JPS63241131A - Copper alloy for sliding material - Google Patents

Copper alloy for sliding material

Info

Publication number
JPS63241131A
JPS63241131A JP7024887A JP7024887A JPS63241131A JP S63241131 A JPS63241131 A JP S63241131A JP 7024887 A JP7024887 A JP 7024887A JP 7024887 A JP7024887 A JP 7024887A JP S63241131 A JPS63241131 A JP S63241131A
Authority
JP
Japan
Prior art keywords
alloy
sliding
copper alloy
swash plate
shoe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7024887A
Other languages
Japanese (ja)
Inventor
Hidehiko So
宗 秀彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Mining Co Ltd filed Critical Nippon Mining Co Ltd
Publication of JPS63241131A publication Critical patent/JPS63241131A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the titled copper alloy having high strength, having small softening of the material at height temp. and having good sliding characteristics by limiting the contents of Ni and Si. CONSTITUTION:The copper alloy contg. by weight, 0.4-4.0% Ni, 0.1-1.0% Si and the balance consisting of copper with inevitable impurities is prepd. The total 0.001-3.0% of one or more kinds among Zn, P, Sn, As, Cr, Mg, Mn, Sb, Co, Al, Ti, Zr, Be, Ag, Pb, B and lanthanoid elements are furthermore added to the alloy at need as the auxiliary components. The copper alloy which is strengthened in the range of not very lowering the heat conductivity, has the small lowering of hardness particularly under high temps. and has the good sliding characteristics can be obtd. by the above-mentioned constitution. Said alloy is therefore suitable for a sliding material such as a shoe of a swash plate type compressor, etc., in which the sliding conditions are extremely severe.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、摺動特性に優れた摺動材料用銅合金に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a copper alloy for sliding materials having excellent sliding properties.

(従来の技術および問題点) 一般に銅系の摺動材料には、リン青銅、高力黄銅等が知
られている。しかしながら、このような公知の銅系材料
では、特に苛酷な摺動条件にさらされる衝動材料として
は1・分なものではなかった。
(Prior Art and Problems) Phosphor bronze, high-strength brass, and the like are generally known as copper-based sliding materials. However, such known copper-based materials cannot be used as impulse materials exposed to particularly severe sliding conditions.

このように、l、!/酷な条件下で使用されるjH動部
材の代表的なものに、特開昭61−166936に示さ
れているような斜板式コンプレッサのシューがある。
Like this, l,! A typical example of a jH moving member used under severe conditions is the shoe of a swash plate compressor as shown in Japanese Patent Laid-Open No. 166936/1983.

この斜板式コンプレッサを簡単に説明すると、第1図に
示されるように、斜板1には、これを跨ぐ形態に係留さ
れたビス1−ン2を備える。斜板1を回転させるとピス
トン2が往復動し、その結果内部に封入された冷媒ガス
をシリンダボア3に吸入し、圧縮する。斜板1はシリン
ダブロック4に回転可能に支持されたシャツI〜5に固
定されており、ピストン2はシュー6およびボール7を
介して斜板1に係留されている。シャツ1−5により斜
板1が一体的に回転させられると、シュー6は斜板1の
摺動面」−を摺動しつつ斜板1の外周部の軸方向におけ
る運動をボール7を介してビス1〜ン2に伝達する構造
となっている。このような斜板式コンプレッサはカーク
ーラに用いられている。
Briefly explaining this swash plate type compressor, as shown in FIG. 1, a swash plate 1 is provided with a screw 1-2 which is moored to straddle the swash plate 1. When the swash plate 1 is rotated, the piston 2 reciprocates, and as a result, the refrigerant gas sealed inside is sucked into the cylinder bore 3 and compressed. The swash plate 1 is fixed to shirts I to 5 which are rotatably supported by a cylinder block 4, and the piston 2 is moored to the swash plate 1 via a shoe 6 and a ball 7. When the swash plate 1 is rotated integrally by the shirt 1-5, the shoes 6 slide on the sliding surface of the swash plate 1 and move the outer circumference of the swash plate 1 in the axial direction via the balls 7. The structure is such that the signal is transmitted to screws 1 to 2. Such swash plate compressors are used in car coolers.

