JPH0519205B2 - - Google Patents
Info
- Publication number
- JPH0519205B2 JPH0519205B2 JP58092473A JP9247383A JPH0519205B2 JP H0519205 B2 JPH0519205 B2 JP H0519205B2 JP 58092473 A JP58092473 A JP 58092473A JP 9247383 A JP9247383 A JP 9247383A JP H0519205 B2 JPH0519205 B2 JP H0519205B2
- Authority
- JP
- Japan
- Prior art keywords
- reading
- light
- writing
- recording medium
- optical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003287 optical effect Effects 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 2
- 230000031700 light absorption Effects 0.000 claims 2
- 239000000975 dye Substances 0.000 description 19
- 230000035945 sensitivity Effects 0.000 description 6
- 238000000862 absorption spectrum Methods 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/12—Heads, e.g. forming of the optical beam spot or modulation of the optical beam
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2472—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes cyanine
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2475—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes merocyanine
Description
【発明の詳細な説明】
技術分野
本発明は光情報記録媒体の書き込み読み出し方
法に関する。DETAILED DESCRIPTION OF THE INVENTION Technical Field The present invention relates to a method for writing and reading optical information recording media.
従来技術
従来、回転しているデイスク状の情報記録媒体
にレーザ光を照射して情報の記録再生を行なう情
報記録再生装置に用いられる記録媒体としては
種々のものが提案されている。この中で本発明者
等が提案した光情報記録媒体は記録層として金属
的な光反射(ブロンズ光沢)を示す有機色素薄膜
を用いることから、感度、解像力などがすぐれ
(従つてS/Nが高くなる)また製造コストも安
価であるという利点を有する。しかしながら、感
度が高くなればなるほど読み出し光に対する劣化
も早くなり、例えば感度が5mWのものは読み出
しパワー0.4mWでも100万回以上の繰返し読み出
しが可能となるが、2.5mWのもので同一の読み
出しパワーではかなり低下する。このため、感度
の高い記録媒体に情報を書き込む場合は読み出し
光パワーを低くする必要があるが読み出しパワー
を小さくするとレーザダイオードのノイズや光セ
ンサーのノイズ成分の比率が大きくなりS/Nの
低下をきたす。したがつて、感度の高い光情報記
録媒体に適した情報の書き込み読み出し方法が望
まれている。BACKGROUND ART Conventionally, various types of recording media have been proposed for use in information recording and reproducing apparatuses that record and reproduce information by irradiating a rotating disk-shaped information recording medium with a laser beam. Among these, the optical information recording medium proposed by the present inventors uses an organic dye thin film that exhibits metallic light reflection (bronze luster) as a recording layer, so it has excellent sensitivity and resolution (therefore, S/N is low). It also has the advantage of being low in manufacturing cost. However, the higher the sensitivity, the faster the deterioration with respect to the readout light.For example, with a sensitivity of 5mW, reading can be repeated more than 1 million times even with a readout power of 0.4mW, but with a sensitivity of 2.5mW, with the same readout power It will drop considerably. Therefore, when writing information to a highly sensitive recording medium, it is necessary to lower the readout optical power, but when the readout power is lowered, the ratio of laser diode noise and optical sensor noise components increases, resulting in a decrease in S/N. Come. Therefore, a method for writing and reading information suitable for highly sensitive optical information recording media is desired.
目 的
本発明は上記現状に鑑みてなされたものであつ
て、その目的は感度も高くかつ読み出し光にも耐
え得る光情報記録媒体の書き込み読み出し方法を
提供することである。Purpose The present invention has been made in view of the above-mentioned current situation, and its purpose is to provide a method for writing and reading an optical information recording medium that has high sensitivity and can withstand reading light.
構 成
本発明は金属的な光反射特性を示す有機色素の
吸収スペクトルと正反射スペクトルの特性すなわ
ち金属的な反射を示す有機色素薄膜は吸収スペク
トルのピーク値よりも長波長側に正反射のスペク
トルが存在することを利用してなされたものであ
る。Structure The present invention is based on the characteristics of the absorption spectrum and specular reflection spectrum of an organic dye that exhibits metallic light reflection characteristics. This was done by taking advantage of the existence of
この点を有機色素として例えば以下の構造式を
有するシアニン色素を用いる場合について説明す
ると、この色素で形成した薄膜の吸収スペクトル
と正反射スペクトルとの関係は第1図に示したよ
うになる。 To explain this point in the case where a cyanine dye having the following structural formula is used as an organic dye, for example, the relationship between the absorption spectrum and the specular reflection spectrum of a thin film formed with this dye is as shown in FIG.
