JPH11300516A - Cemented carbide end mill with excellent wear resistance - Google Patents

Cemented carbide end mill with excellent wear resistance

Info

Publication number
JPH11300516A
JPH11300516A JP11159098A JP11159098A JPH11300516A JP H11300516 A JPH11300516 A JP H11300516A JP 11159098 A JP11159098 A JP 11159098A JP 11159098 A JP11159098 A JP 11159098A JP H11300516 A JPH11300516 A JP H11300516A
Authority
JP
Japan
Prior art keywords
end mill
cemented carbide
cutting edge
forming component
wear resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP11159098A
Other languages
Japanese (ja)
Inventor
Kazuki Okada
一樹 岡田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP11159098A priority Critical patent/JPH11300516A/en
Publication of JPH11300516A publication Critical patent/JPH11300516A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23CMILLING
    • B23C5/00Milling-cutters
    • B23C5/02Milling-cutters characterised by the shape of the cutter
    • B23C5/10Shank-type cutters, i.e. with an integral shaft
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23CMILLING
    • B23C2210/00Details of milling cutters
    • B23C2210/20Number of cutting edges
    • B23C2210/203Number of cutting edges four

Abstract

PROBLEM TO BE SOLVED: To provide an end mill which exhibits an excellent wear resistance over the long run and to elongate its service life without the occurrence of a defect in a peripheral cutting edge, by endowing the entire peripheral cutting edge with toughness as high as that of cemented carbide used for inside part. SOLUTION: An end mill is formed of cemented carbide which comprises 6-15% of Co as a binding phase forming component; 0.1-2% of V and/or Cr as another binding phase forming component; and the remainder substantially of WC (tungsten carbide) as a dispersion phase forming component, an average particle diameter of WC particles being 1 μm or less. In addition, in a relief surface of a cutting edge at a peripheral cutting edge, a hard diffused boric layer is formed in a depth of 0.3-5 μm from the relief surface.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、超硬合金のもつ
すぐれた靭性を損なうことなく、耐摩耗性を著しく向上
させ、もって使用寿命の延命化を可能ならしめた超硬合
金製エンドミルに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cemented carbide end mill which significantly improves wear resistance without impairing the excellent toughness of cemented carbide, thereby extending service life. It is.

【0002】[0002]

