JPS60246725A - Cleaning cloth and knitted fabric - Google Patents

Cleaning cloth and knitted fabric

Info

Publication number
JPS60246725A
JPS60246725A JP60041992A JP4199285A JPS60246725A JP S60246725 A JPS60246725 A JP S60246725A JP 60041992 A JP60041992 A JP 60041992A JP 4199285 A JP4199285 A JP 4199285A JP S60246725 A JPS60246725 A JP S60246725A
Authority
JP
Japan
Prior art keywords
cleaning
fiber
knitted fabric
wide
woven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60041992A
Other languages
Japanese (ja)
Inventor
松井 雅男
英一 工藤
中森 強
内藤 久雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanebo Ltd filed Critical Kanebo Ltd
Priority to JP60041992A priority Critical patent/JPS60246725A/en
Publication of JPS60246725A publication Critical patent/JPS60246725A/en
Pending legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 眼鏡のレンズ、カメラその他の光学的装置、鋭及び窓カ
ラス、研磨され或いはメッキされた°金机製品、塗装さ
れた製品、高級な家具、漆器、食器。
[Detailed Description of the Invention] Eyeglass lenses, cameras and other optical devices, sharp and window glasses, polished or plated metal products, painted products, high-grade furniture, lacquerware, and tableware.

ガラス製品など各種の製品の表面は汚れのない状態が留
まれ,それらを美しく保つために清掃用の不織布金主体
とする布帛や柔らかい#.朔が使用されている。
The surfaces of various products, such as glass products, remain clean and beautiful, and in order to keep them beautiful, cleaning materials such as non-woven metal-based fabrics and soft #1 cleaning materials are used. Shu is used.

これらの清掃用布帛や紙類は,セルロース系などの天然
物由来の短繊維からなるものが多い。セルロースなどの
天然物は,カ・なシ清掃力はあるが。
Many of these cleaning cloths and papers are made of short fibers derived from natural products such as cellulose. Natural products such as cellulose have strong cleaning power.

I 強度,lt1久性の点で劣る。例えば清掃中に布帛
から繊維の断片が脱落し,逆に埃を発生することもよ〈
見られる。
I Inferior in strength and lt1 durability. For example, fiber fragments may fall off from the fabric during cleaning, creating dust.
Can be seen.

一方合成に維は、強舵,耐久性の点ですぐれているが、
6J掃力の点で劣シ、実際にはelとんど使われていな
い。
On the other hand, synthetic fibers are superior in terms of strong rudder and durability, but
6J is inferior in terms of sweeping power, and in reality EL is hardly used.

本発明の目的は、人造繊維連わCフインメ/ト力)ら容
易VC製造することが出来,且つすぐわた清掃力を市す
る新しい荀掃用織・編物を堤供するにあろう 51Jち本発明の?′i!!′偕用織・編物相識扱?F
’r Idr物と接触する面?形成する繊維の25多以
上が1を当シ5000c/を以上の表面積を南し、且つ
多角形又はそれに類似の形状,扁平率が25以上の扁平
な形状及び扁平率が25以上の扁平な部分耐組み合わせ
た形状Lシ選ば7また少l(とも1柚の横断面形状Ll
−[する広狭面積人造繊維連続フィラメントからなるこ
とケ特徴とするものである。
It is an object of the present invention to provide a new woven or knitted fabric for sweeping, which can be easily manufactured from artificial fibers and has excellent cleaning power. of? 'i! ! 'Kaiyo weaving and knitting are treated as mutual knowledge? F
'r IdrSurface that comes into contact with objects? 25 or more of the forming fibers have a surface area of 5000 cm or more, and are polygonal or similar in shape, flattened shapes with an oblateness of 25 or more, and flat parts with an oblateness of 25 or more. The combined shape L is selected from 7 and a few L.
- It is characterized by being made of wide and narrow area artificial fiber continuous filaments.

本発明名等は、多年合成繊維の研究に従事1−でいるが
、偶然判定の形状の横断面と南フ゛る繊維か極めて優れ
罠笛憧力を廟すること?見出し、詳細にその現象を追求
した結果、前記ガンス殿品等の表面?清掃する清掃力は
,に維の単位$量当シの表面積が太きく、且つ横断面が
扁平もしくは多角形である時に特に優れていることを見
出し,本発明を完成ノ/)に到ったう 例えは、通常最も工(使ゎれるボリアミド、ポリエステ
ル、ホリアクリル系などの繊維てt41#1〜fedの
内形断面の場合,表面積は工2自p1000〜3 0 
0 0 cdで、清掃力は極めて乏しい、しかし、同じ
素材ポリマーを使用しても,例えは繊度0. 5 d 
、扁平率25の扁平糸は、if当シの表面積が約120
00−であシ、清掃力は上記通常の糸の5〜20倍とい
う優nだものである。
The inventor of this invention has been engaged in research on synthetic fibers for many years, but it was by chance that the cross section of the shape and the south facing fiber were extremely excellent and had an aspirational power. As a result of pursuing the phenomenon in detail, we found that the surface of the Gans Gance item etc. It was discovered that the cleaning power is particularly excellent when the surface area per unit dollar amount of fiber is large and the cross section is flat or polygonal, and the present invention was completed. For example, in the case of the internal cross section of T41#1~fed, which is usually used for polyamide, polyester, polyacrylic fibers, etc., the surface area is T41#1~30.
0 0 cd, the cleaning power is extremely poor. However, even if the same material polymer is used, the fineness is 0.0 cd. 5 d
, a flat thread with an oblateness of 25 has a surface area of about 120 if
00-Ashi has excellent cleaning power, 5 to 20 times that of the above-mentioned ordinary thread.

