JPH0565207B2 - - Google Patents
Info
- Publication number
- JPH0565207B2 JPH0565207B2 JP63061770A JP6177088A JPH0565207B2 JP H0565207 B2 JPH0565207 B2 JP H0565207B2 JP 63061770 A JP63061770 A JP 63061770A JP 6177088 A JP6177088 A JP 6177088A JP H0565207 B2 JPH0565207 B2 JP H0565207B2
- Authority
- JP
- Japan
- Prior art keywords
- adsorption
- temperature
- performance
- solid amine
- retained moisture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000001179 sorption measurement Methods 0.000 claims description 49
- 150000001412 amines Chemical class 0.000 claims description 40
- 239000007787 solid Substances 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 27
- 230000000717 retained effect Effects 0.000 claims description 24
- 230000007423 decrease Effects 0.000 claims description 14
- 238000005259 measurement Methods 0.000 claims description 6
- 238000004458 analytical method Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000007789 gas Substances 0.000 description 16
- 238000011069 regeneration method Methods 0.000 description 11
- 230000008929 regeneration Effects 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003957 anion exchange resin Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は固体アミンによるCO2除去装置の制御
方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for controlling a CO 2 removal device using a solid amine.
（従来技術）
固体アミンによるCO2除去プロセスにおいて、
固体アミンの再生には水蒸気による直接加熱再生
方式が用いられている。このプロセスの吸着−再
生工程での固体アミンの保有水分は次のように変
化する。(Prior art) In the CO 2 removal process using solid amine,
A direct heating regeneration method using steam is used to regenerate solid amines. The water content of the solid amine during the adsorption-regeneration step of this process changes as follows.
(1) 吸着工程における保有水分の変化
固体アミン層を通過する供給ガスの温度、湿
度及び流速に応じた分だけ固体アミン粒子表面
から保有水分が蒸発し減少する。この現象は、
固体アミン層を通過するガス中の水分と固体ア
ミン粒子表面の水分との間に平衡関係が成立す
るまで続くので、固体アミンから失われる保有
水分の総量は、吸着時間または平衡到達時間
（平衡に達するまでに要する時間）の短かい方
で定まる。(1) Change in retained moisture in the adsorption process The retained moisture evaporates and decreases from the solid amine particle surface by an amount corresponding to the temperature, humidity, and flow rate of the supplied gas passing through the solid amine layer. This phenomenon is
This continues until an equilibrium relationship is established between the moisture in the gas passing through the solid amine layer and the moisture on the surface of the solid amine particles, so the total amount of retained moisture lost from the solid amine is determined by the adsorption time or the time to reach equilibrium. (time required to reach the target) is determined by the shorter of the two.
(2) 再生工程における保有水分の変化
固体アミンの再生には、通常100〜120℃の飽
和水蒸気が用いられる。固体アミン層に供給さ
れた水蒸気は、固体アミン層内で凝縮し、この
時に発生する潜熱によつて吸着されたCO2は固
体アミンから脱離し、固体アミンは再生され
る。この凝集した水の内、一部は固体アミンに
吸着されることになる。吸着される水分の総量
は吸着工程での固体アミンの乾燥の度合、固体
アミン自体が保有可能な水量（飽和吸着水量）、
固体アミンの水分吸着速度及び再生時間等によ
つて定まる。(2) Changes in retained moisture during the regeneration process Saturated steam at 100 to 120°C is usually used to regenerate solid amines. The water vapor supplied to the solid amine layer condenses within the solid amine layer, and the CO 2 adsorbed at this time is desorbed from the solid amine by the latent heat generated, and the solid amine is regenerated. A portion of this coagulated water will be adsorbed by the solid amine. The total amount of water adsorbed depends on the degree of drying of the solid amine during the adsorption process, the amount of water that the solid amine itself can hold (saturated adsorbed water amount),
It is determined by the water adsorption rate of solid amine, regeneration time, etc.