【従来の技術】従来、一般にエンドミルが、図1(a)
に概略正面図で、同(b)に切刃部が概略縦断面図で例
示される通り、シャンク部と外周刃が形成された切刃部
からなり、かつ前記外周刃がすくい面と逃げ面で構成さ
れた形状をもち、さらにこれが超硬合金からなることも
良く知られるところである。
2. Description of the Related Art Conventionally, an end mill is generally used as shown in FIG.
As shown in the schematic front view in FIG. 2 and the cutting edge in FIG. 2B as a schematic longitudinal sectional view, the cutting edge comprises a shank portion and a cutting edge portion formed with an outer peripheral edge, and the outer peripheral edge has a rake face and a flank face. It is also well known that this has a shape composed of a cemented carbide.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
の省力化および省エネ化に対する要求は強く、これに伴
い、エンドミルにも使用寿命の一段の延命化が求められ
ているが、エンドミルを硬質の超硬合金で構成すると、
摩耗進行は抑制されるが、反面靭性不足は避けられず、
この結果切刃部の外周刃に欠けやチッピング(微小欠
け)などの欠損が発生し易くなり、一方欠損抑制の目的
で靭性の高い超硬合金で構成すると摩耗進行が速く、い
ずれの場合も使用寿命の延命化を図ることができないの
が現状である。
On the other hand, in recent years, there has been a strong demand for labor saving and energy saving in cutting, and with this demand, end mills are required to have a longer service life. When made of cemented carbide,
Wear progress is suppressed, but insufficient toughness is inevitable,
As a result, chips such as chipping and chipping (small chipping) are likely to occur in the outer cutting edge of the cutting edge. On the other hand, if the cutting edge is made of a cemented carbide with high toughness for the purpose of suppressing chipping, the wear progresses quickly, and it is used in any case. At present, the life cannot be extended.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、摩耗進行が遅く、特に切刃部の
外周刃に欠損の発生し難い超硬合金製エンドミルを開発
すべく研究を行った結果、エンドミルを、重量%で(以
下、単に%の表示は重量%を示す)、結合相形成成分と
してCo:6〜15%、同じく結合相形成成分としてV
および/またはCr:0.1〜2%、を含有し、残りが
実質的に分散相形成成分としての炭化タングステン(以
下、WCで示す)からなる組成を有し、かつWC粒の平
均粒径が1μm以下である超硬合金で構成すると共に、
切刃部の外周刃における逃げ面に、表面から0.3〜5
μmの深さに亘って、ほう素(B)元素を拡散させた拡
散ほう化層を形成すると、この結果のエンドミルにおい
ては、上記組成およびWC粒径の超硬合金によってすぐ
れた靭性が確保され、かつ上記拡散ほう化層はきわめて
硬質なので、これが耐摩耗性向上に寄与し、しかし前記
硬質拡散ほう化層は外周刃の逃げ面にのみ形成されてい
るので外周刃自体の靭性低下はなく、外周刃全体は内部
の超硬合金がもつ高靭性と同等の高靭性を保持すること
から、前記外周刃に欠損が発生することはなく、エンド
ミルとして長期に亘ってすぐれた耐摩耗性を発揮し、使
用寿命の延命化を可能にするという研究結果を得たので
ある。
Means for Solving the Problems Accordingly, the present inventors have
From the above-mentioned viewpoints, as a result of researching to develop a cemented carbide end mill in which wear progresses slowly, and in particular, hardly causes chipping on the outer peripheral edge of the cutting edge portion, the end mill was reduced by weight% (hereinafter simply referred to as % Indicates weight%), Co: 6 to 15% as a binder phase-forming component, and V as a binder phase-forming component.
And / or Cr: 0.1 to 2%, the balance being substantially composed of tungsten carbide (hereinafter referred to as WC) as a dispersed phase forming component, and the average particle diameter of WC grains Is made of a cemented carbide having a diameter of 1 μm or less,
The flank of the outer peripheral edge of the cutting edge portion is 0.3 to 5 from the surface.
When a diffusion boride layer in which boron (B) element is diffused is formed over a depth of μm, in the resulting end mill, excellent toughness is secured by the cemented carbide having the above composition and WC grain size. And, since the diffusion boride layer is extremely hard, this contributes to the improvement of wear resistance.However, since the hard diffusion boride layer is formed only on the flank of the outer peripheral edge, there is no decrease in toughness of the outer peripheral edge itself, Since the entire outer peripheral edge retains the high toughness equivalent to the high toughness of the cemented carbide inside, there is no occurrence of fracture in the outer peripheral edge, and it exhibits excellent wear resistance over a long period as an end mill. The research results show that the service life can be extended.

【0005】この発明は、上記の研究結果に基づいてな
されたものであって、結合相形成成分としてCo:6〜
15%、同じく結合相形成成分としてVおよび/または
Cr:0.1〜2%、を含有し、残りが実質的に分散相
形成成分としてのWCからなる組成を有し、WC粒の平
均粒径が1μm以下である超硬合金で構成すると共に、
切刃部の外周刃における逃げ面に、表面から0.3〜5
μmの深さに亘って硬質拡散ほう化層を形成してなる、
耐摩耗性のすぐれた超硬合金製エンドミルに特徴を有す
るものである。
The present invention has been made based on the results of the above-mentioned research, wherein Co: 6 to
15%, also containing V and / or Cr: 0.1 to 2% as a binder phase-forming component, with the balance substantially consisting of WC as a dispersed phase-forming component, and the average grain size of WC grains It is made of cemented carbide having a diameter of 1 μm or less,
The flank of the outer peripheral edge of the cutting edge portion is 0.3 to 5 from the surface.
forming a hard diffusion boride layer over a depth of μm,
It is characterized by a cemented carbide end mill with excellent wear resistance.

