JPH09122653A - Apparatus for producing electrolytic water - Google Patents

Apparatus for producing electrolytic water

Info

Publication number
JPH09122653A
JPH09122653A JP7285393A JP28539395A JPH09122653A JP H09122653 A JPH09122653 A JP H09122653A JP 7285393 A JP7285393 A JP 7285393A JP 28539395 A JP28539395 A JP 28539395A JP H09122653 A JPH09122653 A JP H09122653A
Authority
JP
Japan
Prior art keywords
electrode
compartment
electrolyzed water
diaphragm
power source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7285393A
Other languages
Japanese (ja)
Other versions
JP3667405B2 (en
Inventor
Yutaka Suzuki
裕 鈴木
Kazuyoshi Okada
和義 岡田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoshizaki Electric Co Ltd
Original Assignee
Hoshizaki Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoshizaki Electric Co Ltd filed Critical Hoshizaki Electric Co Ltd
Priority to JP28539395A priority Critical patent/JP3667405B2/en
Publication of JPH09122653A publication Critical patent/JPH09122653A/en
Application granted granted Critical
Publication of JP3667405B2 publication Critical patent/JP3667405B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

PROBLEM TO BE SOLVED: To selectively produce strong acid electrolytic water of pH3 or less and acid-neutral electrolytic water of pH3-7 in one cell by performing electrolysis and electrodialysis selectively in the same electrolytic bath. SOLUTION: The first electrode 13a and the second electrode 13b are arranged in one cell 14a in an electrolytic bath 11, the first electrode 13a and the third electrode 13c are connected to a negative pole side of a direct current power source 15a, the second electrode 13b is connected to the positive side of the direct current power source 15a, and a variable resistor 15c and an opening/closing switch 15b are set in the connection circuit between the direct current power source 15a and the first electrode 13a. By operating the switch 15b, the connection between the first electrode 13a and the direct current power source 15a is connected and disconnected selectively, the electrolysis with a diaphragm, electrolysis without a diaphragm, and electrodialysis of dilute salt water are selected, and electrolytic water having the above characteristics is produced.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、次亜塩素酸、次亜
塩素酸ナトリウム等を主要成分として含有し、殺菌作
用、消毒作用を有するpH3未満の強酸性の電解水と、
pH3〜7の範囲の酸性〜中性の電解水とを選択的に製
造し得る電解水生成装置に関する。
TECHNICAL FIELD The present invention relates to strong acidic electrolyzed water having a pH of less than 3 which contains hypochlorous acid, sodium hypochlorite and the like as main components and has a sterilizing action and a disinfecting action.
The present invention relates to an electrolyzed water generator capable of selectively producing acidic to neutral electrolyzed water having a pH range of 3 to 7.

【0002】[0002]

【従来の技術】次亜塩素酸、次亜塩素酸ナトリウム等を
主要成分として含有し、殺菌作用、消毒作用を有する電
解水を製造するための電解水生成装置の一形式として、
特公平4−42077号公報に示されているように、電
解槽内をイオン透過能を有する隔膜にて区画して形成さ
れた一対の隔室にそれぞれ電極を配置して陽極室と陰極
室とを構成し、これら両電極室に供給される希薄食塩水
を両電極間で有隔膜電解する電解水生成装置がある。当
該電解水生成装置においては、陽極室内で生成される陽
極室側生成水が主として次亜塩素酸を含む強酸性水であ
り、また陰極室内で生成される陰極室側生成水が強アル
カリ性水である。
As a type of electrolyzed water generator for producing electrolyzed water containing hypochlorous acid, sodium hypochlorite, etc. as main components and having a sterilizing action and a disinfecting action,
As disclosed in Japanese Examined Patent Publication (Kokoku) No. 4-42077, an electrode is arranged in each of a pair of compartments formed by partitioning the inside of the electrolytic cell with a diaphragm having ion permeability, and an anode chamber and a cathode chamber are provided. There is an electrolyzed water generator for electrolyzing a dilute saline solution supplied to both electrode chambers with a diaphragm between both electrodes. In the electrolyzed water generator, the anode chamber side generated water generated in the anode chamber is a strongly acidic water containing mainly hypochlorous acid, and the cathode chamber side generated water generated in the cathode chamber is a strong alkaline water. is there.

