JPH09279321A - Production of resin-coated aluminum alloy sheet for can formed by deep drawing and ironing - Google Patents

Abstract

PROBLEM TO BE SOLVED: To produce a resin-coated Al alloy sheet excellent in deep drawing and ironing workabilities, at the time of producing a resin-coated Al alloy sheet from an Al alloy ingot contg. specified amounts of Mn, Mg, Si and Fe, by specifying the secondary cold rolling ratio and the coating temp. of thermoplastic resin. SOLUTION: An Al alloy ingot contg, by weight, 0.01 to 1.0% Mn and 2.5 to 6.0% Mg, contg., as inevitable impurities, <=0.3% Si and <=0.7% Fe so as to satisfy <=0.8% (Si+Fe) is subjected to homogenizing heat treatment and is subjected to hot rolling, cold rolling and continuous annealing by the conventional methods. Next, it is subjected to secondary cold rolling at 30 to <50% rolling ratio, is subjected to surface treatment, is thereafter subjected to heating treatment and is held to 220 to 300 deg.C, both sides are coated with thermoplastic resin (such as ployethlene terephthalate) so as to regulate the thickness to about 5 to 50μm, and immediately after that, it is rapidly cooled to the recrystallization temp. of the thermoplastic resin or below. The resin-coated Al alloy sheet excellent in strength, workability and adhesion and furthermore excellent in dry process deep drawing and ironing workabilities can be obtd.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a material used for a two-piece can produced by a process including drawing and ironing. More specifically, a two-piece can with a thin can wall is manufactured by processing including drawing and ironing, which does not require cooling or lubrication of water or a water-based lubricant, and does not require cleaning of the can after making. Suitable for
The present invention relates to a method for producing a resin-coated aluminum alloy plate for a drawn ironing can coated with a thermoplastic resin.

[0002]

2. Description of the Related Art As a two-piece can in which a can body and a can bottom are formed integrally, a DI can (Draw) obtained by drawing or ironing a tinplate or an aluminum alloy plate is used.
n andIroned Can) have been manufactured. DI can is tinplate or after drawing aluminum alloy plate,
Using several ironing dies and punches arranged continuously, cooling and lubricating with a large amount of water or water-based lubricant to reduce the wall thickness of the can to about 1/3 of the original plate thickness, followed by degreasing , Dried and painted. In recent years,
Japanese Patent No. 310223 discloses a method of manufacturing a two-piece can from a resin-coated metal plate by a combined processing method including drawing and ironing. This method differs from the conventional method for manufacturing DI cans in that after drawing a resin-coated metal plate coated with a high-temperature volatile lubricant, dry drawing and ironing are performed without using water or an aqueous lubricant. A two-piece can having a thin can wall is manufactured by a combined processing method in which the processing is performed simultaneously. According to this composite processing method, the steps of degreasing, washing, drying, and painting the can after forming it into a two-piece can become unnecessary, and a two-piece can can be manufactured without polluting the environment. The present invention has been studied for the purpose of providing a resin-coated aluminum alloy sheet suitable for this composite processing method. Regarding materials suitable for the composite processing method, Japanese Unexamined Patent Publication No. Hei 7-266496 discloses a yield strength,
Materials having limited tensile strength, plate thickness, center line roughness, etc. are disclosed, and examples include JIS 3004 H19 and JIS.
The use of 5052 H38 aluminum alloy is shown.

[0003]

