JPH10153399A - Paper for total heat exchanger and its manufacture - Google Patents

Paper for total heat exchanger and its manufacture

Info

Publication number
JPH10153399A
JPH10153399A JP8326095A JP32609596A JPH10153399A JP H10153399 A JPH10153399 A JP H10153399A JP 8326095 A JP8326095 A JP 8326095A JP 32609596 A JP32609596 A JP 32609596A JP H10153399 A JPH10153399 A JP H10153399A
Authority
JP
Japan
Prior art keywords
total heat
heat exchanger
paper
coating
base paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8326095A
Other languages
Japanese (ja)
Inventor
Osamu Nakano
修 中野
Yoshiaki Tomotake
義明 友竹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokushu Paper Manufacturing Co Ltd
Original Assignee
Tokushu Paper Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokushu Paper Manufacturing Co Ltd filed Critical Tokushu Paper Manufacturing Co Ltd
Priority to JP8326095A priority Critical patent/JPH10153399A/en
Publication of JPH10153399A publication Critical patent/JPH10153399A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide paper for a total heat exchanger excellent in latent heat exchange efficiency, of which the total heat exchanger can be manufactured simply only by hot pressing in a corrugating process without deteriorating the total heat exchange efficiency in a total heat exchange structure of a total heat exchanger and its manufacturing method by eliminating a post-treatment process of a heat exchange agent to eliminate a disadvantage such as deformation of the total heat exchange structure after the process. SOLUTION: There is provided a moisture absorbing/desorbing coated layer taking moisture absorption/desorption powder and a binder as main materials on one surface or on opposite surfaces of a base paper containing 10 to 50wt.% of the moisture absorption/desorption power to 20 to 80wt.% of an inorganic component. Further, a bonding agent layer having a thermal bonding property is partly provided on any of the surfaces in the ratio of an area ratio of 20 to 80% and the amount of coating of 5 to 25g/m<2> to ensure moisture absorption/ desorption property and a thermal bonding property.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、無機質粉体が20
〜80重量%のうち吸放湿性粉体を10〜50重量%含
む基紙の片面若しくは両面に、必要に応じて吸放湿性塗
工層を設け、更に、いずれか一方の面に熱接着剤層を面
積比率で20〜80%、塗工量5〜25g/m2の割合
で部分的に設けた全熱交換体用紙に関するものであり、
熱交換効率が高く、紙製全熱交換体を簡便に製造出来る
ものとして利用される。
[0001] The present invention relates to an inorganic powder containing 20 inorganic powders.
A moisture-absorbing / desorbing coating layer is provided on one or both sides of a base paper containing 10 to 50% by weight of a moisture-absorbing / desorbing powder out of 80 to 80% by weight. The present invention relates to a total heat exchanger paper in which layers are partially provided at an area ratio of 20 to 80% and a coating amount of 5 to 25 g / m 2 ,
It has high heat exchange efficiency, and is used as a paper heat exchanger that can be easily manufactured.

【0002】[0002]

【従来の技術】現在ほとんどの建物、住居では、夏期に
は冷房、冬期には暖房といった冷暖房機が備わってお
り、季節に関係なく快適な環境を作れるようになってい
る。その様な冷暖房機を運転して常に快適な環境を作る
為には冷暖房機内に備えられている全熱交換体が非常に
大きな役目を果たしている。すなわち、全熱交換体の全
熱交換性能がよいことが一定の快適な環境を低エネルギ
ーで長時間作れることにつながるのである。
2. Description of the Related Art Most buildings and houses are equipped with air conditioners such as air conditioners in the summer and heating in the winter, so that a comfortable environment can be created regardless of the season. In order to operate such an air conditioner and always create a comfortable environment, the total heat exchanger provided in the air conditioner plays an extremely important role. That is, the good total heat exchange performance of the total heat exchanger leads to a constant and comfortable environment with low energy for a long time.

【0003】全熱交換器が開発される以前は、密閉され
た室内で冷暖房機の運転をすると室内の空気は徐々に汚
れた空気となるため、その汚れた空気を置換といわれる
方式により換気を行っていた。すなわち、室内の汚れた
空気と新鮮な外気を入れ替えるために、一定時間冷暖房
機を運転したときは、窓や扉などを換気するために十分
な時間開放し換気を行っていた。
[0003] Prior to the development of the total heat exchanger, when the air conditioner is operated in a closed room, the air in the room becomes gradually dirty air, and the dirty air is replaced by a method called replacement. I was going. That is, when the air conditioner is operated for a certain period of time in order to exchange dirty air in the room with fresh outside air, the air is opened and ventilated for a sufficient time to ventilate windows and doors.

【0004】しかし、このような換気による方法は確か
に新鮮な空気を取り込み、換気を行うという目的は達成
できるが、一時的に室内に比べ高温あるいは低温の外気
が導入されるために、設定温湿度に調整する為の余分な
エネルギーが必要であった。
[0004] However, such a ventilation method can certainly achieve the purpose of taking in fresh air and performing ventilation, but because a higher or lower temperature of outside air is temporarily introduced than in a room, the set temperature is not increased. Extra energy was needed to adjust to humidity.

【0005】この余分なエネルギーの消費を解消するた
めに開発されたのが全熱交換器といわれるもので、冷房
運転時には、多湿及び高温の外気と排出される室内の冷
たい空気間で湿分及び熱の交換を行い、冷やされた外気
を取り入れようとするものである。暖房運転時では、外
より取り入れる冷たい空気は排出される室内の暖かい空
気との間で湿分及び熱が交換され、暖かい空気が室内に
取り込まれる様になっている。すなわち、全熱交換器
は、排出される空気と取り込まれる空気の間で温度の交
換(顕熱交換)並びに湿分の交換(潜熱交換)を同時に
行う機能を有している。
[0005] A total heat exchanger has been developed to eliminate this extra energy consumption. During cooling operation, the humidity and moisture between the humid and high temperature outside air and the discharged cold air in the room are reduced. It is intended to exchange heat and take in the cooled outside air. During the heating operation, the cool air taken in from the outside exchanges moisture and heat with the warm air in the room to be discharged, so that the warm air is taken into the room. That is, the total heat exchanger has a function of simultaneously performing temperature exchange (sensible heat exchange) and moisture exchange (latent heat exchange) between the discharged air and the taken-in air.

【0006】従来の全熱交換体に供する材料として、大
別して2種類の材料が主として用いられてきた。即ち、
シリカエロジルを焼き付けしたアルミ箔等の金属材料を
用いて、ハニカムやコルゲート加工を施したものを積層
若しくはローター状に巻いたもの等を基本型として、今
日まで実用に供せられてきた。しかしながら、これらの
材料は不燃性には優れているが、材料自体の吸放湿性が
乏しいため、一定以上の潜熱交換効率を得ることが出来
なかった。
[0006] As the material to be used for the conventional total heat exchanger, roughly two types of materials have been mainly used. That is,
Honeycomb and corrugated metal materials such as aluminum foil baked with silica erosil have been used as a basic type in the form of a laminate or in a rotor shape. However, although these materials are excellent in noncombustibility, the materials themselves have poor moisture absorption and desorption properties, so that a certain or more latent heat exchange efficiency cannot be obtained.