【0003】[0003]

【発明が解決しようとする課題】しかして、当該電解水
生成装置においては、陽極室側生成水はpHが3未満と
いう強い酸性となる。次亜塩素酸、次亜塩素酸ナトリウ
ム等を主要成分として含む水溶液ではpHが低い程殺菌
力は高く、殺菌力の点からすれば低いpH程好ましい。
しかしながら、殺菌処理、消毒処理の対象によっては、
pHが3〜7の範囲の任意の値の電解水であることが好
ましい場合がある。
In the electrolyzed water producing apparatus, however, the water produced in the anode chamber has a strong acidity of less than 3. In an aqueous solution containing hypochlorous acid, sodium hypochlorite, etc. as main components, the lower the pH, the higher the bactericidal activity, and the lower the pH, the more preferable from the viewpoint of the bactericidal activity.
However, depending on the subject of sterilization and disinfection,
It may be preferable that the pH is electrolyzed water having any value in the range of 3 to 7.

【0004】従って、本発明の目的は、次亜塩素酸、次
亜塩素酸ナトリウム等を主要成分として含有し、殺菌作
用、消毒作用を有するpH3未満の強酸性の電解水と、
pH3〜7の範囲の酸性〜中性の電解水とを選択的に製
造し得る電解水生成装置を提供することにある。
Therefore, an object of the present invention is to provide strong acidic electrolyzed water of pH less than 3 which contains hypochlorous acid, sodium hypochlorite and the like as main components and has a sterilizing action and a disinfecting action.
An object of the present invention is to provide an electrolyzed water generator capable of selectively producing acidic to neutral electrolyzed water having a pH range of 3 to 7.

【0005】[0005]

【課題を解決するための手段】本発明に係る電解水生成
装置は、電解槽内をイオン透過能を有する隔膜にて区画
して形成された一対の隔室のうち、一方の隔室には前記
隔膜に近接して第1の電極を配置するとともに同第1の
電極に対向して所定間隔を保持して第2の電極を配置
し、かつ他方の隔室には第3の1枚の電極を配置してな
り、前記第1の電極と前記第3の電極を直流電源の負極
側に接続するとともに、前記第2の電極を前記直流電源
の正極側に接続し、かつ同直流電源と前記第1の電極と
の接続回路に可変抵抗器と開閉スイッチを介装したこと
を特徴とするものである。
The electrolyzed water producing apparatus according to the present invention includes a pair of compartments formed by partitioning the inside of an electrolytic cell with a diaphragm having ion permeable capacity. The first electrode is arranged in the vicinity of the diaphragm, the second electrode is arranged facing the first electrode with a predetermined space therebetween, and the third electrode is arranged in the other compartment. An electrode is arranged, the first electrode and the third electrode are connected to the negative electrode side of the DC power supply, the second electrode is connected to the positive electrode side of the DC power supply, and A variable resistor and an opening / closing switch are provided in the connection circuit with the first electrode.

【0006】[0006]

【発明の作用・効果】本発明に係る電解水生成装置にお
いては、開閉スイッチの操作により第1の電極の直流電
源に対する接続を断続することができるとともに、第1
の電極の直流電源に対する接続時には、可変抵抗器の操
作により第1の電極および第3の電極に対する電流を調
整することができる。
In the electrolyzed water producing apparatus according to the present invention, the connection of the first electrode to the DC power source can be interrupted by operating the opening / closing switch, and
When connecting the electrode of 1 to the DC power source, the current to the first electrode and the third electrode can be adjusted by operating the variable resistor.

【0007】このため、第1の電極の直流電源に対する
接続を遮断した状態においては、一方の隔室内の第2の
電極が陽極になるとともに他方の隔室内の第3の電極が
陰極となって、これら両電極間で希薄食塩水の有隔膜電
解が行われ、一方の隔室内では強酸性であるpH3未満
の電解水が生成されるとともに、他方の隔室内ではpH
11以上の強アルカリ性の電解水が生成される。
Therefore, when the connection of the first electrode to the DC power source is cut off, the second electrode in one compartment becomes the anode and the third electrode in the other compartment becomes the cathode. , A dilute saline electrolysis is performed between these two electrodes, electrolyzed water having a pH of less than pH 3, which is strongly acidic, is generated in one compartment, and a pH in the other compartment is pH.
Strongly alkaline electrolyzed water of 11 or more is produced.

