JPH1044189A - Device and method for manufacturing two-color molding simultaneous muffle painting product - Google Patents

Device and method for manufacturing two-color molding simultaneous muffle painting product

Info

Publication number
JPH1044189A
JPH1044189A JP21916996A JP21916996A JPH1044189A JP H1044189 A JPH1044189 A JP H1044189A JP 21916996 A JP21916996 A JP 21916996A JP 21916996 A JP21916996 A JP 21916996A JP H1044189 A JPH1044189 A JP H1044189A
Authority
JP
Japan
Prior art keywords
molding
primary
primary molding
mold
secondary molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP21916996A
Other languages
Japanese (ja)
Other versions
JP3833310B2 (en
Inventor
Kentaro Fujii
憲太郎 藤井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissha Printing Co Ltd
Original Assignee
Nissha Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissha Printing Co Ltd filed Critical Nissha Printing Co Ltd
Priority to JP21916996A priority Critical patent/JP3833310B2/en
Publication of JPH1044189A publication Critical patent/JPH1044189A/en
Application granted granted Critical
Publication of JP3833310B2 publication Critical patent/JP3833310B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/16Making multilayered or multicoloured articles
    • B29C45/1671Making multilayered or multicoloured articles with an insert

Abstract

PROBLEM TO BE SOLVED: To provide a two-color molding simultaneous muffle painting product manufacturing device and a two-color molding simultaneous muffle painting product manufacturing method thereof in which the two-color molding simultaneous muffle painting product with a good-looking pattern formed on one of both of materials of different material quality can be manufactured efficiently. SOLUTION: In a two-color molding simultaneous muffle painting product manufacturing device provided with a primary molding means composed of a primary molding core mold 11 and a primary molding cavity mold 12, a secondary molding means composed of a secondary molding core mold 14 and a secondary molding cavity mold 15 and a muffle painting sheet feed means, an intermediate plate 19 with a primary molding resin section retaining means is provided to be movable between the position located between the primary molding core mold 11 and the primary molding cavity mold 12 and the position located between the secondary molding core mold 14 and the secondary molding cavity mold 15 and a decorative sheet can be fed between the cavity mold of at least one of either the primary molding means or the secondary means and the intermediate plate 19 by the decorative sheet feed means.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明はAV機器や家電製品
のフロントパネルやケース、ボタン、自動車の計器パネ
ルやボタン等に用いられる2色成形同時絵付け品の製造
装置と製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a manufacturing apparatus and a manufacturing method for a two-color molded simultaneous painting product used for a front panel, a case, a button of an AV device or a home appliance, an instrument panel or a button of an automobile, and the like.

【0002】[0002]

【従来の技術】従来、コンピュータの入力ボタン等の製
品を製造する方法として、色や材質の異なる2種類の溶
融した成形樹脂を1台の射出成形機の2本のノズルより
順次射出して、異なる2種類の成形樹脂部が接合した2
色成形品を製造する、いわゆる2色成形法がある。ま
た、基体シート上に絵柄層などが形成された絵付けシー
トを型閉めして挟み込み、溶融した成形樹脂を射出成形
すると同時に樹脂成形品に絵付けシートを接着させて成
形同時絵付け品を得る、いわゆる成形同時絵付け法があ
る。
2. Description of the Related Art Conventionally, as a method of manufacturing a product such as an input button of a computer, two types of molten molding resins having different colors and materials are sequentially injected from two nozzles of one injection molding machine. 2 where two different types of molding resin parts are joined
There is a so-called two-color molding method for producing a colored molded product. In addition, a painting sheet having a pattern layer or the like formed on a base sheet is closed and sandwiched, and a molten molding resin is injection-molded, and at the same time, the painting sheet is adhered to a resin molded product to obtain a simultaneously molded painting product. There is a so-called molding simultaneous painting method.

【0003】[0003]

【発明が解決しようとする課題】前者の2色成形法によ
る意匠表現としては、射出成形される樹脂の色、素材に
よるもので2色あるは2種類に限定されるため、デザイ
ン的に満足のいくものではなかった。また、後者では、
デザイン的には転写層の絵柄によって満足されても、材
質が単一に限定される。たとえば、ABS樹脂のオーデ
ィオパネル内に熱可塑性エラストマー樹脂でできたボタ
ンを有し、かついずれの樹脂にも多色で美麗な意匠が施
されたものを得ることができなかった。また、インサー
ト成形といって、一次成形品(例えば、成形同時絵付け
品)を先に得ておき、これを別工程で、2次成形用金型
にインサート(配置)し、2次成形樹脂を射出成形する
方法もあるが、1次成形品を得てから経時で2次成形を
するため次のような問題があり、現実にほとんど行なわ
れていない。 1.1次成形品の収縮歪みにより2次成形金型にインサ
ートしにくい。又は、不可能な場合もある。 2.1次成形品が冷えてから、2次成形品を成形するた
め1次成形品と2次成形品との密着ができない。また
は、1次成形品と2次成形品との密着が悪いため、耐久
テストでインサートシートが剥離するという問題があ
る。 3.絵付けは1次成形品側にしかできない(2次成形品
との位置合わせが問題となる。)。 4.工程がわかれコスト高になる。
As the design expression by the former two-color molding method, there are two colors or two types depending on the color and material of the resin to be injection-molded. It didn't work. In the latter,
Even if the design is satisfied by the pattern of the transfer layer, the material is limited to a single material. For example, it was not possible to obtain a button having a button made of a thermoplastic elastomer resin in an audio panel made of an ABS resin, and having a multicolored and beautiful design applied to any resin. Also, in the insert molding, a primary molded product (for example, a simultaneously painted product) is obtained first, and this is inserted (arranged) in a secondary molding die in a separate step, and the secondary molded resin is obtained. There is also a method of injection molding, but since the secondary molding is performed with the passage of time after obtaining the primary molded product, the following problem occurs, and practically, it is hardly performed. 1. It is difficult to insert into the secondary molding die due to shrinkage strain of the primary molded product. Or it may not be possible. 2. Since the secondary molded product is molded after the primary molded product has cooled, close contact between the primary molded product and the secondary molded product is not possible. Alternatively, since the adhesion between the primary molded product and the secondary molded product is poor, there is a problem that the insert sheet is peeled off in the durability test. 3. Painting can be performed only on the primary molded product side (positioning with the secondary molded product becomes a problem). 4. The process is separated and the cost increases.

【0004】この発明の目的は、異材質の材料の一方あ
るいは両方に、見栄えの良い絵柄が形成された2色成形
同時絵付け品を効率良く生産することができる2色成形
同時絵付け品製造装置と2色成形同時絵付け品製造方法
を提供することにある。
[0004] It is an object of the present invention to manufacture a two-color molded simultaneous painting product which can efficiently produce a two-color molded simultaneous painting product in which an attractive pattern is formed on one or both of different materials. It is an object of the present invention to provide an apparatus and a method for producing a two-color molded simultaneous painting product.

【0005】[0005]

【課題を解決するための手段】上記の目的を達成するた
めに、この発明の2色成形同時絵付け品製造装置は、請
求項1に記載したように、1次成形樹脂射出路を有する
1次成形用コア型と1次成形用キャビティ型とからなる
1次成形手段と、2次成形樹脂射出路を有する2次成形
用コア型と2次成形用キャビティ型とからなる2次成形
手段と、絵付けシート供給手段とを有する2色成形同時
絵付け品製造装置において、1次成形樹脂部保持手段を
有する中間プレートが、1次成形用コア型と1次成形用
キャビティ型との間の位置と、2次成形用コア型と2次
成形用キャビティ型との間の位置との間を移動可能に設
けられ、絵付けシート供給手段が、1次成形手段と2次
成形手段の少なくともいずれか一方のキャビティ型と中
間プレートとの間に絵付けシートを供給可能であるよう
にした。
In order to achieve the above-mentioned object, a two-color molding simultaneous painting product manufacturing apparatus of the present invention has a primary molding resin injection path as described in claim 1. A primary molding means including a secondary molding core mold and a primary molding cavity mold, and a secondary molding means including a secondary molding core mold having a secondary molding resin injection path and a secondary molding cavity mold. In the two-color molding simultaneous painting product manufacturing apparatus having the painting sheet supply means, the intermediate plate having the primary molding resin portion holding means is provided between the primary molding core mold and the primary molding cavity mold. And a position between the secondary molding core mold and the secondary molding cavity mold, the painting sheet supply means being at least one of the primary molding means and the secondary molding means. Between one cavity mold and the intermediate plate The painting sheet was to be supplied.

