JPS59134891A - Printed circuit cleaner - Google Patents

Printed circuit cleaner

Info

Publication number
JPS59134891A
JPS59134891A JP744083A JP744083A JPS59134891A JP S59134891 A JPS59134891 A JP S59134891A JP 744083 A JP744083 A JP 744083A JP 744083 A JP744083 A JP 744083A JP S59134891 A JPS59134891 A JP S59134891A
Authority
JP
Japan
Prior art keywords
printed circuit
cleaning
substrate
water
board
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP744083A
Other languages
Japanese (ja)
Other versions
JPH0144033B2 (en
Inventor
豊 川辺
藤山 正人
足立 哲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
METSUKU KK
Original Assignee
METSUKU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by METSUKU KK filed Critical METSUKU KK
Priority to JP744083A priority Critical patent/JPS59134891A/en
Publication of JPS59134891A publication Critical patent/JPS59134891A/en
Publication of JPH0144033B2 publication Critical patent/JPH0144033B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/26Cleaning or polishing of the conductive pattern

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明はプリント基板洗浄液に関するものである。[Detailed description of the invention] The present invention relates to a printed circuit board cleaning liquid.

一般にプリント基板製造工程に1・:いては、例えばメ
ッキ鋼箔のエツチング、ハンダ剥ス1(操作、またはソ
ルダーレベラー、フェージング、ベーキング作≠等にお
いて基板に施こされるイ1ii、 lrの薬品や熱の作
用のために基板が紫色または黄(褐)色に変色し、製品
の品J低下を来す欠点がある。本発明者等はこのような
プリント基板の変色原因について探究した結果、紫色変
色の原因は端子部分を金メッキするときのメッキ浴中の
合、イオンによることかわかった。すなわちプリント基
板の端子部分を金メッキする場合に、前工程における基
板の処理液が金と反応する物質を含有しているときには
、基板に付着している処理液とメッキ浴中の金イオンと
か反応して基板上に紫色変色を生じる。
In general, in the printed circuit board manufacturing process, there are chemicals and chemicals applied to the board during, for example, etching of plated steel foil, solder stripping (operation), solder leveler, fading, baking operations, etc. Due to the action of heat, the printed circuit board discolors to purple or yellow (brown), resulting in a deterioration in product quality.As a result of our investigation into the cause of such discoloration of printed circuit boards, the inventors found that It was discovered that the cause of the discoloration was due to ions in the plating bath when gold-plating the terminals.In other words, when gold-plating the terminals of a printed circuit board, the treatment solution for the board in the previous process contains substances that react with gold. When it is present, the processing solution adhering to the substrate reacts with the gold ions in the plating bath, causing a purple discoloration on the substrate.

そしてこの紫色変色物質は基板内部まで浸透するので、
温水洗浄によっても除去することができフ5仁い。また
基板の黄(褐)色変色はハンダ剥離液中の無機酸の強い
酸化作用によりガラスエポキシ樹脂よりブよる基板が酸
化を受けることによるものと考えられる。
This purple-colored substance penetrates into the inside of the board, so
It can also be removed by washing with warm water. Further, the yellow (brown) discoloration of the substrate is thought to be due to the strong oxidizing action of the inorganic acid in the solder stripping solution, which causes the substrate to oxidize more than the glass epoxy resin.

従って本発明の目的は従来のプリント基板製造工程中に
生じる基板の変色を未然に防ぎ、従来のように一旦変色
した基板ケエメリーは−パー等やその他の俊具により長
時間をかけて除デする操作を省略することができるよう
にしたプリント基板洗浄液を提供することである。
Therefore, the purpose of the present invention is to prevent the discoloration of the board that occurs during the conventional printed circuit board manufacturing process, and to remove the discolored board, which takes a long time using a parser or other tools, as in the conventional method. It is an object of the present invention to provide a printed circuit board cleaning liquid that can omit operations.

本発明のプリント基板洗浄液は、50〜95車量%のア
ルコールエーテル系溶剤と5〜50屯卸%の水浴性アミ
ンまたは/およびアミドを含有している。
The printed circuit board cleaning liquid of the present invention contains 50 to 95% by weight of an alcohol ether solvent and 5 to 50% by weight of a water-bathable amine or/and amide.

本発明によるプリント病根洗浄液に使用するアルコール
エーテル系溶剤は基板に浸透し、水洗すると溶剤と共に
紫色変色を洗浄除去することができる。一方1.ノル板
の黄(喝)色は紫色変色よりも深く基板内部に生じてい
るのでアルコールエーテル系浴剤の浸透性だけによって
は除去づ−ろことかできない。従って黄(褐)色変色物
質でふ)る酸化された基板物質と反応してこれを中和D
YE、元するアクチベーターとして水溶性アミンまたは
アミド9を使用することに′より、黄(喝)色変色を除
去することができる。
The alcohol-ether solvent used in the printed disease root cleaning solution according to the present invention penetrates into the substrate, and when washed with water, the purple discoloration can be washed away together with the solvent. On the other hand 1. Since the yellow color of the Nord plate occurs deeper inside the substrate than the purple discoloration, it cannot be removed solely by the permeability of the alcohol-ether bath agent. Therefore, it reacts with the oxidized substrate material and neutralizes it.
By using a water-soluble amine or amide 9 as the primary activator, the yellow discoloration can be eliminated.