【0006】つぎに、この発明のエンドミルにおいて、
これを構成する超硬合金の組成およびWC粒の平均粒
径、さらに硬質拡散ほう化層の深さを上記の通りに限定
した理由を説明する。 (A) 超硬合金の組成 (a) Co Co成分は焼結性を向上させ、かつ結合相を形成して靭
性を向上させ、もって微細なWC粒と相まって、切刃部
の外周刃に欠損が発生するのを抑制する作用をもつが、
その含有量が6%未満ではエンドミルに必要な十分な靭
性を確保することができず、一方その含有量が15%を
越えると耐摩耗性が急激に低下するようになることか
ら、その含有量を6〜15%、望ましくは8〜13%と
定めた。 (b) VおよびCr これらの成分は、結合相を形成して焼結時におけるWC
粒の成長を抑制する作用をもつが、その含有量が0.1
%未満では、原料粉末であるWC粉末の平均粒径を1μ
m以下にしても焼結時に粒成長して1μmを越えた平均
粒径になってしまい、所望の靭性を確保することができ
ず、切刃部の外周刃に欠損が発生するようになり、一方
その含有量が2%を越えると結合相自体の靭性が低下
し、欠損発生の原因となることから、その含有量を0.
1〜2%、望ましくは0.5〜1.5%と定めた。
Next, in the end mill of the present invention,
The reason for limiting the composition of the cemented carbide and the average particle size of the WC grains, and the depth of the hard diffusion boride layer as described above will be described. (A) Composition of cemented carbide (a) Co The Co component improves the sinterability and forms a binder phase to improve the toughness, and thus, combined with fine WC grains, causes a defect in the outer cutting edge of the cutting edge. Has the effect of suppressing the occurrence of
If the content is less than 6%, sufficient toughness required for an end mill cannot be secured. On the other hand, if the content exceeds 15%, the abrasion resistance rapidly decreases. Was determined to be 6 to 15%, preferably 8 to 13%. (B) V and Cr These components form a binder phase to form WC during sintering.
It has the effect of suppressing grain growth, but its content is 0.1
%, The average particle size of the WC powder as the raw material powder is 1 μm.
m or less, the particles grow during sintering and have an average particle size exceeding 1 μm, so that the desired toughness cannot be secured, and the outer peripheral edge of the cutting edge portion is broken, On the other hand, if the content exceeds 2%, the toughness of the binder phase itself decreases, which causes the occurrence of defects.
1-2%, desirably 0.5-1.5%.

【0007】(B) WC粒の平均粒径 WC粒の平均粒径は、上記の通り原料粉末としてのWC
粉末の平均粒径およびVおよびCr含有量によって調整
するが、その平均粒径が1μmを越えると、WC粒粗大
化に伴う靭性低下が著しくなり、切刃部の外周刃に欠損
が発生し易くなることから、その平均粒径を1μm以下
と定めた。
(B) Average particle size of WC particles The average particle size of WC particles is as described above.
The average particle diameter and the V and Cr contents are adjusted depending on the powder. If the average particle diameter exceeds 1 μm, the toughness is significantly reduced due to the coarsening of the WC grains, and the outer edge of the cutting edge is liable to be chipped. Therefore, the average particle size was set to 1 μm or less.

【0008】(C) 硬質拡散ほう化層の深さ その深さが0.3μm未満では所望の耐摩耗性向上効果
が得られず、一方その深さが5μmを越えると外周刃の
靭性が低下し、欠けやチッピングが多発するようになる
ことから、その深さを0.3〜5μm、望ましくは0.
5〜3μmと定めた。
(C) Depth of Hard Diffusion Boron Layer If the depth is less than 0.3 μm, the desired effect of improving wear resistance cannot be obtained, while if the depth exceeds 5 μm, the toughness of the outer peripheral edge decreases. However, since chipping and chipping occur frequently, the depth is set to 0.3 to 5 μm, preferably 0.1 to 5 μm.
It was determined to be 5 to 3 μm.

【0009】なお、この発明のエンドミルにおける硬質
拡散ほう化層は、エンドミルの外周刃の逃げ面以外の表
面を、例えば酸化アルミニウム(以下、Al23 で示
す)微粉末などを懸濁してなるアルコール溶液を用い
て、マスキングを行い、これをほう化処理炉に装入し、
これに、例えば水素に塩化ボロンを1〜5容量%の割合
で配合してなる混合ガスを導入し、炉内雰囲気圧力を2
〜10Torrとした状態で、650〜900℃の温度
に5〜30分間保持の条件でほう化処理を施すことによ
って、前記マスキングを行わない外周刃の逃げ面に所定
深さに亘って形成することができる。
The hard diffusion boride layer in the end mill according to the present invention is formed by suspending, for example, fine powder of aluminum oxide (hereinafter referred to as Al 2 O 3 ) on the surface other than the flank of the peripheral edge of the end mill. Using an alcohol solution, perform masking and charge it into a boring furnace,
For example, a mixed gas obtained by mixing boron chloride with hydrogen at a ratio of 1 to 5% by volume is introduced into the furnace, and the atmospheric pressure in the furnace is set to 2
A boring process is performed at a temperature of 650 to 900 [deg.] C. for 5 to 30 minutes under a condition of 10 to 10 Torr to form a predetermined depth on the flank of the outer peripheral blade which is not masked. Can be.

