JPH0678030B2 - Inkujietsuto for the recording material - Google Patents

Inkujietsuto for the recording material

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Publication number
JPH0678030B2
JPH0678030B2 JP12077685A JP12077685A JPH0678030B2 JP H0678030 B2 JPH0678030 B2 JP H0678030B2 JP 12077685 A JP12077685 A JP 12077685A JP 12077685 A JP12077685 A JP 12077685A JP H0678030 B2 JPH0678030 B2 JP H0678030B2
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JP
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Grant
Patent type
Prior art keywords
recording
inkujietsuto
recording material
example
cationic compound
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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JP12077685A
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Japanese (ja)
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JPS61277484A (en )
Inventor
和夫 三ツ橋
近衛 三浦
浩 滝本
Original Assignee
三菱化成株式会社
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5227Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、インクジエツト記録法に用いられる被記録材に関する。 DETAILED DESCRIPTION OF THE INVENTION INDUSTRIAL FIELD The present invention relates to a recording material for use in Inkujietsuto recording.

従来の技術 従来、記録紙にインクを噴射して記録像を形成させるインクジエツト記録法において、該記録紙にハロゲン化第四級アンモニウム等の陽イオン性界面活性剤を含有させて耐水性を付与する方法が知られている(特開昭56−99 Description of the Related Art Conventionally, in Inkujietsuto recording method by ejecting ink to form a recorded image on the recording paper, contain a cationic surfactant such as quaternary ammonium halides imparting water resistance to the recording paper methods are known (JP-a-56-99
693号公報)。 693 JP).

しかし、このような記録紙を使用すると、記録材(染料等)の耐光性が著しく低下するという欠点があつた。 However, the use of such recording paper, there has been a drawback that the light resistance of the recording material (dye or the like) is significantly reduced.

発明が解決しようとする問題点 本発明は、耐光性の良好なインクジエツト用被記録材を提供することを目的とするものである。 INVENTION try to Problems The present invention solves, it is an object to provide light resistance good Inkujietsuto for recording material.

問題点を解決するための手段 すなわち本発明は、下記一般式〔I〕又は〔II〕で表わされるカチオン化合物を含有することを特徴とするインクジエツト用被記録材。 Means or the invention for solving the problem, Inkujietsuto for the recording material characterized by containing a cationic compound represented by the following general formula [I] or [II].

一般式 The general formula (式中、R 1は炭素数15〜25の炭化水素残基を表わし、m (In the formula, R 1 represents a hydrocarbon residue of 15 to 25 carbon atoms, m
およびnは両者の和が4〜8となる整数を表わしXはハロゲン原子を表わす)、 一般式 And n X represents the integer sum of both is 4-8 represents a halogen atom), general formula (式中、R 2は炭素数10〜25の炭化水素残基を表わし、X (Wherein, R 2 represents a hydrocarbon residue of 10 to 25 carbon atoms, X
はハロゲン原子を表わす) を要旨とするものである。 Is to summarized as a halogen atom).

本発明のインクジエツト用被記録材の基材としては、代表的には紙を挙げることができるが、布、樹脂フイルムあるいは合成紙等も基材として使用することができる。 The base material of Inkujietsuto for the recording material of the present invention, but typically may be mentioned paper, cloth, resin film or synthetic paper may be used as the substrate.

上記本発明のインクジエツト用被記録材を製造する方法としては、 (a)抄紙工程において、上記一般式〔I〕又は〔II〕 As a method for producing a Inkujietsuto for the recording material of the present invention, (a) in the papermaking process, the general formula [I] or [II]
で表わされるカチオン化合物の水溶液を使用して製紙する方法、 (b)含浸液に上記一般式〔I〕又は〔II〕で表わされるカチオン化合物を添加し、これに基材を浸漬する方法、 (c)塗工液に上記一般式〔I〕又は〔II〕で表わされるカチオン化合物を添加し、この塗工液を基材上に塗布し、乾燥させる方法、 等が挙げられる。 In a method of papermaking by using an aqueous solution of a cationic compound represented, (b) a method of adding a cationic compound represented by the above general formula in the impregnation solution [I] or [II], immersing the base material to, ( was added represented by cationic compounds c) coating solution to the above general formula [I] or [II], the coating liquid was coated on a substrate, method of drying, and the like.

