ　１計算値：　Ｃ，３９，０３：　Ｈ，３，６９：　Ｎ、　１７．０７実測値：　Ｃ，３９，６７：　Ｈ，３，９０：　Ｎ、　１５．９７この化合物を以下化合物１４１と称する。実　施　例　ＬＸＸＩ［［２，４−ジクロル−６−エトキシエチニルー１．３．５−ｔ−リアジンの製造臭化エチルマグネシウム（２Ｍデトラヒドロフラン溶液２１．０ｄ）に、０℃テ２１ｍ　（７）　テト５１：ｌ：　Ｆ　［１−）　５　＞中ニ３．０９　（０，０４モル）のエトキシアセチレンを含む溶液を滴加した。添加終了後、反応混合物を４０℃で１時間加熱し、０℃に冷却し、これを２１−のテトラヒト［］フラン中に７．９％（０，０４モル）の塩化シアヌルを含む溶液に滴加（）だ。反応混合物を約１６時間撹拌し、溶媒を蒸発させ、残留物をエーテルで抽出した。エーテルを蒸発させ、残留物をシリカゲルクロマトグラフィーにかけると、１．５ｇ（０，００７モル）の２．４−ジクロル−６−エトキシエチニルー１．３．５− トリアジンが橙色の油状物として゛得られた。生成物のＮＭＲ分析は次の通りであった： ’ＮＭＲ（ＣＤＣｊ　３　）：δ　１．４（ｔ、３旧、　４．５５（Ｑ、２旧ｐｐｍこの化合物を以下化合物１４２と称する。艮］０．５１の水中に９．５ｇ（０，１モル）のメタンスルホンアミドと４ｇ（０，１モル）の水酸化ナトリウムを含む２５℃の混合物に、１００ｍのアセトン中に１８．４９　（０，１モル）の塩化シアヌルを含む溶液を添加した。添加終了後、反応混合物のｐＨを８．０以下に維持しながら２５ｄの水に４９　（０，１モル）の水酸化ナトリウムを含有する溶液を消和した。反応混合物を冷凍室（ｒｅｆｒｉｇｅｒａｔ−０「）に約１６時間放置後、室温まで加温し、Ｐ遇すると白色固体が得られた。クロロホルムから再結晶すると、４００η（０，００２モル）の２．４−ジクロル−６−メチルスルホンアミド−１，３，５−トリアジンが２０４〜２０６℃の融点を有する白色固体として得られた。生成物の元素分析は次の通りであった：分　析　：　ＣＨＣｊ２　Ｈ４０２Ｓ計算値：　Ｃ，１９，７６：　Ｈ，１，６６：　Ｎ、　２３．０５実測値：　Ｃ，１９，４８：　Ｈ，１，６８：　Ｎ、　２２．４４この化合物を以下化合物１４３と称する。施　例　ＬＸＸＶ２．４−ジクロル−６−（１°・・ピペリジノ・アミノ）−１，３，５−）−リアジンの艷Ｌ１２０ｄのアセトン中に５．ＯｊＪ　（’０．０３モル）の塩化シアヌルを含有する０℃の溶液に、温度を５℃以下に維持しながら、２１ｍのアセトン中に３．１５ｄ！　（０，０３モル）の２．６−ルチジン及び２．７ｇ（０，０３モル）のドアミノピペリジンを含む溶液を消和した。２時間攪拌後、反応混合物を室温まで加温し、１時間攪拌した。次いで反応混合物を濾過し、Ｐ液を蒸発させた。残留物をシリカゲルクロマトグラフィーにかけると、６２０ｑ　（０，００２モル）の２．４−ジクロル−６− （１°−ピペリジノアミノ）−１，３，５−トリアジンが１１４〜１１７℃の融点を有する黄色固体として得られた。生成物の元素分析は次の通りであった：分　析　二　０８　Ｈ１１０１２Ｎ５計算値：　Ｃ，３８，７２：　Ｈ，４，４７；　Ｎ、　２８．２３実測値：　Ｃ，３７，３１：　Ｈ，４，５６：　Ｎ、　２６．７５この化合物を以下化合物１４４と称する。３５０−のアセトン中に９２．２９　（０，５モル）の塩化シアヌルを溶解させて一３０℃に冷却した溶液に、反応温度を一２０℃以下に維持しながら９０９　（２，０モル）の液体ジメチルアミンを添加した。反応混合物の攪拌を止めると内部温度は５℃に上昇した。次いで反応混合物を２Ｋｇの砕いた氷に注入後、反応混合物の温度を０℃に維持しながら表面に空気を吹き込んでアセトンを蒸発させた。濾過後、１２４ｇの固体をペンタンから再結晶させ、シリカゲルりロマトグラフィーにかけると、４ＱＱａｙ　（０，００２モル）の２，４−ビス（ジメチルアミノ）−６−クロル− １，３，５−ｔ−リアジンが６２〜６４℃の融点を有する黄色固体として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ７Ｈ１２ＣＩＮ５実測値：　Ｃ，４１，３２：　Ｈ，５，９４：　Ｎ、　３５．１８この化合物を以下化合物１４５と称する。実　施　例　ＬＸＸ■ ２．４−ジクロル−６−シメチルアミノー１，３．５−トリアジンの製造３８０ｄのアセトン中に９２．２９　（０，５モル）の塩化シアヌルを溶解きせて一３０℃に冷却した溶液に、反応温度を一２０℃以下に維持しながら７９９　（０，７モル）の４０％ジメチルアミン水溶液を添加した。添加終了後、反応混合物を一１０℃で３０分間攪拌した。反応混合物を２に９の砕いた氷に注入後、反応混合物の温度を０℃に維持しながら表面に空気を吹き込んでアセトンを蒸発させた。濾過後、固体をペンタンから再結晶させると、５９．０ｇ（０，３モル）の２．４−ジクロル−６−シメチルアミノー１　、Ｓ、　５−トリアジンが１１１．５〜１１５．５℃の融点を有する白色固体として得られた。生成物の元素分析は次の通りであった：分　析　二　０５　Ｈ６０１２Ｎ４計算ｆａ　：　Ｇ、　３１．１１　；　Ｈ，３，１３；　Ｎ、　２９．０３実測値；　Ｃ，３１，０６：　Ｈ，３，０６：　Ｎ、　２９．４にの化合物を以下化合物１４６と称する。１２０ｄのアセトン及び２００　ｍの砕いた氷−水中に１８．４９（０，１モル）の塩化シアヌルを含む溶液に、反応温度を５℃以下に維持しながら１７．４９　（０，１モル）のモルホリンを添加した。温度を５℃以下且つｐＨを８．０以下に維持しながら、この混合物に水酸化ナトリウム溶液（２Ｎ溶液２５ｄ　）を添加した。反応混合物をＰ遇し、分離した固体をエーテルから再結晶すると、８．０９　（０，０３モル）の２．４−ジクロル−６−（１−モルホリニｌリー１．３．５−トリアジンが１５４〜１５７℃の融点を有する白色固体として得られた。生成物の元素分析は次の通りであった：分　析　：　ＣＨＣ１２Ｈ４０計算’ｆｉｆＩ　：　Ｃ，３５，７６：　Ｈ，３，４３：　Ｎ、　２３．８４実測値：　Ｃ，３５，５８：　Ｈ，３，６０；　Ｎ、　２３．８３この化合物を以下化合物１４７と称する。実　施　例　ＬＸＸｒＸ実施例ＬＸＸ■と同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１４８〜１４９の構造及び分析データを下記表Ｈに示プ。ＣＩ大−」Ｌ二が　ＬＸＸＸｉａ、ｏｇ（０，０９モル）の実施例ＬＸＸＶＩで作成した２、４−ジクロル− ６−シメチルアミノー１．３．５〜トリアジンを、１．３０℃に加熱し、塩素ガスを導入し、溶液に紫外線を５時間照射した。生じた残留物をシリカゲルクロマドグラフイーにかけると、３００■（０，００１モル）の２−ビス（クロロメチル）アミノ−４，６−ジクロル−１，３，５−トリアジンが油状物として得られた。生成物の元素分析は次の通りであった：分　析　：　０５　Ｈ４Ｃ１４Ｎ４計算値：　Ｃ，２２，９２；　Ｈ，Ｃ５４：　Ｎ、　２１．３９実測値：　Ｃ，２３，１０；　Ｉ−１，’１．８７：　Ｎ、　２１．９３この化合物を以下化合物１５０と称する。実　施　例　＋−ｘ　ｘ　ｘ　ｒ２．２’−［１，２−フェニレンビス（オキシ）］−ビス　４．６−名久旦工二１．３．５−トリアジン］の製造実施例し■と同様にして、塩化シアヌルを酸受容体としての２．６−ルチジンの存在下で１．２−ジヒドロキシベンゼンと反応させると、１５４〜１５６℃の融点を有する２、２°−［１，２−フェニレンビス（オキシ）］−ビス［４，６− ジクロル−１，３，５−トリアジン］が得られた。生成物の元素分析は次の通りであった：分　析　：　ＣＨ０１４Ｎ６０２計ＩＩ値：　Ｃ，３５，５０；　Ｈ，０，９９；　Ｎ、　２０．７０実測値；　Ｃ，３５，６０：　Ｈ，１，２９；　Ｎ、　２０．６８この化合物を以下化合物１５１と称する。施　例　ＬＸＸＸＩ［潰１５０ｄのアセトン中に２０．０ｇ（０，１０８モル）の塩化シアヌルを含む攪拌溶液に、−７０℃で１２．６ｄ　（０，１２モル）の２，６−ルチジンを消和した。８．３ｄ　（０，１１モル）の２−ブＯパ・ノールを添加し、得られた混合物を窒素雰囲気上室温で約１６時間攪拌した。次い真空無滴すると、２．０９　（０，０１モル）の２．４−ジクロル−６−イツブＯポキシー１．３．５−トリアジンが１５２〜ｂを有する油状物として得られた。Ｂ：２，４−ジブロム−６−イツブロボキシー１，３．５−トリアジンの製造実施例ＸＴＸと同様にして、２５℃の温度、メチレンクロリド溶液中でＡで作成した２、４−ジクロル−６−イツブＯポキシー１，３．５−トリアジンを臭化水素ガスで処理すると、２．４−ジブロム−６−イツブロボキシー１，３．５−トリアジンが不安定な固体として得られた。生成物の元素分析は次の通りであった：分　析：　Ｃ６Ｈ７Ｂ　ｒ２　Ｎ３　０計算値：　Ｃ、２４，２４：　Ｈ，２，３６；　Ｎ、　１４．１４　：３　ｒ　、　５３．８７実測値：　Ｃ、２１，１４；　Ｈ，２，８３；　Ｎ、　１３．８９　：３　ｒ　、　５３．８８この化合物を以下化合物１５２と称する。施　例　ＬＸＸＸＩ［１５−（３°、５゛−ジクロルフェノキシ）−３，６−ジクロル−１，２，４−トリア５０９　（ム珪０，４４モル）の６−アザウラシル、　４９．８ｄ　（１，０モル）の臭素及び６２５ｄの水を含有する混合物を磁気攪拌機を用いて２７時間攪拌した。混合物をＰ遇すると、白色粉末が得られた。Ｐ液を濃縮して得られた第２の生成物を第１の生成物と合した。白色固体を水から再結晶し、乾燥すると、２３４〜２３７℃の融点を有する５−ブロム−６−アザウラシル５３．４ｇ（０，３３モル）が得られた。２９９、ｓ＊、＜　３゜４モル）のオキシ塩化リン中に１４．４ｇ（０，０１３モル）の上記で作成した５−ブロム−６−アザウラシルを含む溶液に、３ｏ、ｏｇ（０，１クモル）の五塩化リン及び３０ｄ（０，１９モル）のＮ、Ｎ−ジエチルアニリンを添加した。混合物を磁気攪拌し、２時間還流加熱し、室温で２４時間放置した。過剰の溶媒を減圧下で除去し、残留物を２００−の乾燥エーテルで８回抽出した。エーテルを除去し、残留物を７０℃／　０．００７履で一溜すると、５６〜５８℃の融点を有する３、５．６−ドリクロロー１．２．４−トリアジン８．７７９（０，０５モル）が得られた。５０ｄのアセトン中に１．８４ｇ（０，０１モル）の八で作成した３、５゜６− ドリクロロー１．２．４−トリアジンを含む溶液に、１０ｄのアセトンに溶解させた１、６３ｇ（０，０１モル）の３，５−ジクロルフェノール及び１．０７９　（０，０１モル）の２．６−ルチジンを含む溶液を反応温度が０〜５℃に維持されるような速度で冷却且つ攪拌しながら添加した。反応混合物を２時間磁気攪拌し、室温まで加温した。沈澱した２、６−ルチジン塩ＭｌをＰ別し、５０ｄのアセトンで洗浄した。アセトン溶液を約１００９の氷に注入し、沈澱した一生した。固体を乾燥し、ヘキサンから結晶化すると、２．詩（０，００７モル）の５−（３°、５°−ジクロルフェノキシ）−３，６−ジクロル−１，２，４−トリアジンが１３０〜１３２℃ の融点を有する白色固体として得られた。生成物の元素分析は次の通りであった：分　析：　Ｃ９Ｈ３Ｃｆ！　４　Ｎ３０計算値：　Ｃ，３４，７６：　Ｈ，０，９７：　Ｎ、　１３．５１実測値：　Ｃ，３４，６４：　Ｈ，０，９３：　Ｎ、　１３．６９この化合物を以下化合物１５３と称する。、　例　ＬＸＸＸｒＸ実施例ＬＸＸＸ■と同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合実　施　例　ＸＣ３−（２’、４°−ジクロルフェノキシ）−３，６−ジクロル−１，２，４−トリアジンの製造実施例■と同様にして３，５．６−）シクロロー１．２．；’ｌＩ−トリアジン９０〜９３℃の融点を有する５−（２°、４°−ジクロルフェノキシ）−３，６ −ジクＯルー１．２．４−１−リアジン３．０ｇ（０，０１モル）が得られた。生成物の赤外分析は次の通りであった：ＩＲ（ＫＢｒ）３０９０、１５３０．１５０５．１４７０．１４００．１２９５．１２３５．１２０５．１１００１０５０、９８５．８６５．８３０．７５０ロー１この化合物を以下化合物１５７と称する。実　施　例　ＸＣＬ実施例ＸＣと同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１５８〜１６０の構造及び分析データを下記表Ｊに示す。実　施　例　ＸＣＵｈ貼２り」ルベンズアルデヒド０−（３，６−ジクロル−１，２，４−トリアジン−４−イル）オキシムの製造実施例ｘｘｘｖｉと同様にして、３，５．６−ドリクロルー１．２．４−トリアジンを２．６−ジクロルベンズアルドキシムと反応させると、１０３〜１０５℃ の融点を有する２、６−シクロルベンズアルデヒド０−（３，６−ジクロル−１，２，４−トリアジン−４−イル）オキシム０．９３（ｊ（０，００３モル）が１ｑられた。生成物の元素分析は次の通りであ計算値：　Ｃ，３５，５４：　Ｈ，１，１９；　Ｎ、　１６．５８実測値：Ｃ，３５，γ６　：　Ｈ，？、６０；　Ｎ、　１７．０４この化合物を以下化合物１６１と称する。実　施　例　ｘｃｍ３−り０ルー６−（２°、４−ジクロルフェノキシ）ピリダジンの製造２００ｔｄのアセトン中に５．９６９（０，０４モル）の３，６−ジクロルピリダジン、　６．５２９　（０，０４モル）の２，４−ジクロロフェノール及び５．８０ｇ　（０，０４モル）　（７）Ｋ　ｃｏ３ヲ含む混合物を水浴上で２時間加熱した。溶媒を除去し、残留物を１００ｄの１０％ＮａＯＨ水溶液、次いで水で洗浄した。粗な固体をヘキサンから結晶化すると、１．６ｇ（０，００６モル）の３− クロル−６−（２°、４−ジクロルフェノキシ）ピリダジンが８９〜９１℃の融点を有する白色固体として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ５０１３Ｎ２０計算値：　Ｃ，４３，５９；　Ｈ，１，８３：　Ｎ、　１０．１７実測値：　Ｃ，４３，５９：　Ｈ，１，９１；　Ｎ、　１０．０にの化合物を以下化合物１６２と称する。実　施　例　ＸＣＩＶ実施例ｘｃｍと同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１６３の間道及び分析データを下記表Ｋに示す。茄　例　ＸＣＶトリス　４，６−ジクロル−１，３，５−トリアジン−２−イル）アミンの毀】ビス（４，６−ジクロル−１，３，５−トリアジン−２−イル）アミンを製造する実施例ＬＶＩと同様にして１．固体沈澱物を濾過すると、トリス（４，６−ジクロル−１，３，５−トリアジン−２−イル）アミンが３６０℃以上（分解）の融点を有する１ｊ生成物として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ９Ｃｌ　６　Ｎ１゜計算値：　Ｃ，２３，４５：　Ｈ，０，’（１０；　Ｎ、　３０．３９実測値；　Ｃ，２１，８５：　Ｈ，１，１８：　Ｎ、　３３．６５この化合物を以下化合物１６４と称する。実　施　例　ＸＣＶＩ実施例ＸＣ■と同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１６５の構造及び分析データを下記表しに示す。表　し、−施　例　ＸＣＶＩ３−　ロルー６−３゛−クロルフェノキシ）ピリダジンの製造２４ｍの１．２５Ｎ水酸化ナトリウム水溶液中に１．９３ＳＦ　（０，０１５モル）の３−クロルフェノール及び１．５ｇ（０，００５モル）のテトラブチルアンモニウムブロマイドを含む溶液に、５０ｄのトルエン中に２．２３９　（０，０１５モル）の３．６−ジクロルピリダジンを溶解させた溶液を添加した。この混合物を５０℃で３時間加熱した。有機層を分離し、希ＮａＯＨ溶液及び水で洗浄し、ＭｇＳＯ４で乾燥し、蒸発させた。得られた残留物をヘキサンから結晶化すると、１．５５ｇ（０，００６モル）の３−クロル−６−（３’−クロルフェノキシ）ピリダジンが８５〜８８℃の融点を有する白色固体として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ６Ｃ１２Ｎ２０計算値：　Ｃ，４９，８２：　Ｈ，２，５１；　Ｎ、　１１．６２実測値：　Ｃ，４９，８７：　Ｈ，２，４８：　Ｎ、　１１．６５この化合物を以下化合物１６６と称する。４−（４°−ニトロフェノキシ）−２，５，６−ドリクロルビリミジンのＵ実施例工と同様にして、２，４，５．６−テトラクロルビリミジンと４−ニトロフェノールをアセトン溶液中、受容体としての２．６−ルチジンの存在下で反応させ、真空で昇華させ、ヘキサンから２回再結晶化すると、１１４〜１１６℃の融点を有する４−（４−ニトロの元素分析は次の通りであった：分　析　二　Ｃ１ｏＨ４Ｃ１３Ｎ３０３計算値：　Ｃ、３７，４７：　Ｈ，１，２６；　Ｎ、　１３．１１　：ＣＩ、　３３．１８実測値：　Ｃ、３６，８９；　Ｈ，１，５２：　Ｎ、　１３．００　：Ｃｆ１．３２．７９この化合物を以下化合物１６７と称する。実　施　例　ＸＣｒＸ実施例ＸＣ■と同様にして、他の化合物を製造した。植物からの、水分損失を減少させるため後記実施例で使用する化合物１６８〜１６９の構造及び分析データを下記表Ｍに示す。実　施　例　Ｃ２−２゛４°−ジクロルフェノキシ）ペンタクロルシクロトリホス二二並之立１】５０ｄのアセトン中に１０．８ｇ（０，９’３モル）のホスホニトリルクロライドトリｖ　−（ｐｈｏｓｐｈｏｎｉｔｒ１２ｉｃ　ｃｈｌｏｒｉｄｅ　ｔｒｉＩｌｌｅｒ）ヲ含む溶液に、窒素雰囲気下−６０℃の温度で１０ｍのアセトン中に３．１ｄ（０，０３モル）の２，６−ルチジンを含６溶液及び４０ｄのアセトン中にｓ、ｏｇ（０，０３モル）の２．４−ジクロルフェノールを含む溶液を添加した。反応混合物を室温まで加温し、約１６時間撹拌し、濾過し、Ｐ液を氷水に注入した。濾過により固体（６，８ｇ）を集め、昇華により未変換の２．４−ジクロルフェノールを除去した。昇華物中に残存するピンク色の半固体を集めると、０．９Ｕ（０，００２モル）の２−（２°、４゛−ジクロルフェノキシ）ペンタクロルシクロトリホスファゼンが得られた。生成物のＮＭＲ分析は次の通りであった：６　７．２０−７．５５ｐｐＨ１（ｆｆｉ、芳香族プロトン）この化合物を以下化合物１７０と称する。実　施　例　ＣＩ２．４−ジクロル−６−（２°、４゛−ジクロルフェノキシ）へキサヒドロ−１３５−トリアジンの製造５０ｄの無水エヂルエーデル中に３４０η（０，００１モル）の２．４−シクロルー６−（２°、４°−ジクロルフェノキシ）−１，３，５−トリアジンを含む懸濁液に、４００ｑ　（０，０１モル）の水素化ホウ素ナトリウム及び５ｊ１１！のメタノールを少しずつ添加した。混合物を５分間撹拌し、更に４２０１１ｇ（０，０１モル）の水素化ホウ素ナトリウムを添加した。混合物を１５分間撹拌後、１５０ｄのエーテルを添加し、混合物をエーテルと水に分配した。有機層をＮａ２ＳＯ４で乾燥し、蒸発させると、３４０ｉｎｇ　（０，００１モル）の２，４−ジクロル−６−（２°、４°−ジクロルフェノキシ）へキサヒドロ−１，３，５−トリアジンが不安定な白色固体として得られた。生成物のＮＭＲ分析は次の通りであった：１３ＣＮＭＲ（ＧＯＣＮ／Ｄ２０）：・δ　１１８．５３．１２１．８６．１２４．８７．　ｉ２５．７１．１２８．８２．１２９．５゜１３０、０９及び　１３０．９３　ＣＤＩこの化合物を以下化合物１７１と称する。実　施　例　ｃｍ２４−ジクロル−６−４−（４−エトキシフェニルアゾ）−１−ナフトキシ−１，３，５−トリアジンの製造実施例Ｌ１１［と同様にして、１７３〜１１７℃の融点を有する２、４＝ジクロル−６−（４−（４−エトキシフェニルアゾ）−１−ナフ］〜キシＪ−１゜３．５−トリアジンを製造した。生成物の元素分析は次の通りであった：分　析　：　Ｃ２１Ｈ１，ＣＩ　２　Ｎ５０２計　寥γ　値　：　Ｃ，５７，２９：　ト１　３．４３：　Ｎ　、　１５．９０実測値：　Ｃ，５７，５２：　Ｈ，４，０８：　Ｎ、　１５．６にの化合物を以下化合物１７２と称する。実　施　例　Ｃ■ 虹（Ｚ欠且玄」亘に久上土之ｌユノ１シ）−１，３，５−トＩＪンジンの実施例ＸＸ■のＢと同様にして、塩化シアヌルを酸受容体としての２，６−ルチジンの存在下で２−メトキシフェニルと反応させると、９３〜９４．５℃の融点を有する２、４−ジクロル−６−（２−メトキシフェノキシ）−１，３，５−ｔ−リアジンが得られた。生成物の元素分析は次の通りであった：　分　析：　Ｃ１ｏＨ７０１２Ｎ３　ｏ２計算値：　Ｃ，４４，１４：　Ｈ，２，５９；　Ｎ、　１５．４４実測値：　Ｃ，４３，９９：　Ｈ，３，００：　Ｎ、　１５．２７この化合物を以下化合物１７３と称する。実　茄　例　ＣＩＶ虹虹２皇旦にヨＥ恨ピ整仁ジルオキ乞２ユノキシ）−１，３，５−１−！Ｊアｚｚ立立上１施例ＸＸＩ［のＢど同様にして、塩化シアヌルを酸受容体としての２，６−ルチジンの存在下で２−ベンジルオキシフェノールと反応させると、９２〜９４℃ の融点を有する２、４−ジクロＡ／−６−（２−ベンジルオキシフェノキシ）− １，３，５−１−リアジンが得られた。生成物の元素分析は次の通りであった：分　析：　Ｃ１６Ｈ１１Ｃ１２Ｎ３０２計算値：　Ｃ，５５，１９；　Ｈ，３，１８；　Ｎ　、　１２．０７実測値：　Ｃ，５５，５９；　Ｈ，３，１９；　Ｎ、　１１．７にの化合物を以下化合物１１４と称する。実　施　例　Ｃｖ２．４−ジクロル−６−［４−（１−メチル−１−［４−プロポキシフェニル　エｓ、ｏｇ（０，０２モル）のＢ１５ｐｈｅｎｏｌ　Ａ、　３．０４ｇ　（０，０２モル）の炭酸カリウム及び１００−のアセトフェノンの混合物を１５０℃で２時間撹拌、加熱した。室温まで冷却後、３．２２ｄ　（０，０３モル）−の１ −ヨードプロパンを添加し、混合物を１００℃で約１６時間撹拌、加熱した。反応混合物を放誼して冷却し、固体を濾過により除去した。アセトフッエノンを減圧蒸留により除去し、残留物を４−プロポキシフェニル）エチル］フェノールが得られた。フエ’ＨＮＭＲ（ＣＤ、Ｃ１）　３　）　：　δ　ｏ、ｇｏ−１，９１（鵬、ＩＩＨ）。３．９０（ｔ、２Ｈ，Ｊ−７Ｈｚ）。５．１５（Ｓ、Ｈ）、　６．５７−７．２１（ｍ、８Ｈ）ｐｐ園Ｂ：２４−ジクロル−６−４−１−メチル−１−４−プＯボキシフェニルーエチル）フェノキシ−１，３５−トリアジンの貫実施例ＸＸ■の８と同様にして、塩化シアヌルを酸受容体としての２．６−ルチジンの存在下でＡで作成した４−［１−メチル−１−（４−プロポキシフェニル）エチル］フェノールと反応させると、２．４−ジクロル−６−［４−（１−メヂルー１−〔４−プロポキシフェニル１−エチル）Ｊフェノキシ−１，３，５−トリアジンが油状物として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ２１Ｈ２１ＣＩ！　２　Ｎ３０２　。計算ｔｉｌｌ　：　Ｃ，６０，３０：　Ｈ，５，０６：　Ｎ、　１０．０４丈測Ｗｉ：　Ｃ，５９，６２：　Ｈ，５，０６：　Ｎ、　１０．８４この化合物を以下化合物１７５と称する。施　例　ＣＶｌ２４−ジ　ロルー６−４−　（１−％　％壓」ユ（４ス」Σ多ジフェニル　エチ実施例ＣｖのＡと同様にして、ビスフェノールＡをアセトン溶液中、酸受容体としての炭酸カリウムの存在下でヨウ化メチルと反応させると、４−［１−メチル −１−（４−メトキシフェニル）エチル］フェノールが得られた。フェノール中間物のＮＭＲ分析は次の通りであった：１ＨＮＭＲ（ＣＤＣ１３゛）：δ　１．６３（ｓ、６旧、　３．７７（ｓ、３Ｎ）。５．６２（ｓ、Ｈ）、６．５５−７．２７（ｉ＋、８１）ｐｍしての２，６−ルチジンの存在下でＡで作成した４−［１−メチル−１−（４〜メトＡ、ジノエニル）エチル］フェノールと反応させると、１０８・・１１１℃ の融点を有する２、４−ジクロル−６−［４−（１−メヂルー１−［４−メ１− キシフェニル１−エチル）】フェノキシ−１，３，５−）−リアジンが得られた。生成物の元素分析は次の通りであった：分　析　二　０１９Ｈ１７ＣＩ　２　Ｎ３　ｏ２計算［：　Ｃ，５９，４７：　Ｈ，４，３９：　Ｎ、　１０．７７実測値；　Ｃ，５８，３５：　ｌ−１，４，４０；　Ｎ、　１０．７にの化合物を以下化合物１７Ｇと称する。実　施　例　Ｃ■ ２、４−シ’）　ロル−６−［４−（１−メチル−１−４−ヘンシ）Ｌｔｉキシ７エ、：：／ｌｙ１エヂル）Ｊフェノキシ−１，３５−１−リアジンのＪ浩Ａ：４−［１−メチル−１−（４−ベンジルオキシフェニル）工ＬＬＬフェノールの製造実施例ＣｖのＡと同様にして、ビスフェノールＡをアセトン溶液中、酸受容体としての炭酸カリウムの存在下で塩化ベンジルと反応させると、４−［１−メチル −１−（４−ベンジルオキシフェニル）エチル］フェノールが得られた。フェノール中間物のＮ　ＭＲ分析は次の通りであった： ”ＨＮ　〜＋Ｒ（ＣＤＣ１３）　：　６　１．６０（ｓ、６Ｈ）、　４．５７（ｓ、３１１）。５．００（ｓ、２Ｈ）、　６．５６−７．４８（ｍ、８１１）００ｍしての２，６−ルチジンの存在下でＡで作成した４−［１−メチル−１−（４− ベンジルオキシフェニル）エチル］フェノールと反応させると、１１７．５〜１１９℃の融点を有する２、４−ジクロル−６−［４−＜１−メチル−１−［４− ベシジルオキシフェニル］−エチル）１フェノキシ−１゜３．５−トリアジンが得られた。生成物の元素分析は次の通りであった：分　析　：　０２５日２１０！　２　Ｎ３０２計算＊　：　Ｃ，６４，３９：　Ｈ，４，５４：　Ｎ、　９．０１実測値：　Ｃ，６４，０９：　Ｈ，４，５９；　Ｎ、　８．８７実施例ＸＸ■のＡと同様にして、カテコールを酸受容体としての水酸化ナトリウムの存在下で１−ブロモブタンと反応させると、２−（ｎ−ブチルオキシ）フェノールが得られた。フェノール中間物のＮＭＲ分析は次の通りであった：’ｌ−ＩＮＭＲ（ＣＤＣｆｉ　３）：δ０．７３−１．９５（ｍ、　７Ｈ）。３．６３−４．０８（ｔ、２Ｈ）。６．０２−７．３２（ａ＋、４Ｈ）１１ｐｍ実施例ＸＸ■のＢと同様にして、塩化シアヌルを酸受容体としての２，６−ルチジンの存在下でＡで作成した２−（ｎ−ブチルオキシ）フェノールと反応さぜると、２，４−ジクロル−６−（２− ｎ−ブチルオキシフェノキシ）−１，３，５−１−リアジンが油状物として得られた。生成物の元素分析は次の通りであった：分　析゛：　Ｃ４３Ｈ１３Ｃｆ！　２　Ｎ３　ｏ２計算値：　Ｃ，４９，７０：　Ｈ，４，１７；　Ｎ、　１３．３７実測１ｉｆＩ　：　Ｃ，５０，８２：　Ｈ，４，６９：　Ｎ、　１２．９８この化合物を以下化合物１７８と称する。実　施　例　ＣＩＸ実施例Ｃ■と同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１７９〜１８４の構造及び分析データを下記表Ｎに示す。実　施　例　ＣＸ２．４−ジクロル−６−（４−（４−ペンジルオキシーフェニルチオ）フェノキシ−１，３，５−トリアジンの製造Ａ　：　４−［（４−ベンジルオキシフェニルチオ）フェノールの１４ｓ、Ｃ９（０，０２モル）の４，４°−チオビスフェノール、　３．７９ｇ（０，０３モル）の炭酸カリウム及び７５ｍのアセトンの混合物を２時間還流加熱した。空温まで冷却後、反応混合物に４．３５ｇ（０，０３モル）の塩化ベンジルを消和し、次いで１６６時間還流加熱た。反応混合物を室温まで冷却し、Ｃｅ１ｉｔｅを介して濾過して固体物質を除去した。Ｐ液を真空下で濃縮し、残留物をフラッシュクロマトグラフィーで精製スると、２．８２ｇ（０，０１モル）の４−（（４−ベンジルオキシフェニルチオ）］フェノールが得られた。フェノール中間物のＮＭＲ分析は次の通りであっ、た：′１ＨＮＭＲ（ＣＤＣＩ１３）：δ　４．９８（ｓ、Ｈ）、　５．０８（Ｓ、２Ｈ）。６．６５−７．５０（１，１３ｔｌ）　Ｄｐ鋤３：２．４−ジクロル−６−［４ −（４−ベンジルオキシフェニルチオ）Ｊフェノキシ−１，３，５−トリアジンの製造実施例ｘＸ■のＢと同様にして、塩化シアヌルを酸受容体としての２．６ −ルチジンの存在下でＡで作成した４−［（４−ベンジルオキシフェニルチオ）】フェノールと反応させると、１１９〜１２０℃の融点を有する２、４−ジクロル−６−［４−（４−ベンジルオキシフェニルチオ）Ｊフェノキシ−１，３，５ −トリアジンが得られた。生成物の元素分析は次の通りであった：分　析　二　Ｃ２２Ｈ１５Ｃ１２Ｎ３０□　Ｓ計算値：　Ｃ，５７，９０：　Ｈ，３，３１：　Ｎ、　９．２０実測値：　Ｃ，５８，４９：　Ｈ，３，６０；　Ｎ、　８．９４この化合物を以下化合物１８５と称する。１−厘−１９１ＣＸＩ実施例ＣＸと同様にして、他の化合物を製造した。植物からの水分損失を減少させるため後記実施例で使用する化合物１８６〜１８７の構造及び分析データを下記表Ｏに示す。表　Ｏ代表的窒素含有複素環化合物ＩＩ実　旅　例　ＣＸ■ ２−クロル−４−メヂルー６−［４−（１−メチル−１−［４−メトキシフェニルエチル）１−フェノキシ−１，３，５−トリアジンの製造５０ｄのテトラヒドロフラジ中に０．７ｉ　（０，００２モル）の実施例ＣＶＩで作成した２、４− ジクロル−６−［４−（１−メチル−１−〔４−メトキシフェニルエチル）］］フェ／キシー１．３．５−トリアジを含む撹拌溶液に、２．０４〆＜　ｏ、ｏｏｅ＠ル）の２．７Ｍ臭化メチルマグネシウムのエチルエーテル溶液を混合物を水浴上で冷却しながらゆっくり添加した。その後、反応混合物を室温まで加温し、１５時間撹拌した。真空蒸発により溶媒を除去し、残留物をタラッシュクロマトグラフィー（溶出剤３％酢酸エチル−ヘキサン）で精製プると、０．４３ｇ　（０，ＯＯ’１モル）の２−クロル−４−メヂルー６−［４−（１−メチル−１− ［４−メトキシフェニル］エチル月−フエノキシ−１，３，５−トリアジンが６５．０〜６７．５℃の融点を有する淡黄色の結晶として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ２゜Ｈ２ｏＣ！　Ｎ３０２　ｓ言Ｉ　算ｆｆｉ　：　Ｃ，６４，９５：　Ｈ，５，４５：　Ｎ、　１１．３６実測値：　Ｃ，６４，５８：　Ｈ，５，５７：　Ｎ　、　１１．２５この化合物を以下化合物１８８と称する。実　施　例　ＣＸ［［２，４−ジクロル−６−（４−（クロルフェニルスルホニル）Ｊフェノキシ−１，３，５−トリアジンの製造Ａ：４−クロルフェニル４−ヒドロキシフェニルスルホンの製造１００ｄのジメチルスルホキシド中に２８．７ｇ（０，ｉモル）のビス（４−クロルフェニル）スルホンを含む撹拌溶液に、反応混合物を４０℃に加熱しながら１５Ｉ１１！の水中に１３．３ｇ（０，２３モル）の水酸化カリウムを含有する溶液を１０分間で添加した。次いで反応混合物を１０５℃で５時間加熱し、室温まで冷却し、３００ｄの水に注入した。乳白色の沈澱物を戸別し、Ｐ液をＨＣｊで酸性化塩基層をＨＣｌで酸性化し１．エーテル（２ｘ　５０ｄ　）で抽出した。エーテルを蒸発すると、１４３．０〜１４６．０℃の融点を有する４−クロルフェニル４°−ヒドロキシフェニルスルホン１９．２１　（ｊ（０，０８モル）が得られた。キシ−１，３，５−トリアジンの製造実施例ＸＸ■のＢと同様にして、塩化シアヌルを酸受容体としての２，６−ルチジンの存在下でＡで作成した４−クロルフェニル４−ヒドロキシフェニルスルホンと反応・させると、１６７℃の融点を有する２、４−ジクロル−６−（ａ−＊ｏルフェニルスルホニル）１フェノキシ−１，３，５−トリアジンが得られた。生成物の元素分析は次の通りであった：分　析　：　０１５Ｈ８０！　３　Ｎ３０３　ｓ計算値：　Ｃ，４３，２４：　Ｈ，１，９３：　Ｎ、　１０．０８実測値：　Ｃ，４３，１６：　Ｈ，２，０１：　Ｎ、　１０．０１この化合物を以下化合物１８９と称する。実施例ＸＸ■のＢと同様にして、塩化シアヌルを酸受容体としての２．６−ルチジンの存在下でビス（４−ヒドロキシフェニル）スルホンと反応させると、２３０〜２３５℃の融点を有するビス［４−（４，６−ジクロル−１，３，５−）− リアジン−２−イルオキシ）フェニル）】スルホンが得られた。生成物の元素分析は次の通りであった：分　析：　Ｃ１８Ｈ８Ｃｌ　４　Ｎ６０４計算値：　Ｃ，３９，５８：　Ｈ，１，４８：　Ｎ、　１５．３９実１１１１１ｍ　：　Ｃ，４１，３０：　Ｈ，１，７３：　Ｎ、　１４．６１この化合物を以下化合物１９０と称する。 −― （４，６−ジクロ／１．−１．３．５−１−リアジン−ζ−イル）（４，６−シメトキシ二１．３．５−１−リアジン−２−イル）エーリ止Ａ　：　２，４．６ −１−ジメトキシ−１，３，５−ドリア２之立）】１００Ｉｎ！！のメタノール中に１２．０ｇ（０゜３０モル）の水酸化ナトリウムを含有する撹拌溶液へ、反応温度を２５〜３０℃に保持しながら１８．５ｇ　（ｂ、ｉｏモル）の塩化シアヌルを少しずつ１時間を要してゆっくり添加した。この禮反応混合物を空温で２時間撹拌した。混合物を濾過し、Ｐ液からメタノールを減圧蒸発させた。残留物を減圧乾燥し水から結晶化させると、１２２〜１２９℃の融点を有する２、４．６−１−リストキシ−１，３，５−１−リアジン４，３ｇ（０，０２５モル）が得られた。逆相高圧液体クロマトグラフィー分析の結果、生成物のＩｉ！！度は約７５％であった。久左夏１１２５ａｅのメタノール中に１．８６ｇ＜０．０５モル）の水酸化ナトリウムを含有する溶液にＡで作成した２、４．６−トリメトキシ１，３．５−トリアジン４．０ｇ　（０，０２モル）を添加し、１時間遠流加熱した。溶液を冷却し、白色固体を集め乾燥させると、３．９５９　（０，０２モル）の４．６−シメトキシー１，３．５−トリアジン−２−オレイン酸ナトリウムを得た。上記Ｂで作成した４、６−シメトキシー１，３．５−トリアジン−２−オレイン酸ナトリウム（１，５９，０，０１モル）を２５＃ＩＩ！のアセトニトリルに懸濁させ、混合物を水浴で５〜１０”Ｃに冷却した。２５ｔｎｅのアセ１−ニトリル中に１．５４ｇ（０，０１モル）の塩化シアヌルを含有する溶液を、温度を１０℃以下に保持しながら且つ撹拌しながら消和した。反応混合物を水浴で撹拌し、室温までゆっくり加温した。１６時間撹拌後反応混合物を濾過し、溶媒を蒸発除去した。白色固体残留物をフラッシコクロマトグラフィ−（ヘキサン中３０％酢酸エチル）によりＭ製して、１５８．５〜１６０　’Ｃの融点を有する（４，６−ジクロル−１，３，５−トリアジン−２−イル）（４，６−シメトキシー１．３．５− 　）−リアジン−２−イル）エーテル１．３４９　（０，００４モル）を得た。生成物の元素分析は次の通りであった：？　分　析　二　０８　Ｈ６０１２Ｎ６０３計算ｌ　：　Ｃ，３１，５０：　Ｈ，１，９８：　Ｎ、　２７．５５実測値：　Ｃ，３１，７４：Ｈ，２，０７：　Ｎ、　２７．４７２．２゛−チオビス（４，６−ジクロル−１３５−ト’　７’）＞　（Ｄ”　１１００ｍのアセトン中に１０．０ｇ（０，０５モル）の塩化シアヌルを含有する撹拌溶液に、水３０ｄ中に３．２６ｇ（０，０１モル）の硫化ナトリウム九水和物を含有する溶液を３０分間を要して添加した。この間反応混合物の゛温度を外部冷却により０〜５℃に保持した。反応混合物を０〜５℃で１５分間撹拌し、氷水１５０ＩＲ１を添加した。白色沈澱が形成し、これを直ちに戸別し、乾燥した。減圧昇華により粗生成物から未反応の塩化シアヌルを除去し、残留固体をヘキサン／塩化メチレンから再結晶すると、２，２゛−チオビス（４，６−ジクロル−１，３，５−トリアジン）が１４０〜１４５℃の融点を有する白色固体として得られた。高圧液体クロマトグラフィー分析の結果、生成物の純度は７５％であった。生成物の赤外分析は次の通りであった：ＩＲ（ＣＨＣｊ！３　）　：　１５００．１２４０．８５０ｃｍ−’マススペクトル分析では、ＩＩ／ｅ−３３０を示した（算出された分子ｍ　３２９．９８　）。この化合物を以下化合物１９２と称する。２０．２９　（０，１１モル）の塩化シアヌル、　１８．４９　（０，２２モル）の重炭酸ナトリウム、１００ｍのメタノール及び１２５ｍ１の水の混合物を室温で４０分間撹拌し、１００ｄの水で希釈し、生じた固体を戸別した。白色固体を減圧乾燥させると、融点８８〜９０℃の２，４−ジクロル−６−メドキシー１．３．５−トリアジン１３．４９　（０，０８モル）が得られた。５０７のアセトニトリル中に実施例ＣＸｖのＢで作成した２、９１９（０，０２モル）の４，６−シメトキシー１，３．５−１−リアジン−２−オレイン酸ナトリウムを懸濁させた撹拌懸濁物に、Ａで作成した２゜４−ジクロル−６−メドキシー１．３．５−トリアジン２．９３ｇ（０，０２モル）を消和した。反応混合物を４８８時間遠流加熱、１．１７７　（０，００３モル）のジベンゾ−１８− クラウン−６を添加後更に４８時間還流加熱した。混合物を玲ＩＪｌ　ｕ、７５ｍの塩化メチレンで希釈し、濾過した。溶媒を蒸発後、残留物をフラッシュクロマトグラフィー（溶出剤ヘキサン中２０％酢酸エチル）により精製すると、１２６５〜１２８℃の融点を有する（４−クロル−６−メドキシー１，３゜５−トリアジン−２−イル）　（４，６−シーメドキシー１．３．５−トリアジン−２− イル）エーテル１．６０ｇ（０，００５モル）が得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ９Ｈ９Ｃ１Ｎ６０４計算値：　Ｃ，３５，９５；　Ｈ，３，０１：　Ｎ、　２７．９５実測値：　Ｃ，３５，９２；　Ｈ，３，１２：　Ｎ、　２８．０８この化合物を以下化合物１９３と称する。施　例　ＣＸ■ ２−クロル−４，６−シメトキシー１．３．５−ｔ−リアジンの製造１８．５ｇ（０，１０モル）の塩化シアヌル、　１６．８９　（０，２０モル）の重炭酸ナトリウム、　５７ｍのメタノール及び５ｄの水の混合物を徴しく撹拌し、反応温度が約４０℃に上昇するにつれて二酸化炭素の発生が観察された。２０分後二酸化炭素の発生が穏やかになったとき、反応混合物を３０分間還流加熱した。混合物を冷却し、燥し、１粗生成物をシクロヘキナンから結晶化させると、１０．０７分　析：　Ｃ５Ｈ６ＣｌＮ３０２計算値：　Ｃ，３４，２，０：　Ｈ，３，４４：　Ｎ、　２３．９３実測値：　Ｃ，３４，１４；　Ｈ，３，６０：　Ｎ、　２３．９にの化合物を以下化合物１９４と称する。実　施　例　ｃｘｒｘ ’２＞立１１７５ＩｄのＣＨＣｌ３中に２．６Ｖ　（０，００８モル）のＮ−（２，４−ジクロルフェニル）　−Ｎ’−（４，６−ジクロル−１，３，５−ｔ−リアジン−２ −イル）ヒドラジンを含む溶液と４　乙り寺呂に１．３４ｇ（０，０２モル）のＮａＨＣＯ３を含有する液体との２相混合物に、塩素ガス流を１０分間通した。次いで混合物に窒素をバブリングして過剰の塩素を除去し、有磯相を分離し、水洗し、無水ＭＱＳｏ４上で乾燥して、２．４ｇの暗赤色固体を得た。これを、１．０ｇ（０，００３モル）のＮ−（２，４−ジクロルフェニル）−Ｎ−（４，６ −ジクロル−１，３，５−トリアジン−２−イル）とドラジンを使用する以外は前記と同一の反応に従って製造した生成物９８０■を合した。合した生成物を溶出剤として９：１ｖ／ｖヘキサン−酢酸エチルを用いるシリカゲルのフラッシュクロマトグラフィーでｍｔＡすると、粗生成物が赤色固体として得られた。この粗生成物をヘキサンから再結晶し、得られた物質を昇華させると０．９１ｇ　（０，００３モル）の６−（２，４−ジクロルフェニルアゾ）−２，４−ジクロル −１，３，５−トリアジンが１１９〜１２３℃の融点を有する赤色固体として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ９Ｈ３Ｃ１４Ｎ５計算値：　Ｃ，３３，４７；　Ｈ，０，９４；　Ｎ、　２１．６８実測値：　Ｃ、３２，９５：　）−１、０，９７：　Ｎ　、　２１．１４２−（４−メトキシフェニル）−４，６−ジクロル−１，３，５−トリアジンの艮１実施例ＸＬと同様にして塩化シアヌルを４−ブロモアニソールのグリニヤール試薬と反応させると、１３６．５〜１３８．５℃の融点を有する２−（４−メトキシフェニル）−４，６−ジクロル−１，３，５−トリアジンが得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１゜Ｈ７Ｃ１２Ｎ３０計算値：　Ｃ，４６，９０：　Ｈ，２，７６；　Ｎ、　１６．４１実測値：　Ｃ，４６，７６：　Ｈ，２，７８：　Ｎ、　１６．２９この化合物を以下化合物１９６と称する。（以下余白）実−一施実施例ＣＸＸと同様にして、他の化合物を製造した。植物か１９７〜１９９の構造及び分析データを下記表Ｐに示す。表　Ｐ代表的窒素含有複素環化合物Ｉ（Ｊ実　施　例　ｃｘｘｍ２−［（２−フェノキシ）エトキシ−４，６−ジクロル−１３，５−トリアジ区立ｎ実施例ｘｘｘｍと同様にして２−フェノキシエタノールを酸受容体としての２，６−ルチジンの存在下で塩化シアヌルと反応させると、８１〜８３℃の融点を有する２−［（２−フェノキシ）エトキシ］−４，６−ジクロル−１，３，５−トリアジンが得られた。生成物の元素分析は次の通りであった：分　析：　Ｃ４１日９０１２　Ｎ３０２計算値：　Ｃ，４６，１７：　Ｈ，３，１７：　Ｎ、　１４．６９実測値：　Ｃ、４Ｇ、４１　：　Ｈ、３，４４Ｓ　Ｎ　、　１４．６８この゛化合物を以下化合物２００と称する。実　施　例　ｃｘｘｍ２−（２−（２，４−ジクロルフェノキシ）エトキシ］−４，６−ジクロル−１゜３、５−　）−リアジンの製造Ａ：２−（２，４−ジクロルフェノキシ）エーテルの製造２０ｍの水中に２．４４ｇ（０，６６モル）のＮａ０）−１を含む溶液に、ｔｏ、Ｃ９（０，０６モル）の２，４−ジクロルフェノールを消和した。次いで４．８ｄ　（０，０７モル）の２−ブロモエタノールを添加し、混合物を６０℃の温度で約１６時間加熱した。冷却後、反応混合物をジ水で洗浄し、ＭｇＳＯ４で乾燥した。、減圧下で濃縮すると、８．０２ｇ（０，０４モル）の２−（２，Ａ−ジクロルフェノキシ）エーテルが得られた。フェノール中間物のＮＭＲ分析は次の通りであった：１ＨＮＭＲ（ＣＤＣｊ３）：δ２．７３（＋ｅ、Ｈ）、　３．７−４．４ｈ＋、４８）。６、９７　（ｄ、　Ｈ，Ｊ−８１１２）　、　７．４７ｃｄ、　）ｌ、Ｔ、３Ｈぎ）。７．３３（ｄｄ、Ｈ，Ｊ−３，８Ｈｚ）　ｐｐｍ実施例ｘｘｘｍと同様にして塩化シアヌルを酸受容体としての２．６−ルチジンの存在下でＡで作成した２−（２，４−ジクロルフェノキシ）エーテルと反応させると、１０３〜１０４．５℃ の融点を有する２−［２−（２，４−ジクロルフェノキシ）エトキシ］−４，６ −ジクロル−１，３，５−トリアジンが得られた。生成物の元素分析は次の通り分　析二　０１１Ｈ７０１４Ｎ３０２計算値：　Ｃ，３７，２１：　ｌ（、１，９９；　Ｎ、　１１．８４実測値：　Ｃ，３７，０６：　Ｈ，２，１９；　Ｎ、　１１．７３この化合物を以下化合物２０１と称する。実　施　例　ｃｘｘｒｖ２−［（２，４−ジクロルベンジルオキシ）エトキシ−４６−ジクロル−１、ｊ、５−ｔ−リアジーと立見１１２５ｄのエーテル中に１２５ｇの中性アルミナを含有するスラリーに、５．０ｇ（０，０３モル）の２，４−ジクロルベンジルアルコールと６２．５１１１１！！（０，１２モル）のエチレンオキシドの２Ｈエーテル溶液を添加した。この混合物を空温で約１６時間撹拌し、５００ｄのメタノール中に注入し、６時間放置した。アルミナを戸別し、メチノールで洗浄し、Ｐ液を減圧下で濃縮すると、９．２６　（Ｊの粗生成物が透明な液体として得られた。これを、２．０９　（０，０１モル）の２，４−ジクロルベンジルアルコールを使用°する以外は前記と同溶出剤としてヘキサン−酢酸エチル（１：１　ｖ／ｖ　）を使用してフラッシュクロマドグ１ラフイーで精製すると、１．１　（０，００６モル）の２−（２，４−ジクロルベンジルオキシ）エタノールが無色の液体として得られた。この中間物のＮ　Ｍ　Ｒ分析は次の通りであった： ’ＨＮＭＲ（ＣＤＣｊ３）：δ２．４７（ｂｒ、　ｓ、　Ｈ）。３．５−４．０（ｍ、　４Ｈ）。４．６０（ｓ、２１１）、７．１−７．６（＋ｅ、３１１）００ｍ実施例ＸＸＸＩＩと同様にして塩化シアヌルを酸受容体としての２，６−ルチジンの存在下でＡで作成した２−（２，４−ジクロルベンジルオキシ）エタノールと反応させると、２−（２−（２，４−ジクロルベンジルオキシ）エトキシ］− ４，６−ジクロル−１，３，５−トリアジンが無色油状物として得られた。生成物の元素分析は次の通りであった：分　析二　ＣＨ０１４Ｎ３０２計尊値：　Ｃ，３９，０５ニド１．２．４６：　Ｎ　、　１１．３９実測値：　Ｃ，３９，８２：　Ｈ，２，５５：　Ｎ、　１１．３２この化合物を以下化合物２０２と称する。実施例ｃｘｘｍのＡと同様にして、２，４−ジクロルフェノールを酸受容体としての水酸化ナトリウムの存在下で２−（２−クロルエトキシ）エタノールと反応させると、２−［２−（２，４−ジクロルフ’）ｌＮＭＲ（’ＣＤＣｊ３）：δ ２．８３（ｂｒ、ｓ、Ｈ）。３．５−４．０（ｍ、６）１）。４．１−４．４（ａ、２旧。６．８３（ｄ、Ｈ，Ｊ＝２１１Ｚ）。７．２０（ｄｄ、Ｈ，Ｊ−２，８Ｈ２）。７．３７（ｄ、Ｈ，Ｊ、、２Ｈ２）ｐｆ）ＩＩ実施例ｘｘｘｕと同様にして塩化シアヌルを酸受容体としての２，６−ルチジンの存在下でＡで作成した２−［２ −（２，４−ジクロルフェノキシ）エトキシ］エタノールと反応させると、５９，５〜６１．５℃の融点を有する２−（２−［２−（２，４−ジクロルフェノキシ）エトキシ］エトキシ）−４，６−ジクロル−１，３，５−トリアジンが得られた。生成物の元素分析は次の通りであった：分　析　：　０１３Ｈ１１Ｃ！４　Ｎ３　ｏ３計算値：　Ｃ，３９，１２：　Ｈ，２，７８：　Ｎ　、　１０．５３実測値：　Ｃ，３８，６５；　ｌ−１，２，７６：　Ｎ、　１０．７１この化合物を以下化合物２０３と称する。例　ＣＸＸＶＩ２−４−２４−ジクロルフェニル　ブトキシ−４６−ジクロル−１゜実施例ＸＬＶＩＩＩで作成した２、４−ジクロルフェネチルアルコール３０．１９　（０，１６モル）と４８％）−ＩＢｒ水溶液１４０ｄとの混合物を５時間還流加熱した。冷却後、この混合物をエーテルと水の間に分配し、エーテル層を飽和ＮａＨＣＯ３水溶液で抽出し、Ｍ　Ｑ　Ｓ　Ｏ４で乾燥し、減圧濃縮すると、褐色の液体が得られた。これをにｕｇｅｌｒｏｈｒ蒸留すすると、２９．７ｇ（０，１２モル）の２−（２，４−ジクロルフェニル）エチルブロマイドが０．０２５ａＩＩＩＪｌにて７０℃の沸点を有する無色の液体として得られた。この中間物のＮＭＲ分析は次の通りであった： ’ＨＮＭＲ（ＣＤＣｊ３）：δ３．　Ｏ−３，８（１，４１１）。７．０−７．４（ｍ、３１１）ｐｐｍシウム屑に、　３０ｄのテトラヒドロフラン中にＡで作成した２−（２，４−ジクロルフェニル）エチルブロマイドを含む溶液を消和したゎマグネシウムが消費されたとき、グリニヤール試薬の黄色溶液を、３０ｍのテトラヒドロフラン中に　１．９ｇ（’０．０１モル）混合物を５分間撹拌後、３５ｄのテトラヒドロフランを添加した。更にこの混合物を５分間撹拌し、３５ｄ　（０，０７モル）の２Ｍエチレンオキシド溶液を消和した。反応混合物を０℃で２時間、空温で１時間撹拌し、Ｓｏｄの水で０冷した。真空下で減量させ、し、減圧濃縮して得られた液体をシリカゲルクロマトグラフィーで処理すると、２．３７ｇ（０，０１モル）の４−（２，４−ジクロルフェニル）ブタン−１−オールが淡黄色液体として得られた。この中間物のＮＭＲ分析は次の通りであった：’）Ｉ　ＮＭＲ（ＣＤＣｊ３）：δ　１．４３−［８３（ｍ、　４Ｈ）。２．５３−２．９０（ｍ、３１１）。３、５０−３．７７（ｎ＋、２Ｈ）；７．０７（＋ｅ、　２Ｈ）。７．３３（１，）Ｉ）ＩＩｐＩＩＩ実施例ｘｘｘｕと同様にして塩化シアヌルを酸受容体としての２，６−ルチジンの存在下でＢで作成した＋Ｌ−（２，４−ジクロルフェニル）ブタン−１−オールど反応さぜると、２−　［４−（２，４−ジクロルフェニル）ブトキシｌ−４，６−ジク０ルー１．３．５−トリアジンが淡黄色油状物として得られた。生成物の元素分析は次の通りであ訓算値：　Ｃ，４２，５３：　Ｈ，３，０２；　Ｎ、　１１．４５この化合物を以下化合物２０４と称する。実　施　例　ＣＸＸ■ ２４ｉ７且亙Ｊ三りと之ｌニルー３，５−ジメチルフエソキシ）−１゜虹とＥ隻ヱ之之立１３ｅ実施例工と同様にして塩化シアヌルを酸受容体としての２．６−ルチジンの存在下で２．４−ジクロル−３，５−ジメチルフエノールと反応させると、１１８〜１２０℃の融点を有する２、４−ジクロル−６−（２，４−ジクロル−３，５− ジメチルフェノキシ）−１，３，５−トリアジンが得られた。生成物の元素分析は次の通りであった：分　析　二　０１１Ｈ７Ｃ１４Ｎ３０計算値：　Ｃ，３８，９７：　Ｈ，２，０８；　Ｎ、　１２．３９実測値；　Ｃ，３９，１８：　Ｈ，２，２５：　Ｎ、　１２．４７この化合物を以下化合物２０５と称する。、施　例　ＣＸＸ■ 実施例ＣＸＸＶＩと同様にして、池の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２０６〜２１０の構造及び分析データを下記表Ｑに示す。ＪＬ−−ユしＩ実　施　例　ｃｘｘｒｘ実施例ｘｘｘｖｒと同様にして、塩化シアヌルを酸受容体としての重炭酸ナトリウムの存在下でアセトンオキシムと反応させると、６０〜６２℃の融点を有するア、七トン　０−（４，６−ジクロル−、−−′＝−−”　−１，３，５−トリアジン−２−イル）オキシムが得られた。生成物の元素分析は次の通りであった：分　析　二　０６　Ｈ６Ｃ１２Ｎ４０計算Ｍｌ　：　Ｃ，３２，６０；　Ｈ，２，７４；　Ｎ、　２５．３５実測値：　Ｃ，３２，２４；　Ｈ，２，９０；　Ｎ、　２５．２８この化合物を以下化合物２１１ど称する。実　施　例　ｃｘｘｘ実施例ＬＸＸＩ［Ｉと同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２１２及び２１３の構造及び分析データを下記表Ｒに示す。表′Ｒ代表的窒素含有複素環化合物ＣＩＣＩ実　施　例　ＣＸＸＶＩ　− ２−クロル−４−エチニル−６−メドキシー１３５−トＩアシｙＪＩ上実施例ＬＸＸＩ［で作成した２、４−ジクロル−６−ドリメチルシリ（０，００４モル）のフッ化カリウムを０℃で添加した。反応混合物を３０分間撹拌後、飽和塩化アンモニウム水溶液を添加し、メタノールを真空下で蒸発させた。残留物をエーテルで抽出し、エーテル溶液をＭＱＳＯ４で乾燥し、濾過し、蒸発させると、１０８〜１１０℃の融点を有する２−クロル−４−エチニル−６−メドキシー１．３．５−ｔ−リアジンン０．３３ｇ（０，００２モル）が得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ６Ｈ４ＣＩ　Ｎ’３０計算（ｉｆｆ　：　Ｃ，４２，５０：　Ｈ，２，３８：　Ｎ、　２４．７８実測値：　Ｃ，４１，５８：　Ｈ，２，２９：　Ｎ、　２３．９１この化合物を以下化合物２１４と称する。実　施　例　ＣＸＸＸ■ 実施例ＬＸＩと同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２１５〜２１７の構造及び分析データを下記表Ｓに示す。表　Ｓ代表的窒素含有複素環化合物ＮＩ実　施　例　ｃｘｘｘｍ ζ、Ａ二２−久Ｕ↓二ｐ二Ｚ２二丹９フ１ノ１仁吏ンフー秀」江二、Ｌ５−≦過ニー１±９１−２、ンｎｒ−図実施例ＬＸＸｒＶと同様にして、塩化シアヌルを酸受容体としての水酸化ナトリウムの存在下でベンゼンスルホンアミドと反応させると、１８５〜１８６℃の融点を有する２、４−ジクロル−６−フェニルスルホンアミド−１，÷ルー１．３．５−１−リアジンが得られた。生成物の元素分析は次の通りであった二分　析二　ＣＨ０１２Ｎ４０□　Ｓ計算（！Ｉ　：　Ｃ，３５，４２；　Ｈ，１，９８：　Ｎ、　１８．３６実測値：　Ｃ，３５，０４：　Ｈ，２，３２：　Ｎ、　１８．０９この化合物を以下化合物２１８と称する。実　施　例　ｃｘｘｘｒｖ２−クロル−４−（２，４−ジクロルフェノキシ）−６−ヘキサフルオロイツブロボキシー１．３．５−）−リアジンの製造１００ｍのアセトン中に５．０ｇ（０，０２モル）の実施例■で作成した２、４−ジクロル−６−（２，４−ジクロルフェノキシ）−１，３，５−トリアン中に１．９ｄ　（０，０２モル）のヘキサフルオロイソプロピルアル］−ルを含む溶液を添加し・た。（７られた混合物を１０時間遠流加熱し、真空Ｆ（７蒸光乾固した。残留物をシリカゲル上でのフラッシュクロマトグラフィー・にかけ、まず５％酢１１　、’Ｉエチルヘキサン溶液で溶出させ、次いで１５％ジクロ［］メタンのヘキサン溶液で溶出させると１ｊ、３４！？　（０，００３５モル）の２−クロル−４−（２，４−ジクロルフェノキシ）−６−ヘキサフルオロイツブロボキシー、１，３．５−トリアジンが油状物として得られた。生成物の元素分析は次の通りであった：分　析　：　ＣＨＣ１３Ｆ６　Ｎ３０２Ｂ１算値：　Ｃ，３７，３８：　Ｈ，１，０５：　Ｎ、　１０．９０実測値；　Ｃ，３２，５２：　Ｈ，０，８９：　Ｎ、　９．４８この化合物を以下化合物２１９と称する。実　施　例　ｃｘｘｘｖ２−クロル−４−（１：ｉフトキを）−６−（２，２，２−トリフルオロエトキ ’　−１３５−ｔ−リアジンの・Ｊ１実施例ｃｘｘｘｒｖと同様にして、実施例■で作成した２、４−ジクロル−６− （１−ナフトキシ）−１，３，５−トリアジンを酸受容体としての２．６−ルチジンの存在下で２．２．２−トリフルオロエタノールと反応させると、２−クロル−４−（１−ナフトキシ）−６−（２，２，２−トリフルオロエトキシ”）　 −１，３，５−トリアジンが油状物として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１，Ｈ１９Ｃｊ　ＦＮ３０２計算値：　Ｃ，５０，６５：　ｌ−（、２，５５：　Ｎ、　１１．８１実ａ１！！　（ａ　：　Ｃ，５１，０４：　Ｈ，２，７５；　Ｎ、　１１．５３この化合物を以下化合物２２０と称する。施　例　ｃｘｘｘｖｒ２−クロル−４−（２４−ジクロルフェノキシ）−６−エトキシー１．３．５− ト匹乙２之二ｌ】中に３．１７９　（０，０２モル）のブロモアセトアルデヒドジエチルアセタールを含む溶液を添加した。得られた混合物を室温で１時＠撹拌し、ｓ、ｏｇ（０，０２モル）の２．４−ジクロル−６−（２，４−ジクロルフェノキシ）−１，３，５−トリアジンを含む溶液を消和した。得られた混合物を約１６時間室温で撹拌し、真空下で蒸発乾固した。残留物をシリカゲル上でのフラッシュクロマトグラフィーにかけ、５％酢酸エチルのヘキサン溶液で溶出させると１，９ｇ（０，０１モル）の２−クロル−４− （２，４−ジクロルフェノキシ）−６−エトキシー１．３．５−トリアジンが油状物として得られた。生成物の元素分析は次の通りであった：分　析　二　ＣＨＣ１！３　Ｎ３０２計算値：　Ｃ，４１，２２：　Ｈ，２，５１：　Ｎ、　１３．１１実測値：　Ｃ，４１，２４：　ｌ−１，２，５０：　Ｎ、　１２．７５この化合物を以下化合物２２１と称する。１００ｄのアセトン中に５．０ｇ（０，０３モル）の塩化シアヌルを含む溶液に、４℃でまず３．１６ｄ　（０，０３モル）の２．６−ルチジンを含む溶液を添加後１５０ｄのアセトン中に２．６０ｄ　（０，０３モル）の２．２．２−トリクロルエタノールを含む溶液を添加した。混合物を室温で約１６時間撹拌し、溶媒を除去した。残留物を水とエタノールの間に分配させ、有機相を無水硫酸ナトリウムで乾燥し、溶媒を除去後残留物をシリカゲル上でのフラッシュクロマトグラフィーで精製した。酢酸エチル−ヘキサンで溶出させると、１．１９　（０，００４モル）の２．４−ジクロル−６−（２，２，２−トリクロルエトキシ）− １，３，５−トリアジンが７２〜７３℃の融点を有する黄色結晶として得られた。生成物の元素分析は次の通りであった：分　析：　ＣＨ０１５Ｎ３　。計算値：　Ｃ，２０，２０：　Ｈ，ｏ、ｅａ：　Ｎ、　１４．１３実測値；　Ｃ，２０，１９；　Ｈ，０，６８：　Ｎ、　１４．４８この化合物を以下化合物２２２と称する。 ”’ｍ　ｌ　ＩＩ　ＣＸＸＸＷ２４ｉり」」二鼾Ｂ二二又−メチルピロリルｌ、　５−トリアジＺ暗ｌ上２．４ｍ　（０，０３モル）のトメチルビロール、ｓ、ｏｇ（０，０３モル）の塩化シアヌル及び５０ｄのｐ−ジオキサンの混合物を５時間還流加熱した。反応混合物を水に注入し、形成した沈澱物を吸引ｅ過により集め、乾燥した。ヘキサンから結晶化すると、２．０７（０，０１モル）の２．４−ジクロル−６−［２ −（Ｎ−メチルピロリル）１−１．３．５−１−リアジンが１５３〜１５４℃の融点を有する淡黄色結晶として得られた。生成物の元素分析は次の通りであった：分　析　：ＣＨＣｊ！　２　Ｎ４ｇｌ　算値：　Ｃ，４１，９５；　Ｈ，２，６４：　Ｎ、　２４．４６実測値：　Ｃ，４２，００：　Ｈ，２，７３；　Ｎ、　２４．４にの化合物を以下化合物２２３と称する。実　施　例　ｃｘｘｘｒｘＮ−（４，６−ジクロル−１，３，５−ｔ−リアジン−２−イル）−２−オキソヘキサメチレンイミンの製造油中に１０．０９　（０，０９モル）の水素化カリウムを懸濁させた懸濁液に、 −６０℃でまず２００ａ！！の乾燥テトラヒドロフランを添加後１０．０ｇ＜０．０９モル）のε−カプロ分多ムを添加した。混合物を空温まで加温し、１詩間撹拌した後１００ａｄのテトラヒドロフラン中に１６．３ｇ（０，０９モル）の塩化シアヌルを含む溶液を添加し、更に２時間撹拌した。反応混合物を真空蒸発させ、残留物をフラッシュクロマトグラフィーで精製すると、１．２ｇ（０，００５モル）のＮ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）− ２−オキソヘキサメチレンイミンが油状物として得られた。生成物の元素分析は次の通りであった：訓算値：　Ｃ，４１，４０；　Ｈ，３，８６：　Ｎ、　２１．４６実測値：　ｃ、　ａｏ、ｓｓ　；　Ｈ，ａ’、４ｏ：　Ｎ、　２１．０１この化合物を以下化合物２２４と称する。例　ＣＸＬ実施例ｃｘｘｘｒｘと同様にして２−ピロリジノンを水素化カリウムと反応させ、得られたカリウム塩を塩化シアヌルと反応させると、１９２〜１９４℃の融点を有するＮ−（４，６−ジクロル−１，３゜５−トリアジン−２−イル）−２− オキソテトラメチレンイミンが得られた。生成物の元素分析は次の通りであった：分　析　二　Ｃ７Ｈ６Ｃ１２Ｎ４０計算値：　Ｃ，３６，０７；　Ｈ，２，６０；　Ｎ、　２４．０４実測値；　Ｃ，３５，８６；　Ｈ，２，５４：　Ｎ、　２４．０１この化合物を以下化合物２２５と称する。実　施　例　ＣＸＬＩ又ユム上乏盈」」二」ヨＬヒＬ以ヱ乏２ニュ２ツリョ上りと旦旦ｊチル−６−アザ−ビシクロ３．２．１　オクタン及び２，４−ビス（１，３゜３−トリメチル −６−アザ−ビシクロ（３，２，月オクタン−６−イル）−６−ロルー１３５− トリアジンの製造実施例ｃｘｘｘｒｘと同様にして１，３．３−トリメチル−６−アザビシクロ［３，２，１］オクタンを水素化カリウムと反応させ、得られたカリウム塩を塩化シアヌルと反応させると、１３３〜１３５℃の融点を有するＮ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）−１，３，３−トリメチル−６−アザ−ビシクロ［３，２，１］オク、タン及び１６１．５〜１６３℃の融点を有する２、４−ビス（１，３，３−トリメチル−６−アザ−ビシクロ（３，２，月オクタン−６−イル）−６−クロル−１，３，５−トリアジンが得られた。２種の生成物をフラッシュカラムクロマトグラフィーで分離した。２種の生成物の元素分析及びＮＭＲ分析は次の通りであった：Ｎ−（４，６−ジクロル−１，３，５−トリアジン−２−イル）−１，３，３− トリメデル−６−アザ−ビシクロ［３，２，月オクタン分　析　：　Ｃｌ２Ｈ１８Ｃ１２Ｎ３計算値：　Ｃ、５１，８３：　Ｈ，６，０２：　Ｎ、　１８．６０　：Ｃｆｆ１　、２３．５４実測Ｉ　：　Ｃ、５１，８２：　Ｈ，５，８１：　Ｎ、　１８．４７　；ＣＩ　、　２３．７８この化合物を以下化合物２２６と称する。１．１０（ｓ、６Ｈ）。１．３０−２．３０（ｍ、　１２Ｈ）。２．９０−３．７０（ｍ、４旧。４．３０−４．６８（ｍ、２Ｈ）１１ｐｍこの化合物を以下化合物２２７と称する。実　施　例　ＣＸＬＩＩ４．６−ジクロル−２−（３−フェニルフェノキシ）−１，３，５−トリアジンの艮１実施例Ｘと同様にして塩化シアヌルを酸受容体としてのトリイソブＯパノールアミンの存在下で３−フェニルフェノールと反応させると、１８３〜１８５℃の融点を有する４、６−ジクロル−２−（３−フェニルフェノキシ）−１，３，５− ｔ−リアジンが得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１５Ｈ９Ｎ３０計算値：　Ｃ、５６，６３：　Ｈ，２，８５：　Ｎ、　１３．２１　；Ｃｊ　、　２２．２９実測値：　Ｃ、５６，３３；　Ｈ，３，２９：　Ｎ、　１３．１５　：ＣＩ！、　２１．５５この化合物を以下化合物２２８と称する。実　茄　例　ＣＸＬＩ［Ｉ２．３−シクロルート（２−クロルアニリノ）マレイミドの製造４．７ｇ（０，０３モル）の無水ジクロロマレイン酸及び２０ｄの酢酸の撹拌混合物を１００℃ で４５分間加熱した。混合物を室温まで冷却し、水を消和すると沈澱物が形成された。第１の生成物（ｆｉｒｓｔ　ｃｒｏｐ　ｏｒ　ｐｒｏｄｕｃｔ）をＰ別し、母液をゆっくり蒸発させた後濾過すると第２の生成物が得られた。２種の生成物を合すると、５．５５９　（０，０２モル）の２．３−シクロルート（２−クロルアニリノ）マレイミドが１３７〜１３８℃の融点を有する黄色結晶とじて得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ５Ｃｆｌ　３　Ｎ２０２実施例ＣＸＬＩ［と同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２３０〜２５０の構造及び分析データを下記表Ｔに示す。表　Ｔ代表的窒素含有複素環化合物表　■　（続き）表　Ｔ　（続き）代表的窒素含有複素環化合物置換基　元素分析実　旋　例　ＣＸＬＶ６−ヒドロキシ−２−フェニル−３（２旧ビリダジノンの製造１０ｍｆ！（０，１０モル）のフェニルヒドラジン、　１０ｇ（０，１０モル）の無水マレイン酸及び７５ｍの酢酸の撹拌混合物を６時間還流加熱した。混合物を室温まで冷却して形成した沈澱物を戸別すると、１０．６２　ｇ（０，０５モル）の６−ヒドロキシ−２−フェニル−３（２８）ピリダジノンが２６２℃（分解）の融点を有する黄色結晶として得られた。生成物のＮＭＲ分析は次の通りであった：’ｌ＋ＮＭＲ（ＣＤＣｌ２）：δ７．２１（ＡＢ、　、２８．Ｊ−１０Ｈ２）。７．５０−７．８７（１，５Ｈ）ｌ）ｌ）ＩＩこの化合物を以下化合物２５１と称する。３０ｍ　（０，３２モル）のオキシ塩化リン、　３０ｇ（０，１４モル）の五塩化リン及びｓ、ｏｇ（０，０２４モル）の実施例ＣＸＬＶで作成しｆ−υヒドロキシー２−フェニルー３（２Ｈ）ピリダジノンの撹拌混合物を１６０〜１７０℃ で９０分間加熱した。混合物を室温まで冷却し、氷水に注入すると、黄色沈澱物が得られた。粗生成物を戸別し、ルー２−フェニル−３（２＋１）ピリダジノンが１１０〜１１１℃の融点を有する黄色結晶が得られた。生成物の元素分析は次の通りであった：分　析　：　ＣＨＣ１２Ｎ２０計ｎ　１　：　Ｃ，４９，３３：　Ｈ，２，５６：　Ｎ、　１１．１８実測値；　Ｃ，４９，６９；　Ｈ，２，６１：　Ｎ、　１１．５７この化合物を以下化合物２５２と称する。施　例　ＣＸＬＶＩ６−　ロルー２−フェニル−３（２Ｈ）ビリ　ジノンの製造２．０９　（０，０１モル）の実施例ＣＸＬＶで作成した６−ヒドロキシ−２−フェニル−３（２旧ピリダジノン及び２０ｄ　（０，２１モル）のオキシ塩化リンの撹拌混合物を９５℃で２時間加熱した。反応混合物を室温まで冷却し、氷水で急冷した。１ヘキサンを添加し、混（０，００４モル）の６−クロル−２−フェニル−３（２Ｈ）ピリダジノンが１１２〜１１３℃の融点を有する黄白色結晶が得られた。生成物の元素分析は次の通りであった：分　析　：　ＣＨＣ１ｌ！　Ｎ２０計算１　：　Ｃ、５８，１３：　Ｈ，３，４２；　Ｎ、　１３．５６　：ＣＰ、　１７．１６実ｍ　ｉｆｆ；　Ｃ、５ｇ、１０　；Ｈ，３，１０：　Ｎ、　１３．４１　：（：、ｌ　、１６．４７この化合物を以下化合物２５３と称する。１８．８ｇ（０，０９モル）の２．４−ジクロルフェニルヒドラジン塩酸塩及び６００ｄの６Ｎ塩酸の混合物に、１４．７ｇ（０，０９モル）の無水ジクロロマレイン酸を添加した。混合物を６時間還流加熱し、得られた固体を戸別し、氷水及びヘキサンで洗浄すると２９５〜２９８℃（分解）の融点を有する４、５−ジクロル−６−ヒドロキシ−２−（２，４−ジクロルフェニル）　−３（２Ｈ）ピリダジノン７．６９　（０，０２３モル）が得られた。生成物の元素分析は次の通りであった：分　析：　Ｃ１ｏＨ４Ｃｇ　４　Ｎ２０２計　Ｒ（ａ　二　Ｃ，３６，８５：Ｈ，１，２４：Ｎ、　８．５９実測値：　Ｃ，３６，６９：　Ｈ，１，３７：　Ｎ、　８．４４この化合物を以下化合物２５４と称する。実施例ＣＸＬ■と同様にして、０−クロルフェニルヒドラジン隼酸塩を無水ジクロロマレイン酸と反応させると、２４２〜２４４℃の融点を有する４、５−ジクロル−６−ヒドロキシ−２−（２−クロルフ次の通りであった：分　析　：　０１゜Ｎ５　Ｃｐ　３　Ｎ２０２計算ｆｊｉ：　Ｃ，４１，２０：　Ｈ，１，７３：　Ｎ、　９．６１実測値；　Ｃ，４１，１９；　Ｈ，１，９７：　Ｎ、　９．６０この化合物を以下化合物２５５と称する。実　施　例　ＣＬ４５−ジクロル−６−ビロキシー２−（３４−ジクロルフェニル）−３（２Ｈ）ピリダジノンの製造７．５ｇ（０，０３モル）の３，４−ジフェニルヒドラジン塩酸塩。５．０９　（０，３モル）の無水ジクロロマレイン酸及び１００ａｆ！の氷酢酸の撹拌混合物を２日間還流加熱した。混合物を空温まで冷却して形成した黄橙色の結晶を分離した。結晶を吸引Ｐ道すると、２４１〜２４２．５℃の融点を有する４、５−ジクロル−６−ヒドロキシ−２−（３，４−ジクロルフェニル）　− ３（２ｔりビリダジノン２．８７ｇ（０，０１モル）が得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ４Ｃｐ　４　Ｎ２０２計算値：　Ｃ，３６，８５：　）− １，１，２４：　Ｎ、８．５９実測ｆＵ　：　Ｃ，３６，４７：　Ｈ，２，０７；　Ｎ、　７．４９この化合物を以下化合物２５６と称する。実　施　例　ＣＬＩ２．３−ジクロル−Ｎ−（２−メチルアニリノ）マレイミド　び４，５−シロルー６−ヒドロキシ−２−（２−メチルフェニル　−３（２Ｈビリ　ジノ水ジクロロマレイン酸と反応させると、１４６〜１４９℃の融点を有する２、３−ジクロル−Ｎ−（２−メチルアニリノ）マレイミド及び２３４〜２３５．５℃の融点を有する４、５−ジクロル−１６−ヒドロキシ−２−（２−メチルフェニル）−３（２Ｈ）ピリダジノンが得られた。２種の生成物をメチレンクロリドから再結晶して分離した。２種の生成物の元素分析は次の通りであった：２３−ジクロルーＮ−（２−メチルアニリノ）マレイミ。分　析　：　Ｃ１１Ｈ８Ｃｐｌ　２　Ｎ２０２計算値：　Ｃ，４８，７３；　）ｌ　、　２．９７：　Ｎ　、　１０．３３実測ｍ　：　Ｃ，４８，６４：　）Ｉ、　３．１２：　Ｎ、　１０．２３この化合物を以下化合物２５７と称する。４５−シ’）　Ｏルー６−ヒーｏ−ｔシー２−（２−メチレンｘ　二）’ｖ）　 −３（２Ｈ）ビ’ＪＪ−芝ノ１分　析　：　ＣＨＣ１２Ｎ２　ｏ２計算値：　Ｃ，４８，７３；　Ｈ，２，９７：　Ｎ、　１０．３３実測＠　：　Ｃ，４８，２９：　Ｈ，３，０６：　Ｎ、　１０．１にの化合物を以下化合物２５８と称する。施　例　ＣＬＩＩ４５６−ドリクロルー２−２４−ジクロルフェニル）　−３（２Ｈ）ビリダシ／）免ｌ１３．７ｊＪ　（０，０２モル）の五塩化リン、　３７ｊＩｉ！（０，４モル）のオキシ塩化リン及び７．６９　（０，０２３モル）の実施例ＣＸＬ■で作成した４、５−ジクロル−６−ヒドロキシ−２−（２，４−ジクロルフェニル）−３（２旧ピリダジノンの撹拌混合物を１６０〜１７０℃で１４時間加熱した。混合物を空温まで冷却し、沈澱を促進すべく撹拌しながら少量のヘキサンを添加した氷水に注入した。粗生成物を濾過し、氷水で洗浄し、シリカゲル上でのフラッシュクロマトグラフィーで”精製した。５％酢駁エチルのヘキサン溶液で溶出すると、１５４〜１５５．５℃の融点を有する４、５．６−ドリクロルー２−（２，４ −ジクロルフェニル”）−３（２Ｈ）ピリダジノン０．８５ｇ＜０．００２５モル）が得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃ１ｏＨ３Ｃ１５Ｎ２０計算値：　Ｃ，３４，８８：　Ｈ，０，８８：　Ｎ、８．１３実施例ＣＬＩＩと同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２６０〜２６４の構造及び分析データを下記表口に示す。表　口代表的窒素含有複素環化合物実　施　例　ＣＬＩＶ２．３−ジメヂルーＮ−（２−クロロアニリノ）マレイミ゛の製造７．１ｇ（０，０４モル）の０−クロロフェニルヒドラジン塩酸塩。５．０９（０，ｏａモル）の無水２，３−ジメチルマレイン酸及び２５ｄの酢酸の撹拌混合物を１００℃で１１間加熱した。反応混合物を室温まで冷却し、水を消却すると沈澱が形成した。沈澱を戸別し、Ｐ液を冷却して生じた租生成物を固体として分離した。固体を塩化メチレン−ヘキサンから結晶化すると、２．３９　（０，０１モル）の２．３−ジメチルート（２−クロロアニリノ）マレイミドが１１５〜１１７．５℃の融点を有する橙色の精品として得られた。生成物の元素分析は次の通りであった：分　析　：　Ｃｌ２Ｈ１１Ｃｐ　Ｎ２０２計算値：Ｃ，５７，４９；　）ｌ、　４．４２：　Ｎ、　１１．１７実測値：　Ｃ，５７，４９：　Ｈ，４，３２；　Ｎ、　１１．１５この化合物を以下化合物２６５と称する。実　施　例　ＣＬＶ実施例ＬＸＸＸＩＩＩと同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合ＩＩＩＪ２６６〜２６７の構造及び分析データを下記表■に示す。 −表二−−Ｎ二表的窒素含有複素環化合物実　施　例　ＣＬＶ’１１３３〜１３５℃の融点を有するＮ−ヒドロキシマレイミドをＡｌｄｒｉｃｈ　Ｃｈｅｍｉｃａｌ　Ｃｏｍｐａｎｙがら入手し、精製することなくその逆相ＨＰＬＣによるオクタツール／水ｌｏｇ　Ｐ　：　０．００この化合物を以下化合物２６８と称する。〜１７２℃の融点を有する４、５−ジクロル−６−ヒドロキシ−２−（３−トリフルオロメチルフェニル）　−３（２８）ピリダジノンが得られた。生成物の元素分析は次の通りであった：分　析二　０１１Ｈ５ＣＩ！　２　Ｆ３　Ｎ２０２計算値：　Ｃ，４０，６４：　Ｈ，１，５５：　Ｎ、８．６２実測値：　Ｃ，４０，５５：　Ｈ，１，５０：　Ｎ、８．６１この化合物を以下化合物２６９と称する。実　施　例　ＣＬ■ 実施例ＣＸＬＩ［［と同様にして、他の化合物を製造した。植物−表一一一竺一代表的窒素含有複素環化合物実　施　例　ＣＬｒＸと差Ｊ」竺二４．５．６−）己し乞店ｌ二廷堕上ζ止ｌ乏二冗仁へ艮ＬＡ：２− メチルー４．５−ジクロル−６−ヒドロキシ−３（２■ビ１　ジノン！」１元実施例ＣＸＬ■と同様にしてメチルヒドラジンをＨＣ！！水溶液中で無水ジクロロマレイン醒と反応させると、２２９〜２３０℃の融点を有する２−メチル−４，５−ジクロル−６−ヒドロキシ−３（２１１）ビリダジノンが得られた。Ｂ：２−メチル−４，５，６−ドリクロルー３（２旧ピリダジノンの製造３、ｏｇ（０，０２モル）のＡで作成した２−メチル−４，５−ジクロル−６−ヒドロキシ−３（２Ｈ）ビリダジノンと２０ｍのオキシ塩化リンの混合物を溶液が得られるまで加温し、過剰のオキシ塩化リンを減圧下で蒸発させた。残留物を氷水に浸漬し、この混合物を１時間撹拌するとパフ色の固体のスラリーが得られた。この固体を単離し、Ｐ２Ｏ５上で乾燥すると、９６〜９８℃の融点を有する２−メチル−４，５，６−ドリクロルー３（２Ｈ）ビリダジノン０．６ｇ（０，００３モル）が得られた。この化合物を以下化合物２７６と称する。実　旅　例　ＣＬＶ１６０ｍの無水エタノール中に３３．６ｇ（０，２モル）のムコクロＶ酸を含む還流溶液に、２０〆のエタノール中に６．７９　＜　０．２モル）の９５％とドラジンを含む溶液をゆっくり添加した。添加後、還流を２詩間継続し、混合物を冷却して生じた固体をＰ別し、風乾すると、１９３〜１９４℃の融点を有する４、５−ジクロル−３（２＋１）ビリダジノン２４．４ｇ（０，１５モル）が得られた。Ｂ：２−ベンジル−４，５−ジクロル−３（２Ｎ）ｔ：’ユｌ乏１２ユ玉１６．６ｇ（０，０４モル）のＡで作成した４、５−ジクロル−３（２Ｈ）ビリダジノン、９．１７　（０，０８モル）の塩化ベンジル、　２０９　（０，１４モル）の炭酸カリウム及び１２０ｄのＮ、Ｎ−ジメチルホルムアミドの混合物を４０〜９０℃で加熱すると、ゲル状混合物が形成された。混合物を酸性化し、エーテル／アセトンで抽出し、濾過すると褐色の固体が得られた。Ｐ液をエーテルと水に分配し、エーテル相を１０％炭酸ナトリウム溶液及び水で洗浄し、０．５ｇ（０，００２モル）の２−ベンジル−４，５−ジクロル −３（２Ｈ）ビリダジノンが８１〜８２℃の融点を有する白色結晶として得られた。この化合物を以下化合物２７１と称する。実　施　例　ＣＬＸ　工２−〇−ロロベ゛２゛ルー４５−ジクロル−３（２Ｈ）ピリ　ジノンの製造３．４９　（０，０２モル）のムコクロル酸、ｓ、ｔｇ（０，０２モル）のＯ− り「１ルベンジルヒドラジン硫酸塩及び５Ｑｄの無水エタノールの混Ｃ物を６時間速流加熱した。混合物を冷却して形成された沈澱物を集め、風乾すると、３．８ｇ＜０．０１モル）の２−（Ｏ−クロロベンジル）−４，５−ジクロル−３（２旧ビリダジノンが１１４℃の融点を有する白色結晶として得られた。この化合物を以下化合物２７８と称する。実　施　ｆ！ｉ＋ＪＣＬＸｎ２−クロルート（２−メチルフェニル）−マレイミドの製造ド酸の製造１３２ｇ（１，０モル）の無水クロロマレイン酸とキシレンの温合物を撹拌且つ７０℃で加熱しながら、滴下ロートを用い又　１０７９　（１，０モル）の２− メチルアニリンとゆっくり添加した。２−メチルアニリンの添加終了後、反応混合物を７０℃で１時間撹拌した。混合物を冷却し、固体を戸別し、キシレン、ヘキサンで洗浄し、空温で乾燥すると、１１０℃の融点を有する２−（若しくは８ｇ（０，１０モル）の酢酸ナトリウムと９５．０ｇ（０，，４０モル）のＡで作成した２−（若しくは３−）クロル−Ｎ−（２−メチルフェニル）マレアミド酸の撹拌混合物に、１２２．０７　（１，２モル）の無水酢酸を空温で添加し、得られた混合物を８０’Ｃで４０分間撹拌、加熱した。次いで反応混合物を２５℃ に冷却し、２ｔの氷水に注入した。混合物を６００ｄのエチルエーテルで抽出し、エーテル抽出物を長さ１フイートの未充填カラムにより蒸留すると、２ｍ１１ｇにて１３２℃の沸点を有する２−クロル−Ｎ−（２−メチルフェニル）−マレイミド７５．０ｇ（０，３４モル）が得られた。この化合物を以下化合物２７９と称する。実　施　例　ＣＬＸＩ［［実施例ＣＸＬＩＩと同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２８０〜２８３の構造及び分析データを下記表Ｘに示す。表　Ｘ代表的窒素含有複素環化合物２８０　３−　ＣＨ３沸点１３９℃〜１４０℃／　３　ｒａｎ　Ｈ９２８１４− ＣＨ，融点１４８℃ ２８２　２、４−（ＣＨ３）！　沸点ｉ４ｓ℃〜１５０℃／２ｍｍＨ７２８３２ −Ｃ，Ｈｓ　沸点１３６℃７２ＷＨｆ実　施　例　ＣＬＸｒＶトエヂルマレイミドを＾Ｉｄｒｉｃｈ　ＣｈｅＯｌｉｃａｌ　Ｃｏｍｐａｎｙがら入手し、精製することなくそのまま用いた。生成物のｌｏｇ　ｐ値は次の通りであった。逆相ＨＰＬＣによるオクタツール／水ｌｏｇ　ｐ　：　１．１０この化合物を以下化合物２８４と称する。ｖｉｌｔｅｔ、　Ｔｉｎｔａｇｅｌ、　Ｃｏｒｎｗａｌｌ　（英国）から入手し、その活性を調べた。植物からの水分損失を減少させるために後記実施例で使用する化合物２８５〜２８８の構造及び分析データを下記表Ｙに示す。 −１−ｍ−Ｎ− 代表的窒素含有複素環化合物化合物　置換基　逆相ＨＰＬＣによるオクタ実　施　例　ＣＬＸＶＩ２−（３−トリフルオロメチル）−４，５−ジクロル−３（２１（）ピリダジノンの製造２−（３−トリフルオロメチル）−４，５−ジクロル−３（２旧ビリダジノンを＾Ｉｄｒｉｃｈ　Ｃｈｅｍｉｃａ！　Ｃｏ１１ｌｐａｎｙから入手し、精製することなくそのまま用いた。生成物のｔｏｏ　Ｐ値は次の通りであった。逆相ＨＰＬＣによるオクタツール／水ｌｏｇ　Ｐ　：　２．９０この化合物を以下化合物２８９と称する。５０ｇ（０，５モル）の無水コハク酸と３００ｄのトルエンの混合物を１１５〜１２０℃で撹拌、加熱し、この混合物に６９ｇ（０，５モル）の２−エトキシアニリンを滴下ロートにより添加した。次いで反応混合物を沸巴するまで加熱し、トルエンを１８０〜１９０℃のケトル温度で留去さぜた。理論保の水が留出されるまで、混合物を１８０〜１９０℃で加熱した。反応混合物を冷却し、１１の９９％イソプロピルアルコールで希釈し、約１６時間放置した。分離した固体をＰ別し、イソプロピルアルコールで洗浄し、乾燥すると、１０８℃の融点を有するト（２−エトキシフェニル）スクシンイミド７２．０９　（０，３３モル）が得られた。生成物の元素分析は次の通りであった：分　析：　Ｃｌ２Ｈ１３ＮＯ３実測値；Ｎ、　６．７３この化合物を以下化合物２９０と称する。実　施　例　ＣＬＸ■ ３５−ジ　ロルー６−（３，５−ジクロル−４−メトキシフェニル）−４−整一上。ロキシビリ　ジンの製３．５−ジクロル−６−（３，５−ジクロル−４−メトキシフェニル）−４−ヒドロキシピリダジンをＣｈｅａ＋ｉｅ　Ｌｉｎｚ　Ｃｏｍｐａｎｙから入手し、精製することなくそのまま用いた。生成物のＮＭＲ分析は次の通りであった： ’ＩＩＮＭＲ（ＣＤＣｊ　／ＤＭＳＯ−ｄ６）：１６４．５０．１５２．７７、１４７．９２．１４１．９９．１３１．０５゜１３０．５８．１２８．８８．１２８．３４及び６０．５１　ｐｐｍこの化合物を以下化合物２９１と称する。実　施　例　ＣＬＸＩＸ実施例ＣＸＬＩＩ［と同様にして、他の化合物を製造した。植物からの水分損失を減少させるために後記実施例で使用する化合物２９２〜２９６の構造及び分析データを下記表２に示す。表　２代表的窒　含有複素環　合物実施例ＣＬＸＸ代表的な窒素含有複素環化合物の葉放散抵抗および発散率に対する効果葉放散抵抗（ｌｅａｆ　ｄｉｆｆｕｓｉｏｎ　ｒｅｓｉｓｔａｎｃｅ　）とは葉からの水蒸気放散に対する抵抗値であり、発散率（ｔｒａｎｓｔｌｉｒａｔｉＯｎ　ｒａｔｅ）を示づ゛。発散率は、細胞壁からの水の蒸発及び気孔を介する葉からの水の放散を一定時間について測定した値である。葉放散抵抗と発散率との関係を簡単に説明すると、葉放散抵抗が高げれば高いほど発散率が低く、葉放散抵抗が低いほど発散率は高くなる。）２表ＡＡに示した葉放散抵抗と発散率は次のような一般的方法で測定した値である。各試験化合物３０．３Ｍ９を５．５−のアセ１−ンに溶解させた後、最終容量がｉｉ、ｏｍｉとなるように水を加えて試験化合物溶液を作成した。水を添加する際に溶液に曇りが生じＩＣ場合には水の使用を中止し、アセトンを最終容量が１１．０ｍ７！になるまで添加した。こうして得た試料溶液は２ｓ３０ｐｐｍ（重量）の化合物を合有し工いた。下記表ＡＡで使用した最終溶液における試験化合物のｐ匠母度は、試Ｈ懸濁液を水で適宜に８釈して得たものである。鉢植え用混合土（容量で砂質ローム土１／３とピートモス１／３とパーライト１／３とを混合した土）を入れた直径１３．５ＣＩｌｌのプラスチック鉢に、インゲンマメ（Ｐｈａｓｅｏｌｕｓ　−５已１立Ｕ」工ｖ、ａｒ、　ｃｒａｎｂｅｒｒｙ　）の種を３個まいた。種まきから５〜７日優に儒引きを行なって１鉢１株にした。種まきから１０〜１２日後、初生葉が十分に伸びた時点で各濃度の試験化合物（鉢１つにつぎ溶液５＋Ｉｉりを、空気圧ＩＱｐｓｉｇに設定した吸引式噴Ｂ装置を用いてインゲンマメ３本の葉に噴霧した。対照として試験化合物を含まない水−アセトン溶液もインゲンマメ３本に噴霧した。た。処置後２４時間及び４８時間後に菓放散抵抗及び発散率を夫々単位秒、／α 、　ＩＪＳＨ２０／　ｅｘで測定した。測定には、ネブラス力州ロンカーンのＬｉ−Ｃａｒ、　Ｉｎｃ、／Ｌｉ−Ｃｏｒ、　Ｌｔｄから市販されティる［１−Ｃｏｒ１６００型定常状態ボロメータを使用した。各濃度の試験化合物および対照について数値の平均をとって表静に示した。及Ｍ表ＡＡ（続き）代表的な窒素含有複素環化合物の葉放散抵抗および発散率に対する効果表＾＾（続ぎ）葉放散抵抗および発散率に対する効果衣ＡＡ（続き）葉放散抵抗および発散率に対する効果衣ＡＡ（続き）表ＡＡ　（続き）葉放散抵抗および発散率に対する効果衣ＡＡ（続き）菓放散抵抗および発散率に対する効果表ＡＡ（続き）代表的な窒素含有複素環化合物の葉放散抵抗および発散率に対する効果（ａ）　１１５ｐｐｍで処理（ｂ）　２３０ｐｐｍで処理（ｃ）　４６０１）ｌ）１１で処理（ｄ）　９２０ｐｌ）Ｉｎで処理（ｅ）　３２２０ｐｐｐで処理表＾＾の結果から明らかなように、本発明の方法で使用する代表的な窒素含有複素環化合物は非処理の対照に比較して、莱放散抵抗を顕著に高め且つ発散率を顕著に低減させる。水使用効率（ＷＬＩＥ）は、発散防止化合物の有効性（即ち植物による水使用量のコントロール）と該化合物が植物の生育に与える効果（即ち植物の光合成に与える効果）の両方を測定するものである。特に、ＷＬＩＥは一定の時間の水の使用量に対する植物の乾燥分生酸量（ｐｌａｎｔ　ｄｒｙ　ｍａｔｔｅｒ　ｐｒｏｄｕｃｅｄ　）として定義され得る。下記表ＢＢ〜ＦＦに示すＷＵＥは、以下の一般的方法で測定した値である。表８８〜ＦＦに挙げた化合物の溶液は、各試験化合物６２．５Ｊｌ！Ｆを５ｄのアセトンに溶解して作成したものである。この溶液を夫々２ｄ、１ｍ、０．５ｄずつ別々の管に入れ、６管の容色が全部で１２ｍになるまでアセトンを添加した後、さらに水を添加して６管の最終容量を２０Ｍ１とした。上記試料溶液中の試験化合物ｉ！Ｉｒ！１（重量＞ｓｔ夫々１２５０ｐｐｍ　、　６２５ｐｐｍ、　３１２ｐｐｍｒ　（ｉ　フタ。下記＋７）　ＫＡ験で使用した溶液で上記以外の濃度の試験化合物を含有するものは、試料溶液を水で適宜に希釈して得たものである。鉢植え用の±（即ち体積で砂質ローム±１／３どピートモス１／３とパーライト１／３とを混合した土）を入れた直径１０．２ｅｘ（Ｄプラスチック鉢に、夫々ナガハグサ（にｅｎｔｕｃｋｙ　ｂｌｕｅｇｒａｓｓ）又はウシノケグサ（ｔａｉｌ　ｆｅｓｃｕｅ　ｔｕｒｆｇｒａｓｓ　）の種を１２■まいた。種まきを行なう前にプラスチック鉢と士とのｆｆ１ｆｆｉを測定した。種まき後８〜１２遍間ナガハグサ及びウシノケグサを生育させた。またこの期間の植物の高さは２．５〜３．８３に保持された。ガハグサ及びウシノケグサを刈揃えて高さが均等に２．５〜３．８αになるようにした。また処理前に名跡の重量を測定した。各濃度の試験化合物および対照を、空気圧１０ｐｓｉｇに設定した吸引式噴霧装置を用いて４つの鉢に噴霧して施用した（鉢１つに５ｄの溶液を噴ｎ）。対照として試験化合物を含まない水−アセトン溶液も４つの鉢に施用した。乾燥後、全部の鉢を温度８０±５下、湿度５０±５％の温室の中に７日間式れておき、その量水を与えなかった。２４時間毎に全部の鉢の重量を測定し、その日の重量と初期重量から水の使用量を算出した。７日後に鉢の植物を視覚にて観察した。その後植物を均等な高さに刈り揃え、鉢毎の刈り取り屑（ｃｌｉｐｐｉｎｇｓ　）を採集して乾燥し、重量測定を行＜５つだ。水の使用ｍを次の式を用いて算出した。ＷｔＪＥを次の式を用いて算出した。各試験化合物の対照に対するＷＵＥ指数を次の式を用いてｎ６濃度の試験化合物と対照について数値の平均をとって表８８〜ＦＦに示した。１卦ｉ四傘どの濃度でも植物に被害を与えた。１１度が７８ｐｐｍ以上の場合ではほとんど全部の植物が枯れた。植物に実質的な桑害が生じた。１朋代表的な窒素含有複素環　合物のナガハグサに　する　使用効率生じた。瓦■ 代表的な窒素含有複素環′合物のＨ代ｊ的な窒素含ｍ環化合物の傘どの濃度でも植物に被害を与えた。植物に実質的な薬害が生じた。表ＢＢ〜表ＦＦの結果から明らかなように、本発明の方法で使用する代表的な窒素含有複素膿化合物は非処理の対照に比較して水の使用員を顕著に低減させ、しかも植物の生育、即ち植物の光合成に悪影響を与えない。これと対照的に、アトラジンで処理した植物の場合には実質的な薬害が生じた。（以下余白）友屋を四Ω工■ 発散防止化合物を農業に使用した場合、保水効果だけでなく収穫量増大効果も期待できる。換言すれば、発散防止化合物を作物に使用した場合、水分を特に必要とする期間の水分損失をより測定した値である。０．７８ｇ、　１．５５９又は３．１０ｇの化合物４４を７８０ｍ！のアセトンに溶解させて溶液を作成した。施用直前に前記溶液に水を添加して最終容量を１３００ｄとシタ。アセトン７８０Ｉｘ１ト水５２０Ｉｄヲ混合して試験化合物を含まない総［１１３００−の対照溶゛液も作成した。４２ケ所の区画農地のトウモロコシに対して、統計学的処理方法（ｓｔａｔｉｓｔｉｃａｌ　ｔｒｅａｔｍｅｎｔ　ｐｒｏｃｅｄｕｒｅ）で上記製剤を施用した。各区画は、約３フイートの間隔で長さ２０フイートの列を４列並べたものである。以下の作業をランダムに６区画に割りあて（ａｒａｎｄｏｍｉｚｅｄ　ｃｏｍｐｌｅｔｅ　ｂｌｏｃｋ　ｏｆ　ｓｉｘ　ｄｉｆｆｅｒｅｎｔ　ｒｅｐｅｔａｔｉｏｎｓ）、１ブロツクとした。各作業には次の処理が包含される：（１）　試験化合物を含まない対照による処理：Ｏ表ＣＧに示す時ｆｆ１Ｔ１に１区画当り０．７８９の化合物４４を使用する処理： ■　表ＧＧに示ず時期Ｔ１に１区画当り１．５５ｊ７の化合物４４を使用する処理；０）　表ＧＧに示す時期Ｔ１に１区画当り３．１０ｇの化合物４４を使用づる処理： ■　表ＧＧに示す時期Ｔ２に１区画当り０．７８ｇの化合物４４を使用する処理： ■　表ＧＧに示す時期Ｔ２に１区画当り１．５５ｇの化合物４４を使用する処理： ω　表ＧＧに示す時期Ｔ２に１区画当り３．１０！７の化合物４４を使用する処理：空気圧を約２０〜４０ｐｓｉｇに設定した二酸化炭素バックバック噴霧ｌｊｌ　（ｂａｃｋｐａｃｋ　５ｐｒａｙｅｒ）を用いて、上記製剤を各区画に施用した。トウモロコシの植付は時、施用時及び収穫時については、表ＧＧに詳細に示した通りである。各区画の中間２列の内１０フィートｔｉｉ！＜中間２列の夫々両端から５フイート域）のトウモロコシを収穫して収８！番を測定した。生育期間の少なくとも一時期に水圧適状ｌ（ｗａｔｅｒ　５ｔｒｅｓｓ　ｃｏｎｄｉｔｉｏｎｓ）が見られた。夫々の作業に関して各区画で得られた数値の平均値を表ＧＧに示した。Ｋ１代表的な窒素含有複素環化合物の作物収１１Ｂ増大効果−ト　モロコシネＴ１　：検出しくｔａｓｓｅｌ）時、植付けから４６日目の第２回施用収穫　：検出しから３週間後、植付けから６１日目の第２回施用収穫：植付けから　１１４日目表ＧＧの結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いてトウモロコシを処理した場合、同様の条件下でも非処理のトウモロコシに比べてトウモロコシの収８１１が顕著に増大する。釆１」１１遵１月− 代表的な窒素含有複素環化合物の作物収ｖ５Ｈ増大効果−綿発散防止化合物を農業に使用した場合、保水効果だけでなく収穫量増大効果も期待できる。換言すれば、発散防止化合物を作物に使用した場合、水分を特に必要とする期間の水分損失を低減させることによって実際の作物収穫車を増大させることができる。下記表ＨＨに示した綿収＠量は以下の一般的方法により測定した値である。０．７８ｇ、　１．５５ｇ又は３．１０ｇの化合物４４を７８０ｄのアセトンに溶解させて溶液を作成した。施用直前に前記溶液に水を添加して最終容量を１３００ｍとした。アセトン７８０ｄと水５２０ｄを混合して試験化合物を含まない総量１３００ｄの対照溶液も作成した。３６ケ所の区画農地の綿に対して、統計学的処理方法で上記製剤を施用した。各区画は、約３フイートの間隔で長さ２０フイートの列を４列並べたものである。以下の作業をランダムに６区画に割りあて、１ブロツクとした。各作業には次の処理が包含される：（１）　試験化合物を含まない対照による処理：■　表ＨＨに示す時期Ｔ１に１区画当り０．７８９の化合物４４を使用する処理： ■　表目１に示す時期Ｔ１に１区画当り１．５５ｇの化合物４４を使用する処理：ＣＡ）　表ＨＨに示す時期Ｔ１に１区画当り３．１０！７の化合物４４を使用する処理：Ｑ　表Ｈ）Ｉに示す時期Ｔ２に１区画当り０．７８ｇの化合物４４を使用する処理： ■　表ＨＨに示す時期Ｔ２に１区画当り３．１０ｉｉ＋の化合物４４を使用する処理：空気圧を約２０〜４０ｐｓｉｇに設定した二酸化炭素バックバック噴霧機を用いて、上記製剤を各区画に施用した。綿の植付は時、ＩＭ用時及び収穫時については、表ＨＨに詳細に示した通りである。各区画の中間２列の内１０フィート域（中間２列の夫々両端から５フイートＴａ）の綿を収穫して収！Ｉ量を測定した。生育期間の少なくとも一時期に水圧迫状態が見られた。夫々の作業に関して各区画で得られた数値の平均値を表ＨＨに示した。表ＨＨ代表的な窒素含有複素環　合物の＊Ｔ１　：Ｅ花（ｂｌｏｏｍ）時、植付けから４７日目の第１回施用Ｔ２二開花から３３！１間後、植付けから６７日目の第２回施用収Ｖ＆：植付けから１２６日目表ＨＨの結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いて綿を処理した場合、同様の条件下でも非処理の綿に比べて綿の収ｆｆ、１２４が顕著に増大する。発散防止化合物を農業に使用した場合、保水効果だけでなく収稠缶増大効果も期待できる。換言すれば、発散防止化合物を作物に使用した場合、水分を特に必要とする期間の水分損失を低減させることによって実際の作物収穫量を増大させることができる。下記表ＩＩに示したサツマイモ収穫量は以下の一般的方法により測定した値である。０．７８ｇ、１．５５ｇ又は３．１ｏｇの化合物４４を７８０ｄのアセトンに溶解させて溶液を作成した。施用直前に前記溶液に水を添加して最終容量を１３００ｄとした。アセトン７８０ｍと水５２０ｄを混合して試験化合物を含まない総ｆｉ　１３００ｍの対照溶液も作成した。別個の区画農地のサツマイモに対して、統計学的処理方法で上記製剤を施用した。各区画は、約３フイートの間隔で長さ２０フイートの列を４列並べたものである。以下の作業をランダムが包含される：する処理； ■　表ＩＩに示す時期Ｔ１に１区画当り１．５５ｇの化合物４４を使用する処理；に）　表ＩＩに示す時期Ｔ１に１区画当り３．１０ｇの化合物４４を使用する処理：Ｑ　表ＩＩに示す時期Ｔ２に１区画当り０．７８ｇの化合物４４を使用する処理： ■　表ＩＩに示す時期Ｔ２に１区画当り１．５５ｇの化合物４４を使用する処理；空気圧を約２０〜４ｏｐＳｉＯに設定した二酸化炭素バックバック噴霧機を用いて、上記製剤を各区画に施用した。サツマイモの植付は時、ｍ用時及び収穫時については、表Ｉ！に詳細に示した通りである。各区画の中間２列の内１０フィート域（中間２列の夫々両端から５フイート域）のサツマイモを収穫して収穫量を測定した。生育期間の少なくとも一時期に水圧迫状態が見られた。夫々の作業に関して各区画で得られた数値の平均値を表ＩＩに示した。作物収穫量増　効果−サツマイモ＊Ｔ１　：塊茎形成開始（ｔｕｂｅｒ　１ｎｉｔｉａｔｉｏｎ）時。植付けから４３日目の第１回施用Ｔ２：塊茎形成開始から４週間後。植付けから７７日目の第２回施用収穫：植付けから１１４日目表ＩＩの結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いてサツマイモを処理した場合、同様の条件下でも非処理のサツマイモに比べてサツマイモの収穫量が顕著に増大する。１１匠以遅と発散防止化合物を農業に使用した場合、保水効果だけでなく、収穫量増大効果も期待できる。換言すれば、発散防止化合物を・作物に使用した場合、水分を特に必要とする期間の水分損失を低減させることによって実際の作物収穫量を増大させることができる。下記表ＪＪに示した大豆収穫間は以下の一般的方法により測定した値である。０．７８ｇ、　１．５５ｒＪ又は３．１０９の化合物４４を７８０ｍ１のアセトンに溶解させて溶液を作成した。施用直前に前記澄液に水を添加して最終容（６）を１３００ａｄ！とじた。アセトン７８０ｍ１と水５２０Ｉｄ、を混合して試験化合物を含まない総ｉｌ　１３００ｍの対照溶液も作成した。３６ケ所の区画農地の大豆に対して、統計学的処理方法で上記製剤を施用した。各区画は、約３フイートの間隔で長さ２０フイートの列を４列並べたものである。以下の作業をランダムに６含せれる：（１）、試験化合物を含まない対照による処理：■　表ＪＪに示す時期Ｔ１に１区画当り１．５５９の化合物４４を使用する処理：０）　表ＪＪに示す時期Ｔ１に１区画当り３．１０９の化合物４４を使用する処理：０）　表ＪＪに示ず時期Ｔ２に１区画当り０．７８ｇの化合物４４を使用する処理： ■　表ＪＪに示す時期Ｔ２に１区画当り１．５５ｇの化合物４４を使用する処理；但）　表ＪＪに示す時期Ｔ２に１区画当り３．１０ｇの化合物４鴫を使用する処理：空気圧を約２０〜４０ｐｓｉｇに設定した二酸化炭素バックバック噴霧機を用いて、上記製剤を各区画に施用した。大豆の植付り時。施用時及び収穫時については、表ＪＪに詳細に示した通りである。各区画の中間２列の内１０フィート域（中間２列の夫々両端から５フイート域）の大豆を収穫して収穫量を測定した。生育期間の少なくとも一時期に水圧迫状態が見られた。夫々の作業に関して各区画で得られた数値の平均値を表ＪＪに示した。作物数　量増大効果−豆＊Ｔ１　：開花（ｆｌｏｗｅｒｉｎａ）時、植付けから６３日目の第１回施用下２：開花から３選間後、植付けから８６日目の第２回施用収Ｗｔ：植付けから２０１０１日目Ｊの結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いて大豆を処理した場合、同様の条件下でも非処理の大豆に比べて大豆の収！！伍が顕著に増大する。発散防止化合物を農業に使用した場合、保水効果だけでなく収穫量増大効果も期待できる。換言すれば、発散防止化合物を作物に使用した場合−水分・を特に必要とする期間の水分損失を低減させることによって実際の作物収穫量を増大させることができる。下記表にＫ及びＬＬに示した綿とポテトの収穫量は以下の一般的方法により測定した値である。３９．３重量％のプロピレンカーボネート、　３９．３重量％のＥＸＸａｔｅ７００（Ｅｘｘｏｎ　Ｃｈｅｍｉｃａｌｓ、　Ｈｏｕｓｔｏｎ、Ｔｅｘａｓ）　、　１０．０重量％のＡｔ１ｏｙ３４５５Ｆ（ＩＣＩ　Ａｍｅｒｉｃａｓ、　１１ｉ１ｍｉｎｇｔｏｎ、　Ｄａｌａｗａｒｅ）及び１１．４重量％の化合物４４を含む化合物４４の濃厚エマルジミンを作成した。施用直前に前記濃厚エマルジョン３１ｄ　（３，５ｇの化合物４４）又は６２ｄ　（７，０９の化合物４４）を水に添加して最終容量を３１２５１ｄ、と統計学的処理方法で上記製剤を施用した。各区画は、約３フイートの間隔で長さ２０フイτトの列を４列並べたものである。以下の作業をランダムに６区画に割りあて、１ブロツクとした。各作業には次の処理が包含される：（１）　試験化合物を含まない対照による処理；■　表にに及びＬＬに示す時期Ｔ１に１区画当り３．５ｇの化合物４４を使用する処理； ■　表にＫ及びＬＬに示す時期Ｔ１に１区画当り７．０９の化合物４４を使用する処理：Ｃ）　表にＫ及びＬＬに示す時期Ｔ２に１区画当り３．５ｇの化合物４４を使用する処理； ■　表にＫ及びＬＬに示す時期Ｔ２に１区画当り７．０ｇの化合物４４を使用する処理；空気圧を約２０〜４０ｐｓｉｇに設定した二酸化炭素バックバック１！霧機を用いて、上記製剤を各区画に施用した。各作物の植付は時。施用時及び収穫時については、表にに及びＬＬに詳細に示した通りである。各区画の中間２列の内２０フィート域（中間２列の夫々両端から５フイート域）の綿とポテトを収穫して収！！量を測定した。生育期間の少なくとも一時期に水圧迫状態が見られた。夫々の作業に関して各区画で得られた数値の平均値を表にＫ及び作物収穫量増　効果−綿＊Ｔ１　：開花（ｂｌｏｏｍ）の２週間前。植付けから６１日ｎ０第１回施用Ｔ２：開花時、植付けから７３日口の第２回施用収桟：植付けから１６７日目表ＬＬ代表的な窒素含有複素環　合物の作物収穫量増大効果−ポテト、ｉ：Ｔ１　：Ｒ花（ｆｌｏｗｅｒｉｎｇ）時、植付けから７５日口の第２回施用収穫　：開花から３３１ｉ４間後、植付けから９６日口の第２回施用収穫：植付けから１２５日目表ＫＫ及びＬＬの結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いて綿とポテトを処理した場合、同様の条件下でも非処理の作物に比べて作物の収穫量が顕著に増大する。実施例ＣＬＸＸＶＩＩ発散防止化合物を農業に使用した場合、保水効果だけでなく収穫發増大効果も期待できる。換言すれば、発散防止化合物を作物に使用した場合、水分を特に必要とする期間の水分損失を低減させることによ−）て実際の作物収穫」を増大させることができる。下記表Ｈ）４に示した大豆の収ｆｉｆｆｉは以下の一般的方法により測定した値である。− ３９，３重量％のプロピレンカーボネート、　３９．３重Ｄ％のＥｘｘａｔｅ７００（Ｅｘｘｏｎ　Ｃｈｅａ＋１ｃａｌｓ、　Ｈｏｕｓｔｏｎ、　Ｔｅｘａｓ）　、　１０．Ｏｉ１％のＡｔ１ｏｙ３４Ｓ５Ｆ（ＩＣＩ　Ａｍｅｒｉｃａｓ、　Ｗｉｌｉｉｎｇｔｏｎ、　Ｄａｌａｗａｒｅ）及び１１．４重量％゛の化合物４４を含む化合物４４の濃厚エマルジョンを作成した。ＩＭ用直前に前記ｍ厚エマルジョン３１ｄ　（３，５９の化合物４４）又は６２ａｄ！　（７，０９の化合物４４）を水に添加して最終容量を３１２５ｍとした。１８ケ所の区画農地の大豆に対して、統計学的処理方法で上記製剤を施用した。各区画は、約３フイートの間隔で長さ３０フイートの列を４列並べたものである。以下の作業をランダムに６区画に割りあて、１ブロツクとした。各作業には次の処理が包含される：（１）　試験化合物を含まない対照による処理：■　表ＭＨに示す時期Ｔ１に１区画当り　３．５９の化合物４４を使用する処理： ■　表８８に示す時期Ｔ１に１区画当り　７．０９の化合物４４を使用する処理：空気圧を約２０〜４０ｐｓｉａに設定した二酸化炭素バックバック噴霧橙を用いて、上記製剤を各区画に施用した。大豆の植付は時。施用時及び収穫時については、表８８に詳細に示した通りである。各区画の中間２列の内２０フィート域（中間２列の夫々両端から°５フィート［）の大豆を収穫して収Ｗ、量を測定した。生育期間の少なくとも一時期に水圧迫状態が見られた。夫々の作業に関して各区画で得られた数値の平均値を表８８に示した。１堕代表的な窒素含有複素環　Ａ物の＊Ｔ１　：開花（ｆ　ｌｏｗｅｒｉｎｇ）時、植付けから４８日目の第１回施用収穫：植付けから１８６日目表８８の結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いて大豆を処理した場合、同様の条件下でも非処理の大豆に比べて大豆の収穫量が顕著に増大する。１旦１ユＵμ」Ｕ曵表的な窒素含有複素環化合物の代表的な窒素含有複素環化合物のアルファルファの収８！暖増せて化合物の溶液を作成した。、施用直前に前記溶液に水を添加してＩｋ終容量を５５００−とした。アセトン３３００Ｍ！！と水２２００ｄを混　−合して試験化合物を含まない総−量５５００ｔｔｄｌの対照溶液も作成した。空気圧を４０ｐｓｉｇに設定した自己噴射型化学物質噴霧機（ｓｅＨ−ｐｒｏｐｅｌｌｅｄ　ｃｈｅａ＋１ｃａｌ　５ｐｒａｙ　ａｐｐｌｉｃａｔｏｒ）を用いて、上記製剤を生育後１年のアルファルファが植えられている所定の区画に施用した。各区画の大きさは幅２０フィート、長さ３０フイートであった。コントロールを含めた各処理を６ケ所の区画で６回繰返した。切取り後２０日目に前記製剤を施用し、処置後２８日目にアルファルファを収穫した。各区画の中央から１１ｒｌから収穫したアルファルファの収穫量を測定した。生育期間の少なくとも一時期に水圧迫状態が見られた。夫々の作業に関して各区画で得られた数値の平均値を表８８に示した。 −１門新鮮重Ｅ１：収穫直後測定したアルファルファの重量乾燥重量：収穫したアルファルファを９０℃のオープン内で２４時間乾燥後測定した乾燥アルファルファの重量表ＮＨの結果から明らかなように、本発明方法により代表的な窒素含有複素環化合物、即ち化合物４４を用いてアルファルファを処理した場合、同様の条件下でも非処理のアルファルファに比べてアルファルファの収穫量が顕著に増大する。実施例ＣＬＸＸＩポ代表的な容素含有、素環　合物の光合成４′）電　伝達に対する影響植物の光合成に関与する２種の光化学系、即ち光化学系工及び■が電子伝達鎖（ｅｌｅｃｔｒｏｎ　ｔｒａｎｓｐｏｒｔ　ｃｈａｉｎ）により相互に関連していることから、人工の電子ドナー及びアクセプタを使用して光合成の光反応の特殊な部分反応を研究した。ＢｒｅｗｅｒＰ、　Ｅ、、　Ａｒｎｔｚｅｎ、　Ｃ，Ｊ、、及び５ｌｉ４ｅ、　Ｆ、　Ｉｔ４．、　Ｗｅｅｄ　５ｃｉｅｎｃｅ　２７：３００−３１８（１９７９）に記載されている方法に従って、単離した葉緑体アッセイを用いて、表００に記載した化合物により引き起される光合成の阻害度を調べた。通常、前記方法には単離したエントウ豆の葉緑体を浸透的に（Ｏ″ｓｍｏｔｉｃａｌｌｙ）崩壊させ、葉緑体を反応混合物中に導入し、末端電子アクセプタとしてメチルビオロゲンを使用することを含む、Ｇ１１ｓｏｎオキソグラフ（ａｕｘｏ−に示す。１■ 代表的な窒素含有複素環化合物の光合成の電子伝達に対する影響表００の結果から明らかなように、本発明で使用される化合物は光合成の電子伝達を全く阻害しないのに対して、アトラジン（ａｔｒａｚｉｎｅ）及びジウロン（ｄｉｕｒｏｎ）は光合成の電子伝達を実質的に阻害する。以上本発明の実施例を示したが、これによって本発明が限定されるものではなく、本発明は前記した如き概念を包括するものである。本発明の趣旨及び要旨を逸脱することなく各種の変更を行うことも又各種実施例を作成することも可能である。国際調査報告１ｍｍｎ１ｌｅｓａｌａｅｓｃａ＋ｉｅ＋＋Ｎ１１ＰＣＴ／υＳ８７１００２４０ｋｍ＊５ｌｌａ、、ａｌ　ＡｐＮｃａｌｋ＋＋　Ｔｉ１ｌ　ｐｃＴ／υＳ　８７１００２４０■Ｉｎｔ、Ｃ１，’　識別記号　庁内整理番号優先権主張　０１９８岬１２月１５日［相］米国（Ｕ　Ｓ）■９３９，４１（○発明者　キャピイ、ジエイムズ・ジョセ　アメフ　ン・［相］発明者　クーク、アンソンφリチャード　アメン・＠発明　者　シーズ、リチャード争エリク　アメト争メリカ合衆国、ノース・カロライナ−２７６０６，ローリ、カプラ・ドライブ・４９０５メリカ合衆国、ノース・カロライナ・２７７１３．ダラム、ノ＼ンツマ・ドライブ・１２１０メリカ合衆国、ノース・カロライナ・２７７１３．ダラム、イース・コーンウオーリス・ロード・１７２７[L Midantan Yoe Sue Nagaji] Frozen Nioka Ri and Kami Niashin 2- Production of oxime A:2. Preparation of 4-dichlorobenzaldehyde oxime Cooled to a temperature of 0 °C Hydroxylamine hydrochloride 8. 8g<0. 13 mol) 10. 6 g (0.13 mol) of llK11M sodium and Elanor 5 2 in 0m1. 4-Dichlorobenzaldehyde 14. 7 g (0.08 mol λ solution) liquid was added. 3. Stirring at air temperature and under nitrogen pressure. It lasted 5 hours. Next, this The reaction mixture was diluted with 15-m water and extracted with CH2C12 (3x100 d) did. The organic layers were combined, dried over MgSO4 and concentrated under reduced pressure 15. 79 of A colorless solid was obtained. Chroma on silica gel using dichloromethane as eluent By tography, 14. 29 (0.07 mol) of 2. 4-Dichlorobenzoa Rudehyde oxime was obtained as a colorless solid. The NMR spectrum of this substance is as follows: It was: NMR (CDCl2): δ 7. 21 (IN, dd, J=9. 2l-1z), 7. 10 (IH, d, J=2H2), 7. 75(1)1. d. J-9Hz), 8. 09 (IH, s), 8. 49(1)1゜s) ppm 3: 2,4-dichlorobenzal-hydro-(4,6-dichloro-13) ”J- and >-Yuyoehishimama>f] Using a procedure similar to that described above in Example XχI. and reacted with cyanuric chloride. The reaction mixture was filtered to remove the precipitate and The P solution was poured onto ice to produce a yellow solid. Separate this solid and add acetone to 2. Recrystallize from water. 1 g (0,006 mol) of 2. 4-dichlorobene Zaldehyde Q-(4,6-dichloro-1,3,5-triazin-2-yl)o Kisim has a melting point of 124-124. Obtained as pale yellow needle crystals at 5°C. of this product The elemental analysis was as follows: Analysis: C1oH4C14K40 Calculated value: C, 35, 54: H, [19; N, 16. 58 actual measurement value: C, 35,72; H, 1,35; N, 16. 74 This compound is referred to as compound 96 below. It is called. Implementation example xxxv Acetophenone Q-(4,6-dichloro-1,3,5-triazin-2-yl) LLz person standing 11 Tophenone oxime and cyanuric chloride were added according to the procedure of Example xxx■. Acetophenone 0-(4,6-dimethyl) having a melting point of 123-125°C was reacted with Rol-1,3,5-triazin-2-yl)oxime was obtained. element of this product The analysis was as follows: Analysis: C11H8C12K40 Calculated values: C, 46, 67: H, 2, 85: N, 19. 79 Actual value: C , 47, 10; H, 2, 80: N, 19. 77 This compound is referred to as compound 9 below. It is called 7. Implementation example XXXVI 2. 6-Cyclolbenzaldehyde Q-(4,6-dichloro-1,3,5-tri Preparation of azin-2-yl)oxime into 300 d of ice-cold acetone, 18. 9 g (0.1 mol) of 2,6-dichlorobene Zualdoxime and 18. 4 g (0.1 mol) of cyanuric chloride were added. The pH value of the resulting solution was maintained at 6 by addition of 5% sodium bicarbonate solution. After stirring for 3 hours and maintaining the pH at 6, crystals precipitated and were removed by suction-filtration. collected, washed three times with 100 m of 20% aqueous acetone and placed in a vacuum oven for approximately 18 m Dry at 60°C for 134 hours. 9-135. 2 with a melting point of 9°C , 6-dichlorobenzaldehyde Q-(4,6-dichloro-1,3,5-tria zin-2-yl)oxime4. 92 g (0.02 mol) were obtained. source of this product The elementary analysis was as follows: Analysis: CHC14K40 Calculated values: C, 35, 54: H, 1, 19; N, 16. 