JPH07101882A - Preparation containing water-soluble hemicellulose - Google Patents

Preparation containing water-soluble hemicellulose

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Publication number
JPH07101882A
JPH07101882A JP27007693A JP27007693A JPH07101882A JP H07101882 A JPH07101882 A JP H07101882A JP 27007693 A JP27007693 A JP 27007693A JP 27007693 A JP27007693 A JP 27007693A JP H07101882 A JPH07101882 A JP H07101882A
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example
hemicellulose
oil
water
product
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Japanese (ja)
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Hideo Hayashi
Yoshiko Ozawa
Chiaki Sakurada
佳子 小澤
英生 林
千晶 桜田
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Sanei Gen F F I Inc
三栄源エフ・エフ・アイ株式会社
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Abstract

PURPOSE: To obtain a preparation capable of stably providing desirable flavor, color tone, taste, etc., to foods, pet foods, quasi-drugs, etc., for a long period.
CONSTITUTION: This preparation is prepared by using a water-soluble hemicellulose as an emulsifier or a powdered substrate and using ghatti gum.
COPYRIGHT: (C)1995,JPO

Description

【発明の詳細な説明】 DETAILED DESCRIPTION OF THE INVENTION

【0001】 [0001]

【産業上の利用分野】本発明は水溶性ヘミセルロースおよび植物性天然ガム質を含有する製剤に関する。 The present invention relates to a preparation containing a water-soluble hemicellulose and vegetable natural gum. 本発明の製剤は、乳化製剤および粉末製剤を指し、飲食品、ペットフード、医薬部外品等に長期間安定で望ましい香味、色調、風味等を付与するのに使用される。 Formulations of the present invention refers to emulsion formulations and powder formulations, food products, pet food, quasi Hinto the long-term stability and desirable flavor, color tone, are used to impart flavor and the like.

【0002】 [0002]

【従来の技術】従来の乳化製剤は精油類、油溶性色素類、動植物性油脂類のような油性物質を、アラビアガムなどの植物性天然ガム質または非イオン系の界面活性剤等で乳化したものが用いられていた。 BACKGROUND ART Conventional emulsion formulation essential oils, oil-soluble dyes, oily substances such as animal and vegetable fats and oils, emulsified in vegetable natural gum or nonionic surfactants such as such as gum arabic things have been used. また、粉末製剤は油脂や親油性または水溶性の香料および色素等の調合組成物を、アラビアガム等の天然ガム、デキストリンおよび加工澱粉を配合して乳化または分散した後、噴霧乾燥する方法が知られている。 Moreover, the powder formulations are oils and lipophilic or formulation composition, such as a water soluble perfume and dye, natural gums such as gum arabic, were emulsified or dispersed by blending dextrin and modified starch, methods for spray drying known It is. この場合、天然のアラビアガムは乳化性が優れている点で広く製剤の分野で乳化剤もしくは粉末化基材として使用されているが、天然ガム質は天候、気温などの自然環境によってその生産量や品質が一定せず、価格の高騰や品質のバラツキなどの問題があり、また粉末化した場合の皮膜性については充分に安定なものではなく、噴霧乾燥中及び保存中での香味や色調、風味の劣化などが問題であった。 In this case, the natural gum arabic is used as an emulsifier or powdered substrate in the field of wide formulation in terms of its excellent emulsifying property, Ya its production natural gum weather, by natural environment such as temperature without constant quality, there are problems such as variation in rising and quality prices, also not sufficiently stable for coating property when used in powdered, flavor and color in a spray-drying and during storage, the flavor It was such deterioration is a problem. また、デキストリンや加工澱粉は乳化性や皮膜性についてアラビアガムに劣り、非イオン系の界面活性剤を用いた場合は、使用する飲食品や医薬品等のpHや含有成分によって影響を受け易いという特性があった。 Further, dextrin and modified starch is inferior in gum arabic for emulsifying and coating properties, in the case of using the surfactant nonionic, characteristic of easily affected by pH and containing ingredients such as foods and beverages and medicines to be used was there. また近年、上記物質の代替品として水溶性ヘミセルロースが検討されているが、これも乳化性および皮膜性等について充分に安定なものではない。 In recent years, although water-soluble hemicellulose has been studied as a replacement for the material, which is also not sufficiently stable for such emulsifying and film properties.

【0003】 [0003]

【発明が解決しようとする課題】上述の様に、製剤に於いては、製造過程に於ける乳化性はもとより、その包接物の安定性及び皮膜の強度に優れることが求められているが、現状では必ずしも満足されている訳ではなく、更に改善された製剤の創出は当業界の課題であった。 [SUMMARY OF THE INVENTION] As described above, at the preparation, as well the in emulsifiable in the manufacturing process, it has been required to be excellent in the strength of stability and coating of the clathrate , does not mean you are necessarily be satisfied with the status quo, was further creation of improved formulation is the subject of the art.

