JPH07233491A - Water electrolytic device using high molecular electrolyte membrane - Google Patents
Water electrolytic device using high molecular electrolyte membraneInfo
- Publication number
- JPH07233491A JPH07233491A JP6046438A JP4643894A JPH07233491A JP H07233491 A JPH07233491 A JP H07233491A JP 6046438 A JP6046438 A JP 6046438A JP 4643894 A JP4643894 A JP 4643894A JP H07233491 A JPH07233491 A JP H07233491A
- Authority
- JP
- Japan
- Prior art keywords
- water
- oxygen
- cell
- hydrogen
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、高分子電解質膜を用い
る水素及び酸素製造のための水電解装置に関するもので
ある。FIELD OF THE INVENTION The present invention relates to a water electrolysis apparatus for producing hydrogen and oxygen using a polymer electrolyte membrane.
【０００２】[0002]
【従来の技術】従来の水電解により水素及び酸素を製造
するための装置は、図７のプロセスフロー図に示すよう
に、それぞれ独立した水電解槽１、熱交換器２、Ｏ2気
液分離器３、Ｏ2ガス冷却器４、Ｏ2Ｋ．Ｏ．ドラム５、
Ｈ2気液分離器６、Ｈ2ガス冷却器７、Ｈ2Ｋ．Ｏ．ドラ
ム８、及び循環ポンプ９から構成されており、それぞれ
の間を配管で結合されている。電解槽で電解される水
は、循環ポンプ９により熱交換器２で冷却されて、水電
解槽１に供給される。電解槽の陽極側では酸素が発生
し、発生した酸素と未反応の水は、電解槽頂部からＯ2
気液分離器３に導かれここで、酸素と水が分離される。
分離された高温の酸素は、Ｏ2ガス冷却器４で冷却さ
れ、Ｏ2Ｋ．Ｏ．ドラム５で、酸素中の凝縮した水分が
取り除かれ系外に排出される。電解槽の陰極側で発生し
た水素と同伴する水は、電解槽上部からＨ2気液分離器
６に導かれここで、水素と水が分離される。分離された
高温の水素は、Ｈ2ガス冷却器７で冷却され、Ｈ2Ｋ．
Ｏ．ドラム８で、水素中の凝縮した水分が取り除かれ系
外に排出される。2. Description of the Related Art As shown in the process flow diagram of FIG. 7, a conventional apparatus for producing hydrogen and oxygen by water electrolysis has an independent water electrolysis tank 1, heat exchanger 2, O 2 gas-liquid separation. 3, O 2 gas cooler 4, O 2 K.K. O. Drum 5,
H 2 gas-liquid separator 6, H 2 gas cooler 7, H 2 K. O. It is composed of a drum 8 and a circulation pump 9, and the respective parts are connected by piping. The water electrolyzed in the electrolyzer is cooled in the heat exchanger 2 by the circulation pump 9 and supplied to the water electrolyzer 1. Oxygen is generated on the anode side of the electrolytic cell, and the generated oxygen and unreacted water are separated from the top of the electrolytic cell by O 2
It is guided to the gas-liquid separator 3 where oxygen and water are separated.
The separated high-temperature oxygen is cooled by the O 2 gas cooler 4 to obtain O 2 K.K. O. Condensed water in oxygen is removed by the drum 5 and discharged out of the system. Water accompanying hydrogen generated on the cathode side of the electrolytic cell is introduced from the upper part of the electrolytic cell to the H 2 gas-liquid separator 6 where hydrogen and water are separated. The separated high-temperature hydrogen is cooled by the H 2 gas cooler 7 and is cooled to H 2 K.
O. The condensed water in the hydrogen is removed by the drum 8 and discharged to the outside of the system.
【０００３】従来の複極式（フィルタープレス式とも呼
ばれる）電解槽の構造は図１中に示される電解セル部１
１のようになっており、陽極側主電極１１、陰極側主電
極１１４、複極板１１３、電極接合体膜１１２、陽極給
電体及び陰極給電体から構成されている。セルの性能
は、主にセル電圧によって決定され、セル電圧を下げる
努力がなされている。セル電圧に影響を与える要素とし
ては、水の分解反応に要する理論分解電圧、触媒電極の
過電圧及びセルの電気抵抗によるオーム損による電圧が
ある。このうち、セルの電気抵抗は各部材特有の電気抵
抗ばかりではなく、各部材間の接触抵抗に大きく影響さ
れる。接触抵抗の低下は、セルの両端をボルト等で締め
付けることによってなされている。The structure of a conventional bipolar electrode (also called filter press type) electrolytic cell is shown in FIG.
1 and is composed of an anode side main electrode 11, a cathode side main electrode 114, a bipolar plate 113, an electrode assembly film 112, an anode power feed body and a cathode power feed body. Cell performance is largely determined by the cell voltage, and efforts are being made to reduce the cell voltage. Factors that affect the cell voltage include the theoretical decomposition voltage required for the water decomposition reaction, the overvoltage of the catalyst electrode, and the voltage due to ohmic loss due to the electric resistance of the cell. Among these, the electric resistance of the cell is greatly affected not only by the electric resistance peculiar to each member but also by the contact resistance between each member. The contact resistance is reduced by fastening both ends of the cell with bolts or the like.
