JPH0453885A - Pressure-sensitive tape for packaging - Google Patents

Pressure-sensitive tape for packaging

Info

Publication number
JPH0453885A
JPH0453885A JP16230890A JP16230890A JPH0453885A JP H0453885 A JPH0453885 A JP H0453885A JP 16230890 A JP16230890 A JP 16230890A JP 16230890 A JP16230890 A JP 16230890A JP H0453885 A JPH0453885 A JP H0453885A
Authority
JP
Japan
Prior art keywords
base material
adhesive
pressure
adhesive layer
packaging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16230890A
Other languages
Japanese (ja)
Inventor
Masahiko Goto
昌彦 五藤
Ikusuke Shimizu
清水 郁輔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Chemical Co Ltd
Original Assignee
Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to JP16230890A priority Critical patent/JPH0453885A/en
Publication of JPH0453885A publication Critical patent/JPH0453885A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To improve production efficiency and anchoring force by laminating a base material layer consisting of a polyolefin resin and a pressure-sensitive adhesive layer consisting of a styrene thermoplastic block copolymer and a tackifier resin. CONSTITUTION:A material (a) forming a pressure-sensitive adhesive layer is obtd. by compounding 100 pts.wt. styrene thermoplastic block copolymer of A-B-A or A'-B' type (wherein A and A' are each a styrene polymer block; B and B' are each a butadiene polymer block or an isoprene polymer block), 40-200 pts.wt. tackifier resin and, if necessary, 5-100 pts.wt. softening agent (e.g. naphthenic oil). A material (b) forming a base material layer consisting of a polyolefin resin and the component (a) are co-extruded to laminate the base material layer with a thickness of 50-150mum and the pressure-sensitive adhesive layer with a thickness of 10-60mum.

Description

【発明の詳細な説明】 木発明は、ダンボール封緘、荷造り等に用いられる包装
用粘着テープに関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a packaging adhesive tape used for sealing cardboard boxes, packing, etc.

支未立且I 従来より、包装用粘着テープは、数多(の製品が市販さ
れている。その主流は、クラフト紙、布、ポリエステル
フィルム等の基材上に、溶液とした粘着剤(組成物を含
む)を塗布した後に乾燥するものであった。しかし、最
近では、安全衛生上、環境上の問題により脱溶剤化が進
み、溶剤型粘着剤からエマルジョン系やボットメルト系
などの無溶剤型粘着剤へと移り変わっている。
Traditionally, a large number of packaging adhesive tapes have been commercially available.The mainstream is a solution adhesive tape (composition However, due to safety, health, and environmental concerns, there has been an increase in the use of solvent-free adhesives, and solvent-based adhesives have been replaced by solvent-free adhesives such as emulsion and bot-melt adhesives. It has moved on to adhesives.

特に、ホットメルト系粘着剤は、粘着剤を高温で溶融さ
せ、支持体(基材)上に塗工する方法であり、乾燥工程
が省略可能でエネルギー消費が少なく、生産速度も速い
In particular, hot-melt adhesives are a method in which the adhesive is melted at high temperature and coated on a support (base material), and the drying process can be omitted, energy consumption is low, and the production speed is fast.

ところが、ホットメル[・系粘看剤は、一般に、別途製
造した基材上にホットメルトコーター等を用いて塗布す
るか、あるいは離型性担体上に塗布後、基材上に転写す
る方法が採用されている。このような従来の製造方法で
は、基材に対する粘着剤の投錨力や生産効率がいまだ不
充分である。
However, hot melt adhesives are generally coated on a separately manufactured base material using a hot melt coater, or coated on a releasable carrier and then transferred onto the base material. has been done. In such conventional manufacturing methods, the anchoring force of the adhesive to the base material and the production efficiency are still insufficient.

一方、各種フィルムの高機能化を目指して、異なる材料
を同時に一体的に積層して成膜する共押出技術が開発さ
れており、この共押出法により表面保護フィルムを作成
することが提案されている(特公昭46−21120号
公報)。
On the other hand, with the aim of improving the functionality of various films, coextrusion technology has been developed to form films by laminating different materials simultaneously and integrally, and it has been proposed to create surface protection films using this coextrusion method. (Special Publication No. 46-21120).

