JPS6126822B2 - - Google Patents
Info
- Publication number
- JPS6126822B2 JPS6126822B2 JP13072578A JP13072578A JPS6126822B2 JP S6126822 B2 JPS6126822 B2 JP S6126822B2 JP 13072578 A JP13072578 A JP 13072578A JP 13072578 A JP13072578 A JP 13072578A JP S6126822 B2 JPS6126822 B2 JP S6126822B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- fiber treatment
- fluorescent whitening
- acid
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000003093 cationic surfactant Substances 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 4
- 239000001630 malic acid Substances 0.000 claims description 4
- 235000011090 malic acid Nutrition 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- 239000004744 fabric Substances 0.000 description 16
- 230000002087 whitening effect Effects 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 6
- -1 amine salt Chemical class 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical group [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- ZILZQZGAJNDJIY-UHFFFAOYSA-N 2-chloro-5-[2-[4-[4-[2-(4-chloro-3-sulfophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonic acid Chemical group C1=C(Cl)C(S(=O)(=O)O)=CC(C=CC=2C=CC(=CC=2)C=2C=CC(C=CC=3C=C(C(Cl)=CC=3)S(O)(=O)=O)=CC=2)=C1 ZILZQZGAJNDJIY-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Description
本発明はけい光増白性の優れた繊維処理剤組成
物に関する。
従来の繊維処理剤には柔軟性付与成分としてカ
チオン界面活性剤が配合されている。このような
繊維処理剤にアニオン性けい光増白剤を配合する
と、カチオン界面活性剤と複合体を形成してその
けい光増白作用が低下し、十分なけい光増白効果
が達成できないという欠点があつた。
本発明はこの従来の繊維処理剤の欠点を克服す
るため鋭意研究を重ねた結果、低級脂肪族多価カ
ルボン酸又はその塩を所定量配合することによつ
てその目的を満足できることを見出し、本発明を
なすに至つた。
すなわち、本発明は、アニオン性けい光増白剤
0.01〜１重量％と、カチオン界面活性剤0.1〜10
重量％と、コハク酸、クエン酸、リンゴ酸及びそ
れらの塩の中から選ばれた少なくとも１種の多価
カルボン酸成分0.5〜10重量％とを含有してなる
繊維処理剤組成物を提供するものである。
本発明において用いられるアニオン性けい光増
白剤としては、次の(イ)又は(ロ)の化合物の中から選
ばれた少なくとも１種があげられる。
(イ) ４，4′―ビス―（２―スルホスチリル）―ビ
フエニル
（式中のＭは水素原子、アンモニウム基、アル
カリ金属、アルカリ土類金属又はアミン塩を示
す）
(ロ) ４，4′―ビス―（４―クロロ―３―スルホス
チリル）―ビフエニル
（式中のＭは上記と同じ意味をもつ）
このアニオン性けい光増白剤の配合量は、通常
0.01〜１重量％であり、好ましくは0.05〜0.5重量
％の範囲である。
本発明において用いられるカチオン界面活性剤
としては次の一般式（）及び（）で表わされ
る化合物の中から選ばれた少なくとも１種をあげ
ることができる。
（式中のR1は炭素原子数12〜26のアルキル基、R2
は炭素原子数１〜26のアルキル基、R3は炭素原
子数１〜５のアルキル基、R4は炭素原子数１〜
５のアルキル基又はベンジル基であり、Ｘはハロ
ゲンイオン、CH3SO4 -、C2H5SO4 -又は
The present invention relates to a fiber treatment composition having excellent fluorescent whitening properties. Conventional fiber treatment agents contain cationic surfactants as flexibility imparting ingredients. When an anionic fluorescent whitening agent is added to such a fiber treatment agent, it forms a complex with a cationic surfactant, reducing its fluorescent whitening effect and making it impossible to achieve a sufficient fluorescent whitening effect. There