JPS61204277A - Labeling of liquid composition and hydrophobic material - Google Patents
Labeling of liquid composition and hydrophobic materialInfo
- Publication number
- JPS61204277A JPS61204277A JP60043588A JP4358885A JPS61204277A JP S61204277 A JPS61204277 A JP S61204277A JP 60043588 A JP60043588 A JP 60043588A JP 4358885 A JP4358885 A JP 4358885A JP S61204277 A JPS61204277 A JP S61204277A
- Authority
- JP
- Japan
- Prior art keywords
- water
- starch
- soluble
- fluorescent dye
- labeling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は液状組成物及びその用途に関する。更に詳しく
は水溶性螢光染料他を含有する液状組成物及びこれを用
いる疎水性材料の標識付与法に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to liquid compositions and their uses. More specifically, the present invention relates to a liquid composition containing a water-soluble fluorescent dye and the like, and a method for labeling hydrophobic materials using the same.
従来の技術
疎水性繊維等疎水性材料に例えば螢光染料を用いて標識
を付与し、縫製等における工程管理あるいは在庫管理等
を容易にするという方法は広く用いられている。それら
のうち水溶性の螢光染料或いは螢光顔料を適当な溶剤に
溶解し疎水性材料に標識を付与するという方法も公知で
ある。BACKGROUND ART A widely used method is to attach a label to a hydrophobic material such as a hydrophobic fiber using, for example, a fluorescent dye to facilitate process control or inventory control in sewing or the like. Among these methods, a method is also known in which a water-soluble fluorescent dye or fluorescent pigment is dissolved in a suitable solvent to impart a label to a hydrophobic material.
発明が解決しようとする問題点
疎水性材料上に付与された標識は可視光線では認識され
ず特定の光線によってのみ認識される必要があるが前記
したような水溶性の螢光染料又は螢光顔料をアセトン等
の溶剤に溶解して疎水性材料に標識を付与した場合、付
与された螢光染料。Problem to be Solved by the Invention Labels attached to hydrophobic materials cannot be recognized by visible light and need to be recognized only by specific light. When a label is added to a hydrophobic material by dissolving it in a solvent such as acetone, the attached fluorescent dye.
螢光顔料が黄色に着色したり、紫外線の照射によってそ
の標識が検出されず（螢光物質のクエンチング現象）本
来の目的を達成しないということが多い。In many cases, the fluorescent pigment is colored yellow, or the label is not detected by irradiation with ultraviolet light (fluorescent substance quenching phenomenon), and the original purpose is not achieved.
特に水溶性螢光染料を用いて合成繊維、とりわけポリエ
ステル繊維、或いは合成樹脂製品１例えばフィルムなど
く標識を付与する場合、螢光顔料をアセトン等の溶剤に
溶解して主としてジェットプリンターで標識の付与を行
う方法が行われているがこの場合には、使用停止時に溶
剤が揮発してノズルをつめてしまう事故が発生しやすい
。In particular, when a water-soluble fluorescent dye is used to label synthetic fibers, especially polyester fibers, or synthetic resin products such as films, the fluorescent pigment is dissolved in a solvent such as acetone and the label is typically applied using a jet printer. However, in this case, accidents tend to occur where the solvent evaporates and clogs the nozzle when the product is stopped.
問題を解決する為の手段
本発明者は前記したような問題点を解決すべく鋭意研究
を重ねた結果、水溶性螢光染料及びカゼイン、デンプン
、酸化デンプン、カチオン化デンプン、５ＢＲ（スチレ
ン−ブタジェンラバー）ラテックス、ＣＭＣ（カルボキ
シメチルセルローズ）、水溶性ナイロン、又はＰＴＡ（
ポリビニルアルコール）の一種又は二種以上を用いて疎
水性材料に標識を付与することによって前記したような
問題点が解決されることを見出し本発明を完成させた。Means for Solving the Problems As a result of extensive research in order to solve the above-mentioned problems, the inventors of the present invention have developed water-soluble fluorescent dyes, casein, starch, oxidized starch, cationized starch, and 5BR (styrene-butylene). Gen Rubber) latex, CMC (carboxymethyl cellulose), water-soluble nylon, or PTA (
The present invention has been completed based on the discovery that the above-mentioned problems can be solved by labeling a hydrophobic material using one or more types of polyvinyl alcohol.