【０００４】[0004]
【発明が解決しようとする課題】従来のシステムは、各
構成機器を配管でつないだものであり、システムとして
は、次のような問題がある。 （１）各独立した機器の集合体であるため、設置面積が
大きくなる。 （２）機器を配管でつなぐため、その分だけ漏洩の箇所
が大きくなる。 （３）コストが高い。また、電解槽の問題点としては、 （４）セルの締め付け圧力を運転中のあらゆる条件で最
適に保つことは難しい。一定に保つためには、油圧装置
等を設けて、締め付け圧力を制御することが必要であ
る。The conventional system is one in which each component is connected by piping, and the system has the following problems. (1) Since it is a collection of independent devices, the installation area is large. (2) Since the equipment is connected by piping, the location of leakage becomes larger accordingly. (3) Cost is high. Further, as problems of the electrolytic cell, (4) it is difficult to keep the tightening pressure of the cell optimum under all conditions during operation. In order to keep it constant, it is necessary to provide a hydraulic device or the like to control the tightening pressure.
【０００５】本発明は、上記のような問題点を解決する
ためになされたもので、設備をコンパクトにするととも
に、セルの締め付け圧力を一定にするための油圧締付装
置等を設置しないでも済む水電解装置を提供すること
を、その目的とする。The present invention has been made in order to solve the above-mentioned problems, and the equipment can be made compact, and it is not necessary to install a hydraulic tightening device or the like for keeping the tightening pressure of cells constant. It is an object of the present invention to provide a water electrolysis device.
【０００６】[0006]
【課題を解決するための手段】本発明者らは、鋭意検討
した結果、複極式電解槽とプレート式熱交換器とを同一
平面上に配置し、これらを共通のボルトによって締め付
け一体化することによって上記課題が解決されることを
知見し、本発明を完成するに至った。As a result of intensive studies, the inventors of the present invention have arranged a bipolar electrode electrolytic cell and a plate type heat exchanger on the same plane, and fasten them integrally with a common bolt. As a result, they have found that the above problems can be solved, and have completed the present invention.
【０００７】即ち、本発明によれば、高分子電解質膜を
用いる複極式電解槽で水を電解し、陽極に酸素、陰極に
水素を発生させ、複数の熱交換器及び分離器により発生
したガスを冷却し、循環する水を熱交換させることによ
り常温の酸素及び水素を製造する水電解装置において、
前記の電解槽と複数の熱交換器とを同一平面上に配置
し、且つ共通の流路を内部に設け、これらを共通のボル
トで締め付けることにより一体化してなる電解槽熱交換
器複合体としたことを特徴とする水電解装置が提供さ
れ、特に前記電解槽熱交換器複合体が、酸素ガス冷却
部、熱交換器部、電解セル部及び水素ガス冷却部からな
ることを特徴とする水電解装置が提供される。That is, according to the present invention, water is electrolyzed in a bipolar electrolytic cell using a polymer electrolyte membrane to generate oxygen in the anode and hydrogen in the cathode, which are generated by a plurality of heat exchangers and separators. In a water electrolysis apparatus that produces oxygen and hydrogen at room temperature by cooling gas and heat-exchanging circulating water,
An electrolytic cell heat exchanger composite body in which the electrolytic cell and a plurality of heat exchangers are arranged on the same plane, and a common flow path is provided inside, and these are integrated by tightening them with a common bolt. There is provided a water electrolysis device characterized in that, in particular, the electrolytic cell heat exchanger complex, water characterized in that it comprises an oxygen gas cooling unit, a heat exchanger unit, an electrolytic cell unit and a hydrogen gas cooling unit. An electrolysis device is provided.
【０００８】また、本発明によれば、前記電解セル部に
設けられた陽極側主電極及び陰極側主電極の一方又は両
方の外部に接するところに、圧力調整部を設けたことを
特徴とする水電解装置が提供される。Further, according to the present invention, a pressure adjusting portion is provided in contact with the outside of one or both of the anode side main electrode and the cathode side main electrode provided in the electrolytic cell section. A water electrolysis device is provided.