上記のカークーラーに使用される斜板式コンプレッサに
おいて、最も厳しい摺動条件にさらされる部分は第1図
の斜板1とシュー6との摺動部である。摺動速度がエン
ジンのアイドリング状態では約2〜3m/see、最高
回転時の約600Orpmでは20〜25m/secと
なり、通常走行時でも約7〜15m/secの高速にな
る。
In the swash plate compressor used in the above car cooler, the part exposed to the most severe sliding conditions is the sliding part between the swash plate 1 and the shoe 6 shown in FIG. The sliding speed is about 2 to 3 m/sec when the engine is idling, 20 to 25 m/sec at about 600 rpm at maximum rotation, and about 7 to 15 m/sec even during normal running.

しかも、シューの受ける荷重は特に高回転になるとm撃
的荷重になり、このような衝撃荷重を受けながら、しか
も高速摺動するという極めて苛酷な摺動条件が斜板とシ
ューとの摺動部には生じる。
Moreover, the load that the shoe receives becomes a shocking load especially at high rotation speeds, and the sliding part between the swash plate and the shoe has extremely severe sliding conditions of receiving such impact load and sliding at high speed. occurs.

このようなことから上記のような高面圧、衝撃荷重に酎
える材料として、斜板には機械的な剛性、疲労強度、耐
摩耗性を持つ構造用合金鋼のニッケルクロム鋼、ニッケ
ルモリブデン鋼、クロムモリブデン鋼や、球状黒鉛鋳鉄
等が用いられ、また、シュー材料としては、前記のよう
なリン青銅、高力黄銅の他にアルシル合金、銅−鉛一錫
合金、黄銅、青銅、アルミニウム青銅、バビットメタル
、含油軸受合金等が考えられていた。
For this reason, nickel-chromium steel and nickel-molybdenum steel, which are structural alloy steels that have mechanical rigidity, fatigue strength, and wear resistance, are used for swash plates as materials that can handle the high surface pressure and impact loads mentioned above. , chromium molybdenum steel, spheroidal graphite cast iron, etc. are used. In addition to the above-mentioned phosphor bronze and high-strength brass, arsil alloy, copper-lead monotin alloy, brass, bronze, and aluminum bronze are used as shoe materials. , Babbitt metal, oil-impregnated bearing alloys, etc. were considered.

しかし、カークーラ用斜板式コンプレッサ特有の極めて
苛酷な運転条件に対し、上記のシュー材料はどれも満足
できるものはなかった。
However, none of the above shoe materials has been able to satisfy the extremely severe operating conditions unique to swash plate compressors for car coolers.

(1?、’J題点を解決するための手段)このような事
情に鑑みて1本発明者らは種々の研究開発を行った結果
、熱伝導度をあまり低下させない範囲で強化され、かつ
、特に高温下での硬度の低下が少なく、しかも良好な摺
動特性を有する摺動材料を開発した。その要旨とすると
ころは、Ni0.4〜4.0wt%、Si0.1〜1.
0wt%を含み、残部Cuおよび不可避的不純物からな
るか、もしくはNi0.4〜4.0wt%、Si0.1
〜1.0wt%を含み、さらに副成分として、Zn、P
、Sn、As、Cr、Mg、Mn、Sb、Fe%Go、
A1.Ti、Zr、Be。
(1?, Means for Solving Problem 'J) In view of these circumstances, 1. The present inventors have conducted various research and development, and as a result, the thermal conductivity has been strengthened to the extent that it does not decrease too much, and We have developed a sliding material that has good sliding properties, with little decrease in hardness, especially at high temperatures. The gist is that Ni is 0.4 to 4.0 wt%, Si is 0.1 to 1.
0 wt%, with the balance consisting of Cu and unavoidable impurities, or Ni0.4 to 4.0 wt%, Si0.1
~1.0wt%, and further contains Zn and P as subcomponents.
, Sn, As, Cr, Mg, Mn, Sb, Fe%Go,
A1. Ti, Zr, Be.

Ag、Pb、B、ランタノイド元素からなる1種または
2種以上を総量で0.001〜3.Ow t%含み、残
部Cuおよび不可避的不純物からなる銅合金である。
The total amount of one or more of Ag, Pb, B, and lanthanide elements is 0.001 to 3. It is a copper alloy consisting of Ow t% and the remainder Cu and unavoidable impurities.

