JPH0764705B2 - Hair cosmetics - Google Patents

Hair cosmetics

Info

Publication number
JPH0764705B2
JPH0764705B2 JP62077048A JP7704887A JPH0764705B2 JP H0764705 B2 JPH0764705 B2 JP H0764705B2 JP 62077048 A JP62077048 A JP 62077048A JP 7704887 A JP7704887 A JP 7704887A JP H0764705 B2 JPH0764705 B2 JP H0764705B2
Authority
JP
Japan
Prior art keywords
hair
weight
present
oil
kinds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP62077048A
Other languages
Japanese (ja)
Other versions
JPS63243019A (en
Inventor
健二 鳥居
羊子 福地
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP62077048A priority Critical patent/JPH0764705B2/en
Priority to EP88302767A priority patent/EP0285364B1/en
Priority to DE88302767T priority patent/DE3886247T2/en
Priority to KR1019880003483A priority patent/KR900004087B1/en
Publication of JPS63243019A publication Critical patent/JPS63243019A/en
Priority to US07/708,095 priority patent/US5286476A/en
Publication of JPH0764705B2 publication Critical patent/JPH0764705B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Description

【発明の詳細な説明】 ［産業上の利用分野］ 本発明は毛髪に対し、優れた光沢を与え、なめらかな感
触を付与しながら、かつ良好なセット保持力を有する毛
髪化粧料に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a hair cosmetic composition which imparts excellent gloss and smooth feel to hair and has good set-holding power.

［従来の技術］ 従来、毛髪化粧料には毛髪に光沢やなめらかさを与える
目的でシリコーン油、エステル油、炭化水素油などの油
分を、可溶化、乳化、溶解してもちいられている。特に
シリコン油は、表面張力が低く毛髪のなじみに優れ、良
い光沢が得られ近年多用されているものである。しか
し、油分のもつ限界があり多量に用いたり消費者が長い
あいだ用いたりすると、頭髪が脂ぎる欠点があった。ま
たなめらかさを付与する目的でカチオン活性剤も多用さ
れているが、望ましい光沢を与えるものではなく、多量
に配合すると安全性上も好ましくないという欠点があっ
た。[Prior Art] Conventionally, hair cosmetics have been used by solubilizing, emulsifying, and dissolving oil components such as silicone oil, ester oil, and hydrocarbon oil for the purpose of imparting luster and smoothness to hair. In particular, silicone oil has a low surface tension, is excellent in familiarity with hair, and has good gloss, and has been widely used in recent years. However, there is a limit to the oil content, and when used in large amounts or used by consumers for a long time, there is a drawback that the hair becomes greasy. Further, although a cation activator is often used for the purpose of imparting smoothness, it has a drawback that it does not give a desired luster and that it is not preferable in safety when compounded in a large amount.

また、毛髪セットの目的で高分子化合物；ポリビニルピ
ロリドン系ポリマー、酸性ポリビニルエーテル系ポリマ
ー、酸性アクリル系ポリマーあるいはカチオン性ポリマ
ー等が用いられている。これらは毛髪の固定すなわちセ
ット力に優れるものの、光沢なめらかさを満足するもの
ではなかった。また、毛髪を硬化させ、ごわつきを与え
る欠点があった。Further, for the purpose of hair setting, a high molecular compound such as polyvinylpyrrolidone-based polymer, acidic polyvinyl ether-based polymer, acidic acrylic-based polymer or cationic polymer is used. Although these are excellent in fixing or setting the hair, they do not satisfy gloss smoothness. Further, there is a defect that the hair is hardened and becomes stiff.

本発明者らは、上記事情にかんがみ、これまでに、特定
のシリコンを毛髪化粧料に配合した場合、上述の条件を
満たすことを見出して特許出願をした（特願昭61−2073
28号（特開昭63−183517号公報））。In view of the above circumstances, the present inventors have found that, when a specific silicone is compounded in a hair cosmetic composition, the above conditions are satisfied, and applied for a patent (Japanese Patent Application No. 61-2073).
No. 28 (JP-A-63-183517).

［発明が解決しようとする問題点］ しかしながら、この特定のシリコンをのみでは、沸点が
高く毛髪塗布後の乾きが遅い、また溶液粘度が高く毛髪
に塗布しづらいという欠点があった。そこで本発明者ら
は上述の条件を満たし、かつ毛髪に塗布し易く、毛髪に
塗布後の乾きが早い組成物を得るべく鋭意研究した結
果、本発明を完成するに至った。[Problems to be Solved by the Invention] However, the use of this specific silicone alone has drawbacks in that it has a high boiling point and a slow drying time after application to hair, and has a high solution viscosity and is difficult to apply to hair. Therefore, the present inventors have conducted intensive studies to obtain a composition that satisfies the above-mentioned conditions, is easy to apply to hair, and dries quickly after being applied to hair, and as a result, completed the present invention.

［問題点を解決するための手段］ すなわち、本発明は （Ａ）一般式 ［式中、R1はメチル基またはフェニル基（但し、R1がす
べてフェニル基である場合を除く）、R2はメチル基また
は水酸基を表す。また、ｎは3,000〜20,000の整数を表
す。］ で表されるシリコンの一種または二種以上を0.1〜25重
量％、 （Ｂ）環状シリコンの一種又は二種以上を45〜98.9重量
％、並びに （Ｃ）低級アルコールの一種又は二種以上を１〜30重量
％、 を配合することを特徴とする毛髪化粧料である。[Means for Solving Problems] That is, the present invention provides (A) general formula [In the formula, R 1 represents a methyl group or a phenyl group (excluding the case where all R 1 are phenyl groups), and R 2 represents a methyl group or a hydroxyl group. Further, n represents an integer of 3,000 to 20,000. ] 0.1 to 25% by weight of one or more kinds of silicon represented by, (B) 45 to 98.9% by weight of one or more kinds of cyclic silicon, and (C) one or more kinds of lower alcohols. 1 to 30% by weight of the hair cosmetic composition.

以下、本発明の構成について述べる。The configuration of the present invention will be described below.

本発明で使用するシリコンは上記の一般式で表される高
分子量のもので、式中のｎの値は3,000〜20,000であ
る。分子量でいうと、約25万〜150万程度であり、性状
は常温で軟質ゴム状を呈している。The silicon used in the present invention has a high molecular weight represented by the above general formula, and the value of n in the formula is 3,000 to 20,000. In terms of molecular weight, it is about 250,000 to 1,500,000, and it is soft rubber-like at room temperature.

具体的な構造を化学名で示せば、ジメチルポリシロキサ
ン、メチルフェニルポリシロキサン、末端水酸基含有ジ
メチルポリシロキサン、末端水酸基含有メチルフェニル
ポリシロキサンなどが挙げられる。本発明の高分子量シ
リコーンとしては、例えば、ゼネラル・エレクトリック
社製の商品名SE30、SE76として市販されているものが挙
げられる。Specific chemical structures include dimethyl polysiloxane, methylphenyl polysiloxane, terminal hydroxyl group-containing dimethyl polysiloxane, terminal hydroxyl group-containing methylphenyl polysiloxane, and the like. Examples of the high molecular weight silicone of the present invention include those commercially available under the trade names SE30 and SE76 manufactured by General Electric Company.

従来、重合度が３〜650の範囲のジメチルポリシロキサ
ンは化粧料成分として使用されているが、本発明のごと
き高分子量のシリコンを毛髪化粧料に配合した例は全く
みられない。Conventionally, dimethylpolysiloxane having a degree of polymerization in the range of 3 to 650 has been used as a cosmetic ingredient. However, no example has been found in which a high molecular weight silicone as in the present invention is incorporated into a hair cosmetic.

本発明におけるシリコンの配合量は毛髪化粧料含量中の
0.1〜25重量％、好ましくは0.5〜15重量％である。0.1
％未満では十分な効果が得られず、25％を超えると毛髪
化粧量の粘度が３万cps以上となり、頭髪に塗布が困難
になる。粘度は、塗布のし易さを考慮すると20〜5,000c
psが好ましい。The blending amount of silicone in the present invention depends on the content of hair cosmetics.
It is 0.1 to 25% by weight, preferably 0.5 to 15% by weight. 0.1
If it is less than 25%, a sufficient effect cannot be obtained, and if it exceeds 25%, the viscosity of the amount of makeup on the hair becomes 30,000 cps or more, and application to the hair becomes difficult. The viscosity is 20-5,000c considering the ease of application.
ps is preferred.

本発明のシリコンを毛髪化粧料に配合する場合、環状シ
リコンに溶解して配合することが好ましい。もちろん、
毛髪化粧料中に別々に配合して系中で溶解させても構わ
ない。When the silicone of the present invention is added to the hair cosmetic composition, it is preferable that the silicone be dissolved in cyclic silicone and then added. of course,
You may mix | blend separately in hair cosmetics and may make it melt | dissolve in a system.

本発明の環状シリコンは次の一般式で表され、具体例を
挙げれば、オクタメチルシクロテトラシロキサン、デカ
メチルシクロペンタシロキサン、テトラデカメチルシク
ロヘプタシロキサンなどである。The cyclic silicon of the present invention is represented by the following general formula, and specific examples thereof include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and tetradecamethylcycloheptasiloxane.

（式中、ｎは３〜７の整数を表す。） これらの中から一種又は二種以上が適宜選択され、配合
される。配合量は毛髪化粧料全量中の45〜98.9重量％で
ある。 (In the formula, n represents an integer of 3 to 7.) Among these, one kind or two or more kinds are appropriately selected and mixed. The blending amount is 45 to 98.9% by weight based on the total amount of the hair cosmetic composition.

本発明で用いられる低級アルコールとしては、エタノー
ル、イソプロピルアルコール等が挙げられる。配合量は
毛髪化粧料全量中の１〜30重量％であり、好ましくは５
〜15重量％である。30重量％を越えると高分子量のシリ
コンが溶解しないので好ましくない。Examples of the lower alcohol used in the present invention include ethanol and isopropyl alcohol. The blending amount is 1 to 30% by weight based on the total amount of the hair cosmetic, and preferably 5
~ 15% by weight. If it exceeds 30% by weight, high molecular weight silicon is not dissolved, which is not preferable.

本発明の毛髪化粧料には上記の必須構成成分に加えて、
目的に応じて本発明の効果を損なわない量的、質的範囲
で、紫外線吸収剤、酸化防止剤、防腐剤、ビタミン、ホ
ルモンなどの薬剤、香料を配合してもよい。In addition to the above essential components, the hair cosmetic composition of the present invention,
Depending on the purpose, ultraviolet absorbers, antioxidants, preservatives, vitamins, hormones and other agents, and fragrances may be blended within a quantitative and qualitative range that does not impair the effects of the present invention.

以下、実施例により本発明をさらに詳細に説明する。本
発明は、これらによって限定されるものではない。配合
量は全て重量％である。Hereinafter, the present invention will be described in more detail with reference to Examples. The present invention is not limited to these. All compounding amounts are weight%.

実施例１ ヘアオイル （１）デカメチルシクロペンタシロキサン 70.0％ （２）エタノール（99％） 20.0 （３）ジメチルポリシロキサン（R1およびR2はメチル
基、ｎ＝3,000） 10.0 （４）香料 適量 （１）〜（４）を撹拌溶解、混合する。粘度500cpsの粘
性のある透明性のよい液状ヘアオイルを得た。Example 1 Hair oil (1) Decamethylcyclopentasiloxane 70.0% (2) Ethanol (99%) 20.0 (3) Dimethylpolysiloxane (R 1 and R 2 are methyl groups, n = 3,000) 10.0 (4) Perfume proper amount ( Dissolve and mix 1) to 4) with stirring. A viscous and transparent liquid hair oil having a viscosity of 500 cps was obtained.

実施例２ ヘアオイル （１）オクタメチルシクロテトラシロキサン 69.9％ （２）ジメチルポリシロキサン（R1はメチル基、R2は水
酸基、ｎ＝10,000） 0.1 （３）エタノール（99％） 30.0 実施例１と同様にして、20cpsの液状ヘアオイルを得
た。Example 2 Hair oil (1) Octamethylcyclotetrasiloxane 69.9% (2) Dimethylpolysiloxane (R 1 is a methyl group, R 2 is a hydroxyl group, n = 10,000) 0.1 (3) Ethanol (99%) 30.0 Example 1 and In the same manner, 20 cps liquid hair oil was obtained.

実施例３ ヘアオイル （１）ドデカメチルシクロヘキサシロキサン 45.0％ （２）ジメチルポリシロキサン（R1はメチル基：フェニ
ル基＝1:1 R2はメチル基、ｎ＝20,000） 25.0 （３）イソプロピルアルコール 30.0 （４）香料 適量 実施例１と同様にして、5,000cpsの液状ヘアオイルを得
た。Example 3 Hair Oil (1) Dodecamethylcyclohexasiloxane 45.0% (2) Dimethylpolysiloxane (R 1 is a methyl group: phenyl group = 1: 1 R 2 is a methyl group, n = 20,000) 25.0 (3) Isopropyl alcohol 30.0 (4) Fragrance Suitable amount In the same manner as in Example 1, 5,000 cps liquid hair oil was obtained.

実施例４ ヘアオイル （１）デカメチルシクロペンタシロキサン 40.0％ （２）オクタメチルシクロテトラシロキサン 40.0 （３）ジメチルポリシロキサン（R1およびR2はメチル
基、ｎ＝5,000） 5.0 （４）ジメチルポリシロキサン（R1はメチル基：フェニ
ル基＝1:1 R2は水酸基、ｎ＝15,000） 10.0 （５）エタノール（95％） 2.0 （６）イソプロピルアルコール 3.0 実施例１と同様にして、2,500cpsの透明性のよい液状ヘ
アオイルを得た。Example 4 Hair oil (1) Decamethylcyclopentasiloxane 40.0% (2) Octamethylcyclotetrasiloxane 40.0 (3) Dimethylpolysiloxane (R 1 and R 2 are methyl groups, n = 5,000) 5.0 (4) Dimethylpolysiloxane (R 1 is a methyl group: phenyl group = 1: 1 R 2 is a hydroxyl group, n = 15,000) 10.0 (5) Ethanol (95%) 2.0 (6) Isopropyl alcohol 3.0 As in Example 1, transparent at 2,500 cps A liquid hair oil having good properties was obtained.

［発明の効果］ 本発明の毛髪化粧料は、毛髪に豊かな光沢となめらかさ
を与え、かつ毛髪をしっとりまとめる毛髪化粧料であ
る。[Effect of the Invention] The hair cosmetic composition of the present invention is a hair cosmetic composition that imparts rich luster and smoothness to hair and moistens the hair.

Claims (1)

【特許請求の範囲】[Claims] 【請求項１】（Ａ）一般式 ［式中、R1はメチル基またはフェニル基（但し、R1がす
べてフェニル基である場合を除く）、R2はメチル基また
は水酸基を表す。また、ｎは3,000〜20,000の整数を表
す。］ で表されるシリコンの一種または二種以上を0.1〜25重
量％、 （Ｂ）環状シリコンの一種又は二種以上を45〜98.9重量
％、並びに （Ｃ）低級アルコールの一種又は二種以上を１〜30重量
％、 を配合することを特徴とする毛髪化粧料。1. A general formula (A) [In the formula, R 1 represents a methyl group or a phenyl group (excluding the case where all R 1 are phenyl groups), and R 2 represents a methyl group or a hydroxyl group. Further, n represents an integer of 3,000 to 20,000. ] 0.1 to 25% by weight of one or more kinds of silicon represented by, (B) 45 to 98.9% by weight of one or more kinds of cyclic silicon, and (C) one or more kinds of lower alcohols. 1 to 30% by weight of a hair cosmetic composition.
JP62077048A 1987-03-30 1987-03-30 Hair cosmetics Expired - Lifetime JPH0764705B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP62077048A JPH0764705B2 (en) 1987-03-30 1987-03-30 Hair cosmetics
EP88302767A EP0285364B1 (en) 1987-03-30 1988-03-29 Use of a hair cosmetic composition for preventing generation of split hair or torn hair and for repairing damaged hair
DE88302767T DE3886247T2 (en) 1987-03-30 1988-03-29 Use of a hair cosmetic for the prevention of split hair or broken hair and for the treatment of damaged hair.
KR1019880003483A KR900004087B1 (en) 1987-03-30 1988-03-30 Hair cosmetic composition
US07/708,095 US5286476A (en) 1987-03-30 1991-05-24 Hair cosmetic composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62077048A JPH0764705B2 (en) 1987-03-30 1987-03-30 Hair cosmetics

Publications (2)

Publication Number Publication Date
JPS63243019A JPS63243019A (en) 1988-10-07
JPH0764705B2 true JPH0764705B2 (en) 1995-07-12

Family

ID=13622894

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62077048A Expired - Lifetime JPH0764705B2 (en) 1987-03-30 1987-03-30 Hair cosmetics

Country Status (1)

Country Link
JP (1) JPH0764705B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63313717A (en) * 1987-06-17 1988-12-21 Lion Corp Chemically treating agent for hair
JP5538685B2 (en) * 2008-03-17 2014-07-02 株式会社 資生堂 Hair cosmetics
JP4954308B2 (en) 2010-03-17 2012-06-13 株式会社 資生堂 Hair cosmetics

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5622716A (en) * 1979-07-19 1981-03-03 Unilever Nv Hair treatment product and its manufacture
JPS57112319A (en) * 1980-03-10 1982-07-13 Procter & Gamble Hair conditioning composition
JPS616A (en) * 1984-03-15 1986-01-06 ザ、プロクタ−、エンド、ギヤンブル、カンパニ− Hair conditioning composition
JPS6248615A (en) * 1985-06-06 1987-03-03 ザ、プロクタ−、エンド、ギヤンブル、カンパニ− Hair treatment mousse

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5622716A (en) * 1979-07-19 1981-03-03 Unilever Nv Hair treatment product and its manufacture
JPS57112319A (en) * 1980-03-10 1982-07-13 Procter & Gamble Hair conditioning composition
JPS616A (en) * 1984-03-15 1986-01-06 ザ、プロクタ−、エンド、ギヤンブル、カンパニ− Hair conditioning composition
JPS6248615A (en) * 1985-06-06 1987-03-03 ザ、プロクタ−、エンド、ギヤンブル、カンパニ− Hair treatment mousse

Also Published As

Publication number Publication date
JPS63243019A (en) 1988-10-07

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