JPS62273907A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JPS62273907A JPS62273907A JP11613786A JP11613786A JPS62273907A JP S62273907 A JPS62273907 A JP S62273907A JP 11613786 A JP11613786 A JP 11613786A JP 11613786 A JP11613786 A JP 11613786A JP S62273907 A JPS62273907 A JP S62273907A
- Authority
- JP
- Japan
- Prior art keywords
- hydroxyapatite
- cosmetic
- pigment
- spherical
- human body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 16
- 239000000049 pigment Substances 0.000 claims abstract description 24
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 abstract description 21
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 abstract description 21
- 239000000843 powder Substances 0.000 abstract description 9
- 239000002245 particle Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 239000004606 Fillers/Extenders Substances 0.000 abstract description 4
- 239000000839 emulsion Substances 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 239000012463 white pigment Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 description 7
- 229940057995 liquid paraffin Drugs 0.000 description 7
- 239000003755 preservative agent Substances 0.000 description 7
- 239000004166 Lanolin Substances 0.000 description 5
- 229910052586 apatite Inorganic materials 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000013869 carnauba wax Nutrition 0.000 description 3
- -1 lipstick Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- BHIZVZJETFVJMJ-UHFFFAOYSA-N 2-hydroxypropyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(C)O BHIZVZJETFVJMJ-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- CMCJFUXWBBHIIL-UHFFFAOYSA-N Propylene glycol stearate Chemical compound CC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CMCJFUXWBBHIIL-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- CUSKZEYVILQFHM-UHFFFAOYSA-N [Bi].O=O Chemical compound [Bi].O=O CUSKZEYVILQFHM-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- FHRUGNCCGSEPPE-UHFFFAOYSA-L disodium;2-(4,5-dibromo-3,6-dioxido-9h-xanthen-9-yl)benzoate;hydron Chemical compound [H+].[Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1C2=CC=C([O-])C(Br)=C2OC2=C(Br)C([O-])=CC=C21 FHRUGNCCGSEPPE-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000010514 hydrogenated cottonseed oil Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- ZHALDANPYXAMJF-UHFFFAOYSA-N octadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCC[NH+](CCO)CCO.CCCCCCCCCCCCCCCCCC([O-])=O ZHALDANPYXAMJF-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229940029614 triethanolamine stearate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
Abstract
Description
【発明の詳細な説明】
3、発明の詳細な説明
産業上の利用
本発明は、ハイドロキシアパタイトを顔料として含有し
ている化粧品に関するものである。Detailed Description of the Invention 3. Detailed Description of the Invention Industrial Application The present invention relates to cosmetics containing hydroxyapatite as a pigment.
従来の技術 従来より白粉、口紅、その他の化粧品には。Conventional technology Traditionally used for white powder, lipstick, and other cosmetics.
種々の顔料、例えば、メルク、炭酸カルシウム、カオリ
ンなどの体質顔料、酸化亜鉛、酸化チタンなどの白色顔
料、酸化鉄、群青、クロム緑な箱
どの着出顔料、魚鱗餌、マイカ、雲母チタン。Various pigments, for example extender pigments such as Merck, calcium carbonate, kaolin, white pigments such as zinc oxide, titanium oxide, pigments such as iron oxide, ultramarine, chrome green box, fish scale bait, mica, titanium mica.
オキシ酸化ビスマスなどのパール顔料、及びステアリン
酸マグネシウム、パルミチン酸亜鉛などの金−属石ケン
、その他が使用されている。これらの中で白色顔料は最
も多く使用されており。Pearl pigments such as bismuth oxyoxide, metal soaps such as magnesium stearate, zinc palmitate, and others are used. Among these, white pigments are the most commonly used.
白色に着色する外、他の着色顔料と混合して色合を変え
、隠蔽力を太きくシ、被覆力を調整している。体質顔料
は着色顔料をうすめて、適当な濃さにして着色力を調整
し又感触を調整している。バール顔料は光沢を与え、金
属石ケンは皮膚への付着力の向上、油中への顔料分散を
よくするために使用されている。ハイドロキシアパタイ
トCa、、 (PO4)6(OH)、は歯骨など人体に
存在する無機質で、人体に悪影響を及ぼさないので、歯
磨研磨材、骨補修材として使用されている。然しなから
顔料として化粧品に使用することは試みられていない。In addition to being colored white, it is mixed with other colored pigments to change the hue, increase hiding power, and adjust covering power. Extender pigments are used to dilute coloring pigments to obtain an appropriate density, adjust coloring power, and adjust feel. Burl pigments are used to add luster, and metal soaps are used to improve adhesion to the skin and improve pigment dispersion in oil. Hydroxyapatite Ca, (PO4)6(OH) is an inorganic substance that exists in the human body, such as dental bones, and has no adverse effect on the human body, so it is used as a tooth polishing material and a bone repair material. However, no attempt has been made to use it as a pigment in cosmetics.