°本発明におけるNi、Siは、Cu母材内にNi2S
i 等の金属間化合物として析出し1強化する元素であ
る。
°Ni and Si in the present invention are Ni2S in the Cu base material.
It is an element that precipitates as an intermetallic compound such as i and strengthens 1.

潤滑オイル量の少ない摺動部において最も問題になるの
は摺動部材の熱伝導度である。このためシュー材料とし
てはなじみ性を重んじるよりも熱伝導性を良くし、効果
的に熱を放散させることおよび高温下で硬度の低下を少
なくして組織変化を少なくすることがシューのすベリ性
能を改善する上で有効である。
In sliding parts where the amount of lubricating oil is small, the most important issue is the thermal conductivity of the sliding members. For this reason, for shoe materials, rather than focusing on conformability, it is important to improve thermal conductivity, effectively dissipate heat, and reduce the decrease in hardness at high temperatures to minimize structural changes. It is effective in improving

この意味において、熱伝導率をあまり低下させず、強度
を向上させる析出硬化型のCu −N i −8i系の
合金が有効なのであり、これによって強靭で焼付きにく
い優れた摺動材料を得ることができる。
In this sense, precipitation-hardening Cu-Ni-8i alloys that improve strength without significantly reducing thermal conductivity are effective, and this makes it possible to obtain excellent sliding materials that are tough and resistant to seizure. Can be done.

また、高性能カークーラ用斜板式コンプレッサのシュー
に使用される摺動材料の硬度は、300℃の高温度下に
おいてビッカース硬さくHv)80以上が望ましいこと
も明らかとなったが1本発明に係る摺動材料はいずれも
このような望ましい硬度を有している。
It has also been found that the hardness of the sliding material used for the shoe of a swash plate compressor for a high-performance car cooler is desirably 80 or higher (Vickers hardness Hv) at a high temperature of 300°C. All sliding materials have such desirable hardness.

ここにおいて、本発明に従ってCuに添付される元素の
それぞれの添加量は、次のことを考慮して定められる。
Here, the amount of each element added to Cu according to the present invention is determined in consideration of the following.

すなわち、まずNiはCu中にSiと共添し、溶体化処
理後時効処理を行うことにより、Ni、Si  等の金
属間化合物として析出し、熱伝導度を低下させずに強度
を向上させる元素であるが、0.4〜4.0wt%添加
する理由は、0.4wt%未満では強度の向上は認めら
れず、4.0wt%を超えると熱伝導度、および加工性
が劣化するためである。Siも同様にNiと共添し、金
属間化合物として析出することにより、熱伝導度を低下
させずに強度を向上させる元素であるが、O,l〜l、
0wt%添加する理由は、011wt%未満では強度の
向上は認められず、1゜0wt%を超えると、熱伝導度
が著しく劣化するためである。望ましくは、Ni、Si
の添加量の比は、金属間化合物(Ni、Si)の組成に
近い(Ni/5i)= (4/L)が良い。さらに副成
分として、Zn、P、Sn、λs、Cr、Mg、Mn−
1Sb、  Fe、Co、Al、Ti、  Zr、Be
、Ag、Pb、B、ランタノイド元素からなる1種また
は2種以上を0.001〜3.Owt%添加するのは、
強度を向上させるためであるが、0゜001wt%未満
ではその効果はなく、3.0wt%を超えると熱伝導率
が低下するためである。
That is, first, Ni is co-added with Si in Cu, and by performing solution treatment and aging treatment, it precipitates as intermetallic compounds such as Ni and Si, and is an element that improves strength without reducing thermal conductivity. However, the reason for adding 0.4 to 4.0 wt% is that if it is less than 0.4 wt%, no improvement in strength will be observed, and if it exceeds 4.0 wt%, thermal conductivity and workability will deteriorate. be. Si is also an element that improves strength without reducing thermal conductivity by co-adding with Ni and precipitating as an intermetallic compound;
The reason for adding 0 wt% is that if it is less than 0.11 wt%, no improvement in strength will be observed, and if it exceeds 1.0 wt%, the thermal conductivity will be significantly degraded. Preferably Ni, Si
The ratio of the amounts added is preferably (Ni/5i)=(4/L), which is close to the composition of the intermetallic compound (Ni, Si). Furthermore, as subcomponents, Zn, P, Sn, λs, Cr, Mg, Mn-
1Sb, Fe, Co, Al, Ti, Zr, Be
, Ag, Pb, B, and one or more lanthanoid elements in an amount of 0.001 to 3. Adding Owt% is
This is to improve the strength, but if it is less than 0°001 wt%, there is no effect, and if it exceeds 3.0 wt%, the thermal conductivity will decrease.