【０００９】本発明により、従来、独立した水電解槽
１、熱交換器２、Ｏ2気液分離器３、Ｏ2ガス冷却器４、
Ｏ2Ｋ．Ｏ．ドラム５、Ｈ2気液分離器６、Ｈ2ガス冷却
器７、Ｈ2Ｋ．Ｏ．ドラム８、及び循環ポンプ９で構成
されていた装置が、電解槽と熱交換器を一体としたため
に、電解槽熱交換器複合体、Ｏ2気液分離器、及び循環
ポンプだけで構成されるようになるとともに、熱交換器
の冷却水の圧力を制御することにより、セルの締め付け
圧力を一定にするための油圧締付装置等の設置の必要性
がなくなる。According to the present invention, conventionally, an independent water electrolysis cell 1, heat exchanger 2, O 2 gas-liquid separator 3, O 2 gas cooler 4,
O 2 K. O. Drum 5, H 2 gas-liquid separator 6, H 2 gas cooler 7, H 2 K.K. O. Since the device composed of the drum 8 and the circulation pump 9 integrates the electrolytic cell and the heat exchanger, it is composed only of the electrolytic cell heat exchanger complex, the O 2 gas-liquid separator, and the circulation pump. In addition, by controlling the pressure of the cooling water of the heat exchanger, it is not necessary to install a hydraulic tightening device or the like for keeping the tightening pressure of the cell constant.
【００１０】[0010]
【実施例】以下、本発明の実施例を図面により説明す
る。 実施例１ 図１に最も代表的な本発明の実施例における電解槽熱交
換器複合体（以下単に複合体と記すことがある）１０の
分解構造図を示す。複合体１０は、図の左側から、Ｏ2
ガス冷却部１３、熱交換器部１２、電解セル部１１及び
Ｈ2ガス冷却部１４より構成されている。実際には、こ
れらを複数（この図では４本）の通しボルトで締め付け
ることにより一体構造としている。なお、図１におい
て、１０１はＯ2側フランジ、１０２はＨ2側フランジ、
１１１は陽極側主電極、１１２は電極接合体膜、１１３
は複極板、１１４は陰極側主電極、１２１は熱交換器ノ
ズルプレート、１３１はＯ2ガス冷却器ノズルプレート
及び１４１はＨ2ガス冷却器ノズルプレートを、それぞ
れ示す。Embodiments of the present invention will be described below with reference to the drawings. Example 1 FIG. 1 shows an exploded structural view of an electrolytic cell heat exchanger complex (hereinafter sometimes simply referred to as a complex) 10 in an example of the most representative present invention. Composite 10 from the left side of FIG, O 2
The gas cooling unit 13, the heat exchanger unit 12, the electrolytic cell unit 11, and the H 2 gas cooling unit 14 are included. In practice, these are tightened with a plurality of (four in this figure) through bolts to form an integrated structure. In FIG. 1, 101 is an O 2 side flange, 102 is an H 2 side flange,
111 is an anode side main electrode, 112 is an electrode assembly film, 113
Is a bipolar plate, 114 is a cathode-side main electrode, 121 is a heat exchanger nozzle plate, 131 is an O 2 gas cooler nozzle plate, and 141 is an H 2 gas cooler nozzle plate.
【００１１】図２にこの場合のプロセスフローを示す。
循環ポンプ２０により供給水は複合体１０の熱交換器部
１２に供給される。供給水はここで冷却水又は廃熱回収
用の熱媒体と熱交換し、所定の温度まで冷却され、内部
チャンネルを通って電解セル部１１に供給される。電解
セル陽極で酸素が発生し、酸素と未反応の水は電解セル
部の上部に集められ、陽極側主電極上部ノズルから排出
される。排出された酸素及び未反応の水は、外部に設け
られたＯ2気液分離器３０で、酸素と水に分離される。
分離された高温の酸素は、複合体Ｏ2ガス冷却部１３の
下部に戻される。ここで冷却水により冷却され、酸素中
の水分は凝縮して下部に設けられた気液分離スペースに
溜まり、熱交換器ノズルプレートを経てＯ2気液分離器
３０に戻される。冷却された酸素は、Ｏ2ガス冷却器ノ
ズルプレートを経て系外に排出される。電解セル陰極で
は水素が発生し、水素と水素に同伴する水は電解セル部
の下部に集められ、内部チャンネルを通ってＨ2ガス冷
却部１４に供給される。ここで冷却水により冷却され、
水素中の水分は凝縮して下部に設けられた気液分離スペ
ースに溜まり、Ｈ2ガス冷却器ノズルプレートを経てＯ2
気液分離器３０に戻される。冷却された水素は、Ｈ2ガ
ス冷却器ノズルプレートを経て系外に排出される。FIG. 2 shows a process flow in this case.
The supply water is supplied to the heat exchanger portion 12 of the composite body 10 by the circulation pump 20. The supply water exchanges heat with cooling water or a heat medium for waste heat recovery, is cooled to a predetermined temperature, and is supplied to the electrolysis cell section 11 through the internal channel. Oxygen is generated in the electrolytic cell anode, and water that has not reacted with oxygen is collected in the upper portion of the electrolytic cell portion and discharged from the anode side main electrode upper nozzle. The discharged oxygen and unreacted water are separated into oxygen and water by an O 2 gas-liquid separator 30 provided outside.
