JPS62187035A - Manufacture of ceramic-coated lamianted board - Google Patents

Manufacture of ceramic-coated lamianted board

Info

Publication number
JPS62187035A
JPS62187035A JP61028695A JP2869586A JPS62187035A JP S62187035 A JPS62187035 A JP S62187035A JP 61028695 A JP61028695 A JP 61028695A JP 2869586 A JP2869586 A JP 2869586A JP S62187035 A JPS62187035 A JP S62187035A
Authority
JP
Japan
Prior art keywords
ceramic
copper foil
manufacturing
resin
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61028695A
Other languages
Japanese (ja)
Inventor
寛士 長谷川
光弘 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP61028695A priority Critical patent/JPS62187035A/en
Publication of JPS62187035A publication Critical patent/JPS62187035A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/02Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
    • H05K3/022Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/38Improvement of the adhesion between the insulating substrate and the metal

Landscapes

  • Laminated Bodies (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は熱伝導性、耐熱性にすぐrLるプリント配線板
用の積層板の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for manufacturing a laminate for printed wiring boards that has excellent thermal conductivity and heat resistance.

(従来の技術) 従来、プリント配線板としてはフェノール樹脂積層板、
エポキシ樹脂積層板が多く用いらrk。
(Conventional technology) Conventionally, phenolic resin laminates,
Epoxy resin laminates are often used.

できた。しかし、最近、電子機器の高性能化。did it. However, recently, electronic devices have become more sophisticated.

小型化に伴い、高密度実装化か望まfL、そjLによっ
て生ずる熱の高密度発生をいかに処理するかということ
が問題になってきた。
With miniaturization, it has become a problem how to deal with the high density generation of heat caused by high density packaging.

これに対し、従来の有機質系基板は熱伝導性が悪いため
熱放散性に欠ける。また耐熱性に乏しいなどのために高
密度実装化は困難であった。
In contrast, conventional organic substrates lack heat dissipation properties due to poor thermal conductivity. In addition, high-density packaging has been difficult due to poor heat resistance.

そのため、熱伝導性にすぐrした基鈑としてアルミナな
どのセラミック基板、あるいは金A4&を8拐としてそ
の表面t−ie縁被at−で覆ったメタルコア基板など
が注目さnている。また、耐熱性の点からも従来のフェ
ノール樹脂、エポキシ樹脂系基板に代わり、ポリイミド
樹脂あるいはポリエーテルエーテルケトン、ポリナル7
オンなどの耐熱性熱可塑性樹脂を用いた基板の開発も行
われている。
For this reason, ceramic substrates such as alumina, or metal core substrates made of A4 gold and covered with a T-IE edge coating, etc., are attracting attention as substrates with excellent thermal conductivity. In addition, from the viewpoint of heat resistance, polyimide resin, polyether ether ketone, Polynal 7
Substrates using heat-resistant thermoplastic resins such as ON are also being developed.

(発明が解決しようとする間踊点) しかし、こrしらの基板についてみると種々の問題点が
ある。すなわち、アルミナ、炭化ケイ素などのセラミッ
ク基板は熱伝導性、耐熱性にすぐnているか、製造工程
かa雑で、加工性が悪い、機械的強度が低い、基板の大
きさに制限があり、大型の基板が得らnないなどの欠点
かある。また、金属板を芯材としたメタルコア基鈑は回
路となる導体部と接しているのは熱伝導率の低い樹脂か
らなる絶縁層であるために金属芯の高熱伝導性を十分に
活かしきγ(ず、熱放散性は十分ではない。また芯材か
金属板であるのでスルーホールの形成が容易ではなく、
非常に権雑な製造工程を必要とする。
(Intermediate Points to be Solved by the Invention) However, when looking at these substrates, there are various problems. In other words, ceramic substrates made of alumina, silicon carbide, etc. have poor thermal conductivity and heat resistance, have a sloppy manufacturing process, have poor workability, have low mechanical strength, and are limited in substrate size. There are drawbacks such as the inability to obtain a large substrate. In addition, the metal core substrate with a metal plate as the core material has an insulating layer made of resin with low thermal conductivity that is in contact with the conductor part that forms the circuit, so the high thermal conductivity of the metal core can be fully utilized. (First, heat dissipation is not sufficient.Also, since it is a core material or a metal plate, it is not easy to form through holes.
It requires a very complicated manufacturing process.