(効 果) 本発明に係るCu合金摺動材料には次の様な効果を認め
ることができる。
(Effects) The following effects can be recognized in the Cu alloy sliding material according to the present invention.

まず従来の黄銅、リン青銅等のシュー材料に比べ、添加
元素の量が著しく少ないため、熱伝導率が高く、放熱性
が良いため、焼付きにくい。また、析出硬化型鋼合金で
あるため、添加量が少ないが。
First, compared to conventional shoe materials such as brass and phosphor bronze, the amount of added elements is significantly smaller, so it has higher thermal conductivity and better heat dissipation, so it is less likely to seize. Also, since it is a precipitation hardening steel alloy, the amount added is small.

強度が高く、かつ高温になっても材料の軟化がほとんど
ない。
It has high strength and hardly softens even at high temperatures.

以上の説明から明らかなように、本発明の合金は摺動条
件が極めて苛酷である摺動材料用に開発されたものであ
るが、前記のようなコンプレッサシュー用のみならず滑
り軸受用のブツシュ、スラストワッシャ等、潤滑オイル
量、負荷等の摺動条件が前記のようなシューはどには厳
しくない摺動部材用の材料として使用することもできる
As is clear from the above description, the alloy of the present invention was developed for use in sliding materials where the sliding conditions are extremely severe, but it can be used not only for compressor shoes as described above but also for bushings for sliding bearings. It can also be used as a material for sliding members such as thrust washers and the like, where the sliding conditions such as the amount of lubricating oil and the load are not severe for shoes such as those mentioned above.

(実施例) 以下に本発明の具体例を示す。(Example) Specific examples of the present invention are shown below.

まず、第1表に示す組成割合で、鋳造法により試料1〜
20を得た。得られた鋳物を850’Cにて2hr大気
中にて加熱し均質化焼鈍を行った後。
First, samples 1 to 1 were cast using the composition ratio shown in Table 1.
I got 20. The obtained casting was heated in the atmosphere at 850'C for 2 hours to perform homogenization annealing.

400〜500℃で所定時間時効処理を行い。Aging treatment is performed at 400 to 500°C for a predetermined period of time.

Cu合会合材料得た。A Cu aggregation material was obtained.

そして、得られたこれらの材料による実機試験を行うた
めに、それぞれ直径18no、厚さ4.5臘に加工を施
してシューを得た。また、このシューには中心に直径約
14+mのボールの一部が内接するように深さ約3膣の
球状凹面が施しである。
In order to conduct actual machine tests using these obtained materials, shoes were processed to have a diameter of 18 mm and a thickness of 4.5 mm, respectively. Further, this shoe has a spherical concave surface with a depth of about 3 vagina so that a part of a ball with a diameter of about 14+ m is inscribed in the center.

なお、比較試料として上記と同様の方法により、第2表
に示す合金組成の試料21〜34を作り、本発明に係る
Cu合金から得られるシューとの比較を行った。
As comparative samples, Samples 21 to 34 having the alloy compositions shown in Table 2 were prepared by the same method as above, and compared with the shoe obtained from the Cu alloy according to the present invention.

