JPS6095557A - Developing method - Google Patents

Developing method

Info

Publication number
JPS6095557A
JPS6095557A JP20518883A JP20518883A JPS6095557A JP S6095557 A JPS6095557 A JP S6095557A JP 20518883 A JP20518883 A JP 20518883A JP 20518883 A JP20518883 A JP 20518883A JP S6095557 A JPS6095557 A JP S6095557A
Authority
JP
Japan
Prior art keywords
image
area
latent image
holding member
potential
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP20518883A
Other languages
Japanese (ja)
Other versions
JPH0638176B2 (en
Inventor
Masao Yoshikawa
吉河 雅雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP20518883A priority Critical patent/JPH0638176B2/en
Publication of JPS6095557A publication Critical patent/JPS6095557A/en
Publication of JPH0638176B2 publication Critical patent/JPH0638176B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/06Apparatus for electrographic processes using a charge pattern for developing
    • G03G15/065Arrangements for controlling the potential of the developing electrode

Abstract

PURPOSE:To obtain a developed image which is faithful to an original image and has no negative characteristics or negative characteristics improved greatly by performing development by using an area including an area wherein the surface potential V on a latent image holding member and image density D after the development are in relation dD/dV>0. CONSTITUTION:The latent image holding member 1 rotates in a direction (a) and is charged electrostatically uniformly by a corona charger 2 and exposed 3 to an image, and a latent image is made by a developing device 4 into a visible image, which is transferred to a transfer material 6 by a transfer charger 5. A developing bias for forming an alternating electric field is applied to the sleeve 10 of the developing device 4 from an oscillator which generates a sine-wave alternating current and a bias power source 15 composed of a DC superposing circuit. Then when the charging potential of the latent image holding member (photosensitive drum) 1 is lowered so that a dark surface potential VD is -300V and a light part potential VL is 0V, the area wherein dD/dV>0 in a V-D curve is used and an area E showing that dD/dV<0 is excluded, so that a developed image has no negative characteristics or negative characteristics improved greatly.

Description

【発明の詳細な説明】 本発明は現像方法に関し、更に詳しぐけ現像剤保持部材
表面に現像剤を保持1−1M 像(M持部材との対向位
置に該現像剤を搬送1−で現像を行なう現像方法に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a developing method. This relates to the developing method used.

従来、表面に乾式現像剤の薄層を形成した現像剤保持部
材と潜像保持部4Aとを、現像部において現像剤薄層の
厚みよりも大きな現像間隙を保持して対向させ、この現
像間隙に連続的に交互電界を形成して、現像剤の転移及
び逆転移を・繰り返し′C現像を行なう現像方法が特公
昭fi8 .32375号公報により知られていZ)。
Conventionally, a developer holding member having a thin layer of dry developer formed on its surface and a latent image holding section 4A are opposed to each other in a developing section with a development gap larger than the thickness of the developer thin layer. A developing method in which an alternating electric field is continuously formed to repeatedly transfer and reverse transfer of the developer and perform 'C development was published in the Japanese Patent Publication No. 8. Z) known from Publication No. 32375.

この現像方法によれば、地力プリがなく階調性に優J1
、細線の細りもない良好な画像が得られる。との現像方
法による潜像保持部材上の表面電位(?i!!l像亀位
)■に対する現像後の画像11NFIDの曲線(V−1
,1曲線)は一般的に第゛1図の(a)のような曲線と
なるものである。
According to this developing method, there is no ground strength and the gradation is excellent.
, a good image with no thin lines can be obtained. Curve of image 11NFID after development (V-1
, 1 curve) is generally a curve like that shown in FIG. 1 (a).

