JPH08500270A - 繊維に対する粒子結合 - Google Patents
繊維に対する粒子結合Info
- Publication number
- JPH08500270A JPH08500270A JP6506513A JP50651394A JPH08500270A JP H08500270 A JPH08500270 A JP H08500270A JP 6506513 A JP6506513 A JP 6506513A JP 50651394 A JP50651394 A JP 50651394A JP H08500270 A JPH08500270 A JP H08500270A
- Authority
- JP
- Japan
- Prior art keywords
- particles
- binder
- fibers
- fiber
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
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- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/02—Adhesive plasters or dressings
- A61F13/0203—Adhesive plasters or dressings having a fluid handling member
- A61F13/0206—Adhesive plasters or dressings having a fluid handling member the fluid handling member being absorbent fibrous layer, e.g. woven or nonwoven absorbent pad, island dressings
- A61F13/0209—Adhesive plasters or dressings having a fluid handling member the fluid handling member being absorbent fibrous layer, e.g. woven or nonwoven absorbent pad, island dressings comprising superabsorbent material
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- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
-
- A—HUMAN NECESSITIES
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- A61F13/00—Bandages or dressings; Absorbent pads
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- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
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- A—HUMAN NECESSITIES
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- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/288—Phosphonic or phosphonous acids or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
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Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.粒子を結合剤で繊維に結合する方法であって、 水素結合官能基を有する繊維を含む繊維質材料を用意し; 水素結合または配位共有結合形成官能基を有する粒子を用意し; ポリグリコール、ポリカルボン酸、ポリカルボキシレート、ポリ(ラクトン) ポリオール、ポリアミド、ポリアミン、ポリスルホン酸、ポリスルホネートおよ びこれらの組み合わせからなる群より選択される高分子結合剤、水より低い揮発 度を有する非高分子結合剤、および、それらの相互もしくは他の結合剤との非反 応性組み合わせからなる群から、粒子と水素結合または配位共有結合を形成する ことのできる少なくとも一つの官能基と繊維質材料と水素結合を形成することの できる少なくとも一つの官能基とを有する結合剤分子を含む結合剤を選択し; 前記結合剤で前記粒子を少なくとも一部被覆するために十分な結合剤の量に前 記粒子を暴露し; 前記粒子を前記繊維質材料に結合する、 各工程を含む方法。 2.前記官能基が、各々、水素結合を形成することのできる、請求項1に記載の 方法。 3.請求項1の方法によって製造される繊維質製品。 4.前記結合剤が高分子結合剤である、請求項1に記載の方法。 5.前記結合剤が、ポリアミン、ポリカルボン酸およびポリアミドからなる群よ り選択される、請求項4に記載の方法。 6.前記結合剤がポリペプチドである、請求項4に記載の方法。 7.前記結合剤が、非高分子有機結合剤である、請求項1に記載の方法。 8.