発明が解決しようとする問題点
最近化粧品による皮膚障害が問題となっているので本発
明は人体に存在し悪影響を及ぼさないハイドロキシアパ
タイトを従来化粧品に使用されている顔料の代りに使用
することにより、人体により安全な化粧品を提供するこ
とにある。Problems to be Solved by the Invention Recently, skin damage caused by cosmetics has become a problem, so the present invention solves the problem by using hydroxyapatite, which exists in the human body and does not have an adverse effect, in place of pigments conventionally used in cosmetics. Our goal is to provide cosmetics that are safer for the human body.
問題を解決するための手段
ハイドロキシアパタイトをゼットミル、ミクロンミル、
コロイドミルなどの超微粉砕機を用いて微粉とし篩分け
して一定範囲の大きさの粒子を採取するか、又はポリエ
ステル、ポリエチレン、ナイロン、ポリメチルメタアク
リレート。Means to solve the problem
Use an ultrafine grinder such as a colloid mill to make a fine powder and sieve it to collect particles with a certain size range, or polyester, polyethylene, nylon, polymethyl methacrylate.
その細球型にそろえられたポリマー球に、ノ・イドロキ
シアパタイト微粉末を、シリコンアクリルエマルジョン
、ウレタンアクリルエマルジョンなどの結合剤の存在下
約20″から80℃の温度大気圧下に混合し、次いで乾
燥させてポリマ球表面にハイドロキシアパタイト微粉末
を付着させた粒子C以下球状ハイドロ中シアパタイトと
記す)を篩分けして一定範囲の大きさの粒子を採取して
従来の白色顔料、体質顔料の代りに化粧品に使用する。Mix hydroxyapatite fine powder into the polymer spheres arranged in a fine spherical shape in the presence of a binder such as a silicone acrylic emulsion or a urethane acrylic emulsion at a temperature of about 20" to 80°C under atmospheric pressure, Next, the particles C (hereinafter referred to as spherical hydroxyapatite), which are dried and have fine hydroxyapatite powder adhered to the surface of the polymer spheres, are sieved to collect particles within a certain range of sizes to produce conventional white pigments and extender pigments. Use in cosmetics instead.
使用するハイドロキシアパタイト、球状ハイドロキシア
パタイトの粒子の大きさは小さければ小さい程、化粧品
の均質性を向上させるのは当然であるが、微粒子にすぎ
ると皮膚を通して体内にとり込まれる可能性があるので
、使用するそれらの粒子の大きさは。Naturally, the smaller the particle size of hydroxyapatite and spherical hydroxyapatite used, the better the homogeneity of cosmetics, but if the particles are too fine, they may be taken into the body through the skin, so The size of those particles is.
反射率、屈折率なども考慮に入れ3μ〜10μ程度であ
ることが望寸しい。Taking into account reflectance, refractive index, etc., it is desirable that the thickness be about 3 μ to 10 μ.
作用
このようにして得られたノ・イドロキシアノ(タイト、
又は球状)・イドロキシ7ノ(タイトは従来の顔料の場
合と同様に処理することによシ各種の化粧品を製造する
ことができる。Effect of the thus obtained hydroxyano (tight,
A variety of cosmetics can be produced by treating hydroxy 7 (or spherical) and idroxy 7 (tite) in the same manner as conventional pigments.
以下に本発明を具体的に実施例で説明する。The present invention will be specifically explained below with reference to Examples.
数字はいずれも重i%を示している。All numbers indicate weight i%.