【0006】また、この発明の2色成形同時絵付け品製
造方法は、請求項2に記載したように、請求項1記載の
2色成形同時絵付け品製造装置と絵付けシートとを用意
し、まず、中間プレートを間に挟んで1次成形用キャビ
ティ型と1次成形用コア型とを型締めした後、1次成形
して1次成形樹脂部保持手段に保持された1次成形樹脂
部を得、次に、前記保持したままの中間プレートを2次
成形用キャビティ型と2次成形用コア型との間の位置ま
で移動させ、1次成形樹脂部が保持された中間プレート
を間に挟んで2次成形用キャビティ型と2次成形用コア
型とを型締めした後、2次成形して2次成形樹脂部を得
ることによって、1次成形樹脂部と2次成形樹脂部とが
1体化し、かつ、1次成形樹脂部と2次成形樹脂部との
少なくともいずれか一方に絵付けシートが接着した2色
成形絵付け品を得る製造方法であって、1次成形用キャ
ビティ型と中間プレートとの間、あるいは、2次成形用
キャビティ型と中間プレートとの間のいずれか少なくと
も一方において、型締め前に絵付けシートを配置するよ
うにした。
According to a second aspect of the present invention, there is provided a method of manufacturing a simultaneous two-color molded article, comprising the steps of: First, the primary molding cavity mold and the primary molding core mold are clamped with the intermediate plate interposed therebetween, and then the primary molding is performed and the primary molding resin held by the primary molding resin holding means is held. Part, and then move the held intermediate plate to a position between the secondary molding cavity mold and the secondary molding core mold, and move the intermediate plate holding the primary molding resin part between the secondary molding cavity mold and the secondary molding core mold. The secondary molding cavity mold and the secondary molding core mold are clamped between them, and then the secondary molding is performed to obtain a secondary molding resin part, whereby a primary molding resin part and a secondary molding resin part are formed. Are integrated and at least one of the primary molding resin part and the secondary molding resin part A method for producing a two-color molded article having a painting sheet adhered thereto, wherein the two-color molded article is provided between a primary molding cavity mold and an intermediate plate or between a secondary molding cavity mold and an intermediate plate. In at least one of them, the painting sheet is arranged before clamping.

【0007】また、この発明の製造方法では、請求項3
に記載したように、1次成形用キャビティ型と中間プレ
ートとの間に配置した絵付けシートの接着層の一部が、
2次成形において2次成形樹脂部に接着するようにして
もよい。
Further, according to the manufacturing method of the present invention, claim 3
As described in, part of the adhesive layer of the painting sheet disposed between the primary molding cavity mold and the intermediate plate,
In the secondary molding, it may be adhered to the secondary molding resin part.

【0008】また、この発明の製造方法では、請求項4
に記載したように、基体シート上に少なくとも絵柄層と
接着層が積層され基体シートが剥離可能な絵付けシート
を用い、1次成形後あるいは2次成形後のいずれか少な
くとも一方において、基体シートを剥離するようにして
もよい。
Further, according to the manufacturing method of the present invention, claim 4
As described in the above, using a painting sheet on which at least a picture layer and an adhesive layer are laminated on the base sheet and the base sheet can be peeled off, the base sheet is formed after at least one of the primary molding and the secondary molding. You may make it exfoliate.

【0009】[0009]

【発明の実施の形態】以下、図面を参照しながらこの発
明を詳しく説明する。この発明の2色成形同時絵付け品
の製造方法に用いる絵付けシート、および2色成形同時
絵付け品製造装置を先に説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below in detail with reference to the drawings. The painting sheet and the two-color simultaneous painting product manufacturing apparatus used in the method for producing a two-color simultaneous painting product of the present invention will be described first.

【0010】絵付けシートを説明する。絵付けシート1
は、基本的に、基体シート2上に少なくとも絵柄層3、
接着層4が積層されたものである。絵付けシート1の種
類は、絵付けシートに成形樹脂が接着した後に基体シー
ト2を剥離しないもの(以下、「インサートシート」と
いう。図6参照)、基体シート2が剥離可能なもの(以
下、「転写シート」という。図7参照)とがある。転写
シートとして用いる場合は、基体シートと絵柄層3との
間に剥離層5を形成するか、基体シート1にニスなどを
塗って剥離性を付与するとよい。転写シートでは、少な
くとも絵柄層3、接着層4が積層されたものを転写層と
いう。以下、1次成形時に用いられる絵付けシート1を
1次成形用絵付けシート6あるいは1次成形用転写シー
トとする。また、2次成形時に用いられる絵付けシート
1を2次成形用絵付けシート7あるいは2次成形用転写
シートとする。また、1次成形樹脂部8に転写されるも
のを1次成形用転写層とし、2次成形樹脂部9に転写さ
れるものを2次成形用転写層とする。基体シート2の材
質は、ポリエチレンテレフタレートやアクリル、熱可塑
性エラストマー等の各種樹脂がある。剥離層5の材質
は、ポリアクリル系樹脂等があり、剥離層5に硬度が要
求される場合には、紫外線硬化性樹脂等の電離放射線硬
化樹脂を使用してもよい。電離放射線硬化樹脂は、単体
での使用してもよいし、他の樹脂と混合して使用しても
よい。絵柄層3は樹脂バインダーと顔料または染料を用
いる。絵柄層3は樹脂バインダーと隠蔽性のある金属顔
料や無機顔料等を用いてもよい。接着層4は、1次成形
樹脂と2次成形樹脂の素材に適した感熱性あるいは感圧
性の樹脂を適宜使用する。たとえば、1次成形樹脂がア
クリル樹脂で、2次成形樹脂がウレタン樹脂の場合は、
接着層として塩化ビニル酢酸ビニル共重合樹脂を用いる
とよい。剥離層5、絵柄層3、接着層4は各種印刷法で
形成する。絵付けシート1は、接着層4が、1次成形樹
脂8に接着する1次接着部と、2次成形樹脂9にのみ接
着する2次接着部とからなるものであってもよい。絵付
けシート1は、接着層4が、1次成形樹脂に接着する1
次接着部のみからなるものでもよい。絵付けシート1
は、2次成形樹脂部9に対応する部分が切り抜かれてい
てもよい。絵付けシート1は、枚葉にカットしてあって
もよいし、ロール状に巻き取ったものでもよい。
The painting sheet will be described. Painting sheet 1
Basically has at least a pattern layer 3 on the base sheet 2,
The adhesive layer 4 is laminated. The types of the decorating sheet 1 are those that do not peel the base sheet 2 after the molding resin adheres to the decorating sheet (hereinafter, referred to as “insert sheets”; see FIG. 6), and those that can peel the base sheet 2 (hereinafter, referred to as “insert sheet”). This is referred to as a “transfer sheet” (see FIG. 7). When used as a transfer sheet, a release layer 5 may be formed between the base sheet and the picture layer 3, or a varnish may be applied to the base sheet 1 to impart releasability. In the transfer sheet, a layer in which at least the picture layer 3 and the adhesive layer 4 are laminated is referred to as a transfer layer. Hereinafter, the painting sheet 1 used at the time of primary molding is referred to as a painting sheet 6 for primary molding or a transfer sheet for primary molding. The painting sheet 1 used at the time of secondary molding is referred to as a painting sheet 7 for secondary molding or a transfer sheet for secondary molding. In addition, what is transferred to the primary molding resin part 8 is a primary molding transfer layer, and what is transferred to the secondary molding resin part 9 is a secondary molding transfer layer. The material of the base sheet 2 includes various resins such as polyethylene terephthalate, acrylic, and thermoplastic elastomer. The material of the release layer 5 is a polyacrylic resin or the like. If the release layer 5 requires hardness, an ionizing radiation curable resin such as an ultraviolet curable resin may be used. The ionizing radiation-curable resin may be used alone, or may be used as a mixture with another resin. The picture layer 3 uses a resin binder and a pigment or a dye. The picture layer 3 may use a resin binder and a metal pigment or an inorganic pigment having a masking property. For the adhesive layer 4, a heat-sensitive or pressure-sensitive resin suitable for the material of the primary molding resin and the secondary molding resin is appropriately used. For example, if the primary molding resin is an acrylic resin and the secondary molding resin is a urethane resin,
It is preferable to use a vinyl chloride-vinyl acetate copolymer resin as the adhesive layer. The release layer 5, the picture layer 3, and the adhesive layer 4 are formed by various printing methods. The decorating sheet 1 may include a primary adhesive portion where the adhesive layer 4 adheres to the primary molding resin 8 and a secondary adhesive portion which adheres only to the secondary molding resin 9. In the painting sheet 1, the adhesive layer 4 is bonded to the primary molding resin.
It may be composed of only the next bonding portion. Painting sheet 1
The portion corresponding to the secondary molding resin portion 9 may be cut out. The painting sheet 1 may be cut into single sheets, or may be rolled up.

【0011】2色成形同時絵付け品製造装置を説明する
(図1〜図4)。2色成形同時絵付け品製造装置は、1
次成形樹脂射出路10を有する1次成形用コア型11と
1次成形用キャビティ型12とからなる1次成形手段
と、2次成形樹脂射出路13を有する2次成形用コア型
14と2次成形用キャビティ型15とからなる2次成形
手段と、絵付けシート供給手段16とを有する2色成形
同時絵付け品製造装置において、1次成形樹脂部保持手
段を有する中間プレート19が1次成形用コア型と1次
成形用キャビティ型との間の位置と、2次成形用コア型
と2次成形用キャビティ型との間の位置との間を移動可
能に設けられ、絵付けシート供給手段16が1次成形手
段と2次成形手段の少なくともいずれか一方において、
前記絵付けシート1を中間プレート19とキャビティ型
との間に供給するものである。
A two-color molding simultaneous painting product manufacturing apparatus will be described (FIGS. 1 to 4). Two color molding simultaneous painting product manufacturing equipment
Primary molding means including a primary molding core mold 11 having a primary molding resin injection path 10 and a primary molding cavity mold 12, and secondary molding core dies 14 and 2 having a secondary molding resin injection path 13. In the two-color molding simultaneous painting product manufacturing apparatus having the secondary molding means including the secondary molding cavity mold 15 and the painting sheet supply means 16, the intermediate plate 19 having the primary molding resin part holding means is provided with the primary molding resin. A painting sheet supply is provided so as to be movable between a position between the molding core mold and the primary molding cavity mold and a position between the secondary molding core mold and the secondary molding cavity mold. Means 16 is at least one of the primary molding means and the secondary molding means,
The painting sheet 1 is supplied between the intermediate plate 19 and the cavity mold.

