JPS6272609A - Bathing agent - Google Patents

Bathing agent

Info

Publication number
JPS6272609A
JPS6272609A JP60214074A JP21407485A JPS6272609A JP S6272609 A JPS6272609 A JP S6272609A JP 60214074 A JP60214074 A JP 60214074A JP 21407485 A JP21407485 A JP 21407485A JP S6272609 A JPS6272609 A JP S6272609A
Authority
JP
Japan
Prior art keywords
sheet
pullulan
water
bathing
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60214074A
Other languages
Japanese (ja)
Other versions
JPH0653657B2 (en
Inventor
Yuji Murakami
有司 村上
Fumiko Iwagami
岩上　史子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunstar Inc
Original Assignee
Sunstar Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunstar Inc filed Critical Sunstar Inc
Priority to JP60214074A priority Critical patent/JPH0653657B2/en
Publication of JPS6272609A publication Critical patent/JPS6272609A/en
Publication of JPH0653657B2 publication Critical patent/JPH0653657B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging

Abstract

PURPOSE:A water-soluble sheet bathing agent which comprises pullulan, etc., is rapidly and completely dissolved in warm water in a bathtub when added thereto, causes no bathing scum, etc., has skin wetting action, stabilizing effect on preservation of other component, preventing action on removal of perfume and raised bathing effect. CONSTITUTION:A water-soluble sheet which comprises a sheet of pullulan, a water-soluble high polymer substance well-known as a polysaccharide consisting of a neutral monosaccharide produced by Aureobasidum pullulans in the outside of mold, if necessary, polyvinyl alcohol and polyvinyl pyrrolidone to raise film-forming properties besides pullulan, further incorporated with at least one selected from a humectant, essence extracted from crude drug, perfume and colorant in the sheet and may be laminated in plural layers. EFFECT:Dispersing fragrance sufficiently during dissolution preventing bad impres sion of too strong fragrance before dissolution caused by conventional bathing agent.

Description

【発明の詳細な説明】 発明の分野 本発明は、浴槽の湯に添加して入浴の効用を高める浴用
剤に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to bath additives that are added to bath water to enhance the effectiveness of bathing.

発明の背景 浴用剤には種々の形態のらのが知られており、その１つ
に、１回分の浴用剤成分を水溶性高分子素材で包装し、
そのまま浴槽に入れて溶解させ、使用後の後始末の手間
を不要にする形態の浴用剤がある。このような浴用剤の
包装に用いる水溶性高分子素材としては、従来、ポリビ
ニルアルコール膜（特開昭５８−１８８８１３号）、ポ
リ酢酸ビニル部分酸化物、ポリビニルアルコール部分ブ
チレート、ビニルピロリドン−酢酸ビニル共重合体（特
開昭５０−１２６００８号）などが知られている。BACKGROUND OF THE INVENTION Various forms of bath additives are known.
There are bath additives that can be placed directly in the bathtub and dissolved, eliminating the need for cleaning up after use. Conventionally, water-soluble polymer materials used for packaging such bath additives include polyvinyl alcohol film (Japanese Patent Application Laid-Open No. 188813/1983), polyvinyl acetate partial oxide, polyvinyl alcohol partial butyrate, and vinylpyrrolidone-vinyl acetate film. Polymers (JP-A-50-126008) and the like are known.

しかしながら、これらの素材は４０℃前後の温湯におけ
る溶解速度が遅く、また、完全には溶けきらず、残留物
が浴槽周縁に付着して湯アカの原因になるなどの欠点が
ある。However, these materials have drawbacks such as a slow dissolution rate in hot water of around 40° C., and the fact that they do not dissolve completely, resulting in residues adhering to the periphery of the bathtub and causing hot water stains.

本発明者らは、このような欠点を解消するため、鋭意検
討を重ねた。そめ結果、プルランがこの目的に適した水
溶性高分子素材であり、そのシート状成型物がきわめて
すぐれた性能を発揮する浴用剤となることを見出し、本
発明を完成するにいたった。The present inventors have made extensive studies in order to eliminate such drawbacks. As a result, they discovered that pullulan is a water-soluble polymeric material suitable for this purpose, and that its sheet-like molded product can be used as a bath additive that exhibits extremely excellent performance, leading to the completion of the present invention.