例1
油性軟膏型ファンデーション
球状ハイドロキルアパタイト 30粉末ハイドロ
中ルアパタイト 10パルミチン酸イソプロピル
15ラノリンアルコール
5酢酸ラノリン 8マイクロク
リスタリンワツクス 7流動パラフイン
25キヤンデリラロウ
0.5防腐剤、酸化防止剤 適量香料
例2
?出仕スティック型ファンデーション
球状ハイドロギルアパタイト 30粉末ハイドロ
キルアパタイト 15流動パラフイン
18ミリスチン酸イソプロピル 1
5液状ラノリン 4.5マイク
ロクリスタリンワツクス 4・5セレシン
10カルナウバロウ
2セスキオレイン酸ソルビタン 1
酸化防止剤・防腐剤 適量香料
適量例3
乳液状ファンデーション
球状ハイドロキシアパタイト 12ステアリン酸
2.4モノステアリン酸プロ
ピレングリコールセトステアリルアルコール
0.2液状ラノリン 2流動
パラフイン 3ミリスチン酸イノ
プロピル 8.5ハラオキシ安息香酸プロピ
ル amカルボキシメチルセルロースナトリウム
0.2
ベントナイト 0・5プロ
ピレングリコール 4トリエタノールア
ミン 1.1パラオキシ安息香酸メチル
適量精製水 64
・1香料 適量例4
クリーム状ファウンデーション
球状ハイドロギルアパタイト16
ステアリン酸 5親油性モノス
テアリン酸グリセリン 2.5セトステアリルアルコ
ール 1モノステアリルアルコール
1モノラウリン酸プロピレングリコール 3流動バ
ラフ・rン 7ミリヌチン酸イソ
プロピル 8バラオキシ安息香酸ブチル
適量トリエタノール7′ミン 1.
2ゾルビツト 3ハラオキ
シ安息香酸メチル 適量精製水
53・3香料
適量例5
ケーキ型ファンデーション
球状ハイドロキシアパタイト 40粉末ハイドロ
キシアパタイト 4゜流動パラフィン
12セスキオレイン酸ノルビタン
4グリセリン 4
防腐剤 適量香料
適量例6
スティック型口紅
球状ハイドロギルアパタイト 2赤色202号
0.5赤色204号
2,5赤色227号Aル−キ
2.5橙色201号 0.2ヒマ
シ油 45.3ヘキサデシル
アルコール 25ミツロウ
9牛ヤンデリラロウ
7カルナウバロウ 2酸化防止剤
、防腐剤 適量香料
適量例7
固形はぼ紅
球状ハイドロキシアパタイト15
粉末ハイドロキシアパタイト 15タルク
40カオリン
20流動パラフイン
5コメデンプン 5香料
適量例8
ケーギ型アイライナー
球状ハイドロキシアパタイト 30粉末ハイドロ
キシアパタイト15
タルク 35流動パラフイ
ン 15ソルビタンセヌキオレエー
ト 5防腐剤 迫
を香料
例9
固形マスカラ
球状ハイドロキルアバタイk 18ステアリン
酸トリエタノールアミン 26バラフイニ/26
ミツロウ 17ラノリン
10カルナウバロウ
3防腐剤 適
量例10
スティック型アイシャドー
球状ハイドロキルアパタイト 8着色顔料
8セレシン
25硬化綿実油 16
ヒマシ油 33流動パラフ
イン 6キヤンデリラロウ
4防腐剤酸化防止剤 適量
例11
粉おしろい
球状ハイドロキルアパタイト45
粉末ハイドロキルアパタイト】5
メルク 40層色顔料
適量香料
適量発明の効果
このようにして得られた化粧品は、安全であることに加
えて、ノ・イドロ争シアパタイト自体の螢光色を帯びた
白色という性質により製品の色調をすき通るようなパー
ル状白色とし1人体との親和性が良いため皮膚につけた
ときの感触を良好に高め、なじみがよく、皮膚への密着
度があるのでのりの良い化粧となり、ハイドロキシアパ
タイトのみで、化粧品中の体質顔料、白色顔料、パール
顔料、金属石ケンの機能を兼ねることができる。このた
め製品の製作が容易であり1人体に対する副作用も削減
される。Example 1 Oil-based ointment-type foundation Spherical hydrokylapatite 30 Powder hydro luapatite 10 Isopropyl palmitate 15 Lanolin alcohol
5 Lanolin acetate 8 Microcrystalline wax 7 Liquid paraffin
25 Kyan Deli La Row
0.5 Preservatives, antioxidants Appropriate amount fragrance example 2? Deshi stick type foundation spherical hydrogyl apatite 30 powder hydrogyl apatite 15 liquid paraffin
18 Isopropyl myristate 1
5 Liquid lanolin 4.5 Microcrystalline wax 4.5 Ceresin
10 carnauba wax
2 Sorbitan sesquioleate 1
Antioxidants/preservatives Appropriate amount of fragrance
Appropriate amount example 3 Milky foundation spherical hydroxyapatite 12 stearic acid 2.4 monostearate propylene glycol cetostearyl alcohol
0.2 Liquid lanolin 2 Liquid paraffin 3 Inopropyl myristate 8.5 Propyl halooxybenzoate am Sodium carboxymethyl cellulose 0.2 Bentonite 0.5 Propylene glycol 4 Triethanolamine 1.1 Methyl p-oxybenzoate Appropriate amount of purified water 64
・1 Fragrance Appropriate Amount Example 4 Creamy Foundation Spherical Hydrogyl Apatite 16 Stearic Acid 5 Lipophilic Glyceryl Monostearate 2.5 Cetostearyl Alcohol 1 Monostearyl Alcohol
1 Propylene glycol monolaurate 3 Fluid balaf 7 Isopropyl myrinutate 8 Butyl oxybenzoate
Appropriate amount of triethanol 7'mine 1.