ここで清掃力とは、前記ガラス製品等の表面の汚れや炒
シなど全除去する能力のことである。例えば指紋等で汚
れた鋭の面を布帛等で軽く拭った場合、灸しくなるに要
する拭う回数が少ない11とfti掃力がある。鏡の指
紋を消すには,手で軽く押さえて拭う場合、例えばティ
ッシュペーパー(柔らかい薄葉紙)で20〜30回を女
する。綿布(起毛品)で回じ<20〜30回、通常の単
糸1〜5dの円形断面の合成繊維布帛(起毛品〕でけ5
0〜100回奮戦する,これに対して本発明の製品では
例え(d数回払つ1ζた0で、多くの場合10回以下で
、指紋等を拭い去ることが出来る。
The cleaning power here refers to the ability to completely remove dirt, grime, etc. from the surface of the glass products, etc. For example, when a sharp surface soiled with fingerprints or the like is lightly wiped with a cloth or the like, there is an fti sweeping force of 11, which requires a small number of wipes to produce moxibustion. To remove fingerprints from a mirror, press lightly with your hand and wipe, for example, with tissue paper (soft thin paper) 20 to 30 times. Spin <20 to 30 times with cotton cloth (raised product), or with synthetic fiber fabric (raised product) with a circular cross section of ordinary single yarn 1 to 5 d.
In contrast, with the product of the present invention, it is possible to wipe away fingerprints, etc. in 10 times or less, with the product of the present invention wiping it off several times.

本発明者等の知見に工tLは,柚維If当シの表面積(
以下単に表面積と記ず)が大きいほど清掃力が大きい。
Based on the knowledge of the present inventors, the surface area of the yuzu fibers (
The larger the surface area (hereinafter simply referred to as surface area), the greater the cleaning power.

本発明の目的4達′fる罠めには,広表面積人準繊維の
表面積は5.0 0 0cd/f以上が必要であり、好
すしくは7000art/を以上、更に好プしくはl 
O,0 0 0ci/ 1以上、華も好1しくは1 5
、0 0 0ad/f以上の範囲である。
In order to achieve the object 4 of the present invention, the surface area of the large surface area quasi-fiber needs to be 5.000 cd/f or more, preferably 7000 art/f or more, and more preferably l
O,000ci/1 or more, preferably 15
, 0 0 0ad/f or more.

表面#(を太きくするための1つの方法は、単糸4細く
することである。例えば円形断m】、密度1、 2 緻
卯1 d O)繊維の表= & ta約3.0 0 0
 cd / fであシ、清掃力は乏しい。同じ< 0.
 3 dの場合、表面積は約5,5 0 0 crj 
/ fであろ程度の清掃力が6D.o.tdの饗,合2
、・面積は約9 6 0 0 tri / f テ清掃
力はかなシ優ねているうし力・し&度をあまシ小さくす
ることは製造技術の点からも、製品の強度、面1久性の
点からも好捷しくない。史に、繊維が破断して七れ自体
が埃となるといった1BJ題も生じる。製造技術上は、
O,OQ 1 d以上、特に001d以上か好礼しい。
One way to make the surface #( thicker is to make the single thread 4 thinner. For example, circular section m], density 1, 2 density 1 d O) fiber surface = & ta about 3.0 0 0
CD/F only, cleaning power is poor. Same < 0.
For 3 d, the surface area is approximately 5,5 0 0 crj
/f has a cleaning power of about 6D. o. td banquet, go 2
・・The area is approximately 9600 tri/f. The cleaning power is very good. Reducing the cleaning power and cleaning power is also important from the manufacturing technology point of view, as well as the strength and durability of the product. It is also not good from the point of view. Historically, 1BJ problems have arisen in which fibers break and the fibers themselves turn into dust. In terms of manufacturing technology,
O, OQ 1 d or more, especially 001 d or more is preferable.

耐久性強取の点からVio、oi(1以上、的にQ、 
l d以上が好ましい。従って円形断面では火用土& 
[1−II f* k l 、0.000 tvl /
 9以上とするには強肛面で短点がある。
In terms of durability, Vio, oi (1 or more, target Q,
ld or more is preferable. Therefore, in a circular cross section, fire earth &
[1-II f* k l , 0.000 tvl /
There is a shortcoming in terms of strong anus to give it a score of 9 or higher.

表面積を大きく′1ゐ他のh法は、繊維の横断面ヶ非円
形特に扁平にすることである。扁平率を大きくすれば、
b度をあ寸シ小びくしないでも表面積2太きぐすること
が出来、耐久性1弥変の点から好提しい。例えは、長辺
と短辺の比が10(#平+10)の矩形のS断面全市す
る繊維の場合。
Another way to increase the surface area is to make the cross section of the fibers non-circular, especially flat. If you increase the aspect ratio,
It is possible to increase the surface area by 2 times without increasing the degree of b, which is preferable from the viewpoint of durability of 1 change. For example, in the case of a fiber that has a rectangular S cross section with a long side to short side ratio of 10 (# flat + 10).

