JPS5837646A - Formation of color transferred image - Google Patents

Abstract

PURPOSE:To obtain a high contrast color transferred image capable of reducing the minimum density by immersing a photosensitive material contg. a DRR (dye releasing redox) compound having a specified sulfonamidoindole as a redox center in a nonviscous developer. CONSTITUTION:A photographic element contg. a DRR compound represented by fromulaI[where Col is a dye or a dye precursor, Ball is alkylamido, arylacylamido, succinimido or phthalimido, R1 is halogen, 1-3C alkyl or alkoxy, R2 is tertiary butyl, tertiary amyl, phenyl or a group represented by formula II (where each of R3 and R4 is H or alkyl), and m is 0-3]in the photosensitive emulsion layer is brought into contact with a nonviscous alkaline processing soln. having <=100cps viscosity at 20 deg.C in the presence of a developer for silver halide, and it is dried and superposed on an image receiving element to diffusion-transfer the formed image onto the image receiving element. Thus, the contrast of the dye image can be enhanced.

Description

[Detailed description of the invention]

TECHNICAL FIELD This invention relates to color photography, and more particularly to a method of forming a color transfer image that forms a color image with improved photographic properties by a color diffusion transfer process. As a method for forming a color transfer image, a so-called color diffusion transfer method using a dye image forming substance is known. No. 53-3819, No. 54-54021, No. 54-
No. 130122 and other publications disclose a diffusion transfer method using a non-diffusible dye-releasing redox compound in which a product oxidized by silver halide reacts with a color image-forming substance to release a diffusible dye. It is being done. The diffusion plate method 7 is intended for use in self-developing cameras to obtain sufficient color diffusion transfer images within a short period of time, and has been embodied in commercially available films. These films consist of two dimensionally stable supports, at least one of which is transparent, between which there is at least one light-sensitive silver halide emulsion layer in combination with a dye-receiving layer and a dye-image-giving material. The films are superimposed and at least one end of the superposition is fixed to provide a laminated integral film unit for convenient handling through image exposure, development, and viewing of the completed image. One embodiment of an integrated color diffusion transfer film unit and color diffusion transfer wR imaging method is disclosed in Canadian Patent No. 928,559. In this embodiment, the support of the photosensitive element is It is transparent and coated with a sensitive layer, a light reflecting layer, an opacifying layer and a photosensitive layer.Alkaline processing compositions and opacifying agents such as those described above, such as carbon black, is located adjacent to the top layer of the photosensitive element and a transparent cover sheet, the cover sheet comprising a transparent support having a neutralizing layer and a timing layer. This film unit is placed in a camera, exposed through a transparent cover sheet, and then
Next, when taking out the film unit from the camera, the film unit is taken out from between a pair of pressure means built into the camera. The pressure means ruptures the container, thereby spreading the processing composition and opacifying agent contained in the container onto the imaging portion of the film unit (thus preventing exposure of the film unit). . The processing composition develops each of the silver halide layers and a dye image is formed as a result of development. The formed dye image then diffuses into the image-receiving layer to create a positive image. This normal image can be viewed through a transparent support with an opaque reflective layer as a backing. Another example of an integrated color diffusion transfer film unit and color diffusion transfer imaging process is described in U.S. Pat. No. 3,415,644. In this embodiment, the photosensitive element includes an opaque support coated with a photosensitive layer in combination with a dye image-providing material. A rupturable container containing an alkaline processing composition as described above, TλO1, and an indicator dye (see U.S. Pat. No. 3,647,437 for details) is used to coat the top layer of the photosensitive element and located adjacent to the transparent image receiving element. The receptor element includes a transparent support, which includes a neutralizing layer;
A timing layer and an image receiving layer are coated. This film unit is housed in a camera, and when the film unit is taken out from the camera 5-1, light is emitted through the transparent image receiving element, and then from between a pair of pressure means built into the camera. Take out the film unit. The container is ruptured by means of pressure, thus
Treatment composition, T10. and the indicator dye is spread over the image forming part of the film unit (thereby preventing exposure of the film coat unit). The spread processing liquid composition images each of the silver halide layers, and a dye image is formed as a result of development. The image formed in this way is diffused into the image-receiving layer, and is therefore placed on a white background (the indicator color chart has shifted by one to a colorless state since the alkali has been consumed by the neutralization layer). Further useful configurations are disclosed, for example, in U.S. Pat. No. 3,362, numbered here for reference only.
, No. 819, No. 3.415,645, No. 3.41 of the same
No. 5,646, No. 2,983,606, No. 2,5
No. 43,181, No. 3.647,437, No. 3,
No. 635,707, British Patent No. 1,330.524, and Canadian Patent No. 674,082. In these films, the processing composition is supplied in a highly viscous form and is adapted to be exposed or spread between a light-sensitive element and a receiving element to form a layer therebetween. Generally, the treatment compositions contain sodium, carboxymethylcellulose, or hydroxyethylcellulose film-forming agents, ie, viscosity-increasing substances, and are applied using rupturable containers or bags. When a processing composition containing such a viscosity-increasing substance is used to spread the processing composition between a photosensitive element and an image-receiving element or between a photosensitive sheet and a processing sheet, the oxidized developer generated in the developing section In the former type of film, a part of the diffusible dye formed from the non-diffusible dye image-forming material through a cross-oxidation reaction with It is known that the image quality of the final transferred image is significantly degraded due to the enlargement of the distance between the photosensitive element and the image receiving element by the Ti1l agent layer. The exposed photosensitive element is immersed in a non-viscous processing composition that does not contain the film-forming agent for a predetermined period of time, during which time the photosensitive element absorbs a relatively small amount of the processing composition and is then wetted. Imaging processes are known in which a photosensitive element and a dry image-receiving element are brought into front-to-front contact to obtain a color diffusion transfer image without the presence of a layer of processing composition between the photosensitive element and the image-receiving element. For example, British Patent No. 1,496,
No. 363 discloses that a photosensitive element comprising a non-diffusive sulfonamide compound which releases a diffusive color patch as a result of a redox reaction of the oxidized form of am produced by development of silver halide with a dye-releasing redox compound is exposed; A processing method is described in which the exposed light-sensitive element is dipped in a non-viscous processing composition and superimposed with an image-receiving element upon or after wetting. In such a dipping process, a viscous processing agent consisting of the film-forming agent is spread between a photosensitive element and an image receiving element, or between a photosensitive sheet and a processing sheet using a container or bag; Normally, the photosensitive element is coated with a non-viscous alkaline processing agent in a container that retains all of its properties.