【0004】 [0004]

【課題を解決するための手段】本発明者らは、これらの欠点を改善するため、水溶性ヘミセルロースの乳化安定性および皮膜強度を著しく増強させる方法を鋭意研究した結果、水溶性ヘミセルロースを乳化剤あるいは粉末化基剤として用いた製剤を製造する時、植物性天然ガム質を少量添加することにより、水溶性ヘミセルロースの乳化力および皮膜強度を著しく増強させ、香料成分の耐熱性、保留性及び香料成分の放出遅延効果に優れた製剤を提供できる知見を得た。 The present inventors Means for Solving the Problems] In order to improve these drawbacks, a result of intensive study how significantly enhance emulsion stability and film strength of the water-soluble hemicellulose, soluble hemicellulose emulsifier or when preparing a formulation using a powdered base, by adding a small amount of vegetable natural gum, is greatly enhanced emulsifying power and film strength of the water-soluble hemicellulose, the heat resistance of the perfume ingredients, retention and perfume ingredients It was obtained a finding that can provide excellent formulation delayed release effect of.

【0005】ここで、植物性天然ガム質とは主にガッティガムを指す。 [0005] Here, the vegetable natural gum mainly refers to the ghatti. ガッティガムはインドの乾いた森林に育成する大木 Anogeissus latifoli Ghatti is to develop the forest, dry Indian large tree Anogeissus latifoli
aから採取され、アラビアガムの約2倍のと言う高い乳化力を持つと言われている。 Taken from a, is said to have a high emulsifying power to say that about 2-fold of the gum arabic. 本発明は、製剤を製造する時、水溶性ヘミセルロースを乳化剤あるいは粉末化基剤として用い、かつ、植物性天然ガム質を少量添加することにより、製造時における乳化性、乳化安定性が優れ、 The present invention is, when manufacturing the formulations, using a water-soluble hemicellulose as an emulsifier or a powdered base, and, by adding a small amount of vegetable natural gum, emulsifying during manufacture, the emulsion stability good,
粉末化後の包接物の安定性、基剤皮膜の強度を増強させ、食品等に長期間安定な香気、色調、風味等を付与することによる。 Stability of inclusions after powdered, enhanced the strength of the base film, long-term stable aroma to foods, by applying color, flavor and the like.

【0006】本発明で用いる油性物質の例としては、例えばオレンジ、ライム、レモン、グレープフルーツなどの柑橘類精油、ペパーミントオイル、シソオイル、などのスパイス類の精油、ペパー、シンナモン、ジンジャーなどのオレオレジン、ジャスミン、ローズなどのアブソリュート、および合成香料化合物、油性調合香料組成物およびこれらの任意の混合物の如き油性の着香料、β− [0006] Examples of the oily substance used in the present invention, such as orange, lime, lemon, citrus essential oils such as grapefruit, peppermint oil, Shisooiru, spices essential oils such as pepper, cinnamon, oleoresin such as ginger, jasmine , absolute, such as rose, and synthetic perfume compounds, oily blended fragrance compositions and flavorings of such oily any mixture thereof, beta-
カロチン、パプリカ色素、アナトー色素、およびクロロフィルなどの油溶性天然色素類、更に肝油、ビタミンA、ビタミンD、ビタミンB2酪酸エステル、天然ビタミンE混合物などの脂溶性ビタミン類、大豆油、菜種油、コーン油、オリーブ油、椰子油、サフラワー油、ひまわり油、米油、牛脂、豚脂、魚油などの動植物油脂、 Carotene, oil-soluble natural dyes of paprika pigments, annatto pigments, and the like chlorophyll, further liver oil, vitamin A, vitamin D, vitamin B2 butyrate, fat-soluble vitamins such as natural vitamin E mixtures, soybean oil, rapeseed oil, corn oil , olive oil, coconut oil, safflower oil, sunflower oil, rice oil, beef tallow, lard, animal and vegetable fats and oils, such as fish oil,
DHA、EPA、γ−リノレン酸などの天然不飽和脂肪酸類、シュクロースジアセテートヘキサイソブチレート、C6〜C12の中鎖飽和脂肪酸トリグリセライドなどの加工食用油脂およびこれら可食性油性材料の任意の混合物を例示することができる。 DHA, EPA, natural unsaturated fatty acids such as γ- linolenic acid, sucrose diacetate hexa-isobutyrate, mixtures of any of the processing edible oils and fats and their edible oleaginous material, such as medium chain saturated fatty acid triglyceride of C6~C12 it can be exemplified. 水溶性物質としては、 Examples of the water-soluble substance,
例えばコーヒー、ハーブ、抹茶、紅茶、ガラナ、カツオ、エビ、カニ、ウニ、ホタテなどのエキストラクト、 For example, coffee, herbs, green tea, black tea, guarana, bonito, shrimp, crabs, sea urchins, extract, such as scallops,
ストロベリー、メロン、バナナ、パイナップル、アップル、ミルク、チーズ、バター、などのエッセンス、コチニール、ベニバナ、ビート、ウコン等の水溶性色素、その他合成着香料、合成着色料、およびこれらの任意の混合物を例示することができる。 Strawberry, illustration melon, banana, pineapple, apple, milk, cheese, essence of butter, such as cochineal, safflower, beet, water-soluble dyes turmeric etc., other synthetic flavoring, artificial coloring, and any mixture thereof can do.