【0007】一方、和紙等のセルロースを主体とした材
料を全熱交換体と使用する場合は、金属材料に比べて吸
放湿性を有しているため、ある程度の潜熱交換効率を向
上させることが可能となったが、更に潜熱交換効率を高
めるために、片段のコルゲート加工を施した後、ロール
状に巻いて成型した個々の熱交換器用ローターに、塩化
リチウム等の熱交換剤を3〜5重量%含浸処理を行って
付着させているのが現状である。
On the other hand, when a material mainly composed of cellulose, such as Japanese paper, is used as the total heat exchanger, it has a higher moisture absorbing and releasing property than the metal material. Although it became possible, in order to further increase the latent heat exchange efficiency, a single-stage corrugating process was performed, and then a heat exchanger such as lithium chloride was added to each of the heat exchanger rotors formed by winding into a roll and molding the rolls. At present, it is attached by performing a weight% impregnation treatment.

【0008】ところが、これらの含浸処理によって、成
型したローターの端部が強いアルカリ性と熱交換剤の潮
解性のために強度低下をきたし、且つ、形状が変化し易
いとの欠点を有していた。
However, these impregnation treatments have disadvantages in that the end of the molded rotor is reduced in strength due to strong alkalinity and deliquescent of the heat exchanger, and the shape is easily changed. .

【0009】特開昭58−51921号や本出願人が提
案した特許第1823632号には、紙の中に吸放湿特
性の優れた粉体を混抄若しくは塗布したシート状物で、
美術品や工芸品等を等を調湿して保存するための方法が
開示されているが、全熱交換体用の材料としての利用を
意図としたものではない。
Japanese Patent Application Laid-Open No. 58-51921 and Japanese Patent No. 1823632 proposed by the present applicant discloses a sheet-like material obtained by mixing or applying powder having excellent moisture absorption / release properties in paper.
Although a method for conditioning and preserving arts and crafts and the like is disclosed, it is not intended to be used as a material for a total heat exchanger.

【0010】更に、特開平5−115739号には、高
吸水性高分子化合物等の吸放湿特性を有する高分子化合
物の繊維や粉体を、天然または合成繊維材料と共にシー
ト状に成形したものや、セピオライト、ゼオライト、ベ
ントナイト、アタパルジャイト、珪藻土、活性炭などの
吸放湿特性を有する無機粉体を、木材パルプと共に紙、
シート、ボード状に成形した後、コルゲート加工を施し
た吸放湿性材料で製造した湿度交換器が提案されてい
る。しかしながら、耐熱性あるいは不燃性に劣るため耐
熱性を必要としない全熱交換器での使用に限られている
のが実状である。
Further, Japanese Patent Application Laid-Open No. H5-115739 discloses that a fiber or powder of a polymer compound having a moisture absorbing and releasing property such as a superabsorbent polymer compound is formed into a sheet together with a natural or synthetic fiber material. And inorganic powders having moisture absorption and desorption properties such as sepiolite, zeolite, bentonite, attapulgite, diatomaceous earth, activated carbon, etc., together with wood pulp, paper,
A humidity exchanger manufactured from a moisture-absorbing and desorbing material that has been formed into a sheet or board and then subjected to corrugation has been proposed. However, in reality, it is limited to use in a total heat exchanger that does not require heat resistance due to poor heat resistance or incombustibility.

【0011】[0011]

【発明が解決しようとする課題】本発明は全熱交換器の
紙製全熱交換体及びその製造において、熱交換剤の後処
理加工を除くことにより加工後の全熱交換体の変形など
の欠点を解消し、更に、全熱交換効率を低下させること
なく、単にコルゲート加工時の熱圧のみによって、簡便
に紙製全熱交換体を製造出来る潜熱交換効率に優れた難
燃性の全熱交換体用紙を提供しようとするものである。
SUMMARY OF THE INVENTION The present invention relates to a paper-made total heat exchanger for a total heat exchanger and a method for manufacturing the same, which eliminates post-processing of a heat exchanger to prevent deformation of the total heat exchanger after processing. Flame retardant total heat with excellent latent heat exchange efficiency that can easily produce a paper total heat exchanger simply by the heat pressure during corrugating without eliminating the disadvantages and without reducing the total heat exchange efficiency It is intended to provide exchange paper.

【0012】[0012]

【課題を解決するための手段】本発明者らは、鋭意研究
の結果これらの問題点を解決した新規な全熱交換体用紙
を開発した。
Means for Solving the Problems As a result of earnest studies, the present inventors have developed a novel total heat exchanger paper which has solved these problems.

【0013】その要旨とするところは、無機質粉体が2
0〜80重量%のうち吸放湿性粉体を10〜50重量%
含む基紙の片面若しくは両面に、必要に応じて吸放湿性
粉体とバインダーを主材とした吸放湿性塗工層を設け、
更にいずれかの一方の面に、熱接着性を有する接着剤層
を部分的に設け、吸放湿性並びに熱接着性を付与したこ
とを特徴とする全熱交換体用紙を得ることにある。
The main point is that the inorganic powder is 2
10 to 50% by weight of hygroscopic powder out of 0 to 80% by weight
On one or both sides of the base paper containing, if necessary, provided a moisture-absorbing and desorbing coating layer mainly composed of a moisture-absorbing and desorbing powder and a binder,
It is still another object of the present invention to obtain a total heat exchanger paper characterized in that an adhesive layer having thermal adhesiveness is partially provided on one of the surfaces to impart moisture absorption / release properties and thermal adhesiveness.

【0014】[0014]

【発明の実施の形態】本発明で使用する製紙用繊維とし
ては、針葉樹未晒クラフトパルプ(NUKP)、針葉樹
晒クラフトパルプ(NBKP)、広葉樹未晒クラフトパ
ルプ(LUKP)、広葉樹晒クラフトパルプ(LBK
P)、針葉樹晒サルファイトパルプ(NBSP)、サー
モメカニカルパルプ(TMP)等の木材パルプの単独若
しくは混合物を主体とし、これに麻、竹、ワラ、ケナフ
パルプ等の非木材パルプや、ポリオレフィン等の合成パ
ルプ、レーヨン、ビニロン、ナイロン、ポリエステル等
の合成繊維、ガラス繊維、炭素繊維等の無機繊維の単独
若しくは混合したものを必要に応じて併用する。
DETAILED DESCRIPTION OF THE INVENTION The papermaking fibers used in the present invention include softwood unbleached kraft pulp (NUKP), softwood bleached kraft pulp (NBKP), hardwood unbleached kraft pulp (LUKP), and hardwood bleached kraft pulp (LBK).
P), softwood bleached sulphite pulp (NBSP), thermomechanical pulp (TMP) or other wood pulp alone or as a mixture, to which non-wood pulp such as hemp, bamboo, straw, kenaf pulp, and synthesis of polyolefins If necessary, synthetic fibers such as pulp, rayon, vinylon, nylon and polyester, and inorganic fibers such as glass fibers and carbon fibers may be used alone or in combination.