SUMMARY OF THE INVENTION The present invention relates to a method disclosed in
It is an object of the present invention to provide a resin-coated aluminum alloy plate suitable for a composite machining method as disclosed in JP-A-313223. The composite machining method targeted by the present invention is a machining method in which redrawing and ironing are performed simultaneously using a die in which a redrawing portion and an ironing portion are paired. One of the features of the combined machining method is to reduce the size of the shoulder radius of the die where redrawing is performed, and to bend and bend back the material at this die shoulder radius to reduce the thickness of the can wall. is there. In this combined machining, the thickness of the machined
Since severe bending and bending back processing is performed with a small die shoulder radius of about several times, the surface of the material is likely to be rough and cracked, and depending on the processing conditions, the can wall is broken at the die shoulder radius. Even when no break occurs in the die shoulder radius portion, rough skin and surface cracks cause a decrease in adhesion between the coating resin film and the aluminum alloy plate, and can wall breakage is extremely likely to occur during subsequent ironing. The present invention is directed to the bending of the shoulder shoulder radius of a small shoulder arm.
An object of the present invention is to provide a resin-coated aluminum alloy plate that is resistant to can wall breakage and has sufficient strength as a can during dry-type composite processing including bending back processing and subsequent ironing processing. Incidentally, the JIS aluminum alloy 3004H1 shown in the example of JP-A-7-266496.
No. 9 has the required strength, but the workability is insufficient for the purpose of the present invention. On the other hand, JI
Although the S aluminum alloy 5052H38 has workability suitable for the composite processing method aimed at by the present invention, it has a small allowable Mn amount, and the amount of scrap of 3004 alloy that can be input in the production of this alloy is significantly limited. That is, the reuse of scrap is restricted.

[0004]

SUMMARY OF THE INVENTION The present invention provides a method for preparing M
n: 0.01 to 1.0%, Mg: 2.0 to 6.0%, Si: ≤ 0.3%, Fe: ≤ 0.7% as unavoidable impurities, and (Si + Fe): After homogenizing and heat-treating aluminum alloy cast iron having a content of ≤0.8%, a step of hot rolling according to a conventional method to form a hot rolled sheet, a step of performing cold rolling and continuous annealing, and then a rolling ratio: 30 Secondary cold rolling at less than 50% and then surface treatment, the surface-treated aluminum alloy plate is heated to a plate temperature of 220 to 30
A method for producing a resin-coated aluminum alloy plate for a drawn and ironing can, which comprises a step of holding the temperature in the range of 0 ° C., coating both surfaces thereof with a thermoplastic resin, and a step of quenching after coating. Further, in the present invention, Mn: 0.01 to 1.0% by weight% and Mg: 2.
0-6.0%, Si as unavoidable impurities: ≤0.3%,
Fe: ≤ 0.7% and (Si + Fe): ≤ 0.7.
After homogenizing and heat-treating 8% aluminum alloy cast iron, it is hot rolled by a conventional method to form a hot rolled sheet, then cold rolled, and continuously annealed, and then the rolling ratio is 50 to 80%. 220-28 after secondary cold rolling at
Stabilizing and heating at a temperature of 0 ° C for 1 minute to 5 hours, then performing a surface treatment, heating the surface-treated aluminum alloy plate to a temperature range of 220 to 300 ° C, and coating both surfaces thereof with a thermoplastic resin. And a step of rapidly cooling after coating, a method for producing a resin-coated aluminum alloy plate for a drawn and ironed can. Furthermore, the present invention is characterized in that the thermoplastic resin to be coated is a thermoplastic polyester resin, and the surface treatment applied to the aluminum alloy plate is etching, and / or electrolytic chromic acid treatment, and / or phosphoric acid. It is characterized by being treated with chromic acid.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention has been extensively studied in order to provide a method for producing a resin-coated aluminum alloy sheet which is excellent in strength, workability, adhesion, and excellent in dry drawing and ironing workability. The present invention has developed a manufacturing method capable of obtaining a target resin-coated aluminum alloy plate by determining the alloy composition, the type of thermoplastic resin, and the type of surface treatment. Hereinafter, the present invention will be described in detail with reference to examples.