[7] Since the processing is carried out by immersing it in a dish, when a photosensitive element made of a dye image-providing substance that is easily oxidized by air is subjected to immersion processing, the minimum density Dm1η corresponding to the undeveloped area is high. There was a drawback. In particular, non-diffusible dye-releasing redox compounds exhibiting a fast rate of dye release, high silver utilization efficiency, and excellent properties with respect to the discrimination of the images formed, e.g. US Patent No. 4
, 135, 929 @, the DRR compound having a ballast group consisting of an N,N-disubstituted carbamoyl group and having a sulfonamide phenol or sulfonamide naphthol as a redox center is extremely sensitive to air oxidation, and is extremely susceptible to air oxidation. When processing with a large value is performed, it is difficult to provide a sufficiently low minimum density Dmin, and it is difficult to obtain a final printed image of good image quality. SUMMARY OF THE INVENTION An object of the present invention is to provide a method for forming a color transfer image that has excellent minimum density, high discrimination, and provides a clear transfer image. 91 A further object of the present invention is to provide a method for forming a color transfer image that does not increase the minimum density even when immersed in a non-viscous alkaline processing liquid. The present inventors have discovered that a photosensitive element comprising a DRR compound represented by the following general formula [1] satisfies the above objects. General formula (II) In the formula, aol represents a dye or a dye precursor, and examples of the dye include azo dyes, azomethine dyes, indoaniline dyes, indophenol dyes, anthraquinone dyes, triphenylmethane dyes, and insico dyes. , or these metals #! ! Examples include salt, etc. Examples of dye precursors include known leuco dyes and those that produce dyes by hydrolysis, and these are disclosed in Japanese Patent Application Laid-Open No. 55-331.
No. 41, No. 55-33142, No. 53-35533, No. 55-53329, No. 48-125818, and disclosed in U.S. Pat. In order to prevent it from being diffused or washed away in its original form by the alkali used during the processing of the photosensitive element, it is necessary to provide a ballast group that will substantially diffuse or wash out and eliminate it. However, Ba1lG'j represents an alkyl acylamide group, an arylacylamide group, a rifushiimide group, and a phthalimide group, and R1 represents a halogen atom or an alkyl group or alkoxy group having 1 to 3 carbon atoms. The alkyl group of the alkylacylamide group represents a straight chain or branched alkyl group having 12 to 20 carbon atoms, and the aryl group of the arylacylamide group represents an alkyl group, alkoxy group, or alkyl group having 5 to 20 carbon atoms. It is preferable to represent an aryl group substituted with an acylamido group or an alkylsulfonamide group. Also, each of the succiimide group and the phthalimide group is an alkyl group having 5 to 20 carbon atoms, an alkoxy group, an alkylacylamide group, or an alkylsulfonamide group. R1 is preferably substituted by a group. R1 is a tert-butyl group, a tert;-amyl group, a phenylated or halogen atom, an alkyl group or alkoxy group having 1 to 2 carbon atoms, an acetylamide group, a methylsulfonamide group. , a nitro group, a carboxyl group, a sulfo group, and a methylsulfo group. m represents an integer of O to 3. Suitable for the method of forming a color transfer image of the present invention. Examples of RR compounds are shown below, but the present invention is not limited thereto. , ＼ ○ ＠ O e ■ O■
@ @ 目■ ■ θ [Stock] ■15
- ■ @ ■0 0 Country Taguri [Ao] ■ o @ . The indole compound of the present invention is characterized by the bonding position of the ballast group.
No. 52-135730, No. 53-46730,
Unlike the indole compound described in No. 54-130122, it is bonded to the 5th or 6th position of the indole ring, but as a result, it has the effect of efficiently releasing the diffusible dye. Although the exact reason is unknown, the inventor thinks about this as follows. In the compound of the present invention, the release mechanism of NH,5o200A' is as shown below.
on [II is oxidized and becomes the quinone diimine structure side,
It is thought that it then undergoes hydrolysis with alkali. The compounds of the present invention have a ballast group of -NH8O,0oIl
By positioning it sterically far away from 21-, it is possible to facilitate OHe's attack on the 10=N- carbon atom on the oxidant side. In this way, η is interpreted to have an important meaning in achieving the above-mentioned excellent effects. U.S. Pat.
We have discovered the completely unexpected property that while exhibiting the same performance as the DRR compound described in US Pat. No. 5,929, final printed images with lower minimum density are obtained. Conventionally, in order to improve the instability of DRR compounds against air oxidation, long-chain alkylhydro dt/n derivatives, M, N
- DRR of reducing compounds such as disubstituted hydroxylamine
Although the DRR of the present invention has been added to the layer containing the compound,
This is not necessary when using compounds. Compared to the viscous processing method, the immersion processing method uses a non-viscous processing solution that is easily susceptible to air oxidation, and the use of a photosensitive dye consisting of a DRR compound having a sulfonamide indole as a redox center is very advantageous. It became clear that In a preferred embodiment of the invention, for example, by passing the exposed photosensitive element through a container of processing solution,
The processing solution is absorbed into the exposed photosensitive element from the non-viscous processing solution. Other techniques can also be used that allow the required small amounts of processing solution to be applied virtually uniformly over the surface of the negative, such as those described in U.S. Pat. No. 3,194,13
A liquid application device with a capillary gap through which the processing solution passes, as disclosed in No. 8, may be used. The required amount of processing solution is applied from the viscous processing composition to the sensitizer, provided that there is no layer of polymer or processing composition between the light-sensitive element and the image-receiving element when they are later superimposed. It is also possible to absorb it into the elements. However, it is preferred to use non-viscous processing solutions, as this allows the use of very simple processing equipment and handling techniques. Despite the specialized techniques for delivering processing solutions to the photosensitive element, the image receiving element is kept dry until it comes into front-to-front contact with the wetted photosensitive element, so that the image receiving element inevitably is wetted only with processing solution extracted from the photosensitive element. The expression "front-to-front contact" is used herein to indicate that there is no layer of processing composition between the superimposed photosensitive element and image receiving element. As used herein, the expressions "non-viscous processing solution" and "non-viscous processing composition" are intended to refer to a processing solution or composition having a viscosity substantially similar to water. be. Preferably 100 at 24'C
It has a viscosity of 10 ops or less, more preferably 10 ops or less. Non-viscous processing compositions do not contain polymeric film-forming substances or other viscosity-imparting components such as those used in commercially practiced color diffusion transfer processes. Generally, non-viscous processing solutions suitable for use in the present invention are obtained from processing compositions of the type described in the prior literature by simply removing the film-forming agent. In some cases, such non-viscous compositions transfer the partially solidified darkness of the processing composition to the other parts of the M-formed photosensitive element and image-receiving element when the elements are removed from superimposed relation. It may also contain a reagent whose primary function is to facilitate bonding, and since this function is not utilized in the method of the present invention, such a reagent may be omitted. In some cases, the new processing techniques of the present invention allow the concentration of one or more agents in a treatment composition to be reduced compared to the concentration when the agent is used in a viscous treatment composition. It became. The particular concentration of a given agent to be used in a non-viscous treatment composition can be readily determined by one skilled in the art by performing routine concentration tests. As previously pointed out, the non-viscous processing composition can be applied to the photosensitive element in a number of ways, such as by the block or head of a porous application device; by transferring the exposed photosensitive element to a container of the non-viscous processing composition; This can be done by dipping the exposed photosensitive element into a liquid or by passing the exposed photosensitive element through a container of the non-viscous processing composition. 51 Methods for bringing the non-viscous processing composition into contact with the photosensitive element according to the present invention include a method of immersing it in an alkaline processing bath, a method of spraying it onto the photosensitive element, a method of supplying it by brushing, etc. For example, U.S. Patent No. 3,103,15
No. 3, No. 3,112,685 x No. 3.195,4
No. 35, No. 3,626,832, No. 3,695,
No. 163 discloses an image forming apparatus in which a photosensitive element is passed through a tank or container holding a processing composition, and then the photosensitive element is pulled out from the container and pressed onto an image receiving element at the same time or after that to bring the image into front-to-front contact. There are descriptions of transfer processor devices and these devices can be utilized in carrying out the present invention, but in particular U.S. Pat.
