JPH0624461A - Motor binding string and its production - Google Patents

Abstract

(57) [Summary] [Objective] In the synthetic fiber manufacturing process or braid manufacturing process, a refrigerant such as CFC134a is obtained by applying an oil agent mainly containing mineral oil, anionic emulsifier and anionic antistatic agent. A motor binding string that does not deteriorate the electrical insulation even when used in a motor using [Structure] A raw yarn made of a treated synthetic fiber produced by using an oil agent containing a mineral oil, an anionic emulsifier, and an anionic antistatic agent as a main component, or a raw oil agent without an anionic detergent or a detergent. After washing and removing the oil, a braid braided with an oil agent containing a mineral oil, an anionic emulsifier, and an anionic antistatic agent as a main component is used as a motor binding cord.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a motor binding cord, and more particularly to a motor binding cord for binding copper wires of a motor of a compressor of a refrigerator or an air conditioner using an alternative CFC and a method for manufacturing the same.

[0002]

2. Description of the Related Art Conventionally, when CFCs 11, 12, 114, 115, etc. have been used as refrigerants for refrigerators, freezers, air conditioners, etc., the motor bundling strings for bundling the copper wires of the compressor motors of these machines are Even if a commercially available synthetic fiber such as polyester fiber was twisted as it was or used in a state of a braid, there was no problem in terms of product performance.

However, since the conventional CFCs may destroy the ozone layer of the earth, their use will be regulated in the future due to laws and voluntary regulations of the industry. As an alternative CFC for these, CFC134
a (ozone depletion factor 0) or 22 (ozone depletion factor 0.0)
5) etc. are being studied.

[0004]

However, if the same binding cord as the conventional one is used for the refrigerant using these alternative CFCs, a current also flows in the refrigerant, causing an abnormal current, which causes a problem of blowing the fuse. I'm causing it. They are,
The alternative CFC has higher polarity than conventional CFCs,
It is presumed that this is because some components of the motor binding cord are eluted to lower the electric insulation. Because of this,
Many electric appliance manufacturers and others have strongly demanded the development of a motor bundling string that exhibits the same performance as conventional ones even if it is replaced with a CFC substitute.

In view of the above circumstances, it is a first object of the present invention to provide a motor binding string which does not deteriorate the electric insulation even if the CFC substitute is used. The other purpose is
It can also be said to play a part in helping to prevent the destruction of the earth's ozone layer by cooperating with the promotion of alternative CFCs.

[0006]

In order to achieve the above-mentioned object, the motor tying cord of the present invention is a synthetic fiber motor tying cord used in a portion which comes into contact with a fluorine-based solvent, wherein the synthetic fiber is mineral oil. An anionic emulsifier and an oil agent containing an anionic antistatic agent as a main component are attached.

Further, the method for manufacturing the motor binding cord of the present invention is
A method for manufacturing a synthetic fiber motor binding string used in a portion that comes into contact with a fluorine-based solvent, comprising mineral oil, an anionic emulsifier,
And a synthetic fiber raw yarn treated with an oil agent containing an anionic antistatic agent as a main component, or after removing the raw thread oil agent by washing with or without an anionic detergent, a mineral oil, an anionic emulsifier , And an oil agent containing an anionic antistatic agent as a main component is subjected to an adhesion treatment.

[0008]

According to the above-mentioned structure of the present invention, the synthetic fiber constituting the motor binding string is adhered with the oil agent containing the mineral oil, the anionic emulsifier, and the anionic antistatic agent as the main components. Freon 134a, 123, 141 containing hydrogen atoms in addition to halogen atoms in its carbon
Even when it is used in a motor or the like in which alternative CFCs such as b, 22, 142b, and 152a are used as a refrigerant, it is possible to obtain a motor binding string that does not deteriorate the electric insulation. The electrical insulation here means that the leak current in the refrigerant is 0.4 milliamperes or less.

According to the structure of the manufacturing method of the present invention, an oil agent containing mineral oil, an anionic emulsifier, and an anionic antistatic agent as a main component is applied in the synthetic fiber manufacturing step or the braid manufacturing step. As a result, even when used in a motor using a refrigerant such as Freon 134a, it is possible to realize a motor bundling string that does not deteriorate the electrical insulation, and to efficiently and rationally manufacture.

[0010]

EXAMPLES The present invention will be described in more detail with reference to the following examples. The present inventors systematically investigated the electrical conductivity of various components contained in a motor binding string in various refrigerants in order to solve the problems of the prior art. In general, synthetic fiber filaments are provided with an appropriate oil agent in order to facilitate the handling of the yarn at the time of drawing, twisting, drawing, and the like. Since an oil agent is required to have various performances, it is rarely a single compound, and a smoothing agent, emulsifier, antistatic agent,
A combination of humidity control agents and sizing agents is used. As the leveling agent, transparent mineral oils that are easily refined and have good thermal stability, such as paraffin oil, petrolatum, white oil (liquid paraffin), and white spindle oil are mainly used. These are emulsified and used in consideration of wettability as well. As an emulsifier, soap, an anionic activator (sulfate),
An emulsifier such as a nonionic activator is used. For the purpose of antistatic, various polymeric resin types are used in addition to those consisting of anionic surfactants, cationic surfactants, nonionic surfactants, betaine-type and imidazoline-type amphoteric surfactants. To be done. As the sizing agent, glue such as various vinyl polymers may be used.

On the other hand, a scouring agent and a cleaning agent for removing the raw thread oil agent are other than those consisting of anionic surfactants, cationic surfactants, nonionic surfactants, betaine-type and imidazoline-type amphoteric surfactants. Various compounds, reducing agents, enzymes and the like are also used in.

In view of such a background, the effect of the surfactant on the electric conductivity in various solvents was investigated by a model experiment. These results are summarized in Table 1 below.

[0013]

[Table 1]

The method for measuring the electric conductivity of the surfactants shown in Table 1 is as follows.
The mixture was added to 0 ml, stirred at room temperature for 10 minutes, and then measured using an electric conductivity meter CM-07 manufactured by Kyoto Electronics Manufacturing Co., Ltd. As is clear from Table 1, the results obtained with water and methanol, which is a relatively highly polar solvent, show that, as expected, lauryl sulfate soda, which is an anionic surfactant having strong ionic dissociation, and lauryl trimethyl, which is a nonionic surfactant. Ammonium chloride has a large effect of increasing electric conductivity.

However, chloroform (C, in which 3 halogen atoms and 1 hydrogen atom are bonded to a carbon atom)
Contrary to expectations, HCl ₃ ) did not show any effect of increasing the electrical conductivity of lauryl sulfate soda, which is an anionic surfactant, and conversely, cations such as lauryl trimethyl ammonium chloride and nonionic surfactants. It has been found that the activator polyoxyethylene nonyl phenyl ether enhances electrical conductivity.

It is presumed that these results are probably due to the solubility in chloroform, and lauryl sulfate soda and anhydrous Glauber's salt, which are highly inorganic, cannot be dissolved, and as a result, the electric conductivity can be increased. It is estimated that there is no such thing. On the other hand, it is speculated that the other two surfactants have a relatively high organicity and a small amount of them are partially dissolved to enhance the electric conductivity.

The present invention was inspired by these unexpected results. Based on this, we have studied mainly on emulsifiers of various anionic surfactants, antistatic agents, scouring agents, and cleaning agents, and succeeded in inventing a motor binding string that does not lower the electrical insulation property even in alternative CFCs.

The alternative fluorocarbons referred to in the present invention are fluorocarbons 134a, 123, 141b, 22, 142 in which methane or ethane-based carbon contains a hydrogen atom in addition to a halogen atom.
b, 152a, etc.

Most of the anionic emulsifiers, antistatic agents, scouring agents, and detergents are anionic surfactants, and are substances in which the anion portion exhibits surface activity upon ion dissociation in an aqueous solution.

Most of the anionic emulsifiers, antistatic agents, scouring agents, and cleaning agents are anionic surfactants, and are substances in which the anion portion exhibits surface activity upon ion dissociation in an aqueous solution.

Anionic surfactants are soaps and N-
Acyl amino acid salt, alkyl ether carboxylate, carboxylate such as acylated peptide, alkylsulfonate, alkylbenzene and alkylbenzenesulfonate, sulfosuccinate, α-olefinsulfonate, N-acylsulfonate, etc. Sulfonates, sulfated oils, alkyl sulfates, alkyl ether sulfates, alkyl amide sulfates, etc. sulfate salts, alkyl phosphates, alkyl ether salts, alkyl allyl ether phosphate phosphate esters, etc. There is salt etc.

The amount of the oil agent adhered in the present invention is about 0.01 to 5% by weight after drying, more preferably 0.5.
Is in the range of up to 3% by weight. The motor ties used in the present invention are made from the same materials, synthetic fibers, that have been used previously. These materials are not limited, but are preferably made of polyester fibers, aramid (aromatic polyamide) fibers, polyphenylene sulfide fibers, polyether ether ketone fibers, polyamide fibers, etc., which have good heat resistance. These fibers may be filaments (long fiber threads) or spun yarns using staples (short fibers).

These fibers are twisted and twisted into two or three strands, or used in a braided state of 4, 8, 16, 32 sets or the like. Of course, higher-order processing such as dyeing and heat setting may be performed.

With the above-mentioned structure, the present invention provides excellent electric insulation even if the CFC substitute is changed, and the refrigerator or air conditioner stops functioning on the way even if it is used for a long time. It was possible to prevent the occurrence of various problems.

Specific experimental examples will be described below. Example 1 3% by weight of paraffin oil was emulsified with 2% by weight of sodium alkylnaphthalene sulfonate to give an antistatic agent of 0.1%.
An emulsion was prepared by adding water to 1% by weight of sodium alkyl sulfonate to prepare a raw yarn oil agent. Polyethylene terephthalate filament fibers (250 denier, 48 filaments) were spun using this raw yarn oil agent, stretched and wound. The oil agent adhered in the spinning and / or stretching process, and the adhered amount was 0.8% by dry weight. Sixteen polyester fibers, 250 denier, and 48 filaments thus obtained were used to assemble into a round striking structure using a braiding device.

The braid thus obtained was dipped in Freon 134a containing 10% by weight of polyalkylene glycol and the leak current was measured.
It was 4 mA or less, and the insulation characteristics were excellent. Further, even after 1 hour of immersion, there was almost no change in this value.
Furthermore, a refrigerator equipped with a compressor incorporating a motor using this motor binding cord was continuously used for several months, but no problem occurred.

Example 2 8 commercially available commercially available 500 denier, 96 filament polyethylene terephthalate filament fibers were used.
The same evaluation as in Example 1 was performed on the motor tying string assembled to be hit, and the leakage current increased to 1.4 milliampere 60 minutes after the motor tying string was immersed.

After washing this with water, sodium alkylbenzene sulfonate was treated with a 2% by weight aqueous solution at 69 ° C. for 20 minutes to wash and remove the raw thread oil agent. Then, it was treated with the same oil as in Example 1. The amount of oil agent adhered is 1.7% by dry weight
Met.

Using this cord, the copper wire portion of the motor was bound by a racing machine. I was able to bind together without problems such as fluffing and reduced strength. In addition, polyalkylene glycol 10
The result of measuring the leak current by immersing this string in Freon 134a containing wt% is 0.4 before and after immersion.
It was less than a milliampere. There was almost no change in this value even after 1 hour of immersion. Furthermore, a refrigerator equipped with a compressor incorporating a motor using this motor binding cord was continuously used for several months, but no problem occurred.

As described above, according to the present embodiment, in the synthetic fiber manufacturing process or the braid manufacturing process, the oil agent containing the mineral oil, the anionic emulsifier, and the anionic antistatic agent as the main components is subjected to the adhesion treatment. By CFC134
Even when used in a motor using a refrigerant such as a, it is possible to realize a motor binding string that does not deteriorate the electrical insulation.

[0031]

As described above, according to the present invention, the synthetic fiber constituting the motor binding string is adhered with the oil agent containing the mineral oil, the anionic emulsifier, and the anionic antistatic agent as the main components. Freon 134a, 12 containing hydrogen atoms in addition to halogen atoms in methane or ethane carbon
Even when used in a motor or the like in which alternative CFCs such as 3, 141b, 22, 142b, and 152a are used as a refrigerant, a motor binding string that does not deteriorate electric insulation can be obtained. Further, according to the configuration of the manufacturing method of the present invention, the motor binding string can be efficiently and rationally manufactured.

Claims (2)

[Claims] 1. A motor binding cord made of synthetic fiber, wherein the synthetic fiber is adhered with an oil agent containing a mineral oil, an anionic emulsifier, and an anionic antistatic agent as main components. string. 2. A method for producing a synthetic fiber motor tying string used in a portion that comes into contact with a fluorine-based solvent, which comprises treating an oil agent containing a mineral oil, an anionic emulsifier, and an anionic antistatic agent as main components. Adhesive treatment with mineral oil, anionic emulsifier, and anionic antistatic agent as main components, after using fiber raw thread or washing and removing the original thread oil with or without anionic detergent A method for manufacturing a motor binding string, which comprises: