JPH083542A - Abrasive material - Google Patents

Abrasive material

Info

Publication number
JPH083542A
JPH083542A JP6135317A JP13531794A JPH083542A JP H083542 A JPH083542 A JP H083542A JP 6135317 A JP6135317 A JP 6135317A JP 13531794 A JP13531794 A JP 13531794A JP H083542 A JPH083542 A JP H083542A
Authority
JP
Japan
Prior art keywords
abrasive
resin
epoxy resin
novolac type
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6135317A
Other languages
Japanese (ja)
Inventor
Katsuya Iida
勝也 飯田
Hiroaki Nishihara
宏招 西原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Bakelite Co Ltd
Original Assignee
Sumitomo Bakelite Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Bakelite Co Ltd filed Critical Sumitomo Bakelite Co Ltd
Priority to JP6135317A priority Critical patent/JPH083542A/en
Publication of JPH083542A publication Critical patent/JPH083542A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain an abrasive material high in abrasive power, high in the roughness of a molded product surface abraded, thus suitable for removing burrs developed during the molding process for electronic parts or plastic molded products (esp., resin-sealed ICs or LSIs). CONSTITUTION:This abrasive material is obtained by grinding a cured product obtained by hot-pressing a thermosetting resin composition, a homogeneous blend comprising 10-35wt.% of an epoxy resin, 5-20wt.% of a novolak-type phenolic resin, and 45-85wt.% of silica powder.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、電子部品、プラスチッ
ク製品等の成形時に発生するバリを除去するため好適な
研磨材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an abrasive suitable for removing burrs generated during molding of electronic parts, plastic products and the like.

【0002】[0002]

【従来の技術】従来、成形品のバリ除去などの後処理用
の研磨材としては、アルミナ、炭化珪素、ガラス等の硬
質材料や、ナイロン、ポリカーボネート、くるみ殻粉等
の軟質材料が主に使用されている。この他に最近は上記
硬質材料と軟質材料の中間特性を有する熱硬化性樹脂硬
化物の研磨材も開発されてきた。この熱硬化性樹脂硬化
物材料は従来の材料にはない硬度を有し、かなり使用さ
れるようになってきている。しかし、年々成形品の用途
は多種多様化しており、研磨材に要求される特性も厳し
くなり、多様化している。特に電気部品関連の成形品で
は寸法精度など要求特性は厳しく、それへの対応も種々
検討されている。
2. Description of the Related Art Conventionally, hard materials such as alumina, silicon carbide, and glass, and soft materials such as nylon, polycarbonate, and walnut shell powder have been mainly used as abrasives for post-treatment such as deburring of molded products. Has been done. In addition to these, recently, an abrasive of a thermosetting resin cured product having intermediate characteristics between the hard material and the soft material has been developed. This thermosetting resin cured material has a hardness that conventional materials do not have, and has come to be used considerably. However, the applications of molded products have been diversified year by year, and the characteristics required for abrasives have become strict and diversified. Especially for molded products related to electric parts, required characteristics such as dimensional accuracy are strict, and various measures are being taken to meet them.

【0003】[0003]

【発明が解決しようとする課題】本発明者はこのような
観点から成形品を後処理するための研磨材を種々検討
し、適切な硬度、研磨性及び耐久性を有する研磨材を完
成させたものである。
The present inventor examined various abrasives for post-treating a molded product from such a viewpoint, and completed an abrasive having appropriate hardness, abrasivity and durability. It is a thing.

【0004】[0004]

【課題を解決するための手段】本発明は、エポキシ樹脂
10〜35重量%、ノボラック型フェノール樹脂5〜2
0重量%及びシリカ粉末45〜85重量%を均一に混合
した熱硬化性樹脂組成物を加熱加圧硬化し、その硬化物
を粉砕することにより得られた研磨材に関するものであ
り、適切な硬度、研磨性及び耐久性を有するものであ
る。
DISCLOSURE OF THE INVENTION The present invention comprises 10 to 35% by weight of an epoxy resin and 5 to 2 novolac type phenolic resins.
The present invention relates to an abrasive obtained by heating and pressurizing a thermosetting resin composition obtained by uniformly mixing 0% by weight and 45 to 85% by weight of silica powder, and pulverizing the cured product. It has abrasiveness and durability.