58 actual measurement m: C, 35,78; H, 1,04: N, 16. 40 This compound is converted into the following compound It is called 98. Implementation example XXX■ N-'(2,4-dichlorophenyl)-N'-(4,6-dichloro-1,3,5 -Production of triazi(2-yl)hydrazine 2. 4-Dichlorophenylhydrazine4. 3 g (0.02 mol) of Example 2,6-lutidine in CHC12 of 125d in a similar manner to that used in XXI. 3. Cyanuric chloride s, e4g (0,03') in the presence of 119 (0,03 mol) f-nil). After stirring at air temperature for about 18 hours, the reaction mixture was concentrated under reduced pressure. Shrink and remove the residue with CHCJ! 3. Recrystallize from 3. 4g (0', 01 mol ) of N-(2,4-dichlorophenyl)-N'-(4,6-dichloro-1,3, 5-triazin-2-yl) and drazine at a melting point of 185. 0-192. 0℃ (decomposition ) was obtained as colorless needle crystals. The elemental analysis of this product is as follows: Analysis: Cl-(Cl4N3 Calculated values: C, 33, 26; H, 1, 55: N, 21. 55 actual measurement value: C, 32, 88: H, 1, 60: N, 20. 74 This compound is called the following compound It is called 99. Implementation example XXX■ N-24-dilorphenyl)-N-(4,6-dichloro-1,3,5-tria Production of 2-2-yl methanesulfonamide with triethylamine and 80m of dry tetrahydrofuran and the tetrahydrofuran into a magnetically stirred solution containing 521 Methanesulfonyl chloride 11. 59 (0. Add dropwise a solution containing 1 mol) did. A white precipitate separated upon addition. Continue stirring at air temperature for about 16 hours. , then the mixture was heated to reflux for 4 hours. the product is isolated by cooling; Filter to remove precipitate and concentrate under reduced pressure 21. 6 g of yellow solid was obtained. 9 :1 Chromatography on silica gel using toluene-ethyl acetate eluent According to 1. 5SF (0. 006 mol) of 2. 4-Dichlorophenyl (methane) , sulfonamide) as a yellow solid. NMR analysis of this product is as follows. It was: NMR (CDCj!3): δ 3. 10 (3H, s), 7. 0(IH, b s). 7, 37 (1H, dd, J=2. 9H2), 7. 55 (IH. d, J-2tlz), 7. 71 (IH, d, J=9Hz) pHmB: N-24-dichlorophenyl)-N-(4. 6-dichlor-1. 3. 5. Example Using a procedure similar to that used for XXXVI, 1. 157 (0. 006 moles) of cyanuric chloride in 1. 5g (0. 006 mol) of 2,4-dichlorophenylmeth sulfonamide and 670■ (0. 006 mol) of 2. 6-lutidine. Separate the colorless precipitate by filtration, and remove the P solution under reduced pressure. Concentrate under 2. 8! A yellow solid of J was obtained. Add this to 3:1 hexane-ethyl acetate Flash chromatography on silica gel using eluent 1. 6g of A yellow solid was obtained. By recrystallization from toluene-hexane 1. 0g (0. 003 mol) of N- (2. 4-dichlorophenyl)-N-(4. 6-dichlor-1. 3. 5-Thria di-2-yl) methanesulfonamide with a melting point of 145-157°C. Yellow needle-shaped crystals were obtained. NMR analysis of this product was as follows: NMR (CDC13): δ 3. 74 (3H, s), 7. 10-7. 68( 3H. m) ppw. 1R (CHCj!3): 1540, 159OaI & 13C NHR ( CDCj3): δ171. 60, 165. 42, 136. 98, 134 ．．　00. 133, 08, 130. 97, 130. 51, 128. 64. 43, 50 ppm. This compound is hereinafter referred to as compound 100. Example xxxrx 2-benzyloxy-4. 6-dichlor-1. 3. Preparation of 5-triazine 0-5℃ Benzyl alcohol in acetone 15me cooled to a temperature of 4. 229 ( 4.18 g (0.04 mol) into a magnetically stirred solution containing 0.04 mol). 04 moles) 2. 6-lutidine was added dropwise, then cyanuric chloride 7,29 in acetone 185d. (0. A solution containing 0.04 mol) was added. After completing the feeding, the reaction mixture The mixture was stirred at 0° C. for about 1 hour and then warmed to room temperature. When the temperature reaches about 20℃, A precipitate of gin salt M salt was separated and sent from house to house. Pour e-liquid onto ice to make a crude product. Precipitated things. This crude product was washed with water and dehydrated5. 79 g of material was obtained. Recrystallized twice from hexane, 78-81. 2-bendi with a melting point of 5°C fluoroxy-4,6-dichloro-1, 3. 5-t-lyazine 0. 41 g (0. 0 02 mol) was obtained. NMR analysis of this product was as follows: NMR (CDCj!): 6 5. 55ppm (2H, s, CH2), 7 ．． 46 (5H, s, aromatic) This compound is hereinafter referred to as compound 101. Example XL 1,2g (0. 05 mol) of magnesium waste and 20 d of ether in a nitrogen atmosphere. The mixture was placed in a 100d 3' neck round bottom flask. 2,4-di in ether 15d Chlorbenzyl chloride 9.7g (0. Add 2 drops of a solution containing 0.05 mol) to start the reaction. The remainder of this solution is then vigorously passed through rapidly. added to. 9. The Grignard reagent prepared as above was cooled to a temperature of 3°C. 2S F (0. 05 mol) of cyanuric chloride and 125 d of ether. Ta. As the addition progressed, an exotherm of up to 7°C and formation of a white precipitate was observed. . Stirring was continued for approximately 16 hours at room temperature, and the resulting heterogeneous mixture was filtered and placed in a magnet. Removed sium salts. Wash the P solution with water! ! ! The layer was dried with MGSO4 and vacuum Darker at the bottom. Reduce to 12. 69 yellow solid was obtained. This substance4. 09 = 1 hex Chromatographed on silica gel using EtOAC eluent. ．． 9 g of product was obtained. By recrystallization from hexane, 1. 7g (0. 005 mole) of 2-(2°. 4°-dichlorobenzyl)-4. 6-dichlor-1. 3. 5-Triazine was obtained as colorless needle crystals with a melting point of 110-112 at 5°C. this life Elemental analysis of the components was as follows: Analysis: C1oH5Ci4 N3 Calculate! : C, 38, 87: H, 1, 63: N, 13. 60 Actual value: C, 38,71; H, 1,70; N, 13. 51 This compound is called the following compound It is called 102. Implementation example XLI 2-(2″,4°-dichlorophenyl)-4,6-dichloro-1,3,5-t- Manufacture of riazine 11. In a manner similar to that described in Example XL. 1 g (0.04 mol) of 2,4- Grignard reagent was prepared from dichloroiodobenzene. This reagent was heated to 3°C. Cyanuric chloride in dry tetrahydrofuran 7Sd cooled to temperature 7. 5g ( 0.04 mol). This causes an exotherm of 6 to 8℃ and a white solid. formation was observed. The reaction mixture was stirred at air temperature for 7 hours and then refluxed for 3 days. It was heated in a stream. The solids were filtered off and the black P liquid was concentrated under reduced pressure. residue Partition between EtOAC and water and dry the dominant layer over HgSO4 and concentrate to 1 4. 9 g of black solid was obtained. Most of the unreacted cyanuric chloride was removed by Kugelro It was distilled off using an hr apparatus. The residue was then eluted with 9:1 hexane:EtOAc. Chromatographed on silica gel using reagent. As a result, 5. 4g coarse The product was obtained. 2. By sublimation (0.05 anHg, 80-85°C). 0g (0.007 mol) of 2-(2“,4°-dichlorophenyl)-4,6-dichloro Ru-1,3,5-1-riazine was obtained as a colorless solid with a melting point of 111-115°C. The elemental analysis of this product was as follows: Calculated: C, 36, 65::H , 1, G3: N, 14. 25 actual measurement value: C, 34, 22: H, 0, 92: N, 13. 20 This compound is hereinafter referred to as compound 103. 1. 40 g (0.06 mol) of magnesium powder was added to the addition funnel under a dry nitrogen atmosphere. Suspended in ethyl ether 4Id in a 50d reaction flask equipped with. Bro Mobenzene (9.48g, 0. 06 mol) and about 21 m of ether in a flask. addition funnel and about 2 d of this solution into the flask, which was warmed. The reaction was started. Add the remaining bromobenzene solution over about 1 hour. Therefore, the reflux rate was set to ¥[j. The mixture was stirred at air temperature for about 16 hours and then Heat to reflux. The Grignard reagent prepared above is then transferred via syringe to a dry addition funnel; Addition funnel of cyanuric chloride in benzene ISd 8. 159 (0.04 mol ) into a stirred, nitrogen-purged dry flask containing a solution of Cool to temperature. Add the Grignard reagent solution dropwise with stirring and add the resulting mixture. The mixture was warmed to air temperature for 4 days. This reaction mixture was combined with 50111i! quench with water After extraction with ether, the organic layer was dried and the solvent was evaporated to give a solid. By crystallization from hexane, 4. First batch of 919 (0,02 mol) of product A yield was obtained which was recrystallized from cyclohexane and then sublimated under reduced pressure to yield 2. 4 -dichloro-6=phenyl-1,3,5-triazine with a melting point of 117-118℃ Obtained as a white crystalline material. The elemental analysis of this product was as follows: Analysis: Cs Hs C1z N3 Calculated value: C, 47, 80; l-1, 2, 23: N, 18. 58 actual measurement value: C, 47, 50; l-1, 2, 26: N, 18. 49 This compound is shown below. It is called compound 104. Implementation example XLIII Preparation of 2-(1-naphthyl)-4,6-dichloro-1,3,5-triazine0. 66SF (0.03 mol) of magnesium scraps, 50% dry tetrahydrofuran jIi! 1-bromonaphthalene in it3. A solution containing 77 m (0.03 mol) liquid was added. The resulting mixture was stirred at room temperature for 20 minutes. 150Id drying Tetrahydrofuran was added and the mixture was stirred at room temperature for 1 hour under nitrogen atmosphere. did. Transfer the Grignard reagent made above to an addition funnel and add dry tetrahypertate. O Fran 30011I! ! Contains cyanuric chloride 5,09 (0,03 mol) in The mixture was added dropwise to the solution at air temperature. After stirring the mixture for 3 hours, the solvent was evaporated and A solid residue was obtained which was partitioned between 10X aqueous NaOH and Etz0. Production plate chromatograph using 20X EtOAc in EtzO layer 160Rg (0,0006 mol) of 2-( 1-naphthyl)-4,6-dichloro-1,3,5-)-riazine with a melting point of 166~ Obtained as a yellow solid at 167°C. The elemental analysis of this product was as follows: Analysis: C1387012N3 Calculated value: C, 56, 54: H, 2, 56 Actual value: C, 55, 27: H, 2,62 This compound is hereinafter referred to as compound 105. Using ethyl ether as a solvent instead of terahydrofuran and Grignard Reagents were prepared in refluxing ether from 2-promonaphthalene to 1. It took 5 hours to create A melting point of 193-194°C was obtained by the same method as used in Example 2-(2-naphthyl)-4,6-dichloro-1,3,5-triazine having Manufactured. The elemental analysis of this product was as follows: Analysis 2 013H7012N3 Calculated values: C, 56, 54: H, 2, 56: N, 15. 22:(:, l, 25. 68 Actual measurements: C, 54, 48: H, 2, 63: N, 14. 54:CR, 2 7,98 This compound is hereinafter referred to as compound 106. Implementation example XLV Production of 2-benzyl-4,6-dichloro-1,3,5-triazine 1. 40g ( 0.06 mol) of magnesium and 0.06 mol) of magnesium. 91 g (0.09 mol) of benzyl chloride and Using the same method as used in Example XL■, the Grignard reagent prepared from 8. It was reacted with 15 g (0.04 mol) of cyanuric chloride. Crude product (2,70 g) is sublimated under reduced pressure and then re-sublimated to form a pure product with a melting point of 82-85°C. 2-Benzyl-4,6-dichloro-1,3,5-triazine 0. 99! IF ( 0,004 mol) was obtained. The elemental analysis of this product was as follows: Analysis: C1oH7C12N3 Calculated values: C, 50, 02: H, 2, 94: N, 17. 49 Actual value: C , 49, 90: H, 2, 85: N, 17. 57 This compound is referred to as compound 1 below. It is called 01. Implementation example XLVI 2-(2°,4′-dichlorobenzylthio)-4,6-dichloro-1,3,5- t-li4. 89 (0.06 mol) of thiourea and 12. 29 (0.06 mol) 2. Stir the mixture of 4-dichlorobenzyl chloride and 50m ethanol. and 4. under nitrogen atmosphere. Heat to reflux for 5 hours. The reaction mixture was then cooled and dissolved in 50 d of water with 86,259 (0, 16 mol) was added dropwise. After the addition is complete, heat the mixture to reflux for 2 hours. During this time, it turned yellow. Stirring at room temperature was continued for 2 days. Then d The tanol is removed under reduced pressure and the aqueous residue is converted to CHCj! 2 (6x100 * ) was extracted. 12. Combine the layers, dry with MgSO4 and concentrate. 19 (0.06 mol) 2,4-dichlorobenzyl mercaptan was obtained as an amber liquid. This generation NMR analysis of the product was as follows: NMR (CDC13): 61. 90 (IH , t, J=8Hz), 3. 79 (2H. d, J=8Hz), 7. 18-7. 33 (211, m). 7. 33-7. 48(1)1. m) ppm. Cyanuric chloride in acetone6. 1 (0.03 mol) to a solution containing A. 2,4-dichlorobenzyl mercaptan6. 79 (0.03 mol) was added Ta. The product was made using a procedure similar to that used in Example XXXI. this The crude product was chromatographed on silica gel using 1:1 hexane-toluene eluent. By the graph, 2. 0 g of wasted product was obtained. By recrystallization 1. 9g (0,0 06 mol) of 55. 5-58. 2-(2°,4°-dichloro) with a melting point of 5°C Benzylthio 1-4,6-dichloro-1,3,5-triazine was obtained. This generation The elemental analysis of the object was as follows: Analysis: C1゜N5　C14N3　S meter Calculated value: C, 35, 22; H, 1, 48: N, 12. 32 Actual measurement value: C, 35, 56: H, 1, 62; N, 12. 47 This compound is referred to as compound 10 below. It is called 8. Implementation example XLVI 6-chloro-2,4-bis-(2°,4°-dichlorobenzylthio)-1,3, 5-to-magazine l- and 2puri [made] The initial chromatographic fractions from Example XLVI were 2. 3g colorless solid It contains 76. 0-80. 0℃ melting 2,4-bis-(2°,4°-dichlorobenzylthio)-6-chloro -1,3,5-triazine2. 2 g (o:ooa mol) was obtained. source of this product The elementary analysis was as follows: Analysis: C17H1oC15N3 S2 calculated value: C, 41, 03: H, 2, 03: N, 8. 44 actual measurement value: C, 41, 3 5: H, 2, 25: N, 8. 93 (margin below) −1 2-(2',4'-dichlorophenethoxy)-4,6-dichloro-1,35-to 1 otsu Zz five balls I A: Rainbow (21st grade Jyu)” Rishishi Otsu/L, m Yuuki (7) l’J Upper Tetrahydrof 500g2 of 124d of 1M solution of poran-tetrahydrofuran complex in the run It was placed in a 3°C neck round bottom flask and cooled to a temperature of 0°C using an ice bath. Tetrahydride Loflan 100mf! . Inside 2. 4-dichlorophenylacetic acid 12. 7! ? Contains (0.06 mol) The solution was added dropwise at a rate that maintained the temperature below 5°C. As the addition progresses gas generation was observed. After the addition was complete, the colorless mixture was heated under reflux for 1 hour and then The mixture was stirred at air temperature for about 16 hours. The reaction mixture was then diluted with 125 methanol. Processed. The solvent was removed under reduced pressure and the residue was dissolved in a needle with 5×NaOH. Washed with aqueous solution. Dry the organic layer with MgSO4, concentrate, 12. 7g (0,0 66 moles) of 2. 4-Dichlorophenethyl alcohol was obtained as a colorless oil. NMR analysis of this product was as follows: NMR (CDC13): 61. 62 (IH, s), 2. 98 (211, t, J =7H2), 3. 88 (2H, t, J=7H2), 7. 10-7. 48 (3 H, In) ppm B: 2-2°4°-dichlorophenethoxy)-4,6-dichloro, 3°aceto cyanuric chloride in the container6. Example X 2,4-dichlorophenethyl prepared in A by a similar procedure used in XXI Alcohol 6. 7 g (0.04 mol). This crude product was mixed with 1:1 toluene. Chromatographed on silica gel using hexane-hexane eluent. obtained 2. recrystallize the obtained material from hexane; 29 (0,006 mol) of 2-( 2'. 4゛-dichlorophenethoxy)-4,6-dichloro-1,3,5-triazine Melting point 106. Obtained as colorless needle crystals at 5-108°C. The elemental analysis of this product is It was as follows: Analysis 2 C11H7C14N3. Calculated values: C, 38, 97: H, 2, 08: N, 12. 40 Actual value: C , 39, 14: H, 2, 35; N, 12. 54 This compound is referred to as compound 1 below. It is called 10. Implementation example XLIX N-(4,6-dichloro-1,3,5-triazin-2-yl)-2,4-dichloro Rolbenzami's rift 2. 2 g (0.01 mol) of 2,4-dichlorobenzoyl chloride and 1. 79 (0.01 mol) of 2-amino-4,6-dichlorotriazine and 8°d of acetic acid Na08 in 4 d of water to a stirred mixture cooled to a temperature of 0 °C containing t A solution containing 400 mg was added. The Na0)l solution was added at such a rate as to maintain the temperature below 4°C. stirring This was continued for 3 hours after the addition was completed. M was then dehydrated with 1sO4 and under reduced pressure. Concentration gave a C3,69 colorless solid. Using 9:1 hexane-EtOAC eluent A colorless solid of 9001 Hg was obtained by flash chromatography. Next This material was dissolved in CH2Cl2 and washed with saturated aqueous Na)(CO3). The organic layer was dried over MqSO4 and concentrated on a rotary evaporator. The residue was dissolved in toluene-hexane. N-(4,6-dichloro) having a melting point of 162-166°C. -1,3,5-triazin-2-yl)-2,4-dichlorobenzamide 30 0η (o, ooi mole) was obtained. The elemental analysis of this product was as follows: Analysis: CHC14N40 Calculated values: C, 35, 54: H, 1, 19; N, 16. 58 actual measurement value: C , 36, 03: H, 1, 54; N, 16. 23 This compound is referred to as compound 1 below. It is called 11. Fork-"L-Plate 11"- N-(4,6-dichloro-1,3,5-)-riazin-2-yl)-2,4-di 20 (0.21 mol) of Chlor 10M into a 3°C neck round bottom flask under nitrogen atmosphere. of acetic anhydride was added and cooled to a temperature of 3°C using a water bath. To this 1. 3. 5g (0.08 mol) of 2. 4-dichloroaniline was added in portions. this mixture The mixture was stirred at air temperature for 17 hours. The colorless solid that formed was removed by filtration and Dry in the oven 16. 5 g (0.08 mol) of 2. 4-dichloroacetani Got Lido. NMR analysis of this product was as follows: NMR (CDCj! 3”): δ 2. 22 (3H, s), 7. 18 (IH, dd). 7. 34 (IH, d), 7. 40-7. 78 (1tl, bs). 8. 28 (IH, d) +11101 2,4-dichlor prepared in A by a procedure similar to that used in Example XLIX Acetanilide 6. 09 (0.03 mol) and cyanuric chloride s, 57 (0.0 A mixture containing 3 moles) and 1201 dl of acetone was added to 12 #Ii! of water. During ~ was treated with 1 solution 1' containing N a OH 1,18y (0,03 mo/lz). Ta. By post-processing, 10. 5 g of colorless oil was obtained, which was mixed with 9=1 hexane- Chromatograph on silica gel using ethyl acetate as eluent.8. 0 9 yellow oil was obtained. This solidified upon standing. When recrystallized from hexane, melting point 106-108 ．． N-(4,6-dichloro-1,3,5-triazin-2-yl) with 5°C Colorless prismatic crystals of -2,4-acetanilide6. 4g (0.02 mol )was gotten. NMR analysis of this product was as follows: NMR (CDCj!3'): δ 2. 82 (3H, s). 7. 18 (IH, d, J=911z). 7. 45 (1H, dd, J=2. 9H2). 7. 6 (IH, d, J=2Hz) ppm. This product is hereinafter referred to as compound 112. Implementation example LI 2. Production of 4-dichloro-6-phenylethynyl-1,3,5-triazine bromide Ethylmagnesium (2M solution in tetrahydrofuran 49d, 0. 1 mole) to Phenylacetylene (1 og, 0.5 d) in tetrahydrofuran (50 d). 1 mole ) was added. Cyanuric chloride (12g, 0.5g) in benzene (65d). 07 mole ) was added dropwise while maintaining the reaction temperature below 25°C. After stirring for 6 hours, evaporate the solvent. and the residue was extracted with ether. Evaporate the solvent and triturate the residue with ether. triturated, 1. 5g (0,006-E/L/) (7) 2. 4-cyclo-6-phenylethynyl-1. 3. 5-1-Ryazine with melting point 1 19 as a yellow solid at 25-131°C. The elemental analysis of this product is as follows. Calculated values: C, 52, 83: H, 2, 02: N, 16. 80 Actual value: C , 53, 37: H, 2, 28: N, 16. 25 This compound is referred to as compound 1 below. It is called 13. Production of (oroethoxy)-6-(phenylethynyl)-1,3,5-triazine By a method similar to that used in Examples XX■ and XX■, 2°4-dichloro-6 -phenylethynyl-1,3,5-triazine 2. 2. 2-trifluoroeta 2-chloro-4-(phenyl) with a melting point of 48-51°C. ethynyl)-6-(2°,2',2'-trifluoroethoxy)-1,3,5- triazine and 2,4-bis-(2°, 2°, 2- trifluoroethoxy)-6-(phenylethynyl)-1,3,5-triazine was gotten. The elemental analysis of these two products was as follows: 2-O-4-phenylethynyl-6-(2°,2',2'-trifluoronidia -135-triazine Analysis: CHCI F3 N30 Calculated values: C, 49, 78: H, 2, 25: F, 18. 17 Actual measurement value: C , 50, 98; H, 2, 42: F, 17. 11 This compound is referred to as compound 1 below. It is called 14. 2. 4-bis-(2°, 2°, 2°-trifluoroethoxy-6-phenylethyl nyl)-1,3,5-triazine Analysis: C15H9F6 N302 Calculated values: C, 47, 76: H, 2, 40: N, 11. 14F, 30. 2 2 Actual measurements: C, 48, 42: H, 2, 32: N, 11. 26F, 29. 3 3 This compound is hereinafter referred to as compound 115. Implementation example Lllll 2-4-(phenylazo)phenoxy-4,6-dichloro-1,3,5-tri-O 2 no tan 11 In a 250Id three-necked round-bottomed flask equipped with a thermometer, addition funnel, and nitrogen inlet. Addition of cyanuric chloride (4,679,0,03 mol) dissolved in Aretone 30d and cooled in a water bath to a temperature of 0-5°C. 4- in acetone 30d into a dropping funnel. Phenylazophenol (5.0g, 0.0g) 03 mol) and 2,6-lutidine (2 , 91ae, 0. 0 to 5 moles), and the mixture was filled with a solution containing 0 to 5 It was added dropwise while maintaining the reaction temperature at . After the addition was complete, the reaction mixture was heated at room temperature for 16 Stir for an hour, pass through a Celite pad, and add ice water (140ml!) . The resulting precipitate was collected in a Buchner funnel. This precipitate was dissolved in EtOAc. Washed with saturated NaHCO3 and water, dried and concentrated. crude production The material was recrystallized twice from hexane:CHCj3 (2:1) to give 162. 0 ~164. 2-(4-(phenylazo)phenoxy) having a melting point of 0°C]-4° 750η (0,002 mol) of 6-dichloro-1,3,5-,triazine was obtained. Ta. The elemental analysis of this product was as follows: Analysis 2 015H9C12N5 0゛Calculated value: C, 52, 04: H, 2, 62: N, 20. 23 Actual measurement value : C, 52, 37: H, 2, 82: N, 20. 20 This compound is reduced to the following: It is called compound 116. Implementation example 2. 2°-[1,3-phenylenebis(oxy1-bis) 4. 6-dichlor-1 35-)-Gozo of Riazin Hair in a 250d three neck round bottom flask fitted with nitrogen inlet, thermometer and addition funnel. Cyanuric chloride (13,46 ct, 0.0 ct) dissolved in Setone 100 d. 07 mole ) and cooled in a water bath to a temperature of 0-5°C. Dissolved in 100d of acetone resorcinol (4,09,0,04 mol) and 2. 6-Luzidine (8,50 m, 0. 03 mol) was placed in the dropping funnel. Gradually pour this solution into an incubator at 0-5°C. The solution was added dropwise while maintaining the desired temperature. The reaction mixture was then stirred at air temperature for 16 hours. . At this point, the precipitate was removed by filtration through a pad of Celite. The oily substance obtained by adding ice water (140 m　) to the P solution was diluted with EtOAc (2 x 150 m m> was extracted from the aqueous solution. The organic layers were combined, dried with MgSO4, and concentrated under reduced pressure. Shrunk. The crude product was purified by flash chromatography on silica (eluent 5 % EtO^C/hexane), 2. 80g (0,007 mol) 2. 2'-[1,3-phenylenebis(oxy)]-bis[4,6-dichlor -1,3,5-)-Riazine] as a white solid with a melting point of 145-148°C. obtained. The elemental analysis of this product was as follows: Analysis: C1□H 4C14N602 calculated value: C, 35, 50; l-1, 0, 99: N, 2 0. 70 actual measurement value: C, 35,07; H, 0,91: N, 20. 40 this The compound is hereinafter referred to as compound 117. Implementation example LV Other compounds were prepared in a manner similar to that used in Example L IV. Compounds 118-121 used in Examples below to reduce water loss from plants The structure and analytical data are shown in Table F below. E table---upper one IC1 Implementation example LVI Bis-(4,6-dichloro-1 1111112 辷LLUJIN-2-(A,)7tyJ艮1 Into a 250 m three-neck, nine-bottom flask fitted with a thermometer and dropping funnel, add 5 ml of acetone. 〇-Cyanuric chloride <2. 789. 0. up to a temperature of 0-5℃ containing 02 mol) Added the cooled solution. 2-amino-4,6-dichloro-1,3□5-tri Azine (2,489, 0,02 mol) was added and the reaction temperature was brought to 0-5°C. water N a OH in 6d (0,6SF0. A cold solution containing 0.02 mol) was boiled for 20 minutes. I added a few drops. The reaction mixture was then stirred at air temperature for 4 hours, and then 4. 5g Na2 It was injected into 250 m of ice water in which CO3 was dissolved. Filter this solution to precipitate the solid (tris[4,6-dichloro-1,3,5-triazin-2-yl]amine) was removed to acidify the P solution. A white precipitate was collected on a Buchner S-Too. obtained Powdered crystals (1.51 g) were sublimated over 2 days to give 204. 0-207, O 0.003 mol of pure bis-(0,003 mol) with a melting point of C was obtained. The analysis was as follows: Analysis: 06 HcI! 4 N6 Calculated values: C, 23, 03: H, 0, 32: N, 31. 33 actual measurement value: C, 22゜67: H, 1, 20: N, 30. 67 This compound is referred to as compound 1 below. It is called 22. N,M-bis(4,6-dichloro-1,3,5-triazin-2-yl-4- of fluorobenzenamine N,N-bis(4,6-dichloro-1,3,5-triazin-2-yl)-4° - Fluorobenzenamine from Haybridge Chea+1cal Com Pany. Limlted, Trevillet, Tintagel, Cornwa ll, obtained from England and recrystallized from toluene. Melting point is 231. 0-23 3. It was measured as 0°C. The elemental analysis of this compound was as follows: Analysis: 012H4014FN7 Calculated values: C, 35, 41; H, 0, 99: N, 24. 08 actual measurement value ζG, 34. 41: H, 1, 06: N, 23. 82 This compound is called the following compound It is called 123. Implementation example L■ N,M-bis(4,6-dichloro-1,3,5-triazin-2-yl)-3° -Production of chloro-4°-fluorobenzenamine N,N-bis(4,6-dichloro -1,3□5-triazin-2-yl)-3'-chloro-4'-fluoroben Zenamine is sold by Haybridge Chemical Company, Lim 1ted, Trevillet, Tintagel, Cornwall, Obtained from England and recrystallized from toluene. Melting point is 228. 5～229゜5 It was measured as °C. The elemental analysis of this compound was as follows: Analysis: Cl2 H3C15FN7 Calculation ff1: C, 32, 65: l-1, 0, 68: N, 22. 21 actual measurements Value: C, 32, 21:)l, 0. 86: N, 21. 65 This compound It is hereinafter referred to as compound 124. 100 m three neck round bottom flask equipped with stirrer, thermometer, dropping funnel and nitrogen inlet 20 al of tetrahydrofuran in Scoo! Cyanuric chloride (3,689,0, After addition of 02 mol), the mixture was stirred vigorously and cooled to a temperature of -15°C to -10°C. Hydrazine hydrate (1,90 g, 55% hydrazine content, 0.0 g in 4 d of water) 03 mol) through the dropping funnel while maintaining the reaction temperature between -15°C and -10°C. added to each. After the addition was complete, the reaction mixture was stirred at 0° C. for 15 minutes. Ice water (4 0d) and the aqueous solution was extracted with EtOAc (2x100 II! l). The material was dried with MQSO4 and concentrated under reduced pressure to obtain 2. 929 (0,009 moles) 2. 2°, 4,4°-tetrachlorohydrazo-1,3,5-triazine is Obtained as a white solid. It began to decompose at 250°C. Elemental analysis of products was as follows: Analysis 2 06 H2014N8 Calculated values: C, 21, 97: H, 0, 61: N, 34. 17 Actual measurement value: C , 23, 64: H, 1, 34: N, 36. 23 Separation and exit to acid trap 250d three-necked 5-triazine (3.20g, 0.5g) 01 mole ) and 100 d of CHCl3 were added. Sodium bicarbonate dissolved in water Sod Um (1.64g, 0. 02 mol) was added. This two-phase solution was stirred slowly. gradually until the phase CHCl3 layer becomes homogeneous and deep red, i.e. about 15 minutes. It was bubbling. At this point, the 08073 layer was separated, washed with water, dehydrated and Na 504), the pale yellow solid obtained by concentration under reduced pressure to form orange crystals was recrystallized from CHCl3. If you do it, 186. 0-190. 2, 2°, 4. having a melting point of 0°C. 4°-tet Laflorazo-1,3°5-triazine2. 1 g (0,006 mol) was obtained It was. The elemental analysis of this product was as follows: Analysis 2 06 C14Na I Calculated values: C, 22, 11: H, 0, 00: N, 34. 38 Actual value: C , 22, 78: H, 0, 28: N, 33. 98 This compound is referred to as compound 1 below. It is called 26. into a 0 °C solution with acetone (25 ml!), keeping the temperature below 5 °C. While 2. 6-lutidine (3,15d, 0. 03 mol) and 4-bitroxy- 3-Methoxybenzaldehyde (4°1259, 0. 03 mol) The liquid was added dropwise. After stirring for 2 hours, the reaction mixture was filtered, the solution was filtered through silica gel, When washed with acetone, 650η (0,002 mol) of 2. 4-dichlor-6- (4°-formyl-2°-methoxyphenoxy)-1,3,5-triazine has a melting point of 156-157. Obtained as a white solid at 5°C. NMR fraction of this product The analysis was as follows: 'HNMR (CDCj　3): δ3. 8(s, 3H ). 7. 2-7. 7 (g+, 3 old. 10. 05(s, 1tnpDl This compound is hereinafter referred to as compound 127. I Example XI Other compounds were prepared in a manner similar to that used in Example LXr. Compounds 128-13 used in Examples below to reduce water loss from plants The structure and analytical data of No. 1 are shown in Table G below. Table G II R Implementation example LXm 2. 4-Dichloro-6-(5-tupleisoxa1ly-3-amino-13. Production of 5-triazine Cyanuric chloride (s, og, 0.0 mg) in acetone (100 m). 03 mol) 2. into a 0°C solution in acetone (50d) while maintaining the temperature below 5°C. 6-lutidine (3,15d, 0. 03 mol) and 3-amino-5-methyliso A solution containing oxazole (2,669, 0,03 mol) was added dropwise. 2 hours After stirring, the reaction mixture was warmed to room temperature and poured into 200 d of ice water. Treat the mixture The solid was dried and recrystallized from chloroform to give 800111ff ( 0,003 mol) of 2°4-dichloro-6-(5-methylisoxasilyl-3 °-amino)-1,3°5-triazinga obtained as a solid with a melting point of 128-132°C. It was done. The elemental analysis of this product was as follows: Analysis: 07 H5C 12N5. Calculated values: C, 34, 17: H, 2, 05: N, 28. 06 Actual value: C , 34, 24: H, 2, 11: N, 28. 15 This compound p is referred to as compound 1 below. It is called 32. Implementation example LXrV Rainbow red Z-6-(2-eu-polyamino)-1,3,5-triazine■ Cyanuric chloride ( 18,49,0,1 mol) while maintaining the reaction temperature below 5°C. 2-aminopyridine (9,49,0,1 mol) in acetone (68d) was added dropwise. added. Then a temperature of 5° C. or less and 8. Sodium hydroxide while maintaining pH below 0 Thorium (2N solution 50d, 0. 1 mol) was added. Pass this reaction mixture was chromatographed on silica gel to yield 590 Itg (0,002 mol). ) 2. 4-dichloro-6-(2-pyridinylamino)-1,3,5-triazi was obtained as an orange solid with a melting point of 170-172°C. The elemental analysis of this product is It was as follows: Analysis: 08 H5012N5 Subtraction value: C, 39, 69: H, 2, 08: N, 28. 93 actual measurement value: C , 34, 08: H, 1, 47; N, 27. 92 This compound is referred to as compound 1 below. It is called 33. 2-aminobenzoxazole (i,og,0. 00 7 mol) and cyanuric chloride (1,38 g, 0. 007 mol) at 0°C. The temperature of the reaction mixture was kept below 10°C and the pH was adjusted to 6. 5-7. I'll keep it at 0 5% sodium hydroxide solution (34ml) was added at a rapid rate. After the addition is complete, the reaction Filter the mixture to remove solid j, 3. 5-triazine has a melting point higher than 250'C Obtained as a white solid. The elemental analysis of this product was as follows: Analysis : C1゜N5 C12N5. Calculated value: C, 42, '58: H, 1,79; N, 24. 83 actual measurement value ; C, 41, 68: H, 1, 78; N, 23. 58 This compound is reduced to It is called Compound 134. Implementation example LXVr 2. 4-dichloro-6-(4-quinazolineoxy)-135-triazine 1 艷子 4-Hydroxyquinazoline (5g, 0.0ml) in acetone (110ml). 03 mol) and cyanuric chloride CG, 3g, 0. of the reaction mixture to a mixture containing 0.03 mol) of Maintain temperature below 10"C and p++ 6. 5-7. speed to keep it at 0 At , 2% sodium hydroxide solution was added. After the addition is complete, warm the reaction mixture to air temperature. Warm and stir for approximately 16 hours. Filter the reaction mixture and place the solids into a Soxhlet extractor. and extracted with refluxing chloroform. Evaporate the solvent and chromatograph on silica gel. When applied to fee, 100 wI (0,0003 mol) of 2゜4-dichloro-6- (4°-quinazolineoxy)-1,3,5-triazine has a melting point higher than 250°C It was given as a solid with . The raw NMR analysis was as follows: 1HNMR (CDCj3'): δ7. 2-8. 2111)If(5H,l). 8. 5 ppm (IH, s) This compound is hereinafter referred to as compound 135. mol) and cyanuric chloride (39,0.02 mol) at 0°C. The temperature of the reaction mixture is kept below 10°C and the pH is set to 6. Speed to maintain between 5 and 180 At 2% sodium hydroxide solution (130d) was added. After addition, mix the reaction Store the product in a refrigerator for about 16 hours, filter the solid product, and recrystallize it from acetone. I let it happen. The solid was placed in a Soxhlet extractor and extracted with refluxing chloroform for approximately 16 hours. did. When the solvent is evaporated, 3. 759 (0.01 mol) of 2-(2-carba Zolyloxy)-4,6-dichloro-1,3,5-triazine has a melting point of 249-2 Obtained as a solid at 56°C. The elemental analysis of this product was as follows: Analysis: 015H8C12N40 Calculation if: C, 54, 40: H, 2, 44: N, 16. 92 children The compound is hereinafter referred to as compound 136. -Example LX■ 24-dichloro-6-4-23-dimethyl-1-phenyl-3-pyrazoli- 5-one-amino-1. Production of 35-triazine Acetone (200m) and Cyanuric chloride (18.4 g, +0.0 g) in crushed ice water (200 d). 1 mole) Add acetone (180I!rI to the containing solution while maintaining the reaction temperature below 5°C). 4-aminoantipyrine (20.3 g, 0.1 g) in 1 mol) was added dropwise. next to lower the temperature to below 5°C and the pH to 8. Sodium hydroxide (2 N solution 50d. 0. 1 mol) was added. The reaction mixture was filtered and the P solution was evaporated.2. 4-Diclo -6-[4-(2,3-dimethyl-1-phenyl-3-pyrazolin-5-one) -amino)]-]1. 3. 5-triazide has a melting point higher than 250"C Obtained as a white solid. The elemental analysis of this product was as follows: Analysis: C14H12C12N20 calculated value: C, 47, 88: H, 3, 45: N, 23°93 actual measurement; C, 46, 57: H, 3, 49: N, 23. 05 This compound is hereinafter referred to as compound 137. into acetone 200d with cooling to a temperature of 0-4°C! ! made it muddy Potassium phthalimide 20. 89 (0.1 mol) of suspension was added. obtained The mixture was stirred at 0 to 4°C for 3 hours, and then at room temperature for about 16 hours. This mixture The material was filtered, and the P solution was poured into ice water to stalemate. Filter this mixture to remove the solids. Drying under reduced pressure yielded 17 g of crude product. This crude product was converted into CH2Cl2-hexane. When recrystallized from 4,6-dichloro- 2-(N-phthalimide)'-1. 3. 5-triazine4. 5g (0.02 mol ) was obtained. The elemental analysis of this product was as follows: Analysis: C11H4C12N402 Calculated value: C, 44, 90: H, 1, 36 Actual value: C, 45, 05: H, 1,97 This compound is hereinafter referred to as compound 138. To a suspension containing 35% by weight KH4,02SF (0,04 mol) in oil, 1 00- in tetrahydrofuran and 3°4. 5. 6-tetra Chlorphthalimide (10.0g, 0.0g) 03 mol) at 4°C. Added at temperature. The mixture was stirred at room temperature for 30 min, cooled to 0 °C, and dried tet 6. Cyanuric chloride in 150 d of lahydrofuran. Contains 479 (0.04 mol) solution was added. The mixture was stirred at room temperature for about 16 hours, filtered, and the P solution was poured into ice water with hot C3H2. Extracted with C12. Cool the methylene chloride solution to air temperature and add hexane to The product was crystallized. When filtered, 700q (0,002 moles) of 4,6-di Chlor-2-(N-3,4,5,6-tetrachlorophthalimide)-1,3,5 -)-Ryazine was obtained as a white solid with a melting point of 298-300°C. this product The IR analysis of was as follows. IR (KB r): 1745. 1510. 　1400. 1370. 1300 and 1235α. This compound is hereinafter referred to as compound 139. Friend” L-nee LXXI 2-4゛6゛-dichloro-1゛13°, 5'-1-lyl-poor 2-yl)-1, 2-Benzisothiazole-3 (2Hken 1. 1-Gioschig purification 200m To a solution containing 100 g (0,054 mol) of cyanuric chloride in acetone , a suspension containing iog (0,054 mol) of saccharin in 100 ml of saccharin liquid was added. After a few minutes the mixture became homogeneous. 5. 2 of 5〆(0,054 mol) , 6-lutidine was added, and the mixture was stirred at air temperature under a nitrogen atmosphere for about 16 hours. Filter the suspension Then, the P liquid is evaporated and the residue is converted to C1] C! ! Crystallized from 2-hexane. child The solid was filtered and the P solution was evaporated to give a residue. The residue is CH2C1 Recrystallization from 2-hexane yields 2. 0 g (0,006 mol) of 2-(4°, 6°-dichloro-1゛,3°,5°-triazin-2°-yl)-1,2-ben Zoisothiazol-3(2H)one 1. 1-dioxide was obtained. of the product The elemental analysis was as follows: Analysis: C1゜H403CI2 H4S calculation Value: C, 38,60; H, 1,30; N, 18. 01: CI, 2 2. 79 Actual measurements: C, 36, 59: Hll, 43: N, 16. 27:Cj), 20. 71 This compound is hereinafter referred to as compound 140. Eggplant example LXXn 24-’″ Roru 6-to 1 tylsilylethynyl-1,3,5-triazi 2 1st place 14. in 80d of tetrahydrofuran. 411Ii! (0.1 mol) of trimethy Add ethylmagnesium bromide (2M solution) to a solution containing lucilylacetylene at -60°C. Trahydrofuran solution 35. 4 m) was added. The solution was warmed to air temperature, stirred for 2 hours, and heated at 40° C. for 1 hour. The solution was cooled to room temperature and 65m! 12 g (0.07 mole) in tetrahydrofuran of was added dropwise to a solution containing cyanuric chloride. After 1 hour at air temperature, the solvent was evaporated and The residue was extracted with ether. Evaporate the ether and chromatize the residue on silica gel. When applied to tography, 1. 2g (0,005 mol) of 2. 4-dichlor-6 -Trimethylsiliruethinyl 1. 3. 5-triazine as a brown oil Obtained. The elemental analysis of the product was as follows: 'Analysis: C8Hg Cj' 2 N3 S i 1 Calculated value: C, 39, 03: H, 3, 69: N, 1 7. 07 actual measurements: C, 39, 67: H, 3, 90: N, 15. 97 this The compound is hereinafter referred to as compound 141. Implementation example LXXI [[ 2,4-dichloro-6-ethoxyethynyl1. 3. Production odor of 5-t-riazine Ethylmagnesium chloride (2M detrahydrofuran solution 21. 0d), 0℃Te2 1m (7) Tet 51:l: F [1-) 5 > Middle 2 3. 09 (0,0 A solution containing 4 mol) of ethoxyacetylene was added dropwise. After the addition is complete, the reaction mixture was heated at 40°C for 1 hour, cooled to 0°C, and added to 21-tetrahydrofuran. Inside 7. It is added dropwise to a solution containing 9% (0.04 mol) of cyanuric chloride. reaction mixture The mixture was stirred for about 16 hours, the solvent was evaporated and the residue was extracted with ether. A After evaporation of the ester and chromatography of the residue on silica gel, 1. 5g (0,007 mol) of 2. 4-dichloro-6-ethoxyethynyl1. 3. 5- The triazine was obtained as an orange oil. The NMR analysis of the product is as follows: there were: 'NMR (CDCj 3): δ 1. 4 (t, 3 old, 4. 55 (Q, 2 old p. pm This compound is hereinafter referred to as compound 142. Ai] 0. 51 in water 9. 5 g (0,1 mol) of methanesulfonamide and 4 g (0,1 mol) of methanesulfonamide 1 mol) of sodium hydroxide in 100 m of acetone at 25°C. 18. A solution containing 49 (0.1 mol) of cyanuric chloride was added. After addition , the pH of the reaction mixture was adjusted to 8. 49 (0,1 mo) in 25 d of water while maintaining the temperature below 0 The solution containing sodium hydroxide was slaked. The reaction mixture was stored in the freezer (re After leaving it for about 16 hours in frigerat-0'), warm it up to room temperature and turn white when exposed to heat. A colored solid was obtained. When recrystallized from chloroform, 400η (0,002 mol) ) 2. 4-dichloro-6-methylsulfonamide-1,3,5-triazine Obtained as a white solid with a melting point of 204-206°C. The elemental analysis of the product was as follows: Analysis: CHCj2 H402S Calculated values: C, 19, 76: H, 1, 66: N, 23. 05 actual measurement value: C , 19, 48: H, 1, 68: N, 22. 44 This compound is referred to as compound 1 below. It is called 43. Example LXXV 2. 4-dichloro-6-(1°...piperidino-amino)-1,3,5-)-ly Ajin's Cock L 5. in 120d of acetone. OjJ ('0. Contains cyanuric chloride (03 mol) The solution at 0° C. is 3.0 m in 21 m acetone, maintaining the temperature below 5° C. 15d! (0.03 mol) of 2. 6-lutidine and 2. 7g (0.03 mol) The solution containing the door aminopiperidine was quenched. After stirring for 2 hours, the reaction mixture was brought to room temperature. and stirred for 1 hour. The reaction mixture was then filtered and the P solution was evaporated. Chromatograph the residue on silica gel When applied to roughy, 620q (0,002 moles) of 2. 4-dichlor-6- (1°-piperidinoamino)-1,3,5-triazine is melted at 114-117°C. Obtained as a yellow solid with spots. Elemental analysis of the product was as follows: Analysis 2 08 H11012N5 Calculated values: C, 38, 72: H, 4, 47; N, 28. 23 Actual measurement value: C , 37, 31: H, 4, 56: N, 26. 75 This compound is referred to as compound 1 below. It is called 44. 350-92% in acetone. 29 (0.5 mol) of cyanuric chloride is dissolved 909 to the solution cooled to -30°C while maintaining the reaction temperature below -20°C. (2.0 mol) of liquid dimethylamine was added. When you stop stirring the reaction mixture Internal temperature rose to 5°C. The temperature of the reaction mixture was then maintained at 0 °C after pouring the reaction mixture into 2 Kg of crushed ice. While doing so, air was blown over the surface to evaporate the acetone. After filtration, 124g of solid When the body was recrystallized from pentane and chromatographed on silica gel, 4Q Qay (0,002 mol) of 2,4-bis(dimethylamino)-6-chloro- 1,3,5-t-lyazine was obtained as a yellow solid with a melting point of 62-64 °C. Ta. Elemental analysis of the product was as follows: Analysis: C7H12CIN5 Actual measurements: C, 41, 32: H, 5, 94: N, 35. 18 This compound It is hereinafter referred to as compound 145. Implementation example LXX■ 2. 4-dichloro-6-dimethylamino-1,3. Production of 5-triazine 380 92.d in acetone. 29 (0.5 mol) of cyanuric chloride was dissolved. 799 (0, 7 mol) of 40% aqueous dimethylamine was added. After the addition is complete, the reaction mixture is The mixture was stirred at -10°C for 30 minutes. After pouring the reaction mixture into 2 to 9 crushed ice, maintain the temperature of the reaction mixture at 0 °C. Air was blown onto the surface to evaporate the acetone. After filtration, the solid is removed from the pentane. When recrystallized, 59. 0 g (0.3 mol) of 2. 4-dichloro-6-dimethyl Amino-1, S, 5-triazine is 111. 5-115. has a melting point of 5°C Obtained as a white solid. The elemental analysis of the product was as follows: Analysis 2 05 H6012N4 Calculation fa: G, 31. 11; H, 3, 13; N, 29. 03 actual measurement Value; C, 31,06: H, 3,06: N, 29. Reducing the compound in 4 to the following: It is called Compound 146. 120 m of acetone and 200 m of crushed ice-water 18. 49 (0.1 mol 17.) into a solution containing cyanuric chloride while maintaining the reaction temperature below 5°C. 49 (0.1 mol) of morpholine was added. The temperature is below 5°C and the pH is 8. Add sodium hydroxide to this mixture, keeping the temperature below 0. Lium solution (25d of 2N solution) was added. The reaction mixture was treated with P and the separated solid When the body is recrystallized from ether, 8. 09 (0.03 mol) 2. 4-Diclo Le-6-(1-morpholinyl-1. 3. 5-triazine at 154-157℃ Obtained as a white solid with melting point. Elemental analysis of the product was as follows: Analysis: CHC12H40 Calculation 'fifi: C, 35, 76: H, 3, 43: N, 23. 84 fruit Measured values: C, 35, 58: H, 3, 60; N, 23. 83 This compound is It is referred to as Compound 147 below. Implementation example LXXrX Other compounds were prepared in the same manner as in Example LXX■. Reduces water loss from plants Structural and analytical data of compounds 148 to 149 used in Examples below to reduce are shown in Table H below. C.I. Dai-”L2 is LXXX 2,4-dichloro- prepared in Example LXXVI of ia, og (0,09 mol) 6-dimethylamino1. 3. 5-triazine, 1. Heat to 30℃ and add chlorine gas. The solution was irradiated with ultraviolet light for 5 hours. The resulting residue was chromatographed on silica gel. When applied to dographies, 300 μ (0,001 mol) of 2-bis(chloromethylene) ) Amino-4,6-dichloro-1,3,5-triazine was obtained as an oil. Ta. Elemental analysis of the product was as follows: Analysis: 05 H4C14N4 Calculated value: C, 22, 92; H, C54: N, 21. 39 Actual measurement value: C, 23,10; I-1,'1. 87: N, 21. 93 This compound is combined as follows It is called object 150. Implementation example +-x x x r 2. 2'-[1,2-phenylenebis(oxy)]-bis 4. 6-Koji Nakudan 1. 3. 5-triazine] Example 2. Using cyanuric chloride as an acid acceptor was carried out in the same manner as in Example 1. 6-lutidine In the presence of 1. When reacted with 2-dihydroxybenzene, a melting temperature of 154-156°C is obtained. 2,2°-[1,2-phenylenebis(oxy)]-bis[4,6- dichloro-1,3,5-triazine] was obtained. The elemental analysis of the product is as follows. It was: Analysis: CH014N602 Total II value: C, 35,50; H, 0,99; N, 20. 70 actual measurement value; C, 35, 60: H, 1, 29; N, 20. 68 This compound is called the following compound It is called 151. Example LXXXI[ Crush 20. in 150d of acetone. Stirring containing 0 g (0,108 mol) of cyanuric chloride Stir the solution at -70°C for 12. Suppresses 2,6-lutidine of 6d (0.12 mol) did. 8. Add 3d (0.11 mol) of 2-buOpanol and add the resulting mixture. The mixture was stirred at room temperature under nitrogen atmosphere for about 16 hours. Next, when vacuum dropless is applied, 2. 09 (0.01 mol) of 2. 4-dichloro-6-itubo poxy 1. 3. 5-t The riazine was obtained as an oil with 152-b. B: 2,4-dibromo-6-itubroboxy 1,3. Production of 5-triazine Prepared with A in a methylene chloride solution at a temperature of 25° C. in the same manner as in Example XTX. 2,4-dichloro-6-ibutoxy 1,3. 5-triazine with bromide water When treated with raw gas, 2. 4-dibromo-6-itubroboxy 1,3. 5-t The riazine was obtained as an unstable solid. The elemental analysis of the product was as follows : Analysis: C6H7B r2 N3 0 Calculated value: C, 24, 24: H, 2 , 36; N, 14. 14:3r, 53. 87 Actual measurements: C, 21,14; H, 2,83; N, 13. 89:3r , 53. 88 This compound is hereinafter referred to as compound 152. Example LXXXI [1 5-(3°, 5′-dichlorophenoxy)-3,6-dichloro-1,2,4-t 6-Azauracil of Lia 509 (0.44 mol), 49. 8d (1, A mixture containing 0 mol) of bromine and 625 d of water was stirred using a magnetic stirrer for 27 h. Stir for a while. The mixture was heated to give a white powder. Obtained by concentrating P solution The second product was combined with the first product. The white solid is recrystallized from water and dried. and 5-bromo-6-azauracil with a melting point of 234-237°C53. 4g (0.33 mol) was obtained. 299, s*, <3°4 mol) in phosphorus oxychloride 14. 4g (0,013 mol) of 5-bromo-6-azauracil prepared above was added with 3o,o g (0,1 mol) of phosphorus pentachloride and 30d (0,19 mol) of N,N-diethyl Luaniline was added. The mixture was stirred magnetically and heated to reflux for 2 hours, then at room temperature for 24 hours. I left it for a while. Excess solvent was removed under reduced pressure and the residue was dissolved in 200% dry ether. Extracted 8 times. The ether was removed and the residue was heated to 70°C/0. Stock up on 007 shoes and 3, 5. having a melting point of 56-58°C. 6-Dori Chlor 1. 2. 4-Thria Gin8. 779 (0.05 mol) was obtained. 1. in 50 d of acetone. 