【0015】基紙に難燃性を付与するために、基紙に難
燃処理を施す場合もある。難燃剤としては、スルファミ
ン酸グアニジン、リン酸グアニジン、スルファミン酸ア
ンモンニウム、リン酸アンモニウム等が使用可能である
が、特に制限するものではない。
In order to impart flame retardancy to the base paper, the base paper may be subjected to a flame retardant treatment. Examples of the flame retardant include, but are not particularly limited to, guanidine sulfamate, guanidine phosphate, ammonium ammonium sulfamate, and ammonium phosphate.

【0016】本発明の基紙に使用する無機質粉体とは、
クレー、カオリン、タルク、二酸化チタン、炭酸カルシ
ウム、水酸化アルミニウム等を単独あるいは混合して使
用されるが特に限定されるもではない。しかしながら、
難燃性を向上させるために、水酸化アルミニウムの如き
自己消火性粉体の使用が好ましい。その使用量は、前述
の吸放湿性粉体と合わせて紙重量の80重量%以下が望
ましい。80重量%以上にすると紙の強度が低下しコル
ゲート加工を施す際に紙が破れるなどの問題が起き、技
術的にも容易な抄紙条件を得ることが困難になる。
The inorganic powder used for the base paper of the present invention is:
Clay, kaolin, talc, titanium dioxide, calcium carbonate, aluminum hydroxide and the like are used alone or in combination, but are not particularly limited. However,
In order to improve the flame retardancy, it is preferable to use a self-extinguishing powder such as aluminum hydroxide. The use amount thereof is desirably 80% by weight or less based on the weight of the paper in combination with the above-mentioned hygroscopic powder. When the content is 80% by weight or more, the strength of the paper decreases, and a problem such as breakage of the paper during corrugating occurs, and it is difficult to obtain technically easy papermaking conditions.

【0017】本発明の基紙に使用する吸放湿性粉体と
は、シリカゲル、シリカアルミナゲル、アルミナゲル、
活性アルミナ、合成ゼオライト、天然ゼオライト、合成
シリカ、酸性白土、活性白土、α−セピオライト、β−
セピオライト、パリゴルスカイト(アタパルジャイ
ト)、アロフェン、イモゴナイト、ベントナイト、珪藻
土、活性炭等の吸放湿特性のある天然及び合成の粉体
を、単独あるいは数種類を組み合わせて使用することが
出来、その使用量は10〜50重量%で好ましくは15
〜45重量%である。10重量%未満であると吸放湿量
が少なくなり、50重量%以上だと吸放湿量は増加する
が潜熱交換効率が頭打ちとなる。
The hygroscopic powder used for the base paper of the present invention includes silica gel, silica alumina gel, alumina gel,
Activated alumina, synthetic zeolite, natural zeolite, synthetic silica, acid clay, activated clay, α-sepiolite, β-
Natural or synthetic powders having moisture absorption and desorption properties, such as sepiolite, palygorskite (atattalgite), allophane, imogonite, bentonite, diatomaceous earth, activated carbon, etc., can be used alone or in combination of several kinds. 50% by weight and preferably 15%
~ 45% by weight. If it is less than 10% by weight, the amount of moisture absorption / desorption decreases, and if it is more than 50% by weight, the amount of moisture absorption / desorption increases, but the latent heat exchange efficiency reaches a peak.

【0018】本発明に使用する基紙は、製紙用原料と無
機質粉体を主材として抄紙され、これに吸放湿性粉体を
混入し、更に各種無機質粉体、乾燥紙力増強剤、湿潤紙
力増強剤、サイズ剤、着色剤、定着剤等適宜添加し抄紙
して得られる。
The base paper used in the present invention is made from papermaking raw materials and inorganic powders as main materials, mixed with moisture-absorbing and desorbing powders, and further contains various inorganic powders, a dry paper strength enhancer, It is obtained by appropriately adding a paper strength enhancer, a sizing agent, a coloring agent, a fixing agent, and the like, followed by papermaking.

【0019】本発明の基紙は、粉落ち防止加工として必
要に応じて、吸放湿性を阻害しない範囲で公知のバイン
ダーを含浸あるいは塗工することができる。バインダー
としてはSBR、MBR等の合成ゴムラテックス、アク
リルエマルジョン、塩化ビニルエマルジョン、塩化ビニ
リデンエマルジョン、及びこれらの共重合エマルジョ
ン、カゼイン、澱粉、PVA等を適宜と組み合わせて使
用するが、発熱量が少なく難燃性のある塩化ビニルや塩
化ビニリデンエマルジョンあるいはこれらとの共重合体
を主体に使用することが好ましい。
The base paper of the present invention can be impregnated or coated with a known binder within a range that does not impair the moisture absorption / release properties, if necessary, as a powder fall prevention process. As the binder, a synthetic rubber latex such as SBR or MBR, an acrylic emulsion, a vinyl chloride emulsion, a vinylidene chloride emulsion, and a copolymer emulsion thereof, casein, starch, PVA, etc. are used in appropriate combination, but the calorific value is small and difficult. It is preferable to use mainly flammable vinyl chloride or vinylidene chloride emulsion or a copolymer thereof.

【0020】本発明は従来の技術で製造可能な基紙を使
用し、その片面若しくは両面に必要に応じて吸放湿性粉
体とバインダーを主材にした吸放湿性塗工層を設け、全
体として吸放湿性を付与する。吸放湿性粉体としては、
前述した全く同様なる粉体を単独あるいは数種類組み合
わせて使用できるが、塗料化が容易であるシリカゲルや
活性白土等を使用することが好ましい。
The present invention uses a base paper which can be produced by a conventional technique, and provides a moisture absorbing / releasing coating layer mainly comprising a moisture absorbing / releasing powder and a binder on one side or both sides as necessary. As moisture absorbing and releasing properties. As the moisture absorbing and releasing powder,
The powders which are completely the same as described above can be used alone or in combination of several kinds, but it is preferable to use silica gel, activated clay, or the like, which can be easily formed into a paint.

【0021】塗料に使用するバインダーとしては、前述
したものと同様にSBR、MBR等の合成ゴムラテック
ス、アクリルエマルジョン、塩化ビニルエマルジョン、
塩化ビニリデンエマルジョン、及びこれらの共重合エマ
ルジョン、カゼイン、澱粉、PVA等を適宜と組み合わ
せて使用するが、発熱量が少なく難燃性のある塩化ビニ
ルや塩化ビニリデンエマルジョンあるいはこれらとの共
重合体を主体に使用することが好ましい。
As the binder used in the paint, synthetic rubber latex such as SBR, MBR, acrylic emulsion, vinyl chloride emulsion,
A vinylidene chloride emulsion and a copolymerized emulsion of these, casein, starch, PVA, etc. are used in combination as appropriate, but mainly a vinyl chloride or vinylidene chloride emulsion having a low calorific value and a flame retardant, or a copolymer thereof. Is preferably used.