Preferably, processing is performed using an image transfer processor of the type described in No. 223,991. Referring to the drawings, FIG. 1 shows that a vitrified photosensitive element 1 is immersed in a container 5 of a non-viscous processing solution 7 for a certain period of time, then taken out from the container and placed together with a dry image-receiving element 3 on a pressure roller 9.
and 11 to indicate front-to-front contact. - the pressure rollers 9 and 11 are connected to the photosensitive element 1 and the image receiving element 3;
Since the polymer consisting of 15 sheets is only pressed, the pressure roller 9 and 11 may be of simple structure and equipment. A squeegee or other device may be provided to remove excess processing solution from the front and/or back surface of the photosensitive element as it is withdrawn from the processing solution 7 prior to superimposing the photosensitive element onto the dry receiver element. In order to ensure that the tips and side edges of the photosensitive element and the image receiving element pass between the pressure rollers 9 and 11 without misalignment, the tips of the photosensitive element and the image receiving element are shifted in advance before passing between the rollers. A processor having such an arrangement in which it is desirable to align the leading edges of the photosensitive element and image receiving element upon insertion into the holding roller is described in the aforementioned U.S. Pat. No. 4,223.991. The preferred construction of the image receiving element and the photosensitive element is shown in detail in superimposed relative position in FIG. The image receiving element 3 has an image receiving layer n
It consists of a support layer 21 that supports the. Photosensitive element 1 includes a layer 33 of cyan dye-releasing redox compound.
, red-sensitive silver halide emulsion layer description, intermediate layer 37, magenta dye-releasing redox compound #39, green-sensitive silver halide emulsion layer 41, intermediate layer 43, yellow dye-releasing redox compound layer 45, and blue-sensitive halogen It consists of a support layer 31 supporting a layer 47 of silver oxide emulsion. The coating rate of the dye-releasing redox compound used in the present invention is preferably 2X
It is 10 to 2×10 mola/75. The dye-releasing redox compound used in the present invention can be dispersed in a hydrophilic colloid carrier by various methods depending on the type of compound. For example, a compound having a dissociable group such as a sulfo group or a carboxyl group can be dissolved in water or an alkaline aqueous solution and then added to the hydrophilic colloid solution. A dye-releasing redox compound, which is difficult to dissolve in aqueous media but easy to dissolve in organic solvents, is dissolved in an organic solvent [
. Add the resulting solution to the hydrophilic colloid solution and disperse it into fine particles by stirring. Suitable solutions include ethyl acetate, tetrahydrofuran 1-methyl ethyl ketone, cyclohexone, β-butoxy-β-ethoxyethyl acetate, dimethylformamide, dimethyl sulfoxide, 2-methoxyethanol, tri-n-butyl phthalate, and the like. . Among these dispersing solvents, those with relatively low vapor pressures are either volatilized during drying of the photographic layer, or used in U.S. Pat.
．． It can also be volatilized by a method such as that described in No. 801171. Among these dispersion solvents, those that are easily soluble in water are listed in U.S. Patent No. H1+ No. 2,949,360 and No.
, 396,027. Incorporation with a dye-releasing redox compound into a photographic element in a solvent that is substantially insoluble in water and has a boiling point above 200° C. at normal pressure to stabilize the dispersion of the dye-releasing redox compound and facilitate the dye image forming process. is advantageous. Suitable high-boiling solvents for this purpose include triglycerate tetralides of higher fatty acids, aliphatic esters such as di-octyl adipate, phthalate esters such as di-n-butyl phthalate, tri- 2. Nisder phosphates such as l/dyl phosphate, tri-n-bovine syl phosphate, amides such as N,N-diethyl laurylamide; 2.
Examples include 4-di-n-amylphenol and droxy compounds. It is advantageous to incorporate a philic polymer with the dye-releasing redox compound in the photographic element to generally stabilize the dispersion of the dye-releasing redox compound and to facilitate the dye image formation process. Philic polymers suitable for this purpose include shellac; phenol-formaldehyde condensates; poly-n-butyl acrylate; copolymers of n-butyl acrylate and acrylic acid; n-butyl arylate, copolymers of styrene and methacramide. There are things etc. These polymers may be dissolved in an organic solution together with a dye-releasing redox compound and then dispersed in a hydrophilic colloid, or they may be prepared by emulsion polymerization or other means into a hydrophilic colloid dispersion of a dye-releasing redox compound. Hydrosils of the polymers may also be added. Dispersion of color patch releasing redox compounds is generally achieved very effectively under high shear forces. For example, high-speed rotating mixer, colloid mill, high-pressure milk homogenizer, British Patent Nos. 1 and 3
A high-pressure homogenizer, an ultrasonic emulsifier, etc. disclosed in Japanese Patent No. 04,264 are useful. Surfactants that are useful as a fraction of the dye-releasing redox compounds used in the present invention include sodium triisopropylnaphthalene sulfonate, sodium dinonylnaphthalene sulfonate,
There are anionic surfactants such as p-dodecylbenzenesulfonate sodium, dioctylsulfosuccinate φ sodium salt, cetyl sulfosuccinate sodium salt, and anionic surfactants disclosed in Japanese Patent Publication No. 39-4293@, and these anionic surfactants and anhydro The combination of xytol with higher fatty acid esters shows particularly good emulsification, as disclosed in US Pat. No. 3,676,141. The silver halide developer used in the present invention can be contained in an alkaline processing liquid or in any layer of the L1-sensing element or image-receiving element, and is not halogenated until the alkaline processing liquid is supplied. It can also be made to act on silver emulsions. Examples of silver halide developers that can be used at °C in the present invention are as follows. Hydroquinones, amine phenols [(e.g. N-
methylaminophenol), 3-bilane IJ-,)nones (e.g., 1-pheny-3-pyrazolidinone, 1
-phenyl-4,4-dimethyl-3-pyrazolidinone,
4-hydroxymethyl-4-methyl-1-phenyl-3
-pyrazolidinone, 4-hydroxymethyl-4-methyl-1-)IJsil--pyrazolidinone), phenylenediamines ((e.g. Eva, N, N-diethyl-p-
7zNylene diamine, 3-methyl-N,N-diethyl-
Among the ones listed here, black and white, such as p-phenylenediamine, 3-methoxy-N-ethoxy-p-phenylenediamine), and reductones, generally have properties that reduce stain formation in the image-receiving layer (mordant layer). Developers are particularly preferred. A silver halide developer can be incorporated into the photosensitive element or the image receiving element as disclosed in, for example, JP-A-55-5333.