発明の概要 本発明は、プルランあるいは、プルランとポリビニルア
ルコールおよび／またはポリビニルピロリドンからなる
水溶性シート状浴用剤を提供するものである。本発明の
浴用剤はこのシートそのものでもよく、また、このシー
トに、保湿剤、生薬抽出エキス、香料および着色料から
なる群から選ばれる少なくとも１種の成分を含有させた
ものでもよい。さらに、本発明の浴用剤には、これらの
非含有シート同士、含有シート同士あるいは非含有シー
トと含有シートを適宜複数枚積層したシート状浴用剤も
包含される。Summary of the Invention The present invention provides a water-soluble sheet bath agent comprising pullulan or pullulan and polyvinyl alcohol and/or polyvinylpyrrolidone. The bath preparation of the present invention may be this sheet itself, or may be one in which this sheet contains at least one component selected from the group consisting of a humectant, an extract of herbal medicine, a fragrance, and a coloring agent. Furthermore, the bath agent of the present invention also includes a sheet-like bath agent in which a plurality of non-containing sheets, two containing sheets, or a plurality of non-containing sheets and containing sheets are laminated as appropriate.

プルランは、オウレオバシジウム・プルランス（Ａｕｒ
ｅｏｂａｓｉｄｉｕｍ　ｐｕｌｌｕｌａｎｓ）が菌体外
に産生ずる中性単純糖からなる多糖類として知られる水
溶性高分子物質で、温湯に速やかに、完全に溶解し、湯
アカを生じるようなこともなく、それ自体、皮膚湿潤作
用、他成分の保存安定化、香料ヌケなどの防止作用を有
し、本発明によれば、シート状という新規な形態を有す
る、きわめてすぐれた性能を発揮する浴用剤が得られる
。Pullulan is derived from Aureobasidium pullulans (Aur
Eobasidium pullulans) is a water-soluble polymer substance known as a polysaccharide consisting of neutral simple sugars produced outside the bacterial body.It dissolves quickly and completely in hot water, does not cause hot water stains, and is itself According to the present invention, a bath agent having a novel sheet-like form and exhibiting extremely excellent performance can be obtained.

発明の詳細 な説明の浴用剤は、基本的に、プルランのシートからな
る。所望により、本発明においては、フィルム形成能を
高めるため、プルランと共にポリビニルアルコールおよ
びポリビニルピロリドンの一方または両方を併用しても
よい。ポリビニルアルコールおよびポリビニルピロリド
ンの量はプルラン１００重量部に対して最大５０重量部
までで、多くなりすぎると、溶解性の低下等を生じる。The bath preparation of the detailed description of the invention basically consists of a sheet of pullulan. If desired, in the present invention, one or both of polyvinyl alcohol and polyvinylpyrrolidone may be used together with pullulan in order to enhance the film-forming ability. The amount of polyvinyl alcohol and polyvinylpyrrolidone is up to 50 parts by weight per 100 parts by weight of pullulan, and if it is too large, the solubility will be lowered.

該シートには、保湿剤、生薬抽出エキス、香料および着
色料から選ばれる成分を単独で、あるいは２種以上併用
して含有させることができる。The sheet can contain a component selected from a humectant, a herbal medicine extract, a fragrance, and a coloring agent alone or in combination of two or more.

保湿剤の例としては、グリセリン、プロピレングリコー
ル、乳酸ナトリウム、ピロリドンカルボン酸ナトリウム
、ポリエチレングリコール、カルボキシメチルセルロー
ス、デキストリン、グアガム、クインスシードガム、カ
ラギーナン、アルギン酸、アラビノガラクタンガム、セ
リン、キトサン、マルチトール、ガラクトサミン、乳酸
菌培養物、尿素、アクアライザー（Ａｑｕａｌｉｚｅｒ
）Ｅ　Ｊ　、ペクチン、可溶性コラーゲン、エラスチン
、ヒアルロン酸ナトリウム、コンドロイチン硫酸、アス
パラギン酸などが挙げられ、単独でも、２種以上併用し
てもよい。保湿剤は、通常、プルラン１００重量部に対
して、１〜５０重量部重量部側合で用いられる。Examples of humectants include glycerin, propylene glycol, sodium lactate, sodium pyrrolidone carboxylate, polyethylene glycol, carboxymethyl cellulose, dextrin, guar gum, quince seed gum, carrageenan, alginic acid, arabinogalactan gum, serine, chitosan, maltitol, Galactosamine, lactic acid bacteria culture, urea, Aqualyzer
) E J , pectin, soluble collagen, elastin, sodium hyaluronate, chondroitin sulfate, aspartic acid, etc., and may be used alone or in combination of two or more. The humectant is usually used in an amount of 1 to 50 parts by weight per 100 parts by weight of pullulan.

