JPH11176447A - Battery and manufacture thereof - Google Patents

Battery and manufacture thereof

Info

Publication number
JPH11176447A
JPH11176447A JP9340312A JP34031297A JPH11176447A JP H11176447 A JPH11176447 A JP H11176447A JP 9340312 A JP9340312 A JP 9340312A JP 34031297 A JP34031297 A JP 34031297A JP H11176447 A JPH11176447 A JP H11176447A
Authority
JP
Japan
Prior art keywords
battery
electrode
active material
winding
current collector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9340312A
Other languages
Japanese (ja)
Inventor
Norikazu Adachi
安達  紀和
Jun Hasegawa
順 長谷川
Satoru Suzuki
覚 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denso Corp
Original Assignee
Denso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denso Corp filed Critical Denso Corp
Priority to JP9340312A priority Critical patent/JPH11176447A/en
Publication of JPH11176447A publication Critical patent/JPH11176447A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

PROBLEM TO BE SOLVED: To provide an electrode constitution, and a battery manufacturing method for reducing electrode winding shifting in a winding type battery. SOLUTION: For a positive electrode 8 and a negative electrode 9, collectors 80, 90 respectively comprising active material attachment zones 8a, 9a and non-attachment zones 8b, 9b are formed by rolling and pressing, and they are wound around a shaft core 2 via a separator 10. The electrodes 8, 9 are welded with end plates 13, 14 at the non-attachment zones 8b, 9b of the collectors 80, 90 extended along a winding direction to be continuous with a positive electrode terminal 3 and a negative electrode terminal 4. In the non-attachment zones 8b, 9b, plural slits 11 and holes 12 are formed to absorb electrode strain stresses.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、電極活物質を付着
させた集電体を巻回してなる電極を備えた電池、及びそ
の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a battery provided with an electrode formed by winding a current collector having an electrode active material attached thereto, and a method of manufacturing the battery.

【0002】[0002]

【従来の技術】電極活物質を付着させた集電体を巻回し
てなる電極を備えた電池(以下、巻回型電池という)に
おいては、電池の電極に電子の授受を行うために、従来
は、例えば、四角形状の金属箔を集電体に用い、この集
電体に電極活物質を付着させたものを円筒状に巻回した
電極とし、巻回した電極の集電体から金属等からなるリ
ード線を取り回し、正負極の端子につなげる構造として
いる。
2. Description of the Related Art In a battery provided with an electrode formed by winding a current collector to which an electrode active material is attached (hereinafter referred to as a wound battery), a conventional method is used to transfer electrons to and from the battery electrode. For example, a rectangular metal foil is used as a current collector, an electrode obtained by attaching an electrode active material to the current collector is formed into a cylindrically wound electrode. The structure is such that lead wires made of are connected and connected to positive and negative terminals.

【0003】しかし、この方法では、大電流を流した場
合、リード部分の抵抗が高くなる理由と、リード線に近
い部分に電流が集中する理由で、容量特性、サイクル特
性、出力密度、回生密度等の電池特性が悪くなるという
問題がある。この問題を解決するために、集電体にリー
ド線を付けるのではなく、集電体の金属箔の端部をリー
ド部として用い、巻回して円筒状となった集電体の上下
端面を、正負極の端子に導通する金属板等に溶接する事
で、抵抗の減少、電流分布の均一化を図っている。
However, according to this method, when a large current flows, the resistance of the lead portion increases and the current concentrates on a portion close to the lead wire. However, there is a problem that the battery characteristics such as these deteriorate. In order to solve this problem, instead of attaching a lead wire to the current collector, the end of the metal foil of the current collector is used as a lead portion, and the upper and lower end surfaces of the wound current collector are formed. By welding to a metal plate or the like conducting to the positive and negative terminals, the resistance is reduced and the current distribution is made uniform.

【0004】[0004]

【発明が解決しようとする課題】ところで、この方法で
用いる電極は、端面で溶接する時の溶接条件から、集電
体において、金属箔の巻回方向に沿った縁部において、
少なくとも端部から2〜3mmは金属部分を露出させる
必要がある。このような電極を製造する方法として、集
電体に活物質(電極材料)を付着させた後必要部分のみ
活物質をはがす方法、及び、活物質付着時に集電体に未
付着部分を設ける方法がある。
By the way, the electrode used in this method has a problem that the welding conditions at the time of welding at the end face cause the current collector to have an edge portion along the winding direction of the metal foil.
It is necessary to expose the metal part at least 2-3 mm from the end. As a method for manufacturing such an electrode, a method in which an active material (electrode material) is attached to a current collector and then the active material is peeled off only at a necessary portion, and a method in which an unattached portion is provided on the current collector when the active material is attached There is.

【0005】前者の活物質をはがす方法では、活物質と
付着性が悪いと電池のサイクル特性が悪くなるのを防止
すべく、活物質を集電体上に強固に付着させてあるた
め、一旦強固に付着した活物質を剥がすのは効率が悪
く、量産性にむかないと考えられる。一方、活物質付着
時に集電体に未付着部分を設ける方法では、図6(a)
に示す様に、金属箔からなる集電体80上に活物質の付
着領域8aと非付着領域8bとを設け、塗布部材(コン
マコータ)P1にて活物質の塗工を行い、次に図6
(b)に示す様に、ロールプレスP2により活物質の付
着強度の向上および電極密度の向上のために圧延(プレ
ス成形)を行い、カッティングする。すると図4(a)
に示す様に、電極8が形成される。
In the former method of removing the active material, the active material is firmly adhered to the current collector in order to prevent the cycle characteristics of the battery from being deteriorated if the adhesion to the active material is poor. It is considered that removing the strongly adhered active material is inefficient and is not suitable for mass production. On the other hand, in the method of providing an unattached portion on the current collector when the active material is attached, FIG.
As shown in FIG. 6, an active material attaching region 8a and a non-adhering region 8b are provided on a current collector 80 made of a metal foil, and the active material is applied by a coating member (comma coater) P1.
As shown in (b), rolling (press molding) is performed by a roll press P2 to improve the adhesive strength of the active material and the electrode density, and then cutting is performed. Then, FIG. 4 (a)
The electrode 8 is formed as shown in FIG.

【0006】そして、この電極8を巻回して電池に組付
けるのであるが、巻回時に、巻きずれが生じ、図4
(b)に示す様に巻回した電極8を電池に組付けたとき
に、巻回した電極8の円筒端面が平面状に揃わず、ずれ
(以下、巻回ずれという)yを生じる。ちなみに、図4
(b)において電極8は正極、9は負極、2は軸芯、1
0はセパレータを示すが、正負は逆でもよい。
[0006] Then, the electrode 8 is wound and assembled into a battery. At the time of winding, a winding shift occurs, and FIG.
As shown in (b), when the wound electrode 8 is assembled to the battery, the cylindrical end faces of the wound electrode 8 are not aligned in a plane, and a displacement (hereinafter referred to as a winding displacement) y occurs. By the way, FIG.
In (b), electrode 8 is a positive electrode, 9 is a negative electrode, 2 is a shaft core, 1
Although 0 indicates a separator, the sign may be reversed.