前記非高分子有機結合剤が、カルボキシル、カルボキシレート、カルボニル 、スルホン酸、スルホネート、ヒドロキシル、リン酸、ホスフェート、アミド、 アミンおよびこれらの組み合わせからなる群より選択される官能基を有する、請 求項7に記載の方法。 9.前記非高分子有機結合剤が、グリセリン、グリセリンモノエステル、グリ セリンジエステル、グリオキサール、アスコルビン酸、尿素、グリシン、ぺンタ エリスリトール、モノサッカライド、ジサッカライド、クエン酸、タウリン、酒 石酸、ジプロピレングリコール、尿素誘導体およびこれらの組み合わせからなる 群より選択される、請求項8に記載の方法。 10.前記非高分子有機結合剤が、グリセリン、グリセリンモノエステル、グリ セリンジエステル、尿素およびこれらの組み合わせからなる群より選択される、 請求項9に記載の方法。 11.前記結合剤が、粒子の重量の約0.01〜50%量存在し、前記粒子が、 繊維質材料および粒子の総重量の0.05〜80%量存在する、請求項1に記載 の方法。 12.前記結合剤が、粒子の重量の約0.03〜20%量存在する、請求項1に 記載の方法。 13.前記結合剤が、粒子の重量の約0.03〜5%量存在する、請求項1に記 載の方法。 14.前記粒子を結合剤に暴露する工程が、粒子を繊維質粒子と合わせつつ、粒 子を結合剤に暴露する工程を含む、請求項1に記載の方法。 15.前記粒子を結合剤に暴露する工程が、繊維質材料の不在で粒子上に結合剤 を付与し、結合剤が不活性状態であることを想定し、ついで、繊維に、熱、活性 化流体を付与するか、または、粒子の存在で、運動エネルギーを粒子または繊維 に加えるか、あるいは、活性化流体を繊維上に存在させつつ、繊維に粒子を加え ることによって、不活性状態より結合剤を活性化することを含む、請求項1に記 載の方法。 16.前記非高分子結合剤が、カルボキシル、カルボキシレート、カルボニル、 スルホン酸、スルホネート、ホスフェート、リン酸、ヒドロキシル、アミン、ア ミドおよびこれらの組み合わせからなる群より選択される官能基を含む、請求項 15に記載の方法。 17.この群より選択される分子上に少なくとも2個の官能基が存在し、この2 個の官能基が、同一であっても、異なっていてもよい、請求項16に記載の方 法。 18.前記結合剤が、ポリグリコール、ポリ(ラクトン)ポリオール、ポリカル ボン酸、ポリアミド、ポリアミンおよびこれらのコポリマー類からなる群より選 択される、請求項15に記載の方法。 19.前記繊維が、湿式レイ繊維シートまたはウエブ製造ラインにおける木材パ ルプ繊維であり、前記結合剤被覆粒子が前記繊維と合わされる、請求項1に記載 の方法。 20.前記粒子を結合剤に暴露する工程が、繊維質の不在で粒子上に結合剤を付 与し、結合剤が不活性状態であることを想定し、ついで、結合剤被覆粒子を繊維 質材料と合わせる前、合わせると同時、あるいは、合わせた後に、活性化流体を 加えることによって、不活性状態より結合剤を活性化することを含む、請求項1 に記載の方法。 21.前記活性化流体が、液体、蒸気または湿潤ガスの形態の水である、請求項 20に記載の方法。 22.前記結合剤が、ポリ(ラクトン)ポリオール、ポリカルボン酸、ポリアミ ド、ポリアミンおよびこれらのコポリマーからなる群より選択される、請求項1 に記載の方法。 23.さらに、架橋剤の存在中で硬化されて、繊維内共有架橋を有する嵩高い繊 維を生成させ、繊維が、繊維化されて、硬化された繊維間の繊維間結合を低下さ せられ、個々に細分化された、水素結合官能性部位を有するセルロース繊維を生 成し; 前記粒子を繊維質材料に結合させる工程が、繊維が硬化されて、前記粒子が前 記繊維に結合する前、間、または、後に、粒子を繊維に加える工程を含む、請求 項1に記載の方法。 24.前記硬化工程が、いずれかの架橋材料を使用し、結合剤被覆粒子および硬 化された繊維質材料を合わせる前に、前記架橋材料を硬化させることを含む、請 求項23に記載の方法。 25.前記粒子が超吸収性粒子を含む、請求項1に記載の方法。 26.前記粒子が超吸収性粒子を含む、請求項23に記載の方法。 27.外部圧力を繊維に加えることによって前記繊維および前記結合された粒子 を圧縮含浸する工程を含む、請求項1に記載の方法。 28.前記粒子が超吸収性粒子である、請求項27に記載の方法。 29.前記粒子が超吸収性粒子であり、前記結合剤が活性状態である、請求項2 7に記載の方法。 30.外部圧力をウエブまたはシートに加えることによって、ウエブまたはシー トを圧縮含浸するような圧縮含浸工程の前に、繊維をウエブまたはシートに成形 する工程を含む、請求項27に記載の方法。 31.さらに、外部圧力を繊維に加えることによって、繊維および結合された粒 子を圧縮含浸する工程を含む、請求項23に記載の方法。 32.前記粒子が超吸収性粒子である、請求項31に記載の方法。 33.前記粒子が超吸収性粒子であり、前記結合剤が活性状態である、請求項3 1に記載の方法。 34.前記圧縮含浸工程が、繊維および接着された粒子を周囲温度下で圧縮含浸 することを含む、請求項29または33に記載の方法。 35.前記圧縮含浸工程が、圧力をウエブまたはシートに加えて、密度約0.0 5g/cc〜約0.7g/ccを有する生成物を生成する、請求項29または33に記 載の方法。 36.前記粒子が、水に可溶であり、結合剤にわずかに可溶である、請求項1に 記載の方法。 37.前記粒子が、25℃で水300mlに少なくとも10gの溶解度を有し、2 5℃で結合剤300mlに約5g以下の溶解度を有する、請求項1に記載の方法。 38.