【0008】また、第1の電極を直流電源に接続した状
態では、第2の電極が陽極になるとともに第1の電極お
よび第3の電極が陰極となり、可変抵抗器の操作によっ
て1の電極および第3の電極に対する電流を調整するこ
とにより、一方の隔室内の第2の電極と第1の電極間で
希薄食塩水の無隔膜電解が行われるとともに、一方の隔
室と他方の隔室間で電気透析が行われる。これにより、
一方の隔室内で無隔膜電解により生成した電解水中のナ
トリウムイオン等陽イオン成分が他方の隔室内へ移行
し、一方の隔室内ではpHが3〜7の範囲の酸性〜中性
の電解水が生成されるとともに、他方の隔室内ではpH
が10〜11のアルカリ性の電解水が生成される。
Further, when the first electrode is connected to the DC power source, the second electrode serves as an anode and the first electrode and the third electrode serve as cathodes, and the first electrode and the third electrode are operated by operating the variable resistor. By adjusting the current to the third electrode, diaphragmless electrolysis of dilute saline solution is performed between the second electrode and the first electrode in one compartment, and between the one compartment and the other compartment. Is electrodialysis. This allows
Cation components such as sodium ions in electrolyzed water generated by non-diaphragm electrolysis in one compartment move to the other compartment, and in one compartment, acidic to neutral electrolyzed water having a pH range of 3 to 7 is produced. As it is produced, the pH in the other compartment
Alkaline electrolyzed water of 10 to 11 is generated.

【0009】このため、開閉スイッチを操作して、第1
の電極の直流電源に対する接続を選択的に断続すること
により、一方の隔室内にてpHが3未満の強酸性の電解
水と、pHが3〜7の酸性〜中性の電解水を選択的に生
成することができる。
Therefore, the first switch is operated by operating the open / close switch.
By selectively interrupting the connection of the electrode of the electrode to the DC power source, the strongly acidic electrolyzed water having a pH of less than 3 and the acidic to neutral electrolyzed water having a pH of 3 to 7 are selectively selected in one compartment. Can be generated.

【0010】[0010]

【発明の実施の形態】以下本発明を図面に基づいて説明
するに、図1には本発明に係る電解水生成装置の一例が
示されている。当該電解水生成装置は、電解槽11、隔
膜12および3枚の電極13a,13b,13cを備え
ている。隔膜12は陽イオンを透過可能なもので、電解
槽11内に配設されて電解槽11内を2つの隔室14
a,14bに区画していており、一方の隔室14aには
第1電極13aと第2電極13bが配設され、かつ他方
の隔室14bには第3電極13cが配設されている。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described below with reference to the drawings. FIG. 1 shows an example of an electrolyzed water producing apparatus according to the present invention. The electrolyzed water producing apparatus includes an electrolytic cell 11, a diaphragm 12, and three electrodes 13a, 13b, 13c. The diaphragm 12 is permeable to cations, and is disposed in the electrolytic cell 11 so that two partition chambers 14 are formed in the electrolytic cell 11.
The first electrode 13a and the second electrode 13b are arranged in one compartment 14a, and the third electrode 13c is arranged in the other compartment 14b.

【0011】第1電極13aは隔膜12に近接して配設
されているとともに、第2電極13bは第1電極13a
とは所定の間隔を保持して対向して配設されていて、隔
膜12とは離れて位置している。また、第3電極13c
は隔膜12から離れて位置して配設されている。第1電
極13aと第3電極13cとは直流電源15aの負極側
に接続され、かつ第2電極13bは直流電源15aの正
極側に接続されている。また、第1電極13aと直流電
源15aの接続回路には開閉スイッチ15bと可変抵抗
器15cが介装されている。
The first electrode 13a is disposed close to the diaphragm 12, and the second electrode 13b is the first electrode 13a.
Are disposed opposite to each other with a predetermined space therebetween, and are located apart from the diaphragm 12. Also, the third electrode 13c
Are arranged apart from the diaphragm 12. The first electrode 13a and the third electrode 13c are connected to the negative electrode side of the DC power supply 15a, and the second electrode 13b is connected to the positive electrode side of the DC power supply 15a. Further, an open / close switch 15b and a variable resistor 15c are interposed in the connection circuit between the first electrode 13a and the DC power supply 15a.

