JPS6097912A - Wax for removal of hair - Google Patents
Wax for removal of hairInfo
- Publication number
- JPS6097912A JPS6097912A JP20448383A JP20448383A JPS6097912A JP S6097912 A JPS6097912 A JP S6097912A JP 20448383 A JP20448383 A JP 20448383A JP 20448383 A JP20448383 A JP 20448383A JP S6097912 A JPS6097912 A JP S6097912A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- hair
- petroleum resin
- resin
- rosin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【発明の詳細な説明】
本発明は、例えばポリイソプレン等のＣ系石油樹脂を配
合してなる人体及び動物の脱毛に用いる脱毛ワックスに
関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a hair removal wax used for hair removal on the human body and animals, which is blended with a C-based petroleum resin such as polyisoprene.
周知の通り、脱毛ワックスとは、加温融解して、５０℃
程度で皮膚に塗布し、冷却固化後一枚の°被膜としては
がす時の物理力によって脱毛を行うワックスである。As is well known, hair removal wax is heated and melted at 50℃.
It is a wax that removes hair by applying physical force to the skin when it is applied to the skin, cooled and solidified, and then peeled off as a single film.
従来、脱毛ワックスの主剤としてはロジン：松脂（アビ
エチン酸を主成分とする。）が用いられており、これに
皮膜性、剥離性、塗布の仕易さ等の使用性を向上させる
目的で、固形油分、粉末等が適量加えられていた。ロジ
ンが主剤として用いられるのは、極めて毛根への密着力
が強く、この為優れた脱毛力を発揮するからである。Conventionally, rosin (mainly consisting of abietic acid) has been used as the main ingredient in hair removal wax, and in order to improve usability such as film properties, peelability, and ease of application, Appropriate amounts of solid oil, powder, etc. were added. Rosin is used as the main ingredient because it has extremely strong adhesion to the hair roots and therefore exhibits excellent hair removal power.
しかし、一方では、ロジンには、皮膚感作性を有すると
いう安全性上の問題があることから、これに代わる種々
の代替品が検討されているが、いずれも脱毛効果がロジ
ン系よりも劣る欠点があった。 本発明者等は、上記の
欠点を解決すべく検討した結果、Ｃ系石油樹脂を用いる
ことにより、安全性が高く、脱毛力もロジン系に劣らな
い脱毛ワックスが得られることを見い出し、本発明を完
成するに至った。However, on the other hand, rosin has a safety problem of skin sensitization, so various alternatives are being considered, but all of them have inferior hair removal effects than rosin-based products. There were drawbacks. As a result of studies to solve the above-mentioned drawbacks, the present inventors discovered that by using a C-based petroleum resin, a hair removal wax that is highly safe and has a hair removal power comparable to that of rosin-based waxes can be obtained, and has developed the present invention. It was completed.
すなわち、本発明はＣ系石油樹脂を含有することを特徴
とする脱毛ワックスである。That is, the present invention is a hair removal wax characterized by containing a C-based petroleum resin.
本発明で用いるＣ 系石油樹脂とは、ナフサ等の熱分解
によって生成するＣ 留分、即ち、イソプレン、シクロ
ペンタジェン、１．３−ペンタジェン、１−ペンテン、
２−ペンテン等ヲ主成分トする不飽和炭化水素の一種又
は２種以上を重合した樹脂であり、市販品からめるとす
れば、例えば次の様な製品があげられる。ニスコレラ（
エクソン社） 、Ｐｉｃｃｏｐａｌｅ Ｒｅ５ｉｎ （
Ｐｉｃｃｏ社） 、ＷｉｎｇＴａｃｋ ９５ （Ｇｏｏ
ｄ ｙｅａｒ社） ％ ５ｕｐｅｒ ５ｔａ−Ｔａｃ
（Ｒｅ−１ｃｈｈｏｌｄ社）、ハイレソッＴ１００に、
Ｃｌｌ０Ｘ （三井石油化学社）、フィントン（日本ゼ
オン）、タソキロール（住人化学）、タックエース（三
井石油化学） 、Ｉｍｐｒｅｚ （Ｉ Ｃ１社）。The C-based petroleum resin used in the present invention refers to the C-fraction produced by thermal decomposition of naphtha, etc., such as isoprene, cyclopentadiene, 1.3-pentadiene, 1-pentene,
It is a resin obtained by polymerizing one or more unsaturated hydrocarbons mainly consisting of 2-pentene and the like, and examples of commercially available products include the following. Nis cholera (
Exxon), Piccopale Re5in (
Picco), WingTack 95 (Goo
d year) % 5uper 5ta-Tac
(Re-1chhold), HiResot T100,
Cll0X (Mitsui Petrochemicals), Finton (Nippon Zeon), Tasoquirol (Sumiman Chemical), Tac Ace (Mitsui Petrochemicals), Imprez (IC1).