【0022】塗料に使用する吸放湿性粉体の単独若しく
は2種類以上に分散剤を添加し水分散した後、バインダ
ーを加え塗料を調製するが、この際、水酸化アルミニウ
ム等の無機質粉体に保水剤、流動性改良剤、防黴剤、防
腐剤、着色剤等を必要に応じて添加する。バインダーの
添加量は、粉体100重量部に対し、通常5〜30重量
%が望ましい。5重量%以下だと塗工層の接着剤として
の量が不足するため塗工層自体の必要強度が得られ難
く、30重量%以上だとバインダーが吸放湿性粉体の表
面を覆ってしまうため吸放湿性が低下するので好ましく
ない。
A dispersing agent is added to one or two or more of the moisture absorbing and releasing powders used in the coating and dispersed in water, and then a binder is added to prepare a coating. At this time, an inorganic powder such as aluminum hydroxide is used. Water retention agents, flow improvers, fungicides, preservatives, coloring agents and the like are added as necessary. Usually, the amount of the binder is preferably 5 to 30% by weight based on 100 parts by weight of the powder. If the amount is less than 5% by weight, the amount of the coating layer as an adhesive is insufficient, so that it is difficult to obtain the required strength of the coating layer itself. If the amount is more than 30% by weight, the binder covers the surface of the moisture-absorbing and releasing powder. Therefore, the moisture absorption / release properties are undesirably reduced.

【0023】この様に調製した塗料を、エアーナイフコ
ーター、ブレードコーター、ロールコーター等の塗工機
で基紙の片面若しくは両面に塗工する。塗工量は片面に
つき5〜30g/m2が望ましい。5g/m2未満では吸
放湿性が乏しくなり、30g/m2以上だと吸放湿性粉
体を混抄した基紙では吸放湿性の効果が頭打ちとなる。
The coating material thus prepared is applied to one or both sides of the base paper with a coating machine such as an air knife coater, blade coater, roll coater or the like. The coating amount is desirably 5 to 30 g / m 2 per side. If it is less than 5 g / m 2 , the moisture absorption / desorption properties are poor, and if it is 30 g / m 2 or more, the moisture absorption / desorption effect of the base paper mixed with the moisture absorption / desorption powder reaches a plateau.

【0024】本発明は基紙の片面若しくは両面に、必要
に応じて吸放湿性粉体の塗工層を設けた後、いずれか一
方の片面に、熱接着剤層を部分的に設け、コルゲート加
工時の熱圧や超音波接着時の熱圧によって熱接着が可能
な全熱交換体用紙を得る。
According to the present invention, a coating layer of a moisture-absorbing and releasing powder is provided on one or both sides of a base paper, if necessary, and then a thermal adhesive layer is partially provided on one side of the base paper. A total heat exchanger paper that can be thermally bonded by the heat pressure during processing or the heat pressure during ultrasonic bonding is obtained.

【0025】通常、熱接着性を示す接着剤としては、熱
可塑性を有する高分子化合物たとえばポリ酢酸ビニル、
ポリアクリル酸エステル類、ポリエチレン−ポリ酢酸ビ
ニル共重合体、熱可塑性エラストマー、アイオノマー、
変性アイオノマー、酢ビ系共重合ポリオレフィン、ポリ
エチレン、各種ワックス類等を主として使用する。
Usually, as the adhesive exhibiting thermal adhesiveness, a polymer compound having thermoplasticity such as polyvinyl acetate,
Polyacrylates, polyethylene-polyvinyl acetate copolymer, thermoplastic elastomer, ionomer,
Modified ionomer, vinyl acetate copolymerized polyolefin, polyethylene, various waxes, etc. are mainly used.

【0026】基紙への塗工は、水系塗料の塗工、溶剤系
塗料の塗工、ホットメルト塗工、エクストルージョン塗
工などのいずれの塗工方法や接着剤を採用しても一向に
差し支えない。
The coating on the base paper can be performed by any method such as water-based coating, solvent-based coating, hot-melt coating, and extrusion coating, or by using an adhesive. Absent.

【0027】しかしながら、本発明での熱接着剤層は、
部分的に設ける必要がある。その理由として、基紙の全
面に熱接着剤層を設けると、コルゲート加工を施し、全
熱交換体として使用した場合に、全熱交換体用紙一方の
表面が透湿性の悪い熱接着剤層で完全に覆われた状態に
なる結果、吸放湿性を阻害し、潜熱交換効率を低下させ
てしまうからである。
However, the thermal adhesive layer in the present invention is
Must be partially provided. The reason is that if a thermal adhesive layer is provided on the entire surface of the base paper, corrugating is applied and when used as a total heat exchanger, one surface of the total heat exchanger paper is a thermal adhesive layer with poor moisture permeability. This is because, as a result of being completely covered, the moisture absorption / release properties are impaired, and the latent heat exchange efficiency is reduced.

【0028】部分的に熱接着剤層を設けるには、前述の
塗工機でグラビアロールの如き彫刻ロールが使用できる
ものが良い。このグラビアロールに深度50〜400μ
mの網点状、菱形状、斜線状、直線状、曲線状等の彫刻
を、面積率で20〜80%施し、これらのロールを用い
て基紙の片面に、部分的に熱接着剤を5〜25g/m2
塗工する。これらの範囲に設定する理由として、グラビ
アロールの深度については50μm以下では浅すぎるた
めに接着剤の転移量が少ないため接着力不足となり、4
00μm以上では熱接着剤の基紙へのピックアップ率が
頭打ちになるためである。面積比率については、20%
以下であると接着面積が少ないめに接着力不足となり、
80%以上であると全熱交換効率が低下するため望まし
くない。塗工量については、5g/m2以下だと接着剤
不足のため熱圧着後の接着強度が弱くなり、30g/m
2以上だと接着強度が頭打ちとなりコストアップするた
め好ましくない。
In order to partially provide the thermal adhesive layer, it is preferable that an engraving roll such as a gravure roll can be used in the above-mentioned coating machine. This gravure roll has a depth of 50-400μ.
m, engraving such as halftone, rhombus, oblique, straight, curved, etc. at an area ratio of 20 to 80%, and using these rolls, partially apply heat adhesive to one side of the base paper 5 to 25 g / m 2
Apply. The reason for setting these ranges is that the depth of the gravure roll is less than 50 μm, which is too shallow, so that the transfer amount of the adhesive is small and the adhesive strength becomes insufficient.
If the thickness is more than 00 μm, the pickup rate of the thermal adhesive to the base paper will level off. About area ratio, 20%
If it is below, the adhesive strength will be insufficient because the adhesive area is small,
If it is 80% or more, the total heat exchange efficiency is undesirably reduced. If the coating amount is 5 g / m 2 or less, the adhesive strength after thermocompression bonding becomes weak due to insufficient adhesive, and the coating amount is 30 g / m 2.
If it is 2 or more, the adhesive strength reaches a peak and the cost increases, which is not preferable.