表面積はトζ肢1dて約6,000m、/r 、 0.
1 dで19000 ca / fとなり、同じに度の
円形断面の糸にくらべて、約2倍の表面積2廟する。一
般に同じ&度のS台、扁平率が大きいeよと表面積が太
きく、fr+ Eぞ1シカか太きい。
The surface area is approximately 6,000 m/r, 0.
It has a surface area of 19,000 ca/f at 1 d, which is about twice as much as a thread with a circular cross section of the same degree. In general, the surface area of the S table with the same degree of &gt; and the e type with a larger flattening ratio is thicker, and the surface area of the fr+ E type is about 1 inch thicker.

本宛IJIJ渚等の知見によれば、扁平糸は、円形や1
1°しtL m イt JThi 平率カl K 近イ
) phi、 m IC< ラヘテ、表面積の大きいこ
とから予期される以上に大きいh4掃力を4−jlる。
According to the knowledge of Nagisa et al. of IJIJ, the flat threads are circular or 1
1° and tL m it JThi phi, m IC< Rahete, the h4 sweeping force is larger than expected due to the large surface area.

その理由はよくわからないが。I'm not sure why.

恐らく、清掃さtする而に対して接触面積が大きくなり
、密層性か工い友めと考えられる。この密着性の良さは
、手で拭ったとき摩擦力が太きいと感じることからも想
像される。
This is probably because the contact area becomes larger when cleaning is performed, and this is thought to be due to dense layering or compatibility. This good adhesion can also be imagined from the fact that when you wipe it with your hand, you feel a strong frictional force.

同様に3角形、4角形等の多角形人ひヤれらに類似する
横断面を有する広狭面積人造−(維も密沿性に優れ1本
発明に好適なものである。
Similarly, polygonal shapes such as triangular and quadrangular shapes with wide and narrow areas having cross sections similar to those of human figures are also suitable for the present invention because of their excellent tightness.

勿論清掃力や密旭性を人きくするだけの目的であれば同
形成いはそれに似た形の部平率かlVc近い繊維でも充
分繊度を小ざくすれは達せらt’Lるが、扁平率の大き
い、atの比較的大きい扁平糸を用いる方が、#1久性
の点なと〃・らよシ好捷しい。この意味で扁平率は大き
いeはとよい。′A:除には柘J平率が25以上でその
効果が力・なシE!A賑に現われ、25以上、特に75
以上でその効果か題名であ/)。
Of course, if the purpose is just to improve the cleaning power and tightness, even fibers with the same shape or a similar shape with a section ratio close to lVc will not be able to achieve a sufficiently small fineness, but It is better to use a flat thread with a relatively large AT ratio and a relatively large AT value in terms of #1 durability. In this sense, e with a large oblateness is good. 'A: For exceptions, if the Tsuge J Hei rate is 25 or more, the effect is strong! A: Appears in a crowd, 25 or more, especially 75
That's the effect or the title/).

勿論柘J平率は限シなく犬さく−3ろことか出来ない。Of course, Tsuge J Heira can only do Inusaku-3 Roto without limitation.

実用的に、は40〜60か限界と渚えらtlゐ。Practically speaking, the limit is between 40 and 60.

ここで、fiTi平率とは、単糸の横断面において、最
大の長さbと、七の長き方向と直角方向のJ早みdとの
比(b/d)iいう、矩形では長辺と短辺の比である。
Here, fiTi flatness is the ratio (b/d)i of the maximum length b and the J speed d in the direction perpendicular to the long direction of the single yarn in the cross section of the single yarn, and in the case of a rectangle, the long side is the ratio of the short side.

不規則な形の長さ及び厚み?定める例?第1図に示す。Irregular shape length and thickness? An example to define? Shown in Figure 1.

1o平糸と1r31様に、(和平な(−平率25以上の
)部分が組み合わされ丸形、梅干な枝倉治する形。
1o flat thread and 1r31-like, (peaceful (-25 or more) parts are combined to form a round shape, a plum-like Edakura shape.

例えば11型、放射型などの形の横断面を肩するものも
好ましい。
For example, it is also preferable to have an 11-type or radial cross-section.

また3角形、4角形等の多角形及びそれらに類似する形
、及び不規則な形も有用であシ、それらの中でも扁平な
ものが上述の理由がら好塘しい。
Polygonal shapes such as triangles and quadrilaterals, shapes similar to them, and irregular shapes are also useful, and among them, flat shapes are preferred for the reasons mentioned above.

本発明の、織・編物は、接触面を形成する繊維に前記広
表面積人造繊維連続フィラメンtf使用する。一般に広
狭面積人造繊維は極めて柔軟であるからガラス類の清掃
用には好適である。しかしあまり柔軟すぎて扱いにぐい
、或いは耐久性などの点で、他の通常の繊維で補強する
必要があれば、広狭面積人造繊維と通常の繊維全混用し
てもよい。
The woven/knitted fabric of the present invention uses the wide surface area artificial fiber continuous filament tf as the fiber forming the contact surface. In general, wide-area artificial fibers are extremely flexible and are therefore suitable for cleaning glass. However, if it is too soft and difficult to handle, or if it is necessary to reinforce it with other ordinary fibers in terms of durability, then wide-area artificial fibers and ordinary fibers may be used in full.

しかし接触面の繊維の25重量%以上f′i該広表面積
人造繊維でなけれは1本発明の目的?達することが出来
ない。但し広表面積人造繊維?接触面を形成する繊維の
50重量%以上とすることが更に好捷しい。
However, if the contact surface is not less than 25% by weight of the fibers f'i, the large surface area of the artificial fibers is not the object of the present invention? I can't reach it. However, is it a wide surface area artificial fiber? More preferably, it accounts for 50% by weight or more of the fibers forming the contact surface.

