JPS6193139A - Production of 3-allyloxypropionic acid - Google Patents
Production of 3-allyloxypropionic acidInfo
- Publication number
- JPS6193139A JPS6193139A JP59214002A JP21400284A JPS6193139A JP S6193139 A JPS6193139 A JP S6193139A JP 59214002 A JP59214002 A JP 59214002A JP 21400284 A JP21400284 A JP 21400284A JP S6193139 A JPS6193139 A JP S6193139A
- Authority
- JP
- Japan
- Prior art keywords
- allyloxypropionitrile
- lower alcohol
- water
- give
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- LBJZZFXUVYHXPH-UHFFFAOYSA-N 3-prop-2-enoxypropanoic acid Chemical compound OC(=O)CCOCC=C LBJZZFXUVYHXPH-UHFFFAOYSA-N 0.000 title 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 6
- IXXSWIVBWMKRHZ-UHFFFAOYSA-N 3-prop-2-enoxypropanenitrile Chemical compound C=CCOCCC#N IXXSWIVBWMKRHZ-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To obtain the titled compound useful as a plasticizer, solvent, etc. safely and advantageously in high yield, by reacting easily obtainable or producible 3-allyloxypropionitrile as a raw material with a lower alcohol in the presence of a catalyst and water.
CONSTITUTION: 3-Allyloxypropionitrile is used as a starting raw material, and reacted with a lower alcohol in the presence of a hydrogen chloride catalyst and water at 0W50°C preferably at 30W40°C, to give an alkylimidate hydrochloride. It is hydrolyzed especially at 40W50°C to give the aimed compound. An amount of the lower alcohol used in the reaction is 1.0W2.0 equivalents based on 3-allyloxypropionitrile, and an amount of water used is ≥0.1mol, preferably 0.2W1.6mol. Since a hydrochloric acid gas is used as the hydrogen chloride catalyst, the gas may be partially replaced with conc. hydrochloric acid.
COPYRIGHT: (C)1986,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59214002A JPS6193139A (en) | 1984-10-12 | 1984-10-12 | Production of 3-allyloxypropionic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59214002A JPS6193139A (en) | 1984-10-12 | 1984-10-12 | Production of 3-allyloxypropionic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6193139A true JPS6193139A (en) | 1986-05-12 |
Family
ID=16648632
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59214002A Pending JPS6193139A (en) | 1984-10-12 | 1984-10-12 | Production of 3-allyloxypropionic acid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6193139A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000031012A1 (en) * | 1998-11-20 | 2000-06-02 | Perstorp Ab | Process for production of an allyloxy carboxylic acid |
-
1984
- 1984-10-12 JP JP59214002A patent/JPS6193139A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000031012A1 (en) * | 1998-11-20 | 2000-06-02 | Perstorp Ab | Process for production of an allyloxy carboxylic acid |
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