Ｃ系石油樹脂は、ロジンのように安全性上の問題を有し
ていないので、従来の脱毛ワックス組成中のロジンを適
量のＣ系石油樹脂で置換すれば安全性向上の効果が発現
され得る。ロジンをＣ系石油樹脂で完全置換することが
安全性の面で好ましいことは当然である。Unlike rosin, C-based petroleum resin does not have safety problems, so replacing rosin in a conventional hair removal wax composition with an appropriate amount of C-based petroleum resin can bring about the effect of improving safety. . Naturally, it is preferable in terms of safety to completely replace rosin with C-based petroleum resin.
Ｃ系石油樹脂の配合量は脱毛ワックス全量中の４０重量
％〜９０％重量％、好ましくは６０重量％〜８５重量％
である。The blending amount of C-based petroleum resin is 40% to 90% by weight, preferably 60% to 85% by weight based on the total amount of hair removal wax.
It is.
また、Ｃ系石油樹脂を用いる場合にも、ロジンの場合と
同様に皮膜性、剥離性を良好にするため、Ｃ系石油樹脂
に加えて、例えば固形パラフィン、ミツロウ、カルナウ
バロウ、キャンデリラロウ、硬化しマシ油、鯨ロウ等の
固形油分等を配合する必要がある。固形油分等の配合量
は全量中の１０〜３０重量％である。Also, when using a C-based petroleum resin, in order to improve the film properties and peelability as in the case of rosin, in addition to the C-based petroleum resin, for example, solid paraffin, beeswax, carnauba wax, candelilla wax, hardened It is necessary to incorporate solid oils such as mustard oil and whale wax. The amount of solid oil etc. is 10 to 30% by weight based on the total amount.
なお、上記Ｃ系石油樹脂及び固形油分で構成される脱毛
ワックスに、さらに加えて酸化チタン、タルク、カオリ
ン、亜鉛華、マイカ等の無機粉末類を配合すると、より
良好な皮膜が形成され、又、剥離性、塗布のし易さ等も
向上する。無機粉末類の配合量は一般的に全量中の５〜
３０重量％である。In addition, if inorganic powders such as titanium oxide, talc, kaolin, zinc white, and mica are further added to the hair removal wax composed of the C-based petroleum resin and solid oil, a better film will be formed. , removability, ease of application, etc. are also improved. The amount of inorganic powders is generally 5 to 5% of the total amount.
It is 30% by weight.
さらに本発明の脱毛ワックスには香料、色材、薬剤等の
成分を添加し得る。Furthermore, components such as fragrances, colorants, and drugs may be added to the hair removal wax of the present invention.
次に実施例を挙げて本発明をさらに詳細に説明する。配
合量は重量％である。Next, the present invention will be explained in more detail with reference to Examples. The blending amount is in weight%.