Preferably, it is a precursor such as that described in British Patent No. is desirable. The processing composition used in the present invention is a liquid composition containing processing components necessary for developing a silver halide emulsion and forming a diffusion transfer dye image, and the solvent is mainly water and methanol is also used. may also contain hydrophilic solvents such as methyl cellosolve. The processing composition has a pH of 1! which is necessary to cause development of the emulsion layer. - Acids formed during the process of maintaining, developing and dyeing images (e.g. hydrohalic acids such as hydrobromic acid,
Contains a sufficient amount of alkali to neutralize carboxylic acids such as acetic acid, etc. As an alkali, lithium hydroxide,
Alkali metal or alkaline earth metal salts such as sodium hydroxide, potassium hydroxide, calcium hydroxide dispersion, tetramethylammonium hydroxide, sodium carbonate, trisodium phosphate, -o- diethylamine, or amines are used, Preferably) It is desirable to contain a caustic alkali at a concentration such that it has a pL of about 12 or more at room temperature, particularly a pH of 14 or more. The silver halide developer can be initially incorporated into the photographic element in what is commonly referred to as a activator solution (agents and preservatives). The activator solution is identical in composition to the silver halide developer solution except for the absence of silver halide developer, and is used when incorporating the silver halide developer into the photographic element. References hereinafter to developer compositions are intended to include both silver halide developer solutions and activator solutions. The processing composition may also contain light-absorbing substances such as carbon black and pH indicator dyes to prevent fogging of the silver halide emulsion by external light during processing, and U.S. Pat. No. 3,579. It may be advantageous in some cases to contain desensitizers such as those described in No. 333. Furthermore, a development inhibitor such as benzotriolizole can be added to the processing liquid composition. In addition, the present alkaline processing composition may contain substances that promote development or dye diffusion, such as benzyl alcohol, glycols and/or amino alcohols described in JP-A-52-127233, and JP-A-55-1989. -745
A compound such as a saturated aliphatic alcohol or a saturated alicyclic alcohol described in No. 41 may be included. In particular, it is preferable to contain fatty acids and aliphatic primary amines such as 11-aminoundecanoic acid and/or 6-aminohexanoic acid described in JP-A-53-81119. In addition, in order to improve the immersion properties of the processing agent components, for example, Research Disclosure 19565, 19566L4
A buffering agent may be added. A preferred multilayer structure of the film unit of the present invention is one in which a blue-sensitive emulsion layer, a green-sensitive emulsion layer, and a red-sensitive emulsion layer are coated in this order from the exposed side, with a layer between the blue-sensitive emulsion layer and the green-sensitive emulsion layer. A yellow filter counterfeit may be placed. If necessary, the selectively sensitized silver halide emulsion layers can be arranged in a different order, for example, all of the blue-sensitive layer, red-sensitive layer, and green-sensitive layer from the exposed side. When carrying out the multicolor color diffusion conversion η method, it is advantageous to use an interlayer in the film unit. The middle layer is made of gelatin, polyacrylamide,
From hydrophilic polymers such as calcium alginate, partially hydrolyzed polyvinyl acetate, hydroxypropyl cellulose, as well as latexes of hydrophilic and hydrophobic polymers as described in U.S. Pat. No. 3,625,685. Composed of a polymer with pores formed. Additionally, to eliminate oxidized silver halide developer and prevent it from migrating into other color-forming units and forming undesirable dyes, see, e.g., U.S. Pat.
No. 6,327, No. 2.360,290, No. 2.4
No. 03,721, No. 3,700,453, JP-A-4
Color mixing inhibitors such as dihydroxybenzene derivatives described in No. 6-2128 and other dihydroxynaphthalene derivatives, aminonaphthol derivatives, sulfonamide phenol derivatives, and sulfonamide naphthol derivatives are added to the intermediate layer. The silver halide emulsion layer used in the present invention comprises photosensitive silver halide dispersed in gelatin and has a thickness of about 0.6 to 6 microns. D.R.R.