さら忙耐熱性樹脂基板は耐熱性は向上しているものの、
樹脂の熱伝導率が低いために熱放散効果は望めない。
Although the heat resistance of heat-resistant resin substrates has improved,
Since the thermal conductivity of the resin is low, no heat dissipation effect can be expected.

本発明はこハらの欠点を改良し、従来の有機質系基板と
同様な製造、加工方法が可能で、しかも熱伝導性、耐熱
性にすぐrした基板を安価に得る製造法を提供するもの
である。
The present invention improves these drawbacks and provides a manufacturing method for producing a substrate that can be manufactured and processed in the same manner as conventional organic substrates and has excellent thermal conductivity and heat resistance at a low cost. It is.

(問題点を解決するための手段) すなわち本発明は、圧延鋼箔の片面に′電気絶縁性のセ
ラミックを両前」してセラミックRjを形成し、そのセ
ラミック層側にプリプレグ’!k IA/1して熱圧成
形して一体化し、鋼箔と有機質基板の間にセラミック層
を設けることを特徴とするものである。
(Means for Solving the Problems) That is, the present invention forms a ceramic Rj on one side of a rolled steel foil by coating an electrically insulating ceramic on both sides, and prepregs on the ceramic layer side! k IA/1 and heat-press molded to integrate, and a ceramic layer is provided between the steel foil and the organic substrate.

銅箔として圧延鋼箔を用いるのはコストとセラミック溶
射層との密層性のためである。一般にプリント配線板の
回路を形成する之めの銅26には圧延鋼箔と電解銅w3
かある。電専銅箔は、製造時にすて和片面は酸化、PA
面化さnており、さらに樹脂との密層性を向上させるた
めに電層により粗面化処理か施さnる。圧延銅箔は電解
鋼箔に比べるともともとは安価であるが樹脂との@層性
を向上させるためKは融化、粗開化処理か必要である。
The reason why rolled steel foil is used as the copper foil is because of the cost and the closeness of the ceramic sprayed layer. Generally, the copper 26 that forms the circuit of a printed wiring board is made of rolled steel foil and electrolytic copper w3.
There is. Densen copper foil is discarded during manufacturing, and one side is oxidized and PA
It is surface-roughened, and is further subjected to surface roughening treatment using an electric layer in order to improve the layering properties with the resin. Rolled copper foil is originally cheaper than electrolytic steel foil, but in order to improve layerability with resin, K needs to be melted or roughened.

本発明で用いるのは酸化、粗面化処理を行っていない生
の圧延鋼箔である。
The raw rolled steel foil used in the present invention is not subjected to oxidation or roughening treatment.

これは次の理由によるものである。本発明においては銅
箔表面にセラミックを溶射してセラミック#を設けるわ
けであるが、そのときの密着性は酸化処理さnた銅箔よ
ジ純粋な鋼箔の方が良好である。このことがら鋼箔とし
て生の圧延鋼箔を用いるのか密層性も良好でさらにコス
ト的にも有利である。なお、セラミックを溶射するに際
しては一般の溶射で行われるように密層力を高めるため
に銅箔の溶射面にプラスト処理が施される。
This is due to the following reason. In the present invention, a ceramic # is provided by thermal spraying a ceramic onto the surface of a copper foil, and the adhesion at this time is better with a pure steel foil than with an oxidized copper foil. For this reason, using raw rolled steel foil as the steel foil has good layer density and is also advantageous in terms of cost. When thermally spraying ceramic, the sprayed surface of the copper foil is subjected to a blast treatment in order to increase the layer strength, as is done in general thermal spraying.

