JPS63295402A - Production of hydrogen - Google Patents

Production of hydrogen

Info

Publication number
JPS63295402A
JPS63295402A JP12847987A JP12847987A JPS63295402A JP S63295402 A JPS63295402 A JP S63295402A JP 12847987 A JP12847987 A JP 12847987A JP 12847987 A JP12847987 A JP 12847987A JP S63295402 A JPS63295402 A JP S63295402A
Authority
JP
Grant status
Application
Patent type
Prior art keywords
hydrogen
reaction
membrane
permselective
chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12847987A
Inventor
Hidekazu Kikuchi
Original Assignee
Ise Kagaku Kogyo Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
    • C01B2203/041In-situ membrane purification during hydrogen production

Abstract

PURPOSE: To obtain high-purity hydrogen with high efficiency and at a low cost by carrying out a hydrogen generating reaction by reversible reaction in a reaction chamber with the wall formed with a hydrogen permselective membrane, and passing the formed hydrogen through the hydrogen permselective membrane to separate and collect the hydrogen.
CONSTITUTION: A reactor 1 is constituted of the reaction chamber 2 at least a part of the wall of which is formed with a hydrogen permselective membrane and an outer tube 3 concentric with the reaction chamber 2. A membrane produced by successively laminating a thin Pd film and a thin Cu film on the surface of a heat-resistant porous body having many small holes by chemical plating, and heating the material can be exemplified as the hydrogen permselective membrane. The raw materials (e.g., methanol and water) for the reaction (e.g., steam reforming reaction of methanol) for generating hydrogen by reversible reaction are then continuously supplied into the reaction chamber, and the raw materials react with each other. The generated hydrogen is passed through the hydrogen permselective membrane, and separated and collected.
COPYRIGHT: (C)1988,JPO&Japio
JP12847987A 1987-05-27 1987-05-27 Production of hydrogen Pending JPS63295402A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12847987A JPS63295402A (en) 1987-05-27 1987-05-27 Production of hydrogen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12847987A JPS63295402A (en) 1987-05-27 1987-05-27 Production of hydrogen

Publications (1)

Publication Number Publication Date
JPS63295402A true true JPS63295402A (en) 1988-12-01

Family

ID=14985753

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12847987A Pending JPS63295402A (en) 1987-05-27 1987-05-27 Production of hydrogen

Country Status (1)

Country Link
JP (1) JPS63295402A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02311301A (en) * 1989-05-25 1990-12-26 Mitsubishi Heavy Ind Ltd Production of hydrogen for fuel cell
US5518530A (en) * 1993-10-18 1996-05-21 Ngk Insulators, Ltd. Connected body comprising a gas separator and a metal, and apparatus for separating hydrogen gas from a mixed gas
US5614001A (en) * 1994-05-23 1997-03-25 Ngk Insulators, Ltd. Hydrogen separator, hydrogen separating apparatus and method for manufacturing hydrogen separator
US5674301A (en) * 1994-05-23 1997-10-07 Ngk Insulators, Ltd. Hydrogen preparing apparatus
US5741474A (en) * 1994-05-23 1998-04-21 Ngk Insulators, Ltd. Process for production of high-purity hydrogen
US5958098A (en) * 1997-10-07 1999-09-28 Westinghouse Savannah River Company Method and composition in which metal hydride particles are embedded in a silica network
US6179902B1 (en) 1997-01-20 2001-01-30 Ngk Insulators, Ltd. Apparatus for recovering, refining, and storing hydrogen gas
WO2001027041A1 (en) * 1999-10-12 2001-04-19 Christopher Maltin Apparatus for treating fluids
WO2001036077A1 (en) * 1999-11-18 2001-05-25 Toyota Jidosha Kabushiki Kaisha Device forming fuel gas for fuel cell and composite material for hydrogen separation
US6315820B1 (en) * 1999-10-19 2001-11-13 Ford Global Technologies, Inc. Method of manufacturing thin metal alloy foils
US6540850B2 (en) * 2001-05-03 2003-04-01 Ford Motor Company Membrane and a method for making a membrane
EP1499452A4 (en) * 2002-04-03 2006-07-05 Colorado School Of Mines Process for preparing palladium alloy composite membranes for use in hydrogen separation, palladium alloy composite membranes and products incorporating or made from the membranes
JP2006232607A (en) * 2005-02-24 2006-09-07 Japan Energy Corp Hydrogen production method
JP2008273764A (en) * 2007-04-26 2008-11-13 Ngk Insulators Ltd Method for producing hydrogen using permselective membrane reactor
US8101243B2 (en) 2002-04-03 2012-01-24 Colorado School Of Mines Method of making sulfur-resistant composite metal membranes
US8778058B2 (en) 2010-07-16 2014-07-15 Colorado School Of Mines Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same
US9044715B2 (en) 2007-08-22 2015-06-02 Colorado School Of Mines Unsupported palladium alloy membranes and methods of making same