The compound is in a separate layer having a thickness of about 1 to 7 microns and is dispersed in a polymeric binder, such as gelatin, permeable to an aqueous alkaline solution. The intermediate layer is, for example, a layer of gelatin approximately 0.5 to 5 microns thick.Of course, these thicknesses are only approximate and can be varied arbitrarily according to the desired product. Commonly useful photographic supports include polymeric films, wood fibers such as paper, metal sheets and foils, glass, and ceramic support elements, and the adhesive strength of the support surface. Antistatic properties, dimensional stability, peeling resistance,
It has one or more subbing layers to enhance hardness, frictional properties and/or other properties. Common useful polymeric film supports include films of cellulose nitrate and hiscel p-suesters, e.g. evacellulose triacetate and diacetate, polystyrene, polyamide, homo- and copolymers of vinyl chloride, poly(vinyl acetal). ), polycarbonates, homo- and copolymers of olefins, such as polyethylene and polypropylene, and polyesters of dibasic aromatic carboxylic acids and dihydric alcohols, such as poly(ethylene terephthalate). Useful paper supports typically include partially acetylated or heavy polyolefins of baryta and/or polyolefins, especially alpha-olefins having from 2 to 10 carbon atoms. Polymers such as polyethylene, polypropylene, copolymers of ethylene and propylene, etc. are coated together. Particularly useful supports constituting image-receiving elements are those that provide a good background for the image, and are preferably about 8
It is preferable to have a reflectance of 0φ or more. Habitually: 7
．． li: Preferably, the FR film contains white pigments such as TlO2, kaolin, ffj (IJ, barium sulfate, zinc oxide, etc.).Furthermore, the silver halide photosensitive layer) Y, for example, should be researched to avoid fogging. The support VC can also be subjected to an opaque treatment as described in Disclosure No. 18336. The polymeric mordant used in the dry image-receiving element of the present invention is:
Polymers containing secondary and tertiary mino groups, including (j4. y
Polymers with a heterocyclic moiety, polymers containing these quaternary cation groups, etc. with a molecular weight of 5,000 to 200,00
0, special K 10,000 to 50,000. For example, US time fi: ur 2,548,564, same! Vinylpyridine polymers and vinylpyridinium cationic polymers disclosed in Patents No. 2,484,430, No. 3,148,061, No. 3,756,814, etc., and vinylpyridinium cationic polymers; No. 2,675,316 Polymer containing a dialkylamino group disclosed in the specification;
Aminoguanidine derivatives disclosed in Specification No. 82,156; No. 3,625,694, No. 3,859,0
No. 96, No. 4,128,538, British Patent No. 1
, 277.453, etc.; a polymer mordant capable of crosslinking with gelatin, etc.; U.S. Patent M 3,95
No. 8,9915, No. 2.721,852, No. 2,
Aqueous sol-type mordant disclosed in No. 798,063 Specification 8 etc.; water-insoluble mordant disclosed in No. 3,898,088; furthermore, No. 3,709,690;
Same No. 3,788.85f5, Same No. 3,642,482
No. 3,488,706, No. 3,557,06
No. 6, No. 3,271,147, I! ! 3,27
1. L48, JP 50-71332, JP 53-3
No. 0328, No. 52-155528, No. 53-125
No. 53-1024, No. 54-74430, No. 5
No. 4-124726, No. 55-22766, No. 55-
Specification of No. 142339: %1: may be mentioned. If a pH lowering material is used in the dry image receiving element of the film unit according to the present invention, the stability of the transferred image will generally be increased. Usually, this pH lowering substance is
After swelling, the pH value of the image layer is increased to about 18 or 1 within an hour.
4 to at least 11, preferably 5 to 8. For example, US Patent 1ff (8,86
2,819 or solid acids or metal salts such as those disclosed in U.S. Pat. No. 2,584,030, such as zinc acetate, zinc sulfate, magnesium acetate, etc. Then you can get good results. Such pII value lowering substances lower the pH value of the film unit after development, terminating development and reducing the q for lignically persistent dye transfer, thus stabilizing the dye image. In an embodiment of the present invention, 1 adjacent to the pH lowering layer 2.
．． an inert timing layer or spacing layer (
Nubezer) layer can be used. Such an inert layer "temporally adjusts" or controls the decrease in the pH value as a function of its proportions when alkali diffuses into the interior of the inert spacing layer. U.S. Patent No. 3,362,821 discloses a case in which a neutralizing layer made of a polymeric acid is provided on the photosensitive element side; The timing layer located between the layers maintains the pH value and water absorption l- of the alkaline processing solution for -9 hours when the photosensitive element is immersed in the alkaline processing solution and the alkaline processing composition is absorbed into the photosensitive rice. It is desirable that the photosensitive layer has good strength and adhesion to the neutralization layer. Compounds with such functions are described, for example, in Zarch Disclosure 20513 and 20514. The silver halide emulsion used in the present invention includes silver bromide, silver iodide,
It is a hydrophilic colloidal dispersion of silver chloride, silver iodobromide, silver chlorobromide, silver chloroiodide, silver chloroiodobromide, and mixed silver halides. For example, it may be manufactured using a different manufacturing method, such as a so-called convergence emulsion, a Lippmann emulsion, a fogged or internal latent image type direct positive emulsion, and depending on the type of photographic light-sensitive material, halogen The grain size, content 1, mixing ratio, etc. of silver oxide will be different. Hydrophilic pupil-retentive colloids that are dispersants for silver halide include various natural or synthetic colloids such as gelatin, gelatin derivatives, and polyvinyl alcohol.
Colloidal substances may be used alone or in combination. The silver halide may also be used to activate gelatin, sulfur sensitizers such as allylthiocarbamide, thiourea, cystine, etc.
Chemical sensitization can be carried out using selenium sensitizers, noble metal sensitizers, such as gold sensitizers, and sensitizers such as ruthenium, rhodium, and iridium, either alone or in combination as appropriate. Furthermore, silver halide emulsions can be optically sensitized, for example, by cyanine dyes and mete-cyanine dyes, and generally three types of silver halide emulsions each having different sensitizing wavelength ranges are used to produce color. A photographic material is obtained. The silver halide emulsion can also be stabilized with triazoles, tetrazoles, imidazoles, azaindenes, quaternary benzothiazolium compounds, zinc or cadmium compounds, and may also be stabilized with quaternary ammonium salts or polyethylene glycols. Sensitizing compounds may also be included. and also suitable gelatin plasticizers such as glycerin, dihydrotetekalkanes such as 1,3-bentanediol, ethylene bisglycolic acid noester, bis-ethoxydiethylene glycol succinate, amides of acrylic acids, latex, etc. In addition, formaldehyde, halogen-substituted fatty acids such as mucobromic acid, compounds with acid anhydride groups, dicarboxylic acid chlorides, vinylesters of methanesulfonic acid, and aldehyde groups separated by divalent or trivalent carbon atoms can be used. Various additives may be included, such as gelatin hardening agents such as sodium bisulfite derivatives of dialdehydes, or spreading agents such as saponins, or coating aids such as sulfosuccinates. Furthermore, various additives commonly used in photo-AVCs, such as antifoggants and ultraviolet absorbers, can also be included, if necessary. In the present invention, as described above, various silver halide emulsions can be used, and when a negative silver halide emulsion is used, a negative color diffusion transfer image can be obtained. Positive color diffusion transfer R images can be obtained by various methods. In addition to the mordant layer of the present invention, a photofading inhibitor, a fluorescent brightener,
Ultraviolet absorber t "Any additive may be included. Various known anti-fading agents can be used, including 2.6-t-butyl-p-cresol,
2,2'-methylenebis(4-methyl-6-t-butyl-phenol), 4,4'-thiobis(3-methyl-6
-t-butyl-phenol). The ultraviolet absorber C is 2-(3', 5'-dittersialyamyl-2'-hydroxyphenyl)benzotriazole, 2-(2'-hydroxy-3', 5
'-ditertibutylphenyl) 5-chlorobenzotriazole, 2-(3',5'-ditertibutyl-
2-hydroquinphenyl)hencytriazole, 2.