本発明になる連続フィラメント?用い罠織優編物は、ル
ープパイル製品、カットパイル製品、起毛品々ど各種の
組織とすることが出来る。
Continuous filament according to the present invention? The trap weave knitted fabric used can be made into various structures such as loop pile products, cut pile products, and raised products.

特にパイル或いは起毛を南フるものは好】薗である。被
清掃物と接触しない部分、例えば地組織や裏面などは通
常の繊維からなっていてもよい。又繊維組織?固定した
9弾性ヶ与える工うな樹脂を付着させてもよい。又清掃
効果?補強するような界面活性剤、油類、柔軟剤ケ付看
させていても工い。尚清掃用紙・編物から切断された級
維片が脱落しない為には、カットパイル製品よシもルー
プパイル製品が好ましく、同Iじ理由で弾性的樹脂類に
よる組織の固定も好ましい。
I especially like those with a southern pile or nap. Portions that do not come into contact with the object to be cleaned, such as the ground texture and the back surface, may be made of ordinary fibers. Also fibrous tissue? A fixed elastic resin may also be attached. Also cleaning effect? Even if you add reinforcing surfactants, oils, and softeners, it will not work. In order to prevent the fibers cut from the cleaning paper or knitted fabric from falling off, loop pile products are preferable to cut pile products, and for the same reason, it is also preferable to use elastic resins to fix the tissue.

本発明の清掃用紙・編物は、広底面積人造繊維連続フィ
ラメントを使用して前記のような組織とすることが出来
る。−カ、単繊維の中Vcl釉或いは2 移J2/、上
の成分が複数のセグメント?形成しつつ接着されている
複合繊維連続フィラメントを用いて上記組織を製造し、
その後複合繊維ケ化学的及び/又は物理的方法で分割フ
ィブリル化し、広衣面私人造M維連枕フィラメントとす
ることも出来る。この複せ蝋維分割法は1表面積の大き
い製品を容易に得ることが出来る罠め極めて実用性の高
い優71.罠方法である。複合繊維の分割フィブリル化
は、一方の成分の溶剤や分解剤による溶解又は分解除去
、膨潤剤による膨潤収縮、加熱にLゐ変形や収ゐ、外力
による摩擦や打撃などの方法を用いることが出来る。
The cleaning paper/knitted fabric of the present invention can be formed into the above-described structure by using a wide base area artificial fiber continuous filament. -F, Vcl glaze in single fiber or 2 transfer J2/, is the upper component multiple segments? manufacturing the above tissue using composite fiber continuous filaments that are bonded together while forming;
Thereafter, the composite fiber can be divided and fibrillated by chemical and/or physical methods to obtain a wide-faced artificial M-fiber filament. This multiple wax fiber splitting method is an extremely practical method that allows products with a large surface area to be easily obtained. It is a trap method. Split fibrillation of composite fibers can be achieved by dissolving or decomposing and removing one component using a solvent or decomposing agent, swelling and shrinking using a swelling agent, heating with L-deformation or convergence, and friction or impact using an external force. .

第2図〜第7図は、上記目的に用いることの出来る抱合
繊維の横断面の例である。第2図及び第7図は、成分1
と成分2がはy平行な層状に複合されたもので、これを
成分lと成分2に分割すれは扁平な細い繊維が得られる
。第3図は、2成分が多数の扇形のセグメントになして
複合されている例、第4図け2成分が放射形と扇形のセ
グメン目Iして複合されている例、第5図はl成分が他
成分の中に多芯的に複合されている例、第6図は、1成
分が他成分の中に不規則な形で分散している多島海的複
合の例を示す。この他のどの↓うな複合形態でも、セグ
メントに分割可能であれは。
Figures 2 to 7 are examples of cross-sections of conjugated fibers that can be used for the above purpose. Figures 2 and 7 show component 1
and component 2 are composited in parallel layers, and by dividing this into component 1 and component 2, flat thin fibers can be obtained. Figure 3 shows an example in which two components are combined into many fan-shaped segments, Figure 4 shows an example in which two components are combined into radial and fan-shaped segments, and Figure 5 shows an example in which two components are combined into radial and fan-shaped segments. FIG. 6 shows an example of an archipelagic composite in which one component is dispersed in other components in an irregular manner. Any other complex form can be divided into segments.

末完FJAに用いることが出来る。しかし極めて扁平な
繊維?得ることができるという観点から、1iRZ図及
び第7図の工うな横断面tWする後金繊維連続フィラメ
ントが本発明には好適である。
It can be used for final FJA. But extremely flat fibers? From the viewpoint that it can be obtained, a gold fiber continuous filament having a circular cross section tW as shown in FIG. 1iRZ and FIG. 7 is suitable for the present invention.

