JPS6144113B2 - - Google Patents
Info
- Publication number
- JPS6144113B2 JPS6144113B2 JP13456880A JP13456880A JPS6144113B2 JP S6144113 B2 JPS6144113 B2 JP S6144113B2 JP 13456880 A JP13456880 A JP 13456880A JP 13456880 A JP13456880 A JP 13456880A JP S6144113 B2 JPS6144113 B2 JP S6144113B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- weight
- component
- acid plasticizers
- components selected
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004014 plasticizer Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 239000003973 paint Substances 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- -1 ethylene glycol monoalkyl ethers Chemical class 0.000 claims description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 4
- 230000003449 preventive effect Effects 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 229910052742 iron Inorganic materials 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- GGSRTHRSSCWGGK-UHFFFAOYSA-L 2,2-dibutyl-5-hydroxy-1,3,2-dioxastannepane-4,7-dione Chemical compound CCCC[Sn]1(CCCC)OC(=O)CC(O)C(=O)O1 GGSRTHRSSCWGGK-UHFFFAOYSA-L 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- HCGFUIQPSOCUHI-UHFFFAOYSA-N 2-propan-2-yloxyethanol Chemical compound CC(C)OCCO HCGFUIQPSOCUHI-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229940031954 dibutyl sebacate Drugs 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
- 229940071145 lauroyl sarcosinate Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
Description
【発明の詳細な説明】
本発明は研磨鉄板、鋼製刃物類などの鉄製品表
面を一時的に保護するための表面保護用塗料に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a surface protection paint for temporarily protecting the surface of iron products such as polished iron plates and steel cutlery.
鉄板、刃物のような表面を一時的に保護するた
めの塗料としては、従来種々提案されているが、
これらは表面からの剥離不良の発生、発錆等の問
題を有している。 Various paints have been proposed to temporarily protect surfaces such as iron plates and cutlery.
These have problems such as poor peeling from the surface and rusting.
本発明は、このような欠点を改良してなるもの
で、(a)重合度250〜800のポリビニルブチラールを
主成分とする樹脂成分と(b)アルコール系溶剤およ
びエチレングリコールモノアルキルエーテルより
選ばれる１種もしくは２種以上の溶媒成分と、(c)
フタル酸系可塑剤および脂肪酸系可塑剤より選ば
れる１種もしくは２種以上の可塑剤成分と、(d)一
般式
（式中Ｒは炭素数10〜18のアルキル基を示す）
で示される防錆剤成分を含むことを特徴とする表
面保護用塗料に関するものである。 The present invention improves these drawbacks and consists of (a) a resin component whose main component is polyvinyl butyral with a degree of polymerization of 250 to 800, and (b) an alcohol solvent and an ethylene glycol monoalkyl ether. one or more solvent components, and (c)
one or more plasticizer components selected from phthalic acid plasticizers and fatty acid plasticizers, and (d) general formula (In the formula, R represents an alkyl group having 10 to 18 carbon atoms)
The present invention relates to a surface protection paint characterized by containing a rust preventive component represented by:
本発明において、用いるポリビニルブチラール
の重合度を250〜800と限定した理由は、250以下
では鉄製品表面への塗膜形成後、これを剥離する
とき連続的に剥離し難いためであり、一方800以
上では塗料粘度が高くなりすぎるためである。ま
た粘度を下げるため希釈して用いると、塗膜が薄
くなり連続塗膜として剥離し難いからである。 In the present invention, the reason why the degree of polymerization of the polyvinyl butyral used is limited to 250 to 800 is that if it is less than 250, it is difficult to peel off the coating film continuously after forming it on the surface of the iron product. This is because the viscosity of the paint becomes too high. In addition, if it is diluted to lower the viscosity, the coating film becomes thinner and difficult to peel off as a continuous coating film.
アルコール系溶剤としてはメチルアルコール、
エチルアルコール、プロピルアルコール、イソプ
ロピルアルコール、ブチルアルコール、アミルア
ルコールの如きＣ数６以下のアルコール、特に一
価アルコールが好適である。 As an alcohol solvent, methyl alcohol,
Alcohols having a carbon number of 6 or less, such as ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol, and amyl alcohol, particularly monohydric alcohols, are preferred.
エチレングリコールモノアルキルエーテルとし
てはアルキル基の炭素数４以下のメチルセロソル
ブ、エチルセロソルブ、ブチルセロソルブ、イソ
プロピルセロソルブ等を好適に使用できる。 As the ethylene glycol monoalkyl ether, methyl cellosolve, ethyl cellosolve, butyl cellosolve, isopropyl cellosolve, etc. in which the alkyl group has 4 or less carbon atoms can be suitably used.