【0012】1次成形用コア型11と2次成形用コア型
14とが固定盤20に取付けられる。1次成形用コア型
11の1次成形樹脂射出路10を介して、射出ユニット
21から射出された1次成形樹脂22がキャビティ内に
充填される。2次成形用コア型14の2次成形樹脂射出
路13を介して、射出ユニット21から射出された2次
成形樹脂23がノズル孔28を通過してキャビティ内に
充填される。1次成形用キャビティ型12と2次成形用
キャビティ型15とは可動盤24に取付けられる。1次
成形用キャビティ型12と2次成形用キャビティ型15
との内面には、絵付けシート1を吸引するための真空吸
引孔(図示せず)が形成されてもよい。1次成形用コア
型11と2次成形用コア型14は、それぞれ1次成形用
キャビティ型12と2次成形用キャビティ型15と対向
するように配置される。可動盤24は油圧シリンダーや
電動サーボモータ駆動方式などの駆動源25によってタ
イバー26をつたって移動する。この移動により型締
め、型開きが行なわれる。
A core mold 11 for primary molding and a core mold 14 for secondary molding are mounted on a fixed platen 20. The cavity is filled with the primary molding resin 22 injected from the injection unit 21 via the primary molding resin injection path 10 of the primary molding core mold 11. The secondary molding resin 23 injected from the injection unit 21 through the secondary molding resin injection path 13 of the secondary molding core 14 passes through the nozzle hole 28 and fills the cavity. The primary molding cavity mold 12 and the secondary molding cavity mold 15 are attached to a movable platen 24. Cavity mold 12 for primary molding and cavity mold 15 for secondary molding
A vacuum suction hole (not shown) for sucking the painting sheet 1 may be formed on the inner surface of the sheet. The primary molding core mold 11 and the secondary molding core mold 14 are arranged so as to face the primary molding cavity mold 12 and the secondary molding cavity mold 15, respectively. The movable platen 24 moves along a tie bar 26 by a drive source 25 such as a hydraulic cylinder or an electric servomotor drive system. By this movement, the mold is closed and the mold is opened.

【0013】中間プレート19は、1次成形樹脂部保持
手段を有する。1次成形樹脂部保持手段は、中間プレー
ト19のうち1次成形樹脂部8が接触する部分に、1次
成形樹脂部に突き刺さる保持ピン32を立てたものでも
よい(図8)。あるいは、1次成形樹脂部保持手段は、
中間プレート19に1次成形用孔17と2次成形用孔1
8とが形成されており、1次成形用孔17と2次成形用
孔18とが1次成形用コア型と1次成形用キャビティ型
との間の位置と、2次成形用コア型と2次成形用キャビ
ティ型との間の位置との間を移動可能なものがある。具
体的には、中間プレート19は、1次成形用キャビティ
型12と1次成形用コア型11との隙間と、2次成形用
キャビティ型15と2次成形用コア型14との隙間との
間を移動する。中間プレート19は、回転動作が可能な
回転盤やスライドが可能なスライド盤などの可動盤24
に取付けるとよい。中間プレート19が軸27を中心と
して回転することによって、保持ピン32や1次成形用
孔17と2次成形用孔18とが円弧を描いて移動するも
のがある(図1〜図4、図8)。軸27は、可動盤24
側からあるいは固定盤20側からの片持ち軸でもよい
し、可動盤24と固定盤20との両方を貫くものでもよ
い。中間プレート19は、スライド盤に取付けてもよ
い。スライド盤は、固定盤に取り付けられても可動盤に
取り付けられてもよい。また、コア型上あるいはキャビ
ティ型上に取り付けられてもよい。また、中間プレート
19は、キャビティ型やコア型に対して接近、離隔する
ように駆動される。中間プレート19は、絵付けシート
1をキャビティ型のパーティング面に押さえ付けるクラ
ンプの役目をすることもできる。
The intermediate plate 19 has means for holding a primary molded resin portion. The primary molded resin portion holding means may be one in which a holding pin 32 that pierces the primary molded resin portion is set up at a portion of the intermediate plate 19 where the primary molded resin portion 8 contacts (FIG. 8). Alternatively, the primary molded resin part holding means is:
The hole 17 for primary molding and the hole 1 for secondary molding are formed in the intermediate plate 19.
8 are formed, and the primary molding hole 17 and the secondary molding hole 18 are positioned between the primary molding core mold and the primary molding cavity mold, and the secondary molding core mold is formed. Some are movable between a position and a secondary mold cavity. Specifically, the intermediate plate 19 has a gap between the primary molding cavity mold 12 and the primary molding core mold 11 and a gap between the secondary molding cavity mold 15 and the secondary molding core mold 14. Move between. The intermediate plate 19 is provided with a movable plate 24 such as a rotary plate capable of rotating operation and a slide plate capable of sliding.
It is good to attach to. The rotation of the intermediate plate 19 about the shaft 27 causes the holding pin 32 or the primary molding hole 17 and the secondary molding hole 18 to move in an arc (FIGS. 1 to 4 and FIG. 4). 8). The shaft 27 is a movable platen 24
It may be a cantilever shaft from the side or the fixed platen 20 side, or may penetrate both the movable platen 24 and the fixed platen 20. The intermediate plate 19 may be mounted on a slide disk. The slide plate may be attached to a fixed plate or a movable plate. Further, it may be mounted on a core mold or a cavity mold. The intermediate plate 19 is driven so as to approach and separate from the cavity mold and the core mold. The intermediate plate 19 can also serve as a clamp for pressing the decorating sheet 1 against the parting surface of the cavity mold.

【0014】射出ユニット21は、横型成形機(金型の
キャビティ型とコア型が左右に向かい合って設置され、
水平方向に型閉めされるもの)でも竪型成形機(金型の
キャビティ型とコア型が上下に向かい合って設置され、
垂直方向に型閉めされるもの)でもよい。2種類の材料
を可塑化させるためのシリンダーが2本あり、その各々
に金型に樹脂を注入あるいは射出するノズル孔28がつ
いた成形機でもよい。2本のシリンダーは並行、対向の
いずれでもよく、また、直角方向に配置されてもよい。
シリンダーは、垂直方向、水平方向のいずれに配置され
てもよい。前記1次成形用コア型11と2次成形用コア
型14とは上下に並んでいてもよいし左右に並んでいて
もよいし、射出路を向かい合わせに並んでいてもよい。
1本のシリンダーから2つの成形樹脂射出ノズルに枝分
れするものでもよい。
The injection unit 21 is provided with a horizontal molding machine (a cavity mold and a core mold of a mold are installed facing each other,
Even with horizontal molding, the vertical molding machine (cavity mold and core mold of the mold are installed facing each other up and down,
The mold may be closed vertically). A molding machine having two cylinders for plasticizing two kinds of materials, each having a nozzle hole 28 for injecting or injecting a resin into a mold may be used. The two cylinders may be either parallel or opposed, and may be arranged at right angles.
The cylinder may be arranged either vertically or horizontally. The primary molding core mold 11 and the secondary molding core mold 14 may be arranged vertically, may be arranged side by side, or may be arranged with the injection path facing each other.
It may be one that branches from one cylinder to two molding resin injection nozzles.

【0015】絵付けシート供給手段16は、1次成形手
段と2次成形手段の少なくともいずれか一方において、
絵付けシート1を中間プレート19とキャビティ型との
間に供給するものである。絵付けシート供給手段16
は、絵付けシート送り出し装置29と絵付けシート巻き
取り装置30とからなるものがある(図1〜図4)。あ
るいは、絵付けシート供給手段16は、絵付けシート送
り出し装置29と、絵付けシート切断手段と、絵付けシ
ートピンチ手段とからなるものがある。絵付けシート送
り出し装置29は、ロール状に巻き取った絵付けシート
1とこれを可動盤に支持する支持ロッド31や、絵付け
シート1を送り出すニップロールや、キャビティとの正
確な位置合わせのためのセンサーなどからなる。絵付け
シート巻き取り装置30は、絵付けシート送り出し装置
29から送られてきてロール状に巻き取った絵付けシー
ト1とこれを固定盤20に支持する支持ロッド31など
からなる。切断手段は、絵付けシート1を、コア型とキ
ャビティ型との間に位置する部分と、コア型とキャビテ
ィ型との間にまだ位置していない部分とに切り離し、絵
付けシート1に切断端部を形成するための手段である。
ピンチ手段は、コア型とキャビティ型との間にまだ入っ
てきていない絵付けシート1の切断端部をつかみ、コア
型とキャビティ型との間に絵付けシート1を引き込み導
入する手段である。
The painting sheet supply means 16 is provided in at least one of the primary molding means and the secondary molding means.
The painting sheet 1 is supplied between the intermediate plate 19 and the cavity mold. Painting sheet supply means 16
Includes a painting sheet feeding device 29 and a painting sheet winding device 30 (FIGS. 1 to 4). Alternatively, the painting sheet supply unit 16 includes a painting sheet feeding device 29, a painting sheet cutting unit, and a painting sheet pinch unit. The painting sheet feeding device 29 is used for accurately aligning the painting sheet 1 wound up in a roll shape with a support rod 31 for supporting the painting sheet 1 on a movable platen, a nip roll for feeding the painting sheet 1, and a cavity. Consists of sensors, etc. The decorating sheet winding device 30 includes the decorating sheet 1 sent from the decorating sheet feeding device 29 and wound in a roll shape, and a support rod 31 for supporting the decorating sheet 1 on the fixed platen 20. The cutting means cuts the decorating sheet 1 into a portion located between the core mold and the cavity mold and a portion not yet located between the core mold and the cavity mold, and cuts the decorating sheet 1 into cut ends. Means for forming a part.
The pinch means is a means for grasping the cut end of the painting sheet 1 that has not yet entered between the core mold and the cavity mold, and drawing and introducing the painting sheet 1 between the core mold and the cavity mold.