The separated high-temperature oxygen is returned to the lower part of the complex O 2 gas cooling unit 13. Here, it is cooled by cooling water, and the water content in oxygen is condensed and collected in the gas-liquid separation space provided in the lower part, and returned to the O 2 gas-liquid separator 30 via the heat exchanger nozzle plate. The cooled oxygen is discharged out of the system through the O 2 gas cooler nozzle plate. Hydrogen is generated at the electrolysis cell cathode, and hydrogen and water accompanying the hydrogen are collected in the lower part of the electrolysis cell section and supplied to the H 2 gas cooling section 14 through the internal channel. Here it is cooled by cooling water,
Moisture in hydrogen condenses and collects in the gas-liquid separation space provided at the bottom, and passes through the H 2 gas cooler nozzle plate to O 2 gas.
It is returned to the gas-liquid separator 30. The cooled hydrogen is discharged out of the system through the H 2 gas cooler nozzle plate.
【００１２】電解セルの締め付け圧力の調整は、冷却水
戻りラインに設けられた圧力コントロールバルブ５０に
よって行なわれる。この場合、冷却水の圧力を調整する
ことによって、電解セル部１１の締め付け圧力を一定に
保つことができる。なお、図２中、４０は直流電源を、
６０は補給純水ラインに設けられたＯ2気液分離器３０
の液面コントロールバルブを、７０はＯ2ガス排出ライ
ンに設けられた圧力コントロールバルブを、８０はＨ2
ガス排出ラインに設けられた圧力コントロールバルブ
を、それぞれ示す。The tightening pressure of the electrolysis cell is adjusted by the pressure control valve 50 provided in the cooling water return line. In this case, the tightening pressure of the electrolysis cell unit 11 can be kept constant by adjusting the pressure of the cooling water. In FIG. 2, 40 is a DC power supply,
Reference numeral 60 is an O 2 gas-liquid separator 30 provided in the makeup pure water line
Liquid level control valve, 70 is a pressure control valve installed in the O 2 gas discharge line, and 80 is H 2
The pressure control valves provided in the gas exhaust line are shown respectively.
【００１３】実施例２ 図３にもう１つの実施例における電解槽熱交換器複合体
１０の分解構造図を示す。この場合は、Ｏ2ガス冷却部
１３、熱交換器部１２、電解セル部１１、Ｈ2ガス冷却
部１４に、セル１１の締め付け圧力を調整するための独
立した圧力調整部１５が設けられている。独立した締め
付け圧力調整部１５を設けることにより、冷却水の圧力
を制御するために余分にかかる電力のロスを低減するこ
とができる。この場合のプロセスフローは図４で示さ
れ、冷却水戻りラインに圧力コントロールバルブ５０が
ないこと以外は、図２と同様である。Example 2 FIG. 3 shows an exploded structural view of an electrolytic cell heat exchanger complex 10 in another example. In this case, the O 2 gas cooling unit 13, the heat exchanger unit 12, the electrolytic cell unit 11, and the H 2 gas cooling unit 14 are provided with independent pressure adjusting units 15 for adjusting the tightening pressure of the cells 11. There is. By providing the independent tightening pressure adjusting unit 15, it is possible to reduce the loss of electric power that is extraly applied to control the pressure of the cooling water. The process flow in this case is shown in FIG. 4 and is the same as FIG. 2 except that there is no pressure control valve 50 in the cooling water return line.
【００１４】図４において、循環ポンプ２０により供給
水は電解槽熱交換器複合体１０の熱交換器部１２に供給
される。供給水はここで冷却水又は廃熱回収用の熱媒体
と熱交換し、所定の温度まで冷却され、内部チャンネル
を通って電解セル部１１に供給される。電解セル陽極で
酸素が発生し、酸素と未反応の水は電解セル部の上部に
集められ、陽極側主電極上部ノズルから排出される。排
出された酸素及び未反応の水は、外部に設けられたＯ2
気液分離器３０で、酸素と水に分離される。分離された
高温の酸素は、複合体Ｏ2ガス冷却部１３の下部に戻さ
れる。ここで冷却水により冷却され、酸素中の水分は凝
縮して下部に設けられた気液分離スペースに溜まり、熱
交換器ノズルプレートを経てＯ2気液分離器３０に戻さ
れる。冷却された酸素は、Ｏ2ガス冷却器ノズルプレー
トを経て系外に排出される。電解セル陰極では水素が発
生し、水素と水素に同伴する水は電解セル部の下部に集
められ、内部チャンネルを通ってＨ2ガス冷却部１４に
供給される。ここで冷却水により冷却され、水素中の水
分は凝縮して下部に設けられた気液分離スペースに溜ま
り、Ｈ2ガス冷却ノズルプレートを経てＯ2気液分離器３
０に戻される。冷却された水素は、Ｈ2ガス冷却器ノズ
ルプレートを経て系外に排出される。In FIG. 4, the supply water is supplied to the heat exchanger section 12 of the electrolytic cell heat exchanger complex 10 by the circulation pump 20. The supply water exchanges heat with cooling water or a heat medium for waste heat recovery, is cooled to a predetermined temperature, and is supplied to the electrolysis cell section 11 through the internal channel. Oxygen is generated in the electrolytic cell anode, and water that has not reacted with oxygen is collected in the upper portion of the electrolytic cell portion and discharged from the anode side main electrode upper nozzle. The discharged oxygen and unreacted water are separated by O 2 provided outside.