ところが、非磁性現像剤を現像剤保持部材上に薄層塗布
して、現像部において現像間隙に連続的に交互電界を形
成して現像を行なうと、第1図の6)に示すよりなV−
D曲線の得られることが判明した。これは先の一般的な
V −1)曲線(a)とけ異なり、中間電位部Bで異常
に現像が促進してγ(潜像電位に対する画像濃度の傾ト
)が高くなり、高電位部Aで画像濃度I)が低下すると
いう特性(以後この特性を負性特性と称する)となるも
のである。これでは中間調部の画像fIM壌°よりもベ
タ黒部の画像濃度の方が薄くなり、夾用に供しない。
However, when a thin layer of non-magnetic developer is applied onto the developer holding member and development is performed by continuously forming an alternating electric field in the development gap in the development section, the V −
It was found that a D curve was obtained. This is different from the general V-1) curve (a) mentioned above, in which development is abnormally accelerated in the intermediate potential area B, and γ (the gradient of image density with respect to the latent image potential) increases, and the high potential area A This is a characteristic in which the image density I) decreases (hereinafter, this characteristic will be referred to as a negative characteristic). In this case, the image density of the solid black part becomes lighter than the image fIM density of the halftone part, and it cannot be used for compensation.

本発明の目的は、上述の従来の欠点を解消し、再生画像
に現わねる現像過程での負性特性の発生を防止した現像
方法を樟供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide a developing method that eliminates the above-mentioned conventional drawbacks and prevents the occurrence of negative characteristics that appear in reproduced images during the developing process.

上記目的を達成する本発明り°、現像剤保持部材の表面
に現像剤を保持し、潜像保持部材との対向位置に搬送し
て、現像を行なう現像方法において、第1図(b)に示
したV−D曲線の負性特性を顕著には示さない領域Eを
用いるようにしたもので、具体的な一例としては該Iw
停保持部祠と該現像剤保る。それによって、現像像が悪
印象を与える程には負性特性を示さないV−1)曲線を
実現し、原画像に忠実な再生画像を得ることがで西る。
To achieve the above object, the present invention provides a developing method in which developer is held on the surface of a developer holding member and is conveyed to a position facing the latent image holding member to perform development, as shown in FIG. 1(b). The region E which does not significantly show the negative characteristics of the V-D curve shown is used, and as a specific example, the Iw
The stop holding part keeps the developer. As a result, it is possible to realize a V-1) curve that does not exhibit negative characteristics to the extent that the developed image gives a bad impression, and to obtain a reproduced image that is faithful to the original image.

ところで、上述の負性特性は、現像間隙に交互電界゛を
゛形成して非磁性現像剤の往復運動を生じさせた際、現
像剤がパウダークラウド化し、このようなパウダークラ
ウド化した現像剤の特異現像として起ζるものと推定さ
れる。即t)、現像剤はコ11゜像バイアスの周波数に
応答して往復運動を繰り返すが、高周波のバイアスを印
加1−、7’/時にit、 ’i11.像剤がバイアス
の変化に応答できず、バウタ゛−クラウド状態となりや
すい。電位の高い部分Aで一1潜像保持部材と現像剤担
持部材との間隙における現像領域内に、比較的広い幅で
現像剤の往復運動を行ない得る一種の電界カーテ/が形
成され、このカーテン内に現像剤は封じ込めらノ1エカ
ーテンの外へ離脱しにくく、り2ウドの発生は少ないも
のと考えられる。電位の低い部分I3で―子連の電界カ
ーテンの幅が狭く、このカーテンから現像剤は離脱しや
すくり之ウドの発生は多いものと考えられる。実際にコ
ピー中に交互電界を与えて現像領域幅を観察すると、電
位の高い部分Aと低い部分BとでViAよりもBの部分
の方が現glさりる幅が広く、これは上述の如くクラウ
ドの発生によって行なわれた現像である。画質的にも1
部分ではパウダークラウド現像特有のエツジ効果が目立
ったものとなる。なお、さらにA部よりも高い電位領域
CでけA領域での現象が継続されて潜像電位に依存して
画像濃度は増加するものと考えられる。
By the way, the above-mentioned negative characteristic is caused by the fact that when an alternating electric field is formed in the development gap to cause reciprocating motion of the non-magnetic developer, the developer becomes a powder cloud, and the developer becomes powder cloud. It is estimated that this occurs as a singular development. t), the developer repeats reciprocating motion in response to the frequency of the image bias; The image agent cannot respond to changes in bias and is prone to a butterfly cloud condition. A type of electric field curtain is formed within the development area in the gap between the latent image holding member and the developer carrying member at the high potential portion A, and this curtain allows the developer to reciprocate over a relatively wide width. It is thought that the developer is hard to escape from the curtain because it is sealed inside, and the occurrence of dirt is small. It is thought that the width of the electric field curtain at the low potential part I3 is narrow, and the developer easily separates from this curtain, resulting in a large number of clouds. When we actually apply an alternating electric field during copying and observe the width of the development area, we find that the developed area width is wider in the area B than in ViA between the area A where the potential is high and the area B where the potential is low, as mentioned above. This is a development performed due to the occurrence of clouds. 1 in terms of image quality
In some areas, the edge effect peculiar to powder cloud development becomes noticeable. It is considered that the phenomenon in area A continues in area C where the potential is higher than area A, and the image density increases depending on the latent image potential.