【0029】[0029]

【実施例】実施例1 針葉樹晒クラフトパルプ(NBKP)20重量部を45
0mlC.S.F.に叩解して得られたパルプスラリー
に、水酸化アルミニウム粉体30重量部(「B−70
3」、日本軽金属(株)製)とシリカゲル粉体50重量
部(「シリカゲルPA−200」、富士シリシア化学
(株)製)を混入し、10%濃度のスラリーを調整し
た。このスラリーの固形分重量に対して湿潤紙力増強剤
(「WS−570」、日本PCM(株)製)を1%、サ
イズ剤(「サイズパインK−902」、荒川化学(株)
製)を0.3%添加した後、アンモニア水でpHを8〜
9に調整した。更にこのスラリーに固形分重量に対して
高分子アニオン性凝集剤(「ハイホルダー351」、栗
田工業(株)製)を0.006%添加した後、常法によ
り長網抄紙機で坪量110g/m2の全熱交換体用紙を
得た。
EXAMPLE 1 20 parts by weight of softwood bleached kraft pulp (NBKP) was added to 45 parts by weight.
0 ml C.I. S. F. 30 parts by weight of aluminum hydroxide powder (“B-70”) was added to the pulp slurry obtained by beating
3) (manufactured by Nippon Light Metal Co., Ltd.) and 50 parts by weight of silica gel powder ("Silica Gel PA-200", manufactured by Fuji Silysia Chemical Ltd.) to prepare a 10% concentration slurry. 1% of a wet paper strength enhancer ("WS-570", manufactured by Nippon PCM Co., Ltd.) and a sizing agent ("Size Pine K-902", Arakawa Chemical Co., Ltd.) based on the solid content weight of the slurry.
Was added, and the pH was adjusted to 8 to 8 with aqueous ammonia.
Adjusted to 9. Further, 0.006% of a polymer anionic coagulant (“HYHOLDER 351”, manufactured by Kurita Kogyo Co., Ltd.) is added to this slurry based on the weight of the solid content, and the basis weight is 110 g using a fourdrinier paper machine in a conventional manner. / M 2 of total heat exchanger paper was obtained.

【0030】実施例2 熱接着性を有する接着剤(「スミカフレックスS−75
2」、住友化学工業(株)製)に、増粘剤としてアルギ
ン酸ソーダを添加し、粘度1500cps、濃度40%
の塗工液を調整した。次いで凹部の面積比率が50%、
深度100μmの彫刻を施したグラビアロールを供えた
塗工機を用いて、実施例1で得られた基紙の片面に、熱
接着性塗工液を固形分で10g/m2塗工し、坪量12
0g/m2の全熱交換体用紙を得た。
Example 2 An adhesive having a thermal adhesive property ("Sumikaflex S-75")
2 ", manufactured by Sumitomo Chemical Co., Ltd.), to which sodium alginate was added as a thickener, having a viscosity of 1500 cps and a concentration of 40%.
Was prepared. Next, the area ratio of the concave portion is 50%,
Using a coating machine provided with a gravure roll engraved to a depth of 100 μm, a heat-adhesive coating liquid was applied on one side of the base paper obtained in Example 1 at a solid content of 10 g / m 2 , Basis weight 12
A total heat exchanger paper of 0 g / m 2 was obtained.

【0031】実施例3 針葉樹晒クラフトパルプ(NBKP)26重量部と広葉
樹晒クラフトパルプ(LBKP)13重量部を混合し、
450mlC.S.F.に叩解して得られたパルプスラ
リーに、水酸化アルミニウム粉体30重量部(同上)と
シリカゲル粉体30重量部(同上)を混入し、10%濃
度のスラリーを調整した。その後は実施例1と全く同様
なる方法で、坪量80g/m2の基紙を得た。更に主成
分としてシリカゲル粉体100重量部(同上)に対し、
MBRラテックス15重量部(「ポリラツク750」、
三井東圧化学工業(株)製)を添加した濃度43%の塗
工液を調整後、エアーナイフコーターを用いて前記基紙
の片面に15g/m2の吸放湿性塗工層を設けた。次い
で実施例2と同様なる方法で、反対面に熱接着性塗工液
を固形分で10g/m2塗工し、坪量105g/m2の全
熱交換体用紙を得た。
Example 3 26 parts by weight of softwood bleached kraft pulp (NBKP) and 13 parts by weight of hardwood bleached kraft pulp (LBKP) were mixed.
450 ml C.I. S. F. 30 parts by weight of aluminum hydroxide powder (same as above) and 30 parts by weight of silica gel powder (same as above) were mixed into a pulp slurry obtained by beating to prepare a 10% concentration slurry. Thereafter, a base paper having a basis weight of 80 g / m 2 was obtained in the same manner as in Example 1. Furthermore, for 100 parts by weight of silica gel powder (as above) as the main component,
15 parts by weight of MBR latex (“Polylac 750”,
After preparing a coating solution having a concentration of 43% to which Mitsui Toatsu Chemical Industry Co., Ltd. was added, a 15 g / m 2 moisture absorbing / releasing coating layer was provided on one side of the base paper using an air knife coater. . Then in the same Naru manner as in Example 2, the heat-adhesive coating liquid was 10 g / m 2 coated with solids on the other side, to obtain a total heat exchanger sheet having a basis weight of 105 g / m 2.

【0032】実施例4 実施例3で得られた坪量80g/m2の基紙の両面に、
実施例3と同様なる方法で吸放湿性塗工層を各々15g
/m2設けた後、一方の面に実施例2と同じ方法で熱接
着性塗工液を固形分で10g/m2塗工し、坪量120
g/m2全熱交換体用紙を得た。
Example 4 On both sides of the base paper having a basis weight of 80 g / m 2 obtained in Example 3,
In the same manner as in Example 3, 15 g each of the moisture-absorbing / releasing coating layers
/ M 2 , a heat-adhesive coating solution was applied on one surface in the same manner as in Example 2 at a solid content of 10 g / m 2, and the basis weight was 120
g / m 2 total heat exchanger paper was obtained.

【0033】実施例5 実施例3と同様なる方法で、片面に吸放湿性塗工層を設
けた坪量95g/m2の基紙の反対面に、実施例2と同
様なる熱接着性塗工液と塗工機を使用し、凹部の面積比
率が50%、深度350μmの彫刻を施したグラビアロ
ールを用いて、熱接着性塗工液を固形分で25g/m2
塗工し、坪量120g/m2の全熱交換体用紙を得た。
Example 5 In the same manner as in Example 3, a heat-adhesive coating similar to that of Example 2 was applied to the other side of a base paper having a basis weight of 95 g / m 2 having a moisture absorbing / releasing coating layer on one side. Using a gravure roll engraved with an area ratio of concave portions of 50% and a depth of 350 μm using a coating liquid and a coating machine, the heat-adhesive coating liquid was solid at 25 g / m 2.
Coating was performed to obtain a total heat exchanger paper having a basis weight of 120 g / m 2 .