本発明に用いることの出来、6複数の成分が層状に複@
されπF9r謂多廣繊維の具体例としては、上記の他末
完明名°等が提案し7C,%公47−14052、同4
7−40888.同47−45607、同47−497
66、同48−16449、同46−8938などの多
層繊維があり、又多tm*雑の紡糸方、法については本
発明者等の提案し罠特公昭47−15526. 同47
−15528、同44−22764、同46−2356
4、同47−15530、同47−15533、同49
−29129などがあけられる。勿論こ扛ら以外のとの
工うな方法でも分割可能な複合繊維r製造し得るもので
あれは甫いることが出来る。
The six components that can be used in the present invention are layered in a complex manner.
In addition to the above, specific examples of so-called multi-hiro fibers include 7C, %Ko 47-14052, 4
7-40888. 47-45607, 47-497
66, 48-16449, 46-8938, etc., and methods for spinning multi-tm* miscellaneous fibers were proposed by the present inventors and published in Trap Publication No. 47-15526. Same 47
-15528, 44-22764, 46-2356
4, 47-15530, 47-15533, 49
-29129 etc. can be opened. Of course, it is also possible to produce splittable conjugate fibers using methods other than those described above.

本発明に係る広敷面積人造繊維連続フィラメントは、公
知のあらゆる紡糸材が用いられる。具体的にはポリアミ
ド、ポリオレフィン、ポリビニル系、ホリアクリロニト
リル系、ポリエステル糸、ポリエーフ・ル系、セルロー
ス系などの紡糸材を用い、浴融、湿式、乾式などの紡糸
法を用いることが出来る。メチレン基、アルキレン基、
脂環基。
For the wide area artificial fiber continuous filament according to the present invention, any known spinning material can be used. Specifically, a spinning material such as polyamide, polyolefin, polyvinyl type, polyacrylonitrile type, polyester yarn, polyEFL type, or cellulose type can be used, and a bath melting, wet type, or dry type spinning method can be used. methylene group, alkylene group,
Alicyclic group.

芳香環基などの親油性の基を主成分とする親油性のポリ
マーカ・らなる広敷面積人造繊維は、指紋、手垢、油脂
に、r、ゐ汚れを除去するに有効である。
A wide-area artificial fiber made of a lipophilic polymer whose main component is a lipophilic group such as an aromatic ring group is effective in removing fingerprints, finger marks, oils and dirt, and stains.

まtcアミノ基、カルボキシル基、アミF基、スルフォ
ン基、水酸基、エーテル結合などの親水基音多量に含む
親水性ポリマーカ・らなる広敷面積人造繊維は、糖、瓢
粉類、その他の水溶性物質、水滴の除去に上動である。
The large-area artificial fibers are made of hydrophilic polymers containing a large amount of hydrophilic radicals such as amino groups, carboxyl groups, amiF groups, sulfone groups, hydroxyl groups, and ether bonds. Great for removing water droplets.

特に親油性ポリマー及び親水性ポリマーの両方からなる
広敷面積人造繊維は。
Especially large area man-made fibers consisting of both lipophilic and hydrophilic polymers.

油脂性及び水性汚れの双方?有効に除去出来−るので好
可しい、との↓つな広敷面積人造繊維は、親油性ポリマ
ーと親水性ポリマーからなる複合繊維を分割することに
↓シ容易に得られる。
Both oil-based and water-based stains? A wide-area artificial fiber, which is preferable because it can be effectively removed, can be easily obtained by dividing a composite fiber made of a lipophilic polymer and a hydrophilic polymer.

親水性ポリマーとは1例えば繊維(1デニ一ル円形l「
而)としπときの25℃65 % RHでの平衡水分率
が3%以上特に5ts以上のものであシ。
Hydrophilic polymers are 1, for example, fibers (1 denier circular shape).
) The equilibrium moisture content at 25°C, 65% RH, and π must be 3% or more, especially 5ts or more.

例えば各種ポリアミド、ポリビニルアルコール。For example, various polyamides and polyvinyl alcohol.

ポリエーテル、セルロース系などの多くのものがあけら
れ゛る。親油性ポリマーとは同平衡水分率が3−未満1
%に2%未満のものであシ、例えは多ぐのポリオレフイ
/、ポリエステルなどがあけられる。ポリビニル糸、ポ
リアクリロニトリル系などのポリマーは、親水基tもつ
モノマーを共重合すれは親水性になるが例えはポリアク
リロニトリルホモポリマーFi親油性である。
Many materials such as polyether and cellulose are available. Lipophilic polymers have an equilibrium moisture content of 3-less than 1
If the amount is less than 2%, for example, many polyolefins/polyesters, etc. can be used. Polyvinyl threads, polyacrylonitrile-based polymers, etc. become hydrophilic when copolymerized with a monomer having a hydrophilic group t; for example, polyacrylonitrile homopolymer Fi is lipophilic.

本発明の清掃用織・編物製品は、メガネ拭き。The cleaning woven/knitted product of the present invention is used to wipe glasses.

レンズ拭き、ガラス拭き、家具拭き、ピアノ鍵板拭き、
塗装面清掃用品、自動車の窓ガラス及び車体の清掃用品
、金槁表面、陶磁器(食器、美術品)床面、木材などの
清掃用品を一包含1“る。
Lens cleaning, glass cleaning, furniture cleaning, piano key board cleaning,
Includes cleaning supplies for painted surfaces, cleaning supplies for car windows and bodies, metal surfaces, ceramics (tableware, artwork) floors, wood, etc.

以下実施例に裏って本発明を具体的に説明する。The present invention will be specifically explained below with reference to Examples.

尚、実施例中「%」とあるに、%に断わシのない限シ「
重音チ」?意味する。
In addition, in the examples, "%" refers to "%" unless otherwise specified.
Juunechi”? means.

実施例工 第7図に示し友パター7の横断面を有Jる260デニー
ル/96フイラメントの複合フィラメントを溶融紡糸し
た。第7図中リセグメン)1は30℃オルンクロールフ
ェノール溶液の固有粘度が0.69のポリエチレンブレ
フタレートC以下Petと略称する)であシ、セタメン
ト2.は30℃硫酸相対粘度273の6ナイロン(以下
Nと略称する)であシ、Pet及びN共、単位セグメン
ト横断面のイ均梅干率龜約10であシ、平均に度は0.
08デニールのものヲ得た。この繊維は計算上2000
0c!d/2の広表面&乞市する。
EXAMPLE A composite filament of 260 denier/96 filament having the cross section of the putter 7 shown in FIG. 7 was melt-spun. In FIG. 7, resegment 1 is polyethylene brephthalate C (abbreviated as Pet) having an intrinsic viscosity of 0.69 in an ornchlorphenol solution at 30°C; is made of nylon 6 (hereinafter abbreviated as N) with a relative viscosity of 273 in sulfuric acid at 30°C. Both Pet and N have an average umeboshi ratio of about 10 in the cross section of the unit segment, and the average degree is 0.
I got one in 08 denier. This fiber is calculated to be 2000
0c! d/2 wide surface & begging market.

この繊維F’、 k ノ<イルとし、地糸及び抜糸は綿
糸20 S/l i用いてタオル組織のノPイル織物を
作成した。この際、糸量換算てパイル部は68チ。
The fibers were F', k, and the threads were cotton threads of 20 S/l i to prepare a towel fabric. At this time, the pile part was 68 inches in terms of yarn amount.

地糸部12チ、抜糸部20%を占める様織物設計した。The fabric was designed so that the ground threads accounted for 12 inches and the removed threads accounted for 20%.

又これと比較の為に、ノゼイル部にtj: F+丈でな
く綿糸20 S/l或いはナイロン260デニール/9
6フイラメ/ト丸断面糸を併用したもの及(ひ該綿糸及
びナイロンフィラメント単独のものを作成した。織上中
は3’8cm、目付tli33(B/iに調整した。織
上后F!使いのものについてはベンジルアルコールエマ
ルジョ/に浸漬して絞り、洗浄乾燥の各工程音道した。
Also, for comparison, tj in the nose part: cotton thread 20 S/l or nylon 260 denier/9 instead of F+ length.
A combination of 6-filament/round cross-section yarn and a single cotton yarn and nylon filament were created. The inside of the weaving was 3'8 cm, and the weight was adjusted to 33 (B/i). After weaving, F! was used. As for the ones, they were dipped in benzyl alcohol emulsion/squeezed, washed and dried.

F+に使っていない試料については精練、水洗乾燥工程
を通した。上記試用1表 1)清掃力に、鏡面VC1■/ cdの量のグリースケ
手の平で強くするようにして充分に塗り付け、30分后
に試料となる布でその面が美しくなるまで拭うに要する
1斂(50i当りフケもって表示した。
Samples not used for F+ were subjected to a scouring, water washing and drying process. Trial 1 Table 1) Add to the cleaning power a mirror surface VC1/cd of grease.Apply it thoroughly with the palm of your hand, and after 30 minutes, wipe the surface with a sample cloth until it becomes beautiful. (Displayed with dandruff per 50i.

実施例2 第2表に示すような繊度構成になる6ナイロン及びポリ
エステルミm並ひに6ナイロンとボ11エステルの複合
繊維?紡出した。第2表中抜合繊#tについては第7図
に示した。uターン横断面ケ有し、繊度及び表面積につ
いては実施例1と同様にして第2表に示す各繊維を単独
で又は併用して各柚の筒編(目付を200r/−に調節
)を製し、精練しく複合糸?市川し罠ものについては、
ベンジルアルコールエマルジョンで処理しン乾燥せる后
25℃65%恒温恒湿の状態に優待した。
Example 2 Composite fibers of nylon 6 and polyester M and nylon 6 and polyester 11 having a fineness configuration as shown in Table 2. I spun it out. The hollow synthetic fiber #t in Table 2 is shown in FIG. Each type of yuzu tube knit (with a fabric weight adjusted to 200r/-) was produced by using each fiber shown in Table 2 alone or in combination, having a U-turn cross section, and using the same fineness and surface area as in Example 1. Is it a refined composite yarn? Regarding Ichikawa's traps,
After being treated with benzyl alcohol emulsion and dried, it was maintained at a constant temperature and humidity of 25° C. and 65%.

これ等を試料として裁断し、実施mh 1と[b1様に
清掃力を計価し罠。
Cut these as samples and measure the cleaning power as per mh1 and [b1.

この結果を総括し、繊維六面積と輛掃力の関係を図示し
罠ものが第8図である。
Figure 8 summarizes these results and illustrates the relationship between the fiber area and the sweeping force.

第8図からも明らかな通シ1表面積で言えは5000f
fl/fで実用的効果が極めて明確となり。
It is clear from Figure 8 that the total surface area per square is 5000f.
The practical effect becomes extremely clear with fl/f.

10000d/lでは従来布帛ではめられない渭掃力會
持つに至る。又18000cm/P以上になると、1〜
2回軽くなでた丈で管面光輝を回復すると言った驚くべ
き効果音発現した。
At 10,000 d/l, it has a sweeping force that cannot be achieved with conventional fabrics. Also, when it becomes more than 18000cm/P, 1~
After stroking it twice, an amazing sound effect appeared that said it would restore the luster of the tube surface.