The gas-liquid separator 30 separates oxygen and water. The separated high-temperature oxygen is returned to the lower part of the complex O 2 gas cooling unit 13. Here, the water is cooled by cooling water, the water content in oxygen is condensed and collected in the gas-liquid separation space provided at the lower part, and returned to the O 2 gas-liquid separator 30 via the heat exchanger nozzle plate. The cooled oxygen is discharged out of the system through the O 2 gas cooler nozzle plate. Hydrogen is generated at the electrolysis cell cathode, and hydrogen and water accompanying the hydrogen are collected in the lower part of the electrolysis cell section and supplied to the H 2 gas cooling section 14 through the internal channel. Here, the water is cooled by cooling water, and the water content in the hydrogen is condensed and collected in the gas-liquid separation space provided in the lower part, and is passed through the H 2 gas cooling nozzle plate to form the O 2 gas-liquid separator 3.
It is set back to 0. The cooled hydrogen is discharged out of the system through the H 2 gas cooler nozzle plate.
【００１５】電解セルの締め付け圧力の調整は、圧力調
整部１５に供給される水又は油（圧力媒体）の圧力を調
整する圧力コントロールバルブ９０によって行なわれ
る。圧力調整部１５は、陽極側主電極、陰極側主電極の
一方又は両方の外側に接するところに設ける。これによ
って、電解セル部１１の締め付け圧力を一定に保つこと
ができる。The tightening pressure of the electrolysis cell is adjusted by a pressure control valve 90 which adjusts the pressure of water or oil (pressure medium) supplied to the pressure adjusting section 15. The pressure adjusting unit 15 is provided in contact with the outside of one or both of the anode-side main electrode and the cathode-side main electrode. Thereby, the tightening pressure of the electrolysis cell unit 11 can be kept constant.
【００１６】実施例３ 図５に、設備を宇宙空間のような重力式分離ができない
場所に設置した場合の実施例における複合体１０の分解
構造図を示す。複合体１０は、図の左側から、Ｏ2ガス
冷却部１３、熱交換器部１２、電解セル部１１及びＨ2
ガス冷却部１４より構成されている。実際には、これら
を複数（この図では４本）の通しボルトで締め付けるこ
とにより一体構造となっている。Embodiment 3 FIG. 5 shows an exploded structural view of the composite body 10 in an embodiment in which the equipment is installed in a place such as outer space where gravity separation is not possible. From the left side of the figure, the composite 10 includes an O 2 gas cooling unit 13, a heat exchanger unit 12, an electrolysis cell unit 11 and H 2 gas.
It is composed of a gas cooling unit 14. In practice, these are integrated by tightening them with a plurality of (four in this figure) through bolts.
【００１７】図６に、この場合のプロセスフローを示
す。循環ポンプ２０により、供給水は複合体１０の熱交
換器部１２に供給される。供給水はここで電解セル部１
１で発生した酸素及び未反応の水と熱交換して所定の温
度まで昇温され、内部チャンネルを通って電解セル部１
１に供給される。電解セル陽極で酸素が発生し、酸素と
未反応の水は電解セル部の上部に集められ、陽極側主電
極上部ノズルから排出される。排出された酸素及び未反
応の水は、複合体１０の熱交換器部１２に供給され、こ
こで供給水と熱交換し、いくぶん温度が下がり、内部チ
ャンネルを通ってＯ2ガス冷却部１３に供給される。こ
こで冷却水により所定の温度まで冷却され、外部に設け
られたＯ2気液分離器３０に導かれ、ここで酸素と水に
分離される。電解セル陰極では水素が発生し、水素と水
素に同伴する水は電解セル部の下部に集められ、内部チ
ャンネルを通ってＨ2ガス冷却部１４に供給される。こ
こで冷却水により冷却され、外部に設けられたＨ2気液
分離器４０に導かれる。ここで気液分離され、分離され
た水素は系外に排出される。FIG. 6 shows a process flow in this case. The supply water is supplied to the heat exchanger portion 12 of the composite body 10 by the circulation pump 20. Supply water here is the electrolysis cell section 1
1 and the unreacted water are heat-exchanged to raise the temperature to a predetermined temperature, and the electrolysis cell section 1 passes through the internal channel.