【0034】実施例6 実施例3と同様なる方法で、片面に吸放湿性塗工層を設
けた坪量95g/m2の基紙の反対面に、実施例2と同
様なる熱接着性塗工液と塗工機を使用し、凹部の面積比
率が40%、深度100μmの彫刻したグラビアロール
を用いて、熱接着性塗工液を固形分で5.6g/m2
工し、坪量100.6g/m2の全熱交換体用紙を得
た。
Example 6 In the same manner as in Example 3, a heat-adhesive coating similar to that of Example 2 was applied to the other side of a base paper having a basis weight of 95 g / m 2 having a moisture absorbing / releasing coating layer on one side. Using a coating liquid and a coating machine, using a gravure roll engraved with an area ratio of concave portions of 40% and a depth of 100 μm, applying a thermal adhesive coating liquid at a solid content of 5.6 g / m 2 , A total heat exchanger paper having an amount of 100.6 g / m 2 was obtained.

【0035】比較例1 実施例1で得られた坪量110g/m2の基紙と実施例
2と同組成で濃度が20%の熱接着性塗工液を用いて、
実施例6と同じグラビアロールで、片面に熱接着性塗工
液を固形分で2.8g/m2塗工し、坪量112.8g
/m2の全熱交換体用紙を得た。
Comparative Example 1 Using the base paper having a basis weight of 110 g / m 2 obtained in Example 1 and a heat-adhesive coating liquid having the same composition as in Example 2 and a concentration of 20%,
The same gravure roll as in Example 6 was used to apply 2.8 g / m 2 of a thermoadhesive coating liquid as a solid content on one side, and the basis weight was 112.8 g.
/ M 2 of total heat exchanger paper was obtained.

【0036】比較例2 針葉樹晒クラフトパルプ(NBKP)26重量部と広葉
樹晒クラフトパルプ(LBKP)13重量部を混合し、
450mlC.S.F.に叩解して得られたパルプスラ
リーに、水酸化アルミニウム粉体55重量部(同上)と
シリカゲル粉体5重量部(同上)を混入し、10%濃度
のスラリーを調製した。その後は実施例1と全く同様な
る方法で、坪量80g/m2の基紙を得た。更に実施例
3と同組成で濃度30%の塗工液を調製し、エアーナイ
フコーターを用いて、片面に吸放湿性塗工層を3g/m
2設け、その反対面に、凹部の面積比率が20%、深度
250μmの彫刻を施したグラビアロールを供えた塗工
機を用いて、実施例2と同様な熱接着性塗工液を固形分
で7g/m2塗工し、坪量90g/m2の全熱交換体用紙
を得た。
Comparative Example 2 Softwood bleached kraft pulp (NBKP) (26 parts by weight) and hardwood bleached kraft pulp (LBKP) (13 parts by weight) were mixed.
450 ml C.I. S. F. 55 parts by weight of aluminum hydroxide powder (same as above) and 5 parts by weight of silica gel powder (same as above) were mixed into a pulp slurry obtained by beating to prepare a 10% concentration slurry. Thereafter, a base paper having a basis weight of 80 g / m 2 was obtained in the same manner as in Example 1. Further, a coating solution having the same composition as in Example 3 and having a concentration of 30% was prepared, and a moisture-absorbing / desorbing coating layer was formed on one surface with an air knife coater at 3 g / m 2.
2 and using a coating machine provided with an engraved gravure roll having an area ratio of the concave portion of 20% and a depth of 250 μm on the opposite surface, using the same heat-adhesive coating liquid as in Example 2, in 7 g / m 2 was applied to obtain a total heat exchanger sheet having a basis weight of 90 g / m 2.

【0037】比較例3 比較例2と同様なる基紙と塗工液を用いて、エアーナイ
フコーターで両面に各々2g/m2の吸放湿塗工層を設
け、次いで凹部の面積比率が90%、深度300μmの
彫刻を施したグラビアロールを供えた塗工機を用いて、
実施例2と同じ熱接着性塗工液を片面に38g/m2
工し、坪量122g/m2の全熱交換体用紙を得た。
COMPARATIVE EXAMPLE 3 Using the same base paper and the same coating liquid as in Comparative Example 2, an air knife coater was used to provide a moisture absorbing / releasing coating layer of 2 g / m 2 on both sides, and then the area ratio of the recess was 90%. %, Using a coating machine with a gravure roll engraved with a depth of 300 μm,
The same heat-adhesive coating liquid as in Example 2 one side 38 g / m 2 was applied to obtain a total heat exchanger sheet having a basis weight of 122g / m 2.

【0038】比較例4 実施例1で得られた基紙の片面全面に、実施例2と同様
なる熱接着性塗工液を用いて、エアーナイフコーターに
て、固形分で熱接着性塗工液を30g/m2塗工し、坪
量140g/m2の全熱交換体用紙を得た。
COMPARATIVE EXAMPLE 4 The same adhesive coating solution as in Example 2 was applied to the entire surface of one side of the base paper obtained in Example 1 using an air knife coater to solid-state heat-adhesive coating. The liquid was applied at 30 g / m 2 to obtain a total heat exchanger paper having a basis weight of 140 g / m 2 .

【0039】以上述べた全熱交換体用紙を用いて、熱接
着面同士又は熱接着面と非熱接着面を、コルゲート加工
機を用いて、熱圧で段繰り加工を施し、コルゲート加工
品を得た。得られたコルゲート加工品で図3、4のよう
な全熱交換体を得た。
Using the above-described total heat exchanger paper, the heat-bonded surfaces or the heat-bonded surface and the non-heat-bonded surface are subjected to step rolling under hot pressure using a corrugating machine to obtain a corrugated product. Obtained. A total heat exchanger as shown in FIGS. 3 and 4 was obtained from the obtained corrugated product.

【0040】表1に実施例及び比較例の全熱交換体用紙
を用いたE段加工したコルゲート加工品で幅12cm、
直径45cmの熱交換器用ローターを作成し、実用試験
を行った際の全熱交換率、耐久強度を示した。尚、全熱
交換効率は、風速1.5m/秒、圧損5mmHgの時の
値であり、効率が65%以下を×印、65〜74%を○
印75%以上を◎印で表記し、○印以上が適とする。ま
た、耐久強度は運転中形状が変形したり、接着部がはく
離した場合を不可とし、変化のないものを可とした。
Table 1 shows a corrugated product having a width of 12 cm, which was subjected to E-stage processing using the total heat exchanger papers of Examples and Comparative Examples.
A rotor for a heat exchanger having a diameter of 45 cm was prepared, and the total heat exchange rate and the durability in a practical test were shown. The total heat exchange efficiency is a value at a wind speed of 1.5 m / sec and a pressure loss of 5 mmHg.
A mark of 75% or more is indicated by ◎, and a mark of ○ or more is appropriate. In addition, the durability strength was determined to be unacceptable when the shape was deformed during the operation or when the bonded portion was peeled off, and was acceptable when there was no change.