【0007】本発明に利用することのできる水溶性ヘミセルロースとしては例えば油糧種子(大豆、パーム、ヤシ、コーン、綿実などの通常油脂や蛋白質を除いた殻) [0007] For example oilseed as water-soluble hemicellulose which can be utilized in the present invention (soya, shells, except palm, coconut, corn, normal fat and protein such as cottonseed)
または穀類(米、小麦など通常澱粉等を除いた粕)等の植物を原料とした水溶性の食物繊維、すなわちアラビノキシラン、アラビノガラクタン等の多糖類、またはこれらの任意の混合物を例示することができる。 Or cereals soluble dietary fiber and the like plants (rice, meal excluding normal starch such as wheat) was used as a raw material, i.e. arabinoxylan, arabinogalactan like polysaccharides or be exemplified any mixture thereof, it can. このような水溶性ヘミセルロースを製剤100部(重量、以下同じ)に対して0.1〜98部、好ましくは5〜50部の割合で含有させる。 0.1 to 98 parts per Formulation 100 parts of the water-soluble hemicellulose (wt, hereinafter the same), preferably is contained in an amount of 5 to 50 parts.

【0008】本発明で利用する植物性天然ガム質は、主にガッティガムであるが、場合により、アラビアガム、 [0008] vegetable natural gum utilized in the present invention is predominantly ghatti, optionally, gum arabic,
タラガム、グワーガム、カラヤガム、キサンタンガム等と併用して用いても良い。 Tara, Guwagamu, karaya, may also be used in combination with xanthan gum and the like. ガッティガム単品あるいは前述の天然ガム質との混合物を製剤100部に対して0. 0 The mixture of the formulation 100 parts of the gum ghatti separately or above the natural gum.
01〜30部、好ましくは0.05〜15部の割合で含有させる。 01 to 30 parts, preferably is contained in an amount of 0.05 to 15 parts. 本発明で用いる乳化方法としては、コロイドミル、ホモミキサー、高圧ホモジナイザー、超音波乳化機等どのようなものでも良く、又、粉末化方法としてもどのようなタイプの噴霧乾燥法でも良い。 As emulsification method used in the present invention, a colloid mill, homomixer, high-pressure homogenizer, is good of any type ultrasonic emulsifier or the like, or may be any type of spray drying method as powdering method. 以下、本発明の効果を実施例を示して更に具体的に説明する。 Hereinafter, more detailed explanation of the effects of the present invention by showing Examples.

【0009】 [0009]

【実施例】 【Example】

実施例1 DHA油8g、天然ビタミンE0.1g、精製椰子油1.9gの混合物を均一に混合して油性材料混合物を得た。 Example 1 DHA oil 8 g, natural vitamin E0.1G, by uniformly mixing a mixture of refined coconut oil 1.9g obtain an oily material mixture. 別に水63gに大豆ヘミセルロース25g、ガッティガム2gを溶解した溶液を得、前述の油性材料混合物の全量を加えて予備撹拌させ、分散させた後、ホモジナイザーにて乳化し、DHA油乳化物(本発明品No. Separately resulting aqueous 63g soybean hemicellulose 25 g, a solution of ghatti 2g, was pre stirred with the entire amount of the oily material the above mixture was dispersed, and emulsified by a homogenizer, DHA oil emulsion (present invention product No.
1)を得た。 1) was obtained.