1 is supplied. Oxygen is generated in the electrolytic cell anode, and water that has not reacted with oxygen is collected in the upper portion of the electrolytic cell portion and discharged from the anode side main electrode upper nozzle. The discharged oxygen and unreacted water are supplied to the heat exchanger section 12 of the composite body 10, where they exchange heat with the supplied water, the temperature of the water is somewhat lowered, and the oxygen and unreacted water pass through the internal channels to the O 2 gas cooling section 13. Supplied. Here, it is cooled to a predetermined temperature by cooling water, guided to an O 2 gas-liquid separator 30 provided outside, and separated into oxygen and water there. Hydrogen is generated at the electrolysis cell cathode, and hydrogen and water accompanying the hydrogen are collected in the lower part of the electrolysis cell section and supplied to the H 2 gas cooling section 14 through the internal channel. Here, it is cooled by cooling water and guided to an H 2 gas-liquid separator 40 provided outside. Here, gas and liquid are separated, and the separated hydrogen is discharged out of the system.
【００１８】電解セルの締め付け圧力の調整は、冷却水
戻りラインに設けられた圧力コントロールバルブ５０に
よって行なわれる。この場合、冷却水の圧力を調整する
ことによって、電解セル部１１の締め付け圧力を一定に
保つことができる。The tightening pressure of the electrolysis cell is adjusted by a pressure control valve 50 provided in the cooling water return line. In this case, the tightening pressure of the electrolysis cell unit 11 can be kept constant by adjusting the pressure of the cooling water.
【００１９】[0019]
【発明の効果】以上のように、本発明の水電解装置によ
れば、電解槽と複数の熱交換器とを一体構造にしたた
め、設備がコンパクトになり、装置が安価にでき、更に
セルの締め付け圧力を調整するための油圧締付装置等を
省くことができる。As described above, according to the water electrolysis apparatus of the present invention, since the electrolysis cell and the plurality of heat exchangers are integrally structured, the equipment can be made compact, the apparatus can be made inexpensive, and the cell A hydraulic tightening device or the like for adjusting the tightening pressure can be omitted.
【図１】本発明の実施例１における電解槽熱交換器複合
体の分解構造図である。FIG. 1 is an exploded structural view of an electrolytic cell heat exchanger complex in Example 1 of the present invention.
【図２】本発明の実施例１におけるプロセスフローを示
す図である。FIG. 2 is a diagram showing a process flow in Example 1 of the present invention.
【図３】本発明の実施例２における電解槽熱交換器複合
体の分解構造図である。FIG. 3 is an exploded structural diagram of an electrolytic cell heat exchanger complex in Example 2 of the present invention.
【図４】本発明の実施例２におけるプロセスフローを示
す図である。FIG. 4 is a diagram showing a process flow in Example 2 of the present invention.
【図５】本発明の実施例３における電解槽熱交換器複合
体の分解構造図である。FIG. 5 is an exploded structural view of an electrolytic cell heat exchanger complex according to a third embodiment of the present invention.
【図６】本発明の実施例３におけるプロセスフローを示
す図である。FIG. 6 is a diagram showing a process flow in Example 3 of the present invention.
【図７】水電解による水素及び酸素の製造に関する従来
法のプロセスフローを示す図である。FIG. 7 is a diagram showing a process flow of a conventional method for producing hydrogen and oxygen by water electrolysis.
１、水電解槽 ２、熱交換器 ３、Ｏ2気液分離器 ４、Ｏ2ガス冷却器 ５、Ｏ2Ｋ．Ｏ．ドラム ６、Ｈ2気液分離器 ７、Ｈ2ガス冷却器 ８、Ｈ2Ｋ．Ｏ．ドラム ９、循環ポンプ １０、電解槽熱交換器複合体 １１、電解セル部 １２、熱交換器部 １３、Ｏ2ガス冷却部 １４、Ｈ2ガス冷却部 １５、圧力調整部 ２０、循環ポンプ ３０、Ｏ2気液分離器 ４０、直流電源 ５０、圧力コントロールバルブ ６０、液面コントロールバルブ ７０、圧力コントロールバルブ ８０、圧力コントロールバルブ ９０、圧力コントロールバルブ １０１、Ｏ2側フランジ １０２、Ｈ2側フランジ １１１、陽極側主電極 １１２、電極接合体膜 １１３、複極板 １１４、陰極側主電極 １２１、熱交換器ノズルプレート １３１、Ｏ2ガス冷却器ノズルプレート １４１、Ｈ2ガス冷却器ノズルプレート1, water electrolysis tank 2, heat exchanger 3, O 2 gas-liquid separator 4, O 2 gas cooler 5, O 2 K.K. O. Drum 6, H 2 gas-liquid separator 7, H 2 gas cooler 8, H 2 K.K. O. Drum 9, circulation pump 10, electrolytic cell heat exchanger complex 11, electrolysis cell section 12, heat exchanger section 13, O 2 gas cooling section 14, H 2 gas cooling section 15, pressure adjusting section 20, circulation pump 30, O 2 gas-liquid separator 40, DC power supply 50, pressure control valve 60, liquid level control valve 70, pressure control valve 80, pressure control valve 90, pressure control valve 101, O 2 side flange 102, H 2 side flange 111, Anode side main electrode 112, electrode assembly film 113, bipolar plate 114, cathode side main electrode 121, heat exchanger nozzle plate 131, O 2 gas cooler nozzle plate 141, H 2 gas cooler nozzle plate