実施例１
ポリイソプレン樹脂 ６０
ミツロウ ２４
固形パラフイン ６
酸化チタン １０
実施例２
イソプレン、シクロペンタジェン、
１−ペンテン共重合樹脂 ８２
木ロウ ８
固形パラフイン ２
タルク ８
実施例３
ポリ１，３−ペンタジェン樹脂 ７５
ミツロウ １０
カルナウバロウ ６
キヤンデリラロウ ９
比較例１
０ジン ６０
ミツロウ ２４
固形パラフイン ６
酸化チタン １０
比較例２
水飴 ８５
固形パラフイン １０
ロジン ５
比較例３
水添ポリブテン樹脂 ６０
固形パラフイン ２０
カルナウバロウ １０
タルク １０
脱毛効果試験（モルモットによる脱毛テスト）モルモッ
トの背部を電気バリカンで刈上する。Example 1 Polyisoprene resin 60 Beeswax 24 Solid paraffin 6 Titanium oxide 10 Example 2 Isoprene, cyclopentadiene, 1-pentene copolymer resin 82 Wood wax 8 Solid paraffin 2 Talc 8 Example 3 Poly 1,3-pentadiene resin 75 Beeswax 10 Carnauba wax 6 Candelilla wax 9 Comparative example 1 0 Gin 60 Beeswax 24 Solid paraffin 6 Titanium oxide 10 Comparative example 2 Starch syrup 85 Solid paraffin 10 Rosin 5 Comparative example 3 Hydrogenated polybutene resin 60 Solid paraffin 20 Carnauba wax 10 Talc 10 Hair removal effect test (guinea pig hair removal test) The back of the guinea pig is trimmed with electric clippers.
脱毛した一匹を背骨から左右２面に分け、各々に加熱融
解して５０°Ｃ程度にした実施例１〜３、比較例１〜３
を塗布し、固化後−気に剥離して脱毛処理した。処理後
、残存した毛の量を下記基準に従って、視感評価した。Examples 1 to 3, Comparative Examples 1 to 3, in which a single animal with hair removed was divided into two sides, left and right from the spine, and heated and melted on each side to about 50 ° C.
was applied, and after solidifying, it was peeled off with air for hair removal treatment. After the treatment, the amount of remaining hair was visually evaluated according to the following criteria.
評価点 １、 はとんど毛が残っている。Evaluation points 1. Most of the hair remains.
２、面状にかなり残っている。2. Quite a lot remains on the surface.
３、線状にまばらに残っている。3. Sparse lines remain.
４、点状に少し残っている。4. A small amount of dots remain.
５、 毛がほとんど認められない。5. Almost no hair is recognized.
結果を第１表に示す（ｎ−５の平均値）。The results are shown in Table 1 (average value of n-5).
（以下余白）
第 １ 表
第１表の結果から明らかな通り、Ｃ系石油樹脂を配合し
てなる実施例１〜３はロジンを用いた脱毛ワックスと同
等の脱毛効果を有し、又、ロジン以外の他の樹脂より優
れている。(Leaving space below) Table 1 As is clear from the results in Table 1, Examples 1 to 3 containing C-based petroleum resin had the same hair removal effect as hair removal wax using rosin. superior to other resins.
（以下余白）
実施例４
ポリイソプレン樹脂 ７０
密ロウ １５
固型パラフイン ５
酸化チタン １０
比較例４
０ジン ７０
密ロウ １５
固型パラフイン ５
酸化チタン １０
比較例５
水添ポリブテン ６０
固型パラフイン ２０
カルナウバロウ １０
タルク １０
脱毛効果試験（実使用テスト）
実施例４、比較例４〜５について、２０〜５０才の女性
パネルの脇毛を用いて、独立判定による５点評価法で比
較テストを行った。評価法については、モルモットの場
合と同様である。結果を第２表に示す。表中の数字は各
評価点に評価されたパネルの人数である。(Leaving space below) Example 4 Polyisoprene resin 70 Black wax 15 Solid paraffin 5 Titanium oxide 10 Comparative example 4 0 Gin 70 Black wax 15 Solid paraffin 5 Titanium oxide 10 Comparative example 5 Hydrogenated polybutene 60 Solid paraffin 20 Carnauba wax 10 Talc 10 Hair Removal Effect Test (Actual Use Test) For Example 4 and Comparative Examples 4 and 5, a comparative test was conducted using the armpit hair of a panel of women aged 20 to 50 using a 5-point evaluation method based on independent judgment. The evaluation method is the same as for guinea pigs. The results are shown in Table 2. The numbers in the table are the number of panel members who were evaluated for each evaluation point.