【0016】以下、この発明の2色成形同時絵付け品の
製造方法を説明する。この発明の2色成形同時絵付け品
の製造方法は、基本的に、前記2色成形同時絵付け品製
造装置と、前記絵付けシートとを用意し、まず、中間プ
レートを間に挟んで1次成形用キャビティ型と1次成形
用コア型とを型締めした後、1次成形して1次成形樹脂
部を得て1次成形樹脂部保持手段に保持し、次に、1次
成形樹脂部を中間プレートの1次成形用孔で保持したま
ま、2次成形用キャビティ型と2次成形用コア型との間
まで移動させ、1次成形樹脂部が保持された中間プレー
トを間に挟んで1次成形用キャビティ型と2次成形用コ
ア型とを型締めした後、2次成形して2次成形樹脂部を
得ることによって、1次成形樹脂部と2次成形樹脂部と
が1体化し、かつ、1次成形樹脂部と2次成形樹脂部と
の少なくともいずれか一方に絵付けシート1が接着した
2色成形絵付け品が得られる製造方法である。
Hereinafter, a method for producing a two-color molded simultaneous painted product of the present invention will be described. The method for producing a two-color molded simultaneous painting product of the present invention basically comprises preparing the two-color molded simultaneous painting product manufacturing apparatus and the painting sheet, and first, interposing an intermediate plate therebetween. After the primary molding cavity mold and the primary molding core mold are clamped, the primary molding is performed to obtain a primary molding resin part, which is held in the primary molding resin part holding means, and then the primary molding resin is retained. While holding the part in the primary molding hole of the intermediate plate, it is moved between the secondary molding cavity mold and the secondary molding core mold to sandwich the intermediate plate holding the primary molding resin part therebetween. After the primary molding cavity mold and the secondary molding core mold are clamped with each other, secondary molding is performed to obtain a secondary molding resin part. At least one of the primary molding resin part and the secondary molding resin part. 1 is a manufacturing method of two-color molding decorating articles adhered is obtained.

【0017】また、この発明の2色成形同時絵付け品の
製造方法は、キャビティ型とコア型との型締め前に、キ
ャビティ型と中間プレートとの間に絵付けシート1を配
置するものである。配置とは、絵付けシート供給装置に
よって配置する場合や、中間プレートの移動によって配
置する場合、人為的、機械的に配置する場合がある。1
次成形時の型締前に、1次成形用キャビティ型と中間プ
レートとの間に絵付けシート1を配置し、2次成形時の
型締前に、2次成形用キャビティ型と中間プレートとの
間に絵付けシート1を配置しない方法がある。あるい
は、1次成形時の型締前に、1次成形用キャビティ型と
中間プレートとの間に絵付けシート1を配置せず、2次
成形時の型締前に、2次成形用キャビティ型と中間プレ
ートとの間に絵付けシート1を配置する方法がある。あ
るいは、1次成形時の型締前に、1次成形用キャビティ
型と中間プレートとの間に絵付けシート1を配置し、か
つ、2次成形時の型締前に、2次成形用キャビティ型と
中間プレートとの間に絵付けシート1を配置する方法が
ある。1次成形用キャビティ型と中間プレートとの間に
配置した1次成形用絵付けシートを1次成形樹脂部に接
着したまま、1次成形樹部を移動し、2次成形用キャビ
ティ型と中間プレートとの間に、1次成形樹部ごと1次
成形用絵付けシートを配置してもよい。
Further, in the method of manufacturing a simultaneously colored two-color article according to the present invention, the painting sheet 1 is arranged between the cavity mold and the intermediate plate before the mold is clamped between the cavity mold and the core mold. is there. The arrangement may be an arrangement by a painting sheet supply device, an arrangement by moving an intermediate plate, or an artificial or mechanical arrangement. 1
Before the mold clamping at the time of the next molding, the painting sheet 1 is arranged between the cavity mold for the primary molding and the intermediate plate. There is a method of not arranging the painting sheet 1 between them. Alternatively, the painting sheet 1 is not disposed between the primary molding cavity mold and the intermediate plate before the primary molding mold clamping, and the secondary molding cavity mold is not molded before the secondary molding mold clamping. There is a method of arranging the decorating sheet 1 between the intermediate sheet and the intermediate plate. Alternatively, the painting sheet 1 is arranged between the cavity mold for primary molding and the intermediate plate before clamping in the primary molding, and the cavity for secondary molding is arranged before clamping in the secondary molding. There is a method of disposing the decorating sheet 1 between the mold and the intermediate plate. The primary molding tree is moved while the painting sheet for primary molding placed between the cavity mold for primary molding and the intermediate plate is adhered to the primary molding resin portion, and the secondary molding cavity mold is moved to the intermediate position. You may arrange | position the painting sheet for primary shaping | molding with a primary shaping | molding tree part between plates.

【0018】以下、この発明の2色成形同時絵付け品の
製造方法の一具体例の各工程を説明する。具体例とし
て、1次成形時の型締前に、1次成形用キャビティ型1
2と中間プレート19との間に絵付けシート1を配置
し、かつ、2次成形時の型締前に、2次成形用キャビテ
ィ型15と中間プレート19との間に絵付けシート1を
配置するものを説明する。まず、1次成形用キャビティ
型12の上部に位置する絵付けシート送り出し装置29
から、一定長さ分の絵付けシート1を1次成形用キャビ
ティ型12の前に送り出し、1次成形用キャビティ型1
2の下部に位置する絵付けシート巻き取り装置30で一
定長さ分の絵付けシート1を巻き取り、1次成形用絵付
けシート6の所定の絵柄を1次成形用キャビティ型12
の1次成形用キャビティの正面に配置させる。1次成形
用絵付けシート6として1次成形用転写シートを用いて
もよい。必要により、1次成形用キャビティ型12と1
次成形用コア型11との型閉めの前に、1次成形用絵付
けシート6を加熱、真空吸引して、1次成形用キャビテ
ィ型12の1次成形用キャビティの内面に密着させても
よい(図1)。この時、中間プレート19あるいはクラ
ンプ部材によって1次成形用キャビティの周囲で1次成
形用絵付けシート6を固定してもよい。1次成形用絵付
けシート6が枚葉の場合は、人為的、機械的(ロボッ
ト)に1枚ずつキャビティ内に配置してもよい。以上の
ようにして、1次成形用絵付けシート6の配置が完了す
る。
Hereinafter, each step of a specific example of the method for producing a two-color molded simultaneous painting product of the present invention will be described. As a specific example, before the mold clamping at the time of the primary molding, the cavity mold for primary molding 1
The painting sheet 1 is arranged between the second mold 2 and the intermediate plate 19, and the painting sheet 1 is arranged between the cavity mold 15 for secondary molding and the intermediate plate 19 before clamping in the secondary molding. What you do is explained. First, the painting sheet feeding device 29 located above the primary molding cavity mold 12
, The painting sheet 1 of a certain length is sent out before the primary molding cavity mold 12 and the primary molding cavity mold 1
The painting sheet 1 for a fixed length is wound up by a painting sheet winding device 30 located at the lower part of the second molding sheet 2 and a predetermined pattern of the primary molding painting sheet 6 is formed into the primary molding cavity mold 12.
Is placed in front of the primary molding cavity. A transfer sheet for primary molding may be used as the painting sheet 6 for primary molding. If necessary, primary molding cavity molds 12 and 1
Before closing the mold with the core mold 11 for the next molding, the painting sheet 6 for the primary molding may be heated and vacuum-sucked so as to be in close contact with the inner surface of the cavity for the primary molding of the cavity mold 12 for the primary molding. Good (Figure 1). At this time, the primary molding painting sheet 6 may be fixed around the primary molding cavity by the intermediate plate 19 or the clamp member. When the primary forming painting sheet 6 is a single sheet, it may be artificially and mechanically (robot) arranged one by one in the cavity. As described above, the arrangement of the primary forming painting sheet 6 is completed.