-(2'-Hydroxy-5'-methylphenyl)benzotriazole, 2-(hydroxy-5-tert-butylphenyl)benzotriacy = A, 2-hydroxy-4-methoxybenzophenone, 2
．． 2'-dihydroxy-4-methoxybenzophenone,
2-hydroxy-4-methoxy-2'-carboxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone, 2,4-dihydroxybenzophenone, 2
Various known compounds can be used, such as -ethylhexyl-2-ruphenyl-3,5-ditertyarifthyl-4-human xybenzoate. As the fluorescent whitening agent, various known compounds such as stilbenes, coumarins, carbostyrils, diphenylpyrazolines, naphthalimides, and arylazolyls are used. As a specific example, whitefluo
r B%whitephore PON (Sumitomo Chemical)
, Haklcal PY-1800, Haklcal PY-200
0, py-B (both Showa Kagaku), Kayalig
ht B, same OS (Nippon Kayaku), High Bright ro
ot (Dainichi Hatoka), Uvitex OB (01ba
-Geigy), Mikephore ETN (Mitsui Toatsu) 461, and other commercially available products. The dry image-receiving element according to the invention also contains a development inhibitor 2.03.
No. 5,589 may also be included. The film unit or member of the present invention is a monochrome or multicolor positive II! In the three-color system that can be used to create images, each silver halide emulsion layer of the film dye provides an image dye having a primary spectral absorption within the range of the visible spectrum to which the silver halide emulsion is sensitive. in a communal relationship with sexual substances. That is, the blue-sensitive silver halide emulsion layer has a yellow image color water-providing substance associated therewith, and the green-sensitive silver halide emulsion layer has a magenta image dye-providing substance associated therewith. The red-sensitive silver halide emulsion layer also has a cyan 11 image dye-providing substance associated therewith. The image dye-providing material associated with each silver halide emulsion layer can be contained within the silver halide emulsion layer itself or in a layer adjacent to the silver halide emulsion layer. After processing of the photographic elements described above, it is preferred that an image distribution of dyes or dye-forming substances remain within the element in addition to the developed silver after dispersion has taken place. If residual silver and halogenation (U) are removed by normal methods e.g. bleach baths,
1. A color image is obtained in the element consisting of residual non-diffusible compounds when processed in a fixing bath or removed in a bleach constant bath. The image distribution of the dye or dye-forming substance can also be diffused out of the element into these baths rather than into the image-receiving element, if desired. if,
If negative-working silver halide emulsions are used in certain preferred light-sensitive elements, positive color images such as reflection prints, color transbare arrays or motion picture films can be produced in this manner. If a direct positive silver halide emulsion is used in such a photosensitive element, a negative color image will result. It will be appreciated that the present invention can be utilized to process individual sheets of film or can be used in continuous processing of long strips of film, such as motion picture film. The sheet material used may be a substantially planar sheet or a roll, and may be used to supply the processing liquid, control the distribution of the processing composition, such as is used in the case of viscous processing solutions, or for capturing and retaining the treated products,
No masks, traps, containers or other equipment are required. If desired, a white border can be provided in the transferred image by exposing the border of each workpiece to white light prior to imaging, or by other techniques apparent to those skilled in the art. Examples are shown below to make the effects of the present invention more clear, but the present invention is not limited thereto. Example-1 Poly(ethylene prephthalate) film support-r=
A series of photosensitive elements were prepared having the following layers coated on it. The coatings of these elements had the same diffusible dye of the DRR compound contained in the DRR49-compound-containing layer, but differed in the type of redox center. In addition, in each # below, the numerical value written in parentheses is the coating of the material 1-(9/rIt) unless otherwise specified. ('') Exemplary compound + 1) magenta DTIR compound (0
, 52), magenta DRR compound-containing layer (2) consisting of tricresyl phosphate (0,3) and gelatin (1,5)
) Negative silver bromide emulsion (08g in terms of silver), 2-
5ec-octadecylhydroquinone-5=potassium sulfonate (11.3 g per mole of silver) and gelatin (1
, 3) (3) Monochrome photographic elements 14 were prepared by coating with a protective layer consisting of gelatin (1,0). Similarly, the exemplified compound (
DR of 2), (3), (7), (12) and (13)
Each R compound was applied at the same molar concentration. Each element is passed through nine stages of silver wedges with a density difference of 0.15 per stage to the specified EX-jY:
and placed in a container containing an aqueous solution of a non-viscosity alkaline treatment composition listed in Table 1 VC below.
immersion for 5 seconds, then passing this element and the dry image-receiving element between front-to-front surfaces, adjusted to press both elements firmly without wringing out the processing solution absorbed into the photosensitive element. I pressed the contact and made one anus. Any excess liquid on the surface of the photosensitive element opposite the image receiving element was removed by a roll. Table 1 KOH56・1g 11-aminoundecanoic acid 295-methylbenzotriazole 7.2gMeboulhyde Kino 7
4.5gJI,o
The t i image-receiving element consists of an image-receiving layer applied to a white pigmented support coat, as shown in its construction below. Gelatin (2,7), poly(styrene-N, N-dimethyl-N-benzyl-N-p-(methacryloylaminophenyl) methylammonium chloride-coshynylbenzene) (2,7), 4-hydroxymethyl-4-methyl- 1-phenyl-3-pyrazolidinone (0,67)
, and tetragis(vinylsulfonylmethyl)methane.The white pigment-containing support light-sensitive element and image-receiving element were superimposed for (4) seconds and then separated from each other, and the image-receiving element was washed with water. As a control, the magenta DRH compound-containing layer contained the following magenta DRR compound having a redox center other than the sulfonamide indole according to the present invention.