2 Sorbit 3 Methyl haloxybenzoate Appropriate amount of purified water
53.3 fragrance
Appropriate amount example 5 Cake-type foundation spherical hydroxyapatite 40 powder hydroxyapatite 4° liquid paraffin
12 Norbitane sesquioleate
4 Glycerin 4 Preservatives Appropriate amount of fragrance
Appropriate amount example 6 Stick type lipstick spherical hydrogyl apatite 2 Red No. 202 0.5 Red No. 204
2,5 Red No. 227 A Ruki
2.5 Orange No. 201 0.2 Castor oil 45.3 Hexadecyl alcohol 25 Beeswax
9 Cow Yanderirarou
7 Carnauba wax 2 Antioxidants, preservatives Appropriate amount of fragrance
Appropriate amount example 7 Solid pink spherical hydroxyapatite 15 Powdered hydroxyapatite 15 Talc
40 kaolin
20 liquid paraffin
5 rice starch 5 flavorings
Appropriate amount example 8 Keigi-shaped eyeliner spherical hydroxyapatite 30 Powdered hydroxyapatite 15 Talc 35 Liquid paraffin 15 Sorbitan senukioleate 5 Preservatives Perfume example 9 Solid mascara spherical hydroxyapatite K 18 Triethanolamine stearate 26 Varafini/26 Beeswax 17 lanolin
10 carnauba wax
3 Preservative Appropriate amount Example 10 Stick type eye shadow spherical hydrokyl apatite 8 Color pigment
8 Ceresin
25 Hydrogenated cottonseed oil 16
Castor oil 33 Liquid paraffin 6 Candelilla wax
4 Preservative Antioxidant Appropriate Amount Example 11 Powder Powder Spherical Hydrokylapatite 45 Powdered Hydrokylapatite] 5 Merck 40 layer color pigment
Appropriate amount of fragrance
Effects of the Invention The cosmetics obtained in this manner are not only safe, but also have a pearl-like appearance that penetrates through the color tone of the product due to the fluorescent white property of siapatite itself. It is white in color and has a good affinity with the human body, so it feels good when applied to the skin, blends well, and adheres well to the skin, making it a makeup that goes on well. It can also function as white pigment, pearl pigment, and metal soap. Therefore, the product is easy to manufacture and side effects on the human body are reduced.