【0010】[0010]

【発明の実施の形態】つぎに、この発明の超硬合金製エ
ンドミルを実施例により具体的に説明する。原料粉末と
して、それぞれ平均粒径:0.8μmのWC粉末、同
1.5μmのVC粉末、同2.3μmのCr3 2
末、および同1.2μmのCo粉末を用意し、これら原
料粉末を所定の割合に配合し、湿式ボールミルで72時
間混合し、減圧乾燥した後、1ton/cm2 の圧力
で、7〜30mmの範囲内の所定の直径を有し、かつ5
0〜135mmの範囲内の所定の長さを有する長尺状成
形体にプレス成形し、これらの長尺状成形体を真空中、
1380〜1480℃の範囲内の所定温度に1時間保持
の条件で焼結して、表1に示される結合相形成成分含有
量にして、実質的に残りのWC粒が同じく表1に示され
る平均粒径を有する長尺状焼結素材とし、これらの長尺
状焼結素材から研削加工にて表1に示される外周刃外径
および長さをもった図1に示す形状の4枚刃のエンドミ
ル本体A〜Hを成形し、これらのエンドミル本体A〜H
の切刃部における外周刃の逃げ面を除く全ての面を、平
均粒径:1.0μmのAl2 3 粉末を懸濁してなるア
ルコール溶液を塗布してマスキングを施した後、5To
rrのH2 +3容量%BCl3 の混合ガス中、温度:7
50℃に5〜30分の範囲内の所定時間保持の条件でほ
う化処理を行い、前記外周刃の逃げ面にほう素(B)元
素を拡散させ、それぞれ表2に示される深さの硬質拡散
ほう化層を形成し、最終的に前記マスキングを除去する
ことにより本発明エンドミル1〜8をそれぞれ製造し
た。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, a cemented carbide end mill according to the present invention will be specifically described with reference to examples. As raw material powders, WC powder having an average particle diameter of 0.8 μm, VC powder of 1.5 μm, Cr 3 C 2 powder of 2.3 μm, and Co powder of 1.2 μm were prepared. Are mixed in a predetermined ratio, mixed in a wet ball mill for 72 hours, dried under reduced pressure, and then at a pressure of 1 ton / cm 2 , having a predetermined diameter in the range of 7 to 30 mm, and 5
It is press-molded into long shaped bodies having a predetermined length in the range of 0 to 135 mm, and these long shaped bodies are placed in a vacuum,
Sintering is performed at a predetermined temperature in the range of 1380 to 1480 ° C. for 1 hour to obtain a binder phase forming component content shown in Table 1, and substantially the remaining WC grains are also shown in Table 1. A long-sintered sintered material having an average particle size, and a four-blade having the outer diameter and length shown in Table 1 by grinding from the long-sintered material and having a shape shown in FIG. End mill bodies A to H are formed, and these end mill bodies A to H
After applying an alcohol solution of an Al 2 O 3 powder having an average particle diameter of 1.0 μm to all surfaces except the flank of the outer peripheral edge of the cutting edge portion, the surface is masked by applying 5 To.
rr in a mixed gas of H 2 + 3% by volume BCl 3 , temperature: 7
Boriding treatment is performed at 50 ° C. for a predetermined time within a range of 5 to 30 minutes to diffuse boron (B) element into the flank of the outer peripheral edge. The end mills 1 to 8 of the present invention were manufactured by forming a diffusion boride layer and finally removing the masking.

