JPS58210142A - Wear resistant alloy - Google Patents

Wear resistant alloy

Info

Publication number
JPS58210142A
JPS58210142A JP9117682A JP9117682A JPS58210142A JP S58210142 A JPS58210142 A JP S58210142A JP 9117682 A JP9117682 A JP 9117682A JP 9117682 A JP9117682 A JP 9117682A JP S58210142 A JPS58210142 A JP S58210142A
Authority
JP
Japan
Prior art keywords
alloy
wear
resistant alloy
wear resistant
various
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9117682A
Other languages
Japanese (ja)
Inventor
Naoto Kanbara
蒲原 尚登
Tatsuyoshi Aisaka
逢坂 達吉
Mitsuo Kawai
光雄 河合
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP9117682A priority Critical patent/JPS58210142A/en
Publication of JPS58210142A publication Critical patent/JPS58210142A/en
Pending legal-status Critical Current

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  • Sliding-Contact Bearings (AREA)

Abstract

PURPOSE:To obtain a wear resistant alloy suitable for use as the material of various sliding parts, etc. by blending Ni with specified amounts of Cr, Nb, Mo and W. CONSTITUTION:This wear resistant alloy consists of, by weight, 10-45% Cr, 3- 15% Nb, 4-20% Mo, 2.0-6.0% W and the balance Ni. Nb in the alloy composition reacts with Ni, strengthening the alloy matrix and enhancing the wear resistance. W makes the grains fine and enhances the wear resistance. Nb and W are added by said amounts causing no reduction of the toughness. The wear resistant alloy has small wear and abrasion losses and superior build-up weldability, and it contains no Co, so the alloy is suitale for use as a material for various plants such as chemical and nuclear power plants and as the material of sliding parts of various machines.

Description

【発明の詳細な説明】 〔発明の属する技術分野〕 本発明は化学、分よび原子カプラントなど各種のプラン
トのフェース部や、ジェットポンプの部品および各種機
械の摺動部部品などに好適な耐摩耗合金に関する。
[Detailed description of the invention] [Technical field to which the invention pertains] The present invention provides a wear-resistant material suitable for face parts of various plants such as chemical, separation, and atomic couplants, parts of jet pumps, and sliding parts of various machines. Regarding alloys.

〔従来技術とその問題点〕[Prior art and its problems]

従来より耐学耗合金としてCo−Cr −Ni−W系合
金(通称、ステライト)が広く用いられていたが、最近
コバルト資源の枯渇、化学プラントの反応制御、あるい
は原子カプラントの安全性向上の観点から、NIを基体
とした耐摩耗合金が開発されている。
Co-Cr-Ni-W alloys (commonly known as stellite) have traditionally been widely used as wear-resistant alloys, but recently they have been used from the viewpoint of depletion of cobalt resources, reaction control of chemical plants, or improving the safety of atomic couplants. Since then, wear-resistant alloys based on NI have been developed.

しかしこの新しく開発されたN!基耐摩耗合金はまだ従
来より用いられているCo J 合金(通称、ステライ
ト)に比べ耐摩耗性が十分でない本発明者らは上記点に
嚇み検討を進めた結果成る欅のクロームーニオプーモリ
フテンータングステンー二ノゲル系合金が上記の各種プ
ラント用溝成部材などとして1、要求さtしている耐摩
耗性を備えていることを見い出した。
However, this newly developed N! The base wear-resistant alloy still has insufficient wear resistance compared to the conventionally used Co J alloy (commonly known as Stellite). It has been found that the Riften-Tungsten-Ninogel alloy has the abrasion resistance required for the above-mentioned various plant grooving members.

〔発明の目的〕[Purpose of the invention]

本発明は上記@姑に基づき各種プラントにおけるパルプ
のフェース部やジェットポンプの部品および各種機械0
摺動部部品などに好適な耐摩耗合金を機供しようとする
ものである。
The present invention is based on the above @mother-in-law, and the present invention is based on pulp face parts and jet pump parts in various plants and various machines.
The aim is to provide a wear-resistant alloy suitable for sliding parts and the like.

〔発明の概要〕[Summary of the invention]

以下本発明の詳細な説明すると本発明の耐琴耗合金は重
量比でクローム10〜45チ、ニオブ3〜15%、モリ
ブデン4〜2(1、タングステン2〜6チ、残部ニッケ
ルより成ることを$1とするものである。
In detail, the present invention will be described below. The wear-resistant alloy of the present invention is composed of 10-45% chromium, 3-15% niobium, 4-2% molybdenum (1), 2-6% tungsten, and the balance nickel. The amount shall be $1.