本発明で、水溶性螢光染料とは、母体構造としテステル
ベン核或いはビスチリルビフェニル核ヲ持ち、主として
セルローズ系繊維、パルプ、合成洗剤などに使用される
もの、及び母体構造としてクマリン核を持ち、主として
羊毛、ナイロンなどのポリアミド繊維の螢光増白に使用
されるもので水溶性のものをいう。標識付与にジェット
プリンターを使用する場合には、一般に不純物例えば無
機塩類の含有量が少ない水溶性螢光染料の液状品が好適
である。In the present invention, water-soluble fluorescent dyes include those having a testerbene nucleus or bistyrylbiphenyl nucleus as a matrix structure and are mainly used for cellulose fibers, pulp, synthetic detergents, etc., and those having a coumarin nucleus as a matrix structure, It is mainly used for fluorescent whitening of polyamide fibers such as wool and nylon, and is water-soluble. When a jet printer is used for labeling, liquid products of water-soluble fluorescent dyes that contain a small amount of impurities such as inorganic salts are generally suitable.
これらの水溶性螢光染料を使用するには、粉体のものは
所要量の水または温湯で溶解し、液状のものは所要量の
水で稀釈して使用する。To use these water-soluble fluorescent dyes, powder ones are dissolved in the required amount of water or hot water, and liquid ones are diluted with the required amount of water.
−力水溶性螢光染料の水溶液に添加するカゼイン。- Casein added to an aqueous solution of a water-soluble fluorescent dye.
ゼラチン、デンプン、酸化デンプン、カチオン化デンプ
ン、ＳＢＲラテックス、ＣＭＣ１水溶性ナイロ゛ン又は
？’７Ａ（以後これらを添加剤という）の一種又は二種
を水を用いて溶解、液状又は糊状力ゝ
にしたあと前記水溶液に添加する嗅鼻、あるいは前記の
如くして見られた添加剤の液状又は糊状品に前記水溶性
螢光染料の水溶液を添加してもよい。Gelatin, starch, oxidized starch, cationized starch, SBR latex, CMC1 water-soluble nylon or? '7A (hereinafter referred to as additives) is dissolved in water to form a liquid or paste, and then added to the aqueous solution, or an additive found as described above. An aqueous solution of the water-soluble fluorescent dye may be added to the liquid or pasty product.
水溶性螢光染料と添加剤との割合は添加剤に対して水溶
性螢光染料が乾燥品換算で５チ（重量）以上好ましくは
１０％（重量）以上含有されるよりに調製するのが好ま
しい。The ratio of the water-soluble fluorescent dye to the additive is adjusted so that the water-soluble fluorescent dye is contained in an amount of at least 5% (by weight) or more preferably at least 10% (by weight) on a dry basis. preferable.
こうして見られた水溶性螢光染料の水溶液と液状又は糊
状の添加剤との混合物の粘度は後記する標識の付与手段
に応じて水又は前記添加剤を用いて調製される。The viscosity of the thus obtained mixture of the aqueous solution of the water-soluble fluorescent dye and the additive in the form of liquid or paste is adjusted using water or the additive, depending on the labeling means described below.
水溶性螢光染料のうち母体構造がクマリン核を持つもの
のようにその水溶液のイオン性がカチオン性であるもの
については添加剤としてカチオン化されたデンプンを使
用するのが良い。For water-soluble fluorescent dyes whose parent structure has a coumarin nucleus and whose aqueous solution has a cationic ionicity, it is preferable to use cationized starch as an additive.