【0007】このような巻回ずれyが大きい(例えば、
20mm程度)と、例えば、電池の容器内に納まらな
い、或いは、正負極の端子に導通する金属製の端面プレ
ートと巻回した電極8の円筒端面との接触が不均一とな
り両者の溶接がうまく行かない等の問題が起こってく
る。従って、巻回ずれyは小さいほど良い。本発明者等
は、この巻回ずれyの原因について検討を進めた。その
結果、上記圧延工程において、集電体80上には付着領
域8aと非付着領域8bが存在するため、圧延時に両領
域8a、8bの伸びの違いによって、図4(a)に示す
様に、圧延後の集電体80平面内において、電極8自体
が巻回方向に円弧状に曲がったものとなるためであるこ
とがわかった。この円弧状のそりxが大きい電極8を巻
回すると、上記巻回ずれyが大きいものとなる。
Such a winding deviation y is large (for example,
For example, the contact between the metal end plate that does not fit in the battery container or the metal end plate that conducts to the terminals of the positive and negative electrodes and the cylindrical end surface of the wound electrode 8 becomes non-uniform, and welding of the two is performed well. Problems such as not going will occur. Therefore, the smaller the winding deviation y, the better. The present inventors have studied the cause of the winding deviation y. As a result, in the above-mentioned rolling process, since the adhering region 8a and the non-adhering region 8b exist on the current collector 80, the difference in elongation between the two regions 8a and 8b during the rolling causes the difference as shown in FIG. It was found that the reason was that the electrode 8 itself was bent in an arc shape in the winding direction in the plane of the current collector 80 after rolling. When the electrode 8 having a large arc-shaped warp x is wound, the winding deviation y becomes large.

【0008】本発明は上記点に鑑みて、巻回型電池にお
いて、電極の巻回ずれを低減する電極構成及び電池の製
造方法を提供することを目的とする。
SUMMARY OF THE INVENTION In view of the above, it is an object of the present invention to provide an electrode configuration and a method of manufacturing a battery in a wound type battery, which reduce the winding deviation of the electrodes.

【0009】[0009]

【課題を解決するための手段】本発明者等は、リード部
を一体化した集電体を巻回してなる電極において、集電
体に、上記円弧状のそりxによる歪みを吸収するための
吸収部を設けることに着目し、以下の技術的手段を採用
することとした。すなわち、請求項1記載の発明におい
ては、同一面上に電極活物質が付着した付着領域(8
a、9a)と、電極活物質が付着していない非付着領域
(8b、9b)とを有する導電性の箔を圧延して形成さ
れた集電体(80、90)を巻回してなる電極(8、
9)を備え、非付着領域(8b、9b)が集電体(8
0、90)のうち巻回方向に沿って延びる縁部(81、
91)に設けられている電池において、縁部(81、9
1)には歪みを吸収するための切欠部(11、12)が
形成されていることを特徴とする。
Means for Solving the Problems The inventors of the present invention have developed an electrode formed by winding a current collector having a lead portion integrated therein, and having the current collector absorb the distortion caused by the arc-shaped warp x. Focusing on providing the absorbing section, the following technical means were adopted. That is, according to the first aspect of the present invention, the region (8) where the electrode active material is
a, 9a) and an electrode formed by winding a current collector (80, 90) formed by rolling a conductive foil having non-adhered regions (8b, 9b) to which no electrode active material is adhered. (8,
9), and the non-adhesion regions (8b, 9b) are provided with a current collector (8b).
0, 90) extending along the winding direction (81,
91), the edges (81, 9)
1) is characterized in that notches (11, 12) for absorbing distortion are formed.

【0010】それによって、上記円弧状のそりの応力を
切欠部(11、12)で吸収することで低減できる。従
って、巻回後の電極(8、9)において巻回ずれを低減
した巻回型電池を提供することができる。ここで、切欠
部は、請求項2記載の発明のように、上記縁部(81、
91)において箔の外周端部(82、92)から切込ま
れたスリット(11)、および縁部(81、91)にお
いて箔の外周端部(82、92)よりも内側に形成され
た空孔(12)の少なくとも一方から構成されているも
のにできる。
Accordingly, the stress of the arc-shaped warp can be reduced by absorbing the stress in the notches (11, 12). Therefore, it is possible to provide a wound type battery in which winding deviations in the wound electrodes (8, 9) are reduced. Here, the notch is formed by the edge (81,
The slit (11) cut from the outer peripheral edge (82, 92) of the foil at 91) and the void formed inside the outer peripheral edge (82, 92) of the foil at the edge (81, 91). It can be composed of at least one of the holes (12).

【0011】また、このようなスリット(11)及び空
孔(12)を集電体(80、90)に形成すると、スリ
ット(11)及び空孔(12)部分が電解液の通り道と
なり、電解液の注入時間、エージング時間を短縮化でき
るという付随効果もある。また、請求項3の発明は、請
求項2記載のスリット(11)及び空孔(12)におい
て、空孔(12)がスリット(11)の切込みの終点に
形成されていることを特徴とする。それによって、スリ
ット(11)の切れ込みが空孔(12)で止まるため、
必要以上にスリット(11)の切れ込みが延びるのを防
止でき、強度的に優れたものにできる。
When such slits (11) and holes (12) are formed in the current collectors (80, 90), the slits (11) and holes (12) pass through the electrolytic solution, and There is an additional effect that the liquid injection time and the aging time can be reduced. According to a third aspect of the present invention, in the slit (11) and the hole (12) according to the second aspect, the hole (12) is formed at an end point of the cut of the slit (11). . Thereby, the cut of the slit (11) stops at the hole (12),
It is possible to prevent the slit (11) from being extended more than necessary, and it is possible to improve the strength.

【0012】なお、本発明者等の検討によれば、スリッ
ト(11)は、請求項4記載の発明のように、その切込
み長さが非付着領域(8b、9b)の幅よりも短いもの
で、十分に上記歪み吸収の効果があることがわかった。
また、請求項5記載の発明は、本発明の目的を達成する
ための電池の製造方法について成されたものである。
According to the study by the present inventors, the slit (11) has a cut length shorter than the width of the non-adhesion regions (8b, 9b) as in the invention according to claim 4. It was found that there was a sufficient effect of absorbing the strain.
The invention described in claim 5 has been made on a method of manufacturing a battery to achieve the object of the present invention.