以上の述べたように固体アミンの保有水分は吸
着工程で減少し、再生工程で増加する。即ち、固
体アミン側からみると吸着工程で乾燥し、再生工
程で湿潤することになる。したがつて、吸着工程
で失われた水分が再生工程で補強されるような条
件下では、固体アミンは一定の範囲で水分を保持
することゝなり、安定したCO2吸着性能を維持す
ることができる。 As described above, the water content of the solid amine decreases during the adsorption process and increases during the regeneration process. That is, when viewed from the solid amine side, it dries during the adsorption process and becomes wet during the regeneration process. Therefore, under conditions where the moisture lost in the adsorption process is reinforced in the regeneration process, the solid amine will retain moisture within a certain range, making it difficult to maintain stable CO 2 adsorption performance. can.
しかしながら、上述の関係（固体アミンの乾燥
−湿潤）を維持するためには、装置の設置場所に
おける環境条件（温度、湿度）を一定に保つ必要
があり、環境条件が変動すると固体アミンは乾
燥、湿潤いずれかの方法に偏り、CO2吸着性能が
低下する。 However, in order to maintain the above relationship (drying-wetting of the solid amine), it is necessary to keep the environmental conditions (temperature, humidity) constant at the location where the equipment is installed, and if the environmental conditions change, the solid amine will dry out or become wet. If wetness is biased towards one of the methods, the CO 2 adsorption performance will decrease.
次に固体アミンの吸着性能と保有水分の関係に
ついてのべる。この関係をグラフに描くと第３図
のようになる。ハミルトンスタンダード社（米
国）が実施したIRA−45（米国ロームアンドハー
ス社製、弱塩基性陰イオン交換樹脂）でのテスト
結果によれば、IRA−45のCO2の吸着性能を維持
するためには、保有水分の範囲は18〜35％とされ
ている。この範囲を外れると性能が低下すること
になり、その原因として以下のことが挙げられ
る。 Next, we will discuss the relationship between solid amine adsorption performance and water content. If you draw this relationship on a graph, it will look like Figure 3. According to the test results of IRA-45 (manufactured by Rohm and Haas, USA, weakly basic anion exchange resin) conducted by Hamilton Standard Co., Ltd. (USA), in order to maintain the CO 2 adsorption performance of IRA-45, It is said that the moisture content ranges from 18 to 35%. If it falls outside this range, the performance will deteriorate, and the reasons for this are as follows.
(1) 保有水分が下限以下の場合（IRA−45では18
％以下）
固体アミンのCO2吸着反応はイオン交換反応
によるものであるが、交換基のアミン類が十分
に水和されていないと、イオン交換反応が抑制
され、第４図ａに示すように急激に吸着性能が
低下する。(1) If the retained moisture is below the lower limit (18 for IRA-45)
% or less) The CO 2 adsorption reaction of solid amines is due to an ion exchange reaction, but if the amines in the exchange group are not sufficiently hydrated, the ion exchange reaction will be suppressed, as shown in Figure 4 a. Adsorption performance decreases rapidly.
(2) 保有水分が上限以上の場合（IRA−45では35
％以上）
第４図ｃに示すように、吸着初期の吸着速度
は低下するものゝ、保有水分が下限以下（第４
図ａ）のような急激な低下はみられない。これ
は固体アミン粒子表面に水の層ができ、CO2が
イオン交換サイトに到達するまでの抵抗とな
る。つまりCO2の拡散速度が低下することによ
る現象である。(2) If the retained moisture is above the upper limit (35 for IRA-45)
% or more) As shown in Figure 4c, the adsorption rate at the initial stage of adsorption decreases;
There is no sharp decline as shown in Figure a). This creates a layer of water on the surface of the solid amine particles, which provides resistance for CO 2 to reach the ion exchange site. In other words, this phenomenon is caused by a decrease in the diffusion rate of CO 2 .