[0006]

EXAMPLES First, the reasons for limiting the alloy components and the like of the aluminum alloy plate to be the coated substrate of the resin-coated aluminum alloy plate in the present invention will be described below. In addition,% of each alloy component is shown by weight%. In the present invention, in order to make it easy to mix, melt and reuse the scrap generated during the production of the aluminum alloy plate and the scrap of the used aluminum can 3003, which is a can body material of the aluminum DI can. The alloy and the alloy component of the 5052 alloy, which is a lid material, were examined in consideration of the amounts of Mn and Mg in particular. JI
In the S standard, 3004 material has Mn: 1.0 to 1.5.
%, Mg: 0.8-1.3%, 5052 material: Mn: 0.1
%, Mg: 2.2 to 2.8%. The Mn content of the aluminum alloy plate serving as the coated substrate of the resin-coated aluminum alloy plate of the present invention is the lower limit of Mn of 3004 alloy.
It is assumed that the amount can be included. This makes it possible to significantly increase the mixing ratio of the abundant scrap of the 3004 alloy when producing the aluminum alloy used in the present invention.

[Mn] Mn is inexpensive and is added to obtain strength, but if it is less than 0.01%, the effect is insufficient. On the other hand, regarding the upper limit of the addition amount, it is assumed that the scrap of the can body material is mixed and reused, and the addition amount is assumed to be in the range of 1.0% or less of the lower limit of the 3004 alloy. Al-Fe-Mn crystallized substances are formed by the addition of Mn.
The hard α phase, which is a transformation product, is not preferable for the bending / unbending workability which is the subject of the present invention. In commercially available aluminum DI processing, an Al—Fe—Mn crystallized substance has a lubricating action during ironing, and is indispensable for improving ironing workability. However, in the present invention, since an aluminum alloy plate whose surface is coated with a resin is processed, the lubricating action of the Al-Fe-Mn-based crystallized substance is not necessary, but rather the workability is impaired. That is, the crystallized product is not suitable for the composite working method for applying the resin-coated aluminum alloy sheet of the present invention. The compound processing method is
Redrawing and ironing are performed simultaneously using a pair of dies with a redrawing part and an ironing part, and the shoulder radius of the redrawing die is set to a small shoulder radius several times less than the plate thickness. However, the crystallized material significantly impairs the bendability / returnability at the die shoulder radius portion. That is, the surface of the aluminum alloy is easily roughened and cracked at the time of bending / unbending, and the adhesion of the coating resin film based on the roughness is lowered. In addition, the amount, size,
Depending on the processing conditions, the can wall is broken. Therefore, the upper limit of the amount of Mn is set to 1.0% in consideration of the amount of Mg described below.

[Mg] Mg is an element that is more effective than Mn in improving the strength, and is added to obtain the necessary strength as a can. However, when the added amount increases, the workability decreases. In the present invention, the upper limit of the Mn content is set to 1.0% for the above-mentioned reason.
However, it is not in the range where the workability is sufficient. Therefore, the range of the Mg content is set to 2.0 to 6.0% in order to reduce the deterioration of the workability and the fluctuation of the workability. When the Mn content is near the upper limit of 1.0% of the present invention, Mg
If it exceeds 6.0%, the workability becomes poor, and it becomes difficult to apply it to severe processing applications. . On the other hand, if the Mg content is less than 2.0%, the strength becomes insufficient, and the economic efficiency is improved. The two-piece can formed by molding the resin-coated aluminum alloy plate according to the present invention by using the above-described composite processing is applied to contents in which the internal pressure of the can is positive, such as beers, carbonated beverages, and beverages filled with nitrogen gas. However, the internal pressure of the can differs depending on the contents. For this reason, a material having a large amount of Mn and Mg is applied to a material for a can filled with a content having a high internal pressure of the can. If the pressure resistance of the can bottom is insufficient, the can bottom will buckle and become unusable as a product. The yield strength and thickness of the sheet mainly affect the pressure resistance of the can bottom. When the yield strength is low, it is necessary to increase the thickness of the sheet, but the economic efficiency is impaired. Therefore, from the viewpoint of economical efficiency, it is suitable for a material with a large amount of Mn and Mg added and a high strength thin plate thickness, but if the strength is increased by increasing the amount of Mn and Mg added, the workability of the material decreases. . The aluminum alloy of the present invention has a higher Mg content than that of a general aluminum alloy for cans and can provide high strength, but the workability is somewhat insufficient. Therefore, it is preferable to reduce the plate thickness at the time of manufacturing the plate and to perform the forming process with a low degree of processing at the time of the composite processing.