Claims (1)
粧品。Cosmetics containing fine hydroxyapatite powder as a pigment.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11613786A JPS62273907A (en) | 1986-05-22 | 1986-05-22 | Cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11613786A JPS62273907A (en) | 1986-05-22 | 1986-05-22 | Cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62273907A true JPS62273907A (en) | 1987-11-28 |
JPH0427203B2 JPH0427203B2 (en) | 1992-05-11 |
Family
ID=14679646
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11613786A Granted JPS62273907A (en) | 1986-05-22 | 1986-05-22 | Cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62273907A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6327411A (en) * | 1986-07-22 | 1988-02-05 | Shiseido Co Ltd | Dust preparation for skin external use |
JPS6327414A (en) * | 1986-07-22 | 1988-02-05 | Shiseido Co Ltd | Skin drug for external use |
US6096324A (en) * | 1995-06-13 | 2000-08-01 | Laboratory Skin Care | Methods of delivering materials into the skin, and compositions used therein |
WO2000072808A1 (en) * | 1999-05-26 | 2000-12-07 | Color Access, Inc. | Cosmetic compositions containing fluorescent minerals |
US6579516B1 (en) | 1995-06-13 | 2003-06-17 | Zahra Mansouri | Methods of delivering materials into the skin, and compositions used therein |
JP2008184399A (en) * | 2007-01-29 | 2008-08-14 | Shiseido Co Ltd | Powdery cosmetic |
WO2016117640A1 (en) * | 2015-01-21 | 2016-07-28 | 株式会社 資生堂 | Makeup cosmetic |
JP2016138095A (en) * | 2015-01-21 | 2016-08-04 | 株式会社 資生堂 | Makeup cosmetic |
JP2021008416A (en) * | 2019-06-28 | 2021-01-28 | サンスター スイス エスエー | Composition for oral cavity |
US11759405B2 (en) | 2018-12-27 | 2023-09-19 | Sunstar Suisse Sa | Composition for oral cavity |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61129108A (en) * | 1984-11-26 | 1986-06-17 | Shiseido Co Ltd | Makeup cosmetic |
JPS6256415A (en) * | 1985-09-04 | 1987-03-12 | Shiseido Co Ltd | Cosmetic |
-
1986
- 1986-05-22 JP JP11613786A patent/JPS62273907A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61129108A (en) * | 1984-11-26 | 1986-06-17 | Shiseido Co Ltd | Makeup cosmetic |
JPS6256415A (en) * | 1985-09-04 | 1987-03-12 | Shiseido Co Ltd | Cosmetic |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6327414A (en) * | 1986-07-22 | 1988-02-05 | Shiseido Co Ltd | Skin drug for external use |
JPS6327411A (en) * | 1986-07-22 | 1988-02-05 | Shiseido Co Ltd | Dust preparation for skin external use |
US7655250B2 (en) | 1995-06-13 | 2010-02-02 | Laboratory Skin Care, Inc. | Topical formulations comprising ceramic hydroxyapatite particles |
US6096324A (en) * | 1995-06-13 | 2000-08-01 | Laboratory Skin Care | Methods of delivering materials into the skin, and compositions used therein |
US7771753B2 (en) | 1995-06-13 | 2010-08-10 | Laboratory Skin Care, Inc. | Topical formulations comprising ceramic hydroxyapatite particles |
US6579516B1 (en) | 1995-06-13 | 2003-06-17 | Zahra Mansouri | Methods of delivering materials into the skin, and compositions used therein |
JP2003500429A (en) * | 1999-05-26 | 2003-01-07 | カラー アクセス,インコーポレイティド | Cosmetic composition containing fluorescent mineral |
AU773680B2 (en) * | 1999-05-26 | 2004-06-03 | Color Access, Inc. | Cosmetic compositions containing fluorescent minerals |
US6753002B2 (en) | 1999-05-26 | 2004-06-22 | Color Access Inc. | Cosmetic compositions containing fluorescent minerals |
JP2005206613A (en) * | 1999-05-26 | 2005-08-04 | Color Access Inc | Cosmetic composition containing fluorescent mineral |
US6592882B2 (en) | 1999-05-26 | 2003-07-15 | Color Access, Inc. | Cosmetic compositions containing fluorescent minerals |
WO2000072808A1 (en) * | 1999-05-26 | 2000-12-07 | Color Access, Inc. | Cosmetic compositions containing fluorescent minerals |
JP2008184399A (en) * | 2007-01-29 | 2008-08-14 | Shiseido Co Ltd | Powdery cosmetic |
WO2016117640A1 (en) * | 2015-01-21 | 2016-07-28 | 株式会社 資生堂 | Makeup cosmetic |
JP2016138095A (en) * | 2015-01-21 | 2016-08-04 | 株式会社 資生堂 | Makeup cosmetic |
US11759405B2 (en) | 2018-12-27 | 2023-09-19 | Sunstar Suisse Sa | Composition for oral cavity |
JP2021008416A (en) * | 2019-06-28 | 2021-01-28 | サンスター スイス エスエー | Composition for oral cavity |
Also Published As
Publication number | Publication date |
---|---|
JPH0427203B2 (en) | 1992-05-11 |
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