セラミックとしてはセラミック基板として最も多く用い
らrしているアルミナが好適であるか。
Is alumina, which is the most commonly used ceramic substrate, suitable as a ceramic?

その他にスピネル、ムライト、ベリリア、炭化ケイ素、
窒化アルミニウムなどの高熱伝導性で電気絶縁性のセラ
ミックを用いることができる。
In addition, spinel, mullite, beryllia, silicon carbide,
A highly thermally conductive, electrically insulating ceramic such as aluminum nitride can be used.

ざらにプリプレグについて述べると、樹脂としては電気
特性、成形加工性の点からエポキシ樹脂、ポリイミド樹
脂が好適であるが、その個にフェノール樹脂、不飽和ポ
リエステル樹脂。
To briefly discuss prepregs, epoxy resins and polyimide resins are preferred from the standpoint of electrical properties and moldability, but phenolic resins and unsaturated polyester resins are also preferred.

メラミン4+1脂、ビニルエステル値(J指などの熱硬
化性樹脂、あるいはポリサル7オン、ポリチーチルエー
テルケトン、yj?IJエーテルサルフオン。
Melamine 4+1 fat, vinyl ester value (thermosetting resin such as J finger, or polysal 7one, polythiyl ether ketone, yj?IJ ethersulfon).

ポリエーテルイミドなどの熱可塑性樹脂を用いることが
できる。また繊維としては一般に用いらnるガラス繊維
の他に、ケプラー繊維1紙、SiCMtm、シリカ繊維
などを用いることができる。
Thermoplastic resins such as polyetherimide can be used. Further, as the fiber, in addition to the commonly used glass fiber, Kepler fiber paper, SiCMtm, silica fiber, etc. can be used.

セラミックのm刑法としてはプラズマ両射法、ガス溶射
法、水プラズマm側法などの各all浴法法適用できる
All bath methods such as plasma spraying, gas spraying, and water plasma m-side methods can be applied to ceramics.

さらにセラミック層を溶射した鋼箔は有機質基板の両面
に用いても1片面に用いてもさしつかえない。
Further, the steel foil sprayed with a ceramic layer may be used on both sides or one side of the organic substrate.

(作用) 本発明の方法により得らrLる積層板を工有機貴基板の
表面に熱伝導性の良好なセラミック層を有するために熱
放散性にすぐrLる。また、1gl路の形成は表面の鋼
箔にレジスト層を形成してエツチング処理を行うことに
より容易に形成することができ、スルーホールの形成も
便米の有慎質、4板と同様の方法で行うことかでさる。
(Function) The laminate obtained by the method of the present invention has excellent heat dissipation properties because it has a ceramic layer with good thermal conductivity on the surface of the noble substrate. In addition, the 1gl path can be easily formed by forming a resist layer on the surface steel foil and performing an etching process, and the through hole can also be formed using the same method as the 4th plate. It depends on what you do.

ざらに醸化処理していない銅箔にセラミックを溶射する
ために銅箔とセラミック層の@層性も良好である。’!
7t、 −ffに無機質であるセラミックと有機償であ
るプラスチックは親和性が乏しいため十分なりiaが得
らnないといわjしているが1本発明のようにセラミッ
クの浴刺ノーに1リプレグを載置して熱圧酸形すると、
両側#は粗面であり気孔も存在するために#j11.低
粘度化したiM!4脂がその間隙に浸透して接右面槓が
増大する。そのために十分な密着性力l得らrLる。ま
た、セラミック溶射層の気孔も樹脂により封孔さrLる
という長所もある。
Since ceramic is thermally sprayed onto copper foil that has not been subjected to rough fermentation treatment, the layering properties between the copper foil and the ceramic layer are also good. '!
It is said that it is not possible to obtain sufficient ia because of the poor affinity between ceramic, which is an inorganic substance, and plastic, which is an organic compound, for 7t, -ff. When placed in hot pressure acid form,
Both sides # are rough and have pores, so #j11. iM with lower viscosity! 4 fat permeates into the gap and increases the contact surface. For this purpose, sufficient adhesion force is obtained. Another advantage is that the pores in the ceramic sprayed layer can be sealed by the resin.