前記粒子が、実質的に、水および結合剤に可溶である、請求項1に記載の 方法。 39.さらに、熱、活性化流体を付与するか、または、粒子の存在で、粒子また は繊維に、運動エネルギーを加えるか、あるいは、活性化流体を繊維上に存在さ せつつ、繊維に粒子を加えることによって、不活性状態より粒子上の結合剤を 活性化する工程を含む、請求項37に記載の方法。 40.水素結合官能基を有する繊維を含む繊維質材料; 水素結合または配位共有結合形成官能基を有する粒子; ポリグリコール、ポリカルボン酸、ポリカルボキシレート、ポリ(ラクトン) ポリオール、ポリアミド、ポリアミン、ポリスルホン酸、ポリスルホネートおよ びこれらの組み合わせからなる群より選択される高分子結合剤、水より低い揮発 度を有する非高分子結合剤、および、それらの相互もしくは他の結合剤とのひ反 応性組み合わせからなる群から、粒子と水素結合または配位共有結合を形成する ことのできる少なくとも一つの官能基と繊維質材料と水素結合を形成することの できる少なくとも一つの官能基とを有する結合剤分子を含む結合剤; を含み、 前記結合剤が、主として、前記粒子上に存在し、前記粒子が、前記繊維質材料 に結合している、繊維質製品。 41.前記結合剤が、ポリアミン、ポリカルボン酸およびポリアミドからなる群 より選択される、請求項40に記載の製品。 42.前記非高分子有機結合剤が、カルボキシル、カルボキシレート、カルボニ ル、スルホン酸、スルホネート、ヒドロキシル、リン酸、ホスフェート、アミド 、アミンおよびこれらの組み合わせからなる群より選択される官能基を有する、 請求項40に記載の製品。 43.前記非高分子有機結合剤が、グリセリン、グリセリンモノエステル、グリ セリンジエステル、グリオキサール、アスコルビン酸、尿素、グリシン、ぺンタ エリスリトール、モノサッカライド、ジサッカライド、クエン酸、タウリン、酒 石酸、ジプロピレングリコール、尿素誘導体およびこれらの組み合わせからなる 群より選択される、請求項40に記載の製品。 44.前記非高分子有機結合剤が、グリセリン、グリセリンモノエステル、グリ セリンジエステル、尿素およびこれらの組み合わせからなる群より選択される、 請求項40に記載の製品。 45.前記結合剤が、ポリグリコール、ポリ(ラクトン)ポリオール、ポリカ ルボン酸、ポリアミド、ボリアミンおよびこれらのコポリマー類からなる群より 選択される、請求項40に記載の製品。 46.前記粒子が、水に可溶であり、結合剤にわずかに可溶である、請求項40 に記載の製品。 47.前記粒子が超吸収性粒子を含む、請求項40に記載の製品。 48.密度0.05〜0.7g/ccを有するウエブの形態の、請求項40に記載の 製品。 49.繊維が水素結合官能性を有する繊維内共有結合を有する個々に細分化され た嵩高い繊維; 粒子が水素結合または配位共有結合官能基を有し、水素結合または配位共有結 合を形成することのできる少なくとも一つの官能基と水素結合を形成することの できる少なくとも一つの官能基とを有する結合剤分子を含む結合剤である、主と して粒子上に存在する結合剤で少なくとも一部被覆され、前記結合剤の存在で前 記繊維に結合する前記結合された粒子0.05〜80%を含む、請求項40に記 載の繊維質製品。 50.密度0.05〜0.7g/ccを有する、請求項49に記載の製品。 51.粒子を結合剤で繊維に結合する方法であって、 水素結合官能基を有する繊維を含む繊維質材料を用意し; 水素結合または配位共有結合形成官能基を有する粒子を用意し; ポリグリコール、ポリカルボン酸、ポリカルボキシレート、ポリ(ラクトン) ポリオール、ポリアミド、ポリアミン、ポリスルホン酸、ポリスルホネートおよ びこれらの組み合わせからなる群より選択され、繰り返し単位を有する高分子結 合剤、水より低い揮発度を有する非高分子結合剤、および、それらの相互もしく は他の結合剤との非反応性組み合わせからなる群から、粒子と水素結合または配 位共有結合を形成することのできる少なくとも一つの官能基と繊維質材料と水素 結合を形成することのできる少なくとも一つの官能基とを有する結合剤分子を含 む結合剤を選択し; 前記粒子を前記繊維質材料に結合するに十分な量、前記粒子上に結合剤を噴霧 して、前記粒子を前記繊維質材料と合わせる、 各工程を含む方法。 52.粒子を結合剤で繊維に結合する方法であって、 水素結合官能基を有する繊維を含む繊維質材料を用意し; 水素結合または配位共有結合形成官能基を有する粒子を用意し; ポリグリコール、ポリカルボン酸、ポリカルボキシレート、ポリ(ラクトン) ポリオール、ポリアミド、ポリアミン、ポリスルホン酸、ポリスルホネートおよ びこれらの組み合わせからなる群より選択される結合剤分子を有する高分子結合 剤、水より低い揮発度を有する非高分子結合剤、および、それらの相互もしくは 他の結合剤との非反応性組み合わせからなる群から、粒子と水素結合または配位 共有結合を形成することのできる少なくとも一つの官能基と繊維質材料と水素結 合を形成することのできる少なくとも一つの官能基とを有する結合剤分子を含む 結合剤を選択し; 前記粒子を十分な量の結合剤と合わせ、非共有結合を形成するのに好ましい条 件下、合わせた粒子および結合剤を繊維質材料に導入して前記粒子を前記繊維質 材料に結合する、 各工程を含む方法。 53.前記繊維質材料を生成する工程が、架橋剤の存在中で硬化されて、繊維内 共有架橋を有する嵩高い繊維を生成する水素結合官能部位を有する個々に細分化 されたセルロース繊維を生成する工程を含む、請求項52に記載の方法。 54.