were flaws. The present invention has been made as a result of extensive research to overcome the drawbacks of conventional fiber treatment agents, and it has been discovered that the objective can be satisfied by blending a predetermined amount of lower aliphatic polycarboxylic acids or salts thereof. He came up with an invention. That is, the present invention provides anionic fluorescent brightener
0.01-1% by weight and cationic surfactant 0.1-10
% by weight, and 0.5 to 10% by weight of at least one polyhydric carboxylic acid component selected from succinic acid, citric acid, malic acid, and salts thereof. It is something. The anionic fluorescent brightener used in the present invention includes at least one compound selected from the following compounds (a) and (b). (a) 4,4'-bis-(2-sulfostyryl)-biphenyl (M in the formula represents a hydrogen atom, an ammonium group, an alkali metal, an alkaline earth metal, or an amine salt) (b) 4,4'-bis-(4-chloro-3-sulfostyryl)-biphenyl (M in the formula has the same meaning as above) The amount of this anionic fluorescent brightener is usually
It is in the range of 0.01 to 1% by weight, preferably 0.05 to 0.5% by weight. As the cationic surfactant used in the present invention, at least one kind selected from compounds represented by the following general formulas () and () can be mentioned. (R 1 in the formula is an alkyl group having 12 to 26 carbon atoms, R 2
is an alkyl group having 1 to 26 carbon atoms, R 3 is an alkyl group having 1 to 5 carbon atoms, and R 4 is an alkyl group having 1 to 5 carbon atoms.
5 is an alkyl group or benzyl group, and X is a halogen ion, CH 3 SO 4 - , C 2 H 5 SO 4 - or
【式】を示す。）
（式中のR1，R3及びＸは上記と同じ意味をもち、
ｍ及びｎは１〜20、ｍとｎの和は２〜50である）
このカチオン界面活性剤は通常0.1〜10重量
％、好ましくは0.3〜８重量％の範囲で用いられ
る。
また、多価カルボン酸成分としては、コハク
酸、クエン酸、リンゴ酸又はそれらの塩例えばア
ルカリ金属塩が用いられる。そしてこれらは、単
独で又は２種以上の混合物として用いられる。そ
の使用量は0.5〜10重量％の範囲が適当であり、
１〜６重量％の範囲が好ましい。
本発明の繊維処理剤組成物にはその他の通常の
処理剤に用いられている添加剤を用いることもで
きる。そのような添加剤としては、ソルビタン脂
肪酸エステル、ポリオキシエチレンアルキル（ア
ルケニル）エーテル、セチルアルコール、エチレ
ングリコール、プロピレングリコール、グリセリ
ン、塩化ナトリウム、臭化ナトリウム、硫酸ナト
リウム、香料、色素などをあげることができる。
また、本発明の組成物において、非イオン界面
活性剤、両性界面活性剤などを添加すれば、洗浄
性をも備えた組成物とすることができる。この際
の添加剤の例としては、炭素原子数７〜18の第一
級又は第二級アルコールのポリオキシエチレンエ
ーテル（EO＝５〜20）、ベタイン、スルホベタ
インなどがあり、さらに分子量100〜10000のポリ
オキシエチレン（プロピレン）エーテル、エタノ
ール、イソプロパノール、無機電解質、香料、色
素などがあげられる。
本発明の繊維処理剤組成物においては、アニオ
ン性けい光増白剤は柔軟剤としてのカチオン界面
活性剤を併用しても優れたけい光増白作用を示
す。特に合成繊維（例えばナイロン布）に対して
けい光増白作用が大きい。したがつて、この組成
物は柔軟性付与効果も優れる。また、本発明の組
成物において、洗浄性を有する成分を含有させれ
ば、洗浄性を兼ね備えた繊維処理剤組成物を得る
ことができる。
次に本発明を実施例に基づき、さらに詳細に説
明する。
実施例 １
下記の表に示す組成の繊維処理剤を調製した。
次いでこの処理剤組成物を濃度0.1重量％とし、
浴比30倍、温度25℃、処理時間５分間の条件で布
の処理を行いけい光増白性を試験した。その結果
