JPS5564584A - Preparation of 3,7-diaminodibenzo-thiophene-5,5-dioxide - Google Patents
Preparation of 3,7-diaminodibenzo-thiophene-5,5-dioxideInfo
- Publication number
- JPS5564584A JPS5564584A JP13792078A JP13792078A JPS5564584A JP S5564584 A JPS5564584 A JP S5564584A JP 13792078 A JP13792078 A JP 13792078A JP 13792078 A JP13792078 A JP 13792078A JP S5564584 A JPS5564584 A JP S5564584A
- Authority
- JP
- Japan
- Prior art keywords
- dioxide
- catalyst
- hydrogen
- alkylamide
- diaminodibenzo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FUXZRRZSHWQAAA-UHFFFAOYSA-N 5,5-dioxodibenzothiophene-3,7-diamine Chemical compound C1=C(N)C=C2S(=O)(=O)C3=CC(N)=CC=C3C2=C1 FUXZRRZSHWQAAA-UHFFFAOYSA-N 0.000 title 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- YRXRGRLSHSSUNF-UHFFFAOYSA-N 3,7-dinitrodibenzothiophene 5,5-dioxide Chemical compound C1=C([N+]([O-])=O)C=C2S(=O)(=O)C3=CC([N+](=O)[O-])=CC=C3C2=C1 YRXRGRLSHSSUNF-UHFFFAOYSA-N 0.000 abstract 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium on carbon Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004760 aramid Substances 0.000 abstract 1
- 229920003235 aromatic polyamide Polymers 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 230000002194 synthesizing Effects 0.000 abstract 1
Abstract
PURPOSE: To obtain the title substance in high purity and yield, by hydrogenating a 3,7-dinitrodibenzothiophene-5,5-dioxide in the presence of a Pd-C catalyst in a solvent of an N-alkylamide at a specific partial pressure of hydrogen and a specified reaction temperature.
CONSTITUTION: A compound (D) of formula I is hydrogenated in the presence of 1W20wt% based on (D) of a supported Pd catalyst on carbon carrier in an N- alkylamide solvent, e.g. N,N-dimethyl-formamide, under a partial pressure of hydrogen of 1W100Kg/cm2.G at 20W140°C with agitation for 0.5W10hr to give the title substance.
USE: Useful as a diamine component for the synthesis of aromatic polyamides.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13792078A JPS6228792B2 (en) | 1978-11-10 | 1978-11-10 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13792078A JPS6228792B2 (en) | 1978-11-10 | 1978-11-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5564584A true JPS5564584A (en) | 1980-05-15 |
| JPS6228792B2 JPS6228792B2 (en) | 1987-06-23 |
Family
ID=15209768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13792078A Expired JPS6228792B2 (en) | 1978-11-10 | 1978-11-10 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6228792B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5360840A (en) * | 1992-12-29 | 1994-11-01 | Hercules Incorporated | Epoxy resin compositions with improved storage stability |
| US10497880B2 (en) | 2010-09-27 | 2019-12-03 | Semiconductor Energy Laboratory Co., Ltd. | Organic compound, light-emitting element, light-emitting device, electronic device, and lighting device |
-
1978
- 1978-11-10 JP JP13792078A patent/JPS6228792B2/ja not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5360840A (en) * | 1992-12-29 | 1994-11-01 | Hercules Incorporated | Epoxy resin compositions with improved storage stability |
| US10497880B2 (en) | 2010-09-27 | 2019-12-03 | Semiconductor Energy Laboratory Co., Ltd. | Organic compound, light-emitting element, light-emitting device, electronic device, and lighting device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6228792B2 (en) | 1987-06-23 |
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