第1図から明らかなように、上記有機色素膜を
有する記録媒体は800nmに吸収スペクトルのピー
クをもつが反射スペクトルのそれは890nmであ
る。それ故、800nmの光で情報を書き込むと最適
の感度が得られ一方890nmの光で情報を読み出す
と最高のコントラストが得られることになる。 As is clear from FIG. 1, the recording medium having the organic dye film has an absorption spectrum peak at 800 nm, but a reflection spectrum peak at 890 nm. Therefore, writing information with 800 nm light provides optimal sensitivity, while reading information with 890 nm light provides the highest contrast.
したがつて、基板上に金属的な光反射特性を示
す有機色素記録層を有する光情報記録媒体に適用
される本発明の書き込み読み出し方法は、光情報
書き込み時に記録層の光学吸収のより高い波長の
光を利用し一方光情報読み出し時に記録層の光反
射率のより高い波長の光を利用することにある。 Therefore, the writing/reading method of the present invention, which is applied to an optical information recording medium having an organic dye recording layer exhibiting metallic light reflection characteristics on a substrate, uses a wavelength higher in the optical absorption of the recording layer when writing optical information. On the other hand, when reading optical information, light of a wavelength with a higher light reflectance of the recording layer is used.
本発明における有機色素記録層は金属的な光反
射特性を示す有機色素単独もしくは他の成分例え
ば結着剤との混合物からなるものであつて、基板
上に例えば有機色素溶液を1000Å以下の厚さで塗
布し乾燥することによつて容易に形成することが
できる。 The organic dye recording layer in the present invention is composed of an organic dye exhibiting metallic light reflection characteristics, either alone or in a mixture with other components such as a binder. It can be easily formed by coating and drying.
本発明の記録層を形成する有機色素は、金属的
な光反射特性を示す色素であれば任意のものであ
つてもよく、色素が特定の光波長域で示す金属様
の反射(いわゆるブロンズ光沢)であつて、実際
には書き込み、読み出しの使用レーザ波長に対し
て反射率20%以上好ましくは30%のものが好まし
い。有機色素の代表的な例としては、シアニン色
素、メロシアニン色素などをあげることができ
る。 The organic dye forming the recording layer of the present invention may be any dye as long as it exhibits metallic light reflection characteristics. ), and it is actually preferable to have a reflectance of 20% or more, preferably 30%, with respect to the laser wavelength used for writing and reading. Typical examples of organic dyes include cyanine dyes and merocyanine dyes.
本発明方法に使用されるレーザ光は使用色素の
吸収波長に応じて選択する必要があるが比較的安
価なHe−Neレーザまたは半導体レーザが好まし
い。 The laser beam used in the method of the present invention must be selected depending on the absorption wavelength of the dye used, but relatively inexpensive He--Ne lasers or semiconductor lasers are preferred.
また、本発明の方法に用いられる書き込み読み
出し装置は第2図に示すように読み出し光学系1
と書き込み光学系2を独立して有するものである
が、例えばアクチエータ部分などは共用すること
ができる。 Further, the writing/reading device used in the method of the present invention has a reading optical system 1 as shown in FIG.
Although the writing optical system 2 and the writing optical system 2 are independently provided, for example, the actuator portion and the like can be shared.
実施例
以下の実施例によつて本発明をさらに説明する
がこれに限定されるものではない。EXAMPLES The present invention will be further illustrated by the following non-limiting examples.
実施例 1
の色素の1.25%エチレンジクロライド溶液を1.2
mm厚のアクリル板上に塗布し、約500Åの薄膜を
形成し、記録媒体を得た。この記録媒体の光学的
なスペクトル特性は第3図に示すとおりである。Example 1 1.25% ethylene dichloride solution of dye
A recording medium was obtained by coating on an acrylic plate with a thickness of mm to form a thin film of about 500 Å. The optical spectral characteristics of this recording medium are as shown in FIG.
書き込みには800nmの半導体レーザを用い、読
み出しには850nmの半導体レーザを用いた。 An 800 nm semiconductor laser was used for writing, and an 850 nm semiconductor laser was used for reading.
書き込みは線速1.24m、記録面パワー2.5mW、
ビーム径1.4μmの光を用い0.6875MHzで行つた。
記録面パワーを0.5mWに減少させて読み出しを
行い、バンド幅30KHzで読み出したところ、
C/N52dBを得たが数100回の読み出しを繰り返
すうちに、C/Nは30dBに低下した。また
0.1mWで読み出しを行うとC/Nは45dBしか得
られなかつた。読み出し用のレーザ光を850nmの
ものにすると、読み出しパワーを0.5mWでC/
Nは52dB得られ、数100回の読み出しを繰り返し
てもC/Nの低下は認められなかつた。 Writing at linear speed of 1.24 m, recording surface power of 2.5 mW,
The experiment was conducted at 0.6875MHz using light with a beam diameter of 1.4μm.