（辺・下′ 白）
第 ２ 表
以上の通り、Ｃ石油樹脂系の脱毛ワックスは、ロジン系
にくらべ、同等あるいは良好な脱毛効果を示した。(Side/Bottom' white) Table 2 As shown above, the C petroleum resin-based hair removal wax showed the same or better hair removal effect than the rosin-based hair removal wax.
次にＣ系石油樹脂の代表例として、ポリイソプレン樹脂
をとり、このものとロジンとの感作性の比較テストを行
った。Next, a polyisoprene resin was taken as a representative example of C-based petroleum resin, and a comparison test was conducted on the sensitization properties of this resin and rosin.
試験は体重３８０〜４２０ｇの健常なハートレイ系アル
ピノモルモットを用い、５ａｔｏらの方法（Ｓａｔｏ
Ｙ、。The test used healthy Hartley Alpino guinea pigs weighing 380 to 420 g, using the method of Sato et al.
Y.
Ｋａｔｓｕｎｕｍａ Ｙ、、 Ｉｃｈｉｋａｗａ Ｈ，
、Ｋｏｂａｙａｓｈｉ Ｔ、、 ｅｔａｔ、、＾ｍｏｄ
ｉｆｉｅｄ ｔｅｃｈｎｉｑｕｅ ｏｆ ｇｕｉｎｅａ
ｐｉｇ ｔｅｓｔ−ｊｎｇ ｔｏ １ｄｅｎｔｉｔｙ
ｄｅｌａｙｅｄ ｈｙｐｅｒｓｅｎｓｅｔｉｖｉｔｙ
ａｌ−１ｅｒｇｅｎｓ、Ｃｏｎｔａｃｔ Ｄｅｒｍａ
ｔｊｔｉｓ、７．２２５−２３７．１９８１）に準じて
行った。Katsunuma Y, Ichikawa H,
, Kobayashi T,, etat,, ^mod
ified technique of guinea
pig test-jng to 1dentity
delayed hypersensitivity
al-1ergens, Contact Derma
tjtis, 7.225-237.1981).
結果を第３表、第４表に示す。The results are shown in Tables 3 and 4.
０
第３表（ポリイソプレン樹脂の感作性試験結果、インダ
クシロン：５０％ｎ−へキサン溶液）（以下余白）
第４表（ロジンの感作性試験結果、インダウ９９フ２２
０
（以下余白）
１
第３表及び第４表から明らかな如く、ロジンについては
低濃度域でもかなりの感作反応を示すが、ポリイソプレ
ン樹脂の場合、はとんど感作性がない。0 Table 3 (Results of sensitization test for polyisoprene resin, induxilone: 50% n-hexane solution) (blank below) Table 4 (Results of sensitization test for rosin, Indow 99F22
0 (The following is a blank space) 1 As is clear from Tables 3 and 4, rosin exhibits a considerable sensitizing reaction even in a low concentration range, but polyisoprene resin has almost no sensitizing effect.
以上の通り、本発明は、ポリイソプレン等のＣ系石油樹
脂を用いることにより、高い安全性及び良好な脱毛力を
実現した優れた脱毛ワックスである。As described above, the present invention is an excellent hair removal wax that achieves high safety and good hair removal power by using C-based petroleum resin such as polyisoprene.