3,5゜6- made with 84g (0,01 mol) of 8 Dorikuro 1. 2. In a solution containing 4-triazine, dissolved in 10 d of acetone, 1,63 g (0.01 mol) of 3,5-dichlorophenol and 1. 079 (0.01 mol) of 2. Maintain the reaction temperature of the solution containing 6-lutidine at 0-5℃ The mixture was added with cooling and stirring at a rate such that The reaction mixture was stirred magnetically for 2 hours. Stir and warm to room temperature. The precipitated 2,6-lutidine salt Ml was separated from P and washed with 50 d of acetone. Ace The solution was poured into approximately 1,000 g of ice and allowed to precipitate. Dry the solid and hexa When crystallized from 2. 5-(3°,5°-dichlor) of poem (0,007 mol) phenoxy)-3,6-dichloro-1,2,4-triazine at 130-132°C Obtained as a white solid with a melting point of . The elemental analysis of the product was as follows :Analysis: C9H3Cf! 4 N30 calculated value: C, 34, 76: H, 0 , 97: N, 13. 51 actual measurement value: C, 34, 64: H, 0, 93: N , 13. 69 This compound is hereinafter referred to as compound 153. , Example LXXXrX Other compounds were prepared in the same manner as in Example LXXX■. water loss from plants Compound implementation examples used in the examples below to reduce XC 3-(2',4°-dichlorophenoxy)-3,6-dichloro-1,2,4-to Manufacture of riazine 3 and 5 in the same manner as in Example ①. 6-) Cycloro 1. 2. ;’lI-triazine 5-(2°,4°-dichlorophenoxy)-3,6 with a melting point of 90-93°C -Jik O Lou 1. 2. 4-1-Riazine3. 0 g (0.01 mol) was obtained. Infrared analysis of the product was as follows: IR (KBr) 3090, 1530. 1505. 1470. 1400. 1295. 1235. 1 205. 11001050, 985. 865. 830. 750 Rho 1 This compound is hereinafter referred to as compound 157. Implementation example XCL Other compounds were prepared similarly to Example XC. Reduces water loss from plants In order to It is shown in Table J. Implementation example XCU Rubenzaldehyde 0-(3,6-dichloro-1,2,4-triazide) Production of (4-yl)oxime Similarly to Example xxxvi, 3,5. 6-Dolichlor 1. 2. 4-Thria 2. Gin. When reacted with 6-dichlorobenzaldoxime, 103-105℃ 2,6-cyclobenzaldehyde 0-(3,6-dichloro-1 ,2,4-triazin-4-yl)oxime 0. 93(j (0,003 mol) is I was given 1q. The elemental analysis of the product is as follows: Calculated value: C, 35, 54: H , 1, 19; N, 16. 58 actual measurement value: C, 35, γ6: H,? , 60; N, 17. 04 This compound is hereinafter referred to as compound 161. Implementation example xcm Production of 3-ri0-6-(2°,4-dichlorophenoxy)pyridazine 200 tons 5.d in acetone. 969 (0,04 mol) of 3,6-dichloropyridazine, 6. 529 (0.04 mol) of 2,4-dichlorophenol and 5. 80g A mixture containing (0.04 mol) (7) K co3 was heated on a water bath for 2 hours. . The solvent was removed and the residue was washed with 100 d of 10% aqueous NaOH and then with water. Ta. When the crude solid is crystallized from hexane, 1. 6g (0,006 mol) of 3- Chlor-6-(2°,4-dichlorophenoxy)pyridazine has a melting temperature of 89-91°C. Obtained as a white solid with spots. Elemental analysis of the product was as follows: min. Analysis: C1oH5013N20 Calculated value: C, 43, 59; H, 1, 83: N, 10. 17 Actual measurement value: C , 43, 59: H, 1, 91; N, 10. Compound 16 below It is called 2. Implementation example XCIV Other compounds were prepared in the same manner as Example xcm. Reduces water loss from plants Table K below shows the route and analytical data of compound 163 used in the examples below. Shown below. Eggplant example XCV Destruction of tris 4,6-dichloro-1,3,5-triazin-2-yl)amine] Production of bis(4,6-dichloro-1,3,5-triazin-2-yl)amine In the same manner as Example LVI, 1. Filtration of the solid precipitate yields tris(4,6-di Chlor-1,3,5-triazin-2-yl)amine at 360℃ or higher (decomposition) Obtained as a 1j product with melting point. The elemental analysis of the product was as follows: Analysis: C9Cl 6 N1° Calculated value: C, 23, 45: H, 0,' (10; N, 30. 39 actual measurement value; C, 21, 85: H, 1, 18: N, 33. 65 Combine this compound as follows It is called object 164. Implementation example XCVI Other compounds were prepared in the same manner as in Example XC■. Reduces water loss from plants The structure and analytical data of compound 165 used in the examples below are shown below. Shown below. Table , -Example XCVI 3-Loru 6-3゛-Chlorphenoxy)pyridazine production 24m 1. 25 1. in N aqueous sodium hydroxide solution. 93SF (0,015 mol) of 3-chlor Phenol and 1. 5g (0,005 mol) of tetrabutylammonium bromer 2. to a solution containing 50 d of toluene. 3 of 239 (0,015 mol) ．． A solution of 6-dichloropyridazine was added. This mixture was heated to 50°C. Heated for 3 hours. The organic layer was separated and washed with dilute NaOH solution and water, MgSO4 dried and evaporated. When the resulting residue is crystallized from hexane, 1. 55 g (0,006 mol) of 3-chloro-6-(3'-chlorophenoxy)pyridazi was obtained as a white solid with a melting point of 85-88°C. Elemental analysis of the product is It was as follows: Analysis: C1oH6C12N20 Calculated values: C, 49, 82: H, 2, 51; N, 11. 62 actual measurement value: C , 49, 87: H, 2, 48: N, 11. 65 This compound is referred to as compound 1 below. It is called 66. U implementation of 4-(4°-nitrophenoxy)-2,5,6-dolychlorpyrimidine 2, 4, 5 in the same way as the example. 6-tetrachlorpyrimidine and 4-nitrophe 2. Nol in acetone solution as acceptor. Reacted in the presence of 6-lutidine , melting point of 114-116 °C after sublimation in vacuo and recrystallization twice from hexane. The elemental analysis of 4-(4-nitro with Analysis 2 C1oH4C13N303 calculated value: C, 37, 47: H, 1, 26; N, 13. 11: CI, 33. 18 Actual value: C, 36,89; H, 1,52: N, 13. 00: Cf1. 32. 79 This compound is hereinafter referred to as compound 167. Implementation example XCrX Other compounds were prepared in the same manner as in Example XC■. Reduces water loss from plants Structural and analytical data of compounds 168 to 169 used in Examples below to reduce are shown in Table M below. Implementation example C 2-2゛4°-dichlorophenoxy)pentachlorocyclotriphos 22-parallel 1 ] 10. in 50d of acetone. 8 g (0,9'3 mol) of phosphonitrile chloride dotori v-(phosphonitr12ic chloride triI ller) in 10 m of acetone at a temperature of -60°C under a nitrogen atmosphere. 3. 6 solution containing 1d (0.03 mol) of 2,6-lutidine and 40d of acetone s, og (0.03 mol) in 2. Add a solution containing 4-dichlorophenol did. The reaction mixture was warmed to room temperature, stirred for about 16 hours, filtered, and the P solution was poured into ice water. Injected. The solid (6.8 g) was collected by filtration and the unconverted 2. 4-ji Chlorphenol was removed. When the pink semi-solid remaining in the sublimate is collected, 0. 9U (0,002 mol) 2-(2°, 4′-dichlorophenoxy)pentachlorocyclotriphosphase was obtained. NMR analysis of the product was as follows: 6 7. 20-7. 55ppH1 (ffi, aromatic proton)This compound is It is called compound 170. Implementation example CI 2. 4-dichloro-6-(2°,4′-dichlorophenoxy)hexahydro-1 Production of 35-triazine 340η (0,001 mol) of 2. 4-Cyclo Contains Ru6-(2°,4°-dichlorophenoxy)-1,3,5-triazine The suspension contains 400q (0.01 mol) of sodium borohydride and 5j11 ! of methanol was added little by little. Stir the mixture for 5 minutes and add 42011 g (0.01 mol) of sodium borohydride was added. Stir the mixture for 15 minutes Afterwards 150 d of ether were added and the mixture was partitioned between ether and water. organic layer Drying with Na2SO4 and evaporation yields 340 ing (0,001 mol) of 2 ,4-dichloro-6-(2°,4°-dichlorophenoxy)hexahydro-1, 3,5-triazine was obtained as an unstable white solid. NMR analysis of the product is It was as follows: 13CNMR (GOCN/D20):・δ 118. 53. 121. 86. 12 4. 87. i25. 71. 128. 82. 129. 5゜130, 09 and 1 30. 93 CDI This compound is hereinafter referred to as compound 171. Implementation example cm 24-dichloro-6-4-(4-ethoxyphenylazo)-1-naphthoxy-1 , 3,5-triazine production Example L11 [2,4=dichloro having a melting point of 173-117°C] Ru-6-(4-(4-ethoxyphenylazo)-1-naph)~xyJ-1゜3. 5-triazine was produced. Elemental analysis of the product was as follows: Analysis: C21H1, CI 2 N502 total gamma value: C,57,2 9: G1 3. 43: N, 15. 90 actual value: C, 57, 52: H , 4, 08: N, 15. The compound No. 6 is hereinafter referred to as compound 172. Implementation example C■ Rainbow (Z missing and Gen' ni Kugami Dono l Yuno 1 shi) -1,3,5-to IJ engine example In the same manner as in B of XX■, cyanuric chloride is used as an acid acceptor for 2,6-lutidine. When reacted with 2-methoxyphenyl in the presence of 93-94. has a melting point of 5°C 2,4-dichloro-6-(2-methoxyphenoxy)-1,3,5-t-ria Gin was obtained. Elemental analysis of the product was as follows: Analysis: C1oH7012N3 o2 calculated value: C, 44, 14: H, 2, 59; N, 15. 44 actual measurement value: C, 43,99: H, 3,00: N, 15. 27 This compound is hereinafter referred to as compound 173. Fruit eggplant example CIV Rainbow Rainbow 2 Emperor's Day yo E grudge pi sei jinjiruoki kigo 2 Yunoxi) -1, 3, 5-1-! Jaz z stand up 1 Example XXI[B] Using cyanuric chloride as an acid acceptor, 2,6- When reacted with 2-benzyloxyphenol in the presence of tidine, 92-94°C 2,4-dichloroA/-6-(2-benzyloxyphenoxy)- with a melting point of 1,3,5-1-riazine was obtained. Elemental analysis of the product was as follows: Analysis: C16H11C12N302 Calculated value: C, 55, 19; H, 3, 18; N, 12. 07 actual measurement value: C, 55, 59; H, 3, 19; N , 11. The compound No. 7 is hereinafter referred to as compound 114. Implementation example Cv 2. 4-dichloro-6-[4-(1-methyl-1-[4-propoxyphenyl) B15phenol A of S, og (0.02 mol), 3. 04g (0, A mixture of 02 mol) potassium carbonate and 100 mol acetophenone was added at 150°C. Stir and heat for 2 hours. After cooling to room temperature, 3. 22d (0.03 mol)-1 -Iodopropane was added and the mixture was stirred and heated at 100° C. for about 16 hours. anti The reaction mixture was allowed to cool and the solids were removed by filtration. Reduce acetofluorenone 4-propoxyphenyl)ethyl]phenol was removed by pressure distillation. Obtained. Hue’HNMR (CD, C1) 3): δ o, go-1,9 1 (Peng, IIH). 3. 90 (t, 2H, J-7Hz). 5. 15 (S, H), 6. 57-7. 21 (m, 8H) pp garden B: 24-dichloro-6-4-1-methyl-1-4-boxyphenylethyl ) phenoxy-1,35-triazine in the same manner as in Example XX-8. 2. Cyanuric acid as an acid acceptor. 4-[ prepared in A in the presence of 6-lutidine React with 1-methyl-1-(4-propoxyphenyl)ethyl]phenol And, 2. 4-dichloro-6-[4-(1-medilu 1-[4-propoxyphenylene (1-ethyl) J phenoxy-1,3,5-triazine was obtained as an oil. . The elemental analysis of the product was as follows: Analysis: C21H21CI! 2 N302. Calculation till: C, 60, 30: H, 5, 06: N, 10. 04 length measurement Wi: C, 59, 62: H, 5, 06: N, 10. 84 This compound is It is referred to as Compound 175 below. Example CVl 24-di roll 6-4- (1-% % 壓"yu(4s"Σpolydiphenylethyl) Similarly to Example Cv A, bisphenol A was added to the acid acceptor in an acetone solution. When reacted with methyl iodide in the presence of potassium carbonate as 4-[1-methyl -1-(4-methoxyphenyl)ethyl]phenol was obtained. in phenol NMR analysis of the intermediate was as follows: 1HNMR (CDC13゛): δ 1. 63 (s, 6 old, 3. 77(s, 3N ). 5. 62 (s, H), 6. 55-7. 27(i+,81)pm The 4-[1-methyl-1-(4- MethoA, dinoenyl)ethyl] When reacted with phenol, the temperature was 108...111℃. 2,4-dichloro-6-[4-(1-medyru-1-[4-me1- xyphenyl 1-ethyl)] phenoxy-1,3,5-)-riazine was obtained. . The elemental analysis of the product was as follows: Analysis 2 019H17CI 2 N3 o2 calculation [: C, 59, 47: H, 4, 39: N, 10. 77 fruit Measured values; C, 58, 35: l-1, 4, 40; N, 10. The compound of 7 It is hereinafter referred to as compound 17G. Implementation example C■ 2,4-shi’) Lti-6-[4-(1-methyl-1-4-henshi) 7E, ::/ly1Egil) J Phenoxy-1,35-1-Ryazine J Hiroshi A: 4-[1-methyl-1-(4-benzyloxyphenyl) engineering LLL phenol] manufacturing Similarly to Example Cv A, bisphenol A was added to the acid acceptor in an acetone solution. When reacted with benzyl chloride in the presence of potassium carbonate as 4-[1-methyl -1-(4-benzyloxyphenyl)ethyl]phenol was obtained. pheno NMR analysis of the alcohol intermediate was as follows: "HN ~ +R (CDC13): 6 1. 60 (s, 6H), 4. 57( s, 311). 5. 00(s, 2H), 6. 56-7. 48 (m, 811) 00m The 4-[1-methyl-1-(4- When reacted with benzyloxyphenyl)ethyl]phenol, 117. 5-1 2,4-dichloro-6-[4-<1-methyl-1-[4- besidyloxyphenyl]-ethyl)1phenoxy-1゜3. 5-triazine Obtained. Elemental analysis of the product was as follows: Analysis: 025th 210! 2 N302 calculation *: C, 64, 39: H, 4, 54: N, 9. 01 actual measurement value: C, 64, 09: H, 4, 59; N, 8. 87 In the same manner as in Example XX■A, catechol was used as an acid acceptor. When reacted with 1-bromobutane in the presence of sodium hydroxide, 2-(n-butane methyloxy)phenol was obtained. The NMR analysis of the phenol intermediate is as follows. was: 'l-INMR (CDCfi 3): δ0. 73-1. 95 (m, 7H). 3. 63-4. 08 (t, 2H). 6. 02-7. 32(a+,4H)11pmSalt in the same manner as B in Example XX■ 2-( When reacted with n-butyloxy)phenol, 2,4-dichloro-6-(2- n-butyloxyphenoxy)-1,3,5-1-riazine was obtained as an oil. It was. The elemental analysis of the product was as follows: Analysis: C43H13Cf! 2 N3 o2 calculated value: C, 49, 70: H, 4, 17; N, 13. 37 fruit Measurement 1ifI: C, 50, 82: H, 4, 69: N, 12. 98 this transformation The compound is hereinafter referred to as compound 178. Implementation example CIX Other compounds were prepared in the same manner as in Example C■. Reduces water loss from plants The structures and analytical data of compounds 179 to 184 used in the examples below are shown below. Shown in Table N. Implementation example CX 2. 4-dichloro-6-(4-(4-penzyloxy-phenylthio)phenoki) Production of C-1,3,5-triazine A: 4-[(4-benzyloxyphenylene 14s of (ruthio)phenol, 4,4°-thiobisphene of C9 (0,02 mol) Knoll, 3. of 79 g (0.03 mol) of potassium carbonate and 75 m of acetone. The mixture was heated to reflux for 2 hours. After cooling to air temperature, 4. 35g (0, 03 mol) of benzyl chloride was quenched and then heated under reflux for 166 hours. reaction mixture was cooled to room temperature and filtered through Celite to remove solid material. P liquid Concentrate under vacuum and purify the residue by flash chromatography.2. 8 2 g (0,01 mol) of 4-((4-benzyloxyphenylthio)]phenol was obtained. The NMR analysis of the phenol intermediate was as follows: '1H NMR (CDCI 13):δ 4. 98 (s, H), 5. 08 (S, 2H). 6. 65-7. 50 (1,13tl) Dp plow 3:2. 4-dichloro-6-[4 -(4-benzyloxyphenylthio)J phenoxy-1,3,5-triazine Preparation of Example 2.2 using cyanuric chloride as the acid acceptor in the same manner as in B of Example xX■. 6 -4-[(4-benzyloxyphenylthio) prepared in A in the presence of lutidine ] When reacted with phenol, 2,4-dichloro having a melting point of 119-120°C Ru-6-[4-(4-benzyloxyphenylthio)J phenoxy-1,3,5 - triazine was obtained. Elemental analysis of the product was as follows: Analysis 2 C22H15C12N30□ S calculated value: C, 57, 90: H , 3, 31: N, 9. 20 actual measurement value: C, 58, 49: H, 3, 60; N, 8. 94 This compound is hereinafter referred to as compound 185. 1-Rin-191CXI Other compounds were prepared similarly to Example CX. Reduces water loss from plants In order to It is shown in Table O. Table O Representative nitrogen-containing heterocyclic compounds I I Actual journey example CX■ 2-chloro-4-medyru-6-[4-(1-methyl-1-[4-methoxyphenyl) Preparation of 1-phenoxy-1,3,5-triazine (50d tetrahydride) 0 during rofrazi. Example 7i (0,002 mol) 2,4- prepared with CVI dichloro-6-[4-(1-methyl-1-[4-methoxyphenylethyl)]] Fe/kishi 1. 3. To the stirred solution containing 5-triazide, add 2. 04〆<　o, oo e@le) 2. Add a 7M solution of methylmagnesium bromide in ethyl ether to water. It was added slowly while cooling on the bath. The reaction mixture was then warmed to room temperature, Stirred for 15 hours. The solvent was removed by vacuum evaporation and the residue was subjected to Tallash chromatography. Purification by chromatography (eluent: 3% ethyl acetate-hexane) yielded 0. 43g ( 2-chloro-4-medyru-6-[4-(1-methyl-1- [4-methoxyphenyl]ethyl-phenoxy-1,3,5-triazine is 6 5. 0-67. Obtained as pale yellow crystals with a melting point of 5°C. product element The analysis was as follows: Analysis: C2°H2oC! N302 s word I Calculation ffi: C, 64, 95: H, 5, 45: N, 11. 36 actual measurements: C, 64, 58: H, 5, 57: N, 11. 25 This compound is reduced to It is called Compound 188. Implementation example CX [[ 2,4-dichloro-6-(4-(chlorphenylsulfonyl)J phenoxy-1 , 3,5-triazine production A: Production of 4-chlorophenyl 4-hydroxyphenylsulfone 100d dime 28. in chilsulfoxide. 7 g (0, i mol) of bis(4-chlorophenyl) 15I11! into a stirred solution containing the sulfone while heating the reaction mixture to 40°C! of 13. Underwater. A solution containing 3 g (0.23 mol) of potassium hydroxide for 10 minutes Added with. The reaction mixture was then heated at 105°C for 5 hours, cooled to room temperature, and heated for 3 hours. Injected into 00d water. Separate the milky white precipitate and acidify the P solution with HCj. Acidified with HCl 1. Extracted with ether (2x 50d). When the ether is evaporated, 143. 0-146. 4-chlorph with a melting point of 0°C phenyl 4°-hydroxyphenyl sulfone19. 21 (j (0.08 mol) Obtained. Production of xy-1,3,5-triazine Using cyanuric chloride as an acid acceptor, 2,6-ruti 4-Chlorphenyl 4-hydroxyphenyl sulfonate prepared in A in the presence of When reacted with 2,4-dichloro-6-(a-* 1 phenoxy-1,3,5-triazine was obtained. Elemental analysis of the product was as follows: Analysis: 015H80! 3 N303 s Calculated value: C, 43, 24: H, 1, 93: N, 10. 08 actual measurement value: C, 43, 16: H, 2,01 : N, 10. 01 This compound is hereinafter referred to as compound 189. 2. Using cyanuric chloride as the acid acceptor in the same manner as in Example XX■B. 6-Luci Reaction with bis(4-hydroxyphenyl)sulfone in the presence of zine gives 23 Bis[4-(4,6-dichloro-1,3,5-)- with a melting point of 0-235°C riazin-2-yloxy)phenyl] sulfone was obtained. Elemental content of product The analysis was as follows: Analysis: C18H8Cl 4 N604 Calculated value: C , 39, 58: H, 1, 48: N, 15. 39 fruit 11111m: C, 41, 30: H, 1, 73: N, 14. 61 This compound is referred to as compound 19 below. It is called 0. --- (4,6-dichloro/1. -1. 3. 5-1-Ryazin-ζ-yl) (4,6-cy Methoxy21. 3. 5-1-Ryazin-2-yl) Ehrlistop A: 2,4. 6 100In! ! of methanol Inside 12. Add the reaction mixture to a stirred solution containing 0 g (0°30 mol) of sodium hydroxide. 18. While maintaining the reaction temperature at 25-30°C. 5 g (b, io moles) of shea chloride The null was slowly added in portions over an hour. This reaction mixture was heated at air temperature for 2 hours. Stir for hours. The mixture was filtered and methanol was evaporated from the P solution under reduced pressure. The residue is dried under vacuum and crystallized from water to give 2 with a melting point of 122-129°C. ,4. 6-1-listoxy-1,3,5-1-riazine 4,3 g (0,025 mole) ) was obtained. As a result of reverse phase high pressure liquid chromatography analysis, the product Ii! ! The degree was about 75%. Kusaka 11 1.25 ae in methanol. 86g<0. 05 mol) of sodium hydroxide. 2, 4. prepared in A in the solution containing 6-trimethoxy1,3. 5-triazine 4 ．． 0 g (0.02 mol) was added and heated in a far current for 1 hour. After cooling the solution and collecting and drying the white solid, 3. 959 (0.02 mol) of 4. 6-Simethoxy 1,3. Obtain sodium 5-triazine-2-oleate Ta. 4,6-Simethoxy 1,3. prepared in B above. 5-triazine-2-olein Sodium acid (1,59,0,01 mol) 25#II! suspended in acetonitrile. The mixture was cooled in a water bath to 5-10"C. 1. A solution containing 54 g (0.01 mol) of cyanuric chloride was heated to a temperature of 1 The mixture was quenched while maintaining the temperature below 0°C and stirring. Stir the reaction mixture in a water bath. , and slowly warmed to room temperature. After stirring for 16 hours, the reaction mixture was filtered and the solvent was evaporated. Removed. The white solid residue was purified by flashcochromatography (30% ethyl acetate in hexane). ), manufactured by M, 158. It has a melting point of 5 to 160'C (4,6-dichloro (1,3,5-triazin-2-yl)(4,6-simethoxyl) 3. 5- )-Ryazin-2-yl)ether 1. 349 (0,004 mol) was obtained. Elemental analysis of the product was as follows: ? Analysis 2 08 H6012N6 03 calculation l: C, 31, 50: H, 1, 98: N, 27. 55 actual measurement value : C, 31, 74: H, 2, 07: N, 27. 472. 2゛-thiobis( 4,6-dichloro-135-t'7')＞(D''1100m in acetone 10. 30 d of water is added to a stirred solution containing 0 g (0.05 mol) of cyanuric chloride. Inside 3. A solution containing 26 g (0.01 mol) of sodium sulfide nonahydrate was It took 0 minutes to add. During this time, the temperature of the reaction mixture was maintained at 0-5°C by external cooling. The reaction mixture was stirred for 15 minutes at 0-5°C and 150 IR1 of ice water was added. A white precipitate formed which was immediately taken apart and dried. Is the crude product produced by sublimation under reduced pressure? Remove unreacted cyanuric chloride from When crystallized, 2,2゛-thiobis(4,6-dichloro-1,3,5-triazine) was obtained as a white solid with a melting point of 140-145°C. high pressure liquid chromatography As a result of graphical analysis, the purity of the product was 75%. Infrared analysis of the product follows It was as follows: IR (CHCj!3): 1500. 1240. 850cm-'Mass Spec Torr analysis showed II/e-330 (calculated molecule m 329. 98 ). This compound is hereinafter referred to as compound 192. 20. 29 (0.11 mol) of cyanuric chloride, 18. 49 (0.22 mol ) of sodium bicarbonate, 100ml of methanol and 125ml of water was added to the chamber. Stir at room temperature for 40 minutes, dilute with 100 d of water and discard the resulting solid. white solid When dried under reduced pressure, 2,4-dichloro-6-medoxy 1 with a melting point of 88-90°C ．． 3. 5-triazine 13. 49 (0.08 mol) was obtained. 2,919 (0,02 moles) of 4,6-simethoxy 1,3. 5-1-Ryazine-2-oleate sodium Add the 2゜4-dichloro-6-medium prepared in A to the stirred suspension in which LiCl was suspended. Sea 1. 3. 5-triazine2. 93 g (0.02 mol) were slaked. reaction mixture Distant current heating of the material for 488 hours, 1. 177 (0,003 mol) of dibenzo-18- After adding Crown-6, the mixture was heated under reflux for an additional 48 hours. Rei IJl u, 75 diluted with methylene chloride and filtered. After evaporation of the solvent, the residue is flash-chromatographed. Purification by chromatography (eluent 20% ethyl acetate in hexane) yields 12 It has a melting point of 65-128°C (4-chloro-6-medoxy 1,3°5-tri Azin-2-yl) (4,6-cy-medoxy 1. 3. 5-triazine-2- il) ether 1. 60 g (0,005 mol) were obtained. Elemental analysis of the product is It was as follows: Analysis: C9H9C1N604 Calculated value: C, 35,95; H, 3,01: N, 27. 95 Actual value: C , 35, 92; H, 3, 12: N, 28. 08 This compound is referred to as Compound 1 below. It is called 93. Example CX■ 2-Chlor-4,6-simethoxy1. 3. Production of 5-t-lyazine 18. 5g (0.10 mol) of cyanuric chloride, 16. 89 (0.20 mol) of sodium bicarbonate A mixture of thorium, 57m methanol and 5d water was vigorously stirred and the reaction temperature Carbon dioxide evolution was observed as the temperature increased to about 40°C. 20 minutes later diacid When the evolution of carbonization subsided, the reaction mixture was heated to reflux for 30 minutes. mixture 10. Cool and dry the product and crystallize the crude product from cyclohexane. 0 7 Analysis: C5H6ClN302 Calculated values: C, 34, 2, 0: H, 3, 44: N, 23. 93 actual measurement value: C, 34, 14; H, 3, 60: N, 23. The compound in 9 is the following compound 1 It is called 94. Implementation example cxrx ’2>Tate 11 75Id in CHCl3. 6V (0,008 mol) of N-(2,4-dimethyl lorphenyl) -N'-(4,6-dichloro-1,3,5-t-riazine-2 -yl) hydrazine-containing solution and 4 Otori Teraro 1. 34g (0.02 mol) A stream of chlorine gas was passed through the two-phase mixture with the liquid containing NaHCO3 for 10 minutes. The mixture is then bubbled with nitrogen to remove excess chlorine, the isotropic phase is separated, and water is added. Wash and dry over anhydrous MQSo4.2. 4g of dark red solid was obtained. This is 1 ．． 0 g (0,003 mol) of N-(2,4-dichlorophenyl)-N-(4,6 -dichloro-1,3,5-triazin-2-yl) and dorazine. 980 ml of product prepared according to the same reaction as described above were combined. Dissolve the combined product. Flushing of silica gel using 9:1 v/v hexane-ethyl acetate as solvent Chromatography on mtA gave the crude product as a red solid. this The crude product is recrystallized from hexane and the resulting material is sublimed to 0. 91g ( 0,003 mol) of 6-(2,4-dichlorophenylazo)-2,4-dichlor -1,3,5-triazine was obtained as a red solid with a melting point of 119-123°C. It was done. The elemental analysis of the product was as follows: Analysis: C9H3C14N 5 Calculated values: C, 33,47; H, 0,94; N, 21. 68 Actual value: C , 32,95: )-1, 0,97: N, 21. 142-(4-methoxy phenyl)-4,6-dichloro-1,3,5-triazine 1 Cyanuric chloride was subjected to the Grignard assay of 4-bromoanisole in the same manner as in Example XL. When reacted with drugs, 136. 5-138. 2-(4-methoxy) having a melting point of 5°C Cyphenyl)-4,6-dichloro-1,3,5-triazine was obtained. product The elemental analysis of was as follows: Analysis: C1゜H7C12N30 Calculated value: C, 46,90: H, 2,76; N, 16. 41 Actual value: C , 46, 76: H, 2, 78: N, 16. 29 This compound is referred to as compound 1 below. It is called 96. (Margin below) Execution - Ichizu Other compounds were prepared similarly to Example CXX. Structure of plants 197-199 The construction and analytical data are shown in Table P below. Table P Representative nitrogen-containing heterocyclic compounds I (J Implementation example cxxm 2-[(2-phenoxy)ethoxy-4,6-dichloro-13,5-triazine standing n Using 2-phenoxyethanol as the acid acceptor in the same manner as in Example xxxm, When reacted with cyanuric chloride in the presence of 6-lutidine, it has a melting point of 81-83°C. 2-[(2-phenoxy)ethoxy]-4,6-dichloro-1,3,5-to Reazine was obtained. Elemental analysis of the product was as follows: Analysis: C41 day 9012 N302 calculated value: C, 46, 17: H, 3, 17: N, 14. 69 actual measurement value: C, 4G, 41: H, 3,44S N , 14. 68 This compound is hereinafter referred to as compound 200. Implementation example cxxm 2-(2-(2,4-dichlorophenoxy)ethoxy)-4,6-dichloro-1 ゜3,5-　-Production of riazine A: Preparation of 2-(2,4-dichlorophenoxy)ether 2. 4 To a solution containing 4 g (0.66 mol) of Na0)-1, to, C9 (0.06 mol) ) was quenched with 2,4-dichlorophenol. Then 4. 8d (0.07 mol ) of 2-bromoethanol was added and the mixture was heated at a temperature of 60 °C for about 16 hours. Ta. After cooling, the reaction mixture was washed with diwater and dried over MgSO4. , concentrated under reduced pressure. When reduced, 8. 02 g (0.04 mol) of 2-(2,A-dichlorophenoxy) Ether was obtained. NMR analysis of the phenol intermediate was as follows: 1HNMR (CDCj3): δ2. 73 (+e, H), 3. 7-4. 4h+, 48). 6, 97 (d, H, J-8112), 7. 47cd, )l, T, 3H gi). 7. 33 (dd, H, J-3,8Hz) ppm Salt in the same manner as Example XXXM 2. Cyanuric acid as an acid acceptor. 2-( prepared in A in the presence of 6-lutidine 103-104 when reacted with 2,4-dichlorophenoxy)ether. 5℃ 2-[2-(2,4-dichlorophenoxy)ethoxy]-4,6 with a melting point of -dichloro-1,3,5-triazine was obtained. The elemental analysis of the product is as follows. Analysis 2 011H7014N302 Calculated value: C, 37, 21: l(, 1,99; N, 11. 84 actual measurement value: C, 37, 06: H, 2, 19; N, 11. 73 This compound is called the following compound It is called 201. Implementation example cxxrv 2-[(2,4-dichlorobenzyloxy)ethoxy-46-dichloro-1,j , 5-t-reazi and standing room 1 5. To a slurry containing 125 g of neutral alumina in 125 d of ether; 0 g (0.03 mol) of 2,4-dichlorobenzyl alcohol and 62. 51111 ! ! (0.12 mol) of ethylene oxide in 2H ether was added. this The mixture was stirred at air temperature for about 16 hours, poured into 500 d of methanol, and left for 6 hours. I placed it. When the alumina is separated from each other, washed with methanol, and the P solution is concentrated under reduced pressure, 9. The crude product of 26 (J) was obtained as a transparent liquid. 09 ( 0.01 mol) of 2,4-dichlorobenzyl alcohol was used. Flush using hexane-ethyl acetate (1:1 v/v) as the same eluent. When purified with Shuchromadografi, 1. 1 (0,006 mol) of 2-( 2,4-dichlorobenzyloxy)ethanol was obtained as a colorless liquid. child The NMR analysis of the intermediate was as follows: 'HNMR (CDCj3): δ2. 47 (br, s, H). 3. 5-4. 0 (m, 4H). 4. 60 (s, 211), 7. 1-7. 6 (+e, 311) 00m Using cyanuric chloride as an acid acceptor in the same manner as in Example XXXII, 2-(2,4-dichlorobenzyloxy)ethanol prepared in A in the presence of When reacted with 2-(2-(2,4-dichlorobenzyloxy)ethoxy]- 4,6-dichloro-1,3,5-triazine was obtained as a colorless oil. Generate The elemental analysis of the object was as follows: Analysis 2 CH014N302 Measurement value: C, 39,05 nido 1. 2. 46: N, 11. 39 Actual measurement value: C, 39, 82: H, 2, 55: N, 11. 32 This compound is called the following compound It is called 202. 2,4-dichlorophenol was used as the acid acceptor in the same manner as in Example cxxm A. reaction with 2-(2-chloroethoxy)ethanol in the presence of sodium hydroxide 2-[2-(2,4-dichlorof')lNMR('CDCj3): δ 2. 83 (br, s, H). 3. 5-4. 0(m,6)1). 4. 1-4. 4 (a, 2 old. 6. 83 (d, H, J=211Z). 7. 20 (dd, H, J-2, 8H2). 7. 37(d,H,J,,2H2)pf) II Chloride as in Example xxxu 2-[2 -(2,4-dichlorophenoxy)ethoxy] When reacted with ethanol, 59 , 5-61. 2-(2-[2-(2,4-dichlorophenokyl) having a melting point of 5°C c)ethoxy]ethoxy)-4,6-dichloro-1,3,5-triazine is obtained. It was. The elemental analysis of the product was as follows: Analysis: 013H11C! 4 N3 o3 calculated value: C, 39, 12: H, 2, 78: N, 10. 5 3 actual measurement values: C, 38, 65; l-1, 2, 76: N, 10. 71 this transformation The compound is hereinafter referred to as compound 203. Example CXXVI 2-4-24-dichlorophenyl butoxy-46-dichloro-1゜Example XL 2,4-dichlorophenethyl alcohol prepared in VIII 30. 19 (0, A mixture of 16 mol) and 140 d of 48%)-IBr aqueous solution was heated under reflux for 5 hours. . After cooling, the mixture was partitioned between ether and water and the ether layer was dissolved in saturated NaHC. Extract with O3 aqueous solution, dry with MQS O4, and concentrate under reduced pressure to obtain a brown liquid. was gotten. When this is distilled into ugelrohr, 29. 7 g (0.12 mol) of 2-( 2,4-dichlorophenyl)ethyl bromide is 0. 7 at 025aIIIJl Obtained as a colorless liquid with a boiling point of 0°C. The NMR analysis of this intermediate is as follows. It was as follows: 'HNMR (CDCj3): δ3. O-3,8 (1,411). 7. 0-7. 4 (m, 311) ppm Add the 2-(2,4-di-2-(2,4-di- Magnesium is consumed after slaked a solution containing chlorophenyl)ethyl bromide. When the yellow solution of Grignard reagent was added to 30 m tetrahydrofuran 1. 9g ('0. After stirring the mixture for 5 minutes, the 35d tetrahydrofuran Orchid was added. The mixture was further stirred for 5 minutes and 35d (0.07 mol) of 2M ethylene oxide was added. The cid solution was quenched. The reaction mixture was stirred at 0 °C for 2 h and at air temperature for 1 h, and the Sod Cooled to 0 with water. The volume was reduced under vacuum, concentrated under reduced pressure, and the resulting liquid was poured into a silica gel. When treated with chromatography, 2. 37 g (0.01 mol) of 4-(2, 4-Dichlorophenyl)butan-1-ol was obtained as a pale yellow liquid. this NMR analysis of the intermediate was as follows:') I NMR (CDCj3): δ 1. 43-[83(m, 4H). 2. 53-2. 90 (m, 311). 3, 50-3. 77 (n+, 2H); 7. 07 (+e, 2H). 7. 33(1,)I)IIpIII 2,6-lutidine using cyanuric chloride as an acid acceptor in the same manner as in Example xxxu. +L-(2,4-dichlorophenyl)butan-1-o prepared in B in the presence of When mixed in a similar manner, 2-[4-(2,4-dichlorophenyl)butoxyl-4 , 6-zik 0 ru 1. 3. 5-triazine was obtained as a pale yellow oil. Generate The elemental analysis of the object is as follows. Calculated values: C, 42, 53: H, 3, 02; N , 11. 45 This compound is hereinafter referred to as compound 204. Implementation example CXX■ 24i7 and 亙J三りと之l 3,5-dimethylphethoxy)-1゜Rainbow and E ship Enodate 13e 2. Using cyanuric chloride as an acid acceptor in the same manner as in Example. Presence of 6-lutidine Below 2. When reacted with 4-dichloro-3,5-dimethylphenol, 118- 2,4-dichloro-6-(2,4-dichloro-3,5- Dimethylphenoxy)-1,3,5-triazine was obtained. Elemental analysis of products was as follows: Analysis 2 011H7C14N30 Calculated value: C, 38,97: H, 2,08; N, 12. 39 Actual measurement value; C , 39, 18: H, 2, 25: N, 12. 47 This compound is referred to as compound 2 below. It is called 05. , Example CXX■ The pond compound was prepared analogously to Example CXXVI. water loss from plants Structures and analytical data of compounds 206 to 210 used in Examples below to reduce The data are shown in Table Q below. JL--Yushi I Implementation example cxxrx Similar to Example xxxvr, cyanuric chloride was added to sodium bicarbonate as the acid acceptor. has a melting point of 60-62 °C when reacted with acetone oxime in the presence of A, 7 tons 0-(4,6-dichloro-,--'=--"-1,3,5-tri Azin-2-yl)oxime was obtained. The elemental analysis of the product was as follows : Analysis 2 06 H6C12N40 Calculation Ml: C, 32,60; H, 2,74; N, 25. 35 Actual measurement value: C, 32, 24; H, 2, 90; N, 25. 28 This compound is combined as follows What is the name of thing 211? Implementation example cxxx Other compounds were prepared analogously to Example LXXI[I. water loss from plants Structure and composition of compounds 212 and 213 used in the examples below to reduce The analytical data is shown in Table R below. Table'R Representative nitrogen-containing heterocyclic compounds C.I. C.I. Implementation example CXXVI - Example L XXI of potassium fluoride was added at 0°C. After stirring the reaction mixture for 30 minutes, saturated aqueous chloride was added. Aqueous ammonium solution was added and methanol was evaporated under vacuum. Aete the residue The ether solution was dried with MQSO4, filtered and evaporated to give 10 2-chloro-4-ethynyl-6-medoxy with a melting point of 8-110°C1. 3 ．． 5-t-reagin 0. 33 g (0,002 mol) were obtained. product element The analysis was as follows: Analysis: C6H4CI N’30 Calculation (if: C, 42, 50: H, 2, 38: N, 24. 78 actual measurements Value: C, 41, 58: H, 2, 29: N, 23. 91 This compound is shown below. It is called compound 214. Implementation example CXXX■ Other compounds were prepared similarly to Example LXI. Reduces water loss from plants Structural and analytical data of compounds 215 to 217 used in the examples below to are shown in Table S below. Table S Representative nitrogen-containing heterocyclic compounds N I Implementation example cxxxm ζ, A22-KuU↓2p2Z22dan9F1no1JinjiNfuShu"E2,L5-≦pass Knee 1±91-2, nr-figure Similarly to Example LXXrV, cyanuric chloride was used as an acid acceptor for sodium hydroxide. When reacted with benzenesulfonamide in the presence of 2,4-dichloro-6-phenylsulfonamide-1, ÷ 1. 3 ．． 5-1-Ryazine was obtained. The elemental analysis of the product was as follows: 2 CH012N40□S Calculation (!I: C, 35, 42; H, 1, 98: N, 18. 36 actual measurements : C, 35, 04: H, 2, 32: N, 18. 09 This compound is made into the following It is called Compound 218. Implementation example cxxxrv 2-Chlor-4-(2,4-dichlorophenoxy)-6-hexafluorotube Roboxy 1. 3. Preparation of 5-)-Riazine 5. in 100 m of acetone. 0g( 0.02 mol) of 2,4-dichloro-6-(2,4-dichloro-6-(2,4-dichloro) prepared in Example 2) 1. rufenoxy)-1,3,5-torian. 9d (0.02 mol) of hex A solution containing safluoroisopropyl alcohol was added. (7. Mixture The mixture was heated with distant current for 10 hours and dried under vacuum F (7 hours).The residue was blown onto silica gel. Apply rush chromatography, first add 5% vinegar 11, 'I ethylhexane. solution and then with 15% dichloro[]methane in hexane. 1j, 34! ? (0,0035 mol) of 2-chloro-4-(2,4-dichloro phenoxy)-6-hexafluoroitubroboxy, 1,3. 5-triazine was obtained as an oil. Elemental analysis of the product was as follows: Analysis: CHC13F6 N302B1 calculated value: C, 37, 38: H, 1 , 05: N, 10. 90 actual measurement value; C, 32, 52: H, 0, 89: N , 9. 48 This compound is hereinafter referred to as compound 219. Implementation example cxxxv 2-chloro-4-(1:i)-6-(2,2,2-trifluoroethoxy) '-135-t-Riazine J1 2,4-dichloro-6- prepared in Example ■ in the same manner as Example cxxxrv. 2. Using (1-naphthoxy)-1,3,5-triazine as an acid acceptor. 6-Luci In the presence of gin 2. 2. When reacted with 2-trifluoroethanol, 2-chloro Ru-4-(1-naphthoxy)-6-(2,2,2-trifluoroethoxy”) -1,3,5-triazine was obtained as an oil. The elemental analysis of the product was as follows: Analysis: C1, H19Cj FN3 02 calculated value: C, 50, 65: l-(, 2, 55: N, 11. 81 fruit a 1! ! (a: C, 51, 04: H, 2, 75; N, 11. 53 this The compound is hereinafter referred to as compound 220. Example cxxxvr 2-chloro-4-(24-dichlorophenoxy)-6-ethoxy1. 3. 5- Two animals, two, two l] Inside 3. 179 (0.02 mol) of bromoacetaldehyde diethylacetate A solution containing 100 mg of chlorine was added. The resulting mixture was stirred at room temperature for 1 hour @ s, og (0 , 02 mol) of 2. 4-dichloro-6-(2,4-dichlorophenoxy)-1, The solution containing 3,5-triazine was quenched. The resulting mixture was heated at room temperature for about 16 hours. Stir and evaporate to dryness under vacuum. The residue was flash chromatographed on silica gel with 5% ethyl acetate. When eluted with a hexane solution of 1.9 g (0.01 mol) of 2-chloro-4- (2,4-dichlorophenoxy)-6-ethoxy1. 3. 5-triazine is oil It was obtained as a solid substance. Elemental analysis of the product was as follows: Analysis 2 CHC1!3 N302 Calculated values: C, 41, 22: H, 2, 51: N, 13. 11 Actual measurement value: C , 41, 24: l-1, 2, 50: N, 12. 75 Combine this compound with the following It is called object 221. 5. in 100d of acetone. In a solution containing 0 g (0.03 mol) of cyanuric chloride , first 3. at 4℃. 2 of 16d (0.03 mol). Add a solution containing 6-lutidine. 2. in acetone for 150 d after heating. 60d (0.03 mol) of 2. 2. 2-Tori A solution containing chloroethanol was added. The mixture was stirred at room temperature for about 16 hours until the solution The medium was removed. The residue was partitioned between water and ethanol and the organic phase was dissolved in anhydrous sodium sulfate. After removing the solvent, flash chromatograph the residue on silica gel. Purified with roughy. When eluted with ethyl acetate-hexane, 1. 19 (0, 004 mol) of 2. 4-dichloro-6-(2,2,2-trichloroethoxy)- 1,3,5-triazine was obtained as yellow crystals with a melting point of 72-73 °C. . The elemental analysis of the product was as follows: Analysis: CH015N3. Calculated values: C, 20, 20: H, o, ea: N, 14. 13 Actual measurement value; C , 20, 19; H, 0, 68: N, 14. 48 This compound is referred to as compound 2 below. It is called 22. ”'m　　　Ⅱ　CXXXW 24i ri” 2-snoring B 2-bifurcated-methylpyrrolyl, 5-triadiZ-dark 2. 4 m (0,03 mol) of tomethylvirol, s, og (0,03 mol) A mixture of cyanuric chloride and 50d p-dioxane was heated to reflux for 5 hours. reaction The mixture was poured into water and the precipitate formed was collected by suction filtration and dried. Hexa When crystallized from 2. 07 (0.01 mol) 2. 4-dichloro-6-[2 -(N-methylpyrrolyl) 1-1. 3. 5-1-Ryazine at 153-154℃ Obtained as pale yellow crystals with melting point. The elemental analysis of the product was as follows :Analysis:CHCj! 2 N4 gl Calculated value: C, 41,95; H, 2,64: N, 24. 46 actual measurements: C, 42,00: H, 2,73; N, 24. The compound in 4 is the following compound It is called 223. Implementation example cxxxrx N-(4,6-dichloro-1,3,5-t-riazin-2-yl)-2-oxo Production of hexamethyleneimine 10. in oil. 09 (0.09 mol) of potassium hydride in a suspension, First 200a at -60℃! ! 10. After adding dry tetrahydrofuran. 0g<0 ．． 09 mol) of ε-capro fraction was added. Heat the mixture to air temperature for 1 verse. 16. in 100ad of tetrahydrofuran after stirring. 3g (0.09 mol) of A solution containing cyanuric chloride was added and stirred for an additional 2 hours. Vacuum evaporate the reaction mixture and the residue was purified by flash chromatography to obtain 1. 2g (0,0 05 mol) of N-(4,6-dichloro-1,3,5-triazin-2-yl)- 2-oxohexamethyleneimine was obtained as an oil. The elemental analysis of the product was as follows: Calculated value: C, 41,40; H, 3, 86: N, 21. 46 actual measurements: c, ao, ss; H, a', 4o: N, 21. 01 This compound is hereinafter referred to as compound 224. Example CXL 2-pyrrolidinone was reacted with potassium hydride in the same manner as in Example cxxxrx. , when the obtained potassium salt is reacted with cyanuric chloride, the melting point is 192-194 °C. N-(4,6-dichloro-1,3゜5-triazin-2-yl)-2- Oxotetramethyleneimine was obtained. The elemental analysis of the product was as follows :Analysis 2 C7H6C12N40 Calculated values: C, 36,07; H, 2,60; N, 24. 04 Actual measurement value; C , 35, 86; H, 2, 54: N, 24. 01 This compound is referred to as compound 2 below. It is called 25. Implementation example CXLI Also, Yum on the top of the mountain, ``2'', 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 2, 6, 6, Zabicyclo 3. 2. 1 Octane and 2,4-bis(1,3゜3-trimethyl -6-aza-bicyclo(3,2,mo-octane-6-yl)-6-Loru 135- Manufacture of triazines 1, 3 in the same manner as Example cxxxxrx. 3-trimethyl-6-azabicyclo[ 3,2,1]octane is reacted with potassium hydride, and the resulting potassium salt is chlorinated. When reacted with cyanuric, N-(4,6-dicyclopentane) with a melting point of 133-135 (roll-1,3,5-triazin-2-yl)-1,3,3-trimethyl-6-a Zabicyclo[3,2,1]oc, tan and 161. Has a melting point of 5-163℃ 2,4-bis(1,3,3-trimethyl-6-aza-bicyclo) ctane-6-yl)-6-chloro-1,3,5-triazine was obtained. 2 types The products were separated by flash column chromatography. Elements of two products Analysis and NMR analysis were as follows: N-(4,6-dichloro-1,3,5-triazin-2-yl)-1,3,3- Trimedel-6-aza-bicyclo [3, 2, octane analysis: Cl2H1 8C12N3 Calculated values: C, 51,83: H, 6,02: N, 18. 60:Cff1 , 23. 54 Actual measurement I: C, 51,82: H, 5,81: N, 18. 47;CI , 23. 78 This compound is hereinafter referred to as compound 226. 1. 10 (s, 6H). 1. 30-2. 30 (m, 12H). 2. 90-3. 70 (m, 4 old. 4. 30-4. 68(m,2H)11pm This compound is hereinafter referred to as compound 227. Ru. Implementation example CXLII 4. 6-dichloro-2-(3-phenylphenoxy)-1,3,5-triazine 1 Cyanuric chloride was used as an acid acceptor in the same manner as in Example X. When reacted with 3-phenylphenol in the presence of 4,6-dichloro-2-(3-phenylphenoxy)-1,3,5- t-Ryazine was obtained. Elemental analysis of the product was as follows: Analysis: C15H9N30 Calculated values: C, 56, 63: H, 2, 85: N, 13. 21; Cj, 22. 29 Actual value: C, 56,33; H, 3,29: N, 13. 15: CI! , 21. 55 This compound is hereinafter referred to as compound 228. Fruit eggplant example CXLI[I 2. Production of 3-cycloroot (2-chloroanilino)maleimide 4. 7g (0, A stirred mixture of 03 mol) dichloromaleic anhydride and 20 d acetic acid was heated at 100°C. and heated for 45 minutes. A precipitate forms when the mixture is cooled to room temperature and the water is slaked. It was. Separate the first crop or product by P A second product was obtained after slow evaporation of the mother liquor and filtration. Two types of generation When you put things together, 5. 559 (0.02 mol) of 2. 3-cycloroot (2-cycloroot) Loranilino)maleimide is obtained as yellow crystals with a melting point of 137-138°C. It was done. The elemental analysis of the product was as follows: Analysis: C1oH5Cfl 3 Other compounds were prepared in the same manner as N202 Example CXLI [. Is it a plant? Compounds 230 to 250 used in the Examples below to reduce water loss in The structure and analytical data are shown in Table T below. Table T Representative nitrogen-containing heterocyclic compounds Table ■ (continued) Table T (continued) Representative nitrogen-containing heterocyclic compounds Substituent elemental analysis Actual example CXLV Preparation of 6-hydroxy-2-phenyl-3(2-old pyridazinone 10mf!(0, 10 mol) of phenylhydrazine, 10 g (0.10 mol) of maleic anhydride and 75 m acetic acid was heated to reflux for 6 hours. Cool the mixture to room temperature 10. 62 g (0.05 mol) of 6-hydro xy-2-phenyl-3(28)pyridazinone has a melting point of 262°C (decomposed) Obtained as yellow crystals. NMR analysis of the product was as follows:'l+N MR (CDCl2): δ7. 21 (AB, , 28. J-10H2). 7. 50-7. 87(1,5H)l)l)II This compound is hereinafter referred to as compound 251. to be called. 30 m (0.32 mol) of phosphorus oxychloride, 30 g (0.14 mol) of penta-salt Example CXLV of phosphorus chloride and s,og (0,024 mol) was prepared with f-υhydro The stirred mixture of xy-2-phenyl-3(2H)pyridazinone was heated to 160-170°C. and heated for 90 minutes. The mixture was cooled to room temperature and poured into ice water, resulting in a yellow precipitate. was gotten. The crude product was separated into 2-phenyl-3(2+1)pyridazinone. Yellow crystals were obtained with a melting point of 110-111°C. The elemental analysis of the product is It was as follows: Analysis: CHC12N20 Total n 1: C, 49, 33: H, 2, 56: N, 11. 18 actual measurements; C, 49, 69; H, 2, 61: N, 11. 57 This compound is combined as follows It is called object 252. Example CXLVI 6-Production of loru-2-phenyl-3(2H) biridinone2. 09 (0,0 6-hydroxy-2-phenyl-3 (2 A stirred mixture of pyridazinone and 20d (0.21 mol) of phosphorus oxychloride was added to the Heated at 5°C for 2 hours. The reaction mixture was cooled to room temperature and quenched with ice water. 1 hex 6-chloro-2-phenyl-3(2H) mixed with (0,004 mol) Yellow-white crystals of pyridazinone with a melting point of 112-113°C were obtained. product The elemental analysis of was as follows: Analysis: CHC1l! N20 Calculation 1: C, 58, 13: H, 3, 42; N, 13. 56: CP, 17. 16 Actual miff; C, 5g, 10; H, 3, 10: N, 13. 41:( :, l, 16. 47 This compound is hereinafter referred to as compound 253. 18. 8 g (0,09 mol) of 2. 4-dichlorophenylhydrazine hydrochloride and 14. to a mixture of 600 d of 6N hydrochloric acid. 7 g (0.09 mol) of anhydrous dichloromer Leic acid was added. The mixture was heated under reflux for 6 hours and the resulting solid was poured into ice water. When washed with Chlor-6-hydroxy-2-(2,4-dichlorophenyl)-3(2H)pi Ridazinone7. 69 (0,023 mol) was obtained. Elemental analysis of the product follows It was as follows: Analysis: C1oH4Cg 4 N202 total R (a 2 C, 36,85:H, 1,24:N, 8. 59 actual measurement value: C, 36, 69: H, 1, 37: N, 8. 44 This compound is hereinafter referred to as compound 254. In the same manner as in Example CXL■, 0-chlorophenylhydrazine oxalate was added to anhydrous dichloromethane. When reacted with roromaleic acid, the 4,5-dichloromethane Rol-6-hydroxy-2-(2-chlorf was as follows: Analysis: 01°N5 Cp 3 N202 calculation fji: C, 41, 20: H, 1, 73: N, 9. 61 actual measurement value; C, 41,19; H, 1,97 : N, 9. 60 This compound is hereinafter referred to as compound 255. Implementation example CL 45-dichloro-6-biloxy 2-(34-dichlorophenyl)-3(2H) Production of pyridazinone 7. 5 g (0.03 mol) of 3,4-diphenylhydrazine hydrochloride. 5. 