第3.4表には、これらのCu合会合材料諸特性値であ
る。本発明合金は、硬さ160Hv以上、熱伝導率1.
5J/aII−5ec・℃以上と高強度で熱放散性も良
好であることがわかる。また、軟化特性は400℃にお
いて5分間放置したときの硬さの値である。本発明合金
は、高温下に放置されても軟化しにくいことがわかる。
Table 3.4 shows various characteristic values of these Cu aggregation materials. The alloy of the present invention has a hardness of 160 Hv or more and a thermal conductivity of 1.
It can be seen that it has high strength of 5J/aII-5ec·°C or more and good heat dissipation properties. Moreover, the softening property is the value of hardness when left at 400° C. for 5 minutes. It can be seen that the alloy of the present invention does not easily soften even when left at high temperatures.

さらに、実験1.2により、これらのCu合金組成の摺
動した場合の発熱特性と実機試験での評価を行った。
Furthermore, in Experiment 1.2, the heat generation characteristics of these Cu alloy compositions when sliding were evaluated and evaluated in actual machine tests.

実験−1(発熱特性) 第1表、第2表の各試料を用いて発熱温度を測定する実
験を行った。
Experiment-1 (Exothermic properties) An experiment was conducted to measure the exothermic temperature using each sample in Tables 1 and 2.

測定方法としては円板を回転させ、これにシューを押圧
し、その抑圧荷重を漸増させながら、その時のシューの
発熱温度を測定した4 条件 (1)すベリ速度  13m/5ee一定(2)荷  
 重  40kg/alFより20kg1aJずつ漸増 各荷重段階は30分 (3)潤滑オイル  低粘度オイル5SU70(4)潤
滑方法  フェルト塗布 約0.8cc/分 (5)試 験 片  ディスク:真直度1μm以下、あ
らさく最大)0.4〜 0.6−S シュー:真直度1μm以下、 あらさく最大)0.4〜0.6 S 第3表、第4表中の発熱温度の項目は、荷重を100g
としたときの発熱温度である。本発明合金は荷重をかけ
て摺動させても、発熱量は少ないことがわかる。第2図
は第3表、第4表中の代表的な合金材料の荷重に対する
発熱温度である。本発明合金は、従来のリン青銅、高力
黄銅と比較し、発熱量が少ないことがわかる。
The measurement method was to rotate the disc, press the shoe against it, and measure the heat generation temperature of the shoe while gradually increasing the suppressing load.4 Conditions (1) Buri speed 13m/5ee constant (2) Load
Weight Gradually increase by 20 kg/aJ from 40 kg/alF, each load stage is 30 minutes (3) Lubricating oil Low viscosity oil 5SU70 (4) Lubrication method Felt application Approximately 0.8 cc/min (5) Test piece Disc: Straightness 1 μm or less, rough Maximum thickness) 0.4~0.6-S Shoe: Straightness 1μm or less, Maximum roughness) 0.4~0.6S The exothermic temperature items in Tables 3 and 4 are based on a load of 100g.
This is the exothermic temperature when It can be seen that even when the alloy of the present invention is slid under load, the amount of heat generated is small. FIG. 2 shows the heat generation temperature with respect to the load of typical alloy materials in Tables 3 and 4. It can be seen that the alloy of the present invention generates less heat than conventional phosphor bronze and high-strength brass.

実験−2(実機試験) 次に実機試験を行った。以下の条件で斜板式コンプレッ
サを運転し、焼付きの有無を試験した。
Experiment-2 (actual machine test) Next, a real machine test was conducted. The swash plate compressor was operated under the following conditions and tested for seizure.

(1)コンプレッサ  斜板式コンプレッサ(総排気量
150cc) ・(2)回  転  数   400Orpm(3)吐
出側ガス圧  Pd=4〜5kg/at!(4)吸入側
ガス圧  Ps=約−50mmHg(5)作動時間 2
0 Hr 5 (6)潤滑オイル  冷凍機オイル 150ω(7)相
手材料  球状黒鉛鋳鉄 (8)ガ ス 量  100g (正規の約10%)第
3表、第4表の実機試験の項目は、この試験の結果であ
り、内容は。
(1) Compressor Swash plate compressor (total displacement 150cc) (2) Number of revolutions 400Orpm (3) Discharge side gas pressure Pd = 4~5kg/at! (4) Suction side gas pressure Ps = approx. -50mmHg (5) Operating time 2
0 Hr 5 (6) Lubricating oil Refrigerator oil 150Ω (7) Compatible material Spheroidal graphite cast iron (8) Gas amount 100 g (Approx. 10% of the regular value) The items of the actual machine test in Tables 3 and 4 are based on this test. The results and contents are.