なお第４図ｂは保有水分が適切な範囲（IRA
−45では18〜35％）にある場合の典型的な例
で、破過時間（固体アミン層出口にCO2が吸着
されずに流出してくるまでに要する時間）が長
いことがわかる。 Figure 4b shows the appropriate range of retained moisture (IRA
It can be seen that the breakthrough time (the time required for CO 2 to flow out without being adsorbed at the outlet of the solid amine layer) is long in a typical example when the temperature is 18% to 35% at −45%.
また固体アミンの適切な保有水分範囲は固体
アミンの種初によつて変わるが、一般的には生
乾きの状態がよいとされている。IRA−45の場
合で説明すると、その保有可能な水分は40〜45
％で、適切な範囲は上述の如く18〜35％であ
る。 Further, the appropriate range of moisture content of the solid amine varies depending on the species of the solid amine, but it is generally said that a half-dried state is best. In the case of IRA−45, the moisture content it can hold is 40 to 45
%, a suitable range is 18-35% as described above.
以上で、吸着−再生工程の保有水分の変化及び
保有水分のCO2吸着性能への影響について説明し
たが、従来技術では直接的な保有水分の制御はな
されておらず、環境条件を保有水分が変動しない
よう調節している程度であつた。 Above, we have explained the changes in retained moisture during the adsorption-regeneration process and the influence of retained moisture on CO2 adsorption performance.However, in the conventional technology, retained moisture is not directly controlled, and environmental conditions are controlled by retained moisture. The amount was adjusted to the extent that it did not fluctuate.
したがつて、空調が整備されていないような場
所においては、保有水分の変動は避けられず、吸
着性能を維持できなかつた。 Therefore, in places where air conditioning is not provided, fluctuations in retained moisture are unavoidable, making it impossible to maintain adsorption performance.
（発明により解決しようとする課題）
本発明は固体アミンの吸着性能曲線（以下、破
過曲線）の形が保有水分の増減に伴い変動するこ
とに着目し、固体アミンの保有水分を適切な範囲
に保たせるための製御方法を提供しようとするも
のである。(Problems to be Solved by the Invention) The present invention focuses on the fact that the shape of the adsorption performance curve (hereinafter referred to as breakthrough curve) of a solid amine changes as the water content increases, and the water content of the solid amine is adjusted to an appropriate range. The purpose of this paper is to provide a manufacturing method to maintain the same.
（発明による課題の解決手段）
供給ガスの供給路に温湿度調整装置と、又処理
ガスの排出路にCO2分析計と、該CO2分析計によ
る分析結果を格納しかつ前記温湿度調整装置に設
定信号を送る制御用コンピユータとを備え、吸着
工程に入ると同時に処理ガス中のCO2濃度を検出
して制御用コンピユータに記憶させておき、吸着
工低が終了するとCO2濃度測定データから吸着性
能を計算し、性能低下の有無を判別し、性能低下
傾向にある場合はあらかじめ制御用コンピユータ
の記憶装置に格納されている保有水分に応じた破
過曲線の形と比較して保有水分を推定し、更に計
算された保有水分と最適保有水分の偏差に応じた
温度及び湿度を計算し、次の吸着工程における設
定値として固体アミンのCO2の高い吸着性能を維
持可能にした。(Means for Solving the Problems by the Invention) A temperature and humidity adjustment device in a supply gas supply path, a CO 2 analyzer in a process gas discharge path, and an analysis result by the CO 2 analyzer is stored, and the temperature and humidity adjustment device The CO 2 concentration in the processed gas is detected and stored in the control computer as soon as the adsorption process begins, and when the adsorption process is finished, the CO 2 concentration measurement data is Calculate the adsorption performance, determine whether there is a decline in performance, and if there is a tendency for performance to decline, calculate the retained moisture by comparing it with the shape of the breakthrough curve according to the retained moisture stored in the storage device of the control computer in advance. The temperature and humidity were estimated and further calculated according to the deviation between the calculated moisture content and the optimal moisture content, making it possible to maintain the solid amine's high CO 2 adsorption performance as set values for the next adsorption process.