尚扁平性向の高い糸使いのもの程1表面積が大なわけで
あるが、清掃ケスト中には布と被清掃物との間に適紋の
密着性?感じ、(すべりが少ない為に)か作を繰返すの
に容易であった。
In addition, the surface area is larger for threads with a higher tendency to flatness, but in cleaning kests, there is a problem with the adhesion of the print between the cloth and the object to be cleaned. It felt easy to repeat the operation (because there was less slippage).

実施例3 混蝋或いは複合紡糸に工つて単糸繊吸2o。Example 3 Single yarn fiber suction 2o by blended wax or compound spinning.

Lo、0.5デニールのポリエステル及び6−ナイロン
の混繊率が1:1であ、6繊維倉伺平率?変化せしめて
作成した。
Lo, the blend ratio of 0.5 denier polyester and 6-nylon is 1:1, and the 6-fiber ratio is 1:1. It was created by changing it.

との組紐のセク7ヨン、檜平率及び計算上衣面第3表 第3表に示す糸k 1 o Od糸と1−で用い、目付
170り/ CMの平織物にして、オ白糾乾煉后山掃力
を評価し、第9図の結果2得た。
Using the yarn k1ood yarn shown in Table 3 and 1- of the braided cord with a section 7-yon, cypress flat rate and calculation jacket surface, make it into a plain woven fabric with a basis weight of 170 ri/cm, and dry it with white We evaluated the Lenghou Mountain sweeping force and obtained the result 2 shown in Figure 9.

第9図にJ、ゐと齢平率5以上で用最、9の?l+掃力
があることが理解できよう。父上記平織物にサンドベー
パによって起毛してτ内掃力?評価し罠ところ、全般に
やや(20%程朋)清掃力の水準が向上したう
Figure 9 shows J, I, and age average of 5 or more. You can understand that there is l + sweeping force. Is the plain fabric above my father brushed with a sand vapor and the sweeping force within τ? After evaluation, the level of cleaning ability improved slightly (by about 20%) overall.

【図面の簡単な説明】[Brief explanation of drawings]

第1図に1本発明に係る広敷面積人造繊維のhi平率を
めろ際の、長さbと厚みdの決矩方法を例示した説明図
である。第2図〜第7図は、本発明に係る爪光面積人造
繊維を得るに治した複合桓維の横断面図であるっ第8図
は、&維表面積とfrt掃力の関係?示す図である。−
!だ第9図は、秘イ維の湘平率と清掃力の関係ケ示す図
である。 出願人 痴シ、喚才赤人゛々社 第1図 第2図 第3図 第4因
FIG. 1 is an explanatory diagram illustrating a method for determining the length b and thickness d when determining the hi flatness of the wide area artificial fiber according to the present invention. Figures 2 to 7 are cross-sectional views of composite fibers cured to obtain artificial fibers according to the present invention. Figure 8 shows the relationship between fiber surface area and frt sweeping force. FIG. −
! Figure 9 is a diagram showing the relationship between the cleaning rate and the cleaning power of the secret fiber. Applicant Chishi, Kanzai Akajinsha Figure 1 Figure 2 Figure 3 Cause 4

Claims (1)