○;異常なし Δ;一部焼付き ×;焼付き ××;試験中に変形もしくは摩耗 である。これらの表かられかる様に、本発明合金は、斜
板式コンプレッサのシューに用いても、発熱、軟化、変
形、摩耗、焼付きの起こらない、非常に良好な摺動材料
用銅合金であることがわかる。
○: No abnormality Δ: Partial seizure ×; Seizure XX: Deformed or worn during the test. As can be seen from these tables, the alloy of the present invention is a very good copper alloy for sliding materials that does not generate heat, soften, deform, wear, or seize even when used in the shoes of swash plate compressors. I understand that.

(以下余白) 第1表 第2表 第3表 第4表(Margin below) Table 1 Table 2 Table 3 Table 4

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、斜板式コンプレッサを説明するための縦断面
図である。 1、斜板       2.ピストン 3、シリンダボア   4.シリンダブロック5、シャ
フト     6.シュー 7、ボール 第2図は、本発明の効果を調べるための実験において得
られた発熱特性の代表的なグラフである。
FIG. 1 is a longitudinal sectional view for explaining a swash plate compressor. 1. Swash plate 2. Piston 3, cylinder bore 4. Cylinder block 5, shaft 6. Shoe 7 and Ball FIG. 2 is a typical graph of heat generation characteristics obtained in an experiment to investigate the effects of the present invention.

Claims (2)

【特許請求の範囲】[Claims] (1)Ni0.4〜4.0wt%、Si0.1〜1.0
wt%を含み、残部Cuおよび不可避的不純物からなる
摺動材料用銅合金。
(1) Ni0.4-4.0wt%, Si0.1-1.0
Copper alloy for sliding materials containing % wt% and the balance consisting of Cu and unavoidable impurities.
(2)Ni0.4〜4.0wt%、Si0.1〜1.0
wt%を含み、さらに副成分としてZn、P、Sn、A
s、Cr、Mg、Mn、Sb、Fe、Co、Al、Ti
、Zr、Be、Ag、Pb、B、ランタノイド元素から
なる1種または2種以上を総量で0.001〜3.0w
t%含み、残部Cuおよび不可避的不純物からなる摺動
材料用銅合金。
(2) Ni0.4-4.0wt%, Si0.1-1.0
wt%, and further contains Zn, P, Sn, and A as subcomponents.
s, Cr, Mg, Mn, Sb, Fe, Co, Al, Ti
, Zr, Be, Ag, Pb, B, and one or more lanthanoid elements in a total amount of 0.001 to 3.0w.
A copper alloy for sliding materials, which contains t% and the balance is Cu and unavoidable impurities.
JP7024887A 1986-11-20 1987-03-26 Copper alloy for sliding material Pending JPS63241131A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP27515186 1986-11-20
JP61-275151 1986-11-20

Publications (1)

Publication Number Publication Date
JPS63241131A true JPS63241131A (en) 1988-10-06

Family

ID=17551384

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7024887A Pending JPS63241131A (en) 1986-11-20 1987-03-26 Copper alloy for sliding material

Country Status (1)