【0019】次に、中間プレート19を間に挟んで1次
成形用キャビティ型12と1次成形用コア型11とを型
締めする。1次成形樹脂部保持手段として、中間プレー
ト19の1次成形用孔17を用いる場合は、1次成形用
キャビティ型12の表面と、中間プレート19の1次成
形用孔17の内面と、1次成形用コア型11の表面とか
らなる1次成形空間が形成される。1次成形用孔17
は、樹脂を通過させ、かつ1次成形樹脂部を保持する機
能を併せ持つこともできる。1次成形樹脂部保持手段と
して、中間プレート19上の保持ピン32を用いる場合
は、中間プレートに孔を有する必要は必ずしもなく、1
次成形用キャビティ型12の表面と1次成形用コア型1
1の表面とからなる1次成形空間が形成することができ
る。1次成形空間に1次成形樹脂22を射出して1次成
形し1次成形樹脂部8を得る。型締めは、駆動源25と
軸27とによって可動盤24を前方に押出すとよい。型
閉めによって、1次成形用キャビティ型12と中間プレ
ート19とで1次成形用絵付けシート6を挟み込む(図
2)。1次成形用キャビティ型12と中間プレート19
との接触を先にして、中間プレート19と1次成形用コ
ア型11との接触を後にする場合は、中間プレート19
の軸27を可動盤24側に引き込むとよい。1次成形樹
脂22の射出によって、1次成形樹脂部8と1次成形用
絵付けシート6の接着層4とが接着する(図2)。1次
成形用絵付けシート6として1次成形用転写シートを用
いる場合は、1次成形用転写シートの接着層と1次成形
樹脂部とが接着する。接着とは、溶融状態の1次成形樹
脂22が1次成形用絵付けシート6の接着層4に接触し
た状態で冷却固化して、1次成形樹脂部8が成形される
とともに1次成形樹脂部8と接着層4とがひっついて一
体となることをいう。1次成形樹脂22の射出は、射出
ユニット21の射出機構によって1次成形樹脂射出ノズ
ル、1次成形樹脂射出路10に成形樹脂を流して行な
う。1次成形樹脂22と2次成形樹脂23とは、相互に
異なる色の成形樹脂であってもよいし、相互に異なる硬
度の成形樹脂であってもよい。相互に異なる色の成形樹
脂とする場合の具体例は、1次成形樹脂22が黒色で2
次成形樹脂23が透明色である組合せや、1次成形樹脂
が白色で2次成形樹脂が青色である組合せがある。1次
成形樹脂も2次成形樹脂も透明でもよい。相互に異なる
硬度の成形樹脂とする場合の具体例は、1次成形樹脂が
JIS A硬度100以上の硬度の高い熱可塑性樹脂で
あって、2次成形樹脂がJIS A硬度30〜100の
熱可塑性エラストマーである組合せがある。または、1
次成形樹脂がJIS A硬度30〜100の熱可塑性エ
ラストマーで、2次成形樹脂がJIS A硬度100以
上の硬度の高い樹脂である組合せがある。JIS A硬
度100以上の硬度の高い樹脂としては、他に、アクリ
ルスチレン樹脂、アクリルスチレンブタジエン樹脂、ポ
リカーボネート樹脂、アクリル樹脂、ナイロン樹脂、ス
チレン樹脂、塩化ビニル樹脂、ポリエステル樹脂、ポリ
ウレタン樹脂、ポリプロピレン樹脂、ポリエチレン樹
脂、ポリブチレンテレフタレート樹脂、あるいはこれら
の樹脂のアロイ(混ぜ物、複合品ともいう。)がある。
JIS A硬度30〜100の熱可塑性エラストマーと
しては、スチレン−ブタジエン−スチレン(SBS)ブ
ロックコポリマー、水素添加SBSブロックコポリマー
等のスチレン系エラストマー、ポリエステル系エラスト
マー、ポリウレタン系エラストマー、ポリアミド系エラ
ストマーがある。この他、JIS A硬度30〜100
の熱可塑性エラストマーとして、シリコーン2液硬化樹
脂をLIM(リキッドインジェクションモールディン
グ)射出成形により設けてもよい。
Next, the primary molding cavity mold 12 and the primary molding core mold 11 are clamped with the intermediate plate 19 interposed therebetween. When the primary molding hole 17 of the intermediate plate 19 is used as the primary molding resin portion holding means, the surface of the primary molding cavity mold 12, the inner surface of the primary molding hole 17 of the intermediate plate 19, A primary molding space including the surface of the secondary molding core mold 11 is formed. Hole 17 for primary molding
Can also have a function of passing the resin and holding the primary molded resin portion. When the holding pins 32 on the intermediate plate 19 are used as the primary molded resin portion holding means, it is not always necessary to have holes in the intermediate plate.
Surface of Primary Molding Cavity Mold 12 and Primary Molding Core Mold 1
A primary molding space including the first surface can be formed. The primary molding resin 22 is injected into the primary molding space to perform primary molding to obtain the primary molding resin portion 8. The mold clamping may be performed by pushing the movable platen 24 forward by the drive source 25 and the shaft 27. By closing the mold, the painting sheet 6 for primary molding is sandwiched between the cavity mold 12 for primary molding and the intermediate plate 19 (FIG. 2). Primary molding cavity mold 12 and intermediate plate 19
When the contact between the intermediate plate 19 and the primary molding core mold 11 is performed first, and then the intermediate plate 19 is
The shaft 27 may be drawn into the movable platen 24 side. By the injection of the primary molding resin 22, the primary molding resin portion 8 and the adhesive layer 4 of the primary molding painting sheet 6 adhere (FIG. 2). When a transfer sheet for primary molding is used as the painting sheet 6 for primary molding, the adhesive layer of the transfer sheet for primary molding and the primary molding resin portion are bonded to each other. The bonding means that the primary molding resin 22 in a molten state is cooled and solidified in a state in which the primary molding resin 22 is in contact with the adhesive layer 4 of the painting sheet for primary molding 6, whereby the primary molding resin portion 8 is molded and the primary molding resin is formed. This means that the portion 8 and the adhesive layer 4 are stuck together to be integrated. The injection of the primary molding resin 22 is performed by flowing the molding resin through the primary molding resin injection nozzle and the primary molding resin injection path 10 by the injection mechanism of the injection unit 21. The primary molding resin 22 and the secondary molding resin 23 may be molding resins of mutually different colors or molding resins of mutually different hardness. A specific example in the case of using molding resins of different colors is that the primary molding resin 22 is black and 2
There are combinations in which the secondary molding resin 23 is transparent, and combinations in which the primary molding resin is white and the secondary molding resin is blue. Both the primary molding resin and the secondary molding resin may be transparent. A specific example in which molding resins having different hardnesses are used is that the primary molding resin is a thermoplastic resin having a high hardness of JIS A hardness of 100 or more, and the secondary molding resin is a thermoplastic resin having a JIS A hardness of 30 to 100. Some combinations are elastomeric. Or 1
There is a combination in which the secondary molding resin is a thermoplastic elastomer having a JIS A hardness of 30 to 100 and the secondary molding resin is a high hardness resin having a JIS A hardness of 100 or more. Other resins having a high hardness of JIS A hardness of 100 or more include acrylic styrene resin, acrylic styrene butadiene resin, polycarbonate resin, acrylic resin, nylon resin, styrene resin, vinyl chloride resin, polyester resin, polyurethane resin, polypropylene resin, There is a polyethylene resin, a polybutylene terephthalate resin, or an alloy (also called a mixture or a composite product) of these resins.
Examples of the thermoplastic elastomer having a JIS A hardness of 30 to 100 include styrene-based elastomers such as styrene-butadiene-styrene (SBS) block copolymer and hydrogenated SBS block copolymer, polyester-based elastomer, polyurethane-based elastomer, and polyamide-based elastomer. In addition, JIS A hardness 30-100
As a thermoplastic elastomer, a silicone two-liquid curing resin may be provided by LIM (liquid injection molding) injection molding.