を下記の表に示した。
なおけい光増白剤は次のようにして測つた。
(イ) けい光強度による方法
エルレフオ（Elrepho）を用い、キセノン光
源で、フイルター11によつて測定した。紫外線
カツトフイルターを入れた場合の反射率と入れ
ない場合の反射率を測定し、次式に従いけい光
強度を求め、その値を10倍して表示した。
けい光強度（Zf）＝（フイルターなしの反射率
―フイルター入りの反射率）×1.008
(ロ) 目視法
試料布及びブランク布の織目と厚さを同じに
して黒色の台紙上に並べ北側の開放窓りの散光
を45〜60゜の角度で当て、布に対して垂直方向
より目で見て白度を評価する。５名の判定者に
より、次の基準により評価し、その合計点で表
示した。
判定基準
試料布がブランク布より明らかに白度が大きい
：＋２
試料布がブランク布よりやや白度が大きい
＋１
試料布がブランク布と白度が同等である
：０
試料布がブランク布よりやや白度が小さい
：−１
試料布がブランク布より明らかに白度が小さい
：−２[Formula] is shown. ) (R 1 , R 3 and X in the formula have the same meanings as above,
(m and n are 1 to 20, and the sum of m and n is 2 to 50.) This cationic surfactant is usually used in an amount of 0.1 to 10% by weight, preferably 0.3 to 8% by weight. Further, as the polyvalent carboxylic acid component, succinic acid, citric acid, malic acid, or salts thereof, such as alkali metal salts, are used. These may be used alone or as a mixture of two or more. The appropriate amount to use is in the range of 0.5 to 10% by weight.
A range of 1 to 6% by weight is preferred. The fiber treatment agent composition of the present invention may also contain other additives used in conventional treatment agents. Such additives may include sorbitan fatty acid esters, polyoxyethylene alkyl (alkenyl) ethers, cetyl alcohol, ethylene glycol, propylene glycol, glycerin, sodium chloride, sodium bromide, sodium sulfate, fragrances, dyes, etc. can. Furthermore, by adding a nonionic surfactant, an amphoteric surfactant, etc. to the composition of the present invention, the composition can also have cleaning properties. Examples of additives in this case include polyoxyethylene ether (EO = 5 to 20) of primary or secondary alcohols having 7 to 18 carbon atoms, betaine, sulfobetaine, etc., and molecular weights of 100 to 18. These include 10,000 polyoxyethylene (propylene) ethers, ethanol, isopropanol, inorganic electrolytes, fragrances, and dyes. In the fiber treatment composition of the present invention, the anionic fluorescent whitening agent exhibits an excellent fluorescent whitening effect even when used in combination with a cationic surfactant as a softener. In particular, it has a strong fluorescent whitening effect on synthetic fibers (for example, nylon cloth). Therefore, this composition also has an excellent flexibility imparting effect. Furthermore, if the composition of the present invention contains a component having detergency, a fiber treatment composition having detergency can be obtained. Next, the present invention will be explained in more detail based on examples. Example 1 A fiber treatment agent having the composition shown in the table below was prepared.