本発明において使用するアルコールエーテル系溶剤とし
てはエチレングリコールモノノチルエーテル、エチレン
クリコールイソアミルエーテル、エチレンクリコールモ
ノフェニルエーテル、シエチルセロンルフ、セロソルブ
アセテート、ジエチレングリコールモノエチルエーテル
、ジエチレンi リコールモノメチルエーテル等が挙げ
られる。
Examples of alcohol ether solvents used in the present invention include ethylene glycol mononotyl ether, ethylene glycol isoamyl ether, ethylene glycol monophenyl ether, ethyl seronulf, cellosolve acetate, diethylene glycol monoethyl ether, diethylene i-licol monomethyl ether, etc. Can be mentioned.

本発明において使用1−る水浴性アミンまたはアミドと
してはジエチレントリアミン、ジエチルアミン、モノエ
タノールアミン、ジェタノールアミン、トリエタノール
アミン、ブチルモノエタノールアミン、シクロヘキシル
アミン、ベンジルアミン、フェニルアミン等が挙げられ
る。
The water-bathable amines or amides used in the present invention include diethylenetriamine, diethylamine, monoethanolamine, jetanolamine, triethanolamine, butylmonoethanolamine, cyclohexylamine, benzylamine, phenylamine, and the like.

不発明のプリント基板洗浄剤によれば、紫色変色は基板
を常温で1〜2分間分間浄洗浄剤中漬するかまたは該洗
浄液を基板に噴霧することにより、また黄(イ旧色変色
は65〜40℃で1〜2分間浸漬または噴霧することに
より完全に除去される。
According to the uninvented printed circuit board cleaning agent, purple discoloration can be removed by soaking the board in the cleaning agent for 1 to 2 minutes at room temperature, or by spraying the cleaning solution onto the board. Complete removal is achieved by soaking or spraying for 1-2 minutes at ~40°C.

浸漬または噴霧を終了した基板は次いで水洗するが、水
洗時に基板の振動または洗浄水の攪拌を行うと洗浄効果
は更に大きくなる。
The substrate that has been immersed or sprayed is then washed with water, and the cleaning effect will be even greater if the substrate is vibrated or the washing water is stirred during washing.

以下の実施例によって本発明を更に具体的に説明する。The present invention will be explained in more detail with reference to the following examples.

実施例による洗浄液は銅スル−ホールプリント基板製造
の工程の次の各洗浄段階に用いた:(13ff’C,2
時間) 実施例1 次の糸+1成の洗浄gン調肥して洗浄(1+を行った。
The cleaning solution according to the example was used in each of the following cleaning steps in the process of manufacturing a copper through-hole printed circuit board: (13ff'C, 2
Time) Example 1 The next thread +1 was washed, fertilized and washed (1+ was performed).

実施例2 次のi+を成の洗浄液を調z3シて洗浄(Illを行っ
た。
Example 2 Cleaning (Ill) was performed using the following i+ cleaning solution.

実施例6 次の組成の洗浄液を調製して洗浄(lullを行った。Example 6 Cleaning (lulling) was performed by preparing a cleaning solution with the following composition.

洗浄工程(11、(Illおよび+fillを実施例1
.2および乙の洗浄液で実施したとぎに基板は全く変色
を生じtcかったが、水のみで各洗n一工程を実施した
ときには基板は紫色または黄CfF4’)色の名−しい
変色を生じt4゜またアルコールエーテル系溶剤または
アミンの創れか一方のみを用いて洗浄したときにも変色
防止効果は全く見られなかった。
Washing step (11, (Ill and +fill in Example 1)
.. When the cleaning solution of 2 and 3 was used, the substrate did not change color at all, but when each cleaning step was performed with only water, the substrate showed a notable discoloration of purple or yellow (CfF4') color. Further, no discoloration prevention effect was observed when cleaning was performed using either alcohol ether solvent or amine solvent alone.

本発明によるプリント基板洗浄液で洗浄した基板の電気
的特性は極めて良好であり、水洗しただけの基板と絶縁
抵抗試験の結果を比較すると次の通りである。
The electrical characteristics of the board cleaned with the printed circuit board cleaning solution of the present invention are extremely good, and the results of the insulation resistance test are as follows when compared with the board that was only washed with water.