09 (0.3 mol) of dichloromaleic anhydride and 100af! of glacial acetic acid The stirred mixture was heated to reflux for 2 days. A yellow-orange color formed by cooling the mixture to air temperature. The crystals were isolated. When you suction the crystal, 241-242. has a melting point of 5°C 4,5-dichloro-6-hydroxy-2-(3,4-dichlorophenyl) - 3 (2t pyridazinone 2. 87 g (0.01 mol) were obtained. product element The analysis was as follows: Analysis: C1oH4Cp 4 N202 calculated value: C, 36, 85:)- 1, 1, 24: N, 8. 59 actual measurement fU: C, 36, 47: H, 2,07 ; N, 7. 49 This compound is hereinafter referred to as compound 256. Implementation example CLI 2. 3-dichloro-N-(2-methylanilino)maleimide and 4,5-silol -6-Hydroxy-2-(2-methylphenyl-3(2H bilidinohydrochloride) When reacted with romaleic acid, 2,3-dichloro with a melting point of 146-149 °C -N-(2-methylanilino)maleimide and 234-235. Melting point of 5℃ 4,5-dichloro-16-hydroxy-2-(2-methylphenyl)-3 (2H) Pyridazinone was obtained. Recrystallization of two products from methylene chloride and separated. Elemental analysis of the two products was as follows: 23-dichloro-N-(2-methylanilino)maleimi. Analysis: C11H8Cpl 2 N202 calculated value: C, 48, 73;) l, 2. 97: N, 10. 33 actual measurement m: C, 48, 64:) I , 3. 12: N, 10. 23 This compound is hereinafter referred to as compound 257. 45-shi’) O-ru 6-he o-t-shi 2-(2-methylene x 2)’v) -3 (2H) Bi'JJ-Shibano 1 Analysis: CHC12N2 o2 Calculated value: C, 48, 73; H, 2, 97: N, 10. 33 actual measurements @: C, 48, 29: H, 3, 06: N, 10. Compound 1 below is compound 2 It is called 58. Example CLII 456-Dolichloro-2-24-dichlorophenyl)-3(2H) viridasi/ ) exemption l1 3. 7jJ (0.02 mol) of phosphorus pentachloride, 37jIi! (0.4 mol) of Phosphorus oxychloride and 7. 69 (0,023 mol) Example CXL■ 4,5-dichloro-6-hydroxy-2-(2,4-dichlorophenyl)-3( A stirred mixture of two former pyridazinone was heated at 160-170°C for 14 hours. blend Cool to air temperature and add a small amount of hexane to ice while stirring to promote precipitation. injected into water. Filter the crude product, wash with ice water and flash on silica gel. It was purified by chromatography. It was eluted with 5% ethyl acetate and hexane solution. , 154-155. 4,5. having a melting point of 5°C. 6-Dolichlorou 2-(2,4 -dichlorophenyl”)-3(2H)pyridazinone 0. 85g<0. 0025mo ) was obtained. The elemental analysis of the product was as follows: Analysis: C1oH 3C15N20 Calculated values: C, 34, 88: H, 0, 88: N, 8. 13 Example CLII and Other compounds were produced in the same manner. After to reduce water loss from plants The structures and analytical data of compounds 260 to 264 used in the examples are shown in the table below. vinegar. Front mouth Representative nitrogen-containing heterocyclic compounds Implementation example CLIV 2. Production of 3-dimedylene N-(2-chloroanilino)maleimy7. 1g (0 , 04 mol) of 0-chlorophenylhydrazine hydrochloride. 5. 09 (0,oa mol) of 2,3-dimethylmaleic anhydride and 25d of acetic acid The stirred mixture was heated at 100° C. for 11 hours. Cool the reaction mixture to room temperature and add water. A precipitate formed upon quenching. Separate the precipitate from house to house, cool the P solution, and solidify the resulting product. Separated as a body. When the solid is crystallized from methylene chloride-hexane, 2. 39 (0.01 mol) of 2. 3-dimethyleth(2-chloroanilino)maleimide is 115-117. Obtained as an orange-colored fine product with a melting point of 5°C. source of product The elementary analysis was as follows: Analysis: Cl2H11Cp N202 calculated value: C, 57, 49;) l, 4. 42: N, 11. 17 actual measurement value: C, 57, 49: H, 4, 32; N, 11. 15 This compound is hereinafter referred to as compound 265. Implementation example CLV Other compounds were prepared similarly to Example LXXXIII. water loss from plants Structures of compounds IIIJ266-267 used in the Examples below to reduce loss and analysis data are shown in Table ■ below. -Table 2--N2 Superficial nitrogen-containing heterocyclic compounds Implementation example CLV’1 Aldrich N-hydroxymaleimide with a melting point of 133-135°C Chemical Company and its reverse phase HP without purification. Octatool/water log P by LC: 0. 00This compound is the following compound It is called 268. 4,5-dichloro-6-hydroxy-2-(3-trichloro) with a melting point of ~172°C. Fluoromethylphenyl)-3(28)pyridazinone was obtained. The elemental analysis of the product was as follows: Analysis 2 011H5CI! 2 F3 N202 calculated value: C, 40, 64: H, 1, 55: N, 8. 62 actual measurement value : C, 40, 55: H, 1, 50: N, 8. 61 This compound is called the following compound It is called 269. Implementation example CL ■ Other compounds were prepared in a similar manner to Example CXLI [[. Plants - Table 111 Table 1 Representative nitrogen-containing heterocyclic compounds Implementation example CLrX 4. 5. 6-) To stop the fall of one's own beggar store LA: 2- Methyl-4. 5-dichloro-6-hydroxy-3 (2■bi1 dinon!) 1 yuan Methylhydrazine was converted to HC! in the same manner as in Example CXL■. ! Anhydrous dichloride in aqueous solution When reacted with romalein, 2-methyl-4 has a melting point of 229-230°C. ,5-dichloro-6-hydroxy-3(211)pyridazinone was obtained. B: 2-Methyl-4,5,6-dolychloro-3 (2-former pyridazinone production 3, o g (0.02 mol) of 2-methyl-4,5-dichloro-6-hydro prepared with A A solution was obtained of a mixture of xy-3(2H)pyridazinone and 20m phosphorus oxychloride. The excess phosphorus oxychloride was evaporated under reduced pressure. Put the residue in ice water After soaking and stirring the mixture for 1 hour, a slurry of puff-colored solids was obtained. child The solid of Chill-4,5,6-dolychloro-3(2H)pyridazinone 0. 6g (0,003 mole) was obtained. This compound is hereinafter referred to as compound 276. Actual journey example CLV 33. in 160m absolute ethanol. Contains 6 g (0.2 mol) of Mucochlor V acid 6. Add 20ml of ethanol to the refluxing solution. 79 < 0. 2 moles) and 95% of The solution containing Radin was added slowly. After the addition, reflux was continued for 2 cycles and the mixture was After cooling, the resulting solid was separated from P and air-dried to produce 4, which has a melting point of 193-194°C. , 5-dichloro-3(2+1)pyridazinone24. 4 g (0.15 mol) was obtained It was. B: 2-benzyl-4,5-dichloro-3 (2N) t: 12% 16. 6 g (0.04 mol) of 4,5-dichloro-3(2H) viridazino prepared with A 9. 17 (0.08 mol) benzyl chloride, 209 (0.14 mol) of potassium carbonate and 120 d of N,N-dimethylformamide at 40 to Upon heating at 90° C., a gel-like mixture was formed. The mixture was acidified, extracted with ether/acetone, and filtered to give a brown solid. It was. The P solution was partitioned between ether and water, and the ether phase was dissolved in 10% sodium carbonate solution and Wash with water and 0. 5 g (0,002 mol) of 2-benzyl-4,5-dichlor -3(2H)pyridazinone was obtained as white crystals with a melting point of 81-82 °C. Ta. This compound is hereinafter referred to as compound 271. Implementation example CLX work Production of 2-0-rorobe 2-45-dichloro-3(2H)pyridinone 3. 49 (0.02 mol) of mucochloric acid, s, tg (0.02 mol) of O- At 6 o'clock, a mixture of 1 rubenzylhydrazine sulfate and 5 Qd of absolute ethanol was added. The mixture was heated in rapid flow. 3. Cool the mixture and collect the precipitate formed and air dry. 8g<0. 01 mol) of 2-(O-chlorobenzyl)-4,5-dichloro-3( 2-old pyridazinone was obtained as white crystals with a melting point of 114°C. This compound is hereinafter referred to as compound 278. Implementation f! i+JCLXn Production of 2-chlorout(2-methylphenyl)-maleimide Production of doric acid A warm mixture of 132 g (1.0 mol) of chloromaleic anhydride and xylene was stirred and While heating at 70°C, add 1079 (1.0 mol) of 2- Methylaniline was added slowly. After the addition of 2-methylaniline is complete, the reaction mixture is The mixture was stirred at 70°C for 1 hour. Cool the mixture, separate the solids, add xylene, When washed with xane and dried at air temperature, the 2-(or 8- g (0.10 mol) of sodium acetate and 95. Made with 0 g (0,,40 mol) of A 2-(or 3-)chloro-N-(2-methylphenyl)maleamic acid to the stirred mixture of 122. 07 (1.2 mol) of acetic anhydride was added at air temperature to obtain The resulting mixture was stirred and heated at 80'C for 40 minutes. The reaction mixture was then heated to 25°C. and poured into 2 tons of ice water. The mixture was extracted with 600 d of ethyl ether. , the ether extract is distilled through an unpacked column 1 foot long, resulting in 2 m11 2-chloro-N-(2-methylphenyl)-male having a boiling point of 132°C at Imide 75. 0 g (0.34 mol) was obtained. This compound is hereinafter referred to as compound 279. Implementation example CLXI [[ Other compounds were prepared similarly to Example CXLII. water loss from plants Structures and analytical data of compounds 280 to 283 used in the examples below to reduce The data are shown in Table X below. Table X Representative nitrogen-containing heterocyclic compounds 280 3- CH3 boiling point 139℃~140℃/3 ran H92814- CH, melting point 148℃ 282 2, 4-(CH3)! Boiling point i4s℃~150℃/2mmH72832 -C, Hs Boiling point 136℃72WHf Implementation example CLXrV Toedilmaleimide ＾Idrich CheOtical Company and used as is without purification. The log p value of the product is as follows Met. Octatool/water log p by reverse phase HPLC: 1. 10 This compound is It is referred to as Compound 284 below. Obtained from viltet, Tintagel, Cornwall (UK) , and investigated its activity. Used in Examples below to reduce water loss from plants The structures and analytical data of compounds 285-288 are shown in Table Y below. -1-m-N- Representative nitrogen-containing heterocyclic compounds Compound Substituent Octa implementation example by reversed phase HPLC CLXVI 2-(3-trifluoromethyl)-4,5-dichloro-3(21()pyridazino manufacturing 2-(3-trifluoromethyl)-4,5-dichloro-3 (2-former pyridazinone) ^Idrich Chemica! Obtained from Co11lpany and purified I used it as is. The too P value of the product was as follows. Octatool/water log P by reverse phase HPLC: 2. 90 This compound is It is referred to as Compound 289 below. A mixture of 50 g (0.5 mol) of succinic anhydride and 300 d of toluene was added to Stir and heat at 120°C and add 69 g (0.5 mol) of 2-ethoxy to this mixture. Nilin was added via dropping funnel. The reaction mixture is then heated to boiling, Toluene was distilled off at a kettle temperature of 180-190°C. The theoretical water is distilled out The mixture was heated at 180-190°C until the temperature reached 180-190°C. Cool the reaction mixture and add 9 of 11 It was diluted with 9% isopropyl alcohol and left for about 16 hours. The separated solid is P When separated, washed with isopropyl alcohol and dried, it has a melting point of 108°C. (2-Ethoxyphenyl)succinimide72. 09 (0.33 mol) was obtained It was done. Elemental analysis of the product was as follows: Analysis: Cl2H13NO3 Actual measurement value; N, 6. 73 This compound is hereinafter referred to as compound 290. Implementation example CLX■ 35-dichloro-6-(3,5-dichloro-4-methoxyphenyl)-4-seiichi Up. Made by Roxivili Gin 3. 5-dichloro-6-(3,5-dichloro-4-methoxyphenyl)-4-hyperoxyphenyl Droxypyridazine was obtained from Chea+ie Linz Company, It was used as is without purification. NMR analysis of the product was as follows: 'IINMR (CDCj/DMSO-d6): 164. 50. 152. 77, 147. 92. 141. 99. 131. 05°130. 58. 128. 88. 1 28. 34 and 60. 51 ppm This compound is hereinafter referred to as compound 291. Implementation example CLXIX Other compounds were prepared similarly to Example CXLII. water loss from plants Structure and analysis of compounds 292 to 296 used in the examples below to reduce The data are shown in Table 2 below. Table 2 Representative nitrogen-containing heterocyclic compounds Example CLXX Typical nitrogen-containing heterocyclic compounds Effect on leaf radiation resistance and radiation rate What is leaf diffusion resistance? It is the resistance value to water vapor dissipation from the n rate). The rate of divergence is determined by the evaporation of water from the cell wall and through the stomata. This is the value measured over a certain period of time of water dissipation from the Leaf radiation resistance and radiation rate To explain the relationship simply, the higher the resistance to leaf radiation, the lower the rate of leaf radiation; The lower the resistance, the higher the divergence rate. )2 The leaf radiation resistance and radiation rate shown in Table AA are as follows. This is a value measured using a general method such as 30 for each test compound. 3M9 to 5. After dissolving in 5-acetylene, the final volume is A test compound solution was prepared by adding water to give ii and omi. add water If the solution becomes cloudy during IC, stop using water and add acetone to a final volume of 1 1. 0m7! was added until The sample solution thus obtained contained 30 ppm (by weight) of the compound. the below described The p-value of the test compound in the final solution used in Table AA is determined by diluting the test H suspension with water. It was obtained by appropriately dividing 8 times. Potting soil mix (1/3 sandy loam soil, 1/3 peat moss, and 1 part perlite) /3 soil) in diameter 13. Into a 5 CIll plastic pot. Genmame (Phaseolus -5 1 tate U) engineering v, ar, cranber ry) seeds were sown. One pot per plant after 5 to 7 days of sowing. I made it. Test each concentration 10 to 12 days after sowing, when the first leaves have fully grown. Compound (solution 5 + Ii per pot, suction type set to air pressure IQpsig) Three kidney bean leaves were sprayed using spray B equipment. Contains the test compound as a control. A water-acetone solution without water was also sprayed on three kidney beans. Ta. 24 hours and 48 hours after treatment, the radiation resistance and radiation rate were measured in units of seconds, /α, respectively. , IJSH20/ex. For measurements, L Commercially available from i-Car, Inc./Li-Cor, Ltd. [1-C An or1600 steady state bolometer was used. Test compounds and controls at each concentration The average of the numerical values was calculated and shown clearly. M Table AA (continued) Typical nitrogen-containing heterocyclic compounds Effect on leaf radiation resistance and radiation rate Table ^^ (continued) Effect on leaf radiation resistance and radiation rate Clothes AA (continued) Effect on leaf radiation resistance and radiation rate Clothes AA (continued) Table AA (continued) Effect on leaf radiation resistance and radiation rate Clothes AA (continued) Effect on shedding resistance and shedding rate Table AA (continued) Typical nitrogen-containing heterocyclic compounds Effect on leaf radiation resistance and radiation rate (a) Treated at 115 ppm (b) Treated at 230 ppm (c) 4601)l) Process in 11 (d) Treated with 920 pl) In (e) Processed at 3220ppp As is clear from the results in Table ^^, typical nitrogen-containing complexes used in the method of the present invention The elemental ring compound significantly increases the resistance to shearing and the rate of shedding compared to the untreated control. significantly reduced. Water use efficiency (WLIE) is a measure of the effectiveness of anti-transpiration compounds (i.e. the amount of water used by plants). control) and the effect of the compound on plant growth (i.e., control of plant photosynthesis). It measures both the positive and negative effects. In particular, WLIE Plant dry matter pro reduced). The WUEs shown in Tables BB to FF below are as follows: This is a value measured using a general method. Solutions of the compounds listed in Tables 88-FF were prepared for each test compound 62. 5 Jl! F to 5d It was created by dissolving it in acetone. This solution was added for 2d, 1m, and 0. 5d They were placed in separate tubes, and acetone was added until the total color of the six tubes reached 12 m. Afterwards, more water was added to bring the final volume of the 6 tubes to 20 M1. sample in the above sample solution. Test compound i! Ir! 1 (weight>st 1250ppm, 625ppm, respectively) 312ppmr (i lid. +7 below) Solution used in KA test other than above Containing the test compound at a certain concentration is obtained by appropriately diluting the sample solution with water. be. ± for potted plants (i.e. sandy loam ± 1/3 by volume, peat moss 1/3 and perlite) 1/3 of the soil) in diameter 10. 2ex (each in a D plastic pot) entucky bluegrass or ta il fescue turfgrass) seeds were sown. Sowing seeds Before that, I measured the ff1ffi between the plastic pot and the pot. 8 to 12 times after sowing In the meantime, we have grown staghorn grass and staghorn grass. Also, the height of the plants during this period was 2. 5-3. It was held at 83. 2. Mow the grassweed and grasshopper so that the height is even. 5-3. Become 8α I made it. The weight of the marks was also measured before processing. test compound and control at each concentration. The four pots were sprayed using a vacuum sprayer set at an air pressure of 10 psig. (sprayed 5 d of solution per pot). Water-a without test compound was used as a control. A setone solution was also applied to four pots. After drying, keep all pots at a temperature of 80 ± 5 and a humidity of 5. The plants were kept in a greenhouse at 0±5% for 7 days without watering. every 24 hours We measured the weight of all the pots on the same day, and calculated the amount of water used from that day's weight and the initial weight. . After 7 days, the plants in the pots were visually observed. Then trim the plants to an even height. Clippings from each pot were collected, dried, and weighed. Five. Water usage m was calculated using the following formula. WtJE was calculated using the following formula. The WUE index for each test compound relative to the control was calculated using the following formula: The average values for the and control values are shown in Tables 88 to FF. 1 trigram i four Umbrella caused damage to plants at all concentrations. Most cases where 11 degrees is 78 ppm or higher All the plants withered. Substantial mulberry damage occurred to the plants. 1 friend Typical nitrogen-containing heterocyclic compounds Efficiency of use to make Nagahagusa occured. Tile ■ Typical nitrogen-containing heterocyclic compounds H of alternative nitrogen-containing m-ring compounds Umbrella caused damage to plants at all concentrations. Substantial phytotoxicity occurred to the plants. As is clear from the results in Tables BB to FF, typical nitrogen used in the method of the present invention complex-containing complex pus compounds significantly reduced water usage compared to untreated controls; It does not adversely affect plant growth, that is, plant photosynthesis. In contrast, at Substantial phytotoxicity occurred in the case of plants treated with Radin. (Margin below) Four-ohm construction of Tomoya■ When anti-emission compounds are used in agriculture, they can not only have water retention effects but also increase yields. I can wait. In other words, when anti-transpiration compounds are used on crops, they may have particular moisture requirements. This is the value obtained by measuring the water loss during the period. 0. 78g, 1. 559 or 3. 780m for 10g of compound 44! of acetone A solution was prepared by dissolving it in Immediately before application, water is added to the solution to bring the final volume to 1. 300d and shita. Add test compound by mixing 780 Ix1 acetone and 520 Id water. A control solution of total [11,300- A statistical processing method (statis The above formulation was applied according to the treatment procedure). . Each lot consists of four 20-foot-long rows spaced approximately 3 feet apart. . The following tasks were randomly assigned to 6 sections (randomized com Plet block of six different repeats ions), one block. Each task includes the following processing: (1) Trial Treatment with control without test compound: per compartment in ff1T1 at the time shown in Table CG. 0. Treatment using compound 44 of 789: ■ Not shown in Table GG, 1. Process using compound 44 of 55j7 Reason; 0) 3.0% per section at time T1 shown in Table GG. Where 10g of compound 44 is used Reason: ■ 0.0% per section at time T2 shown in Table GG. Treatment using 78 g of compound 44 : ■ 1.0% per plot at time T2 shown in Table GG. Treatment using 55 g of compound 44 : ω　3.00 per section at time T2 shown in Table GG. Process using compound 44 of 10!7 Reason: Carbon dioxide back-back spray with air pressure set at approximately 20-40 psig The above formulation was applied to each section using (backpack 5player). . Maize planting times, application times, and harvest times are detailed in Table GG. That's right. 10 feet tii of the middle two rows of each section! <Both ends of the middle two rows Harvested corn (5 feet range) and yielded 8! The number was measured. growing period At least for a period of time, water pressure conditions ns) was observed. Table GG shows the average value of the numerical values obtained in each section for each task. It was shown to. K1 Typical nitrogen-containing heterocyclic compounds Crop yield 11B increasing effect - corn T1: 2nd application harvest on 46th day after planting (at the time of detection) : 2nd application 3 weeks after detection, 61 days after planting Harvest: 1 from planting 14th day As is clear from the results in Table GG, typical nitrogen-containing heterocyclization by the method of the present invention When maize was treated with Compound 44, under similar conditions Corn yield 811 is significantly increased compared to untreated corn. Bottle 1” 11th January - Typical nitrogen-containing heterocyclic compounds Crop yield v5H increasing effect - cotton When anti-emission compounds are used in agriculture, they can not only have water retention effects but also increase yields. I can wait. In other words, when anti-transpiration compounds are used on crops, they may have particular moisture requirements. Increasing the actual crop harvesting vehicle by reducing water loss during the be able to. The cotton yields shown in Table HH below were determined by the following general method: It is a value. 0. 78g, 1. 55g or 3. 10g of compound 44 in 780d of acetone A solution was prepared by dissolving it. Immediately before application, water is added to the solution to bring the final volume to 13. 00m. Mix 780 d of acetone and 520 d of water without test compound A control solution with a total volume of 1300 d was also made. The above formulation was applied to cotton in 36 plots of farmland using a statistical processing method. each The bays are four 20 foot long rows spaced approximately 3 feet apart. The following tasks were randomly assigned to six sections, forming one block. Each task has the following Processing includes: (1) Treatment with a control that does not contain the test compound: ■ 1 at time T1 shown in Table HH 0 per section. Treatment using compound 44 of 789: ■ 1.0% per plot during period T1 shown in Table 1. Treatment using 55 g of compound 44 : CA) 3.0% per section at time T1 shown in Table HH. Using compound 44 of 10!7 Processing: Q　Table H) 0.00 per section at time T2 shown in I. Process using 78g of compound 44 Reason: ■ 3.0% per plot at time T2 shown in Table HH. Using compound 44 of 10ii+ process: using a carbon dioxide back-back sprayer with air pressure set at approximately 20-40 psig. Then, the above formulation was applied to each section. Regarding cotton planting time, IM time and harvest time are as detailed in Table HH. 10 feet area within the middle two rows of each section (5 feet Ta from each end of the middle two rows) ) to harvest and harvest cotton! The amount of I was measured. Water pressure during at least part of the growing season condition was observed. The average value of the numerical values obtained in each section for each task is shown in Table HH. did. Table HH Typical nitrogen-containing heterocyclic compounds *T1: E bloom, first application 47 days after planting T2 second bloom 2nd application yield V&: 33!1 hours after planting and 67 days after planting: 126 days after planting day As is clear from the results in Table HH, typical nitrogen-containing heterocyclization by the method of the present invention When cotton is treated with Compound 44, untreated cotton under similar conditions The yield of cotton, 124, increases significantly compared to the above. When anti-emission compounds are used in agriculture, they can be expected to not only have a water retention effect but also increase the yield of cans. I can wait. In other words, when anti-transpiration compounds are used on crops, they may have particular moisture requirements. increase actual crop yield by reducing water loss during be able to. The sweet potato yields shown in Table II below are calculated using the following general method: This is the measured value. 0. 78g, 1. 55g or 3. Dissolve 1 og of compound 44 in 780 d of acetone. A solution was prepared. Immediately before application, water was added to the solution to bring the final volume to 130 ml. It was set to 0d. Mix 780ml of acetone and 520ml of water to make a total sample containing no test compound. A control solution with fi 1300m was also prepared. The above formulation was applied to sweet potatoes in separate plots of farmland using a statistical treatment method. . Each lot consists of four 20-foot-long rows spaced approximately 3 feet apart. Ru. Random tasks include: processing; ■ 1.0 per plot at time T1 shown in Table II. Treatment using 55 g of compound 44 ; ) 3.0% per section at the time T1 shown in Table II. Using 10g of compound 44 Reason: Q: 0.0% per section at time T2 shown in Table II. Treatment using 78 g of compound 44 : ■ 1.0% per plot at time T2 shown in Table II. Treatment using 55 g of compound 44 ; Using a carbon dioxide back-back sprayer with air pressure set to about 20 to 4 opSiO Then, the above formulation was applied to each section. When planting sweet potatoes, at the time of m use and at the time of harvest. For that, see Table I! As shown in detail in . 10 feet in the middle two rows of each section Harvest the sweet potatoes in the two rows (5 feet from each end of the middle two rows) and measure the yield. It was measured. Water stress was observed during at least part of the growing season. The average values obtained in each section for each task are shown in Table II. Crop yield increase effect – sweet potato *T1: Time of initiation of tuber formation. First application 43 days after planting T2: 4 weeks after the start of tuber formation. Second application 77 days after planting Harvest: 114 days after planting As is clear from the results in Table II, typical nitrogen-containing heterocyclization by the method of the present invention When sweet potatoes were treated with Compound 44, no The yield of sweet potatoes is significantly increased compared to treated sweet potatoes. After the 11th master craftsman When anti-emission compounds are used in agriculture, they not only have a water retention effect but also have the effect of increasing yields. You can expect it. In other words, when applied to crops, anti-wicking compounds can be used to Increase actual crop yield by reducing water loss during the required period. can be set. The soybean harvest intervals shown in Table JJ below are measured using the following general method. This is the specified value. 0. 78g, 1. 55rJ or 3. 109 of compound 44 in 780ml of acetate A solution was prepared by dissolving it in water. Immediately before application, water was added to the clear liquid to give a final volume (6 ) to 1300ad! Closed. Test by mixing 780ml of acetone and 520Id of water. A control solution of 1300 m total il containing no test compound was also prepared. The above formulation was applied to soybeans in 36 plotted farmlands using a statistical processing method. Each lot consists of four 20-foot-long rows spaced approximately 3 feet apart. . Contains 6 random tasks: (1), treatment with a control that does not contain the test compound: ■ 1 at time T1 shown in Table JJ 1 per section. Treatment using compound 44 of 559: 0) 3.0% per plot at time T1 shown in Table JJ. Treatment using compound 44 of 109 Reason: 0) Not shown in Table JJ, 0.0% per plot at time T2. Process using 78g of compound 44 Reason: ■ 1.0% per plot at time T2 shown in Table JJ. Treatment using 55 g of compound 44 ; However, at the time T2 shown in Table JJ, 3. Where to use 10g of compound 4 Reason: using a carbon dioxide back-back sprayer with air pressure set at approximately 20-40 psig. Then, the above formulation was applied to each section. At the time of soybean planting. The timing of application and harvesting are shown in detail in Table JJ. 10 feet within the middle two rows of each lot (5 feet from each end of each middle two row) of soybeans were harvested and the yield was measured. Water pressure during at least part of the growing season It was observed. Table JJ shows the average values obtained in each section for each task. Ta. Effect of increasing number and quantity of crops - beans *T1: At the time of flowerina, under the first application on the 63rd day after planting 2: 2nd application yield Wt 86 days after planting, 3 selections after flowering: 2 after planting 0101 As is clear from the results on day J, typical nitrogen-containing heterocyclization was achieved by the method of the present invention. When soybeans were treated with compound 44, untreated soybeans were treated under similar conditions. Yield of soybeans compared to soybeans! ! 5 increases significantly. When anti-emission compounds are used in agriculture, they can not only have water retention effects but also increase yields. I can wait. In other words, when transpiration control compounds are used on crops – moisture is particularly Increase actual crop yield by reducing water loss during critical periods. can be done. The cotton and potato yields shown in K and LL in the table below are as follows: This is a value measured using a standard method. 39. 3% by weight propylene carbonate, 39. 3% by weight EXXate7 00 (Exxon Chemicals, Houston, Texas), 10. 0% by weight of At1oy3455F (ICI Americas, 11 i1mington, Delaware) and 11. 4% by weight of compound 44 A concentrated emuldimine containing compound 44 was prepared. Immediately before application, apply the thick emulsion. 31d (3.5 g of compound 44) or 62d (7.09 of compound 44) The above formulation was applied by adding it to water to give a final volume of 31251 d and using a statistical method. Ta. Each section consists of four 20 foot long rows spaced approximately 3 feet apart. be. The following tasks were randomly assigned to six sections, forming one block. Each task includes the following processing: (1) Treatment with a control that does not contain the test compound; ■ Time periods shown in Tables and LL 3 per section in T1. Treatment using 5 g of compound 44; ■7.7% per plot at time T1 shown in K and LL in the table. Using compound 44 of 09 Processing: C) At time T2 shown in K and LL in the table, 3. Using 5g of compound 44 processing; ■ 7.5% per plot at time T2 shown in K and LL in the table. Using 0g of compound 44 processing; Carbon dioxide back bag 1 with air pressure set at about 20-40 psig! using a fog machine Then, the above formulation was applied to each section. Each crop is planted at different times. The time of application and harvest are as shown in detail in the table and in LL. Each ward 20 feet of cotton in the middle two rows of the picture (5 feet from each end of the middle two rows) Harvest and harvest potatoes! ! The amount was measured. Water pressure during at least part of the growing season condition was observed. The average values obtained for each plot for each operation are shown in the table for K and crop yield increase. Effect-cotton *T1: Two weeks before bloom. 1st application of n0 61 days after planting T2: 2nd application at flowering time, 73 days after planting: 167 days after planting Table LL Typical nitrogen-containing heterocyclic compounds Crop yield increase effect - Potato , i:T1:R At the time of flowering, the second application 75 days after planting. Harvest: Second application 331i4 days after flowering, 96 days after planting Harvest: Planting 125th day after application As is clear from the results in Tables KK and LL, typical nitrogen-containing Similar conditions were observed when cotton and potato were treated with a heterocyclic compound, namely compound 44. The yield of crops is significantly increased compared to untreated crops even under conditions of treatment. Example CLXXVII When anti-emission compounds are used in agriculture, they can not only have a water retention effect but also increase yield. I can wait. In other words, when anti-transpiration compounds are used on crops, they may have particular moisture requirements. increase the actual crop yield by reducing water loss during the can be done. The soybean yield shown in Table H) 4 below is determined by the following general method. This is the value measured by. − 39.3% by weight of propylene carbonate, 39. Triple D% Exxate7 00 (Exxon Chea+1 cals, Houston, Texas) , 10. At1oy34S5F with Oi1% (ICI America, Wiliington, Delaware) and 11. 4% by weight of compound 4 A concentrated emulsion of compound 44 containing 4 was prepared. Immediately before IM use, the m-thick Emma Lujon 31d (compound 44 of 3,59) or 62ad! (7,09 compound 44) was added to the water to give a final volume of 3125 m. The above formulation was applied to soybeans in 18 plotted farmlands using a statistical processing method. Each lot consists of four 30-foot-long rows spaced approximately 3 feet apart. . The following tasks were randomly assigned to six sections, forming one block. Each task has the following Includes processing of: (1) Treatment with a control that does not contain the test compound: ■ 1 at the time T1 shown in Table MH Per section 3. Treatment using compound 44 of 59: ■ 7 per plot at time T1 shown in Table 88. Treatment using compound 44 of 09 : Using a carbon dioxide back-back spray orange with air pressure set at approximately 20-40 psia. Then, the above formulation was applied to each section. Time to plant soybeans. The timing of application and harvesting are shown in detail in Table 88. 20 feet of the middle two rows of each lot (°5 feet from each end of the middle two rows [ ) soybeans were harvested and the yield W and amount were measured. Water pressure during at least part of the growing season condition was observed. Table 88 shows the average values obtained in each section for each task. Indicated. 1 fall Representative nitrogen-containing heterocycle A product *T1: First application at flowering (f lowering), 48 days after planting Harvest: 186 days after planting As is clear from the results in Table 88, typical nitrogen-containing heterocyclization by the method of the present invention When soybeans were treated with compound 44, untreated soybeans were treated under similar conditions. The yield of soybean is significantly increased compared to soybean. 1 1 yu Uμ”U Typical nitrogen-containing heterocyclic compounds Collection of representative nitrogen-containing heterocyclic compounds in alfalfa 8! Warm up the solution of the compound It was created. , water was added to the solution immediately before application to give a final Ik volume of 5500- Ta. Acetone 3300M! ! and 2200 d of water, containing no test compound. A control solution was also prepared with a total volume of 5500 ttdl. A self-injecting chemical sprayer (seH-prop) with air pressure set at 40 psig. using elled chea+1cal 5play applicator) Then, apply the above formulation to a designated plot where alfalfa is planted after one year of growth. did. Each lot was 20 feet wide by 30 feet long. control Each treatment, including the roll, was repeated 6 times in 6 plots. 20 days after cutting The alfalfa was harvested 28 days after treatment. 1 from the center of each section The yield of alfalfa harvested from 1rl was measured. At least during the growing season Water pressure was observed for a period of time. The average of the values obtained in each section for each operation The average values are shown in Table 88. -1 gate Fresh weight E1: Weight of alfalfa measured immediately after harvest Dry weight: Harvested alfalfa Dried alfalfa was measured after drying it in an open room at 90°C for 24 hours. As is clear from the results of the weight table NH, typical nitrogen-containing complexes can be produced by the method of the present invention. When alfalfa was treated with a ring compound, namely compound 44, similar conditions Even under conditions, the yield of alfalfa increases significantly compared to untreated alfalfa. Ru. Example CLXXI Typical element-containing, elemental ring compounds Photosynthesis 4') Effect on electrical transport Two types of photosystems involved in photosynthesis in plants, namely photosystems and electron transport chain ( are interconnected by an electron transport chain). Therefore, the special light reactions of photosynthesis can be developed using artificial electron donors and acceptors. We studied partial reactions. BrewerP, E., Arntzen, C.J. , , and 5li4e, F, It4. , Weed 5science 27: 300-318 (1979). The degree of inhibition of photosynthesis caused by the compounds listed in Table 00 was determined using a Examined. Typically, the method involves injecting isolated pea chloroplasts osmotically (O″sm tically), the chloroplasts are introduced into the reaction mixture, and the terminal electron access G11son oxograph, including using methyl viologen as a protein. (shown in auxo-). 1■ Typical nitrogen-containing heterocyclic compounds Effects of photosynthesis on electron transport As is clear from the results in Table 00, the compounds used in the present invention are effective for photosynthetic electron transport. whereas atrazine and diuron (diuron) substantially inhibits photosynthetic electron transport. Although the embodiments of the present invention have been shown above, the present invention is not limited thereto. , the present invention encompasses the concepts as described above. Missing the spirit and gist of the present invention It is possible to make various changes and create various embodiments without departing from the scope of the invention. Ru. international search report 1mmn1lesalaesca+ie++N11PCT/υS8710024 0km*5lla,, al ApNcalc++ Ti1l pcT/υS 8 7100240 ■ Int, C1,' Identification symbol Internal serial number priority claim 01 98 Cape December 15th [phase] United States (US) ■939,41 (○ Inventor Capy , James Jose American [Phase] Inventors Cooke, Anson φRichard Amen. @ Inventors: Seeds, Richard dispute, Eric, Amet dispute Capra Drive, Lori, North Carolina-27606, United States 4905 United States, North Carolina 27713. Durham, No\ntsuma Drai Bu 1210 United States, North Carolina 27713. Durham, Ys Cornwo - Squirrel Road 1727

Claims

[Claims] 1. can be applied to plant surfaces without substantially inhibiting electron transport for plant photosynthesis. An effective amount sufficient to reduce water loss of the formula: R1-X-R2 (In the formula, R1 is a monocyclic aromatic or non-aromatic ring system, a bicyclic aromatic or non-aromatic ring system , substituted or unsubstituted selected from polycyclic aromatic or non-aromatic ring systems and bridged ring systems. a substituted carbocyclic or heterocyclic ring system, which ring system may be saturated or unsaturated; , the permissible substituents may be the same or different and contain one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲mathematical formula, chemical formula , tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas, chemical formulas, There are tables etc.▼ or R1 is a substituted heteroatom or a substituted carbon atom, or two or more carbon atoms or is a substituted or unsubstituted compound containing a combination of foreign atoms and the following permissible substituents: Straight chain or branched chain, the substituents may be the same or different, and may contain one or more substituents. More hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl , alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyh loalkenylthio, thiocyano, propargylthio, hydroxyimino, alco xiimino, trialkylsilyloxy, aryldialkylsilyloxy, Realylsilyloxy, formamidino, alkylsulfamide, dialkyl Sulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydro xy, amino, aminocarbonyl, alkylaminocarbonyl, dialkylami nocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dial Kylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivatives Derivative salt, formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalk cokyl, alkoxycarbonyl, substituted amino (in which case permissible substituents are the same) one or two propargyl, alkoxyalkyl, which may be one or different; Alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkyl (alkenyl), alkylthio, polyhaloalkylthio, alkylsulfini polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkyl sulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloa rukylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsulfonylamino Lyle, aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivatives derivative salts, phosphonic acids and their derivative salts, alkoxycarbonylamino, alkylamino Nocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhalogen rhoalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloa alkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluor loalkanol, cyanoalkylamino, semicarbazonomethyl, alkoxyca Rubonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted atom Ryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonomethyl, hydroxy condensed with mono-, di- or polysaccharides group, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, alkyl Ryloxy, aralkoxy, arylthio, aralkylthio, alkylthio oalkyl, arylthioalkyl, arylsulfinyl, arylsulfony haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy cy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, Polyhaloalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl Nyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryl Oxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkyl Aminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carbo xyalkylthio, alkoxycarbonylalkoxy, acyloxy, haloacyl oxy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy , alkenylsulfonyloxy, arylsulfonyloxy, haloalkylsulf Honyloxy, polyhaloalkylsulfonyloxy, aroylamino, haloacyl Ruamino, alkoxycarbonyloxy, arylsulfonylamino, aminocarbon Rubonyloxy, cyanato, isocyanato, isothiocyano, cycloalkyla mino, trialkylammonium, arylamino, aryl(alkyl)amino ノ、araalkylamino、alkoxyalkylphosphinyl、alkoxyalkyl Ruphosphinothioyl, Alkylhydroxyphosphinyl, Dialkoxyphosph ino, hydroxyamino, alkoxyamino, aryloxyamino, aryl Oximino, oxo, thiono, alkylaminoalkoxy, dialkylamino alkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy , dialkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and X is a covalent single bond or a double bond. double bonds, substituted or unsubstituted heteroatoms or substituted carbon atoms, or two or more or more carbon atoms or heteroatoms in combination with the following permissible substituents: Substituted or unsubstituted linear or branched chain, in which the substituents may be the same or different. optionally one or more hydrogen, halogen, alkylcarbonyl, alkyl Carbonyl alkyl, alkoxycarbonyl alkyl, alkoxycarbonyl alkyl Rukylthio, polyhaloalkenylthio, thiocyano, propargylthio, hydro ximino, alkoxyimino, trialkylsilyloxy, aryl dialkyl Lucilyloxy, triarylsilyloxy, formamidino, alkylsulfur Amide, dialkylsulfamide, alkoxysulfonyl, polyhaloalkoxy Sulfonyl, hydroxy, amino, aminocarbonyl, alkylaminocarbonyl , dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothio Carbonyl, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl Rubonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloal Kyl, polyhaloalkokyl, alkoxycarbonyl, substituted amino (allowed in this case) The substituents that can be substituted may be the same or different and include one or two propargyl, a Rukoxyalkyl, alkylthioalkyl, alkyl, alkenyl, haloalke or polyhaloalkenyl), alkylthio, polyhaloalkylthio, Alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl. Polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonyl Amino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamide -, trialkylsilyl, aryldialkylsilyl, triarylsilyl, Sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alkoxycarbonyl alcohol mino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyl Oxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyl Oxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonome thyl, alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazonomethyl, substituted or is unsubstituted arylhydrazonomethyl, mono-, di- or polysaccharide Condensed hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkyl Koxyalkyl, aryloxy, aralkoxy, arylthio, aralkyl ruthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl , arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloal Kenylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, Ryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyh loacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosul Honyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxy Alkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, acyl halooxy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkyloxy Rusulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy , haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, alloy Ruamino, haloacylamino, alkoxycarbonyloxy, arylsulfony Ruamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano , cycloalkylamino, trialkylammonium, arylamino, ary (alkyl)amino, araalkylamino, alkoxyalkylphosphinyl , alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, arylox Cyamino, aryloxyimino, oxo, thiono, alkylaminoalkoxy , dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl , cyanoalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X -R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼,▲Mathematical formulas, chemical formulas, tables, etc. There are ▼ or ▲ there are mathematical formulas, chemical formulas, tables, etc. ▼, and R2 is a monocyclic aromatic Aromatic or non-aromatic ring systems, bicyclic aromatic or non-aromatic ring systems, polycyclic aromatic or substituted or unsubstituted at least one selected from non-aromatic ring systems and bridged ring systems. A heterocyclic ring system having one nitrogen atom, said ring system being saturated or unsaturated. Often, the permissible substituents can be the same or different and include one or more hydroxides. element, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxy carbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenyl Thio, thiocyano, propargylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy, aryrodialkylsilyloxy, triarylsilyloxy Ryloxy, formamidino, alkyl sulfamide, dialkyl sulfamide , alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino , aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl , aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl Ocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, form