Next, this treatment agent composition was made to have a concentration of 0.1% by weight,
The fabric was treated under the conditions of a bath ratio of 30 times, a temperature of 25° C., and a treatment time of 5 minutes, and the fluorescent whitening property was tested. The results are shown in the table below. Incidentally, the fluorescent whitening agent was measured as follows. (a) Method using fluorescence intensity Measurement was carried out using Elrepho with a xenon light source and filter 11. The reflectance with and without an ultraviolet cut filter was measured, and the fluorescence intensity was determined according to the following formula, and the value was multiplied by 10 and displayed. Fluorescence intensity (Zf) = (Reflectance without filter - Reflectance with filter) x 1.008 (b) Visual method Arrange the sample fabric and blank fabric on a black mount with the same weave and thickness, and place them on the north side. Apply diffused light from an open window at an angle of 45 to 60 degrees, and visually evaluate the whiteness of the fabric from a direction perpendicular to it. Evaluations were made by five judges based on the following criteria, and the total score was displayed. Judgment Criteria The sample cloth is clearly whiter than the blank cloth: +2 The sample cloth is slightly whiter than the blank cloth +1 The sample cloth has the same whiteness as the blank cloth: 0 The sample cloth is slightly whiter than the blank cloth Whiteness is low: -1 Sample cloth has clearly lower whiteness than blank cloth: -2
【表】【table】
【表】
この表の結果よりわかるように低級脂肪族多価
カルボン酸又はその塩を所定量含んでいる繊維処
理剤は増白性が優れている（実験番号１〜12）。
一方、多価カルボン酸の含有量が0.5重量％未満
か又は全く含んでいない場合はけい光増白性が悪
い（実験番号13〜22）。
実施例 ２
下記配合組成物の洗浄性をも備えた繊維処理剤
を調製し、実施例１と同様の方法でナイロン布に
対するけい光増白剤を試験したところ、いずれも
優れた効果を示した。
配合例 １
（成 分） （重量％）
Ｃ11〜15アルコールエトキシレート 20
（EO＝14）
ジステアリルジチルアンモニウムクロリド
0.5
４，4′―ビス（２―スルホスチリル）―ビフエニ
ル 0.2
リンゴ酸 ４
水 残部
配合例 ２
（成 分） （重量％）
ソフタノール120 25
（商品名、日本触媒社製）
ジステアリルジメチルアンモニウムクロリド
0.6
４，4′―ビス（２―スルホスチリル）―ビフエニ
ル 0.2
クエン酸 ５
水 残部[Table] As can be seen from the results in this table, fiber treatment agents containing a predetermined amount of a lower aliphatic polycarboxylic acid or its salt have excellent whitening properties (Experiment Nos. 1 to 12).
On the other hand, when the content of polyhydric carboxylic acid is less than 0.5% by weight or is not contained at all, the fluorescent whitening property is poor (Experiment Nos. 13 to 22). Example 2 A fiber treatment agent with cleaning properties was prepared using the following compounded composition, and when the fluorescent brightener was tested on nylon cloth in the same manner as in Example 1, all showed excellent effects. . Formulation example 1 (Ingredients) (Weight %) C 11-15 alcohol ethoxylate 20 (EO=14) Distearylditylammonium chloride
0.5 4,4'-bis(2-sulfostyryl)-biphenyl 0.2 Malic acid 4 Water Balance Example 2 (Ingredients) (% by weight) Softanol 120 25 (Product name, manufactured by Nippon Shokubai Co., Ltd.) Distearyldimethylammonium chloride
0.6 4,4'-bis(2-sulfostyryl)-biphenyl 0.2 Citric acid 5 Water Balance
Claims (1)
カチオン界面活性剤0.1〜10重量％と、コハク
酸、クエン酸、リンゴ酸及びそれらの塩の中から
選ばれた少なくとも１種の多価カルボン酸成分
0.5〜10重量％とを含有してなる繊維処理剤組成
物。1 0.01 to 1% by weight of an anionic fluorescent whitening agent,
0.1 to 10% by weight of a cationic surfactant and at least one polyhydric carboxylic acid component selected from succinic acid, citric acid, malic acid and their salts.
A fiber treatment agent composition containing 0.5 to 10% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13072578A JPS5558257A (en) | 1978-10-24 | 1978-10-24 | Textile finish composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13072578A JPS5558257A (en) | 1978-10-24 | 1978-10-24 | Textile finish composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5558257A JPS5558257A (en) | 1980-04-30 |
| JPS6126822B2 true JPS6126822B2 (en) | 1986-06-23 |
Family
ID=15041129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13072578A Granted JPS5558257A (en) | 1978-10-24 | 1978-10-24 | Textile finish composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5558257A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4460485A (en) * | 1983-07-15 | 1984-07-17 | Lever Brothers Company | Polyester fabric conditioning and whitening composition |
| US4769159A (en) * | 1986-02-18 | 1988-09-06 | Ecolab Inc. | Institutional softener containing cationic surfactant and organic acid |
| JP2565311B2 (en) * | 1986-09-12 | 1996-12-18 | ライオン株式会社 | Softener composition |
-
1978
- 1978-10-24 JP JP13072578A patent/JPS5558257A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5558257A (en) | 1980-04-30 |
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