上記被記録材の製造方法(a)及び(b)において、上記カチオン化合物の水溶液の濃度は、水溶液の呈する粘度及び該化合物カチオン化合物の溶解度によつて最適な範囲は異なるが、0.05〜2重量%の範囲が挙げられる。 In the manufacturing method of the recording material (a) and (b), the concentration of the aqueous solution of the cationic compound, the optimal range Te cowpea on the solubility of the viscosity of the compound and the cationic compound exhibited by the aqueous solution are different, 0.05-2 wt % range of the like.

そして、基材に含有させる該カチオン化合物の量としては、基材に対して0.05〜2重量%の範囲が挙げられ、該カチオン化合物の量が多過ぎるとインクの吸収が低下するため好ましくない。 Then, the amount of the cationic compound contained in the base material, the range of 0.05 to 2% by weight are listed for the base material is not preferable because the amount of the cationic compound is too large ink absorption decreases.

また、上記被記録材の製造方法(c)において、塗工液としては、上記カチオン化合物の他に従来公知の種々の成分が加えられてよく、例えば微粉ケイ酸、クレー、タルク、ケイソウ土、炭酸カルシウム、硫酸カルシウム、 Further, the method of manufacturing a recording medium (c), as the coating solution may in addition to conventionally known various components are added in the cationic compound, for example finely divided silicic acid, clay, talc, diatomaceous earth, calcium carbonate, calcium sulfate,
硫酸バリウム、酸化チタン、酸化亜鉛、サチンホワイト、ケイ酸アルミニウム、リトボン等の無機質顔料類; Barium sulfate, titanium oxide, zinc oxide, satin white, aluminum silicate, inorganic pigments such as lithopone;
デンプン、ゼラチン、カゼイン、アラビアゴム、アルギン酸ソーダ、カルボキシメチルセルロース、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ソーダ等の水溶性高分子;合成ゴムラテツクス等の合成樹脂ラテツクス;ポリビニルブチラール、ポリビニルクロライド等の有機溶剤可溶性樹脂;更には分散剤螢光染料、pH調整剤、消泡剤、潤滑剤、防腐剤、界面活性剤等の各種添加剤を挙げることができる。 Synthetic resin latexes of synthetic Gomuratetsukusu like; starch, gelatin, casein, gum arabic, sodium alginate, carboxymethylcellulose, polyvinyl alcohol, polyvinyl pyrrolidone, water-soluble polymers such as sodium polyacrylate polyvinyl butyral, an organic solvent-soluble, such as polyvinyl chloride resin; and may be exemplified dispersant fluorescent dye, pH adjusting agents, antifoaming agents, lubricants, preservatives, various additives such as a surfactant.

塗工液に加えられる該カチオン化合物の量としては、0. The amount of the cationic compound to be added to the coating solution, 0.
03〜5重量%の範囲が挙げられる。 03-5% by weight in the range thereof. そして、該塗工液は、公知の手法(例えばロールコーター法、ブレードコーター法、エアナイフコーター法)により、通常1〜50 The coating Koeki a known technique (for example a roll coater method, blade coater method, an air knife coater method) by, 1 to 50
g/m 2 、好ましくは2〜30g/m 2 (乾燥塗工量)の範囲の量を基材上に塗工する。 g / m 2, preferably to coat the amount ranging from 2 to 30 g / m 2 (dry coating amount) on the substrate.

効果 本発明のインクジエツト用被記録材は、インクが速やかにその内部に吸収され、異色の記録液が短時間内に同一箇所に重複して付着した場合にも記録液の流れ出しや滲み出し現象がなく、高解像度の鮮明な画像を与えるものである。 Inkujietsuto for the recording material of the advantages the present invention, ink is rapidly absorbed therein, flows out and oozed phenomenon also recording liquid when the recording liquid different color adheres overlap at the same position in a short time rather, it is intended to provide a clear image of high resolution. しかも耐水性、耐光性双方とも優れた特性を発揮し、インクジエツト記録用の被記録材として好適なものである。 Moreover water resistance, and excellent properties as light resistance both is suitable as a recording material for Inkujietsuto recording.

実施例 以下、本発明を実施例によつて具体的に説明するが、本発明は、以下の実施例に限定されるものではない。 Examples will now be described by connexion specifically to the present invention embodiment, the present invention is not limited to the following examples.

実施例1 下記組成から成る塗工用組成物を作成した。 It created a coating composition comprising a first embodiment the following composition.

基材としては、JIS P8122に基づくサイズ度が35秒の一般上質紙(坪量65g/m 2 )を使用し、この基材上に上記塗工用組成物を乾燥塗工量15g/m 2の割合でブレードコーター法により塗工し、常法により乾燥させることにより、 The substrate generally high quality paper sizing degree of 35 seconds based on JIS P8122 using (basis weight 65 g / m 2), drying the coating composition onto the substrate coating amount 15 g / m 2 by coated and dried by usual manner at a rate of a blade coater method,
本発明の被記録材を得た。 To prepare a recording medium of the present invention.

得られた被記録材に対して、下記4色のインクを用いてカラーインクジエツト記録を行い、得られた記録の耐光性の評価を行つた。 KoTsuta the obtained recording medium, performs color ink jet recording using the ink of the following four colors, the evaluation of light fastness of the resulting recorded.

(i)イエローインク(組成) CIダイレクトイエロー86 2重量部 ジエチレングリコール 30 〃 水 70重量部 (ii)マゼンタインク(組成) CIアシツドレツド37 2重量部 ジエチレングリコール 30 〃 水 70 〃 (iii)シアンインク(組成) CIダイレクトブルー86 2重量部 ジエチレングリコール 30 〃 水 70 〃 (iv)ブラツクインク(組成) CIダイレクトブラツク154 2重量部 ジエチレングリコール 30 〃 水 70 〃 耐光性は、キセノンフエードメーターを用いて100時間照射し、測色色差計マクベス2020を用いて、未照射のものとの色差(ハンターΔE)を求めた。 (I) a yellow ink (composition) CI Direct Yellow 86 2 parts by weight Diethylene glycol 30 〃 water 70 parts by weight (ii) a magenta ink (composition) CI Ashitsudoretsudo 37 2 parts Diethylene glycol 30 〃 water 70 〃 (iii) a cyan ink (composition) CI direct Blue 86 2 parts by weight diethylene glycol 30 〃 water 70 〃 (iv) wanders ink (composition) CI direct loiter 154 2 parts diethylene glycol 30 〃 water 70 〃 lightfastness irradiates 100 hours using a xenon off Aid meter, using calorimetric color sakei Macbeth 2020 was determined color difference (Hunter Delta] E) between that of non-irradiated.

結果を下記第2表に示した。 The results are shown in Table 2 below.

実施例2 下記構造式 Example 2 following structural formula で示されるカチオン化合物の2%の水溶液にサイズ度0 Sizing degree 0 2% aqueous solution of a cationic compound represented in
秒の一般紙(坪量70g/m 2 )を浸漬し、乾燥して本発明の被記録材を得た(基材に対する上記カチオン化合物の含有量:0.6重量%)。 S general paper (basis weight 70 g / m 2) was immersed and dried to prepare a recording medium of the present invention (the content of the cationic compound to the substrate: 0.6 wt%).

得られた被記録材を用いて、実施例1に記載の方法に従つて、インクジエツト記録を行ない、得られた記録の耐光性を評価し、結果を下記第2表に示した。 Using the obtained recording material, the method to the slave connexion described in Example 1, subjected to Inkujietsuto recording, to evaluate the light resistance of the resulting recorded. The results are shown in Table 2 below.

実施例3〜9 実施例2におけるカチオン化合物の代わりに下記第1表に示した化合物を用いた以外は実施例2に記載の方法に従って本発明の被記録材を得た。 Except for using compounds shown in Table 1 below in place of the cationic compound in Example 3-9 Example 2 to prepare a recording medium of the present invention according to the method described in Example 2.

得られた被記録材を用いて実施例1に記載の方法に従って、インクジェット記録を行ない、得られた記録の耐光性を評価し、結果を下記第2表に示した。 Following the procedure described in Example 1 by using the obtained recording medium, performs ink jet recording, to evaluate the light resistance of the resultant recorded. The results are shown in Table 2 below. の代わりに下記第1表に示した化合物を用いた以外は実施例2に記載の方法に従つて本発明の被記録材を得た。 Except for using compounds shown in Table 1 below instead of to prepare a recording medium of the slave connexion present invention to the method described in Example 2.

得られた被記録材を用いて実施例1に記載の方法に従つて、インクジエツト記録を行ない、得られた記録の耐光性を評価し、結果を下記第2表に示した。 The resulting methods accordance connexion described in Example 1 using the recording medium, performs Inkujietsuto recording, to evaluate the light resistance of the resulting recorded. The results are shown in Table 2 below.

比較例1 実施例1において塗工用組成物の成分としてカチオン化合物を添加しなかつたこと以外は、実施例1に記載の方法に従つて被記録材を作成した。 Except that failed to added cationic compound as a component of the coating composition in Comparative Example 1 Example 1 was prepared the Supporting connexion recording material to the method described in Example 1. 得られた被記録材を用いて、実施例1に記載の方法に従つて、インクジエツト記録を行ない、得られた記録の耐光性を評価し、その結果を下記第2表に示した。 Using the obtained recording material, accordance with the method described in Example 1, subjected to Inkujietsuto recording, to evaluate the light resistance of the resulting recorded and the results are shown in Table 2 below.

比較例2 実施例2で使用した基材を無処理のまま被記録材として用い、実施例1に記載の方法に従つて、インクジエツト記録を行ない、得られた記録の耐光性を評価し、その結果を下記第2表に示した。 The substrate used in Comparative Example 2 Example 2 used as a leave recording material naive accordance with the method described in Example 1, subjected to Inkujietsuto recording, to evaluate the light resistance of the resulting recording, its the results are shown in table 2 below.

比較例3 実施例1の塗工用組成物において、カチオン化合物の代りに、ラウリルトリメチルアンモニウムクロライドを用いたこと以外は、実施例1に記載の方法に従つて被記録材を作製した。 In the coating composition of Comparative Example 3 Example 1, in place of the cationic compound, except for using lauryl trimethyl ammonium chloride, to prepare the Supporting connexion recording material to the method described in Example 1. 得られた被記録材を用いて、実施例1に記載の方法に従つて、インクジエツト記録を行ない、得られた記録の耐光性を評価し、その結果を下記第2表に示した。 Using the obtained recording material, accordance with the method described in Example 1, subjected to Inkujietsuto recording, to evaluate the light resistance of the resulting recorded and the results are shown in Table 2 below.

ただし、上記第2表において、Yは、イエローインクを、Mは、マゼンタインクを、Cは、シアンインクを、 However, in the Table 2, Y is a yellow ink, M is magenta ink, C is a cyan ink,
BKは、ブラツクインクを示す。 BK shows a wander ink.

Claims (1)

    【特許請求の範囲】 [The claims]
  1. 【請求項1】下記一般式〔I〕又は〔II〕で表わされるカチオン化合物を含有することを特徴とするインクジェット用被記録材。 1. A following general formula [I] or ink jet recording material, characterized by containing a cationic compound represented by [II]. 一般式 The general formula (式中、R 1は炭素数15〜25の炭化水素残基を表わし、m (In the formula, R 1 represents a hydrocarbon residue of 15 to 25 carbon atoms, m
    およびnは両者の和が4〜8となる整数を表わしXはハロゲン原子を表わす)、 一般式 And n X represents the integer sum of both is 4-8 represents a halogen atom), general formula (式中、R 2は炭素数10〜25の炭化水素残基を表わし、X (Wherein, R 2 represents a hydrocarbon residue of 10 to 25 carbon atoms, X
    はハロゲン原子を表わす) Represents a halogen atom)
JP12077685A 1985-06-04 1985-06-04 Inkujietsuto for the recording material Expired - Lifetime JPH0678030B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12077685A JPH0678030B2 (en) 1985-06-04 1985-06-04 Inkujietsuto for the recording material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12077685A JPH0678030B2 (en) 1985-06-04 1985-06-04 Inkujietsuto for the recording material

Publications (2)

Publication Number Publication Date
JPS61277484A true JPS61277484A (en) 1986-12-08
JPH0678030B2 true JPH0678030B2 (en) 1994-10-05

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Application Number Title Priority Date Filing Date
JP12077685A Expired - Lifetime JPH0678030B2 (en) 1985-06-04 1985-06-04 Inkujietsuto for the recording material

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JP (1) JPH0678030B2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6482503B1 (en) 1993-03-19 2002-11-19 Xerox Corporation Recording sheets containing pyrrole, pyrrolidine, pyridine, piperidine, homopiperidine, quinoline, isoquinoline, quinuclidine, indole, and indazole compounds
US5457486A (en) * 1993-03-19 1995-10-10 Xerox Corporation Recording sheets containing tetrazolium indolinium, and imidazolinium compounds
JP3559679B2 (en) * 1996-07-18 2004-09-02 キヤノン株式会社 Ink-jet recording medium and an inkjet recording method using the same
JP3342366B2 (en) 1997-09-08 2002-11-05 キヤノン株式会社 Ink jet recording recording medium, ink jet recording method and an image forming method using the same
JP3410415B2 (en) 2000-01-26 2003-05-26 セイコーエプソン株式会社 Image forming method and recorded matter using the recording medium

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0434512B2 (en) * 1984-12-20 1992-06-08 Mitsubishi Paper Mills Ltd

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