[Si] Si causes a phase transformation in an Al—Fe—Mn crystallized product to form a so-called hard α phase. This α phase is required in the production of DI cans in order to improve the ironing workability, but it is not preferable for the present invention because it lowers the bending / bending back workability more than the crystallized substances before the phase transformation. Therefore, the upper limit is set to 0.3%, preferably 0.2% or less.

[Fe] Fe is related to Mn, and Al—Fe
-Form Mn-based crystals. As described above, the Al-Fe-Mn system is not preferable for the present invention from the viewpoint of bending and bending-back workability, and the upper limit of Fe, which is an element forming the Al-Fe-Mn system, is set to 0.1.
7%. It is preferably 0.4% or less.

The amount of [Si + Fe] (Si + Fe) is also
An upper limit is set to reduce the amount of the Fe-Mn-based crystallized product, particularly the amount of the hard α phase, to a low level. The upper limits of the amounts of Fe and Si are determined as described above.
l-Fe-Mn crystallized substances impair workability. Therefore, the upper limit is set to 0.8%, preferably 0.5% or less.

As other elements, Cu and Zn are not particularly limited, but Cu and Zn are preferably in the following ranges for the following reasons. Cu exhibits precipitation hardening due to Al-Cu-Mg-based precipitates together with Mg, and is effective from the viewpoint of strengthening, but if it increases, the workability decreases, so 0.3%
It is preferably at most 0.2%, more preferably at most 0.2%. Zn addition has the effect of properly dispersing the crystallized substances,
In order to reduce the harmful effects of the crystallized substance, it is preferable to contain 0.01 to 0.5%.

Next, the manufacturing method of the present invention will be described. An aluminum alloy having the above chemical components is melted and cast by a conventional method, and the obtained ingot is subjected to a homogenizing heat treatment before hot rolling. This homogenization heat treatment aims at homogenization of micro-segregation, precipitation of supersaturated elements, and the like, homogenization of the material, and improvement of hot rollability thereafter. If the temperature is lower than 500 ° C., the effect is insufficient. If the temperature exceeds 600 ° C., the performance of the plate surface is deteriorated due to burning or the like. The holding time in the above temperature range is preferably 1 hour or more.

Subsequent to the homogenizing heat treatment, hot rolling is performed by a conventional method. The temperature at the time of hot rolling is not particularly limited, but the hot start temperature is preferably in the range of 400 to 520 ° C, and the finish rolling temperature is preferably in the range of 230 to 350 ° C.

After the above hot rolling, cold rolling is carried out, and then continuous annealing is carried out. The heating rate and the cooling rate when performing continuous annealing are preferably 100 ° C./min or more. 100
If it is less than ° C / minute, the crystal grains become coarse, resulting in insufficient strength and workability. The heating temperature is 400 to 580 ° C. If the temperature is less than 400 ° C, recrystallization is insufficient and the workability cannot be improved. On the other hand, if the temperature exceeds 580 ° C., the surface of the plate burns, and the surface properties deteriorate. Further, if the heating is performed for more than 5 minutes, the material softens, and the required strength cannot be obtained.

After performing the above continuous annealing treatment, secondary cold rolling is performed. As one mode of this secondary cold rolling and the heat treatment after rolling, the rolling rate is lowered to 30 to less than 50%. As the rolling ratio increases, the crystallized material is stretched in the rolling direction, voids are formed around the crystallized material, and processing strain is accumulated, and the bending / unbending workability is reduced. Therefore, the rolling ratio is set to less than 50% from the viewpoint of workability. In order to obtain the required strength, the lower limit of the rolling reduction is set to 30%. If cold-rolled under these conditions, after performing surface treatment in a later step,
Immediately, the aluminum alloy plate is heated to 220 to 300 ° C., and both surfaces thereof are coated with resin.