この結果、第1図のBに示した中間電位の部分では現像
される領域即ち現像幅が広がって濃度の高い現像像が得
られるが、電位の高い部分Aでは上記の電界カーテンの
影響を受けて画像濃度が低下してしまうものと考えられ
る。
As a result, in the intermediate potential area shown in B in Figure 1, the area to be developed, that is, the development width, is widened and a developed image with high density is obtained, but in the high potential area A, it is affected by the electric field curtain described above. It is thought that this causes the image density to decrease.

実験によれば、現像バイアスとして直流又は周波数応答
が十分な低周波バイアスを用いた時には、負性特性は発
生しなかった。従って、このような負性特性を防止する
には現像剤の往復運動の回数を減らせばよい。しかし、
単に現像バイアスの周波数を減じただけでは、画像濃度
が低くまた地力プリを生じて画像品質の低下をもたらす
欠点が生ずる。
According to experiments, negative characteristics did not occur when a direct current or a low frequency bias with sufficient frequency response was used as the developing bias. Therefore, in order to prevent such negative characteristics, it is sufficient to reduce the number of reciprocating movements of the developer. but,
Merely reducing the frequency of the developing bias results in the disadvantage that the image density is low and that the image quality is degraded due to the occurrence of ground curl.

そこで本発明では、印加する現像バイアスの周波数は変
えずに、第1図のBに示した中間電位の製置の高い現像
像の得られる領域が、原画像の最も濃度の高い部分と対
応するように、潜像保持部材と、現像剤担持部材との間
の交互電界を設定することによって、負性特性を示さな
い若しくけ負性特性が大幅に改善された原画像に忠実な
現像像を得ることが可能になった。
Therefore, in the present invention, without changing the frequency of the applied developing bias, the area where a developed image with a high intermediate potential as shown in B in FIG. 1 is obtained corresponds to the highest density part of the original image. By setting an alternating electric field between the latent image holding member and the developer carrying member, a developed image that does not exhibit negative characteristics or has significantly improved negative characteristics and is faithful to the original image can be obtained. It became possible to obtain.

以下図面を参照して本発明の実施例について説明する。Embodiments of the present invention will be described below with reference to the drawings.

第2図は、本発明を適用した複写装置の概略図で、光導
電層を有する潜像保持部材lは矢印a方向に回転し、コ
ロナ帯電器2で一様に帯電された後、原橋に対応する画
像無光3を受it、現像装置4によって潜像が可視像化
される。その後、潜像保持部材上の可視像は転写帯電器
5により紙等の転写材6に転写され、不図示の定着装置
によって転写材上に定着される。また、転写後の潜像保
持部材は、クリー二/グ装置7によってクリー二/グさ
れる。
FIG. 2 is a schematic diagram of a copying apparatus to which the present invention is applied, in which a latent image holding member l having a photoconductive layer rotates in the direction of arrow a, and after being uniformly charged by a corona charger 2, The latent image is made into a visible image by the developing device 4. Thereafter, the visible image on the latent image holding member is transferred onto a transfer material 6 such as paper by a transfer charger 5, and fixed onto the transfer material by a fixing device (not shown). Further, the latent image holding member after the transfer is cleaned by a cleaning device 7.

