JPS5497592A - Improved zeolite adsorber and its manufacture and uses - Google Patents

Improved zeolite adsorber and its manufacture and uses

Info

Publication number
JPS5497592A
JPS5497592A JP424478A JP424478A JPS5497592A JP S5497592 A JPS5497592 A JP S5497592A JP 424478 A JP424478 A JP 424478A JP 424478 A JP424478 A JP 424478A JP S5497592 A JPS5497592 A JP S5497592A
Authority
JP
Japan
Prior art keywords
acid
zeolite
treated
type zeolite
isomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP424478A
Other languages
Japanese (ja)
Inventor
Tetsuya Miyake
Koji Inada
Motohisa Asano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP424478A priority Critical patent/JPS5497592A/en
Priority to GB7901075A priority patent/GB2013641B/en
Priority to DE19792901081 priority patent/DE2901081C2/en
Priority to FR7901254A priority patent/FR2415076A1/en
Priority to NL7900468A priority patent/NL7900468A/en
Publication of JPS5497592A publication Critical patent/JPS5497592A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • B01J20/186Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity

Abstract

PURPOSE: To obtain denatured zeolite having greatly improved selective adsorbability for aromatic C8 hydrocarbons by treating faujasite type zeolite with an inorganic acid and/or an organic acid.
CONSTITUTION: A faujasite type zeolite, particularly Y-type zeolite of a SiO2/ Al2O3 molar ratio of 3 to 5, is brought into contact with an aqueous solution of an inorganic acid and/or an organic acid under the condition of pH 0.5 to 4.0 and 10 to 90°C. As the inorganic acid, hydrochloric acid may be cited, and also as the organic acid, acetic acid may be cited. The acid treatment increases the SiO2/ Al2O3 molar ratio of Y-type zeolite to 4.5 to 7.5. Then, the zeolite treated with the acid is substituted with combined ions, e.g., K-Ba, etc., to confer upon it a selective adsorbability for p-xylene suitable for the separation of isomers, and then the zeolite thus treated is treated by heating at more than 100°C, particularly at 300 to 600°C for activation. The zeolite is then used for the separation of isomers.
COPYRIGHT: (C)1979,JPO&Japio
JP424478A 1978-01-20 1978-01-20 Improved zeolite adsorber and its manufacture and uses Pending JPS5497592A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP424478A JPS5497592A (en) 1978-01-20 1978-01-20 Improved zeolite adsorber and its manufacture and uses
GB7901075A GB2013641B (en) 1978-01-20 1979-01-11 Zeolite adsorbent and method of preparing same
DE19792901081 DE2901081C2 (en) 1978-01-20 1979-01-12 Modified zeolite with a faujasite structure, process for its preparation and use
FR7901254A FR2415076A1 (en) 1978-01-20 1979-01-18 ZEOLITHE ADSORBANT AND ITS PREPARATION PROCESS
NL7900468A NL7900468A (en) 1978-01-20 1979-01-19 ZEOLIETADSORBENS AND THE METHOD FOR MANUFACTURE THEREOF.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP424478A JPS5497592A (en) 1978-01-20 1978-01-20 Improved zeolite adsorber and its manufacture and uses

Publications (1)

Publication Number Publication Date
JPS5497592A true JPS5497592A (en) 1979-08-01

Family

ID=11579124

Family Applications (1)

Application Number Title Priority Date Filing Date
JP424478A Pending JPS5497592A (en) 1978-01-20 1978-01-20 Improved zeolite adsorber and its manufacture and uses

Country Status (5)

Country Link
JP (1) JPS5497592A (en)
DE (1) DE2901081C2 (en)
FR (1) FR2415076A1 (en)
GB (1) GB2013641B (en)
NL (1) NL7900468A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104628010A (en) * 2013-11-08 2015-05-20 中国石油天然气股份有限公司 Modification treatment method of Y-type zeolite

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA805231B (en) * 1980-05-19 1981-08-26 Mobil Oil Corp Low acidity alkali metal containing zeolites
DE3120891A1 (en) * 1981-05-26 1982-12-23 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe METHOD FOR REMOVAL OR PARTIAL REMOVAL OF INTERESTING SUBSTANCES CONTAINED IN A FLOWING WATER, AND DEVICE FOR IMPLEMENTING THE METHOD
FR2540093B1 (en) * 1983-02-02 1987-01-23 Rhone Poulenc Spec Chim PROCESS FOR THE PREPARATION OF AN ALKALINE SILICO-ALUMINATE FOR USE IN TOOTHPASTE COMPOSITIONS
SE8402393D0 (en) * 1983-06-09 1984-05-03 Sten Andersson SET TO CLEAN AIR AND WATER FROM THE CALVET
EP0394948B1 (en) * 1989-04-24 1996-01-31 Kanebo Ltd. Stabilized synthetic zeolite and a process for the preparation thereof
US5443812A (en) * 1989-04-24 1995-08-22 Kanebo Ltd. Stabilized synthetic zeolite and a process for the preparation thereof
US5206195A (en) * 1990-05-31 1993-04-27 Kanebo Ltd. Stablized synthetic zeolite and a process for the preparation thereof
US5200168A (en) * 1992-01-31 1993-04-06 Mobil Oil Corp. Process for the dealumination of zeolite Beta
US5676914A (en) * 1994-04-26 1997-10-14 Competitive Technologies, Inc. Method for the destruction of methylene iodide
DE102017207817A1 (en) * 2017-05-09 2018-11-15 Clariant International Ltd Zeolite-containing adsorbent for the selective separation of isomers from aromatic hydrocarbon mixtures, its preparation and use

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5220455A (en) * 1975-08-11 1977-02-16 Sanyo Electric Co Ltd Heating hot-water delivery device

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE644432A (en) * 1964-02-27
FR1427463A (en) * 1964-03-23 1966-02-04 Socony Mobil Oil Co Process for preparing zeglitic-type materials with a high silica content
US3488146A (en) * 1967-09-01 1970-01-06 Mobil Oil Corp Method for preparing crystalline aluminosilicates of improved stability
US3686343A (en) * 1970-10-01 1972-08-22 Exxon Research Engineering Co Paraxylene recovery with zeolite adsorbent
JPS51106688A (en) * 1975-03-17 1976-09-21 Toray Industries
DE2617571A1 (en) * 1975-04-24 1976-11-11 Grace W R & Co PROCESS FOR MANUFACTURING ZEOLITHES WITH HIGH SILICON OXIDE-ALUMINUM OXIDE RATIO

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5220455A (en) * 1975-08-11 1977-02-16 Sanyo Electric Co Ltd Heating hot-water delivery device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104628010A (en) * 2013-11-08 2015-05-20 中国石油天然气股份有限公司 Modification treatment method of Y-type zeolite

Also Published As

Publication number Publication date
GB2013641B (en) 1982-07-21
NL7900468A (en) 1979-07-24
DE2901081C2 (en) 1986-03-27
DE2901081A1 (en) 1979-08-02
GB2013641A (en) 1979-08-15
FR2415076B1 (en) 1983-04-08
FR2415076A1 (en) 1979-08-17

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