JPS60204666A - Aluminum oxide base ceramic material - Google Patents

Aluminum oxide base ceramic material

Info

Publication number
JPS60204666A
JPS60204666A JP59061678A JP6167884A JPS60204666A JP S60204666 A JPS60204666 A JP S60204666A JP 59061678 A JP59061678 A JP 59061678A JP 6167884 A JP6167884 A JP 6167884A JP S60204666 A JPS60204666 A JP S60204666A
Authority
JP
Japan
Prior art keywords
oxide
aluminum oxide
weight
ceramic material
sintered body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59061678A
Other languages
Japanese (ja)
Inventor
宮田 謹一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aisin Corp
Original Assignee
Aisin Seiki Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aisin Seiki Co Ltd filed Critical Aisin Seiki Co Ltd
Priority to JP59061678A priority Critical patent/JPS60204666A/en
Publication of JPS60204666A publication Critical patent/JPS60204666A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/20Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
    • G03G15/2003Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔発明の幻象〕 本発明は、酸化アルミニウム基セラミ・ンク4A1′1
6、二関4°るもの(あり、詳しくは、高靭1:1゛を
有する酸化アルミニラJ、焼結体を得るのに好適な粉末
組成物に関する。
[Detailed Description of the Invention] [Phantom of the Invention] The present invention provides an aluminum oxide-based ceramic ink 4A1'1
6, 2-segment 4° (specifically, it relates to a powder composition suitable for obtaining a sintered body of aluminum oxide J having high toughness of 1:1).

〔本発明の利用分野〕[Field of application of the present invention]

この発明は、高靭性を有し構造部月、切削工具などに利
用される。
This invention has high toughness and is used for structural parts, cutting tools, etc.

〔従来技術およびその問題点〕[Prior art and its problems]

従来、酸化アルミニウム焼結体として、特開昭57− 
t 403 ′r 2 q公報に係るものがあり、この
ものは酸化アルミニウム=99%と残りが不可避不純物
とからなる混合粉末を焼結して得られ、この焼結体は高
硬度を有し、かつ耐摩耗性、耐食性などにもずくれてい
るが、靭性に乏しく、破壊靭性値が2〜2.5 MN−
m−”程度と低いため、構造部祠として使用するには不
適当であるという問題がある。
Conventionally, as an aluminum oxide sintered body, JP-A-57-
There is a publication related to t403'r2q, which is obtained by sintering a mixed powder consisting of 99% aluminum oxide and the remainder being unavoidable impurities, and this sintered body has high hardness, It also has excellent wear resistance and corrosion resistance, but it has poor toughness, with a fracture toughness value of 2 to 2.5 MN-
There is a problem in that it is unsuitable for use as a structural shrine because it is as low as about m-''.

〔技術的課題〕[Technical issues]

そごで、本発明は酸化アルミニウム焼結体の靭性を改善
して強度を向」二さ・lることをその技術的課題とする
ものである。
Therefore, the technical object of the present invention is to improve the toughness and increase the strength of aluminum oxide sintered bodies.

〔技術的手段〕[Technical means]

上記技術的課題を解決するノ、こめにiii& u ノ
コ技術的手段は、 酸化マグネシラJ、 : 0.5〜1重■%酸化チタニ
ウム 20.1〜0.3重量%酸化ケイ素 :0゜1〜
0.2重量% 酸化・イタ1−リウJ、Lこよる部分安定化酸化ジルコ
lニウム :8へ・15重里% 酸化アルミニウム:残r111 を含む混合粉末からなり、該混合15)末の平均径が1
μ以−「である酸化アルミニウム基1!ラミック月1′
、1を用いることである。
The technical means for solving the above technical problems are: Magnesilla oxide J: 0.5 to 1% by weight Titanium oxide 20.1 to 0.3% by weight Silicon oxide: 0°1 to
Partially stabilized zirconium oxide by 0.2% by weight of oxidation and 1-Liu J, L: 8% by weight and 15% by weight of aluminum oxide: The average diameter of the powder of the mixture 15) is 1
μ - "Aluminum oxide group 1! Lamic moon 1'
, 1.

(技術的手段の作用〕 上記技術的手段は次のよ・うに作用する。(Effect of technical means) The above technical means works as follows.

酸化“7グネンウム、酸化チタニウム、酸化ケイ素は、
焼結促進のために添加され、その添加量が多くてもある
いは少なくても焼結促進が1nわれるので、酸化マグネ
シウムを0.5〜1重量%、酸化チタニウムを0.1〜
0.3重量%、酸化ケイ素を0゜1〜0.2fffti
%の範囲で配合して用いる。
7gnium oxide, titanium oxide, silicon oxide are
It is added to promote sintering, and no matter how much or how little it is added, sintering will be accelerated by 1n, so magnesium oxide should be 0.5 to 1% by weight and titanium oxide should be 0.1 to 1% by weight.
0.3% by weight, silicon oxide 0°1-0.2fffti
% and used.

酸化、イタ1−リウム6.二よる部う)安定化ジルコニ
ウム、は靭性を向十、さ・lる作用があり、8へ用5市
量%の範囲で配合して用いることができ、8重用%未満
あるいは15重け%を越え゛ζ酸化イツトリウムによる
部分安定化酸化ジルコニウムを添加すると、破壊靭性値
が低下する。
Oxide, italium 6. 2) Stabilized zirconium has the effect of increasing toughness and can be used in a range of 8% to 5% by weight, less than 8% by weight or 15% by weight. When zirconium oxide partially stabilized by yttrium oxide is added in excess of ζ, the fracture toughness value decreases.

酸化アルミニウム基セラミック焼結体においては、破壊
エネルギーが酸化イタ1−リウムによる部分安定化ジル
コニウムの正方品から単斜晶への相変態の変態エネルギ
ーとして吸収されるか、あるいは破壊時のクラックの進
展が酸化イツトリウム添加による部う)ジルコニウムに
当たり枝分かれするピン止め効果のエネルギーとして吸
収されるために、破壊靭性値が向上するものと考えられ
る。
In aluminum oxide-based ceramic sintered bodies, the fracture energy is absorbed as the transformation energy of partially stabilized zirconium by italium oxide, which undergoes a phase transformation from a tetragonal to monoclinic crystal, or the fracture energy is absorbed as the transformation energy of the phase transformation of partially stabilized zirconium by italium oxide, or the crack propagation occurs at the time of fracture. It is thought that the fracture toughness value improves because the energy of the pinning effect that occurs when the zirconium oxide hits the zirconium and branches due to the addition of yttrium oxide.

酸化マグネシウム、酸化チタニウム、酸化ケイ素、酸化
イタ1−リウムによる部分ジルコニウム、酸化アルミニ
ウムからなる混合わ)末の平均粒径は111以下であり
、1μを越えると焼結性が急激に低下し、高強度な焼結
体がiワら机ない。
The average particle size of the powder (a mixture consisting of magnesium oxide, titanium oxide, silicon oxide, partial zirconium with italium oxide, and aluminum oxide) is 111 or less, and if it exceeds 1 μm, the sinterability decreases rapidly, resulting in high There is no strong sintered body.

本発明のセラミック材料の焼結は、1550 ’C以上
で1〜3時間行なうのが々fましい。焼結時間が1時間
より短い場合には緻密な焼結体が得られず、3時間を越
えると焼結体は過焼成になり強度低下する。
Sintering of the ceramic material of the present invention is preferably carried out at 1550'C or higher for 1 to 3 hours. If the sintering time is shorter than 1 hour, a dense sintered body cannot be obtained, and if it exceeds 3 hours, the sintered body becomes overfired and its strength decreases.

〔本発明によって生した特有のすJ果〕本発明は、次の
特有の効果を生しる。すなわら窒化ケイ素、炭化ケイ素
等の非酸化物セラミックスによ−っても本発明の前記技
術的課題を解決す/′」ことができるが、これでは原I
I :Iス1が高く、しかもセラミック焼結体の製造法
が7M VIUであるとG1う別の問題を生しる。これ
に対して不発明番、1、酸化イタ1リウムによる部分安
泰化酸化ジ)Iノ、’、’Iニウムを含有さ−lるので
あるから、製法が簡f1′(であり、容易にセラミック
焼結体が得られる。
[Special effects produced by the present invention] The present invention produces the following specific effects. In other words, non-oxide ceramics such as silicon nitride and silicon carbide can also be used to solve the technical problems of the present invention;
I: If Is1 is high and the ceramic sintered body is manufactured using 7M VIU, another problem arises. On the other hand, since the invention number 1 contains partially stabilized di)I oxide with italium oxide, the manufacturing method is simple and easy. A ceramic sintered body is obtained.

〔実施例〕〔Example〕

以F、上記技術的手段の−・具体例を示′1実施例につ
いて説明3る。
Hereinafter, specific examples of the above-mentioned technical means will be shown and an embodiment will be explained.

酸化マグネシウム:0.9重量%、酸化チタニウム20
.1重M%、酸化ケ・イ素:0.1止母%、酸化・イタ
1リウノ・による部う)安定化酸化ジ)1・二Iご−パ
フJ、;10、9 f口m%、酸化アルミニウム:88
11量シロ、それぞれの平均粒径:]、+1以下からな
る1?ラミ・ンク4旧°1の混合Il々襲こ幻して、成
形助月とし′こメチ)I/1!ルI:1−ス1.5重量
%および水を加え°C124時間ボールミル混合後、乾
燥粉砕して600 kg/cJで成形した後、1600
 ’cで2時間焼成して焼結体を得た。前記焼結体から
1法4 X 3 X 3 (1−の試験片を作成しノツ
チ法により破壊靭性を測定゛4ると6 M N−m−”
であり、従来の酸化アル札ニウム:99%と不可避不純
物とからなる酸化アルミニウム焼結体の破壊靭性値2〜
2.5 M N −m−丁と比べて著しく向上すること
がわかる。
Magnesium oxide: 0.9% by weight, titanium oxide 20
.. 1 weight M%, oxidation, silicon oxide: 0.1 stopper%, oxidation, italium oxide, stabilized di) 1,2 Igo-puff J,; 10, 9 f mouth m% , aluminum oxide: 88
11 quantities, each average particle size: ], 1 consisting of +1 or less? Raminku 4 old ° 1 mixture Il and others attack, molded Suketsuki Toshi'komechi) I/1! Le I: Added 1.5% by weight of 1-su and water, mixed in a ball mill for 124 hours at °C, dried and pulverized, molded at 600 kg/cJ,
'C for 2 hours to obtain a sintered body. A test piece of 4 x 3 x 3 (1-) was prepared from the sintered body and the fracture toughness was measured by the notch method.
The fracture toughness value of the conventional aluminum oxide sintered body consisting of 99% aluminum oxide and unavoidable impurities is 2~
It can be seen that this is significantly improved compared to 2.5 M N -m-t.

特許出願人 1イシン精116株式会社 代表有中井令夫patent applicant 1 Ishin Sei 116 Co., Ltd. Representative Reio Arinakai

Claims (1)

【特許請求の範囲】 酸化マクネノウム二0.5〜1市景% 酸化チクニ・:ノム :0.1〜0.3重量%酸化ケイ
素 二01〜0,2重量% 酸化イツトリウムによる部分安定化酸化シルJニウム 
:8〜15i景% 酸化アルミニウノ、:残部 を含む混合4′5)末からなり、該混合粉末の(11均
i’t>経かlII以下である酸化アルミニウム基1ど
シミツク祠オ″1゜
[Claims] Macnenoum 20.5 to 1% by weight Chikuni oxide: Nom: 0.1 to 0.3% by weight Silicon oxide 201 to 0.2% by weight Sil oxide partially stabilized by yttrium oxide J-nium
: 8 to 15% Aluminum oxide powder, including the remainder of the aluminum oxide group, which has an aluminum oxide group of less than
JP59061678A 1984-03-28 1984-03-28 Aluminum oxide base ceramic material Pending JPS60204666A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59061678A JPS60204666A (en) 1984-03-28 1984-03-28 Aluminum oxide base ceramic material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59061678A JPS60204666A (en) 1984-03-28 1984-03-28 Aluminum oxide base ceramic material

Publications (1)

Publication Number Publication Date
JPS60204666A true JPS60204666A (en) 1985-10-16

Family

ID=13178152

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59061678A Pending JPS60204666A (en) 1984-03-28 1984-03-28 Aluminum oxide base ceramic material

Country Status (1)

Country Link
JP (1) JPS60204666A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6483566A (en) * 1987-09-25 1989-03-29 Riken Kk Alumina-zirconia composite sintered form and production thereof
WO2005042047A1 (en) * 2003-10-30 2005-05-12 Kyocera Corporation Biological member and method for manufacture thereof
JP2005211252A (en) * 2004-01-28 2005-08-11 Kyocera Corp Biological member, method for manufacture thereof and artificial joint
JP2005239469A (en) * 2004-02-25 2005-09-08 Kyocera Corp Alumina-zirconia-based ceramic and production method therefor
JP2005239468A (en) * 2004-02-25 2005-09-08 Kyocera Corp Alumina-zirconia-based ceramic and its production method
CN100435860C (en) * 2003-10-30 2008-11-26 京瓷株式会社 Biological member and method for manufacture thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6483566A (en) * 1987-09-25 1989-03-29 Riken Kk Alumina-zirconia composite sintered form and production thereof
WO2005042047A1 (en) * 2003-10-30 2005-05-12 Kyocera Corporation Biological member and method for manufacture thereof
CN100435860C (en) * 2003-10-30 2008-11-26 京瓷株式会社 Biological member and method for manufacture thereof
US7820577B2 (en) 2003-10-30 2010-10-26 Kyocera Corporation Biomedical member and method for producing the same
JP2005211252A (en) * 2004-01-28 2005-08-11 Kyocera Corp Biological member, method for manufacture thereof and artificial joint
JP2005239469A (en) * 2004-02-25 2005-09-08 Kyocera Corp Alumina-zirconia-based ceramic and production method therefor
JP2005239468A (en) * 2004-02-25 2005-09-08 Kyocera Corp Alumina-zirconia-based ceramic and its production method
JP4601304B2 (en) * 2004-02-25 2010-12-22 京セラ株式会社 Alumina / zirconia ceramics and process for producing the same
JP4601303B2 (en) * 2004-02-25 2010-12-22 京セラ株式会社 Alumina / zirconia ceramics and process for producing the same

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