表 実施例2の洗浄液により洗浄fill 8.8xlO1
27,7x1012水のみにより洗浄(Ill    
   9.5X10127.0X10”X 絶縁抵抗試
験条件:狗荷電圧:500V測定器: TOA Su、
per Megohynynttτ;MODEL 5M
−5E ンルダーレベラー条件: フラツクス二ノック社製水浴
性フラックスW−135M ハンダ:JISA級:5rL60%。
Cleaning with cleaning solution of Table Example 2 fill 8.8xlO1
Washing with 27,7x1012 water only (Ill
9.5X10127.0X10”X Insulation resistance test conditions: Voltage: 500V Measuring device: TOA Su,
per Megohynyntt;MODEL 5M
-5E ruler leveler conditions: Water bathable flux W-135M manufactured by Flux Ninok Co., Ltd. Solder: JISA grade: 5rL 60%.

ph40% ハンダ浸漬条件:24ffC,5秒間 基板の種類:Cr−1o、<を形基板 上記の結果から、本発明の洗浄液により洗浄(Illを
行ったときには、洗浄直後でも充分な絶縁抵抗値を示し
、フラックス成分が基板から充分よく除去されているこ
とがわかる。一方水抗したものでは洗浄後の加熱処理に
より抵抗値が略10倍変化していて、洗浄が充分に行わ
れてい1.(いことを示している。
pH40% Solder immersion conditions: 24ffC, 5 seconds Type of board: Cr-1o, < type board From the above results, when cleaning (Ill) with the cleaning solution of the present invention, sufficient insulation resistance was shown even immediately after cleaning. , it can be seen that the flux component was sufficiently removed from the substrate.On the other hand, the resistance value of the substrate that had been resistant to water changed by approximately 10 times due to the heat treatment after cleaning, indicating that the cleaning was sufficiently performed. It is shown that.

手続補正書 昭和5841−2  月22日 昭和58年特許願第 7440   p2 発明の名称 プリント基板洗浄液 3 補正をする者 事f1との関係 持詐出願人Procedural amendment Showa 5841-2 Month 22nd 1981 Patent Application No. 7440 p2 Name of invention Printed circuit board cleaning liquid 3 Person making the amendment Relationship with matter f1: Fraudulent applicant

Claims (1)

【特許請求の範囲】[Claims] 50〜9svt@%のアルコールエーテル系溶剤と5〜
50.14量%の水浴性アミンとからなるプリント基板
洗浄液。
50~9svt@% alcohol ether solvent and 5~9svt@% alcohol ether solvent
A printed circuit board cleaning liquid consisting of 50.14% by weight of a water-bathable amine.
JP744083A 1983-01-21 1983-01-21 Printed circuit cleaner Granted JPS59134891A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP744083A JPS59134891A (en) 1983-01-21 1983-01-21 Printed circuit cleaner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP744083A JPS59134891A (en) 1983-01-21 1983-01-21 Printed circuit cleaner

Publications (2)

Publication Number Publication Date
JPS59134891A true JPS59134891A (en) 1984-08-02
JPH0144033B2 JPH0144033B2 (en) 1989-09-25

Family

ID=11665918

Family Applications (1)

Application Number Title Priority Date Filing Date
JP744083A Granted JPS59134891A (en) 1983-01-21 1983-01-21 Printed circuit cleaner

Country Status (1)

Country Link
JP (1) JPS59134891A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4824763A (en) * 1987-07-30 1989-04-25 Ekc Technology, Inc. Triamine positive photoresist stripping composition and prebaking process
JPH0362895A (en) * 1989-07-31 1991-03-18 Kao Corp Detergent composition
JPH0397792A (en) * 1989-09-11 1991-04-23 Lion Corp Liquid detergent for solder flux
JPH0457897A (en) * 1990-06-27 1992-02-25 Kao Corp Detergent composition
JPH05179294A (en) * 1991-12-26 1993-07-20 Arakawa Chem Ind Co Ltd Cleaning remover for stain and method of removing the same
JP2006032483A (en) * 2004-07-13 2006-02-02 Seiko Epson Corp Manufacturing method of wiring circuit board
CN105331452A (en) * 2015-11-24 2016-02-17 桐城信邦电子有限公司 Washing agent of flexible printed circuit board

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4824763A (en) * 1987-07-30 1989-04-25 Ekc Technology, Inc. Triamine positive photoresist stripping composition and prebaking process
US5399464A (en) * 1987-07-30 1995-03-21 Ekc Technology, Inc. Triamine positive photoresist stripping composition and post-ion implantation baking
JPH0362895A (en) * 1989-07-31 1991-03-18 Kao Corp Detergent composition
JPH0397792A (en) * 1989-09-11 1991-04-23 Lion Corp Liquid detergent for solder flux
JPH0453920B2 (en) * 1989-09-11 1992-08-27 Lion Corp
JPH0457897A (en) * 1990-06-27 1992-02-25 Kao Corp Detergent composition
JPH05179294A (en) * 1991-12-26 1993-07-20 Arakawa Chem Ind Co Ltd Cleaning remover for stain and method of removing the same
JP2006032483A (en) * 2004-07-13 2006-02-02 Seiko Epson Corp Manufacturing method of wiring circuit board
CN105331452A (en) * 2015-11-24 2016-02-17 桐城信邦电子有限公司 Washing agent of flexible printed circuit board

Also Published As

Publication number Publication date
JPH0144033B2 (en) 1989-09-25

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