以下、実施例全挙げて本発明をさらに詳細に説明する。Hereinafter, the present invention will be explained in further detail with reference to all Examples.

(実20例) @1図(工銅箔へのセラミック溶射工程の模式図、第2
図をエセラミック#j創銅箔とプリプレグの積層#4成
図である。
(20 actual examples) @Figure 1 (Schematic diagram of ceramic spraying process on engineered copper foil, 2nd
The figure is a diagram of lamination #4 of Eceramic #j created copper foil and prepreg.

表面を酸化、粗面化処理していない圧延@箔(厚さ55
μ)の片rjfJをプラスト処理後、第1図に示す方法
によりプラズマ溶射法によってブラスト処理面にアルミ
ナを約100μの厚さに溶射して1片面にアルミナ層を
設けた銅箔を得た。
Rolled @ foil (thickness: 55 mm) without surface oxidation or roughening treatment
After the pieces rjfJ of μ) were blast-treated, alumina was sprayed on the blast-treated surface to a thickness of about 100 μm by plasma spraying according to the method shown in FIG. 1 to obtain a copper foil having an alumina layer on one side.

この鋼箔とカラスクロス/エポキシ位4月百含浸プリプ
レグ8を第2図の積/*構成に積み重ね。
This steel foil and crow cloth/epoxy impregnated prepreg 8 were stacked in the product/* configuration shown in Figure 2.

島田成形してa層at得た。Shimada molding was performed to obtain the a-layer at.

この積層板はカラス繊維基材エポキシ樹脂の表面にアル
ミナ層を有し−さらにその上に銅糸屑を有するものであ
り、鋼箔とセラミック間。
This laminate has an alumina layer on the surface of the glass fiber-based epoxy resin and further has copper thread scraps on top of it, and is between the steel foil and the ceramic.

およびセラミックとエポキシ樹ハ旨山】の密着性を1良
好であり、一般のガラス繊維基材エポキシ樹脂銅張積層
板と同様の方法でエツチングによる回路形成、スルーホ
ールの形成が可能であった。
The adhesion between the ceramic and the epoxy resin was excellent, and it was possible to form circuits and through-holes by etching in the same manner as general glass fiber-based epoxy resin copper-clad laminates.

また1回路に接して熱伝導性のよいアルミナ層があるた
め、熱放散性にすぐrL、  Lかも耐熱性もよく、さ
らに耐アーク性、耐トラツキング性も良好なものであっ
た。
In addition, since there was an alumina layer with good thermal conductivity in contact with one circuit, the heat dissipation properties were excellent, and the heat resistance was also good, and the arc resistance and tracking resistance were also good.

(発明の効果) 本発明によnば高熱伝導性、高耐熱性に優iL九積#板
を容易にしかも安価に製造することかできる。また本発
明によシ得らrLる積層板を工時性的にもすぐnたもの
で1回路形成、スルーホールの形成などの後加工も従来
の有機質基鈑と同様の方法で行うことができ、従来のセ
ラミック基板、メタルコア基板の問題点を解決し得るも
のである。
(Effects of the Invention) According to the present invention, it is possible to easily and inexpensively produce an iL nine-laminated #board with excellent high thermal conductivity and high heat resistance. In addition, the laminate obtained by the present invention is easy to manufacture, and post-processing such as forming one circuit and forming through holes can be performed in the same manner as with conventional organic substrates. This can solve the problems of conventional ceramic substrates and metal core substrates.