前記の如く調製された水溶性螢光染料と前記添加剤の混
合物を疎水性材料に付与する方法としては、シルクスク
リーンを用いる方法、筆などを用いる方法、ジェットプ
リンターを用いる方法など目的に応じて使用出来る。The mixture of the water-soluble fluorescent dye prepared as described above and the additive may be applied to the hydrophobic material depending on the purpose, such as a method using a silk screen, a method using a brush, a method using a jet printer, etc. Can be used.
疎水性材料としては、織物％編物あるいはフィルム、板
などのシート状のものは勿論、複雑な形に成形されたも
のでも付与する方法、装置を工夫すれば付与することが
可能である。又該材料は無色のものはもちろん着色又は
染色されたものにも適用される。付与後は標識に直接触
れないような方法で乾燥すれば良い。As the hydrophobic material, it is possible to apply not only woven fabrics, sheet-like materials such as films and plates, but also materials formed into complicated shapes by devising a method and an apparatus for applying the hydrophobic material. Moreover, the material can be applied not only to colorless materials but also to colored or dyed materials. After application, the label should be dried in a way that does not allow direct contact with the label.
実施例 実施例により本発明を更に詳細に説明する。Example The present invention will be explained in more detail with reference to Examples.
実施例１
カヤホール日リキッド（水溶性螢光染料、日本化薬ｆｆ
、 ８分２ ｓ％、Ｃ・工・フルオレスセント８７）１
２をゴーセノールＧＩＪ−０５Ｈ（日本合成化学工業製
ＰＴＡ ）の２０％溶液？？を中に加えて良くかきまぜ
た後、 １３５０メツシユのシルクスクリーンを使用
してポリエステル１００％加工系織物上に模様をプリン
トし、６０℃の熱風中で乾燥した。この標識は太陽光で
は検出出来ないが、ブラックライトのもとでは鮮やかな
模様の螢光発色が見られ、標識として検出出来た。Example 1 Kayahole Nippon Liquid (water-soluble fluorescent dye, Nippon Kayaku ff
, 8 min 2 s%, C/Engineering/Fluorescent 87) 1
2 is a 20% solution of Gohsenol GIJ-05H (PTA manufactured by Nippon Gosei Kagaku Kogyo)? ? After stirring well, a pattern was printed on a 100% polyester fabric using a 1350 mesh silk screen, and the mixture was dried in hot air at 60°C. This marker cannot be detected in sunlight, but under black light, a bright pattern of fluorescent light can be seen and it can be detected as a marker.
同様にカヤホール日リキッド１１をアルギン５ＳＬ（富
士化学工業製アルギン酸ンーダ）の２０％溶液に加えた
ものでプリントしたものは、標識物が黄色に着色しブラ
ックライトを照射しても螢光発色は見られなかった。Similarly, when printing with Kayahole Nippon Liquid 11 added to a 20% solution of Algin 5SL (Fuji Chemical Co., Ltd. alginate powder), the markings were colored yellow and no fluorescence was observed even when exposed to a black light. I couldn't.
実施例２
実施例１においてポリエステル１００％加工糸織物の代
わりにポリエチレンシートを用イル他ハ実施例１と同様
に処理してブラックライトによって鮮明に検出される標
識を得た。Example 2 A polyethylene sheet was used in place of the 100% polyester fabric in Example 1. The sheet was treated in the same manner as in Example 1 to obtain a label that could be clearly detected with a black light.
実施例５
カヤホールＡｓコンク（水溶性螢光染料１日本（［製、
純分５０％、Ｃ６工、フルオレスセン）９０）１ｔを２
０ａｅの温湯に溶解し、これをデンプンの２０％水溶液
を煮て作った糊中に加え、実施例１と同様にポリエステ
ル加工糸織物上にプリントし。Example 5 Kayahole As conc (water-soluble fluorescent dye 1 manufactured by Japan)
50% pure, C6 engineering, fluorescein)90) 1t to 2
It was dissolved in 0ae warm water, added to a glue made by boiling a 20% starch aqueous solution, and printed on a polyester textured yarn fabric in the same manner as in Example 1.