生薬抽出エキスの例としては、ソウジュラ、ビヤクジュ
ツ、カノコソウ、カイガイ、コウボク、センキュウ、ト
ウヒ、トウキ、ジャスミン、ショウキョウ末、ニンジン
、ケイヒ、シャクヤク、ハツカ葉、オウゴン、サフラン
、ブクリヨウ、ドクヵツ、ショウブ、ガイヨウ、マツブ
サ、ビヤクシ、ジュウヤク、米ヌカ、サフラン、オウバ
ク、ウィキョウ、チンピ、カン皮末、いり糠、カミツレ
、桃の葉、ヨクイニン、ローズマリー、オトギリソウ、
エビスグサ、スイカズラ、ホップなどから常法によって
得られるエキスが拳げられ一蛍独で１゜２種以上併用し
てもよく、卵黄末なども用いてもよい。これらの生薬抽
出エキスは、通常、プルラン１００重量部に対して、０
．０１〜５０重量部程度の割合で用いられる。Examples of crude drug extracts include sourdough, birchium, valerian, snail, kobo, nebula, spruce, jasmine, jasmine, ginger powder, carrot, cinnamon bark, peony, scutellariae leaf, scutellariae, saffron, valerian, sardine cutlet, calamus, and staghorn. , Japanese bean sprouts, Japanese bean sprouts, Japanese apricots, rice bran, saffron, oak root, fennel, chimpi, kang bark powder, bran bran, chamomile, peach leaves, Japanese radish, rosemary, Hypericum perforatum,
Extracts obtained by conventional methods from Ebisu grass, honeysuckle, hops, etc. may be used in combination of 1 degree or more, and egg yolk powder may also be used. These herbal medicine extracts usually contain 0% per 100 parts by weight of pullulan.
．． It is used in a proportion of about 0.01 to 50 parts by weight.

香料の例としては、ｄＱ−メントール、Ｑ−メントール
、ハツカ油、ｄ−カンフル、ｄＱ−カンフル、テレピン
油、ヒノキ油、硅皮油、ケイヒ油、ベルガモツト油、菖
蒲油、パイン油、ラベンダー油、全層などが挙げられ、
単独でも、２種以上併用してもよい。香料は、通常、プ
ル９２１００重量部に対して、０．１〜２０重量部重量
部側合で用いられる。Examples of fragrances include dQ-menthol, Q-menthol, peppermint oil, d-camphor, dQ-camphor, turpentine oil, cypress oil, silica oil, cinnamon oil, bergamot oil, iris oil, pine oil, lavender oil, Examples include all layers,
They may be used alone or in combination of two or more. The fragrance is usually used in an amount of 0.1 to 20 parts by weight based on 100 parts by weight of PULL 92.

着色料の例としては、青色１号、青色２号、黄色４号、
黄色２０２号の（１）、緑色２０４号などが挙げられ、
単独でも、２種以上併用してもよい。Examples of colorants include Blue No. 1, Blue No. 2, Yellow No. 4,
Examples include yellow No. 202 (1), green No. 204, etc.
They may be used alone or in combination of two or more.

着色料は、通常、プルラン１００重量部に対して、０、
Ｏ１〜５重量部程度の割合で用いられる。The coloring agent is usually 0 to 100 parts by weight of pullulan.
O is used in a proportion of about 1 to 5 parts by weight.

