JPS54129034A - Coating resin composition curable with actinic energy radiation - Google Patents

Coating resin composition curable with actinic energy radiation

Info

Publication number
JPS54129034A
JPS54129034A JP3698478A JP3698478A JPS54129034A JP S54129034 A JPS54129034 A JP S54129034A JP 3698478 A JP3698478 A JP 3698478A JP 3698478 A JP3698478 A JP 3698478A JP S54129034 A JPS54129034 A JP S54129034A
Authority
JP
Japan
Prior art keywords
meth
resin composition
energy radiation
actinic energy
acrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3698478A
Other languages
Japanese (ja)
Other versions
JPS6157875B2 (en
Inventor
Yuzo Tsunoda
Yoshihei Meiwa
Masaaki Namikata
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP53036984A priority Critical patent/JPS6157875B2/ja
Publication of JPS54129034A publication Critical patent/JPS54129034A/en
Publication of JPS6157875B2 publication Critical patent/JPS6157875B2/ja
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C08G18/683—Unsaturated polyesters containing cyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/343—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate in the form of urethane links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3215—Polyhydroxy compounds containing aromatic groups or benzoquinone groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4255—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing oxyalkylated carbocyclic groups and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C08G18/673—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing two or more acrylate or alkylacrylate ester groups

Abstract

PURPOSE: A coating resin composition rapidly curable with the irradiation of actinic energy radiation giving a coating film having excellent adhesivity, composed mainly of a specific (meth)acrylurethane resin and a (meth)acrylate having a polymerizable double bond.
CONSTITUTION: A resin composition composed of (A) 30W95 wt% of a (meth)acrylurethane resin obtained by the reaction of (a) a polyoxyalkylene bisphenol A of formula I or II (R1 is 2W4C alkylene; X is halogen, methyl; a is 1,2; m, n are integer of ≥1, provided that m + n is an integer of 2W8) or its derivative, with (b) a polyisocyanate and (c) a hydroxyl-containing (meth)acrylate, and (B) 70W5 wt% of a (meth)acrylate having a polymerizable double bond (e.g. acrylic acid ester).
COPYRIGHT: (C)1979,JPO&Japio
JP53036984A 1978-03-30 1978-03-30 Expired JPS6157875B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP53036984A JPS6157875B2 (en) 1978-03-30 1978-03-30

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP53036984A JPS6157875B2 (en) 1978-03-30 1978-03-30
DE19792910714 DE2910714A1 (en) 1978-03-30 1979-03-19 Radiation-curable synthetic resin coating compsn. - with excellent adhesion to polar surfaces is based on acrylo-urethane! resin and hydroxy-alkyl acrylate

Publications (2)

Publication Number Publication Date
JPS54129034A true JPS54129034A (en) 1979-10-06
JPS6157875B2 JPS6157875B2 (en) 1986-12-09

Family

ID=12485006

Family Applications (1)

Application Number Title Priority Date Filing Date
JP53036984A Expired JPS6157875B2 (en) 1978-03-30 1978-03-30

Country Status (2)

Country Link
JP (1) JPS6157875B2 (en)
DE (1) DE2910714A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5543179A (en) * 1978-07-24 1980-03-26 Ici America Inc Vinylester urethane

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3200907A1 (en) * 1982-01-14 1983-07-21 Bayer Ag, 5090 Leverkusen RADIATION-curable aqueous binder emulsions
BR8303781A (en) * 1982-07-28 1984-04-24 Goodyear Tire & Rubber Unsaturated polyurethane and process for its production
JPS6341782U (en) * 1986-09-03 1988-03-18
JP3220221B2 (en) * 1992-04-20 2001-10-22 ジェイエスアール株式会社 Liquid curable resin composition
NL9201304A (en) * 1992-07-21 1994-02-16 Dsm Nv A method of producing a coated, three-dimensionally shaped object.
US7375144B2 (en) 2005-06-16 2008-05-20 Eastman Chemical Company Abrasion resistant coatings

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5543179A (en) * 1978-07-24 1980-03-26 Ici America Inc Vinylester urethane
JPS5640163B2 (en) * 1978-07-24 1981-09-18

Also Published As

Publication number Publication date
JPS6157875B2 (en) 1986-12-09
DE2910714A1 (en) 1979-10-11

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