【0013】即ち、電池同一面上に電極活物質が付着し
た付着領域(8a、9a)と、電極活物質が付着してい
ない非付着領域(8b、9b)とを有する導電性の箔を
圧延して形成された集電体(80、90)を巻回してな
る電極(8、9)を備え、非付着領域(8b、9b)が
集電体(80、90)のうち巻回方向に沿って延びる縁
部(81、91)に設けられている電池を製造する製造
方法であって、箔に電極活物質を付着させ、付着領域
(8a、9a)と非付着領域(8b、9b)とを有する
集電体(80、90)を形成する工程と、これら両領域
(8a、9a、8b、9b)を有する集電体(80、9
0)の縁部(81、91)に歪みを吸収するための切欠
部(11、12)を形成する工程と、両領域(8a、9
a、8b、9b)を有する集電体(80、90)を圧延
する工程と、集電体(80、90)を巻回する工程とを
備えたことを特徴とする。
That is, a conductive foil having an adhesion area (8a, 9a) where the electrode active material is adhered on the same surface of the battery and a non-adhesion area (8b, 9b) where the electrode active material is not adhered is rolled. Electrodes (8, 9) formed by winding the current collectors (80, 90) formed in such a manner that the non-adhesion regions (8b, 9b) are wound in the winding direction of the current collectors (80, 90). A method for manufacturing a battery provided at edges (81, 91) extending along the electrode, wherein an electrode active material is adhered to a foil, and an adhered area (8a, 9a) and a non-adhered area (8b, 9b) Forming a current collector (80, 90) having: and a current collector (80, 9) having both of these regions (8a, 9a, 8b, 9b).
0), forming notches (11, 12) at the edges (81, 91) for absorbing distortion, and both regions (8a, 9).
a, a step of rolling a current collector (80, 90) having a, 8b, 9b) and a step of winding the current collector (80, 90).

【0014】ここで、切欠部(11、12)の形成工程
は、圧延工程の前に行っても後に行ってもよい。圧延工
程の前に切欠部(11、12)を形成した場合、圧延工
程において、付着領域(8a、9a)と非付着領域(8
b、9b)との材料の伸びの違いによる歪みを、切欠部
(11、12)が吸収するため上記円弧状のそりを低減
できる。従って、巻回の際に、巻回ずれを低減した巻回
型電池を提供することができる。
Here, the step of forming the notches (11, 12) may be performed before or after the rolling step. When the notches (11, 12) are formed before the rolling step, in the rolling step, the adhering areas (8a, 9a) and the non-adhering areas (8
The notch (11, 12) absorbs the distortion due to the difference in the elongation of the material from that of b, 9b), so that the arc-shaped warpage can be reduced. Therefore, it is possible to provide a wound battery in which winding deviation is reduced during winding.

【0015】一方、圧延工程の後に切欠部(11、1
2)を形成した場合、圧延工程で発生した上記円弧状の
そりの応力を切欠部(11、12)で吸収して電極形状
を補正できるので、巻回ずれを低減した巻回型電池を提
供することができる。なお、上記各手段の括弧内の符号
は、後述する実施形態記載の具体的手段との対応関係を
示すものである。
On the other hand, after the rolling step, the notch (11, 1
When 2) is formed, the above-mentioned arc-shaped warpage stress generated in the rolling step can be absorbed by the cutouts (11, 12) to correct the electrode shape, thereby providing a wound type battery with reduced winding deviation. can do. In addition, the code | symbol in the parenthesis of each said means shows the correspondence with the concrete means of embodiment mentioned later.

【0016】[0016]

【発明の実施の形態】以下、本発明を図に示す実施形態
について説明する。本実施形態の巻回型電池はリチウム
イオン二次電池に適用したものとして説明する。図1
に、そのリチウムイオン二次電池の構造を示す。1は金
属製の円筒状の容器であり、電池本体を区画形成するも
のである。2は軸芯であり、容器の中心に配置され電極
の巻回の際の芯となる。軸芯2は、正極端子3と負極端
子4とが絶縁部5を介して互いに絶縁されるように、対
向接続されて構成されている。そして各端子3、4は、
電池使用時に外部端子との接点として用いられる。な
お、軸芯2には後述する電解液注入用の穴2aが形成
(図1では図示せず、図5参照)されている。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a block diagram showing a first embodiment of the present invention. The description will be made assuming that the wound type battery according to the present embodiment is applied to a lithium ion secondary battery. FIG.
The following shows the structure of the lithium ion secondary battery. Reference numeral 1 denotes a metal cylindrical container which defines a battery main body. Reference numeral 2 denotes a shaft core, which is disposed at the center of the container and serves as a core when winding the electrode. The shaft core 2 is configured so that the positive terminal 3 and the negative terminal 4 are connected to each other so as to be insulated from each other via the insulating portion 5. And each terminal 3, 4
Used as contacts with external terminals when using batteries. In addition, a hole 2a for injecting an electrolytic solution, which will be described later, is formed in the shaft core 2 (not shown in FIG. 1; see FIG. 5).

【0017】6及び7は栓であり、それぞれ各端子3及
び4の開口部3a及び4aに挿入され、各開口部3a、
4aを密閉する。なお、各端子3及び4の開口部3a及
び4aは、電解液注入口となっており、電解液注入後、
栓6、7にて密閉される。8は正極であり、金属箔(例
えばAl箔等)の集電体80にLiMn2 4 、LiN
iO2 、LiCoO2 等の正極活物質を付着させたもの
である。9は負極であり、金属箔(例えばCu箔等)の
集電体90にグラファイトなどのカーボン系の粒子の負
極活物質を付着させたものである。
Reference numerals 6 and 7 denote plugs, which are inserted into the openings 3a and 4a of the terminals 3 and 4, respectively.
4a is sealed. The openings 3a and 4a of the terminals 3 and 4 serve as electrolyte injection holes.
Sealed with stoppers 6 and 7. Reference numeral 8 denotes a positive electrode, and LiMn 2 O 4 , LiN
A positive electrode active material such as iO 2 or LiCoO 2 is attached. Reference numeral 9 denotes a negative electrode in which a negative electrode active material of carbon-based particles such as graphite is adhered to a current collector 90 such as a metal foil (for example, a Cu foil).

【0018】正極8と負極9は、両極8、9を電気的に
絶縁するためのセパレータ(例えば、ポリエチレン多孔
フィルム)10を両極8、9間に介在させて、軸芯2回
りに巻回されて、容器1内に収納されている。正極8
は、集電体80の両面のそれぞれにおいて、正極活物質
が付着した付着領域(ハッチング部分)8aと付着して
いない非付着領域(非ハッチング部分)8bとを有して
いる。非付着領域8bは、巻回方向に沿った集電体80
の縁部81において、集電体の外周端部82から所定幅
(例えば、少なくとも2〜3mm)を持って設けられて
いる。なお、本実施形態では非付着領域8bと縁部81
とは一致する。
The positive electrode 8 and the negative electrode 9 are wound around the shaft core 2 with a separator (for example, a polyethylene porous film) 10 for electrically insulating the electrodes 8 and 9 interposed between the electrodes 8 and 9. And stored in the container 1. Positive electrode 8
Has an attached region (hatched portion) 8a to which the positive electrode active material is attached and a non-attached region (non-hatched portion) 8b to which the cathode active material is not attached. The non-adhesion region 8b is provided with a current collector 80 along the winding direction.
At a predetermined width (for example, at least 2 to 3 mm) from the outer peripheral end 82 of the current collector. In the present embodiment, the non-adhesion region 8b and the edge 81
Matches.