As another aspect after the secondary cold rolling and after the rolling, the rolling rate is set to 50 to 80%, which is higher than that in the above aspect. When cold-rolling under these conditions, after rolling 220-
Stabilization heat treatment is performed at a temperature range of 280 ° C. for 1 minute to 5 hours. If the rolling ratio exceeds 80%, the workability becomes insufficient even if heated at 220 ° C. or lower, which is the lower limit of the heating temperature for stabilizing heating, for 5 hours or more. If the rolling ratio is 50% or less, 22
When heated at 0 ° C or higher for 5 hours or more, the strength is insufficient, so
The lower limit of the rolling rate is 50%. On the other hand, in this aspect, since the cold rolling rate is as high as 50 to 80%, it is necessary to heat at 220 ° C. for at least 5 hours in order to recover the workability. However, the required strength cannot be obtained by heating at a temperature exceeding 220 ° C. for 5 hours or more, so the upper limit of the heating time is 5 hours. Also, the heating temperature is 280 ° C.
If it exceeds, the softening occurs in an extremely short time and the strength cannot be controlled to the required strength. Therefore, the upper limit of the heating temperature is 280 ° C. and the lower limit of the heating time is 1 minute.

After being subjected to any of the above-mentioned two types of secondary cold rolling, and secondary cold rolling and subsequent stabilizing heat treatment, the aluminum alloy plate is subjected to anodizing treatment, immersion chromic acid treatment, and phosphorus. Acid chromic acid treatment, alkaline solution, etching treatment with an acid solution, surface treatment by a known method such as electrolytic chromic acid treatment, the present invention, etching treatment, and or electrolytic chromic acid treatment, or phosphoric chromic acid Treatment is more preferred. In particular, when forming a two-layer coating consisting of metallic chromium and hydrated chromium oxide on an aluminum alloy plate by electrolytic chromic acid treatment, the amount of hydrated chromium oxide is in terms of the processing adhesion of the laminated resin film. Chromium may be 3 to 25 mg / m ² , and 7 to ²
The range of 0 mg / m ² is more preferable. Further, the amount of metallic chromium is not particularly limited, but from the viewpoint of corrosion resistance after processing and processing adhesion of the laminated resin film, it is 1 to 100.
ranges preferably mg / m ^2, the range of 5 to 30 mg / m ² is more preferable. When the phosphoric acid chromic acid treatment is applied, the amount of the chromate film formed is 5 to 5 as chromium.
The range may be 50 mg / m ² , 15-30 mg /
The range of m ² is more preferable.

Next, in the present invention, the thermoplastic resin laminated on at least one side of the aluminum alloy plate includes:
It is possible to use a single-layer or multi-layer resin film containing polyester resin, polyolefin resin, polyamide resin, polycarbonate resin, etc. as a main component, a resin film obtained by blending two or more of these resins, or a resin film obtained by copolymerization. it can. Particularly for drawn ironing cans subjected to severe molding processing of the present invention, polyethylene terephthalate, copolymerized polyester resin mainly composed of ethylene terephthalate repeating units, polybutylene terephthalate, polyester resin mainly composed of butylene terephthalate repeating units, or Either a polyester resin obtained by blending at least two kinds of these polyester resins, or a multilayer polyester resin obtained by laminating at least two kinds of the above polyester resins, and further, a polycarbonate resin, or at least one polyester resin and the above polyester resin It consists of a multi-layer resin obtained by laminating at least two types of polycarbonate resin and the above-mentioned polyester resin. Stretched in two directions, biaxial orientation resin film produced by heat is preferable.

The thickness of the laminated resin film is 5 to 50.
The range of μm is preferable, and the range of 10 to 30 μm is more preferable. When the thickness is 5 μm or less, it is difficult to continuously laminate a metal plate at a high speed. On the other hand, if the thickness of the laminated resin film is 50 μm or more, it is not preferable from the viewpoint of economic efficiency as compared with an epoxy resin paint widely used as a material for cans.

