JPS6272640A - Production of 1,2-dihydroxy-3-methoxybenzene compound - Google Patents
Production of 1,2-dihydroxy-3-methoxybenzene compoundInfo
- Publication number
- JPS6272640A JPS6272640A JP60213294A JP21329485A JPS6272640A JP S6272640 A JPS6272640 A JP S6272640A JP 60213294 A JP60213294 A JP 60213294A JP 21329485 A JP21329485 A JP 21329485A JP S6272640 A JPS6272640 A JP S6272640A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- formula
- amount
- dimethyl sulfate
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 1,2-dihydroxy-3-methoxybenzene compound Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N Dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N Pyrogallol Chemical class OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To obtain the titled compound useful as an intermediate for the production of pharmaceuticals, agricultural chemicals, etc., easily in high yield, by reacting a 1,2,3-trinhydroxybenzene derivative with dimethyl sulfate in the presence of boric acid and an alkali while controlling the amount of water used as a solvent.
CONSTITUTION: The objective compound is produced by reacting the 1,2,3- trihydroxybenzene derivative of formula (A is H, carboxyl or COOR1; R1 is lower alkyl) with dimethyl sulfate in the presence of boric acid salt (preferably 0.8W1.5mol per 1mol of the compound of formula) and an alkali (e.g. sodium hydroxide, etc., in an amount of e.g. 0.5W2mol per 1mol of the raw material) in ≤30ml, preferably 5W25ml of water (based on 1g of the compound of formula) to effect the conversion of the compound to monomethyl ether. The amount of the dimethyl sulfate is e.g. 0.5W2mol per 1mol of the raw material.
COPYRIGHT: (C)1987,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60213294A JPS6272640A (en) | 1985-09-26 | 1985-09-26 | Production of 1,2-dihydroxy-3-methoxybenzene compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60213294A JPS6272640A (en) | 1985-09-26 | 1985-09-26 | Production of 1,2-dihydroxy-3-methoxybenzene compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6272640A true JPS6272640A (en) | 1987-04-03 |
Family
ID=16636737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60213294A Pending JPS6272640A (en) | 1985-09-26 | 1985-09-26 | Production of 1,2-dihydroxy-3-methoxybenzene compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6272640A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009126784A (en) * | 2007-11-19 | 2009-06-11 | Mitsubishi Gas Chem Co Inc | Method for producing 2-iodo-3,4-dimethoxybenzonitrile |
-
1985
- 1985-09-26 JP JP60213294A patent/JPS6272640A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009126784A (en) * | 2007-11-19 | 2009-06-11 | Mitsubishi Gas Chem Co Inc | Method for producing 2-iodo-3,4-dimethoxybenzonitrile |
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