〔発明の効果〕〔Effect of the invention〕

本発明の耐摩耗合金は、上記の如くクローム−ニオブ−
モリブデン−ニッケル系でその組成比は、クローム10
〜45重噴憂、ニオブ3〜15重を俤、モリブデン4〜
20チ、タングステン2〜6重政チ、ニッケル残部と礁
択する必要があシ、その1由は次の如くである。まずク
ロームは耐食性および合金の素地を・浅化するために必
要な成分でその組成比が10冬未満では効果が不十分で
おりまた45チを越えると粗大な初晶の相が過度に析出
し所要の耐摩耗性が得られな(八、ニオブはニッケルと
反応して合金゛の素地の・強化と耐摩耗性の向上に寄与
する成分であるがその1が3名未満では幼果が不十分で
、また15%を越えると靭性の低ドがみられ材料の機械
的強度が損なわれるからでちる。モリブデンは耐食性の
向上と合金素地をj虫化し耐摩耗性の同上に寄与するも
のでその量が4’1未満では効果が不十分であるが20
チを越えると合金の靭性の低下が与られるからである。
The wear-resistant alloy of the present invention has a chromium-niobium-
Molybdenum-nickel system with a composition ratio of chromium 10
~45 layers, 3~15 layers of niobium, 4~ molybdenum
It is necessary to choose between 20 pieces of tungsten, 2 to 6 pieces of tungsten, and the rest of nickel.One reason for this is as follows. First of all, chromium is a necessary component for corrosion resistance and for shallowing the matrix of the alloy.If the composition ratio is less than 10%, the effect is insufficient, and if it exceeds 45%, coarse primary crystal phases will precipitate excessively. The required wear resistance cannot be obtained (8. Niobium is a component that reacts with nickel and contributes to strengthening the base of the alloy and improving wear resistance, but if less than 3 people contain niobium, the young fruit will fail. If it exceeds 15%, the toughness decreases and the mechanical strength of the material is impaired.Molybdenum improves corrosion resistance and hardens the alloy matrix, contributing to wear resistance. If the amount is less than 4'1, the effect is insufficient, but 20
This is because if the amount exceeds 1, the toughness of the alloy decreases.

タングステンは結晶粒の微細化と共に耐摩耗性の向上(
寄与するものでちるが、その量が2.0チ未満では効果
が不十分でまた6、0%を越えると合金の靭性の低下が
みられるからである。
Tungsten improves wear resistance as the crystal grains become finer (
However, if the amount is less than 2.0%, the effect will be insufficient, and if it exceeds 6.0%, the toughness of the alloy will decrease.

しかして、本発明に係る耐摩耗合金はニオブの一部をタ
ンタルで置換してもよい、tたニッケルの一部を鉄で置
換することもできる。さらに溶解時に添加する脱離、脱
窒剤としてのマンガンやシリコンなどを含んでいても差
支えない。
Thus, in the wear-resistant alloy according to the present invention, a portion of niobium may be replaced with tantalum, and a portion of nickel may be replaced with iron. Furthermore, it may contain manganese, silicon, or the like as a denitrifying agent and a denitrifying agent added during melting.

〔老明の漏唯列〕[Lao Ming's leaky sequence]

表−1に示す組成(重i係)。の合金を先ず用意し、高
周波真空誘導溶解炉を用いて溶解搗造後、この燭遺品か
ら試験片を切り出し特性評価試験を行なった。
Composition shown in Table 1 (weighted i). First, an alloy was prepared, and after melting and shaping using a high-frequency vacuum induction melting furnace, test pieces were cut out from the candlesticks and subjected to characteristic evaluation tests.

この特性評価試験は超音波感動方式によるキャビテーシ
ョンエロージョン試*2よびアムスラー型による摩耗試
験を行なったキャビテーションエロージョン試噴は学振
法に進じて3時間行、なったその焙果を茨−1に併せて
示した。なお表−1における損耗1は試験による試験片
の重を減少(mg)を試瑣時間分と密度(g/d)とで
除した値に1×103を乗したもので詩關当りの体積減
少鎗を示すものである。
In this characteristic evaluation test, we conducted a cavitation erosion test*2 using an ultrasonic impression method and a wear test using an Amsler type.The cavitation erosion test was conducted for 3 hours according to the Gakushin method. Also shown. In addition, wear 1 in Table 1 is calculated by multiplying the value obtained by dividing the weight loss (mg) of the test piece by the test time and the density (g/d) by 1 x 103, and the volume per test piece. It shows a decreasing spear.

また、rムスラー型による摩耗試験は試験荷重309、
摺#幇耗距離1(100m潤滑剤として水(ice/秒
)を;受用して行なった。その請来を表−IK併せて示
したわなお一々−1に訃ける毫粍睦は試験による試験片
の礪殖減少t(mg)を示すものである。
In addition, the wear test using the r Musler type test load was 309,
The wear distance 1 (100 m) was carried out using water (ice/second) as the lubricant. It shows the reduction in welt growth t (mg) of the test piece.