【0005】研磨材は従来、金属製品、プラスチック製
品等のバリ除去、付着物除去、表面処理等に使用され、
その被研磨物の品質と研磨目的によって無機質研磨材、
有機質研磨材、金属研磨材等が使用されてきた。最近は
被研磨物の素材も多様化し、形状も複雑なものがあり、
既存の研磨材では適合できないものも生じてきた。本発
明の研磨材は良好な研磨力を有し、さらにアルミナ等の
無機研磨材に比較して適度な柔軟性を有することから被
研磨物を傷つけず、耐久性の良好な特性を有するもので
ある。
Abrasives have hitherto been used for removing burrs from metal products, plastic products, etc., removing deposits, surface treatments, etc.
An inorganic abrasive, depending on the quality of the object to be polished and the purpose of polishing,
Organic abrasives, metal abrasives, etc. have been used. Recently, the materials to be polished are diversified and the shapes are complicated,
Some have not been compatible with existing abrasives. The abrasive of the present invention has good polishing power and further has appropriate flexibility as compared with inorganic abrasives such as alumina, so that it does not damage the object to be polished and has good durability characteristics. is there.

【0006】本発明の研磨材の有機結合剤成分であるエ
ポキシ樹脂は適度な弾性を有し靭性の高いものであり、
充填材との結合力も極めて良好である。シリカ粉末はそ
れ自体研磨材として使用される場合もあるが、研磨力が
強すぎ、被研磨物を傷つける恐れが大きい。本発明の研
磨材はシリカの研磨力を生かし、これをエポキシ樹脂と
結合させることにより、被研磨物を傷つけることがない
という特長を有するものである。
The epoxy resin, which is the organic binder component of the abrasive of the present invention, has appropriate elasticity and high toughness,
The binding force with the filler is also very good. The silica powder itself may be used as an abrasive, but its polishing power is too strong and there is a great risk of damaging the object to be polished. The abrasive of the present invention has the feature that it does not damage the object to be polished by utilizing the polishing power of silica and binding it with an epoxy resin.

【0007】このように、本発明の研磨材は、素材であ
るエポキシ樹脂組成物中にシリカ粉末を45〜85重量
%含有しているので、研磨性が優れ、被研磨物の損傷も
なく、耐久性が良好である。即ち、研磨材組成を上記の
如き複合組成とすることにより、無機研磨材の研磨力と
有機研磨材の柔軟性を併せ有するものである。
As described above, since the abrasive material of the present invention contains 45 to 85% by weight of silica powder in the epoxy resin composition as a raw material, it has excellent abrasiveness and does not damage the object to be abraded. Good durability. That is, by using the above-mentioned composite composition as the abrasive composition, it has both the polishing power of the inorganic abrasive and the flexibility of the organic abrasive.

【0008】樹脂成分はエポキシ樹脂とノボラック型フ
ェノール樹脂とからなるが、組成物中15〜55重量%
である。15重量%未満ではシリカ分が多くて研磨力が
強くなり過ぎ、結合力が不足するので耐久性が劣るよう
になる。55重量%を越えると研磨力が低下するように
なる。エポキシ樹脂は靭性及び結合力の点で、ノボラッ
ク型又はビフェノール型エポキシ樹脂が好ましく、特に
クレゾールノボラック型エポキシ樹脂が好ましい。一
方、ノボラック型フェノール樹脂は柔軟性の優れたアル
キルフェノール、アルキルベンゼン又はジシクロペンタ
ジエン変性ノボラック型フェノール樹脂が好ましい。
The resin component consists of an epoxy resin and a novolac type phenol resin, and is 15 to 55% by weight in the composition.
Is. If it is less than 15% by weight, the silica content is large and the polishing force becomes too strong, and the bonding force becomes insufficient, resulting in poor durability. If it exceeds 55% by weight, the polishing power will decrease. The epoxy resin is preferably a novolac type or biphenol type epoxy resin from the viewpoint of toughness and bonding strength, and particularly preferably a cresol novolac type epoxy resin. On the other hand, the novolac type phenolic resin is preferably an alkylphenol, alkylbenzene or dicyclopentadiene modified novolac type phenolic resin having excellent flexibility.

【0009】本発明の研磨材の粒度は、通常60〜10
00μmの範囲内であるが、100〜800μmが好ま
しい。この粒径より小さいものは研磨力が小さく、粒径
が大きすぎると被研磨物を傷つける恐れが生じてくる。
The grain size of the abrasive of the present invention is usually 60 to 10.
It is in the range of 00 μm, but preferably 100 to 800 μm. If the particle size is smaller than this, the polishing power is small, and if the particle size is too large, the object to be polished may be damaged.