The resin film may be laminated directly on the aluminum alloy plate, or may be laminated between the resin film and the aluminum alloy plate with a thermosetting adhesive such as an epoxy-phenol resin interposed therebetween. Laminating the resin film on the aluminum alloy plate with the thermosetting adhesive interposed by applying the thermosetting adhesive in advance on one side of the resin film or the aluminum alloy plate that adheres to each other Can be.

The temperature of the aluminum alloy plate when coating the resin film differs depending on the type of resin to be coated.
220-300 ° C. When the obtained resin-coated aluminum alloy plate is drawn and ironed at 220 ° C or lower,
The resin film coated with poor processing adhesion easily peels off. On the other hand, at 300 ° C. or higher, the resin film to be coated melts and adheres to a laminating roll or the like, making the coating operation impossible. For the above reasons, the upper and lower limits of the temperature of the aluminum alloy plate when coating the resin film are determined.

Next, the above-mentioned thermoplastic resin film is brought into contact with both sides of the aluminum alloy plate heated to the above-mentioned temperature, superposed between a pair of laminating rolls, sandwiched and pressed, and then immediately heated. Cool rapidly below the recrystallization temperature of the plastic tree. From the above steps, a resin-coated aluminum alloy plate for a drawn and ironed can is obtained.

As described above, a high-temperature volatile lubricant is applied to the upper surface of a thermoplastic resin film-coated aluminum alloy plate manufactured by using the manufacturing method of the present invention, and then drawn and ironed to obtain water or It is possible to manufacture a two-piece can having a thin can wall without requiring cooling or lubrication with a water-based lubricant or the like and without requiring cleaning of the can after can-making. As a high-temperature volatile lubricant, when drawing and ironing and heating at a temperature of about 200 ° C. for several minutes,
It is desirable that the particles be scattered by 0% or more. Specifically, the material is selected from liquid paraffin, synthetic paraffin, natural wax, or other simple substance, or a mixture thereof according to processing conditions and heating conditions after processing. As the characteristics of the lubricant to be applied, those having a melting point in the range of 25 to 80 ° C and a boiling point in the range of 180 to 400 ° C are desirable for achieving the object of the present invention. In addition, the application amount should be determined in consideration of the surface to be the outer surface of the can, the surface to be the inner surface of the can, processing conditions, heating conditions after processing, and the like.
A range of 100 mg / m ² , preferably 30-60 mg / m ² is suitable.