Amide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkyl Koxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) may contain one or two propargyl, alkoxyalkyl, alkylthio Alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio. Polyhaloalkylthio, alkylsulfinyl, polyhalo Alkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Rukylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl nylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl triarylsilyl, sulfonic acid and its derivative salts, phosphorus acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyl Oxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl , alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy cy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkano , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydride Razonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxy iminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonome Hydroxy group, haloalkaline group fused with methyl, mono-, di- or polysaccharide Kyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy , aralkoxy, arylthio, aralkylthio, alkylthioalkyl, Arylthioalkyl, arylsulfinyl, arylsulfonyl, haloal Kylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloal Quinyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloal Kenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propane Lugyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbo Nyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl Nyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkyl Thio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly Lihaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyl Sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy , polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, a Rukoxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy Cy, cyanato, isocyanato, isothiocyano, cycloalkylamino, tria rukylammonium, arylamino, aryl(alkyl)amino, araal Kylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphino Thioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydro xyamino, alkoxyamino, aryloxyamino, aryloxyimino , oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, Alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Sulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and R3 is a monocyclic aromatic or or non-aromatic ring systems, bicyclic aromatic or non-aromatic ring systems, polycyclic aromatic or Substituted or unsubstituted carbocyclic or heterocyclic ring systems selected from non-aromatic ring systems and bridged ring systems Cyclic ring systems, said ring systems may be saturated or unsaturated, and the permissible substituents include: One or more hydrogens, halogens, alkyl carbons, which may be the same or different. Bonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, alco xycarbonylalkylthio, polyhaloalkenylthio, thiocyano, propal Gilthio, hydroxyimino, alkoxyimino, trialkylsilyloxy, Aryldialkylsilyloxy, triarylsilyloxy, formamidino , alkyl sulfamide, dialkyl sulfamide, alkoxysulfonyl, poly Lihaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl, alkyl lyaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, Lucylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, sia , hydroxycarbonyl and its derivative salts, formamide, alkyl, alkoxy cy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (In this case, the permissible substituents may be the same or different and include one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alke nyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhalalkenyl Loalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfinyl Kylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloalkyl carbonylamino, trialkylsilyl, aryldialkylsilyl, thoria lylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alcohol xycarbonylamino, alkylaminocarbonyloxy, dialkylaminoca Rubonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkyloxy nil, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, Lihaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino, Semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, alkoxycarbonylhydrazonomethyl Minomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazonomethyl methyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- or poly Hydroxy group, haloalkyl, haloalkenyl, halo fused with saccharide Alkynyl, alkoxyalkyl, aryloxy, aralkoxy, aryl Thio, aralkylthio, alkylthioalkyl, arylthioalkyl, aryl lsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloal Kylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkyni ruthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, alkoxy cissulfonyl, aryloxysulfonyl, propargyloxy, aroyl, ha loacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, acyl Rkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl Nyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbonyl Alkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, alloy oxy, alkylsulfonyloxy, alkenylsulfonyloxy, aryl Sulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfony oxy, aroylamino, haloacylamino, alkoxycarbonyloxy, Arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato , isothiocyano, cycloalkylamino, trialkylammonium, ary ruamino, aryl(alkyl)amino, araalkylamino, alkoxyal Kylphosphinil, alkoxyalkylphosphinothioyl, alkylhydroxy Cyphosphinil, dialkoxyphosphino, hydroxyamino, alkoxyamino No, aryloxyamino, aryloxyimino, oxo, thiono, alkyl Aminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy, al Koxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼,▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ , or R3 is a substituted heteroatom or substituted carbon atom, or two or more carbon atoms Substitutions containing elementary atoms or heteroatoms in combination with the following permissible substituents: Unsubstituted straight chain or branched chain, the substituents may be the same or different 1 one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonyl Alkyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthio , polyhaloalkenylthio, thiocyano, propargylthio, hydroxyimino , alkoxyimino, trialkylsilyloxy, aryldialkylsilyloxy xy, triarylsilyloxy, formamidino, alkylsulfamide, di Alkylsulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl , hydroxy, amino, aminocarbonyl, alkylaminocarbonyl, dial Kylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl , dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and Derivative salts, formamide, alkyl, alkoxy, polyhaloalkyl, poly Haloalkokyl, alkoxycarbonyl, substituted amino (in which case permissible substitutions) Substituents may be the same or different, including one or two propargyl, alkoxy alkyl, alkylthioalkyl, alkyl, alkenyl, haloalkenyl or poly lyhaloalkenyl), alkylthio, polyhaloalkylthio, alkyls Rufinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloa alkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino, poly Lihaloalkylsulfonylamino, polyhaloalkylcarbonylamino, thoria alkylsilyl, aryldialkylsilyl, triarylsilyl, sulfonic acid and phosphonic acid and its derivative salts, phosphonic acid and its derivative salts, alkoxycarbonylamino, alkoxycarbonylamino, Kylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl , polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyl Lihaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyhaloalkynyloxy, Lifluoroalkanol, cyanoalkylamino, semicarbazonomethyl, alkaline Koxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted Substituted aryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted Aryl hydrazonomethyl, mono-, di- or polysaccharides and condensed hydrogen droxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxyal Kyl, aryloxy, aralkoxy, arylthio, aralkylthio, a Rukylthioalkyl, Arylthioalkyl, Arylsulfinyl, Earls sulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkeni halooxy, haloalkynyloxy, haloalkynylthio, haloalkenyl sulfo Nyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryloxy Sulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, acyl Ryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dia rukylaminosulfonyl, arylaminosulfonyl, carboxyalkoxy, Carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy, ha loacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfonyl Oxy, alkenylsulfonyloxy, arylsulfonyloxy, haloalkyl sulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino, ha loacylamino, alkoxycarbonyloxy, arylsulfonylamino, a Minocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloal Kylamino, trialkylammonium, arylamino, aryl (alkyl )amino, araalkylamino, alkoxyalkylphosphinyl, alkoxy Alkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxy Phosphino, hydroxyamino, alkoxyamino, aryloxyamino, a Ryloxyimino, oxo, thiono, alkylaminoalkoxy, dialkyl Aminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoal Koxy, dialkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and Y1 and Y4 are each oxygen or sulfur, Y2 and Y3 are each oxygen, sulfur, amino or a covalent bond, R4 and R5 are each hydrogen, substituted or red-substituted alkyl, polyhaloalkyl, phenyl or benzyl, the permissible substituents being the same or different; Often one or more hydrogen, halogen, alkylcarbonyl, alkylcarboxylate Nylalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkyl Thio, polyhaloalkenylthio, thiocyano, propargylthio, hydroxyl Mino, alkoxyimino, trialkylsilyloxy, aryldialkylsilyl Ruoxy, triarylsilyloxy, formamidino, alkylsulfamide , dialkylsulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl Nyl, hydroxy, amino, aminocarbonyl, alkylaminocarbonyl, di alkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbo Nyl, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloalkyl, Polyhaloalkoxy, alkoxycarbonyl, substituted amino (in this case acceptable) The substituents may be the same or different and include one or two propargyl, alkoxy, Sialkyl, alkylthiofurkyl, alkyl, alkenyl, haloalkenyl or is polyhaloalkenyl), alkylthio, polyhaloalkylthio, alkylthio Rusulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhalogen loalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino , polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, Realkylsilyl, aryldialkylsilyl, triarylsilyl, sulfone Acids and their derivative salts, phosphonic acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alke Nyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy , polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy , polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, Alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or is unsubstituted aryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- or polysaccharides hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy Alkyl, aryloxy, aralkoxy, arylthio, aralkylthio , alkylthioalkyl, arylthioalkyl, arylsulfinyl, aryl lsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloa rukenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenyl Sulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryl Oxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl , dialkylaminosulfonyl, arylaminosulfonyl, carboxyalco xy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy cy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfur Honyloxy, alkenylsulfonyloxy, arylsulfonyloxy, halo Alkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroylamine No, haloacylamino, alkoxycarbonyloxy, arylsulfonylamino No, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cyano loalkylamino, trialkylammonium, arylamino, aryl (aryl) (alkyl)amino, araalkylamino, alkoxyalkylphosphinyl, alkylamino, Koxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dial Koxyphosphino, hydroxyamino, alkoxyamino, aryloxyamino No, aryloxyimino, oxo, thiono, alkylaminoalkoxy, dia Rukylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, sia Noalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X-R3 , -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼or ▲There are mathematical formulas, chemical formulas, tables, etc.▼). A method of reducing water loss from plants, the method comprising: 2. R1 and R3 each have the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ Monocyclic aromatic or non-aromatic ring system with; ▲Mathematical formulas, chemical formulas, tables, etc. ▼ Bicyclic aromatic or non-aromatic ring system having a formula selected from; ▲ mathematical formula, chemical formula There are tables, etc.▼ ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ as well as ▲There are mathematical formulas, chemical formulas, tables, etc.▼, a polycyclic aromatic or non-aromatic ring system having a formula selected from; and ▲There are mathematical formulas, chemical formulas, tables, etc.▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼ and ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ a saturated or unsaturated bridged ring system having a formula selected from; or an unsubstituted carbocyclic or heterocyclic ring system, in the above formula, A1 is a carbon having 0 to 4 double bonds or 0 to 2 triple bonds together with B1 a ring-forming chain of atoms forming a ring system or a heterocyclic system, B1 is a saturated or unsaturated carbon atom, A2 and A3 together with B2 and B3 respectively A ring-forming chain of atoms that together form a carbocyclic or heterocyclic system, and B2 and B3 is a saturated or unsaturated carbon atom or a saturated nitrogen atom, respectively; A4, A5, A6 and A7 together with B4, B5, B6 and B7 respectively A ring-forming chain of atoms forming a monocyclic or heterocyclic ring system, B4, B5, B6, and B7 are each saturated or unsaturated carbon atoms or saturated nitrogen atoms and A8, Ag and A10 together with B8, B9, B10 and B11 respectively form carbon a ring-forming chain of atoms forming a ring system or a heterocyclic system, B8, Bg and B10 are each a saturated or unsaturated carbon atom or a saturated nitrogen atom , B11 is a saturated or unsaturated carbon atom, nitrogen atom or phosphorus atom, A11, A12 and A13 together with B12 and B13 respectively form a carbocyclic ring system or is a ring-forming chain of atoms forming a heterocyclic ring system, and B12 and B13 are each a saturated carbon An elemental atom or a nitrogen atom, and Z may be the same or different and one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkyl Oxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalke Nylthio, thiocyano, propargylthio, hydroxyimino, alkoxyimine -, trialkylsilyloxy, aryldialkylsilyloxy, triary lucilyloxy, formamidino, alkylsulfamide, dialkylsulfur mido, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, a mino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbo Nyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylami Notiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivative salts, lumamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) May contain one or two propargyl, alkoxyalkyl, alkyl thioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, poly Haloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl , alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl sulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, Lyldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphoric acid Sulfonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbo Nyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalke Nyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyl Oxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalka Nor, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonyl hydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl group ximinomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazo Hydroxy group fused with monomethyl, mono-, di- or polysaccharide, halo Alkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryl xy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl aryl, arylthioalkyl, arylsulfinyl, arylsulfonyl, halo Alkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, halo Alkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhalo alkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, lopargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxyca rubonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminos sulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyal Kylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy , polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alke Nylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy xy, polyhaloalkylsulfonyloxy, aroylamino, haloacylamino , alkoxycarbonyloxy, arylsulfonylamino, aminocarbonyl Oxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, to Realkylammonium, arylamino, aryl(alkyl)amino, ara Alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosph dinotioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, Droxyamino, alkoxyamino, aryloxyamino, aryloxyamino Mino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy cy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dial Killsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and R3, R4, R5, Y1 , Y2, Y3, Y4 and X have the same meanings as above. 3. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'1 may be the same or different and may be one or more hydrogen, halogen, alkali Kylcarbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl , alkoxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, Propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl Oxy, aryldialkylsilyloxy, triarylsilyloxy, form Amidino, alkyl sulfamide, dialkyl sulfamide, alkoxy sulfonate Nyl, polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl , alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbo Nyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nito cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, Substituted amino (in which case the permissible substituents may be the same or different and include one or more substituents) is two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl , alkenyl, haloalkenyl or polyhaloalkenyl), alkylthio , polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulfini , alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonyl Mino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhal Loalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl , triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts , alkoxycarbonylamino, alkylaminocarbonyloxy, dialkyl Aminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy , alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkyl Nyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkyl Amino, Semicarbazonomethyl, Alkoxycarbonylhydrazonomethyl, Al Coxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydro Lazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- Or hydroxy group, haloalkyl, haloalkeni fused with polysaccharide , haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, Arylthio, aralkylthio, alkylthioalkyl, arylthioalkyl , arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, halo Alkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, Alkoxysulfonyl, aryloxysulfonyl, propargyloxy, allo yl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl Nyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylami Nosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxyca Rubonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy , aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, Arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl Sulfonyloxy, aroylamino, haloacylamino, alkoxycarbonyl Oxy, arylsulfonylamino, aminocarbonyloxy, cyanato, iso cyanato, isothiocyano, cycloalkylamino, trialkylammonium , arylamino, aryl(alkyl)amino, araalkylamino, alco xyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkyl Hydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alco oxyamino, aryloxyamino, aryloxyimino, oxo, thiono, Alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy cy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X , =X, -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼or▲There are mathematical formulas, chemical formulas, tables, etc. ▼ and X'1 is O'S, SO, SO2, NH, CH2, CO, single covalent bond, CH2O, CH2S, -CH(CH3)O, -CH(CN)O-, -CH=NO -, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡ C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (A Y'1 and Y'2 are halogen and alkyl, respectively. or alkoxy; X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 4. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'2 and R'3 may be the same or different and represent one or more water element, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxy carbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenyl Thio, thiocyano, propargylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy Ryloxy, formamidino, alkyl sulfamide, dialkyl sulfamide , alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino , aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl , aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl Ocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, form Amide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkyl Koxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) may contain one or two propargyl, alkoxyalkyl, alkylthio Alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhalo Alkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Rukylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl nylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl triarylsilyl, sulfonic acid and its derivative salts, phosphorus acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyl Oxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl , alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy cy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkano , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydride Razonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxy iminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonome Hydroxy group, haloalkaline group fused with methyl, mono-, di- or polysaccharide Kyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy , aralkoxy, arylthio, aralkylthio, alkylthioalkyl, Arylthioalkyl, arylsulfinyl, arylsulfonyl, haloal Kylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloal Quinyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloal Kenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propane Lugyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbo Nyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl Nyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkyl Thio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly Lihaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyl Sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy , polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, a Rukoxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy Cy, cyanato, isocyanato, isothiocyano, cycloalkylamino, tria rukylammonium, arylamino, aryl(alkyl)amino, araal Kylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphino Thioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydro xyamino, alkoxyamino, aryloxyamino, aryloxyimino , oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, Alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Sulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and X'2 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH(CH3)O, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH 2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, Y'3 is halogen, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 5. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'4, R'5 and R'6 may be the same or different and represent one or more water element, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxy carbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenyl Thio, thiocyano, propargylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy Ryloxy, formamidino, alkyl sulfamide, dialkyl sulfamide , alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino , aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl , aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl Ocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, form Amide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkyl Koxycarbonyl, substituted amino (in this case, permissible substituents are the same or different) may contain one or two propargyl, alkoxyalkyl, alkylthio Alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhalo Alkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Rukylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl nylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl triarylsilyl, sulfonic acid and its derivative salts, phosphorus acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyl Oxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl , alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy cy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkano , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydride Razonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxy iminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonome Hydroxy group, haloalkaline group fused with methyl, mono-, di- or polysaccharide Kyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy , aralkoxy, arylthio, aralkylthio, alkylthioalkyl, Arylthioalkyl, arylsulfinyl, arylsulfonyl, haloal Kylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloal Quinyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloal Kenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propane Lugyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbo Nyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl Nyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and X'3 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH(CH3)O, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH 2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, and X, R3, R4, R5, Y1, Y2, Y3 and Y 4 has the same meaning as above) The method according to claim 1, comprising: 6. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, thiocyano, propargylthio, hydroxyimino, Al:] ximino, trialkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy Ryloxy, formamidino, alkyl sulfamide, dialkyl sulfamide , alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino , aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl , aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl Ocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, form Amide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkyl Koxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) may contain one or two propargyl, alkoxyalkyl, alkylthio Alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhalo Alkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Rukylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl nylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl triarylsilyl, sulfonic acid and its derivative salts, phosphorus acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyl Oxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl , alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy cy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkano , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydride Razonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxy iminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonome Hydroxy group, haloalkaline group fused with methyl, mono-, di- or polysaccharide Kyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy , aralkoxy, arylthio, aralkylthio, alkylthioalkyl, Arylthioalkyl, arylsulfinyl, arylsulfonyl, haloal Kylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloal Quinyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloal Kenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propane Lugyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbo Nyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl Nyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkyl Thio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly Lihaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyl Sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy , polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, a Rukoxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy Cy, cyanato, isocyanato, isothiocyano, cycloalkylamino, tria rukylammonium, arylamino, aryl(alkyl)amino, araal Kylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphino Thioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydro xyamino, alkoxyamino, aryloxyamino, aryloxyimino , oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, Alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Sulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and Y'9, Y'10, Y' 11 and Y'12 may be the same or different and may be hydrogen, halogen, alkyl, or lyhaloalkyl, cyano or aryl; m and n' may be the same or different and have a value of 0 to 5, X'4 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH( CH3)O, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH 2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, and Y'13 and Y'14 may be the same or different Often halogen, alkyl or alkoxy, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 7. The compound has the formula ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in which case permissible substituents may be the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkyldilyl, doryarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and Y'9 and Y'10 are the same. Hydrogen, halogen, alkyl, polyhaloalkyl, cyano may be one or different. or aryl, m' and n may be the same or different and have a value of 0 to 5, X'5 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH( CH3)O, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH 2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, Y'15 is O or S, Y'91 and Y'92 are each halogen, X'6 is O or S, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 8. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in which case permissible substituents may be the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and X'7 may be the same or different. may be O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH (CH3)O, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH 2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, m' is a value of 0 to 5, Y'16 is hydrogen, alkyl, alkylcarbonyl, alkylsulfonyl or poly is haloalkylsulfonyl, Y'93 and Y'94 are each halogen, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 9. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in which case permissible substituents may be the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruhonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and Y'95 and Y'96 are Each is a halogen, and X, R3, R4, R5, Y1, Y2, Y3 and Y4 are the above-mentioned ) The method according to claim 1, comprising: 10. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'19 and Y'21 may be the same or different and represent hydrogen, halogen, alkyl carbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, a Rukoxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, pro- pargylthio, hydroxyimino, alkoxyimino, trialkylsilylthio cy, aryldialkylsilyloxy, triarylsilyloxy, formamide dino, alkylsulfamide, dialkylsulfamide, alkoxysulfonyl , polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl, a Rukylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl , alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, Cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alkyl koxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted Amino (in this case, the permissible substituents may be the same or different and include one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alkyl alkenyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloalkenyl Lihaloalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl, Alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino , alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloa alkylcarbonylamino, trialkylsilyl, aryldialkylsilyl, Realylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, a Rukoxycarbonylamino, alkylaminocarbonyloxy, dialkylamino Nocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, a rukynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl , polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamide No, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, alkoxy Shiiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazo monomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- or is a hydroxy group condensed with a polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, aryl ruthio, aralkylthio, alkylthioalkyl, arylthioalkyl, Arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, halo Alkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloal Quinylthio, Haloalkenylsulfonyl, Polyhaloalkenylsulfonyl, Al Koxysulfonyl, aryloxysulfonyl, propargyloxy, aroyl , haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl , alkylaminosulfonyl, dialkylaminosulfonyl, arylaminos sulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbo Nylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, a Loyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ali sulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy Honyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy Cy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyan nato, isothiocyano, cycloalkylamino, trialkylammonium, a lylamino, aryl(alkyl)amino, araalkylamino, alkoxy Alkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydride roxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxy Amino, aryloxyamino, aryloxyimino, oxo, thiono, al Kylaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy, Alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X,= X, -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼ , ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ , A' is synonymous with R1 above, X'10 is synonymous with the above X, Y'20 is halogen, cyano, alkyl, alkoxy, polyhaloalkyl, poly haloalkoxy or polyhaloalkylsulfonyloxy, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 11. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'12 has the same meaning as R1, Y'22 is halogen, cyano, alkyl, alkoxy, polyhaloalkyl, poly haloalkoxy or polyhaloalkylsulfonyloxy, Y'23 is hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl , alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyh loalkenylthio, thiocyano, propargylthio, hydroxyimino, alco xiimino, trialkylsilyloxy, aryldialkylsilyloxy, Realylsilyloxy, formamidino, alkylsulfamide, dialkyl Sulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydro xy, amino, aminocarbonyl, alkylaminocarbonyl, dialkylami nocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dial Kylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivatives Derivative salt, formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalk Koxy, alkoxycarbonyl, substituted amino (in which case permissible substituents are the same) one or two propargyl, alkoxyalkyl, which may be one or different; Alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkyl (alkenyl), alkylthio, polyhaloalkylthio, alkylsulfini polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkyl sulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloa rukylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsulfonylamino Lyle, aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivatives derivative salts, phosphonic acids and their derivative salts, alkoxycarbonylamino, alkylamino Nocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhalogen loalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloa alkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluor loalkanol, cyanoalkylamino, semicarbazonomethyl, alkoxyca Rubonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted atom Ryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonomethyl, hydroxy condensed with mono-, di- or polysaccharides group, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, alkyl Ryloxy, aralkoxy, arylthio, aralkylthio, alkylthio oalkyl, arylthioalkyl, arylsulfinyl, arylsulfony haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy cy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, Polyhaloalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl Nyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryl Oxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkyl Aminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carbo xyalkylthio, alkoxycarbonylalkoxy, acyloxy, haloacyl oxy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy , alkenylsulfonyloxy, arylsulfonyloxy, haloalkylsulf Honyloxy, polyhaloalkylsulfonyloxy, aroylamino, haloacyl Ruamino, alkoxycarbonyloxy, arylsulfonylamino, aminocarbon Rubonyloxy, cyanato, isocyanato, isothiocyano, cycloalkyla mino, trialkylammonium, arylamino, aryl(alkyl)amino ノ、araalkylamino、alkoxyalkylphosphinyl、alkoxyalkyl Ruphosphinothioyl, Alkylhydroxyphosphinyl, Dialkoxyphosph ino, hydroxyamino, alkoxyamino, aryloxyamino, aryl Oximino, oxo, thiono, alkylaminoalkoxy, dialkylamino alkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy , dialkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3 , ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ , ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and X, R3, R4, R5, Y1, Y2 , Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 12. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, A'1 has the same meaning as R2, Y'31 and Y'32 may be the same or different and represent halogen, alkyl or alkyl. Lukoxy) The method according to claim 1, comprising: 13. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, A'2 has the same meaning as R1, X'12 is synonymous with the above X, Y'33 and Y'34 may be the same or different and represent halogen, alkyl or alkyl. Lukoxy) The method according to claim 1, comprising: 14. The compound ▲There are mathematical formulas, chemical formulas, tables, etc.▼▲There are mathematical formulas, chemical formulas, tables, etc.▼▲Mathematical formulas, There are chemical formulas, tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas, Includes tables, etc.▼ and ▲Mathematical formulas, chemical formulas, tables, etc.▼ In the above formula, Y'41, Y'42, Y'43, Y'44, Y'45, Y'46, Y'47, Y '48, Y'49, Y'50, Y'51, Y''48, Y'52, Y'53, Y '54, Y'55, Y'56, Y'57, Y''59, Y'58, Y'59, Y '60, Y'61 and Y'62 may be the same or different, and Y'41, Y' 45, Y'48, Y'52, Y'56 and Y'59 are one or more hydrogens, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲mathematical formula, chemical formula , tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas, chemical formulas, There are tables etc. ▼, A'4, A'5, A'6, A'7, A'8 and A'9 is synonymous with the above R1, X'14, X'15, X'16, X'17, X'18 and X'19 may be the same or different. O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH(CH3)O, -CH(CN)O-, -CH=NO-, -C(CH3)= NO-, -CH2CH2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, and X, R3, R4, R5, Y1, Y2, Y3 and Y 4. The method according to claim 1, wherein 4 has the same meaning as above. 15. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, A'10 has the same meaning as R1, X'20 is synonymous with the above X, A'11 is a substituted or unsubstituted five-membered heterocyclic ring having at least one nitrogen atom a ring system in which the permissible substituents can be the same or different and contain one or more Hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkyl Koxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloal Kenylthio, Thiocyano, Propargylthio, Hydroxyimino, Alkoxy Mino, trialkylsilyloxy, aryldialkylsilyloxy, trially silyloxy, formamidino, alkyl sulfamide, dialkyl sulfamide amide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, Amino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl Bonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkyla minothiocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, Formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy , alkoxycarbonyl, substituted amino (in which case the permissible substituents may be the same or 1 or 2 propargyl, alkoxyalkyl, alkyl which may be different ruthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, poly Lihaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl , alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl Sulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, Aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, Phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Bonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloal Kenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkeni polyoxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkynyl Canol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonyl hydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl Oximinomethyl, hydrazonomethyl, substituted or unsubstituted arylhydra Zonomethyl, hydroxy group condensed with mono-, di- or polysaccharide, halide loalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryl Oxy, aralkoxy, arylthio, aralkylthio, alkylthioal Kyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, Loalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, loalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyh loalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, Propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxy carbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylamino Sulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxy Rukylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy cy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alkyloxy Kenylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyl Oxy, polyhaloalkylsulfonyloxy, aroylamino, haloacylami No, alkoxycarbonyloxy, arylsulfonylamino, aminocarbony ruoxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl(alkyl)amino, a alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphos Finothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, Hydroxyamino, alkoxyamino, aryloxyamino, aryloxy imino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalco xy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dia Rukylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and Y′′63 and Y′64 may be the same or different and may contain one or more hydrogen, halogen, or alkyl carbon. carbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, alkylcarbonylalkyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, Coxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, propane lugylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy , aryldialkylsilyloxy, triarylsilyloxy, formamidi No, alkyl sulfamide, dialkyl sulfamide, alkoxysulfonyl, Polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl, alkaline Kylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, Alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, silyl Ano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alcohol xy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted alkyl mino (in this case, the permissible substituents may be the same or different and have 1 or 2 substituents) Propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alkyl kenyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloalkenyl Haloalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino, Alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloal Kylcarbonylamine, trialkylsilyl, aryldialkylsilyl, tricarbonylamine Arylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alkali Koxycarbonylamino, alkylaminocarbonyloxy, dialkylamino carbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkenyl quinyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, Polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino , semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, alkoxy iminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazono Methyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- or Hydroxy group, haloalkyl, haloalkenyl, halocondensed with polysaccharide loalkynyl, alkoxyalkyl, aryloxy, aralkoxy, ary ruthio, araalkylthio, alkylthioalkyl, arylthioalkyl, lylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloa rukylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkyl Nylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, alco xysulfonyl, aryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminokulfonyl, Alkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl Honyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbony alkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, alloyloxy yloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ary sulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy Nyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy , arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanate t, isothiocyano, cycloalkylamino, trialkylammonium, ali arylamino, aryl(alkyl)amino, araalkylamino, alkoxy Rukylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydro xyphosphinil, dialkoxyphosphino, hydroxyamino, alkoxy Mino, aryloxyamino, aryloxyimino, oxo, thiono, alkyl lylaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy, Rukoxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X, =X , -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼or ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 16. The compound ▲There are mathematical formulas, chemical formulas, tables, etc.▼▲There are mathematical formulas, chemical formulas, tables, etc.▼▲Mathematical formulas, There are chemical formulas, tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas, Includes tables, etc.▼ and ▲Mathematical formulas, chemical formulas, tables, etc.