【0012】電解槽11においては、両隔室14a,1
4bに希薄食塩水を供給するための供給管路16a,1
6bと、電解水を流出させるための流出管路17a,1
7bが接続されている。各供給管路16a,16bは供
給ポンプ16cを介して希薄食塩水の貯溜タンク18が
接続されている。また、貯溜タンク18は水道水の供給
源に接続されていて、貯溜タンク18内にて希薄食塩水
の調製が行えるようになっている。なお、符号16d,
16eは開閉バルブを示す。
In the electrolytic cell 11, both compartments 14a, 14a
Supply pipes 16a, 1 for supplying dilute saline to 4b
6b and outflow lines 17a, 1 for outflowing electrolyzed water
7b is connected. A storage tank 18 for dilute saline is connected to each of the supply lines 16a and 16b via a supply pump 16c. Further, the storage tank 18 is connected to a supply source of tap water so that the dilute saline solution can be prepared in the storage tank 18. Note that reference numeral 16d,
Reference numeral 16e indicates an opening / closing valve.

【0013】このように構成した電解水生成装置におい
ては、開閉スイッチ15bの操作により第1電極13a
の直流電源15aに対する接続を断続することができる
とともに、第1電極13aの直流電源15aに対する接
続時には、可変抵抗器15cの操作により第1電極13
aおよび第3電極13cに対する電流を調整することが
できる。従って、当該電解水生成装置においては、開閉
スイッチ15bの操作により、第1電極13aの直流電
源15aに対する接続を遮断した状態と、接続した状態
を選択して、各供給管路16a,16bを通して各隔室
14a,14b内へ供給される希薄食塩水を電解するこ
とができる。
In the electrolyzed water generator thus constructed, the first electrode 13a is operated by operating the open / close switch 15b.
Connection to the DC power supply 15a can be interrupted, and when the first electrode 13a is connected to the DC power supply 15a, the first resistor 13c is operated to operate the first electrode 13a.
The current to the a and the third electrode 13c can be adjusted. Therefore, in the electrolyzed water producing apparatus, the open / close switch 15b is operated to select a state in which the connection of the first electrode 13a to the DC power source 15a is cut off or a state in which the first electrode 13a is disconnected, and the connection is performed through the supply pipelines 16a and 16b. The dilute saline solution supplied into the compartments 14a and 14b can be electrolyzed.

【0014】当該電解水生成装置において、第1電極1
3aの直流電源15aに対する接続を遮断した状態にお
いては、一方の隔室14a内の第2電極13bが陽極に
なるとともに他方の隔室14b内の第3電極13cが陰
極となって、これら両電極間13b,13cで希薄食塩
水の有隔膜電解が行われる。かかる電解は希薄食塩水の
通常の有隔膜電解であって、一方の隔室14a内では強
酸性であるpH3未満の電解水が生成されるとともに、
他方の隔室14b内ではpH11以上の強アルカリ性の
電解水が生成される。
In the electrolyzed water producing apparatus, the first electrode 1
In the state where the connection of 3a to the DC power supply 15a is cut off, the second electrode 13b in one compartment 14a serves as an anode and the third electrode 13c in the other compartment 14b serves as a cathode. Diaphragm electrolysis of dilute saline solution is performed between the spaces 13b and 13c. Such electrolysis is a normal diaphragm electrolysis of dilute saline, and in one compartment 14a, electrolyzed water having a pH of less than 3, which is strongly acidic, is generated,
Strong alkaline electrolyzed water having a pH of 11 or more is produced in the other compartment 14b.