───────────────────────────────────────────────────── フロントページの続き (72)発明者 前澤 彰二 東京都港区西新橋２−８−11 第７東洋海 事ビル８階 財団法人地球環境産業技術研 究機構 ＣＯ２固定化等プロジェクト室内 (72)発明者 森 浩章 東京都港区西新橋２−８−11 第７東洋海 事ビル８階 財団法人地球環境産業技術研 究機構 ＣＯ２固定化等プロジェクト室内 (72)発明者 竹中 啓恭 大阪府池田市緑丘１丁目８番31号 工業技 術院大阪工業技術研究所内 (72)発明者 小黒 啓介 大阪府池田市緑丘１丁目８番31号 工業技 術院大阪工業技術研究所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Shoji Maesawa 2-8-11 Nishi-Shimbashi, Minato-ku, Tokyo 7th Toyo Kaijuku Building 8th Floor CO2 Immobilization Project Office (72) ) Inventor Hiroaki Mori 2-8-11 Nishi-Shimbashi, Minato-ku, Tokyo 8th floor, 7th Toyo Kaiji Building, Research Institute for Global Environmental Science and Technology, CO2 immobilization project room (72) Inventor Keiyasu Takenaka Ikeda, Osaka 1-831 Midorigaoka, Osaka City Industrial Technology Institute, Osaka Institute of Technology (72) Inventor Keisuke Oguro 1-831 Midorigaoka, Ikeda City, Osaka Prefecture Industrial Technology Institute, Osaka Institute of Industrial Technology
Claims (3)
水を電解し、陽極に酸素、陰極に水素を発生させ、複数
の熱交換器及び分離器により発生したガスを冷却し、循
環する水を熱交換させることにより常温の酸素及び水素
を製造する水電解装置において、前記の電解槽と複数の
熱交換器とを同一平面上に配置し、且つ共通の流路を内
部に設け、これらを共通のボルトで締め付けることによ
り一体化してなる電解槽熱交換器複合体としたことを特
徴とする水電解装置。1. Water is electrolyzed in a bipolar electrode cell using a polymer electrolyte membrane to generate oxygen in the anode and hydrogen in the cathode, and cool and circulate the gas generated by a plurality of heat exchangers and separators. In a water electrolysis apparatus for producing room temperature oxygen and hydrogen by heat exchange of water, the electrolyzer and a plurality of heat exchangers are arranged on the same plane, and a common flow path is provided inside, A water electrolysis device characterized in that an electrolytic cell heat exchanger composite body is obtained by integrating them by tightening them with a common bolt.
冷却部、熱交換器部、電解セル部及び水素ガス冷却部か
らなることを特徴とする請求項１記載の水電解装置。2. The water electrolysis apparatus according to claim 1, wherein the electrolytic cell heat exchanger complex comprises an oxygen gas cooling section, a heat exchanger section, an electrolysis cell section and a hydrogen gas cooling section.
極及び陰極側主電極の一方又は両方の外部に接するとこ
ろに、圧力調整部を設けたことを特徴とする請求項２記
載の水電解装置。3. The water according to claim 2, wherein a pressure adjusting portion is provided in contact with the outside of one or both of the anode-side main electrode and the cathode-side main electrode provided in the electrolytic cell section. Electrolysis device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6046438A JP2772385B2 (en) | 1994-02-21 | 1994-02-21 | Water electrolysis device using polymer electrolyte membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6046438A JP2772385B2 (en) | 1994-02-21 | 1994-02-21 | Water electrolysis device using polymer electrolyte membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07233491A true JPH07233491A (en) | 1995-09-05 |
| JP2772385B2 JP2772385B2 (en) | 1998-07-02 |
Family
ID=12747172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6046438A Expired - Lifetime JP2772385B2 (en) | 1994-02-21 | 1994-02-21 | Water electrolysis device using polymer electrolyte membrane |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2772385B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010084747A (en) * | 2000-02-29 | 2001-09-06 | 손정수 | Apparatus for generating an oxygen gas and hydrogen gas |
| KR20020017734A (en) * | 2000-08-31 | 2002-03-07 | 손정수 | Apparatus for generating a hydrogen gas and oxygen gas |
| US6698389B2 (en) * | 1996-07-16 | 2004-03-02 | Lynntech, Inc. | Electrolyzer for internal combustion engine |
| JP2011021212A (en) * | 2009-07-13 | 2011-02-03 | Honda Motor Co Ltd | Water electrolysis system |
| CN102965689A (en) * | 2012-11-19 | 2013-03-13 | 扬州中电制氢设备有限公司 | Ultrathin polar plate electrolytic cell |
| CN103114299A (en) * | 2013-02-08 | 2013-05-22 | 大连交通大学 | Electrolytic device and method for preparing boric acid by using borax |
| JP2015501386A (en) * | 2011-10-28 | 2015-01-15 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | High temperature or fuel cell electrochemical system with improved thermal management |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5254684A (en) * | 1975-10-30 | 1977-05-04 | Linde Ag | Electrolysis apparatus for pressed liquid |
| JPS5477284A (en) * | 1977-12-02 | 1979-06-20 | Asahi Glass Co Ltd | Ion exchange membrane electrolyzer |
| JPS55125284A (en) * | 1979-03-02 | 1980-09-26 | Uhde Gmbh | Hydrogen chloride * electrolysis partitioned chamber |
-
1994
- 1994-02-21 JP JP6046438A patent/JP2772385B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5254684A (en) * | 1975-10-30 | 1977-05-04 | Linde Ag | Electrolysis apparatus for pressed liquid |