【0019】そして、縁部81すなわち非付着領域8b
には、巻回方向に沿って複数個のスリット11及び空孔
12が形成され、歪みを吸収するための切欠部として構
成されている。スリット11は外周端部82から切込ま
れて形成されており、空孔12は各スリット11の切込
みの終点(すなわち外周端部82よりも内側)に円形状
の穴として形成されている。
The edge 81, that is, the non-adhesion region 8b
Are formed with a plurality of slits 11 and holes 12 along the winding direction, and are formed as cutouts for absorbing distortion. The slit 11 is formed by being cut from the outer peripheral end 82, and the hole 12 is formed as a circular hole at the end point of the cut of each slit 11 (that is, inside the outer peripheral end 82).

【0020】なお、切欠部としては、スリット11のみ
及び空孔12のみであってもよい。ここで、スリット1
1及び空孔12のサイズ、配置間隔(巻回方向に沿って
配置するときの配置間隔)についても、本発明者等は検
討した。円形状の空孔12の直径については、縁部81
(非付着領域8b)の幅にもよるが、直径が1mm〜2
0mmであることが好ましく、1mmよりも小さいと歪
み吸収が十分発揮されず、20mmより大きいと縁部8
1が強度的に弱くなり、後述する正極側端面プレート1
3との接合時に変形する等の不具合が起こる。
The notch may be only the slit 11 and only the hole 12. Here, slit 1
The present inventors also examined the sizes of the holes 1 and the holes 12 and the arrangement interval (the arrangement interval when arranged along the winding direction). Regarding the diameter of the circular hole 12, the edge 81
Although it depends on the width of the (non-adhesion area 8b), the diameter is 1 mm to 2 mm.
It is preferably 0 mm, and if it is smaller than 1 mm, the strain absorption is not sufficiently exhibited, and if it is larger than 20 mm, the edge 8
1 becomes weaker in strength, and a positive electrode side end plate 1
Failures such as deformation at the time of joining with No. 3 occur.

【0021】また、スリット11のみの場合、その配置
間隔は5mm〜200mmの範囲にあることが好まし
く、空孔12のみの場合、その配置間隔は3mm〜20
mmの範囲にあることが好ましい。その根拠は、上記の
空孔12直径の好適範囲の根拠と同じであり、スリット
11もしくは空孔12の配置間隔が小さすぎると縁部8
1が強度的に弱くなり、大きすぎると歪み吸収が十分発
揮されないことから、求めたものである。
When only the slits 11 are provided, the arrangement interval is preferably in the range of 5 mm to 200 mm. When only the holes 12 are provided, the arrangement interval is 3 mm to 20 mm.
mm. The grounds are the same as the grounds for the above-described preferable range of the diameter of the hole 12. If the interval between the slits 11 or the holes 12 is too small, the edge 8
1 was weakened in strength, and too large, strain absorption was not sufficiently exhibited.

【0022】本実施形態では、スリット11及び空孔1
2の両方が設けられたものとしているが、その配置間隔
は、上記各々の好適な配置間隔範囲の知見に基づいて、
決められている。例えば、空孔12は直径約φ6mmで
あり、スリット11及び空孔12の配置間隔は60mm
としている。負極9は、集電体90の両面のそれぞれに
おいて、負極活物質が付着した付着領域(ハッチング部
分)9aと付着していない非付着領域(非ハッチング部
分)9bとを有している。非付着領域9bは、巻回方向
に沿った集電体90の縁部91において、集電体の外周
端部92から所定幅(例えば、少なくとも2〜3mm)
を持って設けられている。なお、本実施形態では非付着
領域9bと縁部91とは一致する。
In the present embodiment, the slit 11 and the hole 1
Although both of the two are provided, the arrangement interval is determined based on the knowledge of the respective preferable arrangement interval ranges described above.
It is decided. For example, the hole 12 has a diameter of about φ6 mm, and the arrangement interval between the slit 11 and the hole 12 is 60 mm.
And The negative electrode 9 has an attachment region (hatched portion) 9a to which the anode active material is attached and a non-attached region (non-hatched portion) 9b to which the anode active material is not attached, on both surfaces of the current collector 90. The non-adhesion region 9b is a predetermined width (for example, at least 2-3 mm) from the outer peripheral end 92 of the current collector at the edge 91 of the current collector 90 along the winding direction.
It is provided with. In the present embodiment, the non-adhesion region 9b and the edge 91 match.

【0023】そして、縁部91すなわち非付着領域9b
には、正極8の縁部81に形成されたのと同様の切欠部
としての複数個のスリット11及び空孔12が形成され
ている。また、正極8は、縁部81の外周端部82にお
いて、正極端子3に導通する上記正極側端面プレート1
3と溶接され、負極9は、縁部91の外周端部92にお
いて、負極端子4に導通する負極側端面プレート14と
溶接されている。つまり、両極8、9とも縁部81、9
1が電荷を取出すためのリード部として構成され、その
リード部には活物質が付着していない。
The edge 91, that is, the non-adhesion region 9b
Are formed with a plurality of slits 11 and holes 12 as notches similar to those formed in the edge 81 of the positive electrode 8. Further, the positive electrode 8 is provided at the outer peripheral end 82 of the edge portion 81 with the positive electrode side end face plate 1 electrically connected to the positive electrode terminal 3.
The negative electrode 9 is welded to the negative-electrode-side end face plate 14 that is connected to the negative electrode terminal 4 at the outer peripheral end 92 of the edge 91. That is, both poles 8 and 9 have edges 81 and 9
Reference numeral 1 denotes a lead portion for taking out electric charges, and the lead portion has no active material attached thereto.