【0020】次に、1次成形用キャビティ型12と1次
成形用コア型11とを型開きして、中間プレート19の
1次成形用孔17あるいは保持ピン32に1次成形樹脂
部8を保持したままの状態で、中間プレート19と1次
成形用キャビティ型12とを分離させる。1次成形用孔
17の孔の内面あるいは保持ピン32と、1次成形樹脂
部8との摩擦力が大きいので、1次成形樹脂部8が中間
プレート19に保持されたまま、1次成形樹脂部8と1
次成形用キャビティ型12とを分離することができる。
そして、1次成形樹脂部8を中間プレート19の1次成
形用孔17あるいは保持ピン32で保持したまま、2次
成形用キャビティ型15と2次成形用コア型14との間
まで移動させる(図3)。1次成形用絵付けシート6と
して1次成形用転写シートを用いた場合は、1次成形用
キャビティ型12と1次成形用コア型11との型開きと
ともに1次成形用転写シートの基体シート2を剥離し、
1次成形用転写層が接着した1次成形樹脂部8を中間プ
レート19の1次成形用孔17または保持ピン32で保
持したまま、2次成形用キャビティ型15と2次成形用
コア型14との間まで移動させてもよい。1次成形用転
写シートであっても基体シート2を剥離せずに中間プレ
ート19で移動させてもよい。1次成形樹脂部8を中間
プレート19によって2次成形用キャビティ型15と2
次成形用コア型14との間まで移動させるとともに、2
次成形用キャビティ型と中間プレート19との間に2次
成形用絵付けシート7を配置してもよい。2次成形用絵
付けシート7として、2次成形用転写シートを用いても
よい。中間プレート19の移動は、駆動源と軸とによっ
て中間プレートを回転させたり、スライド盤をスライド
させるとよい。中間プレートの回転を所定位置で停止さ
せるには、摩擦などにより機械的に行なってもよいし、
電磁力などにより電気的に行なってもよい。中間プレー
トの移動の前か後、あるいは同時に、2次成形用キャビ
ティ型と中間プレートとの間に2次成形用絵付けシート
を配置してもよい。2次成形用絵付けシートとして2次
成形用転写シートを用いてもよい。1次成形用キャビテ
ィ型と中間プレートとの間に配置した1次成形用絵付け
シートを1次成形樹脂部に接着したまま、1次成形樹部
を移動し、2次成形用キャビティ型と中間プレートとの
間に、1次成形樹部ごと1次成形用絵付けシートを配置
してもよい。この場合は、絵付けシート1として、接着
層4が、1次成形樹脂8に接着する1次接着部と、2次
成形樹脂9にのみ接着する2次接着部とからなるものを
使用することができる。配置の仕方は、2次成形用キャ
ビティ型の上部に位置する絵付けシート送り出し装置2
9から、一定長さ分の2次成形用絵付けシートを2次成
形用キャビティ型の前に送り出し、2次成形用キャビテ
ィ型の下部に位置する絵付けシート巻き取り装置30に
よって巻き取る方法や、2次成形用キャビティ型15の
上部で2次成形用絵付けシート7を切断する方法など、
前記1次成形用絵付けシートを1次成形用キャビティ型
に配置する場合と同様にするとよい。
Next, the primary molding cavity mold 12 and the primary molding core mold 11 are opened, and the primary molding resin portion 8 is inserted into the primary molding holes 17 or the holding pins 32 of the intermediate plate 19. The intermediate plate 19 and the primary molding cavity mold 12 are separated while being held. Since the frictional force between the inner surface of the hole of the primary molding hole 17 or the holding pin 32 and the primary molding resin portion 8 is large, the primary molding resin portion 8 is held while the primary molding resin portion 8 is held by the intermediate plate 19. Parts 8 and 1
The next molding cavity mold 12 can be separated.
Then, the primary molding resin portion 8 is moved between the secondary molding cavity mold 15 and the secondary molding core mold 14 while holding the primary molding resin portion 8 with the primary molding holes 17 or the holding pins 32 of the intermediate plate 19 ( (Fig. 3). In the case where the transfer sheet for primary molding is used as the painting sheet 6 for primary molding, the base sheet of the transfer sheet for primary molding is opened together with the opening of the cavity mold 12 for primary molding and the core mold 11 for primary molding. Peel off 2
While the primary molding resin portion 8 to which the primary molding transfer layer is adhered is held by the primary molding holes 17 or the holding pins 32 of the intermediate plate 19, the secondary molding cavity mold 15 and the secondary molding core mold 14 are provided. May be moved to between. The transfer sheet for primary molding may be moved by the intermediate plate 19 without peeling the base sheet 2. The primary molding resin portion 8 is formed by the intermediate plate 19 with the secondary molding cavity molds 15 and
While being moved to the position between the next molding core mold 14 and 2
The secondary molding painting sheet 7 may be arranged between the secondary molding cavity mold and the intermediate plate 19. A transfer sheet for secondary molding may be used as the painting sheet 7 for secondary molding. The movement of the intermediate plate 19 may be achieved by rotating the intermediate plate with a drive source and a shaft, or by sliding a slide plate. To stop the rotation of the intermediate plate at a predetermined position, it may be mechanically performed by friction or the like,
It may be performed electrically by electromagnetic force or the like. Before or after the movement of the intermediate plate, or at the same time, a painting sheet for secondary molding may be arranged between the cavity mold for secondary molding and the intermediate plate. A transfer sheet for secondary molding may be used as a painting sheet for secondary molding. The primary molding tree is moved while the painting sheet for primary molding placed between the cavity mold for primary molding and the intermediate plate is adhered to the primary molding resin portion, and the secondary molding cavity mold is moved to the intermediate position. You may arrange | position the painting sheet for primary shaping | molding with a primary shaping | molding tree part between plates. In this case, as the painting sheet 1, a sheet in which the adhesive layer 4 is composed of a primary adhesive portion that adheres to the primary molding resin 8 and a secondary adhesive portion that adheres only to the secondary molding resin 9 is used. Can be. The arrangement method is as follows: the painting sheet feeding device 2 located above the secondary mold cavity mold
9, a secondary molding painting sheet for a certain length is sent out before the secondary molding cavity mold, and is wound by the painting sheet winding device 30 located at the lower part of the secondary molding cavity mold. A method of cutting the painting sheet 7 for secondary molding at the upper part of the cavity mold 15 for secondary molding,
The same applies to the case where the painting sheet for primary molding is arranged in the cavity mold for primary molding.

【0021】次に、1次成形樹脂部8が保持された中間
プレートを間に挟んで1次成形用キャビティ型12と2
次成形用コア型14とを型締めする。1次成形樹脂部保
持手段として、中間プレート19の2次成形用孔18を
用いる場合は、2次成形用キャビティ型15の表面と、
中間プレート19の2次成形用孔18の内面と、2次成
形用コア型14の表面とからなる2次成形空間が形成さ
れる。1次成形樹脂部保持手段として、中間プレート1
9上の保持ピン32を用いる場合は、中間プレート19
の2次成形用孔18を用いない場合は、2次成形用キャ
ビティ型15の表面と2次成形用コア型14の表面とか
らなる2次成形空間を形成することができる。2次成形
空間に2次成形樹脂23を射出して2次成形し2次成形
樹脂部9を得る。型締めは、駆動源25と軸27とによ
って可動盤24を前方に押出すとよい。型閉めによっ
て、1次成形樹脂部8を保持する中間プレート19と2
次成形用キャビティ型15とで2次成形用絵付けシート
7を挟み込む(図4)。2次成形用キャビティ型15と
中間プレート19との接触を先にして、中間プレート1
9と2次成形用コア型14との接触を後にする場合は、
中間プレート19の軸を可動型側に引き込むとよい。2
次成形樹脂23の射出によって、2次成形樹脂部9と2
次成形用絵付けシート7の接着層4とが接着する(図
4)。また、2次成形樹脂23の射出によって、1次成
形樹脂部8と2次成形樹脂部9とが接着し1体化する。
2次成形用絵付けシート7として2次成形用転写シート
を用いる場合は、2次成形用転写シートの接着層と2次
成形樹脂部9とが接着する。1次成形用転写シートの接
着層4を、1次成形樹脂部8より大きめに形成していた
場合は、絵付けシート1として、接着層4が、1次成形
樹脂8に接着する1次接着部と、2次成形樹脂9にのみ
接着する2次接着部とからなるものを使用し、1次成形
用絵付けシート6の接着層4の2次接着部が、2次成形
樹脂部9に接着するようにしてもよい。接着とは、溶融
状態の2次成形樹脂23が2次成形用絵付けシート7の
接着層4に接触した状態で冷却固化して、2次成形樹脂
部9が成形されるとともに1次成形樹脂部8と接着層4
とがひっついて一体となることをいう。2次成形用転写
シートを用いる場合は、転写シートの接着層と2次成形
樹脂部10とを接着させた後、2次成形用転写シートの
基体シート2を剥離する。2次成形において、1次成形
用転写シートの接着層と2次成形樹脂部9とが接着した
場合は、1次成形用転写シートの基体シート2を剥離し
てもよい。2次成形樹脂23の射出は、射出ユニット2
1の射出機構によって2次成形樹脂射出ノズル、2次成
形樹脂射出路13に成形樹脂を流して行なう。
Next, the primary molding cavity molds 12 and 2 are sandwiched by an intermediate plate holding the primary molding resin portion 8 therebetween.
Next, the mold core 14 is clamped. When the secondary molding hole 18 of the intermediate plate 19 is used as the primary molding resin portion holding means, the surface of the secondary molding cavity mold 15 is
A secondary molding space including the inner surface of the secondary molding hole 18 of the intermediate plate 19 and the surface of the secondary molding core mold 14 is formed. The intermediate plate 1 is used as a primary molded resin portion holding means.
When using the holding pin 32 on the intermediate plate 19, the intermediate plate 19
When the secondary molding hole 18 is not used, a secondary molding space including the surface of the secondary molding cavity mold 15 and the surface of the secondary molding core mold 14 can be formed. The secondary molding resin 23 is injected into the secondary molding space to perform secondary molding to obtain the secondary molding resin portion 9. The mold clamping may be performed by pushing the movable platen 24 forward by the drive source 25 and the shaft 27. Intermediate plates 19 and 2 holding the primary molded resin part 8 by closing the mold
The secondary molding painting sheet 7 is sandwiched between the secondary molding cavity mold 15 (FIG. 4). The contact between the cavity mold 15 for secondary molding and the intermediate plate 19 is performed first,
When the contact between 9 and the secondary molding core mold 14 is to be performed later,
The shaft of the intermediate plate 19 may be pulled into the movable mold. 2
By injection of the secondary molding resin 23, the secondary molding resin parts 9 and 2
The adhesive layer 4 of the next forming painting sheet 7 adheres (FIG. 4). In addition, the injection of the secondary molding resin 23 causes the primary molding resin portion 8 and the secondary molding resin portion 9 to adhere to each other to be integrated.
When a transfer sheet for secondary molding is used as the painting sheet 7 for secondary molding, the adhesive layer of the transfer sheet for secondary molding and the secondary molding resin portion 9 are adhered to each other. When the adhesive layer 4 of the transfer sheet for the primary molding is formed to be larger than the primary molding resin portion 8, the primary bonding in which the adhesive layer 4 adheres to the primary molding resin 8 as the painting sheet 1. And a secondary bonding portion that is bonded only to the secondary molding resin 9, and the secondary bonding portion of the adhesive layer 4 of the painting sheet for primary molding 6 is attached to the secondary molding resin portion 9. You may make it adhere. The bonding means that the secondary molding resin 23 in a molten state is cooled and solidified in a state where it is in contact with the adhesive layer 4 of the secondary molding painting sheet 7 to form the secondary molding resin portion 9 and the primary molding resin. Part 8 and adhesive layer 4
And stick together. When a transfer sheet for secondary molding is used, the base sheet 2 of the transfer sheet for secondary molding is peeled off after the adhesive layer of the transfer sheet and the secondary resin part 10 are bonded. In the secondary molding, when the adhesive layer of the primary molding transfer sheet and the secondary molding resin portion 9 adhere to each other, the base sheet 2 of the primary molding transfer sheet may be peeled off. The injection of the secondary molding resin 23 is performed by the injection unit 2
This is performed by flowing the molding resin into the secondary molding resin injection nozzle 13 and the secondary molding resin injection path 13 by the injection mechanism 1.