ここで、本発明の主要部分である現像装置4について詳
しく述べる。現像容器8内の磁性粒子9け、現像剤保持
部材であるスリーブ1 (lに内包されたマグネットロ
ーラ11の磁力によってスリーブ表面に吸着され、スリ
ーブ10の矢印す方向の回転によって搬送される。搬送
された磁性粒子8は、磁性体からなる規制ブレード】2
とマグネットローラ11の磁極Nの磁力とによって現像
容器8からの漏出を防止され、重力によって矢印C方向
に押し戻される。よってスリーブ10上には非磁性トナ
ー13のみが一様に薄層状に塗布され、この非磁性トナ
ー13は矢印す方向にスリーブ上を搬送されて潜像保持
部材lと対向する現像部で現像に供される。一方、矢印
C方向に循環する磁性粒子9Il−1、この循環の間に
非磁性トナー13を取シ込み、上述の循環が繰シ返えさ
れる。この非磁性トナーの薄層塗布方法に関しては本願
出願人による特願昭58−73231号に詳しいので詳
細な説明は略す。
Here, the developing device 4, which is the main part of the present invention, will be described in detail. The nine magnetic particles in the developer container 8 are attracted to the sleeve surface by the magnetic force of the magnetic roller 11 included in the sleeve 1 (l), which is a developer holding member, and are transported by the rotation of the sleeve 10 in the direction of the arrow. The magnetic particles 8 are formed into a regulating blade made of a magnetic material]2
The leakage from the developer container 8 is prevented by the magnetic force of the magnetic pole N of the magnet roller 11, and the developer is pushed back in the direction of arrow C by gravity. Therefore, only the non-magnetic toner 13 is uniformly applied in a thin layer on the sleeve 10, and this non-magnetic toner 13 is conveyed on the sleeve in the direction of the arrow and is developed in the developing section facing the latent image holding member l. Served. On the other hand, the magnetic particles 9Il-1 circulating in the direction of arrow C take in the non-magnetic toner 13 during this circulation, and the above-mentioned circulation is repeated. The method for applying a thin layer of non-magnetic toner is detailed in Japanese Patent Application No. 73231/1983 filed by the applicant of the present application, and therefore a detailed explanation will be omitted.

図中1411:磁性体からなるシール部材で、マグネッ
トロー211の磁極Sの磁力と該部材とによって現像容
器8外への磁性粒子の漏出を防止する。
1411 in the figure: A sealing member made of a magnetic material, which prevents leakage of magnetic particles to the outside of the developer container 8 by the magnetic force of the magnetic pole S of the magnet row 211 and this member.

また、15はスリーブ10へ現像バイアス電圧を印加す
るだめのバイアス電源である。
Further, 15 is a bias power supply for applying a developing bias voltage to the sleeve 10.

このような現像装置4のスリーブlOに、交互電界を形
成するだめの現像バイアスをバイアス電源15から印加
した。バイアス電源15け止弦波交流を発する発振器と
、直流重畳回路とから成り、現像バイアスの特性として
、周波数1. fl 1cllz 、ピーク対ピーク値
1.3kVp−p、これに、直流分を重畳したものを印
加した。つ捷り、上記交流条件に、直流を重畳した状態
のバイアスと、m像電位との間に、交番電界を作用させ
たわけである。
A developing bias for forming an alternating electric field was applied from the bias power supply 15 to the sleeve lO of the developing device 4 as described above. The bias power supply 15 consists of an oscillator that generates a string wave alternating current and a direct current superimposition circuit, and the developing bias has a frequency of 1. fl 1cllz , a peak-to-peak value of 1.3 kVp-p, and a DC component superimposed thereon was applied. In other words, an alternating electric field was applied between the bias in which a direct current was superimposed on the above-mentioned alternating current conditions and the m-image potential.