フタル酸系可塑剤としてはジブチルフタレート
ジヘキシルフタレート、ジオクチルフタレート、
ジイソデシシルフタレート、ブチルベンジールフ
タレート、ジトリデシルフタレート等を挙げるこ
とができる。また、脂肪族系可塑剤としては、ジ
オクチルアジペート、ジオクチルセバケート、ジ
ブチルセバケート、トリアセチルグリセリン等を
挙げることができる。 Phthalic acid plasticizers include dibutyl phthalate, dihexyl phthalate, dioctyl phthalate,
Examples include diisodecyl phthalate, butylbenzyl phthalate, ditridecyl phthalate, and the like. Further, examples of the aliphatic plasticizer include dioctyl adipate, dioctyl sebacate, dibutyl sebacate, triacetylglycerin, and the like.
また前述の一般式で示される防錆剤としては、
オレオイルザルコシン、ラウロイルザルコシネー
トなどが挙げられる。 In addition, as a rust preventive agent represented by the above general formula,
Examples include oleoyl sarcosine and lauroyl sarcosinate.
また必要に応じてジブチルスズジラウレート、
ジオクチルスズジラウレート、ジブチルスズマレ
ート、ジブチルスズラウレートマレート、ジブチ
ルスズラウレートフタレート等の剥離剤を用いる
ことができる。 In addition, dibutyltin dilaurate, if necessary.
A release agent such as dioctyltin dilaurate, dibutyltin malate, dibutyltin laurate malate, dibutyltin laurate phthalate, etc. can be used.
本発明においては樹脂成分としてポリビニルア
ルコールが用いられるが、これの10重量％の範囲
で他の樹脂成分（自然乾燥しうる樹脂、たとえば
アルキツト樹脂、ニトロセルロース等）を用いる
こともできる。 In the present invention, polyvinyl alcohol is used as the resin component, but other resin components (resins that can be dried naturally, such as alkylene resin, nitrocellulose, etc.) can also be used within a range of 10% by weight.
本発明に於ける各成分の量的関係は以下の通り
である。 The quantitative relationship of each component in the present invention is as follows.
樹脂成分100重量部に対して可塑剤成分の量的
割合は、通常10〜50重量部好ましくは15〜30重量
部である。10重量部以下では可塑剤の使用効果に
劣り、50重量部以上使用すると塗膜に粘着性が出
てくるという欠点を有する。 The quantitative ratio of the plasticizer component to 100 parts by weight of the resin component is usually 10 to 50 parts by weight, preferably 15 to 30 parts by weight. If it is less than 10 parts by weight, the effect of using the plasticizer is poor, and if it is more than 50 parts by weight, it has the disadvantage that the coating film becomes sticky.
溶媒成分の使用割合は樹脂成分100重量部当り
通常20〜2000重量部である。 The proportion of the solvent component used is usually 20 to 2000 parts by weight per 100 parts by weight of the resin component.
この範囲を外れると鉄製品表面に剥離可能な良
好な塗膜を形成し難いからである。 This is because if it is outside this range, it will be difficult to form a good peelable coating on the surface of the iron product.
また、防錆剤成分の使用割合は樹脂成分100重
量部当り、通常0.1〜25重量部とされる。少なす
ぎると充分な防錆効果が得られなくなり、一方多
すぎるとブルーミング現象を呈し易くなり、鉄製
品表面を汚染する恐れがある。 The proportion of the rust preventive component used is usually 0.1 to 25 parts by weight per 100 parts by weight of the resin component. If it is too small, sufficient rust prevention effect cannot be obtained, while if it is too large, blooming phenomenon tends to occur and there is a risk of contaminating the surface of iron products.
本発明の塗料には、場合により塗膜表面の仕上
り外観をよくするためシリコーン系の添加剤を加
えることができる。 In some cases, silicone-based additives may be added to the coating material of the present invention in order to improve the finished appearance of the coating surface.
具体例としては、東芝シリコーン社製シリコー
ンオイル、商品名YF−3842、TSF−401、信越
シリコーン社製KP341、KP361等を挙げることが
でき、その添加量は樹脂成分100重量部当り通常
0.01〜1.0重量部である。 Specific examples include silicone oil manufactured by Toshiba Silicone Co., Ltd. under the trade name YF-3842, TSF-401, and KP341 and KP361 manufactured by Shin-Etsu Silicone Co., Ltd., and the amount added is usually in the range of 100 parts by weight of the resin component.
It is 0.01 to 1.0 parts by weight.
本発明により得られる塗料は上述した如きもの
であり、これを包丁、ノミ、ノコ、カンナ刃など
の刃物類或いは釘などの鉄製品の表面に塗工して
一時的保護用塗膜を形成したとき、表面に対する
汚染がなく、しかも必要なときに容易に剥離でき
るものであつた。 The paint obtained by the present invention is as described above, and can be applied to the surface of cutlery such as knives, chisels, saws, planer blades, or iron products such as nails to form a temporary protective coating. At the time, there was no contamination on the surface, and it could be easily peeled off when necessary.