When reading was performed by reducing the recording surface power to 0.5mW and reading with a bandwidth of 30KHz,
A C/N of 52 dB was obtained, but after reading out several hundred times, the C/N decreased to 30 dB. Also
When reading at 0.1 mW, a C/N of only 45 dB was obtained. If the readout laser beam is 850nm, the readout power is 0.5mW and C/
N was obtained at 52 dB, and no decrease in C/N was observed even after reading out several hundred times.
実施例 2
実施例1の色素を上記色素に代える以外には実
施例1と同様の書き込み読み出しを行なつたとこ
ろ、同様の結果を得た。Example 2 Writing and reading were carried out in the same manner as in Example 1, except that the dye in Example 1 was replaced with the above dye, and similar results were obtained.
効 果
本発明の方法によれば、光情報記録媒体の読み
出し光に対する劣化を防止することができる。Effects According to the method of the present invention, it is possible to prevent deterioration of an optical information recording medium due to read light.
第1図および第3図は本発明による有機色素の
吸収スペクトルと反射スペクトルとの関連を示す
図でありそして第2図は本発明の方法に用いる装
置の一例を示す模式図である。
1……読み出し光学系、2……書き込み光学
系、3……モータ、4……光デイスク、5……回
転軸。
1 and 3 are diagrams showing the relationship between the absorption spectrum and the reflection spectrum of an organic dye according to the present invention, and FIG. 2 is a schematic diagram showing an example of an apparatus used in the method of the present invention. 1... Reading optical system, 2... Writing optical system, 3... Motor, 4... Optical disk, 5... Rotating axis.
Claims (1)
収ピークと光反射ピークの波長が異なる有機色素
記録層を有する光情報記録媒体に、光吸収率のよ
り高い波長の光で情報を書き込みそして光反射率
のより高い波長の光で情報を読み出すことを特徴
とする、光情報記録媒体の書き込み読み出し方
法。1. Information is written on an optical information recording medium having an organic dye recording layer on a substrate that exhibits metallic light reflection characteristics and whose light absorption peak and light reflection peak have different wavelengths, using light at a wavelength with a higher light absorption rate, and A method for writing and reading an optical information recording medium, characterized by reading information using light of a wavelength with a higher optical reflectance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58092473A JPS59218634A (en) | 1983-05-27 | 1983-05-27 | Writing and reading-out method of optical information recording medium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58092473A JPS59218634A (en) | 1983-05-27 | 1983-05-27 | Writing and reading-out method of optical information recording medium |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59218634A JPS59218634A (en) | 1984-12-08 |
JPH0519205B2 true JPH0519205B2 (en) | 1993-03-16 |
Family
ID=14055284
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58092473A Granted JPS59218634A (en) | 1983-05-27 | 1983-05-27 | Writing and reading-out method of optical information recording medium |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59218634A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH074980B2 (en) * | 1987-08-05 | 1995-01-25 | 太陽誘電株式会社 | Recording / playback method on disc |
JP3141998B2 (en) * | 1989-06-12 | 2001-03-07 | 富士写真フイルム株式会社 | Information recording medium |
JP2747744B2 (en) * | 1991-04-08 | 1998-05-06 | 富士写真フイルム株式会社 | Optical information recording method |
JPH05120727A (en) * | 1991-10-28 | 1993-05-18 | Ricoh Co Ltd | Optical recording medium and method for recording or reproducing information to or from this medium |
US5486437A (en) * | 1993-04-08 | 1996-01-23 | Sony Corporation | Optical recording method |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5597033A (en) * | 1979-01-15 | 1980-07-23 | Philips Nv | Optical recording element and method of recording optical information |
JPS57103139A (en) * | 1980-10-31 | 1982-06-26 | Discovision Ass | Recording medium and making thereof |
JPS57212639A (en) * | 1981-06-23 | 1982-12-27 | Ricoh Co Ltd | Information recording medium |
JPS5836490A (en) * | 1981-07-24 | 1983-03-03 | Ricoh Co Ltd | Optical information recording medium |
-
1983
- 1983-05-27 JP JP58092473A patent/JPS59218634A/en active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5597033A (en) * | 1979-01-15 | 1980-07-23 | Philips Nv | Optical recording element and method of recording optical information |
JPS57103139A (en) * | 1980-10-31 | 1982-06-26 | Discovision Ass | Recording medium and making thereof |
JPS57212639A (en) * | 1981-06-23 | 1982-12-27 | Ricoh Co Ltd | Information recording medium |
JPS5836490A (en) * | 1981-07-24 | 1983-03-03 | Ricoh Co Ltd | Optical information recording medium |
Also Published As
Publication number | Publication date |
---|---|
JPS59218634A (en) | 1984-12-08 |
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