(Examples) Aluminum alloys having the compositions shown in Tables 1 to 3 were melted, cast and faced by a conventional method, homogenized at 550 ° C. for 1 hour, and then hot rolled by a conventional method.
Cold rolling and continuous annealing are performed, and then secondary cold rolling is performed at the rolling rates shown in Tables 1 to 3 to obtain a plate thickness of 0.25 mm, and the following etching treatment (A) and electrolytic chromic acid treatment (B) are performed. Or, after the etching treatment, further electrolytic chromic acid treatment
Either (C) or chromic acid phosphate treatment (D) was applied. [A] Immersion in a 60 ° C. aqueous sodium hydroxide solution (50 g / l) for 15 seconds, washing with water, and then 15 ° C. sulfuric acid (15 g / l)
It is immersed in l) for 15 seconds, washed with water, and dried. [B] Chromic anhydride: Cathodic electrolysis at a current density of 100 A / dm ² in an aqueous solution of 100 g / l as a main agent and 5 g / l of sodium fluoride as an auxiliary agent at 40 ° C. 41 mg / m ² , 12 hydrated chromium oxides
A two-layer coating consisting of ~ 15 mg / m ² is formed. [C] Immersion in a sodium hydroxide aqueous solution (50 g / l) at 60 ° C. for 15 seconds, washing with water, and then sulfuric acid at 15 ° C. (15 g / l)
l) and then rinsed with water for 15 seconds, followed by chromic anhydride: 100 g / l as a main agent, and sodium fluoride 5 g / l.
100 A / d in an aqueous solution at 40 ° C.
Cathodic electrolysis at a current density of m ² and metallic chromium of 21-28
mg / m ^2, hydrated chromium oxide is to form a two-layer film comprising 7~11mg / m ^2. [D] Phosphoric acid: 70 g / l, chromic anhydride: 12 g / l,
And an aqueous solution of sodium fluoride 5 g / l at 60 ° C. are sprayed to give a chromium amount of 13 to 20 mg / m.
Form the chromate film of ² . Then, after performing a surface treatment by any of the above methods, the aluminum alloy plate was heated under the conditions shown in Tables 1 to 3, and a thickness of 20 μm comprising 12 mol% of polyethylene isophthalate and 88 mol% of polyethylene terephthalate on both surfaces thereof. Were laminated and immediately immersed in water and cooled. After drying, about 50 mg / m ² of glamor wax (boiling point: 115 ° C.) was applied to both surfaces to obtain a test plate. Evaluation of the test plate, the strength after bending and bending back as described above,
Workability by composite processing, pressure resistance, and adhesion between the coated resin film after processing and the aluminum alloy plate surface were examined. The strength after bending / unbending is evaluated as good when the tensile strength of the test plate subjected to bending / unbending at a bending radius of 0.5 mm is 30% or more of the strength of the test plate before processing. , Less than 30% was evaluated as x (defective). With respect to the pressure resistance, a can with a can shape of 65 mm is formed by a normal drawing process, after the can bottom is subjected to a doming process, an internal pressure is applied, and the pressure at which the can bottom buckles is evaluated to determine whether it is good or bad. ² or more ○
(Good), and a case of less than 6.3 kg / cm ^{2 was} rated as × (poor). The composite workability was evaluated by processing a drawn can of 100 mm diameter formed with a drawing ratio of 1.6 into a primary re-drawn can with a diameter of 75 mm and a can wall thickness of 80% of the original plate thickness, followed by a secondary re-drawn process. The sex was evaluated. The secondary redrawing process has a redraw ratio of 1.15.
The re-drawing die shoulder arm is 0.4 mm, and the clearance of the ironing die is changed to evaluate the workability of the die shoulder part and the ironing part by the presence or absence of breakage of the can wall during processing. The case where there was no breakage was rated as O (good), and the case where breakage of the can wall occurred was rated as X (bad). Adhesion is evaluated by the presence or absence of peeling of the coating resin for the inner surface of the can wall after the secondary redrawing process under the same conditions as above, with no peeling being ○ (good),
No peeling was rated as X (poor). The evaluation results are shown in Tables 4 to 6.

[0026]

[Table 1]

[0027]

[Table 2]

[0028]

[Table 3]

[0029]

[Table 4] (Note) −: Not evaluated

[0029]

[Table 5] (Note) −: Not evaluated

[0030]

[Table 6] (Note) −: Not evaluated

[0031]

