JPS62258335A - Production of methyl isobutyl ketone - Google Patents
Production of methyl isobutyl ketoneInfo
- Publication number
- JPS62258335A JPS62258335A JP61101325A JP10132586A JPS62258335A JP S62258335 A JPS62258335 A JP S62258335A JP 61101325 A JP61101325 A JP 61101325A JP 10132586 A JP10132586 A JP 10132586A JP S62258335 A JPS62258335 A JP S62258335A
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- catalyst
- alumina
- hydrogen
- methyl isobutyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 title abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N Strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000292 calcium oxide Substances 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical class 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- -1 calcium oxide Chemical class 0.000 abstract 1
- YLUIKWVQCKSMCF-UHFFFAOYSA-N calcium;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[Mg+2].[Ca+2] YLUIKWVQCKSMCF-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To obtain the aimed compound in high yield by simple operation, by using a catalyst containing palladium supported on a carrier consisting of alumina and a specific metal oxide, e.g. calcium oxide, etc., in reacting acetone with hydrogen to produce the titled compound.
CONSTITUTION: Acetone is reacted with hydrogen in the presence of a catalyst prepared by supporting normally 0.01W5.0wt%, preferably 0.05W1.0wt% palladium on a carrier consisting of alumina and one or more metal oxides selected from calcium oxide, magnesium oxide and strontium oxide normally at 80W250°C, preferably 120W200°C under atmospheric pressure W 50atm, preferably 10W30atm pressure, preferably in the liquid phase to stably afford the aimed methyl isobutyl ketone useful as a raw material for organic solvents, coating materials, stabilizers, etc., in high yield for a long period using the above- mentioned readily preparable catalyst having high activity, selectivity and stability as well as long life.
COPYRIGHT: (C)1987,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61101325A JPH062702B2 (en) | 1986-04-30 | 1986-04-30 | Method for producing methyl isobutyl ketone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61101325A JPH062702B2 (en) | 1986-04-30 | 1986-04-30 | Method for producing methyl isobutyl ketone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62258335A true JPS62258335A (en) | 1987-11-10 |
| JPH062702B2 JPH062702B2 (en) | 1994-01-12 |
Family
ID=14297667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61101325A Expired - Lifetime JPH062702B2 (en) | 1986-04-30 | 1986-04-30 | Method for producing methyl isobutyl ketone |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH062702B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5149881A (en) * | 1990-05-21 | 1992-09-22 | Mitsubishi Kasei Corporation | Method for producing methyl isobutyl ketone |
| US6706928B2 (en) | 2000-05-18 | 2004-03-16 | Johnson Matthey Plc | Aldol condensation reaction and catalyst therefor |
| CN102190568A (en) * | 2010-03-19 | 2011-09-21 | 中国石油天然气股份有限公司 | Method for synthesizing methyl isobutyl ketone |
| CN107185566A (en) * | 2017-06-15 | 2017-09-22 | 中南大学 | A kind of catalyst of acetone hydrogenation liquid phase method synthesizing methyl isobutyl ketone and application |
-
1986
- 1986-04-30 JP JP61101325A patent/JPH062702B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5149881A (en) * | 1990-05-21 | 1992-09-22 | Mitsubishi Kasei Corporation | Method for producing methyl isobutyl ketone |
| US6706928B2 (en) | 2000-05-18 | 2004-03-16 | Johnson Matthey Plc | Aldol condensation reaction and catalyst therefor |
| CN102190568A (en) * | 2010-03-19 | 2011-09-21 | 中国石油天然气股份有限公司 | Method for synthesizing methyl isobutyl ketone |
| CN107185566A (en) * | 2017-06-15 | 2017-09-22 | 中南大学 | A kind of catalyst of acetone hydrogenation liquid phase method synthesizing methyl isobutyl ketone and application |
| CN107185566B (en) * | 2017-06-15 | 2020-01-07 | 中南大学 | Catalyst for synthesizing methyl isobutyl ketone by acetone hydrogenation liquid phase method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH062702B2 (en) | 1994-01-12 |
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