第1図の(b)に示した、V−D曲線は、上記現像バイ
アス条件で、重畳した直流分け、−100Vであった。
The V-D curve shown in FIG. 1(b) had a superimposed direct current division of -100 V under the above-mentioned developing bias conditions.

この時の、潜像保持部拐の暗部表面電位はVD=−55
0V、明部電位■L=0■に設定した。上述の交流条件
においては、第1図の0))に示した、V−D曲線の領
域Fを用いることとなり、これでは負性特性を顕著に示
す領域11を含むこととなる。
At this time, the dark area surface potential of the latent image holding part is VD=-55
The bright area potential was set to 0 V and the bright area potential L = 0. Under the above-mentioned AC conditions, the region F of the V-D curve shown in 0)) in FIG. 1 is used, which includes the region 11 that shows a markedly negative characteristic.

しかるに、潜像保持部拐(感光ドラム)の帯電電位を下
げて、潜像保持部材の暗部表面電位を、VD=−30Q
v、明部電位■L−0■と設定す顕著に示す領域Hを含
まないこととなり、現像像は負性特性を示さなくなるか
、又は、著しく改善される。この時、領域E′を含んで
も実用上差しつかえない。
However, by lowering the charging potential of the latent image holding member (photosensitive drum), the dark area surface potential of the latent image holding member is reduced to VD=-30Q.
The developed image does not include the region H which is clearly shown, where the bright area potential is set as . At this time, there is no practical problem even if the area E' is included.

その他の手段として、現像バイアスに重畳する直流分を
一300■に設定し、潜像保持部材の明部電位を、VL
−−200■とすることにより、同様な、効果が得られ
る。
As another means, the DC component superimposed on the developing bias is set to -300cm, and the bright area potential of the latent image holding member is set to VL.
--200■, similar effects can be obtained.

一般に、現像装置の構成(本実施例では、感光ドラム径
6’0φ、スリーブ径20<6.ドラム・スリーブ間2
50μ)で、ある帯電特性をもつ現像剤を、用いての現
像バイアスの交流条件を定めた場合において、潜像保持
部材の暗部電位VDと明部電位VL、更に現像バイアス
の直流電圧VDCの間に、 ■B:第1図Q))のV−D曲線の中間電位で濃度がM
AXを示す点における?+II像保持部材上の電位と、
現像バイアスの直流分との電位差、 ■G:第1図の低電位領域(]での桃潜像が沖、像され
ない点での潜像保持部材上の電位と現像バイアスの直流
分との電位差、 なることを満たすように、上記v 1.、v 1.、V
l)Cを設定し、潜像保持部材と、現像剤保持部材間に
印加する交番電界を作用させ−I″lげ、負t’l:特
性を示さない若しくは、著しく改!された。原rlIl
l像に忠実な、階調性に富んだ現像像が得ら11る。
In general, the configuration of the developing device (in this example, the photosensitive drum diameter is 6'0φ, the sleeve diameter is 20<6.
50μ), and when using a developer with a certain charging characteristic and setting AC conditions for the developing bias, the difference between the dark area potential VD and bright area potential VL of the latent image holding member, and the DC voltage VDC of the developing bias. , B: The concentration is M at the midpoint potential of the V-D curve in Figure 1 Q))
At the point indicating AX? +II potential on the image holding member;
Potential difference between the DC component of the developing bias and the potential difference between the potential on the latent image holding member and the DC component of the developing bias at the point where the pink latent image is not formed in the low potential area ( ) in Figure 1. , the above v 1., v 1., V
l) C is set, and an alternating electric field is applied between the latent image holding member and the developer holding member. rlIl
A developed image faithful to the original image and rich in gradation can be obtained11.