乾燥した。この標識は実施例１と同様に太陽光線のもと
では検出出来なかりたが、ブラックライト下では鮮やか
な模様に螢光発色し標識として検出出来た。Dry. As in Example 1, this label could not be detected under sunlight, but under black light it fluoresced in a vivid pattern and could be detected as a label.
デンプンの代りにアラビアゴム（関東化学製鹿印粉末）
の２０％溶液を用いた場合は、標識物が黄色く着色し、
ブラックライト下での螢光発色がなく標識としての効果
を示さなかった。Gum arabic instead of starch (Kanto Kagaku Kajirushi powder)
When using a 20% solution of
There was no fluorescence under black light, and it did not show any effect as a label.
実施例４ カヤホール３ＢＳリキツド（水溶性螢光染料。Example 4 Kayahole 3BS Liquid (water-soluble fluorescent dye).
日本化薬製、純分２５％、Ｃ，工、フルオレスセント２
７１）１ｆをＭＢ−３８００（日本食品化工製。Made by Nippon Kayaku, pure content 25%, C, engineering, fluorescent 2
71) 1f to MB-3800 (manufactured by Nihon Shokuhin Kako).
紛
酸化澱虚）の３Ｌｌｂ水溶液を加熱して糊化したもの２
０ｆ中に加え、筆でポリスチレンの白い板に模様を書き
、ヘヤードライヤーで乾燥した。その標識は太陽光では
検出出来なかったが、ブラックライトの下では鮮やかな
模様に螢光発色し、標識として検出出来た。3L lb aqueous solution of powdered oxidized sludge) heated to gelatinize 2
A pattern was drawn on a white polystyrene board with a brush and dried with a hair dryer. The marker could not be detected in sunlight, but under black light it fluoresced in a vivid pattern and could be detected as a marker.
実施例５ カヤホール３ＢＳリキツド（水溶性螢光染料。Example 5 Kayahole 3BS Liquid (water-soluble fluorescent dye).
日本化薬製、純分２５％、Ｃ０工、 フルオレスセント
１６６）１０５Ｆに水？（１ｍｇを加え、これに実施例
１で用いたゴーセノールＧＬ−０５１を５？加えて攪拌
し均一な溶液とした。これをジェットプリンター（イン
クジェットカラーイメージプリンター１０−０７００．
シャープ製）でポリエステルタックに模様をプリントし
、乾燥した。この模様は太陽光線下では検出で舞なかっ
たがブラックライトの下では鮮やかな模様に螢光発色し
標識として検出できた。Made by Nippon Kayaku, pure content 25%, C0 engineering, Fluorescent 166) Water on 105F? (Add 1 mg of Gohsenol GL-051 used in Example 1 to this and stir to make a uniform solution.
Print the pattern on the polyester tack with a SHARP product and let it dry. This pattern could not be detected under sunlight, but under black light it became a vivid pattern that fluoresced and could be detected as a marker.
実施例６
カヤホール３ＢＳリキツド１０？に水９０ｄを加え、こ
れにＡＱナイロンＡ−９０（東し製水溶性ナイロン）を
１２加えて十分攪拌して均一な溶液とした。・これを実
施例５で用いたジェットプリンターによりポリエステル
加工糸織物に模様をプリントし、乾燥した。この標識は
太陽光線下では検出出来なかったがブラックライトのも
とでは明瞭に検出できた。Example 6 Kaya Hall 3BS Liquid 10? 90 d of water was added to the solution, 12 d of AQ nylon A-90 (water-soluble nylon manufactured by Toshi) was added thereto, and the mixture was sufficiently stirred to form a uniform solution. - A pattern was printed on a polyester processed yarn fabric using the jet printer used in Example 5, and then dried. This marker could not be detected under sunlight, but was clearly detectable under black light.