【0024】15及び16は蓋であり、それぞれ容器1
の正極端子3側開口部、負極端子4側開口部を閉塞して
おり、内部の電解液を密封する。17及び18はガスケ
ットであり、それぞれ、正極端子3と蓋15との間、及
び、負極端子4と蓋16との間に介在し絶縁をとる。上
記構成において、電池使用時には、正極8からの電子は
縁部81から、正極側端面プレート13、正極端子3へ
取出され、外部負荷を通って負極端子4、負極側端面プ
レート14、縁部91から負極4へと流れる。
Reference numerals 15 and 16 denote lids, each of which is a container 1.
The opening on the positive electrode terminal 3 side and the opening on the negative electrode terminal 4 side are closed, and the internal electrolytic solution is sealed. Gaskets 17 and 18 are interposed between the positive electrode terminal 3 and the lid 15 and between the negative electrode terminal 4 and the lid 16 for insulation. In the above configuration, when the battery is used, electrons from the positive electrode 8 are extracted from the edge portion 81 to the positive electrode side end plate 13 and the positive electrode terminal 3 and passed through an external load to the negative electrode terminal 4, the negative electrode side end plate 14 and the edge portion 91. To the negative electrode 4.

【0025】次に、本実施形態の電池の製造方法につい
て、図2及び図3を参照して述べる。図2は、本実施形
態の電池の製造方法の工程図であり、(a)は圧延工程
S2の後に切欠部形成工程S3を行う場合、(b)は圧
延工程S2の前に切欠部形成工程S3を行う場合を表
す。図3は、本実施形態の電池の製造方法を説明する説
明図である。
Next, a method for manufacturing the battery according to the present embodiment will be described with reference to FIGS. 2A and 2B are process diagrams of a method for manufacturing a battery according to the present embodiment. FIG. 2A illustrates a case where a notch forming step S3 is performed after a rolling step S2, and FIG. 2B illustrates a notch forming step before a rolling step S2. This represents the case where S3 is performed. FIG. 3 is an explanatory diagram illustrating the method for manufacturing the battery of the present embodiment.

【0026】なお、図2の工程において工程S1、S
2、S3、S4は、正極8と負極9とについて同様に行
われる。図3において、括弧外符号は正極8について、
括弧内は負極9について示す。まず、圧延工程S2の後
に切欠部形成工程S3を行う場合(図2(a))につい
て述べる。なお、以下に示す各構成要素の材質、寸法等
の数値は一例であり、本実施形態はこれに限定されるも
のではない。
In the process shown in FIG.
Steps S2, S3, and S4 are performed similarly for the positive electrode 8 and the negative electrode 9. In FIG. 3, the symbols outside the parentheses indicate the positive electrode 8.
The figures in parentheses indicate the negative electrode 9. First, the case where the notch forming step S3 is performed after the rolling step S2 (FIG. 2A) will be described. In addition, the numerical values of the materials, dimensions, and the like of the components shown below are examples, and the present embodiment is not limited to these.

【0027】正極8の集電体80はAl箔(例えば厚さ
15μm)を用いる。そして、正極活物質としてのLi
Mn2 4 、導電剤としてのグラファイト、バインダー
としてのポリフッ化ビニリデン(PVDF)、溶剤とし
てのN−メチル−2−ピロリドン(NMP)を混合した
ペーストを作製する。活物質塗布工程S1では、図3
(a)に示す様に、上記ペーストを、例えば片側75μ
mの厚さで、集電体80の中央部(図3(a)中のハッ
チング部分)すなわち付着領域8aの両側に、10mm
以上の非付着領域8b(図3(a)中の非ハッチング部
分)を設け、塗布部材(コンマコータ)P1を用いて塗
布(図3(a)参照)し、付着領域8aと非付着領域8
bとを形成する。次に、150℃の乾燥を行う。この時
点での電極の密度(活物質の密度)は1.6g/cm3
である。
The current collector 80 of the positive electrode 8 uses an Al foil (for example, a thickness of 15 μm). And Li as a positive electrode active material
A paste is prepared by mixing Mn 2 O 4 , graphite as a conductive agent, polyvinylidene fluoride (PVDF) as a binder, and N-methyl-2-pyrrolidone (NMP) as a solvent. In the active material application step S1, FIG.
As shown in (a), the above-mentioned paste is, for example, 75 μm on one side.
10 m at the center of the current collector 80 (the hatched portion in FIG. 3A), that is, on both sides of the attachment region 8a.
The above non-adhesion region 8b (the non-hatched portion in FIG. 3A) is provided, and is applied using an application member (comma coater) P1 (see FIG. 3A).
and b. Next, drying at 150 ° C. is performed. At this time, the density of the electrode (the density of the active material) is 1.6 g / cm 3.
It is.

【0028】この後、圧延工程S2では、粒子間の接
触、集電体80との接触を良くして導電性、電極強度を
あげる目的と、電池内の体積を有効に使う目的とから、
ロールプレスP2によって圧延プレスを行い(図3
(b)参照)電極密度を上げる。具体的には、電極密度
を2.5g/cm3 から3.1g/cm3 程度に調整す
ることで、電池容量、サイクル特性、出力特性が優れた
電池が得られる。
Thereafter, in the rolling step S2, the purpose is to improve the contact between the particles, the contact with the current collector 80 to increase the conductivity and the electrode strength, and to use the volume inside the battery effectively.
A rolling press is performed by a roll press P2 (FIG. 3)
(See (b)) Increase the electrode density. Specifically, by adjusting the electrode density from about 2.5 g / cm 3 to about 3.1 g / cm 3 , a battery having excellent battery capacity, cycle characteristics, and output characteristics can be obtained.

【0029】切欠部形成工程S3は、図3(c)に示す
様に、金属カッターによる切り込み、及び打ち抜き加工
等により、集電体80の縁部81(非付着領域8b)
に、切欠部としての複数個のスリット11及び空孔12
を形成する。その後、電極形状補正工程S4では、課題
の欄にて述べた円弧状のそりx(図4(a)参照)を低
減するように、スリット11及び空孔12部分にて正極
8を変形させ、形状補正を行う。
As shown in FIG. 3 (c), the notch forming step S3 is performed by cutting or punching with a metal cutter to form the edge 81 of the current collector 80 (the non-adhered area 8b).
A plurality of slits 11 and holes 12 as notches
To form Then, in the electrode shape correction step S4, the positive electrode 8 is deformed at the slit 11 and the hole 12 so as to reduce the arc-shaped warp x (see FIG. 4A) described in the section of the subject. Perform shape correction.

【0030】負極9も正極8と同様に、活物質塗布工程
S1、圧延工程S2、切欠部形成工程S3、電極形状補
正工程S4を行って作製する。負極9の集電体90はC
u箔(例えば厚さ10μm)を用いる。そして、負極活
物質としてのMCMB(メソフェーズカーボンマイクロ
ビーズ)、PVDF、NMPを混合したペーストを作製
し、このペーストを片側45μmの厚さで塗布、130
℃の乾燥、圧延プレスを行って、片側膜厚35μm、電
極密度1.4g/cm3 の負極9を作製する。そして、
切欠部形成、形状補正を行う。
Similarly to the positive electrode 8, the negative electrode 9 is manufactured by performing an active material coating step S1, a rolling step S2, a notch forming step S3, and an electrode shape correcting step S4. The current collector 90 of the negative electrode 9 is C
U foil (for example, 10 μm in thickness) is used. Then, a paste was prepared by mixing MCMB (mesophase carbon microbeads), PVDF, and NMP as the negative electrode active material, and this paste was applied to a thickness of 45 μm on one side, and 130
The negative electrode 9 having a film thickness on one side of 35 μm and an electrode density of 1.4 g / cm 3 was prepared by drying at a temperature of ° C and a rolling press. And
Notch formation and shape correction are performed.