Similar photosensitive elements were processed in a manner similar to that described above. These results are shown in Table 2. Furthermore, after exposing the photosensitive element, the photosensitive element and the image receiving element are placed one on top of the other, and a container holding an alkaline processing composition containing a thickening agent is attached therebetween to form a pair of integrated photosensitive element and image receiving element. Processing was carried out by spreading a viscous alkaline processing composition between the photosensitive element and the image receiving element by rupturing the container by applying pressure to the container and passing it through a gap between the two sides. . These results are shown in Table 3. Table 2 53 - Control Compound (A) Control Compound (0) 54 - Table 3 The results in Table 2 show that the DRR compound according to the present invention has a sulfonamide indole as a redox center. It is shown that Dmax can be lowered by 1 or more than that of a DRR compound having naphthol as a redox center, while Dmin can be lowered and the distinguishability of dye images can be improved by 1. Control compounds (B) and (0) are inferior to the compounds of the present invention in both Dmax and Dmin. After the photosensitive element made of the control compound was immersed in the alkaline processing solution for 20 seconds, the overlapping time with the image receiving element was prolonged, and although there was an increase in Dm&x, there was a significant increase in Dmj,
This was accompanied by an increase in n. The results in Table 3 show that in the treatment method in which the alkaline viscous treatment liquid is held in a container, substantially the same Dmin and Dmax can be obtained regardless of the redox center. Example 2 Photosensitive elements were prepared by coating the layers in the order described below on a black opaque poly(ethylene terephthalate) film support. Unless otherwise explained, the amount is the numerical value (1/n?'') shown in parentheses. (1) Cyan DRR compound 9 of exemplified compound (18) (0,44), diethylroudamide (0,45) , and a cyan DRR compound-containing layer (2) consisting of gelatin (1,1), a red-sensitive negative silver bromide emulsion (1,1 in terms of silver),
Og) Potassium 2-octadecylhydroquinone-5-sulfonate (silver [1000g]) and gelatin (
1,,6) Red-sensitive silver halide emulsion layer (3) Gelatin (1,0), 2.5-G5CC-
Intermediate layer consisting of dodecylhydride quinone (0,45) and dibutyl phthalate (4) Exemplary compound (4) Tumacenta DRR compound (0,45)
48), magenta DRR compound-containing layer (5) consisting of tricresyl phosphate (0,5) and gelatin (1,1)
Green-sensitive negative silver bromide emulsion (0.8.!i in terms of silver)
), a green-sensitive silver halide emulsion layer (6) of potassium 2-octadecylhydroquinone-5-sulfonate (11°3.f per mole of silver) and gelatin (1,6), gelatin (1,0), Intermediate layer (7) consisting of 2,5-di-5cc-dodecylhydroquinone (0,45) and diptyl Yellow DRR compound (0
, 56) Yellow DRR compound-containing layer consisting of tricresyl phosphate (0,28), 57-gelatin (1,2) (8) Back-lighting negative silver bromide emulsion (0 in terms of #) .8
．． ! 9), back-lighting silver halide emulsion layer (9) of potassium 2-octadecylhydroquinone-5-sulfonate (11.3 g per mole of silver) and gelatin (1,6), tetrakis(vinylsulfonylmethyl)methane ( Protective layer consisting of gelatin (0,25) and gelatin (0,9) The photosensitive element thus prepared was subjected to a prescribed exposure through the silver wedge shown in Example 1, and the exposed photosensitive element was then exposed to light as shown in the table below. After immersion in a 23'C1 non-viscous alkaline processing solution as described in Example 3VC, it was pressed into front-to-front contact by passing between the receiver element and the overlapping pressure ring shown in Example 1. The photosensitive element and the image receiving element were stacked for 3 minutes, then separated from each other and the image receiving element was washed with water containing a small amount of acetic acid. -〇 and - Table 4 KOH37g Benzyl alcohol 8ml] 1-aminoundecanoic acid 2g5-methylbenzotriazole 4.6g1 ('Rr
29 Methylhydroquinone 3.2gn, o
As a control, the second DRR compound-containing layer contained sulfonamide naphthol.
Photosensitive elements were prepared in the same manner as described above except that the following cyan, magenta and yellow E-DRR compounds as dox centers were respectively contained in the same concentrations as the above-mentioned exemplified compounds. Table-5 Control Cyan DFtR Compound 59 - Control Magenta D11R Compound vs. r1 (1 Yellow E) R1 (Compound D of each dye image
min ) 11 and the results were superior to those obtained for photosensitive elements containing control DRR compounds with sulfonamide naphthol as the redox carrier. The transfer 61-1ω- images not obtained by the method described in this example are the same as those obtained using a viscous processing composition containing the same photosensitive element, the same image-receiving element, and a thickening agent. Comparison with the image 2. The minimum density]) was extremely low, the distinguishability was large, and the image was extremely clear and sharp. Example-3 After exposing the photosensitive element prepared in Example-2 above, Table below-
6VC After being immersed in a non-viscous alkaline processing solution containing a silver halide developer described at 5°C for a second, the same facts as those shown in Example 1 were obtained, except that no silver halide developer was contained. - The method described in Example 2VC was repeated using the same receiver element. These results are shown in Table-7. Table -6 1-phenyl-4-hydroxymethyl 6.79 4-methylpyrazolidone 5-methylbenzotriazole 7.2911-aminoundecanoic acid 2y62-KB (251 Methylhyde 1 quinone 4.5gKOIT
56.1 ji+1,0
Table 1-7 Even if the silver halide developer is contained in the alkaline processing solution, the sulfonamide indole of the present invention can be
We show that DRR compounds with dox centers can lower D min and Jj[ to enhance the discrimination of dye images. The present invention relates to an improved method of producing color transfer images as claimed in the claims, and preferred embodiments of the present invention are listed below. (1) The photosensitive element can release a diffusible dye under alkaline conditions as a result of cross-oxidation with an oxidized developer.71. A method of forming a color transfer image as claimed in the claims comprising two or more selectively sensitized silver halide emulsion layers, each containing a different non-diffusible dye-releasing redox compound. 2) The photosensitive elements are stacked on the support, each with a
