JPS5646870A - Geometrical isomer of triazole compound and its preparation - Google Patents
Geometrical isomer of triazole compound and its preparationInfo
- Publication number
- JPS5646870A JPS5646870A JP12457179A JP12457179A JPS5646870A JP S5646870 A JPS5646870 A JP S5646870A JP 12457179 A JP12457179 A JP 12457179A JP 12457179 A JP12457179 A JP 12457179A JP S5646870 A JPS5646870 A JP S5646870A
- Authority
- JP
- Japan
- Prior art keywords
- isomer
- triazole compound
- alkyl
- preparation
- magnetic field
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 triazole compound Chemical class 0.000 title abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 230000000855 fungicidal effect Effects 0.000 abstract 2
- 239000000417 fungicide Substances 0.000 abstract 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 abstract 2
- LACMLEGEQFCFAZ-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pent-1-en-3-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)=CC1=CC=C(Cl)C=C1 LACMLEGEQFCFAZ-UHFFFAOYSA-N 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 abstract 1
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004647 alkyl sulfenyl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 230000008635 plant growth Effects 0.000 abstract 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
NEW MATERIAL:One of the two geometrical isomers of a triazole compound of formula I (X is halogen, alkyl, haloalkyl, alkoxy, phenoxy, phenyl, cyano or nitro; n is 0W5; R is alkyl, cyclopropyl, or alkyl substituted with alkylsulfenyl), wherein the NMR spectrum (in deuterochloroform) of olefinic proton is at the higher magnetic field side in the selected isomer than in the other isomer.
EXAMPLE: The E-isomer of 1-(4-chlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)- 1-penten-3-one.
USE: Agricultural and horticultural fungicide and general-purpose fungicide. It is also effective to kill to weeds and regulate the growth of plant.
PROCESS: The objective compound is prepared by isomerizing one of the two isomers of a triazole compound with photoirradiation, wherein the NMR spectrum of olefinic proton is at the lower magnetic field in the isomer than in the other isomer.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (23)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12457179A JPS5646870A (en) | 1979-09-26 | 1979-09-26 | Geometrical isomer of triazole compound and its preparation |
US06/130,108 US4554007A (en) | 1979-03-20 | 1980-03-13 | Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
IT48189/80A IT1143014B (en) | 1979-03-20 | 1980-03-18 | GEOMETRIC ISOMERS OF 1-SUBSTITUTED-1-TRIAZOLISTYRENE HERBICIDE FUNGICIDE AND REGULATOR OF PLANT GROWTH AND PROCEDURE FOR THEIR PREPARATION |
CA000347897A CA1154449A (en) | 1979-03-20 | 1980-03-18 | Geometrical isomer of 1-substituted-1- triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
NZ193168A NZ193168A (en) | 1979-03-20 | 1980-03-18 | Certain geometric isomers of 1-phenyl-2-(1,2,4-triazol-1-yl)-3-hydrocarbylpropan-3-ols |
BR8001617A BR8001617A (en) | 1979-03-20 | 1980-03-18 | GEOMETRIC ISOMER OF 1-SUBSTITUTED-1-TRIAZOLYL STYLENE, AND ITS PRODUCTION AND USE AS FUNGICIDE, HERBICIDE AND / OR PLANT GROWTH REGULATOR |
IL59671A IL59671A (en) | 1979-03-20 | 1980-03-19 | Geometrical isomers of 1-substituted-1-triazolylstyrenes and their production and use as herbicides and/or plant growth regulants |
PL1980222822A PL123010B1 (en) | 1979-03-20 | 1980-03-19 | Fungicidal, herbicidal and/or plant growth regulating agent and method of manufacture of novel derivatives of triazole |
AU56571/80A AU536825B2 (en) | 1979-03-20 | 1980-03-19 | Geometrical isomer of 1-substituted-1-triazolyl-styrenes |
GB8009190A GB2046260B (en) | 1979-03-20 | 1980-03-19 | Geometrical isomer of 1-substituted-1-triazolylstyrenes and their production and use as fungicides herbicides and/or plant growth regulations |
HU80652A HU186281B (en) | 1979-03-20 | 1980-03-19 | Fungicide, herbicide and control preparation of plant growing and process for producing 1-subsituted-1-triazoly-styrene derivatives used for same |
AR280359A AR226305A1 (en) | 1979-03-20 | 1980-03-19 | GEOMETRIC ISOMER OF DEL-FENIL-2-TRIAZOL (1,2,4) -PROPEN-3-OL USEFUL AS A HERBICIDE AND REGULATOR OF PLANT GROWTH |
DE19803010560 DE3010560A1 (en) | 1979-03-20 | 1980-03-19 | GEOMETRIC ISOMERS OF TRIAZOLE COMPOUNDS AND FUNGICIDES, HERBICIDES AND / OR PLANT GROWTH CONTROLLING AGENTS THEREOF |
YU766/80A YU42969B (en) | 1979-03-20 | 1980-03-19 | Process for producing geometric isomers of 1-substituted-1-triazolyl styroles |
CH217080A CH644851A5 (en) | 1979-03-20 | 1980-03-19 | GEOMETRIC E-ISOMERS OF 1-TRIAZOLYL STYRENE SUBSTITUTED. |
DK118580A DK157811C (en) | 1979-03-20 | 1980-03-19 | GEOMETRIC ISOMERS OF 1-SUBSTITUTED-1-TRIAZOLYL CONTROLS, INTERMEDIATE FOR USE BY THEIR PREPARATION AND FUNGICIDE, HERBICIDE AND / OR PLANT GROWTH REGULATOR CONTAINING THE GEOMETRIC ISOMERS |
FR8006155A FR2460939B1 (en) | 1979-03-20 | 1980-03-19 | 1-TRIAZOLYLSTYRENE 1-SUBSTITUTED GEOMETRIC ISOMERS, THEIR SYNTHESIS INTERMEDIATES, THEIR PRODUCTION AND THEIR USE IN AGRICULTURE AND HORTICULTURE |
NL8001658A NL192791C (en) | 1979-03-20 | 1980-03-20 | Substantially pure geometric isomer of 1-substituted 1-triazolystyrenes, methods of preparation thereof, as well as use as a fungicide, herbicide and / or plant growth control agent. |
FR8015966A FR2457859A1 (en) | 1979-04-05 | 1980-07-18 | GEOMETRIC ISOMERS OF 1-SUBSTITUTED 1-TRIAZOLYLSTYRENES, THEIR PREPARATION AND THEIR USE AS FUNGICIDES |
FR8015965A FR2457858A1 (en) | 1979-04-05 | 1980-07-18 | Geometrical isomers of 1-phenyl-2-triazolyl-penten-3-ol - and ether(s), useful as fungicides, herbicides, growth regulators and antimycotics |
US06/772,429 US4749716A (en) | 1979-03-20 | 1985-09-04 | Geometrical isomer of 1-substituted-1-triazolystyrenes |
MY898/87A MY8700898A (en) | 1979-03-20 | 1987-12-30 | Geometrical isomer of 1-substituted-1-triazolystyrenes, and their production and use as fungicides herbicides and/or plant growth regulants |
LVP-92-391A LV10023B (en) | 1979-03-20 | 1992-12-22 | Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12457179A JPS5646870A (en) | 1979-09-26 | 1979-09-26 | Geometrical isomer of triazole compound and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5646870A true JPS5646870A (en) | 1981-04-28 |
JPH0211589B2 JPH0211589B2 (en) | 1990-03-14 |
Family
ID=14888771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12457179A Granted JPS5646870A (en) | 1979-03-20 | 1979-09-26 | Geometrical isomer of triazole compound and its preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5646870A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63125276A (en) * | 1986-11-14 | 1988-05-28 | 京楽産業株式会社 | Winning apparatus of pinball machine |
JPH01133980U (en) * | 1988-03-04 | 1989-09-12 | ||
JPH01133979U (en) * | 1988-03-05 | 1989-09-12 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55147265A (en) * | 1979-04-05 | 1980-11-17 | Sumitomo Chem Co Ltd | Triazole geometrical isomer compound and its preparation |
JPS55154961A (en) * | 1979-05-19 | 1980-12-02 | Bayer Ag | Geometrical isomer of 4*44dimethyll11phenyll *1*2*44triazolee11yl**11pentenee33ol |
-
1979
- 1979-09-26 JP JP12457179A patent/JPS5646870A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55147265A (en) * | 1979-04-05 | 1980-11-17 | Sumitomo Chem Co Ltd | Triazole geometrical isomer compound and its preparation |
JPS55154961A (en) * | 1979-05-19 | 1980-12-02 | Bayer Ag | Geometrical isomer of 4*44dimethyll11phenyll *1*2*44triazolee11yl**11pentenee33ol |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63125276A (en) * | 1986-11-14 | 1988-05-28 | 京楽産業株式会社 | Winning apparatus of pinball machine |
JPH0467875B2 (en) * | 1986-11-14 | 1992-10-29 | Kyoraku Sangyo Kk | |
JPH01133980U (en) * | 1988-03-04 | 1989-09-12 | ||
JPH01133979U (en) * | 1988-03-05 | 1989-09-12 |
Also Published As
Publication number | Publication date |
---|---|
JPH0211589B2 (en) | 1990-03-14 |
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