（実施例）
第１図は第１吸着反応器１と第２吸着反応器２
を備えた２塔式CO2除去装置である。供給ガスは
温湿度調節装置３で温湿度調節されて供給され、
吸着反応器１又は２でCO2を吸着されたのち、環
境中へ排出される。４は再生用蒸気発生装置、５
はCO2分析計である。６は制御用コンピユータ
で、温湿度調節装置３及びCO2分析計５に結ばれ
ている。(Example) Figure 1 shows the first adsorption reactor 1 and the second adsorption reactor 2.
This is a two-column type CO 2 removal equipment equipped with. The supply gas is supplied after being controlled in temperature and humidity by a temperature and humidity control device 3,
After CO 2 is adsorbed in the adsorption reactor 1 or 2, it is discharged into the environment. 4 is a steam generator for regeneration, 5
is a CO 2 analyzer. 6 is a control computer, which is connected to the temperature/humidity controller 3 and the CO 2 analyzer 5.
今、第１吸着反応器１が吸着工程にあるとする
と、もう一方の第２吸着反応器２は再生工程にあ
り、タイマー等により順次切替えて使用すること
により、環境中のCO2濃度を設定した範囲内に制
御することができるようになつている。 Now, if the first adsorption reactor 1 is in the adsorption process, the other second adsorption reactor 2 is in the regeneration process, and by sequentially switching and using it with a timer etc., the CO 2 concentration in the environment is set. It is now possible to control the temperature within the specified range.
供給ガスは制御用コンピユータ６からの温湿度
設定信号によつて制御される。供給ガス温湿度調
節装置３で一定温湿度に調節され、第１吸着反応
器１の上部から供給され、CO2を除去された後、
下部より排出され環境中へ戻される。この排出さ
れたガス（以下処理ガスという）の一部はCO2分
析計５へ導かれ、CO2濃度が測定される。測定結
果はコンピユータ６の記憶装置へ格納され、次の
吸着工程における温湿度調整装置に対する温湿度
設定のためのデータとなる。 The supply gas is controlled by temperature and humidity setting signals from the control computer 6. The supply gas temperature and humidity are adjusted to a constant temperature and humidity by the temperature and humidity adjustment device 3, and the supply gas is supplied from the upper part of the first adsorption reactor 1, and after CO 2 is removed,
It is discharged from the bottom and returned to the environment. A part of this discharged gas (hereinafter referred to as treated gas) is led to the CO 2 analyzer 5, where the CO 2 concentration is measured. The measurement results are stored in the storage device of the computer 6 and serve as data for setting the temperature and humidity for the temperature and humidity adjustment device in the next adsorption step.
以下第２図のフローチヤートを参照してCO2除
去装置の作用について説明する。 The operation of the CO 2 removal device will be explained below with reference to the flowchart shown in FIG.
第１吸着反応器１が吸着工程に入ると同時に処
理ガス中のCO2濃度を一定間隔（例えば30秒間
隔）で検出し、制御用コンピユータ６の記憶装置
に格納する。この操作は吸着工程終了まで継続す
る。 As soon as the first adsorption reactor 1 enters the adsorption step, the CO 2 concentration in the process gas is detected at regular intervals (for example, every 30 seconds) and stored in the storage device of the control computer 6. This operation continues until the end of the adsorption step.
吸着工程が終了すると、CO2濃度測定データか
ら吸着性能を計算し、性能低下の有無を判別す
る。性能が低下傾向にある場合は、あらかじめ制
御用コンピユータの記憶装置に格納されている第
４図に示した保有水分に応じた破過曲線の形と比
較し保有水分を推定する。更に計算された保有水
分と最適保有水分の偏差に応じた温度及び湿度を
計算し、次の吸着工程における設定値とする。運
転を停止する場合は、フロツピーデイスク等の不
揮発性メモリに格納し、運転再開時の初期値とす
る。 When the adsorption process is completed, the adsorption performance is calculated from the CO 2 concentration measurement data, and it is determined whether or not the performance has deteriorated. If the performance is on the decline, the retained moisture is estimated by comparing it with the shape of the breakthrough curve according to retained moisture shown in FIG. 4, which is stored in advance in the storage device of the control computer. Furthermore, the temperature and humidity are calculated according to the deviation between the calculated retained moisture content and the optimal retained moisture content, and are used as set values for the next adsorption step. When the operation is stopped, the value is stored in a non-volatile memory such as a floppy disk and used as the initial value when the operation is restarted.