【0010】[0010]

【実施例】下記の配合の組成物をトランスファ成形機に
て175℃、3分間成形して得た硬化物を粉砕し、微粉
を除去して粒度200〜400μmの研磨材を製造し
た。 クレゾールノボラック型エポキシ樹脂 20重量部 ノボラック型フェノール樹脂 10 シリカ粉末(平均粒径15μm) 70 ワックス 0.3 カーボンブラック 0.2 得られた研磨材は真比重 1.9、硬度(ロックウェル・
Mスケール)110であった。
EXAMPLE A composition having the following composition was molded by a transfer molding machine at 175 ° C. for 3 minutes to obtain a hardened material, which was crushed to remove fine powder to produce an abrasive having a particle size of 200 to 400 μm. Cresol novolac type epoxy resin 20 parts by weight Novolac type phenolic resin 10 Silica powder (average particle size 15 μm) 70 Wax 0.3 Carbon black 0.2 The obtained abrasive has a true specific gravity of 1.9 and hardness (Rockwell
M scale) 110.

【0011】この研磨材を使用して電気部品用エポキシ
樹脂成形品のバリ除去を行った。比較のために研磨材と
してメラミン樹脂硬化物及びガラスビーズを使用してバ
リ除去を行った。研磨特性(研磨力、成形品面粗度)の
測定結果は表1のとおりであった。
Using this abrasive, burrs were removed from the epoxy resin molded product for electric parts. For comparison, deburring was performed using a cured melamine resin and glass beads as an abrasive. Table 1 shows the measurement results of the polishing characteristics (polishing power, surface roughness of the molded product).

【0012】 [0012]

【0013】[0013]

【発明の効果】前記実施例からも明らかなように、本発
明の研磨材は研磨力が良好で、研磨された成形品面粗度
も良好であり、電子部品、プラスチック成形品の成形時
発生するバリの除去に適し、特に樹脂封止したICやL
SIなどのバリ除去に好適である。
As is clear from the above examples, the abrasive of the present invention has a good polishing power and a good surface roughness of the abraded molded product, which occurs during the molding of electronic parts and plastic molded products. Suitable for removing burrs, especially IC and L sealed with resin
It is suitable for removing burrs such as SI.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B29C 37/02 8927−4F ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display location B29C 37/02 8927-4F

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 エポキシ樹脂10〜35重量%、ノボラ
ック型フェノール樹脂5〜20重量%及びシリカ粉末4
5〜85重量%を均一に混合した熱硬化性樹脂組成物を
加熱加圧することにより得られた硬化物を粉砕してなる
ことを特徴とする研磨材。
1. Epoxy resin 10 to 35% by weight, novolac type phenol resin 5 to 20% by weight, and silica powder 4
An abrasive comprising a thermosetting resin composition in which 5 to 85% by weight is uniformly mixed, and a cured product obtained by heating and pressurizing the pulverized product.
【請求項2】 エポキシ樹脂がノボラック型又はビフェ
ノール型エポキシ樹脂である請求項1記載の研磨材。
2. The abrasive according to claim 1, wherein the epoxy resin is a novolac type or biphenol type epoxy resin.
【請求項3】 エポキシ樹脂がクレゾールノボラック型
エポキシ樹脂である請求項1記載の研磨材。
3. The abrasive according to claim 1, wherein the epoxy resin is a cresol novolac type epoxy resin.
【請求項4】 ノボラック型フェノール樹脂がアルキル
フェノール、アルキルベンゼン又はジシクロペンタジエ
ン変性ノボラック型フェノール樹脂である請求項1記載
の研磨材。
4. The abrasive according to claim 1, wherein the novolac type phenol resin is an alkylphenol, alkylbenzene or dicyclopentadiene modified novolac type phenol resin.
JP6135317A 1994-06-17 1994-06-17 Abrasive material Pending JPH083542A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6135317A JPH083542A (en) 1994-06-17 1994-06-17 Abrasive material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6135317A JPH083542A (en) 1994-06-17 1994-06-17 Abrasive material

Publications (1)

Publication Number Publication Date
JPH083542A true JPH083542A (en) 1996-01-09

Family

ID=15148923

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6135317A Pending JPH083542A (en) 1994-06-17 1994-06-17 Abrasive material

Country Status (1)

Country Link
JP (1) JPH083542A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000045994A1 (en) * 1999-02-01 2000-08-10 Bridgestone Corporation Grinding beads and beads production method and device therefor
WO2003055958A1 (en) * 2001-12-21 2003-07-10 Dynea Canada, Ltd. Abrasive composition containing organic particles for chemical mechanical planarization

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000045994A1 (en) * 1999-02-01 2000-08-10 Bridgestone Corporation Grinding beads and beads production method and device therefor
WO2003055958A1 (en) * 2001-12-21 2003-07-10 Dynea Canada, Ltd. Abrasive composition containing organic particles for chemical mechanical planarization
US6620215B2 (en) 2001-12-21 2003-09-16 Dynea Canada, Ltd. Abrasive composition containing organic particles for chemical mechanical planarization

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