【0031】そして、電池組付工程S5では、形状補正
まで行った正極8と負極9を、東燃タピルス製のPP製
微孔性セパレータ10(例えば厚さ25μm)を介し
て、軸芯2(例えば直径8mm)回りに巻回する。ここ
で例えば正極幅177mm、長さ3000mm、負極幅
181mm、長さ3160mmとできる。そして、容器
1内に組付け、集電体80、90の縁部81、91と各
端面プレート13、14との溶接、電解液注入、封止等
を行い、本実施形態の電池が完成する。
In the battery assembling step S5, the positive electrode 8 and the negative electrode 9 that have been subjected to the shape correction are connected to the shaft core 2 (for example, 25 μm in thickness) through a PP microporous separator 10 (for example, 25 μm in thickness) made by Tonen Tapils. (Diameter 8 mm). Here, for example, the positive electrode width can be 177 mm, the length is 3000 mm, the negative electrode width is 181 mm, and the length is 3160 mm. Then, the battery is assembled in the container 1, and the edges 81, 91 of the current collectors 80, 90 and the end plates 13, 14 are welded, injected with an electrolytic solution, sealed, and the like, thereby completing the battery of the present embodiment. .

【0032】一方、圧延工程S2の前に切欠部形成工程
S3を行う場合(図2(b))、圧延の際、付着領域8
aと非付着領域8bとの材料の伸びの違いによる歪み
を、スリット11及び空孔12が吸収するため、上記円
弧状のそりxを圧延時において低減できる。その後、電
池組付工程S5を行い、本実施形態の電池を完成させ
る。
On the other hand, when the notch forming step S3 is performed before the rolling step S2 (FIG. 2 (b)), the adhesion region 8
Since the slits 11 and the holes 12 absorb the distortion caused by the difference in the elongation of the material between the a and the non-adhesion region 8b, the arc-shaped warp x can be reduced during rolling. Thereafter, a battery assembling step S5 is performed to complete the battery of the present embodiment.

【0033】従って、切欠部形成工程S3を圧延工程S
2の前後どちらで行っても、各電極8、9の円弧状のそ
りxを、同様に低減することができる。スリット11又
は空孔12による効果を以下に示す。ここで、図4
(a)は円弧状のそりxを示し、図4(b)は、電池組
付工程S5すなわち巻回後の正極8及び負極9の巻回ず
れyを示す模式図である。なお、円弧状のそりxの単位
及び巻回ずれyの単位は、それぞれ、mm/m、及びm
mとしている。
Therefore, the notch forming step S3 is replaced with the rolling step S
Regardless of whether it is performed before or after 2, the arc-shaped warp x of each of the electrodes 8, 9 can be similarly reduced. The effect of the slit 11 or the hole 12 will be described below. Here, FIG.
4A is a schematic view showing an arc-shaped warp x, and FIG. 4B is a schematic diagram showing a winding displacement y of the positive electrode 8 and the negative electrode 9 after the battery assembling step S5, that is, after winding. The unit of the arc-shaped warp x and the unit of the winding deviation y are mm / m and m, respectively.
m.

【0034】各端面プレート13、14と接合するため
のリード部である集電体80、90の縁部81、91
に、スリット11のみ設けた場合、円弧状のそりxを、
従来の10mm/mであったのが、0.2mm/mに低
減できた。この集電体80、90を巻回して正極8及び
負極9を構成した電池においては、巻回ずれyを、従来
の20mmに対して0.3mmと抑えることができた。
Edges 81, 91 of current collectors 80, 90, which are leads for joining with end face plates 13, 14, respectively.
When only the slit 11 is provided, the arc-shaped sled x is
The conventional 10 mm / m was reduced to 0.2 mm / m. In the battery in which the current collectors 80 and 90 were wound to form the positive electrode 8 and the negative electrode 9, the winding deviation y could be suppressed to 0.3 mm compared to the conventional 20 mm.

【0035】集電体80、90の縁部81、91に、空
孔12のみを設けた場合、円弧上のそりxを0.8mm
/mとでき、巻回ずれyを0.4mmに低減できた。集
電体80、90の縁部81、91に、スリット11と空
孔12の両方を設けた場合、円弧状のそりxは0mm/
mとなくなり、巻回ずれyも0.2mmに抑えることが
できた。また、スリット11のみでは、電極8、9がス
リット方向に切れやすくなる、つまり、スリット11の
切れ込みの終点が延びていってしまうが、空孔12によ
り、そのような問題も防止できる。
When only the holes 12 are provided at the edges 81 and 91 of the current collectors 80 and 90, the warp x on the arc is 0.8 mm.
/ M, and the winding deviation y was reduced to 0.4 mm. When both the slits 11 and the holes 12 are provided in the edges 81 and 91 of the current collectors 80 and 90, the arc-shaped sled x is 0 mm /
m, and the winding deviation y could be suppressed to 0.2 mm. Further, if the slit 11 alone is used, the electrodes 8 and 9 are likely to be cut in the slit direction, that is, the end point of the slit 11 is extended. However, such a problem can be prevented by the hole 12.

【0036】また、この電極を巻回、端面での溶接を行
った後、電解液の注入を行うが、この注入の際、従来で
は、電極端面の上方面からの電解液流路のみが確保され
ているだけである。しかし、本実施形態においては、軸
芯2に上記電解液注入用の穴2aを設けることで、スリ
ット11及び空孔12によって内部からの電解液流路も
確保され電解液の注入時間も短縮できる。その様子を図
5に示す。図5は、空孔12により形成される電解液流
路の注入時における流れを示す説明図である。
After the electrode is wound and welded at the end face, the electrolyte is injected. In this injection, conventionally, only the electrolyte flow path from the upper surface of the electrode end face is secured. It is just being done. However, in the present embodiment, by providing the hole 2a for injecting the electrolyte in the shaft core 2, the slit 11 and the hole 12 also secure the electrolyte flow path from the inside, and the injection time of the electrolyte can be shortened. . This is shown in FIG. FIG. 5 is an explanatory diagram showing a flow when the electrolyte solution flow path formed by the holes 12 is injected.