【0011】この結果得られた本発明エンドミル1〜
8、並びに比較の目的で上記のエンドミル本体A〜Hを
それぞれ比較エンドミル1〜8として用い、 (a) 被削材:S50C(硬さ:HB 240)、 切削速度:60m/min、 送り:0.015mm/rev、 軸方向切り込み:4.5mm、 径方向切り込み:0.3mm、 (b) 被削材:S50C(硬さ:HB 240)、 切削速度:60m/min、 送り:0.025mm/rev、 軸方向切り込み:7.5mm、 径方向切り込み:0.5mm、 (c) 被削材:S50C(硬さ:HB 240)、 切削速度:60m/min、 送り:0.04mm/rev、 軸方向切り込み:12 mm、 径方向切り込み:0.8mm、 (d) 被削材:S50C(硬さ:HB 240)、 切削速度:60m/min、 送り:0.05mm/rev、 軸方向切り込み:15mm、 径方向切り込み:1mm、 (e) 被削材:S50C(硬さ:HB 240)、 切削速度:60m/min、 送り:0.1mm/rev、 軸方向切り込み:24mm、 径方向切り込み:1.6mm、 (f) 被削材:S50C(硬さ:HB 240)、 切削速度:60m/min、 送り:0.16mm/rev、 軸方向切り込み:37,5mm、 径方向切り込み:2.5mm、 以上(a)〜(f)条件のうちのいずれかの条件(表3
に表示)で炭素鋼の湿式切削試験を行い、逃げ面摩耗幅
が0.3mmに至るまでの切削長さを測定した。これら
の測定結果を表3に示した。
The resulting end mills 1 to 5 of the present invention
8, and for the purpose of comparison, the above-mentioned end mill bodies A to H were used as comparative end mills 1 to 8, respectively. (A) Work material: S50C (hardness: HB 240), Cutting speed: 60 m / min, Feed: 0 0.015 mm / rev, axial cut: 4.5 mm, radial cut: 0.3 mm, (b) work material: S50C (hardness: HB 240), cutting speed: 60 m / min, feed: 0.025 mm / rev, axial cut: 7.5 mm, radial cut: 0.5 mm, (c) work material: S50C (hardness: HB 240), cutting speed: 60 m / min, feed: 0.04 mm / rev, shaft Cut in direction: 12 mm, Cut in radial direction: 0.8 mm, (d) Work material: S50C (hardness: HB240), Cutting speed: 60 m / min, Feed: 0.05 mm / rev, Directional cut: 15 mm, radial cut: 1 mm, (e) Work material: S50C (hardness: HB240), cutting speed: 60 m / min, feed: 0.1 mm / rev, axial cut: 24 mm, radial Cutting depth: 1.6 mm, (f) Work material: S50C (hardness: HB 240), Cutting speed: 60 m / min, Feeding: 0.16 mm / rev, Axial cutting: 37,5 mm, Radial cutting: 2 0.5 mm, any one of the above conditions (a) to (f) (Table 3
), A wet cutting test of carbon steel was performed, and the cutting length until the flank wear width reached 0.3 mm was measured. Table 3 shows the results of these measurements.

【0012】[0012]

【表1】 [Table 1]

【0013】[0013]

【表2】 [Table 2]

【0014】[0014]

【表3】 [Table 3]

【0015】[0015]

【発明の効果】表3に示される結果から、本発明エンド
ミル1〜8は、いずれも硬質拡散ほう化層を外周刃の逃
げ面にのみ形成し、この硬質拡散ほう化層によって外周
刃の靭性が損なわれることがないので、前記外周刃に欠
けやチッピングなどの発生なく、これの形成がない比較
エンドミル1〜8に比して一段とすぐれた耐摩耗性を示
すことが明らかである。上述のように、この発明のエン
ドミルは、外周刃に欠けやチッピングの発生なく、すぐ
れた耐摩耗性を長期に亘って発揮するものであり、使用
寿命の延命化を可能とするものである。
From the results shown in Table 3, all of the end mills 1 to 8 of the present invention have the hard diffusion boride layer formed only on the flank of the outer peripheral edge, and the hard diffusion boride layer has the toughness of the outer peripheral edge. It is evident that the outer edge does not suffer from chipping, chipping, etc., and exhibits a much higher abrasion resistance than the comparative end mills 1 to 8 which do not have the same. As described above, the end mill according to the present invention exhibits excellent wear resistance over a long period of time without chipping or chipping of the outer peripheral edge, and can extend the service life.

【図面の簡単な説明】[Brief description of the drawings]

【図1】エンドミルの概略正面図(a)、および同切刃
部の概略縦断面図(b)である。
FIG. 1 is a schematic front view of an end mill (a) and a schematic longitudinal sectional view of the cutting blade portion (b).