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02311301A (en) * 1989-05-25 1990-12-26 Mitsubishi Heavy Ind Ltd Production of hydrogen for fuel cell
US5518530A (en) * 1993-10-18 1996-05-21 Ngk Insulators, Ltd. Connected body comprising a gas separator and a metal, and apparatus for separating hydrogen gas from a mixed gas
US5614001A (en) * 1994-05-23 1997-03-25 Ngk Insulators, Ltd. Hydrogen separator, hydrogen separating apparatus and method for manufacturing hydrogen separator
US5674301A (en) * 1994-05-23 1997-10-07 Ngk Insulators, Ltd. Hydrogen preparing apparatus
US5741474A (en) * 1994-05-23 1998-04-21 Ngk Insulators, Ltd. Process for production of high-purity hydrogen
US5897970A (en) * 1994-05-23 1999-04-27 Ngk Insulators, Ltd. System for production of high-purity hydrogen, process for production of high-purity hydrogen, and fuel cell system
US5958091A (en) * 1994-05-23 1999-09-28 Ngk Insulators, Ltd. Hydrogen preparing apparatus
US6179902B1 (en) 1997-01-20 2001-01-30 Ngk Insulators, Ltd. Apparatus for recovering, refining, and storing hydrogen gas
US5958098A (en) * 1997-10-07 1999-09-28 Westinghouse Savannah River Company Method and composition in which metal hydride particles are embedded in a silica network
WO2001027041A1 (en) * 1999-10-12 2001-04-19 Christopher Maltin Apparatus for treating fluids
US6733671B1 (en) 1999-10-12 2004-05-11 Christopher Maltin Apparatus for treating fluids
US6315820B1 (en) * 1999-10-19 2001-11-13 Ford Global Technologies, Inc. Method of manufacturing thin metal alloy foils
JP2002033113A (en) * 1999-11-18 2002-01-31 Toyota Motor Corp Fuel gas generating device for fuel cell and composite material for hydrogen separation
WO2001036077A1 (en) * 1999-11-18 2001-05-25 Toyota Jidosha Kabushiki Kaisha Device forming fuel gas for fuel cell and composite material for hydrogen separation
US7255721B1 (en) 1999-11-18 2007-08-14 Toyota Jidosha Kabushiki Kaisha Device forming fuel gas for fuel cell and composite material for hydrogen separation
US6540850B2 (en) * 2001-05-03 2003-04-01 Ford Motor Company Membrane and a method for making a membrane
EP1499452A4 (en) * 2002-04-03 2006-07-05 Colorado School Of Mines Process for preparing palladium alloy composite membranes for use in hydrogen separation, palladium alloy composite membranes and products incorporating or made from the membranes
US8101243B2 (en) 2002-04-03 2012-01-24 Colorado School Of Mines Method of making sulfur-resistant composite metal membranes
US8119205B2 (en) 2002-04-03 2012-02-21 Colorado School Of Mines Process for preparing palladium alloy composite membranes for use in hydrogen separation, palladium alloy composite membranes and products incorporating or made from the membranes
JP2006232607A (en) * 2005-02-24 2006-09-07 Japan Energy Corp Hydrogen production method
JP2008273764A (en) * 2007-04-26 2008-11-13 Ngk Insulators Ltd Method for producing hydrogen using permselective membrane reactor
US9044715B2 (en) 2007-08-22 2015-06-02 Colorado School Of Mines Unsupported palladium alloy membranes and methods of making same
US8778058B2 (en) 2010-07-16 2014-07-15 Colorado School Of Mines Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

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