JPS552641A - Preparation of alkoxysilane - Google Patents
Preparation of alkoxysilaneInfo
- Publication number
- JPS552641A JPS552641A JP7498178A JP7498178A JPS552641A JP S552641 A JPS552641 A JP S552641A JP 7498178 A JP7498178 A JP 7498178A JP 7498178 A JP7498178 A JP 7498178A JP S552641 A JPS552641 A JP S552641A
- Authority
- JP
- Japan
- Prior art keywords
- alkoxysilane
- copper catalyst
- mole
- integer
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To obtain an alkoxysilane, particularly a trialkoxysilane, in high yield and at a high reaction rate, by reacting silicon with an aliphatic alcohol in a solvent in the presence of a copper catalyst and a specific cyclic polyether.
CONSTITUTION: One mole of silicon is reacted with 0.1W50 moles of an aliphatic alcohol in a solvent, e.g. a hydrocarbon, in the presence of 0.0001W0.5 mole of a copper catalyst, e.g. metallic copper or its compound, and one or more types of cyclic polyethers of formula I (R is methylene, ethylene, propylene, 1,2-cyclohexylene, 1,2-phenylene, or 2,3-naphthalene group; n is an integer ≥ 3) in a molar amount of 0.01W10 times that of the copper catalyst at 100W300°C, preferably 150W250°C, to give an alkoxysilane of formula II (R is alkyl group; m is an integer 1W4, particularly 3).
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7498178A JPS552641A (en) | 1978-06-21 | 1978-06-21 | Preparation of alkoxysilane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7498178A JPS552641A (en) | 1978-06-21 | 1978-06-21 | Preparation of alkoxysilane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS552641A true JPS552641A (en) | 1980-01-10 |
JPS6145632B2 JPS6145632B2 (en) | 1986-10-08 |
Family
ID=13562963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7498178A Granted JPS552641A (en) | 1978-06-21 | 1978-06-21 | Preparation of alkoxysilane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS552641A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS611693A (en) * | 1984-06-12 | 1986-01-07 | Shin Etsu Chem Co Ltd | Preparation of alkoxysilane |
US4727173A (en) * | 1987-03-31 | 1988-02-23 | Union Carbide Corporation | Process for producing trialkoxysilanes from the reaction of silicon metal and alcohol |
US4761492A (en) * | 1987-09-28 | 1988-08-02 | Union Carbide Corporation | Process for recovering trimethoxysilane from a trimethoxysilane and methanol mixture |
US4762939A (en) * | 1987-09-30 | 1988-08-09 | Union Carbide Corporation | Process for trialkoxysilane/tetraalkoxysilane mixtures from silicon metal and alcohol |
USRE39650E1 (en) | 1996-10-10 | 2007-05-22 | General Electric Company | Surface-active additives in the direct synthesis of trialkoxysilanes |
US7339068B2 (en) | 2001-01-31 | 2008-03-04 | Momentive Performance Materials Inc. | Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes |
US7582788B2 (en) | 2006-12-01 | 2009-09-01 | Roston Family Llc | Process for preparation of alkoxysilanes |
US7652164B2 (en) | 2005-09-13 | 2010-01-26 | Momentive Performance Materials Inc. | Process for the direct synthesis of trialkoxysilane |
US7858818B2 (en) | 2001-01-31 | 2010-12-28 | Momentive Performance Materials Inc. | Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6365309A (en) * | 1986-09-08 | 1988-03-23 | Toyota Autom Loom Works Ltd | Warning method for life of clutch plate |
-
1978
- 1978-06-21 JP JP7498178A patent/JPS552641A/en active Granted
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS611693A (en) * | 1984-06-12 | 1986-01-07 | Shin Etsu Chem Co Ltd | Preparation of alkoxysilane |
US4727173A (en) * | 1987-03-31 | 1988-02-23 | Union Carbide Corporation | Process for producing trialkoxysilanes from the reaction of silicon metal and alcohol |
US4761492A (en) * | 1987-09-28 | 1988-08-02 | Union Carbide Corporation | Process for recovering trimethoxysilane from a trimethoxysilane and methanol mixture |
US4762939A (en) * | 1987-09-30 | 1988-08-09 | Union Carbide Corporation | Process for trialkoxysilane/tetraalkoxysilane mixtures from silicon metal and alcohol |
USRE39650E1 (en) | 1996-10-10 | 2007-05-22 | General Electric Company | Surface-active additives in the direct synthesis of trialkoxysilanes |
US7339068B2 (en) | 2001-01-31 | 2008-03-04 | Momentive Performance Materials Inc. | Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes |
US7495120B2 (en) | 2001-01-31 | 2009-02-24 | Momentive Performance Materials Inc. | Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes |
US7858818B2 (en) | 2001-01-31 | 2010-12-28 | Momentive Performance Materials Inc. | Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes |
EP2319851A1 (en) | 2001-01-31 | 2011-05-11 | General Electric Company | Nanosized copper catalyst precursors for the direct synthesis of trialkoxysilanes |
US7652164B2 (en) | 2005-09-13 | 2010-01-26 | Momentive Performance Materials Inc. | Process for the direct synthesis of trialkoxysilane |
US7582788B2 (en) | 2006-12-01 | 2009-09-01 | Roston Family Llc | Process for preparation of alkoxysilanes |
Also Published As
Publication number | Publication date |
---|---|
JPS6145632B2 (en) | 1986-10-08 |
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