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 重量%で、 結合相形成成分としてCo:6〜15%、 同じく結合相形成成分としてVおよび/またはCr:
0.1〜2%、を含有し、残りが実質的に分散相形成成
分としての炭化タングステンからなる組成を有し、かつ
炭化タングステン粒の平均粒径が1μm以下である超硬
合金で構成すると共に、 切刃部の外周刃における逃げ面に、表面から0.3〜5
μmの深さに亘って硬質拡散ほう化層を形成したことを
特徴とする耐摩耗性のすぐれた超硬合金製エンドミル。
1% by weight, Co: 6 to 15% as a binder phase-forming component, and V and / or Cr:
0.1 to 2%, the balance being substantially composed of tungsten carbide as a dispersed phase forming component, and comprising a cemented carbide having an average particle size of tungsten carbide particles of 1 μm or less. At the same time, on the flank of the outer peripheral edge of the cutting edge, 0.3 to 5
An end mill made of a hard metal having excellent wear resistance, wherein a hard diffusion boride layer is formed over a depth of μm.
JP11159098A 1998-04-22 1998-04-22 Cemented carbide end mill with excellent wear resistance Withdrawn JPH11300516A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11159098A JPH11300516A (en) 1998-04-22 1998-04-22 Cemented carbide end mill with excellent wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11159098A JPH11300516A (en) 1998-04-22 1998-04-22 Cemented carbide end mill with excellent wear resistance

Publications (1)

Publication Number Publication Date
JPH11300516A true JPH11300516A (en) 1999-11-02

Family

ID=14565231

Family Applications (1)

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Country Status (1)

Country Link
JP (1) JPH11300516A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001287114A (en) * 2000-04-10 2001-10-16 Nachi Fujikoshi Corp Cemented carbide end mill
WO2002014568A2 (en) * 2000-08-11 2002-02-21 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
JP2002126934A (en) * 2000-10-27 2002-05-08 Nachi Fujikoshi Corp Cemented carbide end mill
US6575671B1 (en) 2000-08-11 2003-06-10 Kennametal Inc. Chromium-containing cemented tungsten carbide body
US6612787B1 (en) 2000-08-11 2003-09-02 Kennametal Inc. Chromium-containing cemented tungsten carbide coated cutting insert
US8841005B2 (en) 2006-10-25 2014-09-23 Kennametal Inc. Articles having improved resistance to thermal cracking
US8858870B2 (en) 2008-08-22 2014-10-14 Kennametal Inc. Earth-boring bits and other parts including cemented carbide
US9016406B2 (en) 2011-09-22 2015-04-28 Kennametal Inc. Cutting inserts for earth-boring bits
US9266171B2 (en) 2009-07-14 2016-02-23 Kennametal Inc. Grinding roll including wear resistant working surface
US9435010B2 (en) 2009-05-12 2016-09-06 Kennametal Inc. Composite cemented carbide rotary cutting tools and rotary cutting tool blanks
US9643236B2 (en) 2009-11-11 2017-05-09 Landis Solutions Llc Thread rolling die and method of making same

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001287114A (en) * 2000-04-10 2001-10-16 Nachi Fujikoshi Corp Cemented carbide end mill
US6612787B1 (en) 2000-08-11 2003-09-02 Kennametal Inc. Chromium-containing cemented tungsten carbide coated cutting insert
WO2002014568A3 (en) * 2000-08-11 2002-05-10 Kennametal Inc Chromium-containing cemented carbide body having a surface zone of binder enrichment
US6554548B1 (en) 2000-08-11 2003-04-29 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
US6575671B1 (en) 2000-08-11 2003-06-10 Kennametal Inc. Chromium-containing cemented tungsten carbide body
WO2002014568A2 (en) * 2000-08-11 2002-02-21 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
US6866921B2 (en) 2000-08-11 2005-03-15 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
JP2002126934A (en) * 2000-10-27 2002-05-08 Nachi Fujikoshi Corp Cemented carbide end mill
US8841005B2 (en) 2006-10-25 2014-09-23 Kennametal Inc. Articles having improved resistance to thermal cracking
US8858870B2 (en) 2008-08-22 2014-10-14 Kennametal Inc. Earth-boring bits and other parts including cemented carbide
US9435010B2 (en) 2009-05-12 2016-09-06 Kennametal Inc. Composite cemented carbide rotary cutting tools and rotary cutting tool blanks
US9266171B2 (en) 2009-07-14 2016-02-23 Kennametal Inc. Grinding roll including wear resistant working surface
US9643236B2 (en) 2009-11-11 2017-05-09 Landis Solutions Llc Thread rolling die and method of making same
US9016406B2 (en) 2011-09-22 2015-04-28 Kennametal Inc. Cutting inserts for earth-boring bits

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