【0015】また、第1電極13aを直流電源15aに
接続した状態では、第2電極13bが陽極になるととも
に第1電極13aおよび第3電極13cが陰極となり、
可変抵抗器15cの操作によって第1電極13aおよび
第3電極13cに対する電流を調整することにより、一
方の隔室14a内の第2電極13bと第1電極13a間
で希薄食塩水の無隔膜電解が行われるとともに、一方の
隔室14aと他方の隔室14b間で電気透析が行われ
る。
When the first electrode 13a is connected to the DC power supply 15a, the second electrode 13b serves as an anode and the first electrode 13a and the third electrode 13c serve as cathodes.
By adjusting the currents to the first electrode 13a and the third electrode 13c by operating the variable resistor 15c, the diaphragmless electrolysis of dilute saline solution can be performed between the second electrode 13b and the first electrode 13a in one compartment 14a. At the same time, electrodialysis is performed between the one compartment 14a and the other compartment 14b.

【0016】一方の隔室14aにおける電解は希薄食塩
水の通常の無隔膜電解であって、第3電極13cが第1
電極13aに対して電位が低くなり、一方の隔室14a
内で生成したナトリウムイオン等の陽イオン成分が他方
の隔室14b内へ移動する。両隔室14a,14b内の
電解水のpHは、この陽イオン成分の移動量に対応して
調整される。
The electrolysis in one compartment 14a is a normal diaphragmless electrolysis of dilute saline, in which the third electrode 13c is the first.
The potential becomes lower than that of the electrode 13a, and one of the compartments 14a
Cation components such as sodium ions generated inside move into the other compartment 14b. The pH of the electrolyzed water in both compartments 14a and 14b is adjusted according to the amount of migration of this cation component.

【0017】一方の隔室14a内からの陽イオン成分の
他方の隔室14b内への移動量は第2電極13bと第3
電極13c間に付与される電流値に対応するもので、こ
の電流値は可変抵抗器15cの抵抗値を変更することに
より変更することができる。このため、可変抵抗器15
cの抵抗値を変更することにより、一方の隔室14a内
の陽イオン成分の他方の隔室14b内への移動量を変更
して、一方の隔室14a内で生成される電解水のpHを
3〜7の範囲の任意の値に調整することができる。
The amount of movement of the cation component from one compartment 14a to the other compartment 14b is determined by the second electrode 13b and the third compartment.
It corresponds to the current value applied between the electrodes 13c, and this current value can be changed by changing the resistance value of the variable resistor 15c. Therefore, the variable resistor 15
By changing the resistance value of c, the transfer amount of the cation component in the one compartment 14a into the other compartment 14b is changed, and the pH of the electrolyzed water generated in the one compartment 14a is changed. Can be adjusted to any value in the range 3-7.

【0018】このため、当該電解水生成装置において
は、開閉スイッチ15bを操作して、第1電極13aの
直流電源15aに対する接続を選択的に断続することに
より、一方の隔室14a内にpHが3未満の強酸性の電
解水と、pHが3〜7の酸性〜中性の電解水を選択的に
生成することができる。なお、各隔室14a,14b内
で生成された電解水は流出管路17a,17bを通して
外部へ流出される。
Therefore, in the electrolyzed water producing apparatus, the opening / closing switch 15b is operated to selectively disconnect the connection of the first electrode 13a to the DC power source 15a, whereby the pH in one compartment 14a is increased. Strongly acidic electrolyzed water of less than 3 and acidic to neutral electrolyzed water of pH 3 to 7 can be selectively produced. The electrolyzed water generated in each of the compartments 14a and 14b flows out to the outside through the outflow pipes 17a and 17b.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一例に係る電解水生成装置の概略構成
図である。
FIG. 1 is a schematic configuration diagram of an electrolyzed water generator according to an example of the present invention.