According to the present invention, Mn: 0.01 to 1.
0%, Mg: 2.0-6.0%, S as an unavoidable impurity
i: ≤ 0.3%, Fe: ≤ 0.7%, and (Si
+ Fe): ≦ 0.8% aluminum alloy cast iron having a relationship of homogenizing and heat-treating, followed by hot rolling by a conventional method to form a hot rolled sheet, then cold rolling, followed by continuous annealing Steps to be performed, then secondary cold rolling at a rolling ratio of 30 to less than 50, and then a step of surface-treating, heating the surface-treated aluminum alloy sheet to a sheet temperature of 220 to
A method for producing a resin-coated aluminum alloy sheet for a drawn and ironing can, which comprises the steps of holding the temperature in the range of 300 ° C. and coating a thermoplastic resin on both surfaces thereof, followed by quenching, or Mn: 0. 01-1.0%, Mg: 2.0-
6.0%, Si as unavoidable impurities: ≤0.3%, F
e: contains ≤ 0.7% and (Si + Fe): ≤ 0.8
After the homogenizing heat treatment of aluminum alloy cast iron having a relationship of%, hot rolling by a normal method to obtain a hot rolled sheet,
Then, a step of performing cold rolling, a step of continuously performing continuous annealing, and then a step of performing secondary cold rolling at a rolling rate of 50 to 80, followed by stabilizing heating at a temperature of 220 to 280 ° C. for 1 minute to 5 hours, Resin for squeezing and ironing, which comprises a step of surface-treating, heating the surface-treated aluminum alloy plate to a temperature range of 220 to 300 ° C., coating both surfaces with a thermoplastic resin, and rapidly cooling after coating A method for producing a coated aluminum alloy plate, further characterized in that the thermoplastic resin to be coated is a thermoplastic polyester resin, and the surface treatment applied to the aluminum alloy plate is etching, and or electrolytic chromic acid treatment, or Characterized by phosphoric acid chromic acid treatment, bending and unbending of die shoulder radius of small shoulder arm and subsequent ladder In performing complex machining including machining a dry, hard to occur is can wall rupture, and it is possible to manufacture a resin-coated aluminum alloy sheet having the required strength as a can. Furthermore, the Mn content of the aluminum alloy plate which is the coated substrate of the resin-coated aluminum alloy plate of the present invention is 30
By including the lower limit of Mn content of 04 alloy, it becomes possible to significantly increase the mixing ratio of scrap of 3004 alloy, which is present in a large amount, when producing the aluminum alloy used in the present invention, It also has excellent recyclability.

Front page continuation (72) Masao Komai, Inventor Masao Komai, 1296, Higashitoyo, Shimomatsu, Yamaguchi Prefecture, Toyo Kohan Co., Ltd. Technical Research Laboratory (72) Inventor, Ayu Taniguchi, 1296, 1296, Higashitoyo, Shimomatsu, Yamaguchi Prefecture Toyo Kohan Co., Ltd. Technology In the laboratory

Claims (5)

[Claims] 1. Mn: 0.01 to 1.0% by weight%, M
g: 2.0-6.0%, Si: ≤ as unavoidable impurities
0.3%, Fe: ≤ 0.7%, and (Si + F
e): a step of homogenizing and heat-treating aluminum alloy cast iron with ≤ 0.8%, followed by hot rolling by a conventional method to form a hot-rolled sheet, then cold rolling, and continuous annealing, followed by rolling Rate: a step of secondary cold rolling at 30 to less than 50%, followed by surface treatment, heating the surface-treated aluminum alloy plate, maintaining the plate temperature in the range of 220 to 300 ° C, and heating both sides. A method for producing a resin-coated aluminum alloy sheet for a drawn and ironing can, which comprises a step of coating a plastic resin and a step of quenching after coating. 2. Mn: 0.01 to 1.0% by weight, M
g: 2.0-6.0%, Si: ≤ as unavoidable impurities
0.3%, Fe: ≤ 0.7%, and (Si + F
e): a step of homogenizing heat treatment of aluminum alloy cast iron with ≤0.8%, followed by hot rolling by a conventional method to form a hot rolled sheet, then cold rolling, and continuous annealing, followed by rolling After the secondary cold rolling at a rate of 50 to 80%, 22
Stabilizing and heating at a temperature of 0 to 280 ° C for 1 minute to 5 hours, then performing a surface treatment, heating the surface-treated aluminum alloy plate to a temperature range of 220 to 300 ° C,
A method for producing a resin-coated aluminum alloy sheet for a squeezing and ironing can, which comprises a step of coating a thermoplastic resin on both sides and a step of quenching after coating. 3. The thermoplastic resin to be coated is a thermoplastic polyester resin.
The method for producing a resin-coated aluminum alloy sheet for a drawn and ironed can according to claim 1. 4. The resin-coated aluminum alloy for a drawn and ironing can according to claim 1, wherein the surface treatment applied to the aluminum alloy plate is etching and / or electrolytic chromic acid treatment. Method of manufacturing a plate. 5. The method for producing a resin-coated aluminum alloy plate for a drawn and ironed can according to claim 1, wherein the surface treatment applied to the aluminum alloy plate is a chromic acid chromic acid treatment. Method.