▼ In the above formula, Y'65, Y'66, Y'67'Y'68, Y'69, Y'70, Y'71, Y '72, Y'73, Y'74, Y'75, Y'76, Y'77, Y'78, Y, 79, Y'80 and Y'81 may be the same or different, and Y'67, Y'7 0, Y'73, Y'76 and Y'79 are one or more hydrogen, halogen, atom alkylcarbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl Alkoxycarbonylalkylthio, Polyhaloalkenylthio, Thiocyano , propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl silyloxy, aryldialkylsilyloxy, triarylsilyloxy, holoxy, muamidino, alkyl sulfamide, dialkyl sulfamide, alkoxysulf Honyl, polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl , alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl Bonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, Toro, cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl , alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl , substituted amino (in this case, the permissible substituents may be the same or different and one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl alkenyl, haloalkenyl or polyhaloalkenyl), alkyl radical E, polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl Nyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonyl Amino, alkylcarbonylamino, polyhaloalkylsulfonylamino, poly Haloalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivatives salt, alkoxycarbonylamino, alkylaminocarbonyloxy, dialkyl ruaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy cy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloal Quinyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalky ruamino, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, Lukoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, drazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- - or hydroxy group, haloalkyl, haloalke fused with polysaccharide Nyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy , arylthio, aralkylthio, alkylthioalkyl, arylthioal Kyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl , haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, loalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl , alkoxysulfonyl, aryloxysulfonyl, propargyloxy, alkoxysulfonyl loyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosul Honyl, alkylaminosulfonyl, dialkylaminosulfonyl, aryla minosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxy carbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy cy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy , arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl rusulfonyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy oxy, arylsulfonylamino, aminocarbonyloxy, cyanato, i socyanato, isothiocyano, cycloalkylamino, trialkylammonium , arylamino, aryl(alkyl)amino, araalkylamino, alkylamino Koxyalkylphosphinyl, Alkoxyalkylphosphinothioyl, Alkylphosphinyl hydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkaline Koxyamino, aryloxyamino, aryloxyimino, oxo, thiono , alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalco xy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, - X, =X, -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼or▲There are mathematical formulas, chemical formulas, tables, etc. is ▼, and r' is a value of 0 or 1, A'12, A'13, A'14, A'15, A'16 and A'17 are the same as R1 above. are synonymous, X'21, X'22, X'23, X'24, X'25 and X'26 are the same as X above. righteousness, X, R3, R4, R5'Y1, Y2, Y3 and Y4 have the same meanings as above; The method described in Box 1. 17. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the ceremony Y'82, Y'83, Y'84, Y'85 and R'17 are the same or different. Hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkyl alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloa rukenylthio, thiocyano, propargylthio, hydroxyimino, alkoxy imino, trialkylsilyloxy, aryldialkylsilyloxy, thoria lylsilyloxy, formamidino, alkylsulfamide, dialkylsulf famid, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy , amino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl Rubonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkyl Aminothiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivative salts , formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy cy, alkoxycarbonyl, substituted amino (in which case the permissible substituents are the same) may also be different, including one or two propargyl, alkoxyalkyl, alkyl Kylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalke ), alkylthio, polyhaloalkylthio, alkylsulfinyl, Polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl Rusulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl , aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts , phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Rubonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloa alkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalke Nyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkynyloxy Lukanol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbo Nylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl hydroxyiminomethyl, hydrazonomethyl, substituted or unsubstituted arylhydride hydroxy group fused with lazonomethyl, mono-, di- or polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, ary ruoxy, aralkoxy, arylthio, aralkylthio, alkylthioa alkyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, poly Haloalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl , propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloyloxy cycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylami Nosulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxy Alkylthio, alkoxycarbonylalkoxy, acyloxy, haloacylthio xy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, a rukenylsulfonyloxy, arylsulfonyloxy, haloalkylsulfony oxy, polyhaloalkylsulfonyloxy, aroylamino, haloacylua Mino, alkoxycarbonylokidi, arylsulfonylamino, aminocarbo Nyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino , trialkylammonium, arylamino, aryl(alkyl)amino, araalkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinyl Sphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino , hydroxyamino, alkoxyamino, aryloxyamino, aryloxamino Shiimino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalk koxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, di Alkylsulfonium, -X, =X, -X=R3, =X-R3, ▲-X-R3, There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and X'27 is the same as the above X. and X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) The method according to claim 1, comprising: 18. The compound ▲There are mathematical formulas, chemical formulas, tables, etc.▼▲There are mathematical formulas, chemical formulas, tables, etc.▼ and ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ having a formula selected from: R'18 and Y'90 may be the same or different and represent one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarpazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲mathematical formula, chemical formula , tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas, chemical formulas, There are tables etc. ▼, and A'18 is synonymous with R1 above, X'29 is synonymous with the above X, Claims in which X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above The method described in Box 1. 19. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'19 has the same meaning as R1, X'30 is synonymous with the above X, Z'1 and Z'2 are each O, S, C1-C8 alkylidene, substituted or unsubstituted benzylidene, NH or NR''' (where R''' is alkyl, aryl, aralkyl, alkenyl or alkynyl), Y'91 and Y'92 are each halogen, alkyl or alkoxy) The method according to claim 1, comprising: 20. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'20 has the same meaning as R1, X'31 is synonymous with the above X, Z'3 is O, S, C1-C8 alkylidene, substituted or unsubstituted benzylidene , NH or NR''' (where R''' is alkyl, aryl, aralkyl, alkenyl or alkynyl), Y'93, Y'94 and Y'95 may be the same or different and represent hydrogen, halogen , alkylcarbonyl, alkylcarbonylalkyl, alkoxycarbonyl alkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio, thiosyl Ano, propargylthio, hydroxyimino, alkoxyimino, trialkyl silyloxy, aryldialkylsilyloxy, triarylsilyloxy, Formamidino, alkyl sulfamide, dialkyl sulfamide, alkoxy Sulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, aminocal Bonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothio Carbonyl, alkylaminothiocarbonyl, dialkylaminethiocarbonyl , nitro, cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl Kyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbo Nyl, substituted amino (in which case permissible substituents may be the same or different) 1 or 2 propargyl, alkoxyalkyl, alkylthioalkyl, alkyl alkyl, alkenyl, haloalkenyl or polyhaloalkenyl), alky ruthio, polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulf finyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonyl nylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, Polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkyl Silyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivatives Derivative salt, alkoxycarbonylamino, alkylaminocarbonyloxy, dia rkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyl Oxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhalo Alkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoa Lucylamino, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl , alkoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl , hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono- , hydroxy group condensed with di- or polysaccharide, haloalkyl, haloar rukenyl, haloalkynyl, alkoxyalkyl, aryloxy, araalco xy, arylthio, aralkylthio, alkylthioalkyl, arylthio Alkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl Nyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy , haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl Nyl, alkoxysulfonyl, aryloxysulfonyl, propargyloxy , aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, amino Sulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, ary Ruaminosulfonyl, carboxyalkoxy, carboxyalkylthio, alco oxycarbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyl Oxy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy xy, arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloa Rukylsulfonyloxy, aroylamino, haloacylamino, alkoxylic Bonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato , isocyanato, isothiocyano, cycloalkylamino, trialkylammo nium, arylamino, aryl(alkyl)amino, araalkylamino, Alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, Alkoxyamino, aryloxyamino, aryloxyimino, oxo, thi ono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxy alkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium , -X, =X, -X=R3, =X-R3, -X-R3, ▲ Numerical formulas, chemical formulas, tables, etc. Yes▼,▲There are mathematical formulas, chemical formulas, tables, etc.▼or▲There are mathematical formulas, chemical formulas, tables, etc. ▼, and X'R3, R4, R5, Y1, Y2, Y3 and Y4 are the same as above. righteousness) The method according to claim 1, comprising: 21. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'21 has the same meaning as R1, X'32 is synonymous with the above X, Y'96, Y'97, Y'98 and Y'99 may be the same or different, and hydrogen , halogen, alkyl or alkoxy). Law. 22. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'22 has the same meaning as R1, X'33 and Z'4 are hydrogen, halogen, hydroxy, alkyl, alkoxy, respectively , alkylcarbonyl or alkoxycarbonyl) The method according to claim 1, comprising: 23. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 24. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1. 25. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 26. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 27. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 28. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 29. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 30. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 31. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 32. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 33. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 34. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 35. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 36. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 37. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 38. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 39. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 40. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ The method according to claim 1, comprising: 41. Removes water from the plant surface without substantially inhibiting plant photosynthetic electron transport Applying to the plant surface an effective amount of the compound of claim 105 sufficient to reduce losses. A method for reducing water loss from plants, characterized by: 42. Water loss from the plant surface without substantially inhibiting the photoreaction of plant photosynthesis Claim 1, wherein an effective amount of the compound is applied to the plant surface, sufficient to reduce loss. Method. 43. Claims that apply the compound to the plant surface in the absence of substantial water pressure on the plant The method described in Box 1. 44. Claim 1: The compound is applied to the plant surface during a period before the reproductive growth period of the plant. The method described in. 45. Claims applying the compound to the plant surface during a period prior to substantial soil water loss The method described in 1. 46. Claim 1, wherein the compound is applied to the plant surface during the reproductive growth period of the plant. Method. 47. Approximately 0.0 per are. Apply the compound to the plant surface at a compound concentration of 1 to 100 bonds. The method according to claim 1 as applicable. 48. Approximately 0.0 per are. Apply the compound to the plant surface at a compound concentration of 25 to 15 bonds. The method according to claim 1 as applicable. 49. Claim 1 in which the plant is an agricultural or horticultural crop, an ornamental plant, or a lawn How to put it on. 50. Plants such as corn, cotton, sweet potato, potato, alfalfa, wheat, and lava Wheat, highland rice, barley, oats, sorghum, dry beans, soybeans, sugar icons, sunflowers, tobacco, tomatoes, canola, deciduous fruits, citrus fruits, tea, coconut -He, olive, pineapple, cocoa, banana, sugar cane, Guinea oil Choose from palms, herbaceous bedding plants, trees, lawns, ornamental plants, evergreens, trees and flowers. The method according to claim 1, wherein the method is selected. 51. 2. A method according to claim 1, wherein the plants are transplanted stock. 52. The transplanted stock is tobacco, tomato, eggplant, cucumber, lettuce, and strawberry. Claim 1 selected from berries, herbaceous flowerbed plants, trees, and tree seedlings. How to put it on. 53. Crop yield without substantially inhibiting plant photosynthetic electron transfer to the crop An effective amount sufficient to increase the formula: R1-X-R2 (In the formula, R1 is a monocyclic aromatic or non-aromatic ring system, a bicyclic aromatic or non-aromatic ring system , substituted or unsubstituted selected from polycyclic aromatic or non-aromatic ring systems and bridged ring systems. a substituted carbocyclic or heterocyclic ring system, which ring system may be saturated or unsaturated; , the permissible substituents may be the same or different and contain one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a laalkoxy, arylthio, aralkylthio, furkylthioalkyl, aryl arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc. ▼, or R1 is a substituted different atom or substituted carbon atoms, or two or more carbon atoms or different atoms and Substituted or unsubstituted straight or branched chains containing any combination of permissible substituents. and the substituents may be the same or different and contain one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Bidroximino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkokyl, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and X is a covalent single bond or a double bond. double bonds, substituted or unsubstituted heteroatoms or substituted carbon atoms, or two or more or more carbon atoms or heteroatoms in combination with the following permissible substituents: Substituted or unsubstituted linear or branched chain, in which the substituents may be the same or different. optionally one or more hydrogen, halogen, alkylcarbonyl, alkyl Carbonyl alkyl, alkoxycarbonyl alkyl, alkoxycarbonyl alkyl Rukylthio, polyhaloalkenylthio, thiocyano, propargylthio, hydro ximino, alkoxyimino, trialkylsilyloxy, aryl dialkyl Lucilyloxy, triarylsilyloxy, formamidino, alkylsulfur Amide, dialkylsulfamide, alkoxysulfonyl, polyhaloalkoxy Sulfonyl, hydroxy, amino, aminocarbonyl, alkylaminocarbonyl , dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothio Carbonyl, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl Rubonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloal Kyl, polyhaloalkokyl, alkoxycarbonyl, substituted amino (allowed in this case) The substituents that can be substituted may be the same or different and include one or two propargyl, a Rukoxyalkyl, alkylthioalkyl, alkyl, alkenyl, haloalke or polyhaloalkenyl), alkylthio, polyhaloalkylthio, Alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, Polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonyl Amino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamide -, trialkylsilyl, aryldialkylsilyl, triarylsilyl, Sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alkoxycarbonyl alcohol mino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyl Oxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyl Oxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonome thyl, alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazonomethyl, substituted or is unsubstituted arylhydrazonomethyl, mono, di- or polysaccharide Condensed hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkyl Koxyalkyl, aryloxy, aralkoxy, arylthio, aralkyl ruthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl , arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloal Kenylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, Ryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyh loacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosul Honyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxy Alkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, acyl halooxy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkyloxy Rusulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy , haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, alloy Ruamino, haloacylamino, alkoxycarbonyloxy, arylsulfony Ruamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano , cycloalkylamino, trialkylammonium, arylamino, ary (alkyl)amino, araalkylamino, alkoxyalkylphosphinyl , alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, arylox Cyamino, aryloxyimino, oxo, thiono, alkylaminoalkoxy , dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl , cyanoalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X -R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼,▲Mathematical formulas, chemical formulas, tables, etc. There are ▼ or ▲ there are mathematical formulas, chemical formulas, tables, etc. ▼, and R2 is a monocyclic aromatic Aromatic or non-aromatic ring systems, bicyclic aromatic or non-aromatic ring systems, polycyclic aromatic or substituted or unsubstituted at least one selected from non-aromatic ring systems and bridged ring systems. is a heterocyclic ring system having one nitrogen atom, said ring system being saturated or unsaturated. and the permissible substituents can be the same or different and include one or more Hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxy cyclocarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkeni ruthio, thiocyano, propargylthio, hydroxyimino, alkoxyimino , trialkylsilyloxy, aryldialkylsilyloxy, triaryl Silyloxy, formamidino, alkylsulfamide, dialkylsulfamide alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino No, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl aminothiocarbonyl, alkylaminothiocarbonyl, dialkylamino Thiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivative salts, phor Muamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, a alkoxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) may contain one or two propargyl, alkoxyalkyl, alkylthi oalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhalylthio loalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Alkylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfur honylamino, polyhaloalkylcarbonylamino, trialkylsilyl, ali dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphorus Fonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino oxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkeni alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy xy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkano ol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrogen Dorazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxy Shiiminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazono Hydroxy group fused with methyl, mono-, di- or polysaccharide, halo alkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, arylox cy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl , arylthioalkyl, arylsulfinyl, arylsulfonyl, haloar Rukylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloa rukynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloa rukenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, pro- pargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycal Bonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl Honyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkyl ruthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, Polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alkeni rusulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy cy, polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, Alkoxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy xy, cyanato, isocyanato, isothiocyano, cycloalkylamino, tri Alkylammonium, arylamino, aryl(alkyl)amino, araa Lucylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphine Notioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydro Roxiamino, alkoxyamino, aryloxyamino, aryloxyimine No, oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy , alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Rusulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ Formula, There are chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas , tables, etc. are available▼, and R3 is a monocyclic aromatic or non-aromatic ring system, or a bicyclic ring system. Aromatic or non-aromatic ring systems, polycyclic aromatic or non-aromatic ring systems and bridged ring systems a substituted or unsubstituted carbocyclic or heterocyclic ring system selected from The system may be saturated or unsaturated, and the permissible substituents may be the same or different. one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonyl alkyl, alkoxycarbonylalkyl, alkoxycarbonylalkylthi E, polyhaloalkenylthio, thiocyano, propargylthio, hydroxyimide No, alkoxyimino, trialkylsilyloxy, aryldialkylsilyl oxy, triarylsilyloxy, formamidino, alkylsulfamide, Dialkylsulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl hydroxyl, amino, aminocarbonyl, alkylaminocarbonyl, dia alkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl ru, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and its derived salts, formamide, alkyl, alkoxy, polyhaloalkyl, poly lyhaloalkoxy, alkoxycarbonyl, substituted amino (acceptable in this case) Substituents may be the same or different, including one or two propargyl, alkoxy alkyl, alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloalkylthio, alkyl Sulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhalo Alkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino, Polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, tri- Alkylsilyl, aryldialkylsilyl, triarylsilyl, sulfonic acid and derivative salts thereof, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkoxycarbonylamino, Rukylaminocarbonyloxy, dialkylaminocarbonyloxy, alkeni polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, Polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, a alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or Unsubstituted aryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- or polysaccharide condensed with Hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy aralkyl, aryloxy, aralkoxy, arylthio, aralkylthio, Alkylthioalkyl, arylthioalkyl, arylsulfinyl, ary rusulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloal Kenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenyls sulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryl xysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl , aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxyalkoxy cy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy , haloacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfo Nyloxy, alkenylsulfonyloxy, arylsulfonyloxy, haloar rukylsulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino , haloacylamino, alkoxycarbonyloxy, arylsulfonylamino , aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cyclo alkylamino, trialkylammonium, arylamino, aryl (alkylamino) amino, araalkylamino, alkoxyalkylphosphinyl, alco xyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialco xyphosphino, hydroxyamino, alkoxyamino, aryloxyamino , aryloxyimino, oxo, thiono, alkylaminoalkoxy, dial Kylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, cyano Alkoxy, dialkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc. ▼, or R3 is a substituted different atom or substituted carbon atoms, or two or more carbon atoms or different atoms and Substituted or unsubstituted straight or branched chains containing any combination of permissible substituents. and the substituents may be the same or different and contain one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkokyl, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and Y1 and Y4 are each oxygen or sulfur, Y2 and Y3 are each oxygen, sulfur, amino or a covalent bond, R4 and R5 are each hydrogen, substituted or unsubstituted alkyl, polyhaloalkyl, phenyl or benzyl, the permissible substituents being the same or different; Often one or more hydrogen, halogen, alkylcarbonyl, alkylcarboxylate Nylalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkyl Thio, polyhaloalkenylthio, thiocyano, propargylthio, hydroxyl Mino, alkoxyimino, trialkylsilyloxy, aryldialkylsilyl ruoxy, triarylsilyloxy, formamidino, alkylsulfamide , dialkylsulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl Nyl, hydroxy, amino, aminocarbonyl, alkylaminocarbonyl, di alkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbo Nyl, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloalkyl, Polyhaloalkoxy, alkoxycarbonyl, substituted amino (in this case acceptable) The substituents may be the same or different and include one or two propargyl, alkoxy, Sialkyl, alkylthioalkyl, alkyl, alkenyl, haloalkenyl or is polyhaloalkenyl), alkylthio, polyhaloalkylthio, alkylthio Rusulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, polyhalogen loalkylsulfonyl, alkylsulfonylamino, alkylcarbonylamino , polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, Realkylsilyl, aryldialkylsilyl, triarylsilyl, sulfone Acids and their derivative salts, phosphonic acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alke Nyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy , polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy , polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, Alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or is unsubstituted aryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- or polysaccharides hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxy Alkyl, aryloxy, aralkoxy, arylthio, aralkylthio , alkylthioalkyl, arylthioalkyl, arylsulfinyl, aryl lsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloa rukenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenyl Sulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryl Oxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl , dialkylaminosulfonyl, arylaminosulfonyl, carboxyalco xy, carboxyalkylthio, alkoxycarbonylalkoxy, acyloxy cy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkylsulfur Honyloxy, alkenylsulfonyloxy, arylsulfonyloxy, halo Alkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroylamine No, haloacylamino, alkoxycarbonyloxy, arylsulfonylamino do, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cyclo loalkylamino, trialkylammonium, arylamino, aryl (aryl) (alkyl)amino, araalkylamino, alkoxyalkylphosphinyl, alkylamino, Koxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dial Koxyphosphino, hydroxyamino, alkoxyamino, aryloxyamino No, aryloxyimino, oxo, thiono, alkylaminoalkoxy, dia Rukylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, sia Noalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X-R3 ， -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. Applying a compound that is ▼ or ▲ has a mathematical formula, chemical formula, table, etc. ▼ A method for increasing the yield of plants characterized by: 54. R1 and R3 each have the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ Monocyclic aromatic or non-aromatic ring system with; ▲Mathematical formulas, chemical formulas, tables, etc. ▼ as well as ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ Bicyclic aromatic or non-aromatic ring system having a formula selected from; ▲ mathematical formula, chemical formula , tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas, tables, etc. Has a formula selected from ▼ and ▲ has mathematical formulas, chemical formulas, tables, etc. ▼ polycyclic aromatic or non-aromatic ring systems; and ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ as well as ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ a saturated or unsaturated bridged ring system having a formula selected from; or an unsubstituted carbocyclic or heterocyclic ring system, in the above formula, A1 is a carbon having 0 to 4 double bonds or 0 to 2 triple bonds together with B1 a ring-forming chain of atoms forming a ring system or a heterocyclic system, B1 is a saturated or unsaturated carbon atom, A2 and A3 together with B2 and B3 respectively A ring-forming chain of atoms that together form a carbocyclic or heterocyclic system, and B2 and B3 is a saturated or unsaturated carbon atom or a saturated nitrogen atom, respectively; A4, A5, A6 and A7 together with B4, B5, B6 and B7 respectively are carbon a ring-forming chain of atoms forming a ring system or a heterocyclic system, B4, B5, B6, and B7 are each saturated or unsaturated carbon atoms or saturated nitrogen atoms and A8, A9 and A10 together with B8, B9, B10 and B11 respectively form carbon a ring-forming chain of atoms forming a ring system or a heterocyclic system, 88, B9 and B10 are each a saturated or unsaturated carbon atom or a saturated nitrogen atom , B111 is a saturated or unsaturated carbon atom, nitrogen atom or phosphorus atom, A11, A12 and A13 together with B12 and B13 respectively form a carbocyclic ring system or is a ring-forming chain of atoms forming a heterocyclic ring system, and B12 and B13 are each a saturated carbon An elemental atom or a nitrogen atom, and Z may be the same or different and one or more hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkyl Oxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalke Nylthio, thiocyano, propargylthio, hydroxyimino, alkoxyimine -, trialkylsilyloxy, aryldialkylsilyloxy, triary lucilyloxy, formamidino, alkylsulfamide, dialkylsulfur mido, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, a mino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbo Nyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylami Notiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivative salts, lumamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (in which case permissible substituents may be the same or different) May contain one or two propargyl, alkoxyalkyl, alkyl thioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, poly Haloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl , alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl sulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, Lyldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphoric acid Sulfonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbo Nyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalke Nyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyl Oxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalka Nor, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonyl hydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl group ximinomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazo Hydroxy group fused with monomethyl, mono-, di- or polysaccharide, halo Alkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryl xy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl aryl, arylthioalkyl, arylsulfinyl, arylsulfonyl, halo Alkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, halo Alkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhalo alkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, lopargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxyca rubonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminos sulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyal Kylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy , polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alke Nylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy xy, polyhaloalkylsulfonyloxy, aroylamino, haloacylamino , alkoxycarbonyloxy, arylsulfonylamino, aminocarbonyl Oxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, to Realkylammonium, arylamino, aryl(alkyl)amino, ara Alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosph dinotioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, Droxyamino, alkoxyamino, aryloxyamino, aryloxyamino Mino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy cy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dial Killsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲Formula There are , chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas, There are chemical formulas, tables, etc. ▼, R3, R4, R5, Y1, Y2, Y3, Y4 54. The method of claim 53, wherein and X are as defined above. 55. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'1 may be the same or different and may be one or more hydrogen, halogen, alkali Kylcarbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl , alkoxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, Propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl Oxy, aryldialkylsilyloxy, triarylsilyloxy, form Amidino, alkyl sulfamide, dialkyl sulfamide, alkoxy sulfonate Nyl, polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl , alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbo Nyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nito cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, Substituted amino (in this case, the permissible substituents may be the same or different, and one or more substituents may be substituted) is two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl , alkenyl, haloalkenyl or polyhaloalkenyl), alkylthio , polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulfini alkylsnephonyl, polyhaloalkylsulfonyl, alkylsulfonyl Mino, alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhal Loalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl , triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts , alkoxycarbonylamino, alkylaminocarbonyloxy, dialkyl Aminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy , alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkyl Nyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkyl Amino, Semicarbazonomethyl, Alkoxycarbonylhydrazonomethyl, Al Coxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydro Lazonomethyl, substituted or unsubstituted arylhydrazonomethyl'mono-, di- Or hydroxy group, haloamelekyl, haloalke, condensed with polysaccharide Nyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy , arylthio, aralkylthio, alkylthioalkyl, arylthioal Kyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl , haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, loalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl , alkoxysulfonyl, aryloxysulfonyl, propargyloxy, alkoxysulfonyl loyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosul Honyl, alkylaminosulfonyl, dialkylaminosulfonyl, aryla minosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxy carbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy cy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy , arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl rusulfonyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy oxy, arylsulfonylamino, aminocarbonyloxy, cyanato, i socyanato, isothiocyano, cycloalkylamino, trialkylammonium , arylamino, aryl(alkyl)amino, araalkylamino, alkylamino Koxyalkylphosphinyl, Alkoxyalkylphosphinothioyl, Alkylphosphinyl hydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkaline Koxyamino, aryloxyamino, aryloxyimino, oxo, thiono , alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalco xy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, - X,=X,-X=R3,=X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ and X'1 is O, S, SO, S O2, NH, CH2, CO, single covalent bond, CH2O, CH2S, -CH(CH 3) O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, - CH2CH2O-, -CH2CH2-, -C≡C-, -CH2SO-, -CH2 SO2-, -OCH2CH2O-, -CH(alkyl)- or -CONH- , Y'1 and Y'2 are each halogen, alkyl or alkoxy, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 56. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'2 and R'3 may be the same or different and represent one or more water element, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxy carbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenyl Thio, thiocyano, propargylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy Ryloxy, formamidino, alkyl sulfamide, dialkyl sulfamide , trialkylsilyloxy, polyhaloalkoxysulfonyl, hydroxy, a mino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbo Nyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylami Notiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivative salts, lumamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (in this case, permissible substituents are the same or different) May contain one or two propargyl, alkoxyalkyl, alkyl thioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, poly Haloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl , alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl sulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, Lyldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphoric acid Sulfonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbo Nyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalke Nyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyl Oxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalka Nor, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonyl hydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl group ximinomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazo Hydroxy group fused with monomethyl, mono-, di- or polysaccharide, halo Alkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryl xy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl aryl, arylthioalkyl, arylsulfinyl, arylsulfonyl, halo Alkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, halo Alkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhalo alkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, lopargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxyca rubonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminos sulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyal Kylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy , polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alke Nylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy xy, polyhaloalkylsulfonyloxy, aroylamino, haloacylamino , alkoxycarbonyloxy, arylsulfonylamino, aminocarbonyl Oxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, to Realkylammonium, arylamino, aryl(alkyl)amino, ara Alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosph dinotioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, Droxyamino, alkoxyamino, aryloxyamino, aryloxyamino Mino, oxo, chono, alkylaminoalkoxy, dialkylaminoalkoxy cy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dial Killsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and X'2 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH(CH3)O-, -CH( CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -C≡C-, -CH2SO-, or -CH2SO2- and Y'3 is halogen, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 57. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'4, R'5 and R'6 may be the same or different and represent one or more water element, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxy carbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenyl Thio, thiocyano, propargylthio, hydroxyimino, alkoxyimino, trialkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy Ryloxy, formamidino, alkyl sulfamide, dialkyl sulfamide , alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino , aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl , aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl Ocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, form Amide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkyl Koxycarbonyl, substituted amino (in this case, permissible substituents are the same or different) may contain one or two propargyl, alkoxyalkyl, alkylthio Alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhalo Alkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, Rukylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl nylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl triarylsilyl, sulfonic acid and its derivative salts, phosphorus acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyl Oxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl , alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy cy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkano , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydride Razonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxy iminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonome Hydroxy group, haloalkaline group fused with methyl, mono-, di- or polysaccharide Kyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy , aralkoxy, arylthio, aralkylthio, alkylthioalkyl, Arylthioalkyl, arylsulfinyl, arylsulfonyl, haloal Kylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloal Quinyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloal Kenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propane Lugyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbo Nyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl Nyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkyl Thio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly Lihaloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyl Sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy , polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, a Rukoxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy Cy, cyanato, isocyanato, isothiocyano, cycloalkylamino, tria rukylammonium, arylamino, aryl(alkyl)amino, araal Kylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphino Thioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydro xyamino, alkoxyamino, aryloxyamino, aryloxyimino , oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, Alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Sulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and X'3 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH(CH3)O-, -CH( CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -C H(alkyl)- or -CONH-, X, R3, R4, R5, Y1, Y2 , Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 58. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in which case permissible substituents may be the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and Y'9, Y'10, Y' 11 and Y'12 may be the same or different and may be hydrogen, halogen, alkyl, or lyhaloalkyl, cyano or aryl; m' and n' may be the same or different and have a value of 0 to 5, X'4 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH( CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO- , -CH2CH2O-, -C≡C-, -CH2SO-, -CH2SO2-, -O CH2CH2O-, -CH(alkyl)- or -CONH-, and Y'13 and and Y'14 may be the same or different and represent halogen, alkyl or alkoxy. can be, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 59. The compound has the formula ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in this case, permissible substituents are the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲Math, chemistry There are formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas, chemical formulas , tables, etc. ▼, and Y'9 and Y'10 may be the same or different. hydrogen, halogen, alkyl, polyhaloalkyl, cyano or aryl, m' and n' may be the same or different and have a value of 0 to 5, x'5 is O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH( CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO- , -CH2CH2O-, -C≡C-, -CH2SO-, -CH2SO2-, -O CH2CH2O-, -CH(alkyl)- or -CONH-, and Y'15 is O or S, Y'91 and Y'92 are each halogen, X'6 is O or S, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 60. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in which case permissible substituents may be the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and X'7 is the same or different. O, S, SO, SO2, NH, CH2, CO, single covalent bond, -C H(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=N O-, -CH2CH2O-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl)- or -CONH-, and m' is It is a value of 0 to 5, Y'16 is hydrogen, alkyl, alkylcarbonyl, alkylsulfonyl or poly is haloalkylsulfonyl, Y'93 and Y'94 are each halogen, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 61. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'4, Y'5, Y'6, Y'7 and Y'8 may be the same or different, and hydrogen , halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxyca Rubonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio O, Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, To Realkylsilyloxy, aryldialkylsilyloxy, triarylsilyloxy ruoxy, formamidino, alkyl sulfamide, dialkyl sulfamide, Alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, Aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothio Carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamine Mido, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy xycarbonyl, substituted amino (in which case permissible substituents may be the same or different) Optionally one or two propargyl, alkoxyalkyl, alkylthioa is alkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloa Rukylsulfinyl, Alkylsulfonyl, Polyhaloalkylsulfonyl, Alkylsulfinyl Kylsulfonylamino, alkylcarbonylamino, polyhaloalkylsulfony Ruamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryl Dialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphones Acids and their derivative salts, alkoxycarbonylamino, alkylaminocarbonylamino xy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy , polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol , cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydra Zonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyi Minomethyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethy Hydroxy groups, haloalkyls fused with mono-, di- or polysaccharides haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, arylthio, aralkylthio, alkylthioalkyl, a Rylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Rusulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkyl Nyloxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalke Nylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, propal Gyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbony aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthi O, alkoxycarbonylalkoxy, acyloxy, haloacyloxy, poly haloacyloxy, aroyloxy, alkylsulfonyloxy, alkenyloxy sulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloalkylsulfonyloxy, aroylamino, haloacylamino, alkylamino Koxycarbonyloxy, Arylsulfonylamino, Aminocarbonyloxy , cyanato, isocyanato, isothiocyano, cycloalkylamino, trial Kylammonium, arylamino, aryl(alkyl)amino, aralky Ruamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothi oil, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Cyamino, alkoxyamino, aryloxyamino, aryloxyimino, Oxo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, a Rukoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl Ruphonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and Y'95 and Y'96 are Each is a halogen, and X, R3, R4, R5, Y1, Y2, Y3 and Y4 are the above-mentioned ) 54. The method of claim 53. 62. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, Y'19 and Y'21 may be the same or different and represent hydrogen, halogen, alkyl carbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl, a Rukoxycarbonylalkylthio, polyhaloalkenylthio, thiocyano, pro- pargylthio, hydroxyimino, alkoxyimino, trialkylsilylthio cy, aryldialkylsilyloxy, triarylsilyloxy, formamide dino, alkylsulfamide, dialkylsulfamide, alkoxysulfonyl , polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl, a Rukylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl , alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, Cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl, alkyl koxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, substituted Amino (in this case, the permissible substituents may be the same or different and include one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl, alkyl alkenyl, haloalkenyl or polyhaloalkenyl), alkylthio, polyhaloalkenyl Lihaloalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl, Alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonylamino , alkylcarbonylamino, polyhaloalkylsulfonylamino, polyhaloa alkylcarbonylamino, trialkylsilyl, aryldialkylsilyl, Realylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, a Rukoxycarbonylamino, alkylaminocarbonyloxy, dialkylamino Nocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, a rukynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl , polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamide No, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, alkoxy Shiiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazo monomethyl, substituted or unsubstituted arylhydrazonomethyl, mono, di- or is a hydroxy group condensed with a polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy, aryl ruthio, aralkylthio, alkylthioalkyl, arylthioalkyl, Arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, halo Alkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloal Quinylthio, Haloalkenylsulfonyl, Polyhaloalkenylsulfonyl, Al Koxysulfonyl, aryloxysulfonyl, propargyloxy, aroyl , haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl , alkylaminosulfonyl, dialkylaminosulfonyl, arylaminos sulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbo Nylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy, a Loyloxy, alkylsulfonyloxy, alkenylsulfonyloxy, ali sulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy Honyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy Cy, arylsulfonylamino, aminocarbonyl, oxy, cyanato, isocyanate Anato, isothiocyano, cycloalkylamino, trialkylammonium, Arylamino, aryl(alkyl)amino, araalkylamino, alkoxy Sialkylphosphinyl, Alkoxyalkylphosphinothioyl, Alkylphosphinyl droxyphosphinil, dialkoxyphosphino, hydroxyamino, alkoxy Cyamino, aryloxyamino, aryloxyimino, oxo, thiono, a alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy , alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼or▲There are mathematical formulas, chemical formulas, tables, etc.▼ , A′ has the same meaning as R1 above, X'10 is synonymous with the above X, Y'20 is halogen, cyano, alkyl, alkoxy, polyhaloalkyl, poly haloalkoxy or polyhaloalkylsulfonyloxy, X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 63. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'12 has the same meaning as R1, Y'22 is halogen, cyano, alkyl, alkoxy, polyhaloalkyl, poly haloalkoxy or polyhaloalkylsulfonyloxy, Y'23 is hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl , alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyh loalkenylthio, thiocyano, propargylthio, hydroxyimino, alco xiimino, trialkylsilyloxy, aryldialkylsilyloxy, Realylsilyloxy, formamidino, alkylsulfamide, dialkyl Sulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydro xy, amino, aminocarbonyl, alkylaminocarbonyl, dialkylami nocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dial Kylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivatives Derivative salt, formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalk Koxy, alkoxycarbonyl, substituted amino (in which case permissible substituents are the same) one or two propargyl, alkoxyalkyl, which may be one or different; Alkylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkyl (alkenyl), alkylthio, polyhaloalkylthio, alkylsulfini polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkyl sulfonyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloa rukylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsulfonylamino Lyle, aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivatives derivative salts, phosphonic acids and their derivative salts, alkoxycarbonylamino, alkylamino Nocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhalogen loalkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloa alkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluor loalkanol, cyanoalkylamino, semicarbazonomethyl, alkoxyca Rubonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted atom Ryloxyiminomethyl, hydrazonomethyl, substituted or unsubstituted aryl hydrazonomethyl, hydroxy condensed with mono-, di- or polysaccharides group, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, alkyl Ryloxy, aralkoxy, arylthio, aralkylthio, alkylthio oalkyl, arylthioalkyl, arylsulfinyl, arylsulfony haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy cy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, Polyhaloalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl Nyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryl Oxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkyl Aminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carbo xyalkylthio, alkoxycarbonylalkoxy, acyloxy, haloacyl oxy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy , alkenylsulfonyloxy, arylsulfonyloxy, haloalkylsulf Honyloxy, polyhaloalkylsulfonyloxy, aroylamino, haloacyl Ruamino, alkoxycarbonyloxy, arylsulfonylamino, aminocarbon Rubonyloxy, cyanato, isocyanato, isothiocyano, cycloalkyla mino, trialkylammonium, arylamino, aryl(alkyl)amino ノ、araalkylamino、alkoxyalkylphosphinyl、alkoxyalkyl Ruphosphinothioyl, Alkylhydroxyphosphinyl, Dialkoxyphosph ino, hydroxyamino, alkoxyamino, aryloxyamino, aryl Oximino, oxo, thiono, alkylaminoalkoxy, dialkylamino alkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy , dialkylsulfonium, -X, -X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. There are ▼ or ▲ mathematical formulas, chemical formulas, tables, etc. ▼, and X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 64. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, A'1 has the same meaning as R2, Y'31 and Y'32 may be the same or different and represent halogen, alkyl or alkyl. Lukoxy) 54. The method of claim 53. 65. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, A'2 has the same meaning as R1, X'12 is synonymous with the above X, Y'33 and Y'34 may be the same or different and represent halogen, alkyl or alkyl. Lukoxy) 54. The method of claim 53. 66. The compound ▲There are mathematical formulas, chemical formulas, tables, etc.▼▲There are mathematical formulas, chemical formulas, tables, etc.▼▲Mathematical formulas, There are chemical formulas, tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas, Includes tables, etc.▼ and ▲Mathematical formulas, chemical formulas, tables, etc.▼ In the above formula, Y'41, Y'42, Y'43'Y'44, Y'45, Y'46, Y'47, Y '48, Y'49, Y'50, Y'51, Y''48, Y'52, Y'53, Y '54, Y'55, Y'56, Y'57, Y''59, Y'58, Y'59, Y '60, Y'61 and Y'62 may be the same or different, and Y'41, Y' 45, Y'48, Y'52, Y'56 and Y'59 are one or more hydrogens, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomedyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkylaminoalkoxy Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲There are mathematical formulas, chemical formulas, tables, etc.▼, and A'4, A'5, A'6, A '7, A'8 and A'9 are synonymous with the above R1, X'14, X'15, X'16, X'17, X'18 and X'19 may be the same or different. O, S, SO, SO2, NH, CH2, CO, single covalent bond, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3) =NO-, -CH2CH2O-, -C≡C-, -CH2SO-, -CH2SO2 -, -OCH2CH2O-, -CH(alkyl)- or -CONH-, and , R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above. 53. 67. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, A'10 has the same meaning as R1, X'20 is synonymous with the above X, A'11 is a substituted or unsubstituted five-membered heterocyclic ring having at least one nitrogen atom a ring system in which the permissible substituents can be the same or different and contain one or more Hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkyl Koxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloal Kenylthio, Thiocyano, Propargylthio, Hydroxyimino, Alkoxy Mino, trialkylsilyloxy, aryldialkylsilyloxy, trially silyloxy, formamidino, alkyl sulfamide, dialkyl sulfamide amide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, Amino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl Bonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkyla minothiocarbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, Formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy , alkoxycarbonyl, substituted amino (in which case the permissible substituents may be the same or 1 or 2 propargyl, alkoxyalkyl, alkyl which may be different ruthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl ), alkylthio, polyhaloalkylthio, alkylsulfinyl, poly Lihaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl , alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl Sulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, Aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, Phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Bonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloal Kenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalkeni polyoxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkynyl Canol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbonyl hydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl Oximinomethyl, hydrazonomethyl, substituted or unsubstituted arylhydra Zonomethyl, hydroxy group condensed with mono-, di- or polysaccharide, halide loalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryl Oxy, aralkoxy, arylthio, aralkylthio, alkylthioal Kyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, Loalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, loalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, polyh loalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl, Propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxy carbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylamino Sulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxy Rukylthio, alkoxycarbonylalkoxy, acyloxy, haloacyloxy cy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, alkyloxy Kenylyulfonyloxy, arylsulfonyloxy, haloalkylsulfonyl Oxy, polyhaloalkylsulfonyloxy, aroylamino, haloacylami No, alkoxycarbonyloxy, arylsulfonylamino, aminocarbony ruoxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl(alkyl)amino, a alkylamino, alkoxyalkylphosphinyl, alkoxyalkylphos Finothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, Hydroxyamino, alkoxyamino, aryloxyamino, aryloxy imino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalco xy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dia Rukylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲number There are formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ Mathematical formulas , chemical formulas, tables, etc. are ▼, and Y'63 and Y'64 are the same or different. optionally one or more hydrogen, halogen, alkylcarbonyl, alkyl Carbonyl alkyl, alkoxycarbonyl alkyl, alkoxycarbonyl alkyl Rukylthio, polyhaloalkenylthio, thiocyano, propargylthio, hydro ximino, alkoxyimino, trialkylsilyloxy, aryl dialkyl Lucilyloxy, triarylsilyloxy, formamidino, alkylsulfur Amide, dialkylsulfamide, alkoxysulfonyl, polyhaloalkoxy Sulfonyl, hydroxy, amino, aminocarbonyl, alkylaminocarbonyl , dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothio Carbonyl, dialkylaminothiocarbonyl, nitro, cyano, hydroxycarbonyl Rubonyl and its derivative salts, formamide, alkyl, alkoxy, polyhaloal Kyl, polyhaloalkoxy, alkoxycarbonyl, substituted amino (allowed in this case) The substituents that can be substituted may be the same or different and include one or two propargyl, a lunixyalkyl, alkylthioalkyl, alkyl, alkenyl, haloalke or polyhaloalkenyl), alkylthio, polyhaloalkylthio, Alkylsulfinyl, polyhaloalkylsulfinyl, alkylsulfonyl, Polyhaloalkylsulfonyl, alkylsulfonylamino, alkylcarbonyl Amino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamide -, trialkylsilyl, aryldialkylsilyl, triarylsilyl, Sulfonic acid and its derivative salts, phosphonic acid and its derivative salts, alkoxycarbonyl alcohol mino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, alkynyl, alkynyl Oxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyl Oxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonome thyl, alkoxycarbonylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, hydrazonomethyl, substituted or is unsubstituted arylhydrazonomethyl, mono-, di- or polysaccharide Condensed hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, alkyl Koxyalkyl, aryloxy, aralkoxy, arylthio, aralkyl ruthio, alkylthioalkyl, arylthioalkyl, arylsulfinyl , arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloal Kenylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, Ryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyh loacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosul Honyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxy Alkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, acyl halooxy, haloacyloxy, polyhaloacyloxy, aroyloxy, alkyloxy Rusulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy , haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, alloy Ruamino, haloacylamino, alkoxycarbonyloxy, arylsulfony Ruamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano , cycloalkylamino, trialkylammonium, arylamine, aryl (alkyl)amino, araalkylamino, alkoxyalkylphosphinyl , alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkoxyamino, arylox Cyamino, aryloxyimino, oxo, thiono, alkylaminoalkoxy , dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl , cyanoalkoxy, dialkylsulfonium, -X, =X, -X=R3, =X -R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. There are ▼ or ▲ mathematical formulas, chemical formulas, tables, etc. ▼, and X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 68. The compound ▲There are mathematical formulas, chemical formulas, tables, etc.▼▲There are mathematical formulas, chemical formulas, tables, etc.▼▲Mathematical formulas, There are chemical formulas, tables, etc. ▼▲ There are mathematical formulas, chemical formulas, tables, etc. ▼▲ Mathematical formulas, chemical formulas, Includes tables, etc.▼ and ▲Mathematical formulas, chemical formulas, tables, etc.▼ In the above formula, Y'65, Y'66, Y'67, Y'68, Y'69, Y'70, Y'71, Y '72, Y'73, Y'74, Y'75, Y'76, Y'77, Y'78, Y' 79, Y'80 and Y'81 may be the same or different, and Y'67, Y'7 0, Y'73, Y'76 and Y'79 are one or more hydrogen, halogen, atom alkylcarbonyl, alkylcarbonylalkyl, alkoxycarbonylalkyl Alkoxycarbonylalkylthio, Polyhaloalkenylthio, Thiocyano , propargylthio, hydroxyimino, alkoxyimino, trialkylsilyl silyloxy, aryldialkylsilyloxy, triarylsilyloxy, holoxy, muamidino, alkyl sulfamide, dialkyl sulfamide, alkoxysulf Honyl, polyhaloalkoxysulfonyl, hydroxy, amino, aminocarbonyl , alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl Bonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, Toro, cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl , alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl , substituted amino (in this case, the permissible substituents may be the same or different and one or two propargyl, alkoxyalkyl, alkylthioalkyl, alkyl alkenyl, haloalkenyl or polyhaloalkenyl), alkyl radical E, polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulfinyl Nyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonyl Amino, alkylcarbonylamino, polyhaloalkylsulfonylamino, poly Haloalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivatives salt, alkoxycarbonylamino, alkylaminocarbonyloxy, dialkyl ruaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy cy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhaloal Quinyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalky ruamino, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl, Lukoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl, drazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono-, di- - or hydroxy group, haloalkyl, haloalke fused with polysaccharide Nyl, haloalkynyl, alkoxyalkyl, aryloxy, aralkoxy , arylthio, aralkylthio, alkylthioalkyl, arylthioal Kyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl , haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, loalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl , alkoxysulfonyl, aryloxysulfonyl, propargyloxy, alkoxysulfonyl loyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosul Honyl, alkylaminosulfonyl, dialkylaminosulfonyl, aryla minosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxy carbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyloxy cy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy , arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl rusulfonyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy oxy, arylsulfonylamino, aminocarbonyloxy, cyanato, i socyanato, isothiocyano, cycloalkylamino, trialkylammonium , arylamino, aryl(alkyl)amino, araalkylamino, alkylamino Koxyalkylphosphinyl, Alkoxyalkylphosphinothioyl, Alkylphosphinyl hydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, alkaline Koxyamino, aryloxyamino, aryloxyimino, oxo, thiono , alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalco xy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, - X,=X,-X=R3,=X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and r' is a value of 0 or 1. the law of nature, A'12, A'13, A'14'A'15, A'16 and A'17 are the same as R1 above. are synonymous, X'21'X'22, X'23, X'24, X'25 and X'26 are the same as X above. righteousness, Claims in which X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above The method according to Box 53. 69. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the ceremony Y'82, Y'83, Y'84, Y'85 and R'17 are the same or different. Hydrogen, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkyl alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloa rukenylthio, thiocyano, propargylthio, hydroxyimino, alkoxy imino, trialkylsilyloxy, aryldialkylsilyloxy, thoria lylsilyloxy, formamidino, alkylsulfamide, dialkylsulf fuamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy , amino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl Rubonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkyl Aminothiocarbonyl, nitro, cyano, hydroxycarbonyl and their derivative salts , formamide, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy cy, alkoxycarbonyl, substituted amino (in which case the permissible substituents are the same) may also be different, including one or two propargyl, alkoxyalkyl, alkyl Kylthioalkyl, alkyl, alkenyl, haloalkenyl or polyhaloalke ), alkylthio, polyhaloalkylthio, alkylsulfinyl, Polyhaloalkylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl Nyl, alkylsulfonylamino, alkylcarbonylamino, polyhaloalkyl Rusulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl , aryldialkylsilyl, triarylsilyl, sulfonic acid and its derivative salts , phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbon Rubonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloa alkenyl, alkenyloxy, alkynyl, alkynyloxy, polyhaloalke Nyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkynyloxy Lukanol, cyanoalkylamino, semicarbazonomethyl, alkoxycarbo Nylhydrazonomethyl, alkoxyiminomethyl, substituted or unsubstituted aryl hydroxyiminomethyl, hydrazonomethyl, substituted or unsubstituted arylhydride hydroxy group fused with lazonomethyl, mono-, di- or polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, ary ruoxy, aralkoxy, arylthio, aralkylthio, alkylthioa alkyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloalkenylsulfonyl, poly Haloalkenylsulfonyl, alkoxysulfonyl, aryloxysulfonyl , propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloyloxy cycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylami Nosulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxy Alkylthio, alkoxycarbonylalkoxy, acyloxy, haloacylthio xy, polyhaloacyloxy, aroyloxy, alkylsulfonyloxy, a rukenylsulfonyloxy, arylsulfonyloxy, haloalkylsulfony oxy, polyhaloalkylsulfonyloxy, aroylamino, haloacylua Mino, alkoxycarbonyloxy, arylsulfonylamino, aminocarbo Nyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino , trialkylammonium, arylamino, aryl(alkyl)amino, araalkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinyl Sphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino , hydroxyamino, alkoxyamino, aryloxyamino, aryloxamino Shiimino, oxo, thiono, alkylaminoalkoxy, dialkylaminoalk koxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, di Alkylsulfonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, and X'27 is the same as the above X. and X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 70. The compound ▲There are mathematical formulas, chemical formulas, tables, etc.▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼ and ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ having a formula selected from: R'18 and Y'90 may be the same or different and represent one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, alkoxycar Bonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio , Thiocyano, Propargylthio, Hydroxyimino, Alkoxyimino, Tri Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, formamidino, alkyl sulfamide, dialkyl sulfamide, a alkoxysulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, amino Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca carbonyl, nitro, cyano, hydroxycarbonyl and its derivative salts, formamide do, alkyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxy cycarbonyl, substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, alkylthioalkyl (alkenyl, alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) , alkylthio, polyhaloalkylthio, alkylsulfinyl, polyhaloal Kylsulfinyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Rusulfonylamino, alkylcarbonylamino, polyhaloalkylsulfonyl Amino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldi Alkylsilyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and derivative salts thereof, alkoxycarbonylamino, alkylaminocarbonylox cy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a alkenyloxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, Polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, Cyanoalkylamino, semicarbazonomethyl, alkoxycarbonylhydrazo Nomethyl, alkoxyiminomethyl, substituted or unsubstituted aryloxyimine hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl , hydroxy group fused with mono-, di- or polysaccharide, haloalkyl , haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, ary arthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl Sulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkini halooxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni Rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl , aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl , arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio , alkoxycarbonylalkoxy, acyloxy, haloacyloxy, polyh loacyloxy, aroyloxy, alkylsulfonyloxy, alkenylsulf Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polymer Lihaloalkylsulfonyloxy, aroylamino, haloacylamino, alco oxycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato, isocyanato, isothiocyano, cycloalkylamino, trialkylamino ammonium, arylamino, aryl(alkyl)amino, araalkyl Amino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothio yl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy Amino, alkoxyamino, aryloxyamino, aryloxyimino, xo, thiono, alkylaminoalkoxy, dialkylaminoalkoxy, al Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsul Phonium, -X, =X, -X=R3, =X-R3, -X-R3, ▲There are mathematical formulas, chemical formulas, tables, etc.▼,▲There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲There are mathematical formulas, chemical formulas, tables, etc.▼, and A'18 is the same as R1 above. righteousness, X'29 is synonymous with the above X, Claims in which X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above The method according to Box 53. 71. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'19 has the same meaning as R1, X'30 is synonymous with the above X, Z'1 and Z'2 are each O, S, C1-C8 alkylidene, substituted or unsubstituted benzylidene, NH or NR''' (where R''' is alkyl, aryl, aralkyl, alkenyl or alkynyl), Y'91 and Y'92 are each halogen, alkyl or alkoxy) 54. The method of claim 53. 72. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'20 has the same meaning as R1, X'31 is synonymous with the above X, Z'3 is O, S, C1-C8 alkylidene, substituted or unsubstituted benzylidene , NH or NR''' (where R''' is alkyl, aryl, aralkyl, alkenyl or alkynyl), Y'93, Y'94 and Y'95 may be the same or different and represent hydrogen, halogen , alkylcarbonyl, alkylcarbonylalkyl, alkoxycarbonyl alkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio, thiosyl Ano, propargylthio, hydroxyimino, alkoxyimino, trialkyl silyloxy, aryldialkylsilyloxy, triarylsilyloxy, Formamidino, alkyl sulfamide, dialkyl sulfamide, alkoxy Sulfonyl, polyhaloalkoxysulfonyl, hydroxy, amino, aminocal Bonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothio carbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl , nitro, cyano, hydroxycarbonyl and its derivative salts, formamide, alkyl Kyl, alkoxy, polyhaloalkyl, polyhaloalkoxy, alkoxycarbo Nyl, substituted amino (in which case permissible substituents may be the same or different) 1 or 2 propargyl, alkoxyalkyl, alkylthioalkyl, alkyl alkyl, alkenyl, haloalkenyl or polyhaloalkenyl), alky ruthio, polyhaloalkylthio, alkylsulfinyl, polyhaloalkylsulf finyl, alkylsulfonyl, polyhaloalkylsulfonyl, alkylsulfonyl nylamino, alkylcarbonylamino, polyhaloalkylsulfonylamino, Polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkyl Silyl, triarylsilyl, sulfonic acid and its derivative salts, phosphonic acid and its derivatives Derivative salt, alkoxycarbonylamino, alkylaminocarbonyloxy, dia rkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyl Oxy, alkynyl, alkynyloxy, polyhaloalkenyloxy, polyhalo Alkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoa Lucylamino, semicarbazonomethyl, alkoxycarbonylhydrazonomethyl , alkoxyiminomethyl, substituted or unsubstituted aryloxyiminomethyl , hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl, mono- , hydroxy group condensed with di- or polysaccharide, haloalkyl, haloar rukenyl, haloalkynyl, alkoxyalkyl, aryloxy, araalco xy, arylthio, aralkylthio, alkylthioalkyl, arylthio Alkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl Nyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy , haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl Nyl, alkoxysulfonyl, aryloxysulfonyl, propargyloxy , aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, amino Sulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, ary Ruaminosulfonyl, carboxyalkoxy, carboxyalkylthio, alco oxycarbonylalkoxy, acyloxy, haloacyloxy, polyhaloacyl Oxy, aroyloxy, alkylsulfonyloxy, alkenylsulfonyloxy xy, arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloa Rukylsulfonyloxy, aroylamino, haloacylamino, alkoxylic Bonyloxy, arylsulfonylamino, aminocarbonyloxy, cyanato , isocyanato, isothiocyano, cycloalkylamino, trialkylammo nium, arylamino, aryl(alkyl)amino, araalkylamino, Alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, Alkoxyamino, aryloxyamino, aryloxyimino, oxo, thi ono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxy alkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium , -X, =X, -X=R3, =X-R3, -X-R3, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. There are ▼ or ▲ mathematical formulas, chemical formulas, tables, etc. ▼, and X, R3, R4, R5, Y1, Y2, Y3 and Y4 have the same meanings as above) 54. The method of claim 53. 73. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'21 has the same meaning as R1, X'32 is synonymous with the above X, Y'96, Y'97, Y'98 and Y'99 may be the same or different, and hydrogen , halogen, alkyl or alkoxy) according to claim 53. Method. 74. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, R'22 has the same meaning as R1, X'33 and Z'4 are hydrogen, halogen, hydroxy, alkyl, alkoxy, respectively , alkylcarbonyl or alkoxycarbonyl) 54. The method of claim 53. 75. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 76. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 77. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 78. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 79. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 80. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 81. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 82. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 83. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 84. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 85. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 86. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 87. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 88. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 89. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 90. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 91. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 92. The compound has the formula: ▲Contains mathematical formulas, chemical formulas, tables, etc.▼ 54. The method of claim 53. 93. Increase crop yield without substantially inhibiting photosynthetic electron transport in plants applying to crops an effective amount of the compound of claim 105 sufficient to cause A method to increase the yield of crops. 94. Increases crop yield without substantially inhibiting the light reaction of photosynthesis in plants. 54. The method of claim 53, wherein the compound is applied to the crop in an amount sufficient to cause the crop to grow. 95. Claim 5, wherein the compound is applied to the crop substantially without water pressure on the plant. The method described in 3. 96. Claim 53, wherein the compound is applied to the crop during a period prior to the reproductive growth period of the plant. Method described. 97. Claim 53 Where the compound is applied to the crop during a period prior to substantial soil water loss The method described in. 98. The person according to claim 53, who applies the compound to crops during the reproductive growth period of the plants. Law. 99. Approximately 0.0 per are. Applying compounds to crops at compound concentrations between 1 and 100 bonds 54. The method of claim 53. 100. Approximately 0.0 per are. Applying compounds to crops at compound concentrations of 25 to 15 bonds 54. The method according to claim 53. 101. 54. The method according to claim 53, wherein the crop is an agricultural or horticultural crop. 102. Plants include corn, cotton, sweet potato, potato, alfalfa, wheat, Rye, highland rice, barley, oats, sorghum, dry beans, soybeans, sugar Radishes, sunflowers, tobacco, tomatoes, canola, deciduous fruits. citrus fruits, tea, Coffee, olives, pineapple, cocoa, banana, sugar cane and guinea 54. The method of claim 53, wherein the method is selected from brassica. 103. 54. The method of claim 53, wherein the plants are transplanted stock. 104. The transplanted stock is tobacco, tomato, eggplant, cucumber, lettuce, and stock. Claim 10 selected from robberries, herbaceous flowerbed plants, trees, and tree seedlings. The method described in 3. 105. A compound having a formula selected from: ▲Math, Chemical formula, There are tables, etc.▼(i) In the above formula, R24 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X10 is O, S, SO, SO2, NH, -CH2O-, -CH2S-, -CH( CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO- ， -CH2CH2O-, -CH2CH2-, -C≡C-, -CH2SO-, -C H2SO2-, -OCH2CH2O-, -CH(alkyl)- or -CONH- and j is a value of 0 or 1, a has a value of 2 to 4, Y19 may be the same or different and may be a halogen, Alkyl, Cyano, Polyhaloa Lukiru, Alkoxy, polyhaloalkoxy, Alkylthio, Alkylsulfini le, Alkylsulfonyl, nitro, Acyl or polyhaloalkylsulfonyl the law of nature, however, (i) 2 and 4, 2 and 6, At least two ring positions selected from 2 and 3 and 3 and 4 Pairings are the same or different Substituted with halogen; (ii) ring position 2, 4 and 6 are substituted with chlorine, j has a value of 0 and X When 10 is SO2, R24 is not unsubstituted phenyl; (iii) ring position 2, 3 and 5 are replaced with chlorine, j has a value of 1, and When X10 is S, R24 is not unsubstituted phenyl: ▲Math, Chemical formula, There are tables etc.▼(ii) In the above formula, R25 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X11 is O, S, SO, SO2, NH, CH2, single covalent bond, -CH2O-, -CH2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C- ， -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (alkyl )- or -CONH-, b has a value of 2 to 3; Y20 may be the same or different, halogen, Alkyl, Cyano, Polyhaloa Lukiru, Alkoxy, polyhaloalkoxy, Alkylthio, Alkylsulfini le, Alkylsulfonyl, nitro, Acyl or polyhaloalkylsulfonyl the law of nature, however, At least two of Y20 are ha Is Rogen: ▲Math, Chemical formula, There are tables etc.▼(iii) In the above formula, R26 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X12 is O, S, SO, SO2, NH, CH2, single covalent bond, -CH2O-, -CH2S-, -CH8CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C- ， -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (alkyl )- or -CONH-, Y21 and Y22 are the same or different halogens respectively and Y23 is hydrogen, halogen, Alkyl, polyhaloalkyl, Alkoxy ， polyhaloalkoxy, Cyano, Alkylthio, Alkylsulfinyl, Archi rusulfonyl, nitro, Is acyl or polyhaloalkylsulfonyl: ▲Math, Chemical formula, There are tables, etc.▼(iv) In the above formula, R27 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X13 is O, S, SO, SO2, NH, CH2, single covalent bond, -CH2O-, -CH2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C- ， -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (alkyl )- or -CONH-, Y24 is halogen, Y25 and Y26 are hydrogen, respectively halogen, Alkyl, polyhaloalkyl, Arco Kishi, polyhaloalkoxy, Cyano, Alkylthio, Alkylsulfinyl, a Rukylsulfonyl, nitro, acyl or polyhaloalkylsulfonyl, However, death, At least one of Y25 and Y26 is halogen, Y24, Y25 and Y2 When 6 is chlorine and X13 is O, R27 is not unsubstituted phenyl: ▲Math, Chemical formula, There are tables etc. ▼(v) In the above formula, R28 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X14 is O, S, SO, SO2, NH, CH2, single covalent bond, -CH2O-, -CH2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C- ， -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (alkyl )- or -CONH-, Y27 and Y28 are each halogen, Y2 9 is hydrogen, halogen, Alkyl, polyhaloalkyl, Alkoxy, Polyhaloal Koxi, Cyano, Alkylthio, Alkylsulfinyl, Alkylsulfonyl, nitro, Is acyl or polyhaloalkylsulfonyl: ▲Math, Chemical formula, There are tables etc.▼(vi) In the above formula, R29 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X15 is O, S, SO, SO2, NH, CH2, single covalent bond, -CH2O-, -CH2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C- ， -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (alkyl )- or -CONH-, Y30, Y31 and Y32 are hydrogen, respectively Halogen hmm, Alkyl, Cyano, polyhaloalkyl, Alkoxy, polyhaloalkoxy, Alkylthio, Alkylsulfinyl, Alkylsulfonyl, nitro, Asilmata is polyhaloalkylsulfonyl, however, Y30, At least two of Y31 and Y32 are halogens: ▲Math, Chemical formula , There are tables etc.▼(vii) In the above formula, R30 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl is a rule, X16 is O, S, SO, SO2, NH, CH2, single covalent bond, -CH2O-, -CH2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C(CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C- ， -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH (alkyl )- or -CONH-, Y33, Y34 and Y35 are hydrogen, respectively. Halogen hmm, Alkyl, Cyano, polyhaloalkyl, Alkoxy, polyhaloalkoxy, Alkylthio, Alkylsulfinyl, Alkylsulfonyl, nitro, Asilmata is polyhaloalkylsulfonyl, however, (i)Y33, At least two of Y34 and Y35 are halogens: (ii) When both Y34 and Y35 are chlorine and X16 is O, R30 is not installed Not substituted phenyl: (iii) When both Y33 and Y34 are chlorine and X16 is O, R 30 is not unsubstituted phenyl or 4-methoxyphenyl: ▲Math, Chemical formula, Table etc. ▼(viii) In the above formula, d is a value of 0 to 4, e has a value of 1 or 2 (however, d+e is not greater than 5), R31 is the same - but may be different, Substituted or unsubstituted aryl (provided that R31 is 2- or 4- - when aryl, d is not 0), Aralkyl (However, R31 is 4-ara When it is Lukiru, d is not 0), Alkoxy, cycloalkoxy, Ariluo Kishi, Aralkoxy (however, when R31 is 4-aralkoxy, d must be 0) stomach), arylaryloxy, aralkoxyaralkyl, Alirualua Lukoxy, aryloxyaralkyl, aryloxyalkyl, Ariluo xyaryloxy, Aralkoxyaralkoxy, aryloxyalkoxy Shi, Alkylthio, alkenylthio, arylthio, Aralkylthio, Allie ruthioaralkyl, arylsulfonylarylsulfonyl, alkylamino ， dialkylamino, Acyloxy, Aroyloxy, Alkoxy carbonyl Kishi, Phenylazo (however, X17 is O or S), naphthylazo or adjacent -OCH2O- or -OCH that forms a 5- or 6-membered ring by combining with the carbon atom of 2CH2O-, Y36 may be the same or different and may be halogen, alkyl ， alkenyl, Alkynyl, -C that combines with adjacent carbon atoms to form a 6-membered ring H=CHCH=CH-, -(CH2)4, nitro, Cyano, haloalkyl or po It is a lyhaloalkyl, X17 is O, S, NH, CH2, -CH2O-, -CH 2S- or -OCH2CH2O-, Y37 is halogen, Y38 is halogen, Alkoxy, Alkylthio, Alkylsulfonyl, Polyhalo Alkoxy, polyhaloalkyl, Cyano, nitro, Substituted or unsubstituted aryl Thio, Is aryloxy or arylsulfonyl: ▲Math, Chemical formula, There are tables, etc.▼(ix) In the above formula, f is a value of 0 to 5, R32 may be the same or different and halogen, Alkyl, alkenyl, Archi Nil, polyhaloalkyl, Cyano, nitro, alkylamino, dialkylamino ， Alkoxy, polyhaloalkoxy, Alkylthio, Alkylsulfinyl, a Rukylsulfonyl, polyhaloalkylsulfonyl, Asil, CO2 (alkyl) ， CONH (alkyl), CON(alkyl)2, SO2N (alkyl)2, a Rukylcarbonyloxy, alkoxycarbonyloxy, Replaced or unvalued aryloxy, arylthio, arylsulfonyl or aroyl, X18 is O, S, CH2, a single covalent bond or -C≡C-, Y39 is halogen hmm, polyhaloalkoxy, polyhaloalkyl, Cyano, Alkylsulfonyl, a Rukylsulfonyloxy, Polyhaloalkylsulfonyl or polyhaloalkyls sulfonyloxy, Y40 is haloalkyl, polyhaloalkyl, Alkoxy (However, X18 is also S It is not a heavy covalent bond), polyhaloalkoxy, Cyano, Alkylthio (However, X1 8 is neither O nor a single covalent bond), Alkylsulfonyl, nitro, Dialjob Cyphosphinil or trialkylammonium: ▲Math, Chemical formula, Table etc. Yes▼(x) In the above formula, Y41 may be the same or different and is a halogen; Y42 is the same or different Can be used with halogen, Alkoxy, Alkylthio or polyhaloalkoxy the law of nature, X19 is O, Dithio, -P(=O)(O-alkyl)-, -P (alkyl) −、 -P(O-alkyl)-, sulfinyl, Sulfonyl, Thiosulfinyl, single covalent bond, carbonyl, aminocarbonylamino, aminooxarylamino ， Aminocarbonylalkylenecarbonylamino, aminoalkylene amino, Place Substituted or unsubstituted oxyaryloxy (however 1, 3-Arylenbis (Oki) C) is substituted with at least one substituent), Oxyarylalkyl alkyl reel oxy, oxyarylthioaryloxy, oxyarylsulfonyl Is aryloxy or oxyarylaryloxy: ▲Math, Chemical formula, table There are etc.▼ In the above formula, Y52 and Y53 are each halogen, g is a value of 0 to 5, R33 may be the same or different and halogen, Alkyl, alkenyl, Archi Nil, polyhaloalkyl, Cyano, nitro, amino, alkylamino, Ziarchi Ruamino, Alkoxy, polyhaloalkoxy, Alkylthio, alkyl sulfi Nil, Alkylsulfonyl, polyhaloalkylsulfonyl, alkoxy carboni le, alkylaminocarbonyl, aminocarbonyl, dialkylamino carboni le, dialkylaminosulfonyl, alkylaminosulfonyl, aminosulfony le, alkylcarbonyl, dialkoxyalkyl, alkylcarbonyloxy, alkylcarbonylalkylamino, Combines with adjacent carbon atoms to form a 6-membered ring -CH=CHCH=CH-, substituted or unsubstituted aryl, Aralkyl ， aryloxy, arylthio, Arylsulfonyl or aralkoxy the law of nature, X20 is -CH(alkyl)O-, -C(alkyl)2O-, -OCH2- ， -CH2O-, -CH2-, -C (halogen)2, -OCH2O-, -OCH 2CH2O-, or -C≡C- (where g has a value of at least 1); -OCH (alkyl)-, -OC(alkyl)2, -OCH(alkyl)O-, -OC( alkyl)2O-, -OCH(alkyl)CH2O-, -OCH(alkyl)CH(alkyl)O-, -CH(alkyl)CH(alkyl) )−, -CH(alkyl)-, -C(alkyl)2-, -CH2CH2O-, -OCH2CH2-, -CH(alkyl)CH2O-, -CH2CH2-, -C H(CN)O-, -C(alkyl)(CN)O-, -CH (polyhaloalkyl) O-, -C(CN)=NO-, -C(NH alkyl)=NO-, -C[N(alkyl)2]=NO-, -C(S-alkyl)=NO-, -C(O-alkyl)=NO-, -SC(=O)O-, -NHC(=O)O-, -N(alkyl)C(=O)O-, SO, SO2, -CH2S(O)h-, -C H(alkyl)S(O)h-, -S(O)hCH2-, -OC(=S)S-, − C(=0)S-, -C(=S)-S-, -NH(alkyl)C(=O)S-, − O(C=O)S-, -N(R34)-, -SO2NH-, -SO2N (alkyl )−, -CONH-, -CON(alkyl)-, -SC(=O)N(alkyl) −、 -SC(=0)NH-, -NHSO2NH-, -N(alkyl)SO2N( alkyl)−, -N(alkyl)SO2NH-, -NHSO2N(alkyl)-, -C(O-alkyl)=N-, -C(S-Al kill) = N-, -CH (halogen)-, -C(alkyl)(halogen)-, -C H(CN)-, -C(alkyl)(CN)-, -NH(alkyl)NH-, -N H-N(alkyl)-; -NH-NH- or -N=N- (However, R33 is nitro There is no); -C(=O)-, -C(=O)C(=O)-, -CH(O-alkyl)-, -C H2C(=O)-, -C(=0)CH2, -CH(alkyl)C(=O)-, − C (=0) CH (alkyl), -CH=CH-, -C(alkyl)=CH-, − CH=C(alkyl)-, -C(alkyl)=C(alkyl)-, -C(=O) CH=CH-, -P(Y4)(Y44-alkyl)-, Substituted or unsubstituted -p(Y43)( Y44-aryl) or arylene, -Si (halogen)2-, -Si (alkyl) )2-, -OC(=O)N(alkyl)-, -OCH2C(=O)N(alkyl)-, -N (alkyl) CON (alkyl) −; -OC(=O)NH-, -NHCONH-, -SO2NHC(=O)NH- or -NHC(=S)NH (where g has a value of at least 1); ▲Math, chemistry formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables, etc. ▼) ▲ Formulas, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, There are tables etc. ▼ and here, h is It has a value of 0 to 2, R34 is acyl, Alkylsulfonyl, polyhaloalkyl, polyhaloacyl, Polyhaloalkylsulfonyl or substituted or unsubstituted alloy or arylsulfonyl, Y43 and Y44 are each O or S: ▲ formula, Chemical formula, There are tables etc.▼(xii) In the above formula, R35 is isoxazole, isothiazole, Pyrazole, imidazole, 1, 2, 4-triazole, 1, 2, 4-oxadiazole, 1, 3, 4-Oxazi azole, 1, 2, 4-thiadiazole, 1, 3, 4-thiadiazole, Oxa Zor, Thiazole, benzopyrazole, benzimidazole, Benzoxazo rule, benzothiazole, indole, pyrrole, Fran, Thiophene, benzo Fran, benzothiophene, Viridine, pyrimidine, pyridazine, 1, 3, 5- triazine, 1, 2, 4-triazine, quinoline, isoquinoline, Quinazoline, Phthalazine, benzopyridazine, benzopyrazine, carbazole, dibenzofura hmm, dibenzothiophene, Benzoxazine, phthalimide, benzopyran, Jibe nzopyridine, pyridopyridine, Pyrazolopyrimidine, Tetrahydropyrimidine Zeon, coumarin, piperidine, Morpholine, Tetrahydrofuran, Tetrahydride lothiophene, pyrrolidine, thiomorpholine, piperidin-2-one, piperidi N-2, 6-dione, 2, 5-pyrrolidinedione, 3-morpholine, 2-oxo hexamethyleneimine, 2-oxotetramethyleneimine, 1-pyrazoline, 2 -pyrazoline, Pyrazolidine, 2-imidazolidinone, 2-imidazolidinethio hmm, 2, 4-imidazolidinedione, 1, 2-oxathiolane, 1, 3-Oxa Thiorane, 1, 3-oxathian, 1, 4-oxathian, 2(1H)-pyraji Non, 2H-pyran-2-one, 4H-pyran-4-one, 2H-pyran-2- Thione, 4H-pyran-4-thione, Tetrahydropyran, Tetrahydrothiopi run, 7-Oxabicyclo[2, 2, 1] Heptane, 7-azabicyclo[2, 2 ， 1] Heptane, Oxetane, coumarin, 1, 3-dioxane, 1, 4-Dioki sun and 1, Substituted or unsubstituted heterocyclic ring selected from 3-dioxolane system, X21 is O, S or NH (however, When X21 is NH, R3 5 is not pyridine, and when X21 is S, R35 is unsubstituted benzothiazo ), Y45 and Y46 are each halogen: ▲Math, Chemical formula, There are tables etc.▼( xiii) or ▲Math, Chemical formula, There are tables etc.▼(xiv) In the above formula, R37 and R38 are each halogen, nitro, Cyano, polyhaloalkyl, Polyha loalkoxy, Alkylsulfonyl, polyhaloalkylsulfonyl, Asil, a rukoxycarbonyl, is polyhaloalkylsulfonyl or R39-X22- (However, one of R37 and R38 can always be R39-X22-) R39 is replaced substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl , X22 is O, S, SO, SO2, CH2, single covalent bond, -CH2O-, -CH 2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C( CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, Y47 is halogen, B14 is O, S, NH or NR40 (where, R40 is alkyl, Archi rusulfonyl, alkenyl, Alkynyl, Alkoxycarbonyl; replacement or unsubstituted aryl, Aralkyl, aryloxy, arylamino, aroyl or arylsulfonyl), however, (i) B14 is R39-N<, R39-alkyl-N<, R39-C(=O)N <, R39-SO2N<, When R39-O-N< or R39-NH-N< ， both R37 and R38 are other than R39-X22-; (i1) B14 is R39-N<, R39-alkyl-N<, R39-C(=O) N<, R39-SO2N<, Other than R39-O-N< or R39-NH-N< At this time, - of R37 and R38 is R39-X22-; (iii) In formula (xiii), both R38 and Y47 are chlorine, and When 22 is a single covalent bond, R39 is not unsubstituted phenyl: ▲Math, chemistry formula, There are tables etc.▼(xv) or ▲Math, Chemical formula, There are tables etc.▼(xvi) In the above formula, R41 and R42 are each halogen or R43-X23- (However, R41 and One of R42 is always R43-X23-), R43 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl, X23 is O, S, SO, SO2, CH2, single covalent bond, -CH2O-, -CH 2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C( CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, B15 is O, S, NH or NR44 (here in, R44 is alkyl, Alkylsulfonyl, polyhaloalkylsulfonyl, a Lukenil, Alkynyl, Alkoxycarbonyl; Substituted or unsubstituted aryl ， Aralkyl, aryloxy, arylamino, aroyl or arylsul Honil), however, B15 is R43-N<, R43-alkyl-N<, R43-C(=O)N<, R 43-SO2N<, When R43-O-N< or R43-NH-N<, R4 1 and R42 are both other than R43-X23-, B15 is R43-N<, R43-alkyl-N<, R43-C(=O)N<, R 43-SO2N<, When R43-O-N< or R43-NH-N<, R4 One of 1 and R42 is R43-X23-: ▲Math, Chemical formula, There are tables, etc. ▼ (xvii) or ▲Math, Chemical formula, There are tables etc.