【0041】[0041]

【表1】 [Table 1]

【発明の効果】以上述べた如く本発明の全熱交換体用紙
によれば、以下に示す顕著な効果を有する。
As described above, the total heat exchanger paper of the present invention has the following remarkable effects.

【0042】(1)基紙に、部分的に熱接着剤層を設け
た全熱交換体用紙を用い、通常のコルゲート加工機を用
いて、単なる熱または超音波熱を利用した圧着成形を施
すことにより容易にコルゲート加工品を製造できる。
(1) Using a total heat exchanger paper partially provided with a thermal adhesive layer on a base paper, press-fitting is performed using simple heat or ultrasonic heat using an ordinary corrugating machine. Thereby, a corrugated product can be easily manufactured.

【0043】(2)全熱交換体用紙に吸放湿性が予め付
与されているため、塩化リチウムの様な潮解性物質を使
用することなく、潜熱交換効率を向上することができ、
強度低下がなく、形状保持性の良好な全熱交換体を製造
できる。
(2) Since the heat absorbing and releasing properties are previously given to the total heat exchanger paper, the latent heat exchange efficiency can be improved without using a deliquescent substance such as lithium chloride.
It is possible to produce a total heat exchanger having good shape retention without a decrease in strength.

【0044】(3)吸放湿性塗工層は、吸放湿性能だけ
でなく、空気の透過性を低下させることで、交換すべき
空気の混合を極力減少させ、空気浄化作用を向上させ
る。
(3) The moisture absorbing / releasing coating layer not only reduces the moisture absorbing / releasing performance but also the air permeability, thereby reducing the mixing of the air to be replaced as much as possible and improving the air purifying action.

【0045】(4)接着剤を部分的に塗工しているため
に紙本来の吸放湿性能を大きく阻害せず、潜熱交換効率
の良い全熱交換体を製造できる。
(4) Since the adhesive is partially applied, the whole heat exchanger having a high latent heat exchange efficiency can be manufactured without significantly impairing the original moisture absorption / release performance of the paper.

【0046】(5)アルミ板などの異なり、紙素材であ
るため不要となった場合は焼却処分が可能である。
(5) Unlike an aluminum plate or the like, it is made of paper and can be incinerated when it becomes unnecessary.

【図面の簡単な説明】[Brief description of the drawings]

【図1】基紙に網点状に熱接着性を有する接着剤を部分
的に塗工した全熱交換体用紙。
FIG. 1 is a total heat exchanger paper in which a base paper is partially coated with an adhesive having a thermal adhesive property in a halftone dot shape.

【図2】基紙の両面に吸放湿性粉体を含む塗工層を設け
た後、網点状に熱接着性を有する接着剤を部分的に塗工
した全熱交換体用紙。
FIG. 2 is a total heat exchanger paper in which a coating layer containing a moisture-absorbing and releasing powder is provided on both sides of a base paper, and an adhesive having a thermal adhesive property is partially applied in a halftone dot shape.

【図3】全熱交換体用紙をコルゲート加工後、コアーを
作成し全熱交換体とした例
FIG. 3 shows an example in which a core is formed and a total heat exchanger is formed after corrugating a sheet of the total heat exchanger.

【図4】全熱交換体用紙をコルゲート加工後、積層体を
作成し全熱交換体とした例
FIG. 4 shows an example in which a total heat exchanger paper is corrugated and then a laminate is formed to be a total heat exchanger.

【符号の説明】[Explanation of symbols]

1 基紙 2 熱接着性を有する接着剤 3 吸放湿性粉体とバインダーを主材とする塗工層 4 ローター型全熱交換体 5 積層型全熱交換体 DESCRIPTION OF SYMBOLS 1 Base paper 2 Adhesive which has thermal adhesiveness 3 Coating layer which has a hygroscopic powder and a binder as a main material 4 Rotor type total heat exchanger 5 Laminated type total heat exchanger

Claims (7)