【0037】電解液注入の際、軸芯2の上方がら注入さ
れた電解液は、穴2aから各スリット11及び空孔12
を通って正極8及び負極9の間に流入する。具体的に
は、空孔12を設けた電池では、規定量の電解液を注入
する時間が、従来電池の40分に対して20分に短縮で
きる。(他の実施形態)なお、切欠部は上記スリット1
1及び空孔12に限定されるものではなく、形状は限定
されない。例えば、U字又はV字状の切欠でもよい。
At the time of the injection of the electrolyte, the electrolyte injected from above the shaft core 2 passes through each of the slits 11 and the holes 12 through the hole 2a.
And flows between the positive electrode 8 and the negative electrode 9. Specifically, in the battery provided with the holes 12, the time for injecting a prescribed amount of the electrolyte can be reduced to 20 minutes compared to 40 minutes in the conventional battery. (Other Embodiments) The notch is the slit 1
It is not limited to 1 and the holes 12, and the shape is not limited. For example, a U-shaped or V-shaped notch may be used.

【0038】また、上記実施形態においては、切欠部
(11、12)は、各極8、9の各集電体80、90に
おいて、溶接される各端面プレート13、14側の縁部
81、91に設けられているが、各集電体80、90の
縁部81、91の対向する縁部にも設けてもよい。この
場合、この対向する縁部には、非付着領域を設けたもの
としてもよい。
Further, in the above embodiment, the notches (11, 12) are formed at the current collectors 80, 90 of the poles 8, 9 by the edge portions 81, on the side of the end face plates 13, 14 to be welded. Although it is provided at 91, it may be provided at the opposite edges of the edges 81 and 91 of the current collectors 80 and 90. In this case, a non-adhesion area may be provided on the opposite edge.

【0039】また、圧延工程S2の後に切欠部形成工程
S3を行う場合において、電極形状補正工程S4は無く
ともよい。その場合、電池組付工程S5での巻回の際に
電池組付工程S5の巻回の際に巻回ずれyを低減するよ
うに電極(8、9)を切欠部(11、12)で変形させ
ながら巻回すればよい。また、圧延工程S2の前に切欠
部形成工程S3を行う場合において、圧延工程S2と電
池組付工程S5との間に、更に電極形状補正工程S4を
行ってもよい。
When the notch forming step S3 is performed after the rolling step S2, the electrode shape correcting step S4 may be omitted. In this case, the electrodes (8, 9) are notched (11, 12) so as to reduce the winding deviation y during the winding in the battery assembling step S5 during the winding in the battery assembling step S5. What is necessary is just to wind while deforming. When the notch forming step S3 is performed before the rolling step S2, an electrode shape correcting step S4 may be further performed between the rolling step S2 and the battery assembling step S5.

【0040】また、非付着領域からの電子の取出しにお
いて、上記のように端面プレート13、14と非付着領
域8b、9bとを溶接するもの以外に、非付着領域8
b、9bに集電リボン(例えば、正極にはAl、負極に
はCuからなるもの)を溶接等で空孔が閉塞されないよ
うに接合し、この集電リボンによって各極8、9を各極
端子3、4に導通させる構成としてもよい。
In taking out electrons from the non-adhesion region, other than welding the end face plates 13 and 14 and the non-adhesion regions 8b and 9b as described above, the non-adhesion region 8
A current collecting ribbon (e.g., one made of Al for the positive electrode and one made of Cu for the negative electrode) is joined to each of the electrodes b and 9b by welding or the like so that the holes are not closed. It is good also as a structure which conducts to the child 3,4.

【0041】また、電子の取出しは、上記のように端面
プレート13、14と非付着領域8b、9bとの溶接で
行い、上記集電リボンを集電体80、90の非付着領域
8b、9b(縁部81、91)の補強部材として用いて
もよい。また、縁部81、91の幅は、非付着領域8
b、9bの幅よりも大きい、つまり縁部81、91は付
着領域8a、9aをも含んでいてもよい。この場合、縁
部81、91に設けられたスリット11及び空孔12
は、付着領域8a、9aにまで延びて両領域8a、8
b、9a、9bに跨がって形成されたものでもよい。
The extraction of the electrons is performed by welding the end face plates 13 and 14 with the non-adhesion regions 8b and 9b as described above, and the current collector ribbon is connected to the non-adhesion regions 8b and 9b of the current collectors 80 and 90. (The edge portions 81 and 91) may be used as a reinforcing member. In addition, the width of the edges 81 and 91 is the same as that of the non-adhesion region 8.
The edges 81, 91, which are larger than the widths of b, 9b, may also include the attachment areas 8a, 9a. In this case, the slits 11 and the holes 12 provided in the edges 81 and 91 are provided.
Extend to the attachment regions 8a, 9a and extend to both regions 8a, 8a.
It may be formed so as to straddle b, 9a, 9b.

【0042】なお、上記実施形態は、リチウムイオン二
次電池に限らず、巻回型電池であればどんな電池にも適
用できる。
The above embodiment is not limited to a lithium ion secondary battery, but can be applied to any wound battery.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施形態に係る巻回型電池の構成を示
す説明図である。
FIG. 1 is an explanatory diagram showing a configuration of a wound battery according to an embodiment of the present invention.

【図2】上記実施形態に係る電池の製造方法を示す工程
図である。
FIG. 2 is a process chart showing a method for manufacturing a battery according to the embodiment.

【図3】図2の製造方法を説明する説明図である。FIG. 3 is an explanatory diagram for explaining the manufacturing method of FIG. 2;

【図4】(a)は電極の円弧状のそりを示す模式図であ
り、(b)は電池の巻回ずれを示す模式図である。
FIG. 4A is a schematic diagram showing an arc-shaped warpage of an electrode, and FIG. 4B is a schematic diagram showing a winding deviation of a battery.

【図5】上記実施形態における注入時の電解液流れを示
す説明図である。
FIG. 5 is an explanatory diagram showing a flow of an electrolyte at the time of injection in the embodiment.

【図6】従来の巻回型電池の製造方法を示す説明図であ
る。
FIG. 6 is an explanatory view showing a method for manufacturing a conventional wound battery.