なお、本発明において、得られる塗膜の剥離強
度は100g／cm2以下、好適には10〜50g／cm2で実用
上望ましいものである（東洋測器社製テンシロン
で30.0mm／min、室温にて行なつた測定値）。 In addition, in the present invention, the peel strength of the obtained coating film is 100 g/cm 2 or less, preferably 10 to 50 g/cm 2 , which is practically desirable (30.0 mm/min with Toyo Sokki Tensilon, room temperature) (Measurements taken at
以下本発明を実施例により具体的に説明する。 The present invention will be specifically explained below using examples.
なお、実施例中の部は重量部である。 Note that parts in the examples are parts by weight.
実施例 １
ポリビニルブチラール 100部
ジブチルフタレート 25部
エタノール 350部
オレオイルザルコシン ５部
上記各成分を室温にて均一になるまで撹拌し表
面保護用塗料とした。Example 1 Polyvinyl butyral 100 parts Dibutyl phthalate 25 parts Ethanol 350 parts Oleoyl sarcosine 5 parts The above components were stirred at room temperature until uniform, to prepare a surface protection paint.
得られた塗料を研磨した鉄板表面に塗工し20℃
にて乾燥し、塗膜を形成させた。 The resulting paint was applied to the polished iron plate surface and heated to 20°C.
It was dried to form a coating film.
このものを５％食塩水に24時間浸漬後、３ケ月
間保存し、塗膜の接着力（剥離強度）、抗張力お
よび伸びを東洋測器社製テンシロンで測定（25
℃、300mm／min）したところ、各々21g／cm2、
170Kg／cm2、120％であり容易に剥離が可能であつ
た。 This material was immersed in 5% saline for 24 hours, stored for 3 months, and the adhesion (peel strength), tensile strength, and elongation of the coating film were measured using a Tensilon manufactured by Toyo Sokki Co., Ltd. (25
℃, 300mm/min), 21g/cm 2 ,
It was 170Kg/cm 2 and 120%, and could be easily peeled off.
また鉄板表面も塗工前の光沢を失なつておら
ず、発錆は認められなかつた。 Furthermore, the surface of the iron plate had not lost its luster before coating, and no rust was observed.
なお、塗膜形成直後の塗膜の接着力、抗張力、
伸びは各々20g／cm2、160Kg／cm2、140％であつた
（測定条件は前述に同じ）。 In addition, the adhesion strength, tensile strength,
The elongations were 20 g/cm 2 , 160 Kg/cm 2 , and 140%, respectively (the measurement conditions were the same as above).
Claims (1)
主成分とする樹脂成分と(b)アルコール系溶剤およ
びエチレングリコールモノアルキルエーテルより
選ばれる一種もしくは２種以上の溶媒成分と、(c)
フタル酸系可塑剤および脂肪酸系可塑剤より選ば
れる１種もしくは２種以上の可塑剤成分と、(d)一
般式 （式中Ｒは炭素数10〜18のアルキル基を示す）
で示される防錆剤成分を含むことを特徴とする表
面保護用塗料。[Scope of Claims] 1. (a) a resin component whose main component is polyvinyl butyral with a degree of polymerization of 250 to 800, and (b) one or more solvent components selected from alcoholic solvents and ethylene glycol monoalkyl ethers. ,(c)
one or more plasticizer components selected from phthalic acid plasticizers and fatty acid plasticizers, and (d) general formula (In the formula, R represents an alkyl group having 10 to 18 carbon atoms)
A surface protection paint characterized by containing a rust preventive component represented by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13456880A JPS5759961A (en) | 1980-09-26 | 1980-09-26 | Surface protecting paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13456880A JPS5759961A (en) | 1980-09-26 | 1980-09-26 | Surface protecting paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5759961A JPS5759961A (en) | 1982-04-10 |
| JPS6144113B2 true JPS6144113B2 (en) | 1986-10-01 |
Family
ID=15131375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13456880A Granted JPS5759961A (en) | 1980-09-26 | 1980-09-26 | Surface protecting paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5759961A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4623392A (en) * | 1982-10-25 | 1986-11-18 | Minnesota Mining And Manufacturing Company | Printing ink |
| JPS60192773A (en) * | 1984-03-14 | 1985-10-01 | Rinrei:Kk | Strippable protective coating composition |
| US7012746B2 (en) * | 2002-05-20 | 2006-03-14 | Eastman Kodak Company | Polyvinyl butyral films prepared by coating methods |
| WO2013137147A1 (en) * | 2012-03-16 | 2013-09-19 | 株式会社スリーボンド | Coating composition |
-
1980
- 1980-09-26 JP JP13456880A patent/JPS5759961A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5759961A (en) | 1982-04-10 |
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