特許出願人 株式会社 資 生 堂
３
２
手続補正書（自発）
昭和５８年１１月４−日
１、事件の表示
昭和５８年特許願第２０４４８３号
２、発明の名称
脱毛ワックス
３、補正をする者
４、補正の対象
明細書の特許請求の範囲の欄及び発明の詳細な
な説明の欄
５． 補正の内容
（１）明細書の特許請求の範囲を別紙の通り補正します
。Patent applicant Shiseido Co., Ltd. 3 2 Procedural amendment (voluntary) November 4, 1988 1, Case description 1983 Patent Application No. 204483 2, Name of the invention Hair removal wax 3, Person making the amendment 4. Claims column and Detailed Description of the Invention column of the specification subject to amendment 5. Contents of amendment (1) The scope of claims in the specification will be amended as shown in the attached sheet.
（２）明細書第１頁第８行目「Ｃ系」とあるを、「Ｃジ
系」と補正します。(2) In the 8th line of page 1 of the specification, "C series" should be corrected to "C di series".
（３）明細書第２頁第７行目「Ｃ系」とあるを、ｒＣ５
系」と補正します。(3) "C series" on page 2, line 7 of the specification is rC5
Correct it as "system".
（４）明細書第２頁第１１行目「Ｃ系」とあるを、「Ｃ
５系」と補正します。(4) The phrase “C series” on page 2, line 11 of the specification is replaced with “C
5 series” and correct it.
（５）明細書第２頁第１３行目「Ｃ系」とあるを、「Ｃ
５系」と補正します。(5) The phrase “C series” on page 2, line 13 of the specification has been replaced with “C
5 series” and correct it.
（６）明細書第２頁第１４行目「Ｃ留分」とあるを、「
Ｃ５留分」と補正します。(6) Change the phrase “C fraction” on page 2, line 14 of the specification to “
Correct it as "C5 distillate".
（７）明細書第３頁第６行目「Ｃ系」とあるを、「Ｃ５
系」と補正します。(7) The phrase “C series” on page 3, line 6 of the specification has been replaced with “C5
Correct it as "system".
（８）明細書第３頁第８行目「Ｃ系」とあるを、「Ｃ５
系」と補正します。(8) The phrase “C series” on page 3, line 8 of the specification has been replaced with “C5
Correct it as "system".
（９）明細書第３頁第９行目〜第１０行目「Ｃ系」とあ
るを、「Ｃ５系」と補正します。(9) On page 3, line 9 to line 10 of the specification, "C series" should be corrected to "C5 series."
（１０）明細書第３頁第１２行目「Ｃ系」とあるを、「
Ｃ５系」と補正します。(10) In the 12th line of page 3 of the specification, replace “C series” with “
Correct it to "C5 series".
（１１）明細書第３頁第１５行目「Ｃ系」とあるを、「
Ｃ５系」と補正します。(11) The phrase “C series” on page 3, line 15 of the specification is replaced with “
Correct it to "C5 series".
（１２）明細書第３頁第１７行目「Ｃ系」とあるを、ｒ
Ｃ５系」と補正します。(12) The phrase “C series” on page 3, line 17 of the specification is r
Correct it to "C5 series".
（１３）明細書第４頁第２行目「Ｃ系」とあるを、「Ｃ
５系」と補正します。(13) The phrase “C series” on page 4, line 2 of the specification is replaced with “C
5 series” and correct it.
（１４）明細書第７頁下がら４行目「Ｃ系」とあるを、
「Ｃ５系」と補正します。(14) The 4th line from the bottom of page 7 of the specification says “C series”,
Correct it to "C5 series".
（１５）明細書第１０頁下がら１４行目「Ｃ石油樹脂系
」とあるを、「ｃ５系石油樹脂系」と補正します。(15) In the 14th line from the bottom of page 10 of the specification, the phrase "C petroleum resin based" will be corrected to "C5 petroleum resin based."
（１６）明細書第１０頁下がら１１行目「Ｃ系」とある
を、「Ｃ５系」と補正します。(16) On the 11th line from the bottom of page 10 of the specification, "C series" should be corrected to "C5 series."