第２吸着反応器２についても同様の操作をし、
CO2温度の計測と保有水分の計算を同時に行なう
ことになるが、計測を割込みで行なうか、または
マルチジヨブが可能なコンピユータを使用すれば
解決可能である。こゝでは供給ガスの温度及び湿
度の両者を制御するようにしたが、通常の固体の
乾燥においては、温度よりも湿度に対する依存性
が高いので、環境温度の変化が少ない場合は湿度
調節のみで対応できる。 The same operation is performed for the second adsorption reactor 2,
Measurement of CO 2 temperature and calculation of retained moisture will be performed at the same time, but this can be solved by performing the measurement with an interrupt or by using a computer capable of multi-jobs. In this case, both the temperature and humidity of the supplied gas were controlled, but since the drying of normal solids is more dependent on humidity than temperature, if there is little change in the environmental temperature, only humidity control is required. I can handle it.
なお以上はCO2除去装置について例示したが、
CO2に限らず、SO2等の酸性ガス、NH3等の塩基
性ガスの陰イオン交換樹脂または陽イオン交換樹
脂で吸着除去可能で、かつ水蒸気による直接加熱
再生可能なガスに使用可能である。 The above example is about a CO 2 removal device, but
It can be used not only for CO 2 but also for acidic gases such as SO 2 and basic gases such as NH 3 that can be adsorbed and removed using anion exchange resin or cation exchange resin, and that can be directly heated and regenerated with water vapor. .
またイオン交換樹脂に限らず、水蒸気による直
接加熱再生が可能で、かつ保有水分によつて破過
曲線の形が定まるような吸着特性をもつ吸着剤に
使用可能である。 Moreover, it can be used not only for ion exchange resins but also for adsorbents that can be regenerated by direct heating with water vapor and have adsorption characteristics such that the shape of the breakthrough curve is determined by the amount of water retained.
（効果）
従来技術では、固体アミンの吸着性能の低下の
原因が固体アミンの保有水分の増加によるもの
か、減少によるものか判別できなかつた。これに
対し本発明は破過曲線の形が保有水分と密接な関
係があることに着目して、固体アミンの保有水分
を推定可能として、更にコンピユータ利用によつ
て保有水分を制御可能にしたので、固体アミンの
高精度、CO2吸着性能の維持が可能になつた。(Effects) With the conventional technology, it was not possible to determine whether the cause of the decrease in the adsorption performance of solid amines was due to an increase or a decrease in the water content of the solid amines. In contrast, the present invention focuses on the fact that the shape of the breakthrough curve has a close relationship with the water content, and has made it possible to estimate the water content of solid amines, and also to control the water content by using a computer. , it has become possible to maintain the high precision and CO 2 adsorption performance of solid amines.
第１図は本発明方法を実施するCO2除去装置を
示す。第２図は第１図のCO2除去装置の制御フロ
ーチヤート。第３図は固体アミンに於ける保有水
分と吸着性能の関係を示すグラフ。第４図は典型
的な破過曲線の例を示す。
図において；１……第１吸着反応器、２……第
２吸着反応器、３……供給ガス温湿度調節装置、
４……再生用蒸気発生装置、５……CO2分析計、
６……制御用コンピユータ。
FIG. 1 shows a CO 2 removal device implementing the method of the invention. Figure 2 is a control flowchart of the CO 2 removal device shown in Figure 1. Figure 3 is a graph showing the relationship between water content and adsorption performance in solid amines. FIG. 4 shows an example of a typical breakthrough curve. In the figure; 1...first adsorption reactor, 2...second adsorption reactor, 3...supply gas temperature and humidity adjustment device,
4... Steam generator for regeneration, 5... CO 2 analyzer,
6... Control computer.
Claims (1)
理ガスの排出路にCO2分析計と、該CO2分析計に
よる分析結果を格納し、かつ前記温湿度調整装置
に設定信号を送る制御用コンピユータとを備え、
吸着工程に入ると同時に処理ガス中のCO2濃度を
CO2分析計で検出して制御用コンピユータに記憶
させておき、吸着工程が終了するとCO2濃度測定
データから吸着性能を計算し、性能低下の有無を
判別し、性能低下傾向にある場合は、あらかじめ
制御用コンピユータの記憶装置に格納されている
保有水分に応じた破過曲線の形と比較して保有水
分を推定し、更に計算された保有水分と最適保有
水分の偏差に応じた温度及び湿度を計算し、次の
吸着工程における設定値として固体アミンのCO2
の高い吸着性能を維持可能としたことを特徴とす
る固体アミンによるCO2除去装置の制御方法。1. A temperature/humidity adjustment device in the supply gas supply path, a CO 2 analyzer in the process gas discharge path, and control for storing the analysis results from the CO 2 analyzer and sending a setting signal to the temperature/humidity adjustment device. Equipped with a computer for
At the same time as entering the adsorption process, the CO 2 concentration in the treated gas is
It is detected by a CO 2 analyzer and stored in the control computer, and when the adsorption process is completed, the adsorption performance is calculated from the CO 2 concentration measurement data to determine whether there is a decline in performance, and if there is a tendency for performance to decline, The retained moisture is estimated by comparing it with the shape of the breakthrough curve according to the retained moisture stored in the storage device of the control computer in advance, and the temperature and humidity are determined according to the deviation between the calculated retained moisture and the optimal retained moisture. Calculate the solid amine CO2 as the set value in the next adsorption step.
A method for controlling a CO 2 removal device using a solid amine, which is characterized by being able to maintain high adsorption performance of CO 2 .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63061770A JPH01236915A (en) | 1988-03-17 | 1988-03-17 | Method for controlling apparatus for co2 removal with solid amine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63061770A JPH01236915A (en) | 1988-03-17 | 1988-03-17 | Method for controlling apparatus for co2 removal with solid amine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01236915A JPH01236915A (en) | 1989-09-21 |
| JPH0565207B2 true JPH0565207B2 (en) | 1993-09-17 |
Family
ID=13180674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63061770A Granted JPH01236915A (en) | 1988-03-17 | 1988-03-17 | Method for controlling apparatus for co2 removal with solid amine |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01236915A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5876488A (en) * | 1996-10-22 | 1999-03-02 | United Technologies Corporation | Regenerable solid amine sorbent |
| US9028592B2 (en) * | 2010-04-30 | 2015-05-12 | Peter Eisenberger | System and method for carbon dioxide capture and sequestration from relatively high concentration CO2 mixtures |
| JP5561788B2 (en) * | 2011-07-26 | 2014-07-30 | 日本電信電話株式会社 | Carbon dioxide recovery method and apparatus |
| MX351388B (en) * | 2011-12-22 | 2017-10-12 | Re N Tech Aps | A method for upgrading a gas. |
| JP6413408B2 (en) * | 2014-07-09 | 2018-10-31 | 日立化成株式会社 | CO2 removal device |
| JP6721020B2 (en) * | 2018-10-01 | 2020-07-08 | 日立化成株式会社 | CO2 removal device |
| JP6721019B2 (en) * | 2018-10-01 | 2020-07-08 | 日立化成株式会社 | CO2 removal device |
-
1988
- 1988-03-17 JP JP63061770A patent/JPH01236915A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01236915A (en) | 1989-09-21 |
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