【特許請求の範囲】 1 被清掃物と接触づる面を形成する繊維の25重量%
以上が1f当シ5000−以上の表面積を有し、且つ多
角形又はそれに類似の形状、扁平率が2.5以上の扁平
な形状及び扁平率が2.5以上の扁平な部分を組み合わ
せた形状Lシ選ばれた少なくとも1種の横断面形状を有
する広狭面積人造繊維連続フィラメントからなることを
特徴とする清掃開織・編物。 2 広狭面積人造繊維が1f当、り7000−以上の表
面積を有する特許請求の範囲第1項記載の清掃用線中編
物。 3 広狭面積人造繊維が12当シ10000i以上の表
面積を鳴する特許請求の範囲第2項記載の清掃開織・編
物。 4 広表面積人造繊維が不規則な横断面を有する特許請
求の範囲第1項ないし第3項の倒れかに記載の清掃開織
・編物。 5 広狭面積人造繊維が扁平率5以上の扁平な横断面を
有する特許請求の範囲第1mないし第4項の倒れかに記
載の清掃開織・編物。 6 広宍面棟人造繊維が扁平率7.5以上の扁平な横断
面を有する特許請求の範囲第5項記載の清掃開織・編物
。 7 広狭面積人造繊維の繊度が0.01 d以上である
特許請求の範囲第1項ないし第6項の倒れかに記載の清
掃開織・編物。 8 広狭面積人造繊維が親油性ポリマー及び/又は親水
性ポリマーからなる特許請求の範囲第1項ないし第7項
の何れかに記載の清掃開織・編物。 9 広狭面積人造繊維が単繊維の中に1種或いは2種以
上の成分が複数のセグメント?形成しつつ接着されてい
る複合繊維に由来する特許請求の範囲第1項ないし第8
項の倒れかに記載の清掃開織・編物。 10 複合繊維が複数の成分が層状K1合された多層繊
維である特許請求の範囲第9項記載の清掃相識・編物っ 11 扱7H掃物と接触する面?形成する繊維の501
知−以上が広表面積人造繊維力・らなる特許請求の範囲
第1項ないし第10項の倒れかに記載の清掃用織・編物
[Claims] 1. 25% by weight of the fibers forming the surface that comes into contact with the object to be cleaned
The above has a surface area of 5,000 or more per 1f, and is a polygon or similar shape, a flat shape with an aspect ratio of 2.5 or more, and a shape that is a combination of flat parts with an aspect ratio of 2.5 or more. 1. A cleaning open-woven/knitted fabric characterized by comprising continuous filaments of wide-narrow area artificial fibers having at least one selected cross-sectional shape. 2. The cleaning wire medium knitted fabric according to claim 1, wherein the wide and narrow area artificial fiber has a surface area of 7,000 mm or more per 1 f. 3. The cleaning open-woven/knitted fabric according to claim 2, wherein the wide/narrow area artificial fiber has a surface area of 10,000 i or more. 4. The cleaning open-woven/knitted fabric according to claims 1 to 3, wherein the wide surface area artificial fiber has an irregular cross section. 5. The cleaning open-woven/knitted fabric according to claims 1m to 4, wherein the wide-narrow area artificial fiber has a flat cross section with an aspect ratio of 5 or more. 6. The cleaning open-woven/knitted fabric according to claim 5, wherein the broad-sided man-made fiber has a flat cross section with an aspect ratio of 7.5 or more. 7. The cleaning open-woven/knitted fabric according to claims 1 to 6, wherein the wide/narrow area artificial fiber has a fineness of 0.01 d or more. 8. The cleaning open-woven/knitted fabric according to any one of claims 1 to 7, wherein the wide-narrow area artificial fibers are made of a lipophilic polymer and/or a hydrophilic polymer. 9. Is there a wide/narrow area artificial fiber with multiple segments containing one or more types of components in a single fiber? Claims 1 to 8 derived from composite fibers that are bonded while being formed.
Cleaning open-woven and knitted fabrics as described in the section. 10 Cleaning knowledge/knitted fabric according to claim 9, in which the composite fiber is a multilayer fiber in which a plurality of components are combined in layers K1.11 Handling 7H Surface that comes into contact with cleaning material? 501 of the forming fibers
A cleaning woven/knitted fabric 7 according to claims 1 to 10, wherein the fabric comprises a wide surface area artificial fiber.
JP60041992A 1985-03-05 1985-03-05 Cleaning cloth and knitted fabric Pending JPS60246725A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60041992A JPS60246725A (en) 1985-03-05 1985-03-05 Cleaning cloth and knitted fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60041992A JPS60246725A (en) 1985-03-05 1985-03-05 Cleaning cloth and knitted fabric

Publications (1)

Publication Number Publication Date
JPS60246725A true JPS60246725A (en) 1985-12-06

Family

ID=12623689

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60041992A Pending JPS60246725A (en) 1985-03-05 1985-03-05 Cleaning cloth and knitted fabric

Country Status (1)

Country Link
JP (1) JPS60246725A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01149482U (en) * 1988-04-07 1989-10-17
JPH01160959U (en) * 1988-04-28 1989-11-08
JPH0266621U (en) * 1988-11-02 1990-05-21
JPH0345996U (en) * 1989-09-13 1991-04-26
JPH03128042U (en) * 1990-03-31 1991-12-24
JPH0441717A (en) * 1990-05-31 1992-02-12 Nanya Plastics Corp Partially dissolved, separated, ultrafine conjugate fiber and manufacture thereof
JPH0493055U (en) * 1990-12-27 1992-08-13
JPH06287835A (en) * 1993-03-29 1994-10-11 Kanebo Ltd Spun silk-like cloth
JP2008144313A (en) * 2006-12-12 2008-06-26 Harada Orimono Kk Wiping cloth
JP2012072515A (en) * 2010-09-29 2012-04-12 Kuraray Co Ltd Multi-island exposed-type conjugated fiber, fiber structure obtained from the fiber, and wiping tape composed of the fiber structure
WO2022131312A1 (en) * 2020-12-18 2022-06-23 東レ株式会社 Composite fiber and multifilament

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5338762A (en) * 1976-09-22 1978-04-10 Toray Industries Napped woven cloth and method of producing same
JPS53106872A (en) * 1977-10-05 1978-09-18 Toray Industries Production of fiber sheet article

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5338762A (en) * 1976-09-22 1978-04-10 Toray Industries Napped woven cloth and method of producing same
JPS53106872A (en) * 1977-10-05 1978-09-18 Toray Industries Production of fiber sheet article

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01149482U (en) * 1988-04-07 1989-10-17
JPH01160959U (en) * 1988-04-28 1989-11-08
JPH0266621U (en) * 1988-11-02 1990-05-21
JPH0345996U (en) * 1989-09-13 1991-04-26
JPH03128042U (en) * 1990-03-31 1991-12-24
JPH0441717A (en) * 1990-05-31 1992-02-12 Nanya Plastics Corp Partially dissolved, separated, ultrafine conjugate fiber and manufacture thereof
JPH0493055U (en) * 1990-12-27 1992-08-13
JPH06287835A (en) * 1993-03-29 1994-10-11 Kanebo Ltd Spun silk-like cloth
JP2008144313A (en) * 2006-12-12 2008-06-26 Harada Orimono Kk Wiping cloth
JP2012072515A (en) * 2010-09-29 2012-04-12 Kuraray Co Ltd Multi-island exposed-type conjugated fiber, fiber structure obtained from the fiber, and wiping tape composed of the fiber structure
WO2022131312A1 (en) * 2020-12-18 2022-06-23 東レ株式会社 Composite fiber and multifilament

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