【0010】実施例2 ライムオイル3g、天然ビタミンE0.1g、中鎖飽和脂肪酸トリグリセライド8.5gを溶解して、均一な油性材料混合物を得た。 [0010] Example 2 lime oil 3g, dissolved natural vitamin E0.1G, a medium-chain saturated fatty acid triglyceride 8.5 g, to obtain a homogeneous oily material mixture. 別に水69gに大豆ヘミセルロース20g、ガッティガム1gを溶解した溶液を得、前述の油性材料混合物の全量を加えて予備撹拌させ、分散させた後、ホモジナイザーにて乳化し、ライム油乳化物(本発明品No.2)を得た。 Separately resulting aqueous 69g soybean hemicellulose 20g, a solution of ghatti 1g, after prereacted stirred with the entire amount of the oily material the above mixture was dispersed, and emulsified by a homogenizer, lime oil emulsion (present invention product No.2) was obtained.

【0011】実施例3 イオン交換水200gに大豆ヘミセルロース85g、ガッティガム2g、アラビアガム3gを溶解し、50℃に保持しながらグレープフルーツオイル20gを添加混合する。 [0011] EXAMPLE 3 Ion exchange water 200g soybean hemicellulose 85 g, ghatti 2g, was dissolved arabic gum 3g, admixed grapefruit oil 20g while maintaining the 50 ° C.. この溶液を高圧ホモジナイザーにて乳化し、乳化液を噴霧乾燥してグレープフルーツ香料粉末100g This solution was emulsified in a high pressure homogenizer, grapefruit flavor powder 100g The emulsion was spray-dried
(本発明品No.3)を得た。 Was obtained (Invention Product No.3).

【0012】実施例4 イオン交換水200gにコーンヘミセルロース70gとシュークロース40g、ガッティガム3gを溶解し、5 [0012] Example 4 Ion exchange water 200g corn hemicellulose 70g and sucrose 40 g, was dissolved ghatti 3 g, 5
0℃に保持しながらメントールを12g含んだオイル1 0 ℃ containing menthol 12g while maintaining the oil 1
5gを添加混合する。 Added and mixed 5g. この溶液を高圧ホモジナイザーにて乳化し、乳化液を噴霧乾燥してメントール香料粉末1 This solution was emulsified in a high pressure homogenizer, menthol flavor powder 1 an emulsion by spray-drying
00g(本発明品No.4)を得た。 It was obtained 00g (the product of the present invention No.4).

【0013】実施例5 イオン交換水200gに大豆ヘミセルロース80g、ガッティガム2gを溶解し、50℃に保持しながらβ−カロチン30%懸濁液1.2gを含んだオイル20gを1 [0013] Soybean Hemicellulose 80g Example 5 Ion exchange water 200 g, was dissolved ghatti 2g, oil 20g containing β- carotene 30% suspension 1.2g while maintaining the 50 ° C. 1
40℃に加熱して添加混合する。 It added mixed and heated to 40 ° C.. この溶液を高圧ホモジナイザーで乳化し、乳化液を噴霧乾燥して着色料粉末1 This solution was emulsified in a high pressure homogenizer, an emulsion was spray-dried colorant powder 1
00g(本発明品No.5)を得た。 00g was obtained (the product of the present invention No.5).

【0014】対照例1 実施例1においてガッティガムを使用せず、その重量不足分を大豆ヘミセルロースで補った他は実施例1と同じ条件によってDHA油乳化物(対照品No.1)を得た。 [0014] without the use of gum ghatti in Control Example 1 Example 1 to obtain DHA oil emulsion (controls No.1) under the same conditions the weight shortfall with other embodiments 1 supplemented with soybean hemicellulose.

【0015】対照例2 実施例2においてガッティガムを使用せず、その重量不足分を大豆ヘミセルロースで補った他は実施例2と同じ条件によってライム油乳化物(対照品No.2)を得た。 [0015] without the use of gum ghatti in Control Example 2 Example 2 to give lime oil emulsion (controls No.2) under the same conditions the weight shortfall with other embodiment 2 supplemented with soybean hemicellulose.

【0016】対照例3 実施例2において大豆ヘミセルロースの代わりにアラビアガムを使用した他は実施例2と同じ条件によってライム油乳化物(対照品No.3)を得た。 [0016] to give lime oil emulsion (controls No.3) under the same conditions as in Example 2 except that using gum arabic instead of soybean hemicellulose in Comparison Example 3 Example 2.

【0017】対照例4 実施例3において大豆ヘミセルロースの代わりにアラビアガムを使用した他は実施例3と同じ条件によってグレープフルーツ香料粉末100g(対照品No.4)を得た。 [0017] to obtain a control example 4 except that using gum arabic instead of soybean hemicellulose In Example 3 Example 3 grapefruit flavor powder by the same conditions as 100 g (control product No.4).