【図面の簡単な説明】[Brief explanation of drawings]

第1図ヲ:1本発明の実施例の銅箔へのアルミナ溶射の
模式図、第2□□□はアルミナ溶射鋼箔とプリプレグの
積層構成図である。 符号の説明 1  プラズマ溶射ガン 2 セラミック粉末供給口5
 プラズマ炎    4 セラミック#刺層5 圧延銅
箔     6 銅箔送りロール7 銅箔巻取りロール
 8 プリプレグ代理人弁理士 黄 瀬  章:、。 ゛“・\
Figure 1:1 is a schematic diagram of alumina spraying on copper foil according to an embodiment of the present invention, and Figure 2 is a laminated configuration diagram of alumina sprayed steel foil and prepreg. Explanation of symbols 1 Plasma spray gun 2 Ceramic powder supply port 5
Plasma flame 4 Ceramic #thin layer 5 Rolled copper foil 6 Copper foil feed roll 7 Copper foil winding roll 8 Prepreg representative patent attorney Akira Kise:.゛“・\

Claims (1)

【特許請求の範囲】 1、圧延銅箔の片面に電気絶縁性のセラミック溶射層を
形成し、該銅箔のセラミック溶射層側に所定数のプリプ
レグを積層熱圧成形することを特徴とする積層板の製造
方法。 2、セラミック溶射に用いるセラミックがアルミナを主
成分とするものである特許請求の範囲第1項記載の積層
板の製造方法。 3、プリプレグの樹脂がエポキシ樹脂またはポリイミド
樹脂である特許請求の範囲第1項記載の積層板の製造方
法。 4、プリプレグの繊維がガラス繊維である特許請求の範
囲第1項記載の積層板の製造方法。
[Claims] 1. A lamination characterized by forming an electrically insulating ceramic sprayed layer on one side of a rolled copper foil, and laminating and hot-pressing a predetermined number of prepregs on the ceramic sprayed layer side of the copper foil. Method of manufacturing the board. 2. The method for manufacturing a laminate according to claim 1, wherein the ceramic used for ceramic spraying has alumina as a main component. 3. The method for manufacturing a laminate according to claim 1, wherein the resin of the prepreg is an epoxy resin or a polyimide resin. 4. The method for manufacturing a laminate according to claim 1, wherein the fibers of the prepreg are glass fibers.
JP61028695A 1986-02-12 1986-02-12 Manufacture of ceramic-coated lamianted board Pending JPS62187035A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61028695A JPS62187035A (en) 1986-02-12 1986-02-12 Manufacture of ceramic-coated lamianted board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61028695A JPS62187035A (en) 1986-02-12 1986-02-12 Manufacture of ceramic-coated lamianted board

Publications (1)

Publication Number Publication Date
JPS62187035A true JPS62187035A (en) 1987-08-15

Family

ID=12255612

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61028695A Pending JPS62187035A (en) 1986-02-12 1986-02-12 Manufacture of ceramic-coated lamianted board

Country Status (1)

Country Link
JP (1) JPS62187035A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2713984A1 (en) * 1993-12-22 1995-06-23 Mtu Muenchen Gmbh Part in a fiber-reinforced composite material, comprising a layer of protection against erosion.
EP0681322A3 (en) * 1988-04-25 1998-01-21 Kabushiki Kaisha Toshiba Bonded ceramic metal composite substrates and circuit boards constructed therewith
WO1998007188A1 (en) * 1996-08-08 1998-02-19 Siemens Aktiengesellschaft Wafer frame

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0681322A3 (en) * 1988-04-25 1998-01-21 Kabushiki Kaisha Toshiba Bonded ceramic metal composite substrates and circuit boards constructed therewith
FR2713984A1 (en) * 1993-12-22 1995-06-23 Mtu Muenchen Gmbh Part in a fiber-reinforced composite material, comprising a layer of protection against erosion.
WO1998007188A1 (en) * 1996-08-08 1998-02-19 Siemens Aktiengesellschaft Wafer frame

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