水素結合官能部位で繊維に付着する結合剤被覆粒子であって、 水素結合官能部位または配位共有結合官能部位を有する粒子;および、 水よりも低い揮発度を有し、繊維質材料と水素結合を形成することのできる少 なくとも一つの官能基と粒子と水素結合または配位共有結合を形成することので きる少なくとも一つの官能基とを有し、前記粒子を前記繊維に結合するに十分な 量存在し、活性化された後、前記粒子の少なくとも0.03重量%量である結合 剤を有する結合剤被覆粒子。 55.水素結合官能部位で繊維質材料に付着する結合剤被覆粒子であって、 水素結合官能部位または配位共有結合官能部位である少なくとも一つの官能部 位を有する粒子;および、 グリセリン、グリセリンモノエステル、グリセリンジエステル、尿素およびこ れらの組み合わせからなる群より選択され、水よりも低い揮発度を有し、粒子と 水素結合または配位共有結合を形成することのできる少なくとも一つの官能基と 繊維質材料と水素結合を形成することのできる少なくとも一つの官能基とを有す る結合剤分子を含む結合剤を含む結合剤被覆粒子。 56.前記高分子結合剤が、繰り返し単位を含み、この各繰り返し単位が、繊維 質材料と水素結合を形成することのできる少なくとも一つの官能基と粒子と水素 結合または配位共有結合を形成することのできる少なくとも一つの官能基とを有 する、請求項1に記載の方法。 57.少なくとも一つの水素結合官能基または配位結合官能基を有する粒子;お よび、 グリセリン、グリセリンモノエステル、グリセリンジエステル、尿素およびこ れらの組み合わせからなる群より選択され、水よりも低い揮発度を有し、粒子と 水素結合または配位共有結合を形成することのできる少なくとも一つの官能基と 繊維質材料と水素結合を形成することのできる少なくとも一つの官能基とを有す る結合剤分子を含む結合剤を含み、 前記結合剤の有効量が、粒子の表面上にあって、粒子を前記繊維質材料に結合 する結合剤被覆粒子。 58.請求項12、15、19、20、21、23、25、26、31、32、 36、39、51、52または53の方法によって製造される繊維製品。 59.請求項40、41、43、44、46、47、48または49の繊維製品 によって構成される吸収性物品。
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US07/931,279 US5589256A (en) | 1992-08-17 | 1992-08-17 | Particle binders that enhance fiber densification |
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US07/931,278 US5352480A (en) | 1992-08-17 | 1992-08-17 | Method for binding particles to fibers using reactivatable binders |
US07/931,059 US5543215A (en) | 1992-08-17 | 1992-08-17 | Polymeric binders for binding particles to fibers |
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US07/931,277 US5538783A (en) | 1992-08-17 | 1992-08-17 | Non-polymeric organic binders for binding particles to fibers |
US07/931,284 US5308896A (en) | 1992-08-17 | 1992-08-17 | Particle binders for high bulk fibers |
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AT (3) | ATE224808T1 (ja) |
AU (2) | AU5019893A (ja) |
BR (2) | BR9306920A (ja) |
CA (2) | CA2140264C (ja) |
DE (3) | DE69333678T2 (ja) |
ES (3) | ES2182830T3 (ja) |
NZ (2) | NZ255814A (ja) |
WO (2) | WO1994004351A1 (ja) |
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- 1993-08-16 EP EP20020006487 patent/EP1217120A1/en not_active Withdrawn
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- 1993-08-16 JP JP50651494A patent/JP3539957B2/ja not_active Expired - Fee Related
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JP2013512990A (ja) * | 2009-12-02 | 2013-04-18 | ハンツマン ペトロケミカル エルエルシー | 高分子量分散剤組成物の製造および使用 |
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