Country Link
JP (1) JPS63241131A (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02179839A (en) * 1988-12-29 1990-07-12 Kobe Steel Ltd High strength copper alloy having excellent impact resistance
JPH03115538A (en) * 1989-09-29 1991-05-16 Tsuneaki Mikawa Oxide dispersion strengthened special copper alloy
US5256494A (en) * 1990-11-29 1993-10-26 Daido Metal Company Ltd. Sliding member with a sintered copper alloy layer
US5833920A (en) * 1996-02-20 1998-11-10 Mitsubishi Denki Kabushiki Kaisha Copper alloy for electronic parts, lead-frame, semiconductor device and connector
JP2002020825A (en) * 2000-05-20 2002-01-23 Stolberger Metallwerke Gmbh & Co Kg Electroconductive metallic band and connector
JP2002025334A (en) * 2000-05-20 2002-01-25 Stolberger Metallwerke Gmbh & Co Kg Conductive metal band and connector made of the same
WO2005083137A1 (en) * 2004-02-27 2005-09-09 The Furukawa Electric Co., Ltd. Copper alloy
JP2007084927A (en) * 2005-08-26 2007-04-05 Hitachi Cable Ltd Backing plate made of copper alloy, and method for producing the copper alloy
JP2008163439A (en) * 2007-01-05 2008-07-17 Sumitomo Light Metal Ind Ltd Copper alloy material and method for producing the same, and electrode member of welding equipment
JP2008540837A (en) * 2005-05-13 2008-11-20 フエデラル―モーグル・ウイースバーデン・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング Sliding bearing composite material, use and manufacturing method
DE102007031979A1 (en) * 2007-07-10 2009-01-22 Federal-Mogul Wiesbaden Gmbh Thrust washer made of single layer material, comprises a carrier layer having micro alloy elements, and lead free copper alloy
JP2010280984A (en) * 2009-06-08 2010-12-16 Miyoshi Gokin Kogyo Kk Method for producing copper alloy used as sliding material for motor
KR101319725B1 (en) * 2005-05-13 2013-10-17 페데랄-모굴 비스바덴 게엠베하 Plain bearing composite material, use thereof and production methods therefor
KR101319814B1 (en) * 2005-05-13 2013-10-17 페데랄-모굴 비스바덴 게엠베하 Plain bearing composite material, use thereof and production methods therefor

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02179839A (en) * 1988-12-29 1990-07-12 Kobe Steel Ltd High strength copper alloy having excellent impact resistance
JPH0469219B2 (en) * 1988-12-29 1992-11-05 Kobe Steel Ltd
JPH03115538A (en) * 1989-09-29 1991-05-16 Tsuneaki Mikawa Oxide dispersion strengthened special copper alloy
JPH0530894B2 (en) * 1989-09-29 1993-05-11 Tsuneaki Mikawa
US5256494A (en) * 1990-11-29 1993-10-26 Daido Metal Company Ltd. Sliding member with a sintered copper alloy layer
US5833920A (en) * 1996-02-20 1998-11-10 Mitsubishi Denki Kabushiki Kaisha Copper alloy for electronic parts, lead-frame, semiconductor device and connector
JP2002020825A (en) * 2000-05-20 2002-01-23 Stolberger Metallwerke Gmbh & Co Kg Electroconductive metallic band and connector
JP2002025334A (en) * 2000-05-20 2002-01-25 Stolberger Metallwerke Gmbh & Co Kg Conductive metal band and connector made of the same
WO2005083137A1 (en) * 2004-02-27 2005-09-09 The Furukawa Electric Co., Ltd. Copper alloy
US8951371B2 (en) 2004-02-27 2015-02-10 The Furukawa Electric Co., Ltd. Copper alloy
JP2008540837A (en) * 2005-05-13 2008-11-20 フエデラル―モーグル・ウイースバーデン・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング Sliding bearing composite material, use and manufacturing method
KR101319724B1 (en) * 2005-05-13 2013-10-17 페데랄-모굴 비스바덴 게엠베하 Plain bearing composite material, use thereof and production methods therefor
KR101319725B1 (en) * 2005-05-13 2013-10-17 페데랄-모굴 비스바덴 게엠베하 Plain bearing composite material, use thereof and production methods therefor
KR101319814B1 (en) * 2005-05-13 2013-10-17 페데랄-모굴 비스바덴 게엠베하 Plain bearing composite material, use thereof and production methods therefor
JP2007084927A (en) * 2005-08-26 2007-04-05 Hitachi Cable Ltd Backing plate made of copper alloy, and method for producing the copper alloy
JP2008163439A (en) * 2007-01-05 2008-07-17 Sumitomo Light Metal Ind Ltd Copper alloy material and method for producing the same, and electrode member of welding equipment
DE102007031979A1 (en) * 2007-07-10 2009-01-22 Federal-Mogul Wiesbaden Gmbh Thrust washer made of single layer material, comprises a carrier layer having micro alloy elements, and lead free copper alloy
JP2010280984A (en) * 2009-06-08 2010-12-16 Miyoshi Gokin Kogyo Kk Method for producing copper alloy used as sliding material for motor

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