| JPS5477284A (en) * | 1977-12-02 | 1979-06-20 | Asahi Glass Co Ltd | Ion exchange membrane electrolyzer |
| JPS55125284A (en) * | 1979-03-02 | 1980-09-26 | Uhde Gmbh | Hydrogen chloride * electrolysis partitioned chamber |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6698389B2 (en) * | 1996-07-16 | 2004-03-02 | Lynntech, Inc. | Electrolyzer for internal combustion engine |
| KR20010084747A (en) * | 2000-02-29 | 2001-09-06 | 손정수 | Apparatus for generating an oxygen gas and hydrogen gas |
| KR20020017734A (en) * | 2000-08-31 | 2002-03-07 | 손정수 | Apparatus for generating a hydrogen gas and oxygen gas |
| JP2011021212A (en) * | 2009-07-13 | 2011-02-03 | Honda Motor Co Ltd | Water electrolysis system |
| JP2015501386A (en) * | 2011-10-28 | 2015-01-15 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | High temperature or fuel cell electrochemical system with improved thermal management |
| US10218011B2 (en) | 2011-10-28 | 2019-02-26 | Commissariat à l'énergie atomique et aux énergies alternatives | High-temperature or fuel-cell electrochemical system having improved thermal management |
| CN102965689A (en) * | 2012-11-19 | 2013-03-13 | 扬州中电制氢设备有限公司 | Ultrathin polar plate electrolytic cell |
| CN103114299A (en) * | 2013-02-08 | 2013-05-22 | 大连交通大学 | Electrolytic device and method for preparing boric acid by using borax |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2772385B2 (en) | 1998-07-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6833207B2 (en) | Unitized regenerative fuel cell with bifunctional fuel cell humidifier and water electrolyzer | |
| US6582844B2 (en) | Method of cooling a fuel cell | |
| EP0806498B1 (en) | An apparatus for producing hydrogen and oxygen | |
| US8999135B2 (en) | PEM water electrolyser module | |
| US5879826A (en) | Proton exchange membrane fuel cell | |
| AU716927B2 (en) | Integrated reactant and coolant fluid flow field layer for fuel cell with membrane electrode assembly | |
| US6124051A (en) | Fuel cell stack with novel cooling and gas distribution systems | |
| US5846668A (en) | Fuel cell, electrolytic cell and process of cooling and/or dehumidifying same | |
| CA2392319C (en) | Water electrolyzing device | |
| CA2225728A1 (en) | Water management system for solid polymer electrolyte fuel cell power plants | |
| US7588851B2 (en) | Fuel cell stack structure | |
| US20160079624A1 (en) | Flow cell stack with single plate cells | |
| JPH07233491A (en) | Water electrolytic device using high molecular electrolyte membrane | |
| JP3522769B2 (en) | Operating method of fuel cell plant and fuel cell plant | |
| JP2893238B2 (en) | Water electrolyzer using polymer electrolyte membrane | |
| US6187155B1 (en) | Electrolytic cell separator assembly | |
| US20050211567A1 (en) | Apparatus and method for integrated hypochlorite and hydrogen fuel production and electrochemical power generation | |
| JP2001076751A (en) | Fuel cell system | |
| JP3766893B2 (en) | Hydrogen supply device using solid polymer water electrolyzer | |
| JP3991146B2 (en) | Solid polymer water electrolyzer | |
| JPH0620713A (en) | Fuel cell | |
| US20080020260A1 (en) | Apparatus, system, and method for manifolded integration of a humidification chamber for input gas for a proton exchange membrane fuel cell | |
| US20240011164A1 (en) | Gas-liquid separation device, gas-liquid separation method, electrolysis device, and electrolysis method | |
| JP2003157861A (en) | Fuel cell having water electrolyzing function | |
| JPH09316676A (en) | Cylindrical electrolytic cell and hydrogen and oxygen generator |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313115 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090424 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090424 Year of fee payment: 11 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100424 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100424 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110424 Year of fee payment: 13 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110424 Year of fee payment: 13 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120424 Year of fee payment: 14 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130424 Year of fee payment: 15 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130424 Year of fee payment: 15 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313117 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313117 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| EXPY | Cancellation because of completion of term |