【0022】次に、2次成形用キャビティ型15と2次
成形用コア型14とを型開きして、2色成形同時絵付け
品を取り出す。この発明の製造方法によって得られる2
色成形同時絵付け品としては、1次成形樹脂部8に1次
成形用絵付けシート6(インサートシート)あるいは1
次成形用転写層が接着し、2次成形樹脂部9に2次成形
用絵付けシート7(インサートシート)あるいは2次成
形用転写層が接着したものがある。または、1次成形樹
脂部8に1次成形用絵付けシート6(インサートシー
ト)あるいは1次成形用転写層が接着し、2次成形樹脂
部9には絵付けシートも転写層も接着しないものがあ
る。または、1次成形樹脂部8に1次成形用絵付けシー
ト6(インサートシート)あるいは1次成形用転写層が
接着せず、2次成形樹脂部9にのみ2次成形用絵付けシ
ート7あるいは2次成形用転写層が接着したものがあ
る。または、1次成形樹脂部8に1次成形用絵付けシー
ト6(インサートシート)あるいは1次成形用転写層が
接着し、2次成形樹脂部9には1次成形用絵付けシート
6(インサートシート)あるいは1次成形用転写層の一
部のみが接着したものがある。または、1次成形樹脂部
8に1次成形用絵付けシート6(インサートシート)あ
るいは1次成形用転写層が接着し、2次成形樹脂部9に
1次成形用絵付けシート6(インサートシート)の一部
あるいは1次成形用転写層の一部が接着し、さらに2次
成形樹脂部9には2次成形用絵付けシート7(インサー
トシート)または2次成形用転写層が接着したものがあ
る。または、1次成形樹脂部8に1次成形用絵付けシー
ト6(インサートシート)が接着し、2次成形樹脂部9
には2次成形用転写層が接着したものがある。また、1
次成形樹脂部8と2次成形樹脂部9とが接合しないもの
がある。
Next, the secondary molding cavity mold 15 and the secondary molding core mold 14 are opened to take out the two-color molded simultaneous painting product. 2 obtained by the manufacturing method of the present invention
As the color molding simultaneous painting product, a primary molding painting sheet 6 (insert sheet) or 1
The secondary molding transfer layer is adhered, and the secondary molding resin portion 9 is adhered to the secondary molding painting sheet 7 (insert sheet) or the secondary molding transfer layer. Or, a primary molding painting sheet 6 (insert sheet) or a primary molding transfer layer adheres to the primary molding resin portion 8, and neither the painting sheet nor the transfer layer adheres to the secondary molding resin portion 9. There is. Alternatively, the primary molding painting sheet 6 (insert sheet) or the primary molding transfer layer does not adhere to the primary molding resin portion 8, and the secondary molding painting sheet 7 or There is one in which a transfer layer for secondary molding is adhered. Alternatively, the primary molding painting sheet 6 (insert sheet) or the primary molding transfer layer is adhered to the primary molding resin portion 8, and the primary molding painting sheet 6 (insert Sheet) or one in which only a part of the transfer layer for primary molding is adhered. Alternatively, the primary molding painting sheet 6 (insert sheet) or the primary molding transfer layer is adhered to the primary molding resin portion 8, and the primary molding painting sheet 6 (insert sheet) is attached to the secondary molding resin portion 9. ) Or a part of the transfer layer for primary molding is adhered, and the resin sheet 9 for secondary molding is attached with a painting sheet 7 for secondary molding (insert sheet) or a transfer layer for secondary molding. There is. Alternatively, the primary molding painting sheet 6 (insert sheet) is adhered to the primary molding resin portion 8 and the secondary molding resin portion 9
In some cases, a transfer layer for secondary molding is adhered. Also, 1
In some cases, the secondary molding resin portion 8 and the secondary molding resin portion 9 do not join.

【0023】[0023]

【発明の効果】この発明の2色成形同時絵付け品製造装
置と2色成形同時絵付け品の製造方法は、意匠表現の優
れた、異材質の成形品を効率良く得ることができる。
According to the apparatus for manufacturing a simultaneously painted two-color article and the method for producing a simultaneously painted two-color article according to the present invention, it is possible to efficiently obtain a molded article of a different material excellent in design expression.

【0024】この発明の2色成形同時絵付け品の製造方
法は、たとえば、ABS樹脂のオーディオパネル内に熱
可塑性エラストマー樹脂でできたボタンを有し、かつい
ずれの樹脂にも多色で美麗な意匠が施されたものを得る
ことができる。また、1次成形樹脂部と2次成形樹脂部
とを連続的に得るため、次のような効果がある。 1.1次成形樹脂部が収縮歪みを起こす前に2次成形を
行なえるので、金型にインサートしやすい。 2.1次成形樹脂部が冷える前に、2次成形樹脂部を成
形するため、1次成形樹脂部と2次成形樹脂部とのの密
着が良好である。 3.絵付けは1次成形樹脂部と2次成形樹脂部との両方
にでき、絵柄の位置合わせも正確である。 4.工程が分れていないので低コストである。
According to the method of manufacturing a two-color molded simultaneous painting product of the present invention, for example, a button made of a thermoplastic elastomer resin is provided in an audio panel made of ABS resin, and both of the resins are multicolored and beautiful. A design can be obtained. Further, since the primary molded resin part and the secondary molded resin part are continuously obtained, the following effects are obtained. 1. Since the secondary molding can be performed before the primary molding resin portion undergoes shrinkage distortion, it can be easily inserted into a mold. 2. Since the secondary molded resin part is molded before the primary molded resin part cools, the adhesion between the primary molded resin part and the secondary molded resin part is good. 3. Painting can be performed on both the primary molding resin part and the secondary molding resin part, and the positioning of the pattern is accurate. 4. The cost is low because the processes are not separated.

【0025】この発明の2色成形同時絵付け品の製造方
法は、中間プレートを移動させるものであるため、1次
成形樹脂部を2次成形部へ移動させるのに金型自体を移
動させなくてもよい。また、絵付けシート送り出し装置
や絵付けシート巻き取り装置などの大きな重量の装置が
設置されたキャビティ型を回転動作やスライドをさせる
必要がない。したがって、生産コストが低く生産性が優
れる。また、駆動力の大きな高価な駆動ユニットを必要
とせず、駆動ユニットとキャビティ型側の装置の構造が
複雑にならず低コストとなり、生産コストが低く生産性
が優れる。
In the method of manufacturing a two-color molded simultaneous painting product of the present invention, the intermediate plate is moved, so that the mold itself is not moved to move the primary molding resin portion to the secondary molding portion. You may. Further, there is no need to rotate or slide a cavity mold in which a heavy-weight device such as a painting sheet feeding device and a painting sheet winding device is installed. Therefore, the production cost is low and the productivity is excellent. Further, an expensive driving unit having a large driving force is not required, and the structures of the driving unit and the device on the cavity mold side are not complicated and the cost is low, and the production cost is low and the productivity is excellent.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 この発明の2色成形同時絵付け品製造装置と
2色成形同時絵付け品製造方法の一工程を示す断面図で
ある。
FIG. 1 is a cross-sectional view showing one process of a two-color simultaneous painting product manufacturing method and a two-color simultaneous simultaneous painting product manufacturing method of the present invention.

【図2】 この発明の2色成形同時絵付け品製造装置と
2色成形同時絵付け品製造方法の一工程を示す断面図で
ある。
FIG. 2 is a cross-sectional view showing one step of the two-color simultaneous simultaneous painting product manufacturing apparatus and the two-color simultaneous simultaneous painting product manufacturing method of the present invention.