【符号の説明】[Explanation of symbols]

11…電解槽、12…隔膜、13a,13b,13c…
電極、14a,14b…隔室、15a…直流電源、15
b…開閉スイッチ、15c…可変抵抗器、16a,16
b…塩水の供給管路、17a,17b…生成水の流出管
路。
11 ... Electrolyzer, 12 ... Diaphragm, 13a, 13b, 13c ...
Electrodes, 14a, 14b ... Compartments, 15a ... DC power supply, 15
b ... open / close switch, 15c ... variable resistor, 16a, 16
b ... salt water supply pipeline, 17a, 17b ... produced water outflow pipeline.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】電解槽内をイオン透過能を有する隔膜にて
区画して形成された一対の隔室のうち、一方の隔室には
前記隔膜に近接して第1の電極を配置するとともに同第
1の電極に対向して所定間隔を保持して第2の電極を配
置し、かつ他方の隔室には第3の1枚の電極を配置して
なり、前記第1の電極と前記第3の電極を直流電源の負
極側に接続するとともに、前記第2の電極を前記直流電
源の正極側に接続し、かつ同直流電源と前記第1の電極
との接続回路に可変抵抗器と開閉スイッチを介装したこ
とを特徴とする電解水生成装置。
1. A pair of compartments formed by partitioning the inside of an electrolytic cell with a diaphragm having ion permeability, and one compartment is provided with a first electrode in proximity to the diaphragm. The second electrode is arranged so as to face the first electrode at a predetermined distance, and the third one electrode is arranged in the other compartment, and the third electrode is arranged between the first electrode and the first electrode. The third electrode is connected to the negative electrode side of the DC power supply, the second electrode is connected to the positive electrode side of the DC power supply, and a variable resistor is provided in the connection circuit between the DC power supply and the first electrode. An electrolyzed water generator characterized in that an open / close switch is interposed.
JP28539395A 1995-11-01 1995-11-01 Electrolyzed water generator Expired - Fee Related JP3667405B2 (en)

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JP28539395A JP3667405B2 (en) 1995-11-01 1995-11-01 Electrolyzed water generator

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JP2011206697A (en) * 2010-03-30 2011-10-20 Mitsubishi Electric Corp Reactive oxygen species generation device
JP5210456B1 (en) * 2012-11-20 2013-06-12 日科ミクロン株式会社 Wash water generator
JP5210455B1 (en) * 2012-11-20 2013-06-12 日科ミクロン株式会社 Wash water generator
EP2625317A2 (en) * 2010-10-08 2013-08-14 Ceramatec, Inc Electrochemical systems and methods for operating electrochemical cell with an acidic anolyte
WO2017200772A1 (en) * 2016-05-17 2017-11-23 Cryovac, Inc. Alkaline and chlorine solutions produced using electro-chemical activation
JP2019141807A (en) * 2018-02-22 2019-08-29 国立大学法人弘前大学 Lithium recovery device and lithium recovery method
US10900132B2 (en) 2017-01-26 2021-01-26 Diversey, Inc. Neutralization in electro-chemical activation systems
CN114163032A (en) * 2020-12-10 2022-03-11 佛山市美的清湖净水设备有限公司 Water purification unit's waterway system and have its water purification unit

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011206697A (en) * 2010-03-30 2011-10-20 Mitsubishi Electric Corp Reactive oxygen species generation device
EP2625317A2 (en) * 2010-10-08 2013-08-14 Ceramatec, Inc Electrochemical systems and methods for operating electrochemical cell with an acidic anolyte
EP2625317A4 (en) * 2010-10-08 2014-05-14 Ceramatec Inc Electrochemical systems and methods for operating electrochemical cell with an acidic anolyte
JP5210456B1 (en) * 2012-11-20 2013-06-12 日科ミクロン株式会社 Wash water generator
JP5210455B1 (en) * 2012-11-20 2013-06-12 日科ミクロン株式会社 Wash water generator
WO2017200772A1 (en) * 2016-05-17 2017-11-23 Cryovac, Inc. Alkaline and chlorine solutions produced using electro-chemical activation
US11326261B2 (en) 2016-05-17 2022-05-10 Diversey, Inc. Alkaline and chlorine solutions produced using electro-chemical activation
US10900132B2 (en) 2017-01-26 2021-01-26 Diversey, Inc. Neutralization in electro-chemical activation systems
JP2019141807A (en) * 2018-02-22 2019-08-29 国立大学法人弘前大学 Lithium recovery device and lithium recovery method
CN114163032A (en) * 2020-12-10 2022-03-11 佛山市美的清湖净水设备有限公司 Water purification unit's waterway system and have its water purification unit

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