実施例７
実施例１で用いたカヤホール日リキッド１０ｔを同じく
ゴーセノールＧＬ−Ｑ５Ｈの２０％溶液１０Ｓ’に加え
て本発明の液状組成物をえた。Example 7 A liquid composition of the present invention was obtained by adding 10 tons of the Kayahol liquid used in Example 1 to 10 S' of a 20% solution of Gohsenol GL-Q5H.
発明の効果
疎水性材料に標識を付与するにあたって水溶性螢光染料
とカゼイン、デンプン、酸化デンプン。Effects of the invention Water-soluble fluorescent dyes and casein, starch, oxidized starch in labeling hydrophobic materials.
カチオン化デンプン、スチレン−ブタジエンラバーラテ
ックス、カルボキシメチルセルローズ、水溶性ナイロン
又はポリビニルアルコールの一種又は二種以上を用いる
ことによって着色のない紫外線の照射によって容易に検
出出来る標識を付与することが出来た。By using one or more of cationized starch, styrene-butadiene rubber latex, carboxymethyl cellulose, water-soluble nylon, or polyvinyl alcohol, it was possible to impart a label that can be easily detected by irradiation with ultraviolet light without coloring.
Claims (2)
ンプン、カチオン化デンプン、スチレン−ブタジエンラ
バーラテックス、カルボキシメチルセルローズ、水溶性
ナイロン又はポリビニルアルコールの一種又は二種以上
を含有する液状組成物。(1) A liquid composition containing a water-soluble fluorescent dye and one or more of casein, starch, oxidized starch, cationized starch, styrene-butadiene rubber latex, carboxymethyl cellulose, water-soluble nylon, or polyvinyl alcohol.
ンプン、カチオン化デンプン、スチレン−ブタジエンラ
バーラテックス、カルボキシメチルセルローズ、水溶性
ナイロン又はポリビニルアルコールの一種又は二種以上
を含有する液状組成物を用いることを特徴とする疎水性
材料の標識付与法。(2) Using a liquid composition containing a water-soluble fluorescent dye and one or more of casein, starch, oxidized starch, cationized starch, styrene-butadiene rubber latex, carboxymethyl cellulose, water-soluble nylon, or polyvinyl alcohol. A method for labeling hydrophobic materials, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60043588A JPH06102873B2 (en) | 1985-03-07 | 1985-03-07 | Labeling method for hydrophobic materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60043588A JPH06102873B2 (en) | 1985-03-07 | 1985-03-07 | Labeling method for hydrophobic materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61204277A true JPS61204277A (en) | 1986-09-10 |
| JPH06102873B2 JPH06102873B2 (en) | 1994-12-14 |
Family
ID=12667943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60043588A Expired - Fee Related JPH06102873B2 (en) | 1985-03-07 | 1985-03-07 | Labeling method for hydrophobic materials |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06102873B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02171278A (en) * | 1988-12-26 | 1990-07-02 | Agency Of Ind Science & Technol | Data reading method |
| JPH02171277A (en) * | 1988-12-26 | 1990-07-02 | Agency Of Ind Science & Technol | Data imparting method |
| US5386107A (en) * | 1991-12-23 | 1995-01-31 | Symbol Technologies, Inc. | Scanning arrangement and method in which the focus is varied in operative correlation with the scanning angle |
| US6206289B1 (en) | 1988-08-26 | 2001-03-27 | Accu-Sort Systems, Inc. | Scanner |
| WO2007073223A1 (en) * | 2005-12-20 | 2007-06-28 | Termo Organika Sp. Z O.O. | Agent for modification and identification of components and compositions comprising at least a stilbene derivate, a surface active agent and mono and trihydroxylic alcohols |
| JP2009001697A (en) * | 2007-06-22 | 2009-01-08 | Mitsubishi Pencil Co Ltd | Ink composition for fixing written line and application tool therefor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111238A (en) * | 1975-02-28 | 1976-10-01 | Ciba Geigy Ag | Storageestability aqueous dispersing liquids of waterrsoluble compounds |
| JPS5516085A (en) * | 1978-07-17 | 1980-02-04 | Ciba Geigy Ag | Storageestable concentrated aqueous solution for sulfo group contained fluorescent brightener |