【符号の説明】[Explanation of symbols]

8…正極、9…負極、8a、9a…付着領域、8b、9
b…非付着領域、11…スリット、12…空孔、80、
90…集電体、81、91…縁部、82、92…集電体
の外周端部。
8 Positive electrode, 9 Negative electrode, 8a, 9a Adhered area, 8b, 9
b: non-adhesion area, 11: slit, 12: void, 80,
90 ... current collector, 81, 91 ... edge, 82, 92 ... outer peripheral end of current collector.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 同一面上に電極活物質が付着した付着領
域(8a、9a)と、電極活物質が付着していない非付
着領域(8b、9b)とを有する導電性の箔を圧延して
形成された集電体(80、90)を巻回してなる電極
(8、9)を備え、 前記非付着領域(8b、9b)が前記集電体(80、9
0)のうち巻回方向に沿って延びる縁部(81、91)
に設けられている電池において、 前記縁部(81、91)には歪みを吸収するための切欠
部(11、12)が形成されていることを特徴とする電
池。
1. A conductive foil having an attached area (8a, 9a) on the same surface to which an electrode active material is attached and a non-adhered area (8b, 9b) to which no electrode active material is attached is rolled. Electrodes (8, 9) formed by winding current collectors (80, 90) formed in such a manner that the non-adhesion regions (8b, 9b) are formed in the current collectors (80, 9).
0) of the edges (81, 91) extending along the winding direction
In the battery provided in (1), notches (11, 12) for absorbing distortion are formed in the edges (81, 91).
【請求項2】 前記切欠部は、前記縁部(81、91)
において前記集電体(80、90)の外周端部(82、
92)から切込まれたスリット(11)、および前記縁
部(81、91)において前記集電体(80、90)の
外周端部(82、92)よりも内側に形成された空孔
(12)の少なくとも一方から構成されていることを特
徴とする請求項1に記載の電池。
2. The notch is formed by the edge (81, 91).
In the outer peripheral end portions (82, 82) of the current collectors (80, 90),
92) and holes (81, 91) formed inside the outer peripheral ends (82, 92) of the current collectors (80, 90) at the edges (81, 91). The battery according to claim 1, comprising at least one of (12).
【請求項3】 前記空孔(12)が前記スリット(1
1)の切込みの終点に形成されていることを特徴とする
請求項2に記載の電池。
3. The slit (1) is formed by the hole (12).
3. The battery according to claim 2, wherein the battery is formed at the end point of the cut of 1).
【請求項4】 前記スリット(11)は、その切込み長
さが前記非付着領域(8b、9b)の幅よりも短いこと
を特徴とする請求項2または3に記載の電池。
4. The battery according to claim 2, wherein the slit (11) has a cut length shorter than a width of the non-adhesion region (8b, 9b).
【請求項5】 同一面上に電極活物質が付着した付着領
域(8a、9a)と、電極活物質が付着していない非付
着領域(8b、9b)とを有する導電性の箔を圧延して
形成された集電体(80、90)を巻回してなる電極
(8、9)を備え、 前記非付着領域(8b、9b)が前記集電体(80、9
0)のうち巻回方向に沿って延びる縁部(81、91)
に設けられている電池を製造する製造方法であって、 前記箔に前記電極活物質を付着させ、前記付着領域(8
a、9a)と前記非付着領域(8b、9b)とを有する
前記集電体(80、90)を形成する工程と、 前記両領域(8a、9a、8b、9b)を有する前記集
電体(80、90)の前記縁部(81、91)に歪みを
吸収するための切欠部(11、12)を形成する工程
と、 前記両領域(8a、9a、8b、9b)を有する前記集
電体(80、90)を圧延する工程と、 前記集電体(80、90)を巻回する工程とを備えたこ
とを特徴とする電池の製造方法。
5. A conductive foil having an adhesion area (8a, 9a) to which the electrode active material is adhered on the same surface and a non-adhesion area (8b, 9b) to which the electrode active material is not adhered is rolled. Electrodes (8, 9) formed by winding current collectors (80, 90) formed in such a manner that the non-adhesion regions (8b, 9b) are formed in the current collectors (80, 9).
0) of the edges (81, 91) extending along the winding direction
The electrode active material is attached to the foil, and the attachment area (8) is provided.
a, 9a) and forming the current collector (80, 90) having the non-attached areas (8b, 9b); and the current collector having both areas (8a, 9a, 8b, 9b). Forming notches (11, 12) at the edges (81, 91) of (80, 90) for absorbing strain; and forming the notches having both regions (8a, 9a, 8b, 9b). A method for producing a battery, comprising: a step of rolling a current collector (80, 90); and a step of winding the current collector (80, 90).
JP9340312A 1997-12-10 1997-12-10 Battery and manufacture thereof Pending JPH11176447A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9340312A JPH11176447A (en) 1997-12-10 1997-12-10 Battery and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9340312A JPH11176447A (en) 1997-12-10 1997-12-10 Battery and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH11176447A true JPH11176447A (en) 1999-07-02

Family

ID=18335750

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9340312A Pending JPH11176447A (en) 1997-12-10 1997-12-10 Battery and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH11176447A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11312517A (en) * 1998-04-28 1999-11-09 Shin Kobe Electric Mach Co Ltd Manufacture of battery electrode
JP2001160386A (en) * 1999-12-03 2001-06-12 Japan Storage Battery Co Ltd Cylindrical battery
JP2005044539A (en) * 2003-07-23 2005-02-17 Mitsubishi Heavy Ind Ltd Manufacturing method of secondary battery electrode and roll press device
JP2012238427A (en) * 2011-05-10 2012-12-06 Gs Yuasa Corp Electrochemical device and manufacturing method of electrochemical device
WO2013079570A1 (en) * 2011-11-30 2013-06-06 Volkswagen Varta Microbattery Forschungsgesellschaft Mbh & Co. Kg Electrodes for lithium ion batteries and the production thereof
WO2013187172A1 (en) * 2012-06-11 2013-12-19 Necエナジーデバイス株式会社 Electrode manufacturing method
CN106159196A (en) * 2016-08-29 2016-11-23 天津力神电池股份有限公司 Bury lug formula pole piece and lithium ion battery
CN114846656A (en) * 2020-02-10 2022-08-02 株式会社Lg新能源 Electrode and electrode assembly

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11312517A (en) * 1998-04-28 1999-11-09 Shin Kobe Electric Mach Co Ltd Manufacture of battery electrode
JP2001160386A (en) * 1999-12-03 2001-06-12 Japan Storage Battery Co Ltd Cylindrical battery
JP2005044539A (en) * 2003-07-23 2005-02-17 Mitsubishi Heavy Ind Ltd Manufacturing method of secondary battery electrode and roll press device
JP2012238427A (en) * 2011-05-10 2012-12-06 Gs Yuasa Corp Electrochemical device and manufacturing method of electrochemical device
WO2013079570A1 (en) * 2011-11-30 2013-06-06 Volkswagen Varta Microbattery Forschungsgesellschaft Mbh & Co. Kg Electrodes for lithium ion batteries and the production thereof
WO2013187172A1 (en) * 2012-06-11 2013-12-19 Necエナジーデバイス株式会社 Electrode manufacturing method
JPWO2013187172A1 (en) * 2012-06-11 2016-02-04 Necエナジーデバイス株式会社 Electrode manufacturing method
CN106159196A (en) * 2016-08-29 2016-11-23 天津力神电池股份有限公司 Bury lug formula pole piece and lithium ion battery
CN114846656A (en) * 2020-02-10 2022-08-02 株式会社Lg新能源 Electrode and electrode assembly

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