同表−1にjd比較のためニッケルークローム−tiロ
ン系占溶合宅(比較例4)、ニッケルークローム−モリ
ブデン−シリコン系合金(比較例5)、などの喘合も併
せて示した。
Table 1 also shows the combinations of nickel-chromium-tiron alloy (Comparative Example 4), nickel-chromium-molybdenum-silicon alloy (Comparative Example 5), etc. for jd comparison. .

衣−1 本活明合金を18Cr−8N+ステンレス鋼慌VC内′
!&溶接を施こすとき、18Cr−13Niステンレス
鋼板に若干の熱影響がカロわるが、これを除去するため
に溶体化処理を怖こしても本発明合金の機械的特注には
杉響しない。また、本発明合金を炭素肩板((肉盛溶接
を怖こすとき炭素横板に若干の熱影響が加わるが、これ
を除去するためにオーステナイト化処理、分よび焼戻し
を施こしても本発明合金す〕機械的特性4−には彰響し
ない。
Clothes-1 This active Akira alloy is used in 18Cr-8N + stainless steel VC.
! & When performing welding, the 18Cr-13Ni stainless steel plate is slightly affected by heat, but even if solution treatment is performed to remove this effect, the mechanical customization of the alloy of the present invention will not be affected. In addition, the present invention can be applied to the carbon shoulder plate (when overlay welding, a slight thermal effect is applied to the carbon cross plate, but in order to remove this effect, the present invention can be applied by subjecting it to austenitizing treatment, cracking and tempering). Alloy] Mechanical properties 4- are not affected.

上記試験結果より明らかなように本発明に係る耐1wJ
吐合金は比較列に比べいずれも損耗曖、摩耗綾が少なく
肉盛溶接性にすぐれかつコバルトを含まないことから化
学、原子力などの各種プラント用および各種機械の摺動
部構成材料として適するものと云える。
As is clear from the above test results, the resistance to 1wJ according to the present invention
Compared to the comparison series, the alloys have less wear and tear, have excellent overlay weldability, and do not contain cobalt, so they are suitable for use in various chemical and nuclear power plants, and as materials for the sliding parts of various machines. I can say that.

代理人弁理士 則近憲佑(ほか1名)Representative patent attorney Kensuke Norichika (and one other person)

Claims (1)

【特許請求の範囲】[Claims] 重量比でクローム10〜45%、ニオブ3〜15チモリ
ブデン4〜20qb、タングステン2.0〜6.0係、
残部ニッケルよ抄成ることを!敵とする耐摩耗合金。
By weight, chromium 10-45%, niobium 3-15, thymolybdenum 4-20qb, tungsten 2.0-6.0%,
The remaining nickel is worth it! A wear-resistant alloy as an enemy.
JP9117682A 1982-05-31 1982-05-31 Wear resistant alloy Pending JPS58210142A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9117682A JPS58210142A (en) 1982-05-31 1982-05-31 Wear resistant alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9117682A JPS58210142A (en) 1982-05-31 1982-05-31 Wear resistant alloy

Publications (1)

Publication Number Publication Date
JPS58210142A true JPS58210142A (en) 1983-12-07

Family

ID=14019147

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9117682A Pending JPS58210142A (en) 1982-05-31 1982-05-31 Wear resistant alloy

Country Status (1)

Country Link
JP (1) JPS58210142A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62179890A (en) * 1986-01-31 1987-08-07 Toshiba Corp Wear resistant member
US5873950A (en) * 1996-06-13 1999-02-23 Inco Alloys International, Inc. Strengthenable ethylene pyrolysis alloy
JP2014095101A (en) * 2012-11-07 2014-05-22 Hitachi Ltd Ni-BASED CASTING ALLOY AND STEAM TURBINE CASTING MEMBER USING THE SAME
CN110093520A (en) * 2019-03-19 2019-08-06 江苏汉青特种合金有限公司 A kind of manufacturing method of high-end corrosion resisting alloy

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62179890A (en) * 1986-01-31 1987-08-07 Toshiba Corp Wear resistant member
US5873950A (en) * 1996-06-13 1999-02-23 Inco Alloys International, Inc. Strengthenable ethylene pyrolysis alloy
JP2014095101A (en) * 2012-11-07 2014-05-22 Hitachi Ltd Ni-BASED CASTING ALLOY AND STEAM TURBINE CASTING MEMBER USING THE SAME
CN110093520A (en) * 2019-03-19 2019-08-06 江苏汉青特种合金有限公司 A kind of manufacturing method of high-end corrosion resisting alloy
CN110093520B (en) * 2019-03-19 2021-04-30 江苏汉青特种合金有限公司 Method for manufacturing corrosion-resistant alloy

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