尚、現像装置は第2図に示した実施例に限らず、負性特
性を発生する現像装置でJ+ Jiげ、本発明の適用が
可能である。同様に本実施例においてa、非磁性トナー
の例を示したが、磁性トナーについても負性特性を示す
現像装置に適用可能である。
Note that the developing device is not limited to the embodiment shown in FIG. 2, and the present invention can be applied to any developing device that generates negative characteristics. Similarly, in this embodiment, an example of non-magnetic toner is shown, but magnetic toner can also be applied to a developing device exhibiting negative characteristics.

以上述べたように、本発明では■−1)曲線のは示さな
い領域を用いるように、潜像保持体と、現像剤担持体の
間の交互電界を設定することによ匂、現像像の負性性f
1の発生を改善若1.〈目防止することがでた、周波数
を低く(7たJjη合に41゛する製置の低下や、地か
ぶりの発生がどの画像品質の低下をも防止することがで
きた。
As described above, in the present invention, ■-1) the odor and the developed image are reduced by setting an alternating electric field between the latent image carrier and the developer carrier so as to use the region not shown in the curve; Negativity f
Improved the occurrence of 1. By lowering the frequency (41° in case of 7 Jjη), we were able to prevent any deterioration in image quality, including the occurrence of background fog.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は正常なV −1) [111m ト負ft: 
% fL k 示t V−0曲線のグラフ、第2図一本
発明の実施例を示す複写装置の概略図である。 図において、IVi潜像保持部拐、4 VJ現像装置、
8げ現像剤容器、9は磁性粒子、10げスリーブ、11
けマクネットローラ、12り規制ブ1/−ド、13は非
磁性トナー、14fdシ一ル部材、15げバイアス電源
、を表わす。 出願人 キャノン株式会社 シー1傳1イIfL(V )
Figure 1 shows normal V-1) [111m negative ft:
FIG. 2 is a schematic diagram of a copying machine showing an embodiment of the present invention. In the figure, an IVi latent image holding unit, 4 VJ developing device,
8 developer container, 9 magnetic particles, 10 sleeve, 11
12 represents a magnetic net roller, 12 represents a non-magnetic toner, 14 represents an fd seal member, and 15 represents a bias power source. Applicant Canon Co., Ltd. C1D1I IfL (V)

Claims (2)

【特許請求の範囲】[Claims] (1)潜像保持部祠−ヒの表IVrI市1イ會VK対す
る現像後の画像濃[1)が負性特性を示す現像装置にお
法0
(1) The image density after development [1] for VK of the latent image holding section is negative.
(2) 上記dD/dV>Oなる領域を用いるように、
該潜像保持部材と該現像剤保持部材の間に印加する現像
バイアス用交互電界を、設定したことを特徴とする特許
請求の範囲第1項記載の現像方法。
(2) Using the above region dD/dV>O,
2. The developing method according to claim 1, wherein an alternating electric field for developing bias is applied between the latent image holding member and the developer holding member.
JP20518883A 1983-10-31 1983-10-31 Development method Expired - Lifetime JPH0638176B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20518883A JPH0638176B2 (en) 1983-10-31 1983-10-31 Development method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20518883A JPH0638176B2 (en) 1983-10-31 1983-10-31 Development method

Publications (2)

Publication Number Publication Date
JPS6095557A true JPS6095557A (en) 1985-05-28
JPH0638176B2 JPH0638176B2 (en) 1994-05-18

Family

ID=16502862

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20518883A Expired - Lifetime JPH0638176B2 (en) 1983-10-31 1983-10-31 Development method

Country Status (1)

Country Link
JP (1) JPH0638176B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6132682A (en) * 1997-05-14 2000-10-17 Serim Research Corporation Test strip incubation device
US6325980B1 (en) 1998-05-07 2001-12-04 Serim Research Corporation Test strip incubation device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6132682A (en) * 1997-05-14 2000-10-17 Serim Research Corporation Test strip incubation device
US6277647B1 (en) 1997-05-14 2001-08-21 Serim Research Corp. Test strip incubation device
US6325980B1 (en) 1998-05-07 2001-12-04 Serim Research Corporation Test strip incubation device

Also Published As

Publication number Publication date
JPH0638176B2 (en) 1994-05-18

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