本発明の浴用剤は、例えば、プルランと、池の必要な成
分の水溶液を適宜流延し、乾燥することにより製造でき
る。流延する水溶液は作業の容易さや、得られる浴用剤
の性状等から、固形分含量４０〜７０重量％程度が好ま
しく、乾燥は通常の方法で行うことができる。得られる
シートの厚さは特に限定するものではないが、取り扱い
やすさの点から、通常、５〜７０μ程度の厚さが好まし
い。The bath agent of the present invention can be produced, for example, by appropriately casting an aqueous solution of pullulan and the necessary components of the pond, and drying. The aqueous solution to be cast preferably has a solid content of about 40 to 70% by weight from the viewpoint of ease of operation and properties of the resulting bath additive, and drying can be carried out by a conventional method. The thickness of the obtained sheet is not particularly limited, but from the viewpoint of ease of handling, a thickness of about 5 to 70 μm is usually preferred.

得られたシートは適当な大きさに切断し、あるいは、打
抜等により適当な形状に成形することができる。また、
必要により、水で湿潤させたり、澱粉糊、ポリビニルア
ルコール糊などのような接着剤を用い、あるいは熱圧着
などにより、前記のごとく複数枚積層してもよい。さら
に、例えば、ミシン目などを入れて、使用時適宜の大き
さに切断しやすくしてもよい。本発明の浴用剤は小片に
切断し、さらに、公知の温泉成分等と混合してもよい。The obtained sheet can be cut into an appropriate size or formed into an appropriate shape by punching or the like. Also,
If necessary, a plurality of sheets may be laminated as described above by moistening with water, using an adhesive such as starch glue or polyvinyl alcohol glue, or by thermocompression bonding. Furthermore, for example, perforations or the like may be provided to facilitate cutting to an appropriate size during use. The bath agent of the present invention may be cut into small pieces and further mixed with known hot spring ingredients.

本発明の浴用剤は、使用に際して、浴槽の湯に添加する
と、速やかに、完全に溶け、湯アカなどを生じる問題は
ない。また、保存時の香料の発散をおさえ、溶解時に香
りを、充分に放散することができると共に、溶解前に「
呑りが強すぎる」というような、従来の浴用剤にともな
ういやな印象を与えることも防げる。When the bath agent of the present invention is added to hot water in a bathtub, it dissolves quickly and completely, and there is no problem of hot water stains. In addition, it is possible to suppress the release of fragrance during storage, and to sufficiently dissipate the fragrance during dissolution.
It also prevents the unpleasant impression associated with conventional bath additives, such as the feeling that the bath additives are too strong.

つぎに実施例を挙げて本発明をさらに詳しく説明する。Next, the present invention will be explained in more detail with reference to Examples.

実施例１ プルラン５０ｇを水１００ｍ（に加え、よく混合、溶解
する。得られた溶液に、桃の葉エキス５ｇ、ショウブエ
キス５ｇ、トウヒエキス５９、ハツカ油０．５ｇおよび
グリセリン１０９を加え、よく、昆合し、ポリエチレン
テレフタレート板上へ流延し、室温で乾燥し、約５０μ
の厚さを有するシートを得る。このシートを１５ｃｉＸ
　１０ｃ１Ｎの大きさに裁断し、長辺に沿って、５ＣＩ
間隔にミシン目を入れ、所望の浴用剤を得る。Example 1 Add 50 g of pullulan to 100 m of water, mix well, and dissolve. To the resulting solution, add 5 g of peach leaf extract, 5 g of calamus extract, 59 g of spruce extract, 0.5 g of mustard oil, and 109 g of glycerin, and mix well. , kneaded together, cast onto a polyethylene terephthalate plate, dried at room temperature, and about 50μ
A sheet having a thickness of . This sheet is 15ciX
Cut into 10c1N size, 5CI along the long side.
Make perforations at intervals to obtain the desired bath additive.

この浴用剤は、使用時、必要量をミシン目に沿って切り
取り、浴槽の湯に添加する。When using this bath additive, cut out the required amount along the perforations and add it to the hot water in the bathtub.

実施例２ 実施例１で得られたシートを約３　ｃｍ”の星型に裁断
し、その２０ｇを、黄色２０２の（＋）号０．０４ｇお
よびラベンダー油１．９６５Ｆと混合して浴用剤を得る
。Example 2 The sheet obtained in Example 1 was cut into a star shape of approximately 3 cm, and 20 g of it was mixed with 0.04 g of Yellow 202 (+) and 1.965 F of lavender oil to prepare a bath agent. obtain.