（１７）明細書第１３頁第５行目〜第６行目「Ｃ系」と
あるを、「Ｃ５系」と補正します。(17) On page 13 of the specification, lines 5 and 6, "C series" will be corrected to "C5 series."
以 上
（別紙）
２、特許請求の範囲
（１）Ｃ５系石油樹脂を含有することを特徴とする脱毛
ワックス。Above (Attachment) 2. Claims (1) A hair removal wax characterized by containing C5 petroleum resin.
Claims (1)
ワックス。A hair removal wax characterized by containing +11 C-based petroleum resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20448383A JPS6097912A (en) | 1983-10-31 | 1983-10-31 | Wax for removal of hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20448383A JPS6097912A (en) | 1983-10-31 | 1983-10-31 | Wax for removal of hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6097912A true JPS6097912A (en) | 1985-05-31 |
| JPH052645B2 JPH052645B2 (en) | 1993-01-13 |
Family
ID=16491268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20448383A Granted JPS6097912A (en) | 1983-10-31 | 1983-10-31 | Wax for removal of hair |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6097912A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2306323A (en) * | 1995-10-16 | 1997-05-07 | Reckitt & Colmann Sa | Depilatory containing a thixotropic agent |
| WO2002011687A3 (en) * | 2000-08-10 | 2002-04-11 | Reckitt Benckiser Uk Ltd | Epilatory compositions |
| JP2008179564A (en) * | 2007-01-25 | 2008-08-07 | Nichiban Co Ltd | Anti-inflammatory and analgesic plaster |
| CN105232359A (en) * | 2015-11-04 | 2016-01-13 | 广州市德馨蜡制品有限公司 | Solid depilatory wax for human bodies, and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4980254A (en) * | 1972-12-04 | 1974-08-02 | ||
| JPS5251036A (en) * | 1975-10-22 | 1977-04-23 | Isehan Honten:Kk | Hari removal with a paste based on starchy syru |
| JPS57112315A (en) * | 1980-12-27 | 1982-07-13 | Lion Corp | Stick-like powdery cosmetic |
| JPS57163308A (en) * | 1981-03-30 | 1982-10-07 | Shin Meiwa Ind Co Ltd | Depilating wax |
-
1983
- 1983-10-31 JP JP20448383A patent/JPS6097912A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4980254A (en) * | 1972-12-04 | 1974-08-02 | ||
| JPS5251036A (en) * | 1975-10-22 | 1977-04-23 | Isehan Honten:Kk | Hari removal with a paste based on starchy syru |
| JPS57112315A (en) * | 1980-12-27 | 1982-07-13 | Lion Corp | Stick-like powdery cosmetic |
| JPS57163308A (en) * | 1981-03-30 | 1982-10-07 | Shin Meiwa Ind Co Ltd | Depilating wax |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2306323A (en) * | 1995-10-16 | 1997-05-07 | Reckitt & Colmann Sa | Depilatory containing a thixotropic agent |
| GB2306323B (en) * | 1995-10-16 | 1998-01-14 | Reckitt & Colmann Sa | Depilatory composition containing a thixotropic agent |
| US6203784B1 (en) | 1995-10-16 | 2001-03-20 | Reckitt Benckiser France | Depilatory compositions with thixotropic agents |
| WO2002011687A3 (en) * | 2000-08-10 | 2002-04-11 | Reckitt Benckiser Uk Ltd | Epilatory compositions |
| JP2008179564A (en) * | 2007-01-25 | 2008-08-07 | Nichiban Co Ltd | Anti-inflammatory and analgesic plaster |
| JP4590418B2 (en) * | 2007-01-25 | 2010-12-01 | ニチバン株式会社 | Anti-inflammatory analgesic patch |
| CN105232359A (en) * | 2015-11-04 | 2016-01-13 | 广州市德馨蜡制品有限公司 | Solid depilatory wax for human bodies, and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH052645B2 (en) | 1993-01-13 |
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