【0018】対照例5 実施例3において大豆ヘミセルロースの代わりに加工澱粉を使用した他は実施例3と同じ条件によってグレープフルーツ香料粉末100g(対照品No.5)を得た。 [0018] to give the Comparison Example 5 Example except that using the processed starch instead of soybean hemicellulose in 3 Example 3 grapefruit flavor by the same conditions as powder 100 g (control product No.5).

【0019】対照例6 実施例3において大豆ヘミセルロースの代わりにデキストリンを使用した他は実施例3と同じ条件によってグレープフルーツ油乳化物(対照品No.6)を得た。 [0019] was obtained grapefruit oil emulsion (controls No.6) by the same conditions as the other Example 3 using dextrin instead of soybean hemicellulose in Control Example 6 Example 3.

【0020】対照例7 実施例3においてガッティガムを使用せず、その重量不足分を大豆ヘミセルロースで補った他は実施例3と同じ条件によってグレープフルーツ香料粉末100g(対照品No.7)を得た。 [0020] without the use of gum ghatti in control Example 7 Example 3 was obtained grapefruit flavor powder 100g (controls No.7) under the same conditions as other embodiments 3 supplemented with the weight shortfall in soybean hemicellulose.

【0021】対照例8 実施例4においてコーンヘミセルロースの代わりにアラビアガムを使用した他は実施例4と同じ条件によってメントール香料粉末100g(対照品No.8)を得た。 [0021] to give the Comparison Example 8 Example 4 Menthol flavor powder other using gum arabic instead of the cone hemicellulose under the same conditions as in Example 4 in 100 g (control product No.8).

【0022】対照例9 実施例4においてガッティガムを使用せず、その重量不足分をコーンヘミセルロースで補った他は実施例4と同じ条件によってメントール香料粉末100g(対照品N [0022] Comparison Example 9 In Example 4 without using ghatti, the menthol flavoring powder except that the weight shortfall supplemented with corn hemicellulose under the same conditions as in Example 4 100 g (control product N
o. o. 9)を得た。 9) was obtained.

【0023】対照例10 実施例5において大豆ヘミセルロースの代わりにアラビアガムを使用した他は実施例5と同じ条件によって着色料粉末100g(対照品No.10)を得た。 [0023] to obtain a coloring powder 100 g (control product No.10) by the same conditions as other Example 5 using the gum arabic instead of soybean hemicellulose in Control Example 10 Example 5.

【0024】対照例11 実施例5において大豆ヘミセルロースの代わりに加工澱粉を使用した他は実施例5と同じ条件によって着色料粉末100g(対照品No.11)を得た。 [0024] to obtain a coloring powder 100g other using modified starch instead of soybean hemicellulose in the control Example 11 Example 5 is the same conditions as in Example 5 (control product No.11).

【0025】対照例12 実施例5においてガッティガムを使用せず、その重量不足分を大豆ヘミセルロースで補った他は実施例5と同じ条件によって着色料粉末100g(対照品No.12) [0025] Control Example 12 Example 5 without using ghatti in, coloring powder 100g other supplemented with the weight shortfall in soybean hemicellulose under the same conditions as in Example 5 (control sample No.12)
を得た。 It was obtained.

【0026】比較実験1 実施例1および対照例1で得た乳化組成物を同一日に調製し、レーザー回折式粒度分布計 SALD−1100 [0026] The emulsion composition obtained in Comparative Experiment 1 Example 1 and Control Example 1 was prepared in the same day, a laser diffraction particle size distribution analyzer SALD-1100
((株)島津製作所)を用いて粒度分布を測定した。 A particle size distribution was measured using a (Shimadzu Corporation).
その結果を表1に示す。 The results are shown in Table 1.

【0027】 [0027]

【表1】 [Table 1]

【0028】以上の結果から明らかな通り、本発明品N The more obvious from the results, the product of the present invention N
o. o. 1は、対照品No. 1, control sample No. 1に較べて水溶性ヘミセルロースの乳化力が非常に高くなり、より微細な粒子が得られた。 Emulsifying power of the water-soluble hemicellulose is very high compared to 1, finer particles were obtained.