| JPS608371A (en) * | 1983-06-27 | 1985-01-17 | Sumitomo Chem Co Ltd | Aqueous composition of fluorescent brightener |
-
1985
- 1985-03-07 JP JP60043588A patent/JPH06102873B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111238A (en) * | 1975-02-28 | 1976-10-01 | Ciba Geigy Ag | Storageestability aqueous dispersing liquids of waterrsoluble compounds |
| JPS5516085A (en) * | 1978-07-17 | 1980-02-04 | Ciba Geigy Ag | Storageestable concentrated aqueous solution for sulfo group contained fluorescent brightener |
| JPS608371A (en) * | 1983-06-27 | 1985-01-17 | Sumitomo Chem Co Ltd | Aqueous composition of fluorescent brightener |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6206289B1 (en) | 1988-08-26 | 2001-03-27 | Accu-Sort Systems, Inc. | Scanner |
| JPH02171278A (en) * | 1988-12-26 | 1990-07-02 | Agency Of Ind Science & Technol | Data reading method |
| JPH02171277A (en) * | 1988-12-26 | 1990-07-02 | Agency Of Ind Science & Technol | Data imparting method |
| JPH0515556B2 (en) * | 1988-12-26 | 1993-03-01 | Kogyo Gijutsuin | |
| US5386107A (en) * | 1991-12-23 | 1995-01-31 | Symbol Technologies, Inc. | Scanning arrangement and method in which the focus is varied in operative correlation with the scanning angle |
| WO2007073223A1 (en) * | 2005-12-20 | 2007-06-28 | Termo Organika Sp. Z O.O. | Agent for modification and identification of components and compositions comprising at least a stilbene derivate, a surface active agent and mono and trihydroxylic alcohols |
| JP2009001697A (en) * | 2007-06-22 | 2009-01-08 | Mitsubishi Pencil Co Ltd | Ink composition for fixing written line and application tool therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06102873B2 (en) | 1994-12-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4294641A (en) | Heat transfer sheets | |
| CA2333187C (en) | Marking system | |
| US4786288A (en) | Fabric treating method to give sharp colored patterns | |
| PL83023B1 (en) | ||
| US4543102A (en) | Aqueous printing inks for transfer printing containing polyvinyl alcohol and acrylate polymer | |
| WO2021238969A1 (en) | Coating composition for pet film, pet transfer film, and preparation method therefor and use thereof | |
| JPS61204277A (en) | Labeling of liquid composition and hydrophobic material | |
| US2067435A (en) | Article of manufacture for continuous embossing | |
| CN107558260A (en) | A kind of rose scent microcapsules printing assistant and preparation method thereof | |
| US2259225A (en) | Coloring composition for textiles | |
| US3086873A (en) | Silk screen printing ink | |
| JPH107957A (en) | Erasable colorant composition | |
| KR20060020604A (en) | Coloring composition and coating composition | |
| JP4297451B2 (en) | Marking pen ink | |
| US5008239A (en) | Transfer printing of natural and natural/synthetic fibres | |
| US1832660A (en) | Transfer | |
| DE2557002B1 (en) | Transfer printing of synthetic fibres using aq. dye dispersions - and polymeric thickeners contg. carboxyl gps. | |
| US1573976A (en) | Transfer-ink composition | |
| SU979551A1 (en) | Composition for printing on cotton textile material | |
| US2689162A (en) | Textile decorating composition containing aldehyde-amine resin and zinc silicofluoride cure accelerator | |
| GB543860A (en) | Direct printing and dyeing of materials | |
| US1849996A (en) | Transfer printing and transfer pattern therefor | |
| JPH09255903A (en) | Ink composition | |
| JPS6221884A (en) | Method for coloring or dyeing substrate | |
| CA1249436A (en) | High solids content cb coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |