JPS59160901A - Chemical light emitting unit - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention provides a quality 1 luminescent chemistry that can be utilized in many applications.
Luminescence is when a substance brought to an excited state by the reaction between a certain oxalate ester and an oxidizing agent returns to the ground state d.
1) For example, a solution of bis(245-trichloro-6-carpophytoxyphenyl) oxalate, bis-9,10-7enylethynylandhracene dissolved in dibutyl and phthalate ( A common combination is a solution of a catalyst such as hydrogen peroxide and sodium salicylate dissolved in dimethyl hetatalate (hereinafter referred to as an oxidizing agent).

Many uses have been developed for luminescent materials that apply chemiluminescence, as they do not require a power source or do not generate heat, but conventional ones are used in a flexible plastic outer container. A breakable capsule is enclosed in the capsule, one substance that exhibits a chemiluminescent phenomenon when mixed is filled in the capsule, and the other substance is filled in a hollow container outside the capsule. Second, the flexible plastic outer container is not at all stable to chemiluminescent substances; In order to preserve and maintain the quality of products whose containers are not moisture-proof or gas-impermeable, it is necessary to introduce auxiliary agents such as sagging gel into the packaging, select the material of the bag, and seal it. This caused various problems.

The present invention aims to provide a chemiluminescent material that eliminates the above-mentioned drawbacks.

The gist is a chemiluminescent material in which two types of chemiluminescent substances that exhibit a chemiluminescent phenomenon when mixed are filled in a glass outer container in a gas-isolated state.

The present invention will be described in detail with reference to the drawings below.
has excellent moisture resistance and does not allow gas to pass through.

The outer container is made of glass, which is stable to chemiluminescent substances, and is transparent to light. For example, in addition to being colorless and transparent, the surface may be ground glass-like, a sample may be formed on one surface to create a colored pattern, or the glass may be colored by adding a pigment or the like. As shown in the figure, this outer container has an integrally sealed structure.The hollow part of the outer container has a space for containing at least one of two types of chemiluminescent substances (Al) as shown in FIG. There is a space for the other side (Bl) and a space for gas partitions. If necessary, a large number of these may be filled alternately.

Figure 2 is the same as Figure 1 υ, but the shape has changed, and Figure 4 shows the above chemical substance (AI) placed in the inner tube and placed in the outer tube (
B). The tubes shown in FIGS. 3 and 4 are both closed at one end and open at the other end. In the figure, if one of the chemiluminescent substances (AI) is oxalic acid ester, the other (Bi f1 prefecture/stopping agent).In addition to the original isolation function, gas isolation has the function of a two-liquid heating chamber. Figures 3 and 4 are examples of such gases.In addition to air, these gases include carbon dioxide, nitrogen gas, argon gas, helium gas, and combinations of these gases, and are chemically stable. Select and use.

Furthermore, the inner diameter (cavity part) of the outer container, which is the part for gas isolation, is selected to be such a size that the two types of chemical substances will not easily mix from the viewpoint of handling. In the present invention constructed as described above, the outer container is shaken in the longitudinal direction, and the chemiluminescent substance - (A) or (El) isolated by gas is released, or I'1 (A
l (Bl is replaced with gas, and both substances are mixed and reacted to cause chemiluminescence. Figures 2, 3, and 4 in the figure)
In the figure, chemiluminescence occurs in the spherical hollow S. However, the light emitting portion is not necessarily limited. The light emitting characteristics of the present invention are that the outer container is made of glass that hardly expands, so it suppresses the gas pressure of carbon dioxide gas generated as the chemical reaction progresses, and has the effect of suppressing the chemical reaction for a long time. The property of emitting light was obtained. In particular, if the internal pressure is increased from the beginning, light emission can be obtained for an even longer period of time. As described above, the skewer according to the present invention has an extremely simple structure.

No dehumidifier or other precautions are required on product packaging;
Skewers that can be stored for a long time, can emit light for an unprecedentedly long time, the high transparency of glass allows light to pass through without waste, and skewers that are aesthetically pleasing to the eye. It has a remarkable effect that is not found in other countries.

[Brief explanation of drawings]

FIGS. 1 to 4 are partially cutaway explanatory views showing examples of the chemiluminescent material according to the present invention. In the figure (I), outer glass container (Al, (Bl: 2 chemiluminescent substances, 1 remaining), Figure 2, Figure 3, and current figure.

Claims (1)

[Claims] A chemiluminescent substance formed by filling an outer glass container with two types of chemiluminescent substances that exhibit a chemiluminescent phenomenon when mixed in a gas-isolated state.