Claims (4)

【特許請求の範囲】[Claims] （１）プルランあるいは、プルランと、ポリビニルアル
コールおよび／またはポリビニルピロリドンからなる水
溶性シート状浴用剤。(1) A water-soluble sheet bath agent consisting of pullulan or pullulan, polyvinyl alcohol and/or polyvinylpyrrolidone. （２）シートに保湿剤、生薬抽出エキス、香料および着
色料からなる群から選ばれる少なくとも１種の成分を含
有させた前記第（１）項の浴用剤。(2) The bath agent according to item (1) above, wherein the sheet contains at least one component selected from the group consisting of a humectant, a herbal medicine extract, a fragrance, and a coloring agent. （３）複数層に積層してなる前記第（１）項の浴用剤。(3) The bath agent according to item (1) above, which is formed by laminating multiple layers. （４）少なくともその１層に、保湿剤、生薬抽出エキス
、香料および着色料からなる群から選ばれる少なくとも
１種の成分を含有させた前記第（３）項の浴用剤。(4) The bath agent according to item (3) above, wherein at least one layer thereof contains at least one component selected from the group consisting of a humectant, a herbal medicine extract, a fragrance, and a coloring agent.
JP60214074A 1985-09-26 1985-09-26 Bath agent Expired - Lifetime JPH0653657B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60214074A JPH0653657B2 (en) 1985-09-26 1985-09-26 Bath agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60214074A JPH0653657B2 (en) 1985-09-26 1985-09-26 Bath agent

Publications (2)

Publication Number Publication Date
JPS6272609A true JPS6272609A (en) 1987-04-03
JPH0653657B2 JPH0653657B2 (en) 1994-07-20

Family

ID=16649813

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60214074A Expired - Lifetime JPH0653657B2 (en) 1985-09-26 1985-09-26 Bath agent

Country Status (1)

Country Link
JP (1) JPH0653657B2 (en)

Cited By (42)

* Cited by examiner, † Cited by third party
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JPS63112510A (en) * 1986-10-27 1988-05-17 Tadao Shiraishi Sanitary product containing filmy component
JPH01313418A (en) * 1988-06-13 1989-12-18 Shin Etsu Chem Co Ltd Sheetlike bathing agent composition
JPH03197419A (en) * 1989-12-26 1991-08-28 Kao Corp Substance fractionated from peach leaf and bath liquid containing the same substance
JPH04112821A (en) * 1990-09-04 1992-04-14 Kao Corp Bathing agent composition
WO2000018365A2 (en) * 1998-09-25 2000-04-06 Warner-Lambert Company Fast dissolving orally consumable films
JP2003166000A (en) * 2001-11-23 2003-06-10 秀娟 ▲呂▼ Slice-like sanitary laundry item, manufacturing method therefor and its use
FR2880262A1 (en) * 2005-01-03 2006-07-07 Oreal COSMETIC OR DERMATOLOGICAL ARTICLE COMPRISING A WATER-SOLUBLE SUPPORT
WO2005070376A3 (en) * 2004-01-21 2008-01-03 Wella Ag Hair styling films and method for producing hair fixing products in film form
JP2011042605A (en) * 2009-08-20 2011-03-03 Tonichi Screen Process Kk Sheet-like bathing agent and process for producing the same
US8268764B2 (en) 2008-12-08 2012-09-18 The Procter & Gamble Company Porous, dissolvable solid substrate and surface resident starch perfume complexes
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US8425622B2 (en) 2011-05-27 2013-04-23 The Procter & Gamble Company Soluble solid hair coloring article
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US9295859B2 (en) 2009-12-08 2016-03-29 The Procter & Gamble Company Porous, dissolvable solid substrate and surface resident coating comprising matrix microspheres
US20180015643A1 (en) * 2001-10-09 2018-01-18 Arrow Greentech Limited Method Of Manufacturing Embedded Water Soluble Film Carrier
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JPH0512327B2 (en) * 1988-06-13 1993-02-17 Shinetsu Chem Ind Co
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