【0029】比較実験2 実施例2および対照例2、対照例3のライム油乳化物を同一日に調製し、レーザー回折式粒度分布計 SALD [0029] Comparative Experiment 2 Example 2 and Control Example 2, the lime oil emulsion of Reference Example 3 was prepared in the same day, a laser diffraction particle size distribution meter SALD
−1100 ((株)島津製作所)を用いて粒度分布を測定した。 -1100 (the Shimadzu Corporation) to measure the particle size distribution using. また、同時にグラニュー糖120g、クエン酸4g、を125gの水に溶解し、この溶液に実施例2 At the same time it is dissolving granulated sugar 120 g, citric acid 4g, in water of 125 g, carried to the solution Example 2
および対照例2、対照例3で得られた乳化物を1兼Y加し、炭酸水にて全体を1獅ニした。 And Reference Example 2, and 1 and Y pressurizing the resulting emulsion in Reference Example 3 was 1 獅Ni across at carbonated water. 瓶に充填後打栓し、 And capping after filling the bottle,
炭酸飲料を得た。 To obtain a carbonated beverage. これを室温で静置し、経時変化を観察した。 This was allowed to stand at room temperature, and observed the change with time. 結果を表2に示す。 The results are shown in Table 2.

【0030】 [0030]

【表2】 [Table 2]

【0031】表中の各記号は下記の意味を表す。 [0031] Each symbol in the table represent the following meanings. −R: ネックリングの発生は認められない。 -R: the occurrence of neck ring is not permitted. ±R: ネックリングを僅かに認める。 ± R: slightly admit the neck ring. +R: 明瞭なネックリングを認める。 + R: admit a clear neck ring. ++R: 著しいネックリングを認める。 ++ R: acknowledge the significant neck ring. −P: 沈澱は認められない。 -P: precipitation is not observed. ±P: 沈澱を僅かに認める。 ± P: slightly admit precipitation. +P: 明瞭な沈澱を認める。 + P: admit a clear precipitation. ++P: 著しい沈澱を認める。 ++ P: acknowledge the significant precipitation.

【0032】表2の結果から明らかな通り、本発明品N [0032] As is apparent from the results in Table 2, the product of the present invention N
o. o. 2は、対照品No. 2, control sample No. 2に較べて水溶性ヘミセルロースの乳化力が非常に高くなり、対照品No. Emulsifying power of the water-soluble hemicellulose as compared with the 2 becomes very high, control product No. 3(アラビアガム)よりもやや高い乳化力を示した。 3 shows a slightly higher emulsifying power than the (gum arabic). また、炭酸飲料を室温で約30日静置したところ、対照品No. In addition, it was allowed to stand for about 30 days at room temperature carbonated beverages, control product No. 2では著しいネックリングの発生を認め、商品価値を失った。 In the two recognized the occurrence of a significant neck ring, it lost its commercial value. これに対し、本発明品No. On the other hand, the product of the present invention No. 2および対照品No. 2 and the control product No.
3ではネックリングの発生、沈澱とも認められず安定な炭酸飲料であった。 3, the occurrence of the neck ring, precipitation and was stable carbonated beverages not be observed.

【0033】比較実験3 実施例3および対照例4〜7で得たグレープフルーツ香料粉末を、40℃にて保存し、経時変化を観察した。 The grapefruit flavor powder obtained in Comparative Experiment 3 Example 3 and Reference Example 4-7, and stored at 40 ° C., and observed the change with time. また、グレープフルーツオイルを乳化した際の乳化性についても併せて評価した。 It was also evaluated together also emulsifying properties when emulsified grapefruit oil. その結果を表3に示す。 The results are shown in Table 3.

【0034】 [0034]

【表3】 [Table 3]

【0035】但し表中の各記号は下記の意味を示す。 [0035] wherein each symbol in the table indicates the following meanings. ◎:極めて良好 ○:良好 △:やや悪い ×: ◎: very good ○: good △: Slightly bad ×:
悪い −:評価不能 Bad -: non-evaluable

【0036】表3の結果から明らかなとおり、本発明品No. [0036] As is clear from the results in Table 3, the product of the present invention No. 3は乳化性が良く、保存後6ケ月を経過しても基剤皮膜の強度が優れており、香味の損失も無かったのに対し、対照品No. 3 has good emulsifying properties, even after 6 months after storage has excellent strength of the base material film, whereas the loss of flavor there was no, control product No. 4ではやや乳化性が劣り、基剤皮膜の強度および香味は経時的に低下した。 Slightly emulsifiable in 4 poor, the strength and flavor of base film was decreased over time. その傾向は対照品No. The trend is control product No. 7、対照品No. 7, control product No. 5の順で顕著になる。 It becomes remarkable 5 of the order in. また対照品No. The control product No. 6では乳化が行えなかった。 In 6 emulsification it could not be performed.

【0037】比較実験4 実施例4および対照例8〜9のメントール香料粉末を密封容器に入れ、40℃にて保存後開封し、メントール含量をガスクロマトグラフィーで測定した。 [0037] Put the menthol flavoring powder of Comparative Experiment 4 Example 4 and Control Examples 8-9 in a sealed container, and opened after storage at 40 ° C., was measured menthol content by gas chromatography.

【0038】 [0038]

【表4】 [Table 4]

【0039】・表中の値は試料のメントール含量を示す。 The value of in-table shows the menthol content of the sample. ・( )内の数値は調整時の含量に対する残存率を%で示している。 · () Numbers in indicates the residual ratio for the content at the time of adjustment in%.

【0040】表4の結果から明らかな通り、本発明品N [0040] As is apparent from the results in Table 4, the product of the present invention N
o. o. 4は6ケ月の保存後もメントール含量が低下しないのに対し、対照品No. 4 whereas menthol content even after storage for 6 months is not reduced, control product No. 8および対照品No. 8 and the control product No. 9では経時的にメントール含量が低下し、包接物の損失が認められた。 Over time menthol content decrease in 9, loss of inclusion complex was observed.

【0041】比較実験5 下記に示すチューインガム基材に実施例3で得られたグレープフルーツ粉末香料(本発明品No.3)と対照例4、5、7で得られたグレープフルーツ粉末香料(対照品No.4、5、7)をそれぞれ添加し、混練して圧展成型し、1枚3gのチューインガムを得た。 [0041] Comparative Experiment 5 grapefruit powdered flavor obtained in Example 3 in a chewing gum base material shown below (present invention product No.3) and grapefruit powdered flavor obtained in Reference Example 4, 5 and 7 (controls No .4,5,7) were respectively added, kneaded and 圧展 molded to obtain a chewing gum in one 3g. チューインガム基材組成を表5に示す。 The chewing gum base composition shown in Table 5.

【0042】 [0042]

【表5】 [Table 5]

【0043】これらのチューインガムについて10名の専門パネラーによって官能評価した結果、本発明品は対照例と比較してフレーバーの強さには大きな差がないが持続性、残留性の点で顕著に優れていると判定した。 The result of the sensory evaluation by professional 10 panelists for these chewing gums, the product of the present invention Control Example as compared to but sustained no significant difference in the strength of flavor, significantly superior in terms of residual and it was determined that.

【0044】比較実験6 実施例5および対照例10〜12で得た着色料粉末のβ The colorant powder obtained in Comparative Experiment 6 Example 5 and Control Examples 10 to 12 beta
−カロチン含量を測定した。 - was measured carotene content. 結果を表6に示す。 The results are shown in Table 6.

【0045】 [0045]

【表6】 [Table 6]

【0046】・表中の値は試料中に含まれるβ−カロチンの含量を%で示している。 The values ​​in-table is shown in the content of β- carotene contained in the sample%. ・( )内の数値は添加時の含量に対する残存率を%でしめしている。 - Values ​​in brackets indicates the residual ratio for the content at the time of addition at%.

【0047】表6の結果から明らかな通り、本発明品N [0047] As is apparent from the results in Table 6, the product of the present invention N
o. o. 5は、粉末化に際し殆どβ−カロチンの損失が認められず、対照品No. 5, it is not observed loss of most β- carotene Upon powdered, control product No. 10、11、12と比較して、優れた包接物安定性を示した。 10, 11, 12 as compared to, showed excellent inclusion complex stability.

【0048】 [0048]

【発明の効果】本発明によって得られた製剤は、実施例の結果から明らかなように製造工程に於ける乳化性や乳化安定性が極めて良好で、粉末化する場合についても粉末化後の包接物の安定性、皮膜の強度が特に優れており、各種食品等に長期間安定で望ましい香味、色調、風味等を付与することができるため、工業的意義は極めて大である。 Preparations obtained by the present invention exhibits, obviously very good in emulsifiability and emulsion stability in the manufacturing process as the results of Examples, follicles after pulverization even for the case of powdered stability of abutment, and excellent strength of the film is particularly, long-term stability and desirable flavor to various foods, color, since it is possible to impart flavor, etc., industrial significance is very large.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl. 6識別記号 庁内整理番号 FI 技術表示箇所 A61K 9/14 // A23L 1/22 A 1/275 ────────────────────────────────────────────────── ─── front page continued (51) Int.Cl. 6 identification symbol Agency Docket No. FI art display portion A61K 9/14 // A23L 1/22 a 1/275

Claims (3)

    【特許請求の範囲】 [The claims]
  1. 【請求項1】 水溶性ヘミセルロースおよび植物性天然ガム質を含有することを特徴とする製剤。 1. A preparation characterized by containing a water-soluble hemicellulose and vegetable natural gum.
  2. 【請求項2】 水溶性ヘミセルロースが大豆、とうもろこし、米ぬかを原料とする多糖類である請求項1記載の製剤。 2. A water-soluble hemicellulose is soybean, corn, preparation according to claim 1, wherein a polysaccharide rice bran as a raw material.
  3. 【請求項3】 植物性天然ガム質が、ガッティガムであることを特徴とする請求項1記載の製剤。 3. A vegetable natural gum is, formulation according to claim 1, wherein it is a ghatti.
JP27007693A 1993-09-30 1993-09-30 Preparation containing water-soluble hemicellulose Pending JPH07101882A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27007693A JPH07101882A (en) 1993-09-30 1993-09-30 Preparation containing water-soluble hemicellulose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27007693A JPH07101882A (en) 1993-09-30 1993-09-30 Preparation containing water-soluble hemicellulose

Publications (1)

Publication Number Publication Date
JPH07101882A true true JPH07101882A (en) 1995-04-18

Family

ID=17481197

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27007693A Pending JPH07101882A (en) 1993-09-30 1993-09-30 Preparation containing water-soluble hemicellulose

Country Status (1)

Country Link
JP (1) JPH07101882A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6261622B1 (en) * 1997-08-13 2001-07-17 Kagome Co., Ltd. Water-dispersible carotenoid pigment preparation
WO2004094595A2 (en) 2003-04-17 2004-11-04 Alnylam Pharmaceuticals Inc. MODIFIED iRNA AGENTS
WO2004094345A2 (en) 2003-04-17 2004-11-04 Alnylam Pharmaceuticals Inc. Protected monomers
WO2007046333A1 (en) * 2005-10-19 2007-04-26 San-Ei Gen F.F.I., Inc. Emulsifying agent and emulsion composition prepared with the same
WO2011036811A1 (en) * 2009-09-28 2011-03-31 三栄源エフ・エフ・アイ株式会社 Turmeric pigment composition and method for preparing same
WO2011109427A2 (en) 2010-03-01 2011-09-09 Alnylam Pharmaceuticals, Inc. Improving the biological activity of sirna through modulation of its thermodynamic profile
WO2016057693A1 (en) 2014-10-10 2016-04-14 Alnylam Pharmaceuticals, Inc. Methods and compositions for inhalation delivery of conjugated oligonucleotide
EP3141265A1 (en) 2007-12-04 2017-03-15 Alnylam Pharmaceuticals, Inc. Carbohydrate conjugates as delivery agents for oligonucleotides
US9808030B2 (en) 2011-02-11 2017-11-07 Grain Processing Corporation Salt composition

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6261622B1 (en) * 1997-08-13 2001-07-17 Kagome Co., Ltd. Water-dispersible carotenoid pigment preparation
EP2660322A2 (en) 2003-04-17 2013-11-06 Alnylam Pharmaceuticals Inc. Modified iRNA agents
WO2004094595A2 (en) 2003-04-17 2004-11-04 Alnylam Pharmaceuticals Inc. MODIFIED iRNA AGENTS
WO2004094345A2 (en) 2003-04-17 2004-11-04 Alnylam Pharmaceuticals Inc. Protected monomers
EP2669377A2 (en) 2003-04-17 2013-12-04 Alnylam Pharmaceuticals Inc. Modified iRNA agents
EP2666858A1 (en) 2003-04-17 2013-11-27 Alnylam Pharmaceuticals Inc. Modified iRNA agents
EP2664672A1 (en) 2003-04-17 2013-11-20 Alnylam Pharmaceuticals Inc. Modified iRNA agents
WO2007046333A1 (en) * 2005-10-19 2007-04-26 San-Ei Gen F.F.I., Inc. Emulsifying agent and emulsion composition prepared with the same
EP3141265A1 (en) 2007-12-04 2017-03-15 Alnylam Pharmaceuticals, Inc. Carbohydrate conjugates as delivery agents for oligonucleotides
US10023745B2 (en) 2009-09-28 2018-07-17 San-Ei Gen F.F.I., Inc. Turmeric pigment composition and method for preparing same
WO2011036811A1 (en) * 2009-09-28 2011-03-31 三栄源エフ・エフ・アイ株式会社 Turmeric pigment composition and method for preparing same
WO2011109427A2 (en) 2010-03-01 2011-09-09 Alnylam Pharmaceuticals, Inc. Improving the biological activity of sirna through modulation of its thermodynamic profile
US9808030B2 (en) 2011-02-11 2017-11-07 Grain Processing Corporation Salt composition
WO2016057693A1 (en) 2014-10-10 2016-04-14 Alnylam Pharmaceuticals, Inc. Methods and compositions for inhalation delivery of conjugated oligonucleotide

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