しかし、包装用粘着テープを目的とした場合には、上記
公報開示の天然ゴムや合成ゴム、エチレン−酢酸ビニル
共重合体(EVA)とを用いるのでは、ダンボール封緘
等の包装用には適さないのである。
However, when the adhesive tape is intended for packaging, using the natural rubber, synthetic rubber, or ethylene-vinyl acetate copolymer (EVA) disclosed in the above publication is not suitable for packaging such as cardboard seals. It is.

が  しようとする 本発明の目的は、基材と粘着剤とを同時に一体化して製
造し、生産効率、投錨力に優れた包装用粘着テープを提
供することである。
An object of the present invention is to provide a packaging adhesive tape that is produced by simultaneously integrating a base material and an adhesive, and has excellent production efficiency and anchoring power.

本発明者は、前記従来技術の有する問題点を克服するた
めに鋭意研究した結果、基材層としてポリオレフィン系
樹脂を用い、粘着剤層としてスチレン系熱可塑性ブロッ
ク共重合体および粘着付与樹脂を含有する組成物を用い
、かつ、両者を共押出法により一体的に積層することに
より、上記目的を達成できることを見出し、その知見に
基づいて本発明を完成するに至った。
As a result of intensive research to overcome the problems of the above-mentioned conventional technology, the present inventor used a polyolefin resin as the base material layer and contained a styrene thermoplastic block copolymer and a tackifier resin as the adhesive layer. The inventors have discovered that the above object can be achieved by using a composition that has the following properties and by integrally laminating the two by a coextrusion method, and have completed the present invention based on this knowledge.

を  するための かくして、本発明によれば、ポリオレフィン系樹脂から
なる基材層と、スチレン系熱可塑性ブロック共重合体お
よび粘着付与樹脂を必須成分とする粘着剤層とが共押出
法で積層されていることを特徴とする包装用粘着テープ
が提供される。
Thus, according to the present invention, a base layer made of a polyolefin resin and an adhesive layer containing a styrene thermoplastic block copolymer and a tackifier resin as essential components are laminated by a coextrusion method. An adhesive tape for packaging is provided.

以下、本発明について詳述する。The present invention will be explained in detail below.

基材層を構成するポリオレフィン系樹脂としては、例え
ば、ポリエチレン、ポリプロピレンまたはエチレン−酢
酸ビニル共重合体、エチレン−エチルアクリレート共重
合体等のごとき共重合体、およびこれらの混合物が挙げ
られる。
Examples of the polyolefin resin constituting the base layer include polyethylene, polypropylene, copolymers such as ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, and mixtures thereof.

本発明で使用するスチレン系熱可塑性ブロック共重合体
とは、−数式A−B−AまたはA′B′のブロック共重
合体(ただし、A、A′はスチレン重合体ブロックを示
し、B、B′はブタジェン重合体ブロックまたはイソプ
レン重合体ブロックを示す。)で表わされる熱可塑性エ
ラストマーである。
The styrenic thermoplastic block copolymer used in the present invention is a block copolymer of the formula A-B-A or A'B' (where A, A' indicate a styrene polymer block, B, B' represents a butadiene polymer block or an isoprene polymer block.

スチレン重合体ブロックA、A′は、平均分子量が12
,000〜100,000程度のものが好ましく、その
ガラス転移温度は20℃以上のものが好ましい。また、
ブタジェン重合体ブロックまたはイソプレン重合体ブロ
ックB、B’は、平均分子量がio、ooo〜300,
000程度のものが好ましく、そのガラス転移温度は一
20℃以下のものが好ましい。
Styrene polymer blocks A and A' have an average molecular weight of 12
,000 to about 100,000, and the glass transition temperature is preferably 20°C or higher. Also,
The butadiene polymer block or isoprene polymer block B, B' has an average molecular weight of io, ooo to 300,
The glass transition temperature is preferably about -20°C or less.

そして、上記A、A’成分とB、B′成分との重量比A
:B (またはA’:B’)は、通常、5:95〜50
 : 50、好ましくは10:90〜30 : 70で
ある。
And the weight ratio A of the above A, A' components and B, B' components
:B (or A':B') is usually 5:95-50
:50, preferably 10:90 to 30:70.