▼(xviii) In the above formula, R45, R46, R47 and R48 are each hydrogen, halogen, nitro, Cyano, Po Rehaloalkyl, polyhaloalkoxy, Alkylsulfonyl, polyhaloalkyl Sulfonyl, Asil, Alkylthio, Alkyl, Alkoxy, alkyl sulfi Nyl or R49-X24- (However, R45, R46, One of R47 and R48 is R49-X24- and R45, R46, R47 and R48 must be 2 pieces The following hydrogen, (including alkyl or alkoxy), R49 is substituted or unsubstituted phenyl, 1- or 2-naphthyl or heteroaryl, X24 is O, S, SO, SO2, CH2, single covalent bond, -CH2O-, -CH 2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C( CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C-, -CH2SO-, -CH2SO2-, -OCH2CH2O-, -CH(alkyl )- or -CONH-, Y48 is halogen, B16 is O, Is S or NH: ▲Math, Chemical formula, There are tables etc. ▼(xix) In the above formula, R50 is a monocyclic aromatic or non-aromatic ring system, Bicyclic aromatic or non-aromatic ring system, Substituted or unsubstituted polycyclic aromatic or non-aromatic ring systems and bridged ring systems. a substituted carbocyclic or heterocyclic ring system; These may be saturated or unsaturated; B 17 is -CH=N-, -N=CH-, -CH=CH-, -CO-, -SO2-, -CH2CO-, -COCH2-, -CONH-, -NHCO-, -SO2NH −、 -NHSO2-, -SO2N(alkyl)-, -N(alkyl)SO2-, -OSO2-, -CS-, −N<, -NH-, -N (alkyl)-, -OCH2 ， -SCH2, -NHCH2, -N(alkyl)CH2, -SCO-, -OCH 2-, -OCO-, -CH2-, -CH2CH2- or -SCH2CO- (However, when B17 is -CO- and R50 is phenyl, phenyl is substituted ), Y54 and Y55 are each halogen: ▲Math, Chemical formula, Table etc. There is ▼(xx) in the above formula, R51 is a monocyclic aromatic or non-aromatic ring system, Bicyclic aromatic or non-aromatic ring system, Substituted or unsubstituted polycyclic aromatic or non-aromatic ring systems and bridged ring systems. a substituted carbocyclic or heterocyclic ring system; These may be saturated or unsaturated; B 18 is -CH-N-, -N=CH-, -CH=CH-, -CO-, -SO2-, -CH2CO-, -COCH2-, -CONH-, -NHCO-, -SO2NH −、 -NHSO2-, -SO2N(alkyl)-, -N(alkyl)SO2-, -OSO2-, -CS-, −N<, -NH-, -N (alkyl)-, -OCH2 ， -SCH2, -NHCH2, -N(alkyl)CH2, -SCO-, -OCH 2-, -OCO-, -CH2-, -CH2CH2- or -SCH2CO- , B19 is -CH2- or -CH(alkyl)-, i is a value of 0 or 1 , Y56 and Y57 are each halogen: ▲Math, Chemical formula, There are tables etc.▼( xxi) In the above formula, B20 is -CH2C(CH3)2SCH2-, -CH2CH=C(CH3)OC H2-, -CH2CH2SCH2CH(CH3)-, -CH2CH2SCH2C H2-, -CH2SCH2CO-, -COCH2C(CH3)2CH2CO-, -COCH2CH(C6H5)CH2CO-, -CONH(C6H5)CH2C H2CO-, -COC(CH3)2NHCO-, -CH2CH2N(C6H5)CH2CH2-, -CH2N(C6H5)CH2 CH2-, -CH2CH2CH(C6H5)CH2CH2-, -CO(CH2) 3CO-, -CO(CH2)2CO-, -COCH2CH(CH3)CH2CO −、 -COCH(CH3)CH2CO-, -COC(CH3)2CH2CO-, -COC(CH3)2C(CH3)2CO-, -CO(CH2)4CO-, -C O(CH2)5CO-, -CO(CH2)5CH2-, -CO(CH2)4CH 2-, -CO(CH2)3CH2-, -CO(CH2)2CH2-, -COCH 2SCH2CO-, -COCH2N(R52)CH2CO-, -COCH2OCH2CO-, -CO CH2SCS-, -COCH=CH-N=CH-, -CH2CH(C6H5)CH2-N=CH- or -CO2-CH2CH2- can be, R52 is hydrogen, alkenyl or substituted or unsubstituted aryl or alkaary and Y58 and Y59 are each halogen: ▲Math, Chemical formula, There are tables etc.▼( xxii) In the above formula, R53 is substituted or unsubstituted cycloalkenyl, cycloalkadienyl, Siku loalcatrienyl, Bicycloalkyl, Bicycloalkadienyl, tricyclo Alkyl, Bicycloalkenyl, Tricycloalkenyl or tricycloalkadi Enil, The permissible substituents may be the same or different and may contain one or more substituents. or more alkyl, halogen, haloalkyl, polyhaloalkyl, Alkoxy, a Lukirthio, Alkylsulfonyl, polyhaloalkoxy, nitro, Cyano, Ashi le, aroyl, aryl, alkoxycarbonyl, alkoxycarbonyloxy ， acyloxy, Combined with oxo or adjacent carbon atoms to form a 5- or 6-membered ring -CH=CHCH=CH- or -CH=CHCH2-, Y60 and Y61 are each halogen, X25 is O, S, NH, CH2, -C H2O- or a single covalent bond: ▲Math, Chemical formula, There are tables etc.▼(xxiii) In the above formula, R54 may be the same or different and represent one or more hydrogen atoms, halogen, Al kill, aryl, Aralkyl, alkenyl, Alkynyl, polyhaloalkyl, NH2, NH (alkyl), N (alkyl)2, Alkoxy, polyhaloalkoxy Shi, Alkylthio, Alkylsulfinyl, Alkylsulfonyl, Aralukoki Shi, CO2 alkyl, CONH (alkyl), CONH2, CON (alkyl) 2, SO2N (alkyl)2, SO2NH (alkyl), SO2NH2, Asil ， CO(O-alkyl)2, Acyloxy, Acyl-CON (alkyl) or 2, which combines with adjacent carbon atoms to form a substituted or unsubstituted 6-membered ring; 3-(- CH=CHCH=CH-), 3, 4-(-CH=CHCH=CH-), 2, 3- (CH2)4- or 3, 4-(CH2)4, X26 is O, S, SO, SO2, CH2, single covalent bond, -CH2O-, -CH 2S-, -CH(CH3)O-, -CH(CN)O-, -CH=NO-, -C( CH3)=NO-, -CH2CH2O-, -CH2CH2-, -C≡C-, -C H2SO-, -CH2SO2-, -OCH2CH2O-, -OCH2CH2-Also is -OCH2-, Y50 and Y51 may be the same or different. is: ▲Math, Chemical formula, There are tables, etc. ▼ (xxiv) In the above formula, R68 is substituted or unsubstituted phenyl or 1- or 2-naphthyl, X27 is -CH(alkyl)O-, -C(alkyl)2O-, -OCH2-, − C (halogen)2, -OCH2O-, -OCH2CH2O-, -CH2O-, − C≡C-, -OCH(alkyl)-, -OC(alkyl)2, -OCH (alkyl )O-, -OC(alkyl)2O-, -OCH(alkyl)CH2O-, -OCH(alkyl)CH(alkyl)O-, -CH(alkyl)CH(alkyl) )−, -CH(alkyl)-, -C(alkyl)2-, -CH2CH2O-, -OCH2CH2-, -CH(alkyl)CH2O-, -CH2CH2-, -C H(CN)O-, -C(alkyl)(CN)O-, -CH (polyhaloalkyl) O-, -C(CN)=NO-, -C(NH alkyl)=NO-, -C[N(alkyl)2]=NO-, -C(S-alkyl)=NO-, -C(O-alkyl)=NO-, -SC(=0)O-, -NHC(=O)O-, -N(alkyl)C(=O)O-, SO, SO2, -CH2S(O)h-, -C H(alkyl)S(O)h-, -S(O)hCH2-, -OC(=S)S-, − C(=O)S-, -C(=S)-S-, -NH(alkyl)C(=O)S-, − O(C=O)S-, -N (alkyl)-, -N(R34)-, -SO2NH-, -SO2N(alkyl)-, -CONH-, -CON(alkyl)-, -SC( =O)N(alkyl)-, -SC(=O)NH-, -NHSO2NH-, -N( alkyl)SO2N(alkyl)-, -N(alkyl)SO2NH-, -NHSO2N(alkyl)-, -C(O-alkyl)=N-, -C(S-Al kill) = N-, -CH (halogen)-, -C(alkyl)(halogen)-, -C H(CN)-, -C(alkyl)(CN)-, -NH(alkyl)NH-, -N H-N(alkyl)-; -NH-NH-, -N=N-, -C(=O)-, -C( =O)C(=O)-, -CH(O-alkyl)-, -CH2C(=O)-, -C (=O)CH2, -CH(alkyl)C(=O)-, -C(=O)CH(alkyl ), -CH=CH-, -C(alkyl)=CH-, -CH=C(alkyl)- ， -C(alkyl)=C(alkyl)-, -C(=O)CH=CH-, -P(Y43)(Y44-alkyl)-, Substituted or unsubstituted -P(Y43) (Y44-aryl) or arylene, -Si (halogen)2-, -Si(Al kill) 2-, -OC(=O)N(alkyl)-, -OCH2C(=O)N(alkyl)-, -N (alkyl) CON (alkyl) −; -OC(=O)NH-, -NHCONH-, -SO2NHC(=O)NH- ， -NHC(=S)NH, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula , There are tables, etc.▼▲mathematical formulas, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, table etc. ▼ (where h is a value between 0 and 2, R34 is acyl, Archi rusulfonyl, polyhaloalkyl, polyhaloacyl, polyhaloalkylsulfony or substituted or unsubstituted aroyl or arylsulfonyl, Y43 and beyond and Y44 are respectively O or S), Z1 and Z2 are respectively O, S, C1~C8 Al Kiriden, substituted or unsubstituted benzylidene, NH or NR''' (where R ′′′ is alkyl, aryl, Aralkyl, is alkenyl or alkynyl ) and Y67 and Y68 may be the same or different and are hydrogen, halogen, Alkyl, S That, polyhaloalkyl, Alkoxy, polyhaloalkoxy, haloalkyl, a Lukirthio, Alkylsulfinyl, Alkylsulfonyl, nitro, aryl, polyhaloalkylsulfonyl, alkylamino, dialkylamino, acylami of, Acyloxy, Alkylsulfonyloxy, arylsulfonyloxy, a rukenylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl Sulfonyloxy, Is phosphono or phosphino: ▲Math, Chemical formula, There are tables etc. ▼(xxv) In the above formula, R69 is substituted or unsubstituted phenyl or 1- or 2-naphthyl, X28 is NH, CH2 or a covalent bond, Z3 and Z4 are respectively O, S, C1~ C8 alkylidene, substituted or unsubstituted benzylidene, NH or NR''' ( Here R''' is alkyl, aryl, Aralkyl, alkenyl or alkini ) and Y69 and Y70 may be the same or different and represent hydrogen, halogen, Alkyl, S That, polyhaloalkyl, Alkoxy, polyhaloalkoxy, haloalkyl, a Lukirthio, Alkylsulfinyl, Alkylsulfonyl, nitro, aryl, polyhaloalkylsulfonyl, alkylamino, dialkylamino, acylami of, Acyloxy, Alkylsulfonyloxy, arylsulfonyloxy, a rukenylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl Sulfonyloxy, Phosphono or phosphino (however, Y69 and Y70 are the same) represent the same halogen or do not represent halogen and hydrogen): ▲Math, Chemical formula, There are tables etc. ▼(xxvi) In the above formula, R70 is isoxazole, isothiazole, Pyrazole, imidazole, 1, 2, 4-triazole, 1, 2, 4-oxadiazole, 1, 3, 4-Oxazi azole, 1, 2, 4-thiadiazole, 1, 3, 4-thiadiazole, Oxa Zor, Thiazole, benzopyrazole, benzimidazole, Benzoxazo rule, benzothiazole, indole, pyrrole, Fran, Thiophene, benzo Fran, benzothiophene, pyridine, pyrimidine, pyridazine, pyrazine, 1 ， 3, 5-triazine, 1, 2, 4-triazine, quinoline, isoquinoline, tree Nazolin, Phthalazine, benzopyridazine, benzopyrazine, carbazole, Ji benzofuran, dibenzothiophene, Benzoxazine, phthalimide, benzopi run, dibenzopyridine, pyridoviridine, Pyrazolopyrimidine, Tetrahydro pyrimidinedione, piperidine, Morpholine, Tetrahydrofuran, Tetrahydride lothiophene, pyrrolidine, thiomorpholine, piperidin-2-one, piperidi N-2, 6-dione, 2, 5-pyrrolidinedione, 3-morpholine, 2-oxo hexamethyleneimine, 2-oxotetramethyleneimine, 1-pyrazoline, 2 -pyrazoline, Pyrazolidine, 2-imidazolidinone, 2-imidazolidinethio hmm, 2, 4-imidazolidinedione, 1, 2-oxathiolane, 1, 3-Oxa Thiorane, 1, 3-oxathian, 1, 4-oxathian, 2(1H)-pyraji Non, 2H-pyran-2-one, 4H-pyran-4-one, 2H-pyran-2- Thione, 4H-pyran-4-thione, Tetrahydropyran, Tetrahydrothiopi run, 7-Oxabicyclo[2, 2, 1] Heptane, 7-azabicyclo[2, 2 ， 1] Heptane, Oxetane, coumarin, 1, 3-dioxane, 1, 4-Dioki sun and 1, substituted or unsubstituted saturated or is an unsaturated aromatic or non-aromatic heterocyclic ring system, X29 is -CH(alkyl )O-, -C(alkyl)2O-, -OCH2-, -CH2O-, -CH2-, Covalent bond, -C (halogen)2, -OCH2O-, -OCH2CH2O-, -C ≡C-, -OCH(alkyl)-, -OC(alkyl)2, -OCH(alkyl)O-, -OC(alkyl)2O-, -OCH(alkyl)CH2O-, -OCH(alkyl)CH(alkyl)O-, -CH(alkyl)CH(alkyl) )−, -CH(alkyl)-, -C(alkyl)2-, -CH2CH2O-, -OCH2CH2-, -CH(alkyl)CH2O-, -CH2CH2-, -C H(CN)O-, -C(alkyl)(CN)O-, -CH (polyhaloalkyl) O-, -C(CN)=NO-, -C(NH alkyl)=NO-, -C[N(alkyl)2]=NO-, -C(S-alkyl)=NO-, -C(O-alkyl)=NO-, -SC(=O)O-, -NHC(=O)O-, -N(alkyl)C(=O)O-, SO, SO2, -CH2S(O)h-, -C H(alkyl)S(O)h-, -S(O)hCH2-, -OC(=S)S-, − C(=O)S-, -C(=S)-S-, -NH(alkyl)C(=O)S-, − O(C=O)S-, -NH-, -N (alkyl)-, -N(R34)-, -S.O. 2NH-, -SO2N(alkyl)-, -CONH-, -CON(alkyl)- ， -SC(=O)N(alkyl)-, -SC(=O)NH-, -NHSO2NH −、 -N(alkyl)SO2N(alkyl)-, -N(alkyl)SO2NH-, -NHSO2N(alkyl)-, -C(O-alkyl)=N-, -C(S-Al kill) = N-, -CH (halogen)-, -C(alkyl)(halogen)-, -C H(CN)-, -C(alkyl)(CN)-, -NH(alkyl)NH-, -N H-N(alkyl)-; -NH-NH-, -N-N--C(=O)-, −C(= O)C(=O)-, -CH(O-alkyl)-, -CH2C(-O)-, -C( =O)CH2, -CH(alkyl)C(=O)-, -C(=O)CH(alkyl ), -CH=CH-, -C(alkyl)-CH-, -CH=C(alkyl)-, -C(alkyl)=C(alkyl)-, -C(=O)CH=CH-, -P(Y43)(Y44-alkyl)-, Substituted or unsubstituted -P(Y43) (Y44-aryl) or arylene, -Si (halogen)2-, -Si(Al kill) 2-, -OC(=O)N(alkyl)-, -OCH2C(=O)N(alkyl)-, -N (alkyl) CON (alkyl) −; -OC(=O)NH-, -NHCONH-, -SO2NHC(-O)NH- ， -NHC(=S)NH, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula , There are tables, etc.▼▲mathematical formulas, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, table etc. ▼ (where, h is a value of 0 to 2, R34 is acyl, Al Kirsulfonyl, polyhaloalkyl, polyhaloacyl, polyhaloalkyl sulfo or substituted or unsubstituted aroyl or arylsulfonyl, Y43 and Y44 are O or S respectively), Z5 and Z6 are respectively O, S, C1~C8a Luciliden, substituted or unsubstituted benzylidene, NH or NR''' (where R′′′ is alkyl, aryl, Aralkyl, Alkenyl or alkynyl ) and Y71 and Y72 may be the same or different and represent hydrogen, halogen, Alkyl, S That, polyhaloalkyl, Alkoxy, polyhaloalkoxy, haloalkyl, a Lukirthio, Alkylsulfinyl, Alkylsulfonyl, nitro, Asil, Po Lihaloalkylsulfonyl, amino, alkylamino, dialkylamino, Ashi Ruamino, Acyloxy, Alkylsulfonyloxy, arylsulfonyloki Shi, alkenylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloa Rukylsulfonyloxy, alkoxycarbonyl, alkylaminocarbonyl, aminocarbonyl, dialkylaminocarbonyl, dialkylaminosulfonyl ， alkylaminosulfonyl, aminosulfonyl, dialkoxyalkyl, Ali rsulfonyl, Is phosphono or phosphino: ▲Math, Chemical formula, There are tables, etc. ▼ (xxvii) In the above formula, R71 is substituted or unsubstituted alkyl, alkenyl, Alkynyl, cycloal kill, cycloalkenyl, cycloalkadienyl, cycloalkatrienyl, B cycloalkyl, Bicycloalkenyl, Bicycloalkadienyl, tricycloa Lukiru, tricycloalkenyl or tricycloalkadienyl, X30 is -CH(alkyl)O-, -C(alkyl)2O-, -OCH2-, -CH2O −、 -CH2-, Covalent bond, -C (halogen)2, -OCH2O-, -OCH2 CH2O-, -C≡C-, -OCH(alkyl)-, -OC(alkyl)2, -OCH(alkyl)O-, -OC(alkyl)2O-, -OCH(alkyl)CH2O-, -OCH(alkyl)CH(alkyl)O-, -CH(alkyl)CH(alkyl) )−, -CH(alkyl)-, -C(alkyl)2-, -CH2CH2O-, -OCH2CH2-, -CH(alkyl)CH2O-, -CH2CH2-, -C H(CN)O-, -C(alkyl)(CN)O-, -CH (polyhaloalkyl) O-, -C(CN)=NO-, -C(NH alkyl)=NO-, -C[N(alkyl)2]=NO-, -C(S-alkyl)=NO-, -C(O-alkyl)=NO-, -SC(=O)O-, -NHC(=O)O-, -N(alkyl)C(-O)O-, SO, SO2, -CH2S(O)h-, -C H(alkyl)S-(O)h-, -S(O)hCH2-, -OC(=S)S-, -C(=O)S-, -C(=S)-S-, -NH (alkyl) )C(=O)S-, -O(C=O)S-, -NH-, -N (alkyl)-, − N(R34)-, -SO2NH-, -SO2N(alkyl)-, -CONH-, -CON(alkyl)-, -SC(=O)N(alkyl)-, -SC(=O)N H-, -NHSO2NH-, -N(alkyl)SO2N(alkyl)-, -N(alkyl)SO2NH-, -NHSO2N(alkyl)-, -C(O-alkyl)=N-, -C(S-Al kill) = N-, -CH (halogen)-, -C(alkyl)(halogen)-, -C H(CN)-, -C(alkyl)(CN)-, -NH(alkyl)NH-, -N H-N(alkyl)-; -NH-NH-, -N-N--C(=0)-, −C(= O)C(=O)-, -CH(O-alkyl)-, -CH2C(=O)-, -C( =O)CH2, -CH(alkyl)C(=O)-, -C(=O)CH(alkyl ), -CH=CH-, -C(alkyl)=CH-, -CH=C(alkyl)-, -C(alkyl)=C(alkyl)-, -C(=O)CH=CH-, -P(Y43)(Y44-alkyl)-, Substituted or unsubstituted -P(Y43) (Y44-aryl) or arylene, -Si (halogen)2-, -Si(Al kill) 2-, -OC(=0)N(alkyl)-, -OCH2C(=O)N(alkyl)-, -N (alkyl) CON (alkyl) −; -OC(=O)NH-, -NHCONH-, -SO2NHC(=O)NH- ， -NHC(=S)NH, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula , There are tables, etc.▼▲mathematical formulas, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, table etc. ▼ (where, h is a value of 0 to 2, R34 is acyl, Al Kirsulfonyl, polyhaloalkyl, polyhaloacyl, polyhaloalkyl sulfo Nyl or substituted or unsubstituted aroyl or arylsulfonyl, Y4 3 and Y44 are O or S respectively), Z7 and Z8 are respectively O, S, C1-C8 alkylidene, substituted or unsubstituted penzylidene, NH or NR''' (here and R′′′ is alkyl, aryl, Aralkyl, alkenyl or alkynyl ) and Y73 and Y74 may be the same or different and represent hydrogen, halogen, Alkyl, S That, polyhaloalkyl, Alkoxy, polyhaloalkoxy, haloalkyl, a Lukirthio, Alkylsulfinyl, Alkylsulfonyl, nitro, aryl, polyhaloalkylsulfonyl, alkylamino, dialkylamino, acylami of, Acyloxy, Alkylsulfonyloxy, arylsulfonyloxy, a rukenylsulfonyloxy, haloalkylsulfonyloxy or polyhaloalkyl Is rusulfonyloxy: ▲Math, Chemical formula, There are tables, etc. ▼ (xxvii) In the above formula, B21 is -CH2C(CH3)2SCH2-, -CH2CH=C(CH3)OC H2-, -CH2CH2SCH2CH(CH3)-, -CH2CH2SCH2C H2-, -CH2SCH2CO-, -COCH2C(CH3)2CH2CO-, -COCH2CH(C6H5)CH2CO-, -CONH(C6H5)CH2C H2O-, -COC(CH3)2NHCO-, -CH2CH2N(C6H5)CH2CH2-, -CH2N(C6H5)CH2 CH2-, -CH2CH2CH(C6H5)CH2CH2-, -CO(CH2) 3CO-, -CO(CH2)2CO-, -COCH2CH(CH3)CH2CO −、 -COCH(CH3)CH2CO-, -COC(CH3)2CH2CO-, -COC(CH3)2C(CH3)2CO-, -CO(CH2)4CO-, -C O(CH2)5CO-, -CO(CH2)5CH2-, -CO(CH2)4CH 2-, -CO(CH2)3CH2-, -CO(CH2)2CH2-, -COCH 2SCH2CO-, -COCH2N(R52)CH2CO-, -COCH2OCH2CO-, -CO CH2SCS-, -COCH=CH-N=CH-, -CH2CH(C6H5)CH2-N=CH- or -CO2-CH2CH2- can be, Here R52 is hydrogen, alkenyl or substituted or unsubstituted aryl or alkali is an aryl, Z9 and Z10 are respectively O, S, C1-C8 alkylidene, substituted or unsubstituted penzylidene, NH or NR''' (where R''' is alkyl, aryl, a Lualkil, alkenyl or alkynyl), Y75 and Y76 may be the same or different and are hydrogen, halogen, Alkyl, S That, polyhaloalkyl, Alkoxy, polyhaloalkoxy, haloalkyl, a Lukirthio, Alkylsulfinyl, Alkylsulfonyl, nitro, Asil, Po Lihaloalkylsulfonyl, amino, alkylamino, dialkylamino, Ashi Ruamino, Acyloxy, Alkylsulfonyloxy, arylsulfonyloki Shi, alkenylsulfonyloxy, haloalkylsulfonyloxy, Polyhaloa Rukylsulfonyloxy, Is phosphono or phosphino: ▲Math, Chemical formula, There are tables etc. ▼(xxix) In the above formula, R72 is substituted or unsubstituted phenyl or 1- or 2-naphthyl, X31 is -OCH2-, -CH2-, Covalent bond, -C (halogen)2, −C≡C −、 -OCH(alkyl)-, -OC(alkyl)2, -CH(alkyl}CH(a) Rukiru) −, -CH(alkyl)-, -C(alkyl)2-, -OCH2CH2 −、 -CH2CH2-, SO, -S-, SO2, -CH2S(O)h-, -CH(alkyl)S(O)h-, -S(O)hCH2-, -CH (halogen) −、 -C(alkyl)(halogen)-, -CH(CN)-, -C (alkyl) ( CN)-, -C(=O)-, -CH(O-alkyl)-, -CH2C(=O)- ， -C(=O)CH2, -CH(alkyl)C(-O)-, -C(=O)CH(alkyl), -CH=CH-, -C(alkyl)=CH-, -CH=C(alkyl)-, -C(alkyl)=C(alkyl)-, −C(=O )CH=CH-, Arilene, -Si, (halogen)2-, -Si (alkyl) 2-, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc.▼ ▲Math, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, There are tables etc.▼ (here, h is a value of 0 to 2), Z11 is O, S, C1-C8 alkyritedene, Substituted or unsubstituted benzylide hmm, NH or NR''' (where R''' is alkyl, aryl, Aralkyl ， alkenyl or alkynyl), Y77, Y78 and Y79 may be the same or different and represent hydrogen, halogen, Al kill, Hydroxy, Cyano, polyhaloalkyl, Alkoxy, polyhaloalkoxy Shi, haloalkyl, Alkylthio, Alkylsulfinyl, Alkylsulfonyl ， nitro, Asil, polyhaloalkylsulfonyl, alkylamino, amino, Ji alkylamino, Acylamino, Acyloxy, Alkylsulfonyloxy, a lylsulfonyloxy, alkenylsulfonyloxy, haloalkylsulfony Ruoxy, polyhaloalkylsulfonyloxy, is phosphono or phosphino , however, When Y77 is halogen and Y79 is hydrogen, Y78 is amino, alkyl amino, It cannot be dialkylamino or acylamino, When Y77 and Y78 are the same halogen, Y79 is not hydrogen or hydroxy. Impossible: ▲Math, Chemical formula, There are tables etc. ▼(xxx) In the above formula, R73 is isoxazole, isothiazole, Birasole, imidazole, 1, 2, 4-triazole, 1, 2, 4-oxadiazole, 1, 3, 4-Oxazi azole, 1, 2, 4-thiadiazole, 1, 3, 4-thiadiazole, Oxa Zor, Thiazole, benzopyrazole, benzimidazole, benzoxazo rule, benzothiazole, indole, pyrrole, Fran, Thiophene, benzo Fran, benzothiophene, pyridine, pyrimidine, pyridazine, pyrazine, 1 ， 3, 5-triazine, 1, 2, 4-triazine, quinoline, isoquinoline, tree Nazolin, Phthalazine, benzopyridazine, benzopyrazine, carbazole, Ji benzofuran, dibenzothiophene, Benzoxazine, phthalimide, benzopi run, dibenzopyridine, pyridoviridine, Pyrazolopyrimidine, Tetrahydro pyrimidinedione, piperidine, Morpholine, Tetrahydrofuran, Tetrahydride lothiophene, pyrrolidine, thiomorpholine, piperidin-2-one, piperidi N-2, 6-dione, 2, 5-pyrrolidinedione, 3-morpholine, 2-oxo hexamethyleneimine, 2-oxotetramethyleneimine, 1-pyrazoline, 2 -pyrazoline, Pyrazolidine, 2-imidazolidinone, 2-imidazolidinethio hmm, 2, 4-imidazolidinedione, 1, 2-oxathiolane, 1, 3-Oxa Thiorane, 1, 3-oxathian, 1, 4-oxathian, 2(1H)-pyraji Non, 2H-pyran-2-one, 4H-pyran-4-one, 2H-pyran-2- Thione, 4H-pyran-4-thione, Tetrahydropyran, Tetrahydrothiopi run, 7-Oxabicyclo[2, 2, 1] Heptane, 7-azabicyclo[2, 2 ， 1] Heptane, Oxetane, coumarin, 1, 3-dioxane, 1, 4-Dioki sun and 1, Substituted or unsubstituted saturated or is an unsaturated aromatic or non-aromatic heterocyclic ring system, X32 is -OCH2-, − CH2-, Covalent bond, -C (halogen)2, -C≡C-, -OCH(alkyl)-, -OC(alkyl)2, -CH(alkyl)CH(a Rukiru) −, -CH(alkyl)-, -C(alkyl)2-, -OCH2CH2 −、 -CH2CH2-, SO, -S-, SO2, -CH2S(O)h-, -CH(alkyl)S(O)h-, -S(O)hCH2-, -CH (halogen) −、 -C(alkyl)(halogen)-, -CH(CN)-, -C (alkyl) ( CN)-, -C(=O)-, -CH(O-alkyl)-, -CH2C(=O)- ， -C(=O)CH2, -CH(alkyl)C(=O)-, -C(=O)CH(alkyl), -CH=CH-, -C(alkyl)=CH-, -CH=C(alkyl)-, -C(alkyl)=C(alkyl)-, −C(=O )CH=CH-, Arilene, -Si (halogen)2-, -Si (alkyl)2 −、 ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables, etc.▼▲ formula, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, There are tables etc.▼ (here, h is a value of 0 to 2), Z12 is O, S, C1-C8 alkylidene, Substituted or unsubstituted benzylidene ， NH or NR''' (where R''' is alkyl, aryl, Aralkyl, alkenyl or alkynyl), Y80, Y81 and Y82 may be the same or different and are hydrogen, halogen, Al kill, Hydroxy, Cyano, polyhaloalkyl, Alkoxy, polyhaloalkoxy Shi, haloalkyl, Alkylthio, Alkylsulfinyl, Alkylsulfonyl ， nitro, Asil, polyhaloalkylsulfonyl, alkylamino, aminodia Lucylamino, Acylamino, Acyloxy, Alkylsulfonyloxy, Ali rsulfonyloxy, alkenylsulfonyloxy, haloalkylsulfonyl Oxy, polyhaloalkylsulfonyloxy, Is phosphono or phosphino: ▲Math, Chemical formula, There are tables etc. ▼(xxxi) In the above formula, R74 is substituted or unsubstituted alkyl, alkenyl, Alkynyl, cycloal kill, cycloalkenyl, cycloalkadienyl, cycloalkatrienyl, B cycloalkyl, Bicycloalkenyl, Bicycloalkadienyl, tricycloa Lukiru, tricycloalkenyl or tricycloalkadienyl, X33 is -OCH2-, -CH2-, Covalent bond, -C (halogen)2, -C≡C-, -OCH(alkyl)-, -OC(alkyl)2, -CH(alkyl)CH(a Rukiru) −, -CH(alkyl)-, -C(alkyl)2-, -OCH2CH2 −、 -CH2CH2-, SO, -S-, SO2, -CH2S(O)h-, -CH(alkyl)S(O)h-, -S(O)hCH2-, -CH (halogen) −、 -C(alkyl)(halogen)-, -CH(CN)-, -C (alkyl) ( CN)-, -C(=O)-, -CH(O-alkyl)-, -CH2C(=O)- ， -C(=O)CH2, -CH(alkyl)C(=O)-, -C(=0)CH(alkyl), -CH=CH-, -C(alkyl)=CH-, -CH=C(alkyl)-, -C(alkyl)=C(alkyl)-, −C(=O )CH=CH-, Arilene, -Si (halogen)2-, -Si (alkyl)2 −、 ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables, etc.▼▲ formula, Chemical formula, There are tables, etc.▼ or ▲mathematical formulas, Chemical formula, There are tables etc.▼ (here, h is a value of 0 to 2), Z13 is O, S, C1-C8 alkylidene, Substituted or unsubstituted benzylidene ， NH or NR''' (where R''' is alkyl, aryl, Aralkyl, alkenyl or alkynyl), Y83, Y84 and Y85 may be the same or different and represent hydrogen, halogen, Al kill, Hydroxy, Cyano, polyhaloalkyl, Alkoxy, polyhaloalkoxy Shi, haloalkyl, Alkylthio, Alkylsulfinyl, Alkylsulfonyl ， nitro, Asil, polyhaloalkylsulfonyl, alkylamino, amino, Ji alkylamino, Acylamino, Acyloxy, Alkylsulfonyloxy, a lylsulfonyloxy, alkenylsulfonyloxy, haloalkylsulfony or polyhaloalkylsulfonyloxy: The permissible substituents in formulas (i) to (xxxi) above may be the same or different. optionally one or more hydrogens, halogen, alkylcarbonyl, Alkirca Rubonylalkyl, alkoxycarbonylalkyl, Alkoxycarbonylal Kirchio, polyhaloalkenylthio, Thiocyano, propargylthio, hydroki Shiimino, Alkoxyimino, trialkylsilyloxy, aryl dialkyl silyloxy, triarylsilyloxy, Formamidino, Alkyl sulfur Mido, dialkyl sulfamide, alkoxysulfonyl, polyhaloalkoxys Ruhonyl, Hydroxy, amino, aminocarbonyl, alkylaminocarbonyl ， dialkylaminocarbonyl, aminothiocarbonyl, Alkylaminothioca Rubonil, dialkylaminothiocarbonyl, nitro, Cyano, hydroxycal Bonyl and its derived salts, formamide, Alkyl, Alkoxy, polyhaloalkyl le, polyhaloalkoxy, alkoxycarbonyl, Substituted amino (acceptable in this case) The substituents that may be present may be the same or different and include one or two propargyl, Al Koxyalkyl, alkylthioalkyl, Alkyl, alkenyl, haloarkeni or polyhaloalkenyl), Alkylthio, polyhaloalkylthio, a Rukylsulfinyl, polyhaloalkylsulfinyl, Alkylsulfonyl, Po Lihaloalkylsulfonyl, Alkylsulfonylamino, Alkylcarbonyla Mino, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino ， trialkylsilyl, aryldialkylsilyl, triarylsilyl, Sur fonic acid and its derivative salts, phosphonic acid and its derivative salts, Alkoxycarbonylamide of, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, a Lukenil, polyhaloalkenyl, alkenyloxy, Alkynyl, Alkyniluo Kishi, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyl Kishi, polyfluoroalkanol, cyanoalkylamino, semicarbazonomethi le, Alkoxycarbonylhydrazonomethyl, Alkoxyiminomethyl, replacement young or unsubstituted aryloxyiminomethyl, hydrazonomethyl, replacement or unsubstituted arylhydrazonomethyl, Things, di- or polysaccharide and combined hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, Arco xyalkyl, aryloxy, Aralkoxy, arylthio, Araalkyl Thio, alkylthioalkyl, arylthioalkyl, arylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, C loalkenyloxy, haloalkynyloxy, haloalkynylthio, haloarche Nylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, Ali oxysulfonyl, propargyloxy, aroyl, haloacyl, Polyhalo Asil, aryloxycarbonyl, aminosulfonyl, alkylaminosulfo Nil, dialkylaminosulfonyl, arylaminosulfonyl, Carboxia Lukoxy, carboxyalkylthio, alkoxycarbonylalkoxy, Asil Oxy, haloacyloxy, polyhaloacyloxy, Aroyloxy, alkyl Sulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, aroyl amino, haloacylamino, alkoxycarbonyloxy, arylsulfonyl amino, aminocarbonyloxy, Seanat, isocyanate, isothiocyano, cycloalkylamino, trialkylammonium, arylamino, aryl (alkyl)amino, araalkylamino, alkoxyalkylphosphinyl, alkoxyalkylphosphinothioyl, Alkylhydroxyphosphinyl, Ji Alkoxyphosphino, hydroxyamino, Alkoxyamino, aryloxy amino, aryloxyimino, Oxo, Chiono, alkylaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X, =X, −X=R3, =X- R3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, Table etc. There is ▼ or ▲ formula, Chemical formula, There is a table etc. ▼: R1-X-R36 (xxxii) ▲Math, Chemical formula, There are tables etc.▼(xxxiii) In the above formula, Y62, Y63, Y64, Y65 and Y66 may be the same or different, and halo It is Gen, R1 is a bicyclic aromatic or non-aromatic ring system, Bicyclic aromatic or non-aromatic ring systems, Substituted or unsubstituted polycyclic aromatic or non-aromatic ring systems and bridged ring systems a substituted carbocyclic or heterocyclic ring system, The ring system may be saturated or unsaturated; The permissible substituents can be the same or different and contain one or more hydrogen atoms, C Rogen, alkylcarbonyl, alkylcarbonylalkyl, Alkoxycarbo nyl alkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio, Thiocyano, propargylthio, hydroxyimino, Alkoxyimino, Thoria Rukylsilyloxy, aryldialkylsilyloxy, triarylsilyl Kishi, Formamidino, Alkylsulfamide, dialkyl sulfamide, Al Koxysulfonyl, polyhaloalkoxysulfonyl, Hydroxy, amino, Ami nocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, Ami Notiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocal Bonil, nitro, Cyano, hydroxycarbonyl and its derivative salts, Formamide ， Alkyl, Alkoxy, polyhaloalkyl, polyhaloalkoxy, Alkoxy carbonyl, Substituted amino (in which case permissible substituents may be the same or different) Also often one or two propargyl, alkoxyalkyl, alkylthioalky le, Alkyl, alkenyl, haloalkenyl or polyhaloalkenyl), Alkylthio, polyhaloalkylthio, Alkylsulfinyl, polyhaloalkyl rusulfinil, Alkylsulfonyl, polyhaloalkylsulfonyl, alkyl Sulfonylamino, Alkylcarbonylamino, Polyhaloalkylsulfonylua Mino, polyhaloalkylcarbonylamino, trialkylsilyl, Arylsia Lucilsilyl, triarylsilyl, Sulfonic acid and its derived salts, Phosphonic acid and Biso derived salt, alkoxycarbonylamino, alkylaminocarbonyloxy ， dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, Al Kenyloxy, Alkynyl, Alkynyloxy, polyhaloalkenyloxy, Po Lihaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, S Anoalkylamino, semicarbazonomethyl, Alkoxycarbonylhydrazono Methyl, Alkoxyiminomethyl, Substituted or unsubstituted aryloxyimino Methyl, hydrazonomethyl, substituted or unsubstituted arylhydrazonomethyl, Things, hydroxy group fused with di- or polysaccharide, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, Ara Alkoxy, arylthio, aralkylthio, alkylthioalkyl, Allie ruthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyrus Rufinil, haloalkylsulfonyl, haloalkenyloxy, haloalkynyl Oxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkenyl Sulfonyl, alkoxysulfonyl, aryloxysulfonyl, propargyl Oxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, Acyloxy, haloacyloxy, Polyhalo Acyloxy, Aroyloxy, Alkylsulfonyloxy, alkenyl sulfo Nyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Poly haloalkylsulfonyloxy, aroylamino, haloacylamino, Alcoki cycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, S Anat, isocyanate, isothiocyano, cycloalkylamino, trial kill ammonium, arylamino, aryl(alkyl)amino, Araalkilua Mino, alkoxyalkylphosphinyl, Alkoxyalkylphosphinothioyl le, Alkylhydroxyphosphinyl, dialkoxyphosphino, Hydroxia Mino, Alkoxyamino, aryloxyamino, aryloxyimino, Oki So, Chiono, alkylaminoalkoxy, dialkylaminoalkoxy, Arco xyalkoxy, alkoxyalkenyl, cyanoalkoxy, dialkyl sulfo nium, -X, =X, −X=R3, =X-R3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc. ▼ or ▲ formula, Chemical formula, There are tables etc. ▼ and Or R1 is a substituted heteroatom or a substituted carbon atom, or two or more carbon atoms or different atoms and the following: Substituted or unsubstituted straight or branched chains containing any combination of permissible substituents. There it is, The substituents may be the same or different and contain one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, Alkoxylic Bonyl alkyl, alkoxycarbonylalkylthio, Polyhaloalkenylthio ， Thiocyano, propargylthio, hydroxyimino, Alkoxyimino, bird Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, Formamidino, Alkylsulfamide, dialkyl sulfamide, a Lucoxysulfonyl, polyhaloalkoxysulfonyl, Hydroxy, amino, a Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca Rubonil, nitro, Cyano, hydroxycarbonyl and its derivative salts, Formami Do, Alkyl, Alkoxy, polyhaloalkyl, polyhaloalkokyl, Alcoki cycarbonyl, Substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, Alkylthioal kill, Alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) ， Alkylthio, polyhaloalkylthio, Alkylsulfinyl, Polyhaloal Kirsulfinyl, Alkylsulfonyl, polyhaloalkylsulfonyl, Archi Rusulfonylamino, Alkylcarbonylamino, polyhaloalkylsulfonyl amino, polyhaloalkylcarbonylamino, trialkylsilyl, Arielji alkylsilyl, triarylsilyl, Sulfonic acid and its derived salts, phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy Shi, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a rukenyloxy, Alkynyl, Alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, Alkoxycarbonylhydrazo nomethyl, Alkoxyiminomethyl, Substituted or unsubstituted aryloxyimides nomethyl, hydrazonomethyl, Substituted or unsubstituted arylhydrazonomethyl ， Things, hydroxy group fused with di- or polysaccharide, haloalkyl ， haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, Ali ruthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl sulfinyl, haloalkylsulfonyl, haloalkenyloxy, Halo Alkini Ruoxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, Propargi Ruoxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl ， aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl ， arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio ， alkoxycarbonylalkoxy, Acyloxy, haloacyloxy, Polyha loacyloxy, Aroyloxy, Alkylsulfonyloxy, alkenyl sul Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Po lyhaloalkylsulfonyloxy, aroylamino, haloacylamino, Arco xycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, Seanat, isocyanate, isothiocyano, cycloalkylamino, trialarchy ammonium, arylamino, aryl(alkyl)amino, Araalkyl amino, alkoxyalkylphosphinyl, Alkoxyalkylphosphinothio Ile, Alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy amino, Alkoxyamino, aryloxyamino, aryloxyimino, O Kisso, Chiono, alkylaminoalkoxy, dialkylaminoalkoxy, Al Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, Dialkylsul Honium, -X, =X, −X=R3, =X-R3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc. ▼ or ▲ formula, Chemical formula, There are tables etc. ▼ and X is a covalent single bond or two double bond, substituted or unsubstituted heteroatoms or substituted carbon atoms, Or two or more or more carbon atoms or heteroatoms in combination with the following permissible substituents: A substituted or unsubstituted linear or branched chain, The substituents may be the same or different. optionally one or more hydrogens, halogen, alkylcarbonyl, alkyl carbonylalkyl, alkoxycarbonylalkyl, Alkoxycarbonyla Lukirthio, polyhaloalkenylthio, Thiocyano, propargylthio, hydro Kishiimino, Alkoxyimino, trialkylsilyloxy, aryl dialky lucilyloxy, triarylsilyloxy, Formamidino, alkylsulf Amide, dialkyl sulfamide, alkoxysulfonyl, polyhaloalkoxy Sulfonyl, Hydroxy, amino, aminocarbonyl, alkylamino carboni le, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothio carbonyl, dialkylaminothiocarbonyl, nitro, Cyano, Hydroxica rubonyl and its derivative salts, formamide, Alkyl, Alkoxy, Polyhaloal kill, polyhaloalkokyl, alkoxycarbonyl, Substituted amino (allowed in this case) The substituents which may be the same or different may include one or two propargyl, a Lukoxyalkyl, alkylthioalkyl, Alkyl, alkenyl, haloarche or polyhaloalkenyl), Alkylthio, polyhaloalkylthio, Alkylsulfinyl, polyhaloalkylsulfinyl, Alkylsulfonyl, polyhaloalkylsulfonyl, Alkylsulfonylamino, alkyl carbonyl amino, polyhaloalkylsulfonylamino, Polyhaloalkylcarbonylamide of, trialkylsilyl, aryldialkylsilyl, triarylsilyl, vinegar sulfonic acid and its derived salts, phosphonic acid and its derivative salts, Alkoxycarbonyla Mino, alkylaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, Alkynyl, Alkynyl Oxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyl Oxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonome Chill, Alkoxycarbonylhydrazonomethyl, Alkoxyiminomethyl, replacement or unsubstituted aryloxyiminomethyl, hydrazonomethyl, replacement or is unsubstituted arylhydrazonomethyl, Things, Di- or polysaccharide fused hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, Al Koxyalkyl, aryloxy, Aralkoxy, arylthio, Araarchi Lucio, alkylthioalkyl, arylthioalkyl, arylsulfinyl ， arylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloalkynylthio, haloal Kenylsulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, a lyloxysulfonyl, propargyloxy, aroyl, haloacyl, Polyha Loisil, aryloxycarbonyl, aminosulfonyl, Alkylaminosul Honil, dialkylaminosulfonyl, arylaminosulfonyl, Carboxy Alkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, Ashi Ruoxy, haloacyloxy, polyhaloacyloxy, Aroyloxy, Archi Rusulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy ， haloalkylsulfonyloxy, polyhaloalkylsulfonyloxy, alloy Ruamino, haloacylamino, alkoxycarbonyloxy, arylsulfony Ruamino, aminocarbonyloxy, Seanat, isocyanate, isothiocyano ， cycloalkylamino, trialkylammonium, arylamino, Allie (alkyl)amino, araalkylamino, Alkoxyalkylphosphinyl ， alkoxyalkylphosphinothioyl, Alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxyamino, Alkoxyamino, Aryl Oki Cyamino, aryloxyimino, Oxo, Chiono, alkylaminoalkoxy ， dialkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl ， cyanoalkoxy, dialkylsulfonium, -X, =X, −X=R3, =X -R3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, table etc. ▼ or ▲ formula, Chemical formula, There are tables etc. ▼ and Or R36 monocyclic aromatic or nonaromatic ring systems, Bicyclic aromatic or non-aromatic ring systems, Polycyclic at least three nitrogen atoms selected from aromatic or non-aromatic ring systems and bridged ring systems; A substituted or unsubstituted asymmetric heterocyclic ring system containing elementary atoms, The ring system is Can be saturated or unsaturated, The permissible substituents may be the same or different. hydrogen, halogen, alkylcarbonyl, Alkylcarbonyla Lukiru, alkoxycarbonylalkyl, alkoxycarbonylalkylthio, polyhaloalkenylthio, Thiocyano, propargylthio, hydroxyimino, Alkoxyimino, trialkylsilyloxy, aryldialkylsilyloxy Shi, triarylsilyloxy, Formamidino, Alkylsulfamide, Gia Rukylsulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, Hydroxy, amino, aminocarbonyl, alkylaminocarbonyl, Ziarchi Ruaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, Cyano, Hydroxycarbonyl and its derived salt, formamide, Alkyl, Alkoxy, polyhaloalkyl, Polyha loalkoxy, alkoxycarbonyl, Substituted amino (in this case permissible substitutions The groups may be the same or different; one or two propargyl, Alkoxyal kill, alkylthioalkyl, Alkyl, alkenyl, haloalkenyl or poly haloalkenyl), Alkylthio, polyhaloalkylthio, alkylsul Finil, polyhaloalkylsulfinyl, Alkylsulfonyl, Polyhaloal Kirsulfonyl, Alkylsulfonylamino, Alkylcarbonylamino, Poly haloalkylsulfonylamino, polyhaloalkylcarbonylamino, trial Kirsilil, aryldialkylsilyl, triarylsilyl, Sulfonic acid and its derived salt, phosphonic acid and its derivative salts, alkoxycarbonylamino, Archi Ruaminocarbonyloxy, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, Alkynyl, Alkynyloxy, Poly haloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, Poly fluoroalkanol, cyanoalkylamino, semicarbazonomethyl, Arco xycarbonylhydrazonomethyl, Alkoxyiminomethyl, replaced or left unplaced aryloxyiminomethyl, hydrazonomethyl, Replaced or unreplaced a lylhydrazonomethyl, Things, Hydrode condensed with di- or polysaccharide Roxy group, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl le, aryloxy, Aralkoxy, arylthio, aralkylthio, Al Kylthioalkyl, arylthioalkyl, arylsulfinyl, Aryllus Ruhonyl, haloalkylsulfinyl, haloalkylsulfonyl, haloarkeni Ruoxy, haloalkynyloxy, haloalkynylthio, haloalkenyl sulfo Nil, polyhaloalkenylsulfonyl, alkoxysulfonyl, aryloxy Sulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, a lyloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, Gia rukylaminosulfonyl, arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio, alkoxycarbonylalkoxy, Acyloxy, C loacyloxy, polyhaloacyloxy, Aroyloxy, Alkylsulfonyl Oxy, alkenylsulfonyloxy, arylsulfonyloxy, haloarchi Rusulfonyloxy, polyhaloalkylsulfonyloxy, aroylamino, C loacylamino, alkoxycarbonyloxy, arylsulfonylamino, a Minocarbonyloxy, Seanat, isocyanate, isothiocyano, cycloal Kylamino, trialkylammonium, arylamino, Aryl (alkyl) )amino, araalkylamino, alkoxyalkylphosphinyl, Alkoxy Alkylphosphinothioyl, Alkylhydroxyphosphinyl, Dialkoxy phosphino, hydroxyamino, Alkoxyamino, aryloxyamino, a Reel oximino, Oxo, Chiono, alkylaminoalkoxy, Dialkyl aminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, cyanoal Koxi, dialkylsulfonium, -X, =X, −X=R3, =X-R3, -X -R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc. ▼ or ▲ formula, Chemical formula, There are tables etc. ▼ and Alternatively, R3 is a monocyclic aromatic group. or a non-aromatic ring system, Bicyclic aromatic or non-aromatic ring systems, polycyclic aromatic or is a substituted or unsubstituted carbocyclic or compound selected from non-aromatic ring systems and bridged ring systems. A subcyclic ring system, The ring system may be saturated or unsaturated; Permissible substituents may be the same or different and contain one or more hydrogen atoms, halogen, Alkirca Rubonil, alkylcarbonylalkyl, alkoxycarbonylalkyl, Al koxycarbonylalkylthio, polyhaloalkenylthio, Thiocyano, Propa Lugilcio, hydroxyimino, Alkoxyimino, trialkylsilyloxy ， aryldialkylsilyloxy, triarylsilyloxy, Formamizi of, Alkylsulfamide, dialkyl sulfamide, alkoxysulfonyl, polyhaloalkoxysulfonyl, Hydroxy, amino, aminocarbonyl, Al Kylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, nitro, S That, hydroxycarbonyl and its derivative salts, formamide, Alkyl, Arco Kishi, polyhaloalkyl, polyhaloalkoxy, alkoxycarbonyl, Replacement a mino (in this case, the permissible substituents may be the same or different and have 1 or 2 substituents) propargyl, alkoxyalkyl, alkylthioalkyl, Alkyl, Al Kenil, haloalkenyl or polyhaloalkenyl), Alkylthio, Poly haloalkylthio, Alkylsulfinyl, polyhaloalkylsulfinyl, a Rukylsulfonyl, polyhaloalkylsulfonyl, Alkylsulfonylamino, Alkylcarbonylamino, polyhaloalkylsulfonylamino, Polyhaloal Kylcarbonylamino, trialkylsilyl, aryldialkylsilyl, bird arylsilyl, Sulfonic acid and its derived salts, phosphonic acid and its derivative salts, Al Koxycarbonylamino, alkylaminocarbonyloxy, dialkylamino carbonyloxy, alkenyl, polyhaloalkenyl, alkenyloxy, Al Kinil, Alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino ， semicarbazonomethyl, Alkoxycarbonylhydrazonomethyl, Alkoxy iminomethyl, substituted or unsubstituted aryloxyiminomethyl, Hydrazono Methyl, substituted or unsubstituted arylhydrazonomethyl, Things, G or Hydroxy group fused with polysaccharide, haloalkyl, haloalkenyl, C loalkynyl, alkoxyalkyl, aryloxy, Aralkoxy, Allie Lucio, aralkylthio, alkylthioalkyl, arylthioalkyl, a lylsulfinyl, arylsulfonyl, haloalkylsulfinyl, haloa Rukylsulfonyl, haloalkenyloxy, haloalkynyloxy, haloarchi Nilthio, haloalkenylsulfonyl, polyhaloalkenylsulfonyl, Arco xysulfonyl, aryloxysulfonyl, propargyloxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl, aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl, Arylaminosul Honil, carboxyalkoxy, carboxyalkylthio, alkoxy carboni Lualkoxy, Acyloxy, haloacyloxy, polyhaloacyloxy, Aro Iloxy, Alkylsulfonyloxy, alkenylsulfonyloxy, Allie Rusulfonyloxy, haloalkylsulfonyloxy, polyhaloalkyl sulfo Nyloxy, aroylamino, haloacylamino, alkoxycarbonyloxy ， arylsulfonylamino, aminocarbonyloxy, Seanat, isocyanana to, isothiocyano, cycloalkylamino, trialkylammonium, Ali Ruamino, aryl(alkyl)amino, araalkylamino, Alkoxia rukylphosphinil, alkoxyalkylphosphinothioyl, alkylhydro xyphosphinil, dialkoxyphosphino, hydroxyamino, Alkoxia Mino, aryloxyamino, aryloxyimino, Oxo, Chiono, Archi Ruaminoalkoxy, dialkylaminoalkoxy, alkoxyalkoxy, a Rukoxyalkenyl, cyanoalkoxy, dialkylsulfonium, -X, =X ， −X=R3, =X-R3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc. ▼ or ▲ formula, Chemical formula, There are tables etc. ▼ and Or R3 is a substituted heteroatom or a substituted carbon atom, or two or more carbon atoms or different atoms and the following: Substituted or unsubstituted straight or branched chains containing any combination of permissible substituents. There it is, The substituents may be the same or different and contain one or more hydrogen atoms, halogen, alkylcarbonyl, alkylcarbonylalkyl, Alkoxylic Bonyl alkyl, alkoxycarbonylalkylthio, Polyhaloalkenylthio ， Thiocyano, propargylthio, hydroxyimino, Alkoxyimino, bird Alkylsilyloxy, aryldialkylsilyloxy, triarylsilyl Oxy, Formamidino, Alkylsulfamide, dialkyl sulfamide, a Lucoxysulfonyl, polyhaloalkoxysulfonyl, Hydroxy, amino, a Minocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, a minothiocarbonyl, alkylaminothiocarbonyl, dialkylaminothioca Rubonil, nitro, Cyano, hydroxycarbonyl and its derivative salts, Formami Do, Alkyl, Alkoxy, polyhaloalkyl, polyhaloalkokyl, Alcoki cycarbonyl, Substituted amino (in which case permissible substituents may be the same or different) optionally one or two propargyl, alkoxyalkyl, Alkylthioal kill, Alkyl, alkenyl, haloalkenyl or polyhaloalkenyl) ， Alkylthio, polyhaloalkylthio, Alkylsulfinyl, Polyhaloal Kirsulfinyl, Alkylsulfonyl, polyhaloalkylsulfonyl, Archi Rusulfonylamino, Alkylcarbonylamino, polyhaloalkylsulfonyl amino, polyhaloalkylcarbonylamino, trialkylsilyl, Arielji alkylsilyl, triarylsilyl, Sulfonic acid and its derived salts, phosphonic acid and its derivative salts, alkoxycarbonylamino, alkylaminocarbonyloxy Shi, dialkylaminocarbonyloxy, alkenyl, polyhaloalkenyl, a rukenyloxy, Alkynyl, Alkynyloxy, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy, polyfluoroalkanol, cyanoalkylamino, semicarbazonomethyl, Alkoxycarbonylhydrazo nomethyl, Alkoxyiminomethyl, Substituted or unsubstituted aryloxyimides nomethyl, hydrazonomethyl, Substituted or unsubstituted arylhydrazonomethyl ， Things, hydroxy group fused with di- or polysaccharide, haloalkyl ， haloalkenyl, haloalkynyl, alkoxyalkyl, aryloxy, a Laalkoxy, arylthio, aralkylthio, alkylthioalkyl, Ali ruthioalkyl, arylsulfinyl, arylsulfonyl, haloalkyl sulfinyl, haloalkylsulfonyl, haloalkenyloxy, Halo Alkini Ruoxy, haloalkynylthio, haloalkenylsulfonyl, polyhaloalkeni rusulfonyl, alkoxysulfonyl, aryloxysulfonyl, Propargi Ruoxy, aroyl, haloacyl, polyhaloacyl, aryloxycarbonyl ， aminosulfonyl, alkylaminosulfonyl, dialkylaminosulfonyl ， arylaminosulfonyl, carboxyalkoxy, carboxyalkylthio ， alkoxycarbonylalkoxy, Acyloxy, haloacyloxy, Polyha loacyloxy, Aroyloxy, Alkylsulfonyloxy, alkenyl sul Honyloxy, arylsulfonyloxy, haloalkylsulfonyloxy, Po lyhaloalkylsulfonyloxy, aroylamino, haloacylamino, Arco xycarbonyloxy, arylsulfonylamino, aminocarbonyloxy, Seanat, isocyanate, isothiocyano, cycloalkylamino, trialarchy ammonium, arylamino, aryl(alkyl)amino, Araalkyl amino, alkoxyalkylphosphinyl, Alkoxyalkylphosphinothio Ile, Alkylhydroxyphosphinyl, dialkoxyphosphino, hydroxy amino, Alkoxyamino, aryloxyamino, aryloxyimino, O Kisso, Chiono, alkylaminoalkoxy, dialkylaminoalkoxy, Al Koxyalkoxy, alkoxyalkenyl, cyanoalkoxy, Dialkylsul Honium, -X, =X, −X=R3, =X-R3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc. ▼ or ▲ formula, Chemical formula, There are tables etc. ▼ and Y1 and Y4 are each oxygen or sulfur; Y2 and Y3 are oxygen, respectively. sulfur, amino or covalent; R4 and R5 are each hydrogen or substituted or unsubstituted alkyl, polyhaloalkyl le, phenyl or benzyl, Permissible substituents may be the same or different. often one or more hydrogens, halogen, alkylcarbonyl, Alkylcal Bonyl alkyl, alkoxycarbonylalkyl, alkoxycarbonyl alkyl Lucio, polyhaloalkenylthio, Thiocyano, propargylthio, hydroxy Imino, Alkoxyimino, trialkylsilyloxy, aryl dialkyl Ryloxy, triarylsilyloxy, Formamidino, Alkyl sulfami Do, dialkyl sulfamide, alkoxysulfonyl, Polyhaloalkoxysul Honil, Hydroxy, amino, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, aminothiocarbonyl, Alkylaminothiocal Bonil, dialkylaminothiocarbonyl, nitro, Cyano, Hydroxycarbo Nyl and its derivative salts, formamide, Alkyl, Alkoxy, polyhaloalkyl ， polyhaloalkoxy, alkoxycarbonyl, Substituted amino (acceptable in this case) The resulting substituents may be the same or different and include one or two propargyl, Arco xyalkyl, alkylthioalkyl, Alkyl, alkenyl, haloalkenyl or polyhaloalkenyl), Alkylthio, polyhaloalkylthio, Al Kirsulfinyl, polyhaloalkylsulfinyl, Alkylsulfonyl, Poly haloalkylsulfonyl, Alkylsulfonylamino, Alkyl carbonyl amide of, polyhaloalkylsulfonylamino, polyhaloalkylcarbonylamino, trialkylsilyl, aryldialkylsilyl, triarylsilyl, Sulho acid and its derived salts, phosphonic acid and its derivative salts, Alkoxycarbonylamino ， alkylaminocarbonyloxy, dialkylaminocarbonyloxy, Al Kenil, polyhaloalkenyl, alkenyloxy, Alkynyl, Alkynyloki Shi, polyhaloalkenyloxy, polyhaloalkynyl, polyhaloalkynyloxy Shi, polyfluoroalkanol, cyanoalkylamino, Semicarbazonomethyl ， Alkoxycarbonylhydrazonomethyl, Alkoxyiminomethyl, replacement or or unsubstituted aryloxyiminomethyl, hydrazonomethyl, Replaced or unused substituted arylhydrazonomethyl, Things, Condensation with di- or polysaccharide hydroxy group, haloalkyl, haloalkenyl, haloalkynyl, Alcoki Sialkyl, aryloxy, Aralkoxy, arylthio, Ala alkirchi Oh, alkylthioalkyl, arylthioalkyl, arylsulfinyl, a lylsulfonyl, haloalkylsulfinyl, haloalkylsulfonyl, Halo alkenyloxy, haloalkynyloxy, haloalkynylthio, haloarkeni rusulfonyl, polyhaloalkenylsulfonyl, alkoxysulfonyl, Allie oxysulfonyl, propargyloxy, aroyl, haloacyl, Polyhaloa Sil, aryloxycarbonyl, aminosulfonyl, alkylaminosulfony le, dialkylaminosulfonyl, arylaminosulfonyl, carboxial Koxi, carboxyalkylthio, alkoxycarbonylalkoxy, Asilo Kishi, haloacyloxy, polyhaloacyloxy, Aroyloxy, Archilus sulfonyloxy, alkenylsulfonyloxy, arylsulfonyloxy, C loalkylsulfonyloxy, polyhaloalkylsulfonyloxy, Aroyua Mino, haloacylamino, alkoxycarbonyloxy, Aryl sulfonylua Mino, aminocarbonyloxy, Seanat, isocyanate, isothiocyano, S Chloalkylamino, trialkylammonium, arylamino, Aryl ( alkyl) amino, araalkylamino, alkoxyalkylphosphinyl, a rukoxyalkylphosphinothioyl, Alkylhydroxyphosphinyl, Gia rukoxyphosphino, hydroxyamino, Alkoxyamino, aryloxia Mino, aryloxyimino, Oxo, Chiono, alkylaminoalkoxy, Ji alkylaminoalkoxy, alkoxyalkoxy, alkoxyalkenyl, S anoalkoxy, dialkylsulfonium, -X, =X, -X=R3, -X-R 3, -X-R3, ▲Math, Chemical formula, There are tables, etc.▼, ▲Math, Chemical formula, There are tables etc. ▼ or ▲ formula, Chemical formula, There is a table etc. ▼: 106. of plant photosynthesis Effective enough to reduce water loss from plants without substantially inhibiting electron transfer Water from a plant comprising an amount of the compound of claim 105 and an acceptable carrier. A composition for reducing minute losses. 107. Increase crop yield without substantially inhibiting photosynthetic electron transport in plants an effective amount of the compound of claim 105 and an acceptable carrier, sufficient to cause A composition for increasing the yield of crops consisting of: 108. Combining the compound with one or more other biologically active compounds The method according to claim 1, which is used in conjunction with the method. 109. Combining the compound with one or more other biologically active compounds 54. The method according to claim 53, wherein the method is used in conjunction with the method. 110. Water loss from plants without substantially inhibiting plant photosynthetic electron transport an effective amount of formula R1-X-R2 sufficient to reduce loss of (In the formula, R1, X and R2 are as described in claim 1) Plants or crops are planted by applying to the plant surface or to the crop a compound having methods of reducing water loss from soils that are