【特許請求の範囲】[Claims] 【請求項1】 製紙用原料と無機質粉体を主材として抄
造される基紙において、該無機質粉体が基紙の全体重量
の20〜80重量%を占め、無機質粉体のうち、吸放湿
性粉体が10〜50重量%であることを特徴とする全熱
交換体用紙。
1. In a base paper made mainly from a papermaking raw material and an inorganic powder, the inorganic powder occupies 20 to 80% by weight of the total weight of the base paper. Total heat exchanger paper characterized in that the wet powder is 10 to 50% by weight.
【請求項2】 前記基紙の片面に熱接着性を有する接着
剤層を面積比率20〜80%、塗工量5〜25g/m2
で部分的に設けたことを特徴とする全熱交換体用紙。
2. An adhesive layer having thermal adhesiveness on one side of the base paper having an area ratio of 20 to 80% and a coating amount of 5 to 25 g / m 2.
Total heat exchanger paper characterized in that the paper is partially provided.
【請求項3】 前記基紙の片面に、吸放湿性粉体とバイ
ンダーを主体とする吸放湿性塗工層を5〜30g/m2
設け、反対の面に熱接着性を有する接着剤層を面積比率
20〜80%、塗工量5〜25g/m2で部分的に設け
たことを特徴とする全熱交換体用紙。
3. A moisture absorbing / releasing coating layer mainly composed of a moisture absorbing / releasing powder and a binder is provided on one side of the base paper in an amount of 5 to 30 g / m 2.
A total heat exchanger paper characterized in that an adhesive layer having thermal adhesiveness is provided partially on the opposite surface with an area ratio of 20 to 80% and a coating amount of 5 to 25 g / m 2 .
【請求項4】 前記基紙の両面に、吸放湿性粉体とバイ
ンダーを主体とする吸放湿性塗工層を片面につき5〜3
0g/m2設け、更にいずれかの一方の面に、熱接着性
を有する接着剤層を面積比率20〜80%、塗工量5〜
25g/m2で部分的に設けたことを特徴とする全熱交
換体用紙。
4. A moisture-absorbing / desorbing coating layer mainly composed of a moisture-absorbing / desorbing powder and a binder is provided on both sides of the base paper in an amount of 5 to 3 per side.
0 g / m 2 , and further, an adhesive layer having a thermal adhesive property was provided on one of the surfaces with an area ratio of 20 to 80% and a coating amount of 5 to 5%.
Total heat exchanger paper partially provided at 25 g / m 2 .
【請求項5】 前記基紙に、凹部が面積比率20〜80
%、深度50〜400μmの彫刻を施したグラビアロー
ルを供えた塗工機を用いて、熱接着性を有する接着剤層
を片面に塗工量5〜25g/m2且つ面積比率20〜8
0%の割合で部分的に塗工し、加熱乾燥することを特徴
とする全熱交換体用紙の製造方法。
5. The base paper has a concave portion having an area ratio of 20 to 80.
%, Using a coating machine provided with a gravure roll engraved with a depth of 50 to 400 μm, applying an adhesive layer having thermal adhesiveness to one surface in an amount of 5 to 25 g / m 2 and an area ratio of 20 to 8
A method for manufacturing a total heat exchanger paper, which comprises partially coating at a rate of 0% and drying by heating.
【請求項6】 前記基紙の片面に、吸放湿性粉体とバイ
ンダーを主体とする吸放湿性塗工層を5〜30g/m2
の範囲で設けた後、凹部が面積比率20〜80%、深度
50〜400μmの彫刻を施したグラビアロールを供え
た塗工機を用いて、熱接着性を有する接着剤層を吸放湿
性塗工層の反対の面に塗工量5〜25g/m2の割合で
部分的に塗工し、加熱乾燥することを特徴とする全熱交
換体用紙の製造方法。
6. A moisture absorbing / releasing coating layer mainly composed of a moisture absorbing / releasing powder and a binder is provided on one surface of the base paper in an amount of 5 to 30 g / m 2.
After the provision of the adhesive layer having heat adhesion, the adhesive layer having thermal adhesiveness is coated with a moisture absorbing / releasing coating using a coating machine provided with an engraved gravure roll having an area ratio of 20 to 80% and a depth of 50 to 400 μm. A method for producing a total heat exchanger paper, which comprises partially applying a coating amount of 5 to 25 g / m 2 on the opposite side of the work layer and drying by heating.
【請求項7】 前記基紙の両面に、吸放湿性粉体とバイ
ンダーを主体とする吸放湿性塗工層を5〜30g/m2
の範囲で設けた後、凹部が面積比率20〜80%、深度
50〜400μmの彫刻を施したグラビアロールを供え
た塗工機を用いて熱接着性を有する接着剤層を、いずれ
かの片面に塗工量5〜25g/m2の割合で部分的に塗
工し、加熱乾燥することを特徴とする全熱交換体用紙の
製造方法。
7. A moisture absorbing / releasing coating layer mainly composed of a moisture absorbing / releasing powder and a binder is provided on both sides of the base paper in an amount of 5 to 30 g / m 2.
After providing the adhesive layer having thermal adhesiveness using a coating machine provided with an engraved gravure roll having a concave portion having an area ratio of 20 to 80% and a depth of 50 to 400 μm, A method for producing a total heat exchanger paper, comprising partially applying a coating amount of 5 to 25 g / m < 2 > to the coating and heating and drying.
JP8326095A 1996-11-20 1996-11-20 Paper for total heat exchanger and its manufacture Pending JPH10153399A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8326095A JPH10153399A (en) 1996-11-20 1996-11-20 Paper for total heat exchanger and its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8326095A JPH10153399A (en) 1996-11-20 1996-11-20 Paper for total heat exchanger and its manufacture

Publications (1)

Publication Number Publication Date
JPH10153399A true JPH10153399A (en) 1998-06-09

Family

ID=18184051

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8326095A Pending JPH10153399A (en) 1996-11-20 1996-11-20 Paper for total heat exchanger and its manufacture

Country Status (1)

Country Link
JP (1) JPH10153399A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1403430A4 (en) * 2001-06-01 2004-12-08 Mitsubishi Paper Mills Ltd Total heat exchange element-use paper
WO2008146387A1 (en) * 2007-05-31 2008-12-04 Mitsubishi Electric Corporation Heat exchanger element, process for manufacturing the same, and heat exchange ventilation apparatus
CN101845768A (en) * 2010-06-02 2010-09-29 骏源特种纸(上海)有限公司 Micropore air thermal conversion paper and preparation process thereof
JP2021503562A (en) * 2017-11-17 2021-02-12 アイメリーズ ユーエスエー,インコーポレーテッド Heat seal coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6050398A (en) * 1983-08-30 1985-03-20 Japan Vilene Co Ltd Pipe type total heat exchanger
JPH05177177A (en) * 1991-10-16 1993-07-20 Sekisui Chem Co Ltd Method for cleaning coating roll
JPH06194093A (en) * 1992-11-05 1994-07-15 Mitsubishi Electric Corp Total enthalpy heat exchanger
JPH07300575A (en) * 1994-03-10 1995-11-14 Nakamura Seishishiyo:Kk Hot melt label
JPH08299745A (en) * 1995-05-11 1996-11-19 Seibu Giken:Kk Adsorbing body for moisture exchange

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6050398A (en) * 1983-08-30 1985-03-20 Japan Vilene Co Ltd Pipe type total heat exchanger
JPH05177177A (en) * 1991-10-16 1993-07-20 Sekisui Chem Co Ltd Method for cleaning coating roll
JPH06194093A (en) * 1992-11-05 1994-07-15 Mitsubishi Electric Corp Total enthalpy heat exchanger
JPH07300575A (en) * 1994-03-10 1995-11-14 Nakamura Seishishiyo:Kk Hot melt label
JPH08299745A (en) * 1995-05-11 1996-11-19 Seibu Giken:Kk Adsorbing body for moisture exchange

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1403430A4 (en) * 2001-06-01 2004-12-08 Mitsubishi Paper Mills Ltd Total heat exchange element-use paper
EP2312051A3 (en) * 2001-06-01 2012-05-30 Mitsubishi Paper Mills Limited Total heat exchanging element paper
US9513069B2 (en) 2001-06-01 2016-12-06 Mitsubishi Papaer Mills Limited Total heat exchanging element paper
US9677829B2 (en) 2001-06-01 2017-06-13 Mitsubishi Paper Mills Limited Total heat exchanging element paper
WO2008146387A1 (en) * 2007-05-31 2008-12-04 Mitsubishi Electric Corporation Heat exchanger element, process for manufacturing the same, and heat exchange ventilation apparatus
JPWO2008146387A1 (en) * 2007-05-31 2010-08-12 三菱電機株式会社 HEAT EXCHANGE ELEMENT, ITS MANUFACTURING METHOD, AND HEAT EXCHANGE VENTILATION DEVICE
JP5042310B2 (en) * 2007-05-31 2012-10-03 三菱電機株式会社 HEAT EXCHANGE ELEMENT, ITS MANUFACTURING METHOD, AND HEAT EXCHANGE VENTILATION DEVICE
CN101845768A (en) * 2010-06-02 2010-09-29 骏源特种纸(上海)有限公司 Micropore air thermal conversion paper and preparation process thereof
JP2021503562A (en) * 2017-11-17 2021-02-12 アイメリーズ ユーエスエー,インコーポレーテッド Heat seal coating

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