【図3】 この発明の2色成形同時絵付け品製造装置と
2色成形同時絵付け品製造方法の一工程を示す断面図で
ある。
FIG. 3 is a cross-sectional view showing one process of the two-color simultaneous simultaneous painting production apparatus and the two-color simultaneous simultaneous painting production method of the present invention.

【図4】 この発明の2色成形同時絵付け品製造装置と
2色成形同時絵付け品製造方法の一工程を示す断面図で
ある。
FIG. 4 is a cross-sectional view showing one process of the two-color molded simultaneous painting product manufacturing apparatus and the two-color molded simultaneous painting product manufacturing method of the present invention.

【図5】 この発明の2色成形同時絵付け品製造方法に
よって製造された2色成形同時絵付け品の一例を示す断
面図である。
FIG. 5 is a cross-sectional view showing an example of a two-color molded simultaneous painting product manufactured by the two-color molded simultaneous painting product manufacturing method of the present invention.

【図6】 この発明の2色成形同時絵付け品製造方法に
用いる絵付けシートの一例を示す断面図である。
FIG. 6 is a cross-sectional view showing an example of a painting sheet used in the two-color molding simultaneous painting product manufacturing method of the present invention.

【図7】 この発明の2色成形同時絵付け品製造方法に
用いる絵付けシートの一例を示す断面図である。
FIG. 7 is a cross-sectional view showing an example of a painting sheet used in the two-color molding simultaneous painting product manufacturing method of the present invention.

【図8】 この発明の2色成形同時絵付け品製造装置の
一例を示す断面図である。
FIG. 8 is a cross-sectional view showing an example of the two-color molding simultaneous painting product manufacturing apparatus of the present invention.

【符号の説明】[Explanation of symbols]

1 絵付けシート 2 基体シート 3 絵柄層 4 接着層 5 剥離層 6 1次成形用絵付けシート 7 2次成形用絵付けシート 8 1次成形樹脂部 9 2次成形樹脂部 10 1次成形樹脂射出路 11 1次成形用コア型 12 1次成形用キャビティ型 13 2次成形樹脂射出路 14 2次成形用コア型 15 2次成形用キャビティ型 16 絵付けシート供給手段 17 1次成形用孔 18 2次成形用孔 19 中間プレート 20 固定盤 21 射出ユニット 22 1次成形樹脂 23 2次成形樹脂 24 可動盤 25 駆動源 26 タイバー 27 軸 28 ノズル孔 29 絵付けシート送り出し装置 30 絵付けシート巻き取り装置 31 支持ロッド 32 保持ピン DESCRIPTION OF SYMBOLS 1 Painting sheet 2 Base sheet 3 Picture layer 4 Adhesive layer 5 Release layer 6 Primary molding painting sheet 7 Secondary molding painting sheet 8 Primary molding resin part 9 Secondary molding resin part 10 Primary molding resin injection Road 11 Primary molding core mold 12 Primary molding cavity mold 13 Secondary molding resin injection path 14 Secondary molding core mold 15 Secondary molding cavity mold 16 Painting sheet supply means 17 Primary molding hole 18 2 Next molding hole 19 Intermediate plate 20 Fixed plate 21 Injection unit 22 Primary molding resin 23 Secondary molding resin 24 Movable plate 25 Drive source 26 Tie bar 27 Shaft 28 Nozzle hole 29 Painting sheet feeding device 30 Painting sheet winding device 31 Support rod 32 Holding pin

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 1次成形樹脂射出路を有する1次成形用
コア型と1次成形用キャビティ型とからなる1次成形手
段と、2次成形樹脂射出路を有する2次成形用コア型と
2次成形用キャビティ型とからなる2次成形手段と、絵
付けシート供給手段とを有する2色成形同時絵付け品製
造装置において、1次成形樹脂部保持手段を有する中間
プレートが、1次成形用コア型と1次成形用キャビティ
型との間の位置と、2次成形用コア型と2次成形用キャ
ビティ型との間の位置との間を移動可能に設けられ、絵
付けシート供給手段が、1次成形手段と2次成形手段の
少なくともいずれか一方のキャビティ型と中間プレート
との間に絵付けシートを供給可能であることを特徴とす
る2色成形同時絵付け品製造装置。
1. A primary molding means comprising a primary molding core mold having a primary molding resin injection path and a primary molding cavity mold, and a secondary molding core mold having a secondary molding resin injection path. In a two-color molding simultaneous painting product manufacturing apparatus having a secondary molding means comprising a secondary molding cavity mold and a painting sheet supply means, an intermediate plate having a primary molding resin part holding means is provided with a primary molding. A painting sheet supply means movably provided between a position between the core mold for molding and the cavity mold for primary molding and a position between the core mold for secondary molding and the cavity mold for secondary molding. Wherein a painting sheet can be supplied between the intermediate plate and the cavity mold of at least one of the primary molding means and the secondary molding means.
【請求項2】 請求項1記載の2色成形同時絵付け品製
造装置と絵付けシートとを用意し、まず、中間プレート
を間に挟んで1次成形用キャビティ型と1次成形用コア
型とを型締めした後、1次成形して1次成形樹脂部保持
手段に保持された1次成形樹脂部を得、次に、前記保持
したままの中間プレートを2次成形用キャビティ型と2
次成形用コア型との間の位置まで移動させ、1次成形樹
脂部が保持された中間プレートを間に挟んで2次成形用
キャビティ型と2次成形用コア型とを型締めした後、2
次成形して2次成形樹脂部を得ることによって、1次成
形樹脂部と2次成形樹脂部とが1体化し、かつ、1次成
形樹脂部と2次成形樹脂部との少なくともいずれか一方
に絵付けシートが接着した2色成形絵付け品を得る製造
方法であって、1次成形用キャビティ型と中間プレート
との間、あるいは、2次成形用キャビティ型と中間プレ
ートとの間のいずれか少なくとも一方において、型締め
前に絵付けシートを配置することを特徴する2色成形同
時絵付け品製造方法。
2. A two-color molding simultaneous painting product manufacturing apparatus according to claim 1 and a painting sheet are prepared, and first, a primary molding cavity mold and a primary molding core mold with an intermediate plate interposed therebetween. After the mold has been clamped, primary molding is performed to obtain a primary molded resin portion held by the primary molded resin portion holding means.
After being moved to a position between the secondary molding core mold and the intermediate molding plate holding the primary molding resin part, the secondary molding cavity mold and the secondary molding core mold are clamped. 2
The primary molding resin part and the secondary molding resin part are integrated by obtaining the secondary molding resin part by performing the secondary molding, and at least one of the primary molding resin part and the secondary molding resin part is formed. A method for producing a two-color molded article having a painting sheet adhered thereto, wherein the two-color molded article is provided between a primary molding cavity mold and an intermediate plate or between a secondary molding cavity mold and an intermediate plate. And / or at least one of the above two methods, wherein a painting sheet is arranged before clamping.
【請求項3】 1次成形用キャビティ型と中間プレート
との間に配置した絵付けシートの接着層の一部が、2次
成形において2次成形樹脂部に接着する請求項2記載の
2色成形同時絵付け品製造方法。
3. The two colors according to claim 2, wherein a part of the adhesive layer of the painting sheet disposed between the primary molding cavity mold and the intermediate plate adheres to the secondary molding resin part in the secondary molding. Simultaneous molding product manufacturing method.
【請求項4】 基体シート上に少なくとも絵柄層と接着
層が積層され基体シートが剥離可能な絵付けシートを用
い、1次成形後あるいは2次成形後のいずれか少なくと
も一方において、基体シートを剥離する請求項2または
3記載の2色成形同時絵付け品製造方法。
4. A painting sheet in which at least a picture layer and an adhesive layer are laminated on a base sheet and the base sheet is peelable, and the base sheet is peeled off at least one of after primary molding and secondary molding. The method for producing a two-color molded simultaneous painted product according to claim 2 or 3.
JP21916996A 1996-07-31 1996-07-31 2 color molding simultaneous painting product manufacturing apparatus and 2 color molding simultaneous painting product manufacturing method Expired - Fee Related JP3833310B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21916996A JP3833310B2 (en) 1996-07-31 1996-07-31 2 color molding simultaneous painting product manufacturing apparatus and 2 color molding simultaneous painting product manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21916996A JP3833310B2 (en) 1996-07-31 1996-07-31 2 color molding simultaneous painting product manufacturing apparatus and 2 color molding simultaneous painting product manufacturing method

Publications (2)

Publication Number Publication Date
JPH1044189A true JPH1044189A (en) 1998-02-17
JP3833310B2 JP3833310B2 (en) 2006-10-11

Family

ID=16731289

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP3833310B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102223992A (en) * 2008-11-28 2011-10-19 日本写真印刷株式会社 Mold device for two-color molding and two-color molded article
CN107825651A (en) * 2017-12-14 2018-03-23 显亮(昆山)汽车配件有限公司 The former of staight shank anti-theft key

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102223992A (en) * 2008-11-28 2011-10-19 日本写真印刷株式会社 Mold device for two-color molding and two-color molded article
CN107825651A (en) * 2017-12-14 2018-03-23 显亮(昆山)汽车配件有限公司 The former of staight shank anti-theft key

Also Published As

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