The claimed invention consists of a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer in combination with dispersive yellow, magenta and cyan dye-releasing redox compounds. A method for forming a color transfer image. (3) After the multilayer photosensitive element described above is irradiated with light, it is immersed in an aqueous solution of an alkaline processing composition in the presence of a silver halide developer to absorb the processing solution, thereby removing the silver halide emulsion layer in the exposed areas. oxidizing the oxidized silver halide developer and in turn cross-oxidizing the oxidized silver halide developer with a dye-releasing redox compound to form a diffusively releasing dye of an image distribution. A method for forming a color transfer image. (4) The above-mentioned photosensitive element is superimposed on the image receiving element containing a mordant to which the diffusively releasing dye can be dyed so that the tips of both elements coincide, without providing a layer of processing agent between the two elements. A method of forming a color transfer image as claimed in claim 1, comprising the step of diffusively transferring portions of the image distribution of the diffusively releasing dye to the dye-dyeable image-receiving layer. 5. A method of forming a color transfer image as claimed in claim 1, comprising the step of optionally separating an image-receiving element containing a diffusively emitting dye image from a photosensitive element. (6) The alkaline processing composition aqueous solution does not contain a thickening agent and has a pH of at least 13, and is in an amount sufficient to lower the pH of the image-receiving layer to 8 or below when the photosensitive element and image-receiving element are separated. A patent that includes a layer containing a pH value lowering substance or a neutralizing layer! A method for forming a color transfer image according to the scope of the invention. (7) A neutralizing layer or a layer containing a pH lowering substance. A method of forming a color transfer image as claimed in claim 1, wherein the color transfer image is isolated from photosensitivity by a neutralization rate control layer (timing layer). (8) A method for forming a color transfer image according to the claims, which comprises containing a silver halide developer in either a photosensitive element and/or an image receiving element. (9) The silver halide m f& agent is [-phenyl-3-
The method for forming a color transfer image according to embodiment (8), in which pyrazolidone is used. (10) The method for forming a color transfer image according to embodiment (8), wherein the silver halide developer is 4-hydroxy-4-methyl-1-phenyl-3-birasoliton. (11) Halogen (I [developer is 1-phenyl-3
- The method for forming a color transfer image according to embodiment (8), which is a pyrazolidone precursor. 6-(12) Silver halide developer precursor is 1-phenyl-2
-Acetyl-4,4-dimethyl-3-pyrazolidone The method for forming a color transfer image according to embodiment (11) (13) The silver halide developer precursor is 1-phenyl-2
-pyrazolin-3-yl-N-methyl-[2-(N-methyltrifluoroacetamidomethyl) -4,-p
-) Luenesulfonamitophenyl]carbamate The method for forming a color transfer image according to embodiment (11). (14) A method for forming a color transfer image according to claim 1, wherein a silver halide developer or its precursor is impregnated into a polymer latex and dispersed in a hydrophilic binder. (15) Intermediate between the image-receiving layer and the dye-releasing layer (protective layer or intermediate I
? A method for forming a color transfer image according to claim 1, wherein i> has a scavenger mordant layer containing a small amount of a mordant having stronger dyeing ability than the image-receiving layer. (]6) The non-diffusible dye-releasing redox compound has the following general formula ((a) Ool is a dye or colored water precursor component;
b) Ba1l has a molecular size and shape that renders the compound non-diffusible in the photosensitive element during development in an aqueous alkaline processing composition having a pTI value of at least about 11; organic ballast groups such as simple organic or polymeric groups such as alkylacylamide, arylacylamide, succinimide and phthalimide groups. (The alkyl group of the alkylacylamide group represents a straight chain or branched alkyl group having 12 to 20 carbon atoms, and the aryl group of the arylacylamide group is an alkyl group or alkoxy group having 5 to 20 carbon atoms. , represents an alkyl acylamido group, a ryol group substituted by an alkyl sulfonamide group,
Further, the succinimide group and the phthalimide group may each be substituted with an alkyl group, alkoxy group, alkylacylamide group, or alkylsulfonamide group having 5 to 20 carbon atoms. ) (Q) R is a hyfgen atom or a charcoal atom number 1
~3 alkyl group or alkoxy group, (a)
Rt represents a halogen atom, an argyl group or alkoxy group having 1 to 2 carbon atoms, an acetylamide group, a methylsulfonamide group, a nitro group, a carboxyl group, a sulfo group or a methylsulfo group. (e) n: tJ and m are integers from 0 to 2) J・1. A method for forming a color transfer image according to the claims.

[Brief explanation of drawings]

FIG. 1 is a cross-sectional view illustrating processing of a photosensitive element in a preferred embodiment of the invention. FIG. 2 is a cross-sectional view of the front-to-front contact between a photosensitive element and a dry image-receiving element in a preferred embodiment of the present invention. Agent Takumi Kuwabara 70- Entsuta Kaya 2 1982 10JJ12L1 Commissioner of the Patent Office Jun 1) Haruki-dono - Pa 1, case display Ht Iwa 56 I "Patent Application No. 136547 1J゛2 ,
Name of the invention Method for forming a color transfer image 3 Relationship with the Nagisa case to be amended Patent applicant address 21 G. 1-112 Nishi-Shinjuku, Shinjuku-ku, Tokyo Name (27) Konishiroku Photo Industry Co., Ltd. Address
5, Suji, Sakura-cho, Kuchino-shi, Tokyo Date of the amendment order: 6. Detailed explanation of the invention in the specification subject to the amendment 7. Contents of the amendment: Detailed explanation of the invention. The correction is as follows. 2- Procedural Amendment] ・It I'l No. 14 of 1976 [
↑'r 1irI'+ No. 136547 -', j-2
Name of the invention: Method for forming a color transfer image: l hli 11 wo Zurotoshi (Relationship with 'l Patent mm ■ Person i 1 Location Nishi-Shinjuku, Ri 1-Shuku-ku, Tokyo] - J Item 26 No. 2 Name (+27 ) Konishi Roku Photo Industry Co., Ltd. 7 + Nobuhiko Dainoe Director 5111i 1 [Order 11 I/J Voluntary 6, “Detailed Description of the Invention” column 7 of the specification to be amended, Contents of the amendment Invention The detailed explanation of 1982 1111281.1 is amended as follows: 2- Procedural amendment 1981 1111281.1, ' Commissioner of the Patent Office Kazuo Wakasugi 1 Indication of case Patent application No. 136547 1982 1) 2 Title of invention Color transfer bond Formation method 3 Relationship with the case of the person making the amendment M1 person address for patent purposes Nishi-Shinjuku '1'l12+; No. 2F, Shinjuku-ku, Tokyo
Name (+27) Rokuman Konishi Mashigyo Co., Ltd. 71 Nobuhiko Moto for representative director 4 Voluntary application of agent 6, Column 7 of “Details of the invention” of the reference specification of the amendment,
Contents of amendment (1) Details of the invention 1Yjll /:C description is amended as follows. −2=

Claims (1)

[Claims] (1) After imagewise exposure of a light-sensitive element having a layer containing a light-sensitive silver halide emulsion and a color image-forming material, the light-sensitive C element is prepared in the presence of a silver halide developer into a viscous and
(Diffusion of the imagewise distribution of the diffusive color patch or color source precursor component corresponding to the imagewise exposure generated by the cross-oxidation reaction with the oxidized developer brought into contact with the alkaline processing liquid occurs. The photosensitive element is then superimposed with a dried bone element, and then in vivo, at least a portion of the imagewise distribution is diffusely transferred to the image receiving element to form a color image on the image receiving element. , and then optionally separating the image-receiving element from the photosensitive element, in a color ambiguous transfer surface imaging process, in which the color imaging material has a semi-binary characteristic represented by the general formula (1) and the general formula CI). In the formula, OOl is a dye or a dye precursor, l3all is an alkylacylamide group, arylacylamide group, succinimide group, and phthalimide group, 1R1 is a halogen atom, an alkyl group having 1 to 3 carbon atoms, or an alkoxy group, and - is a group selected from tart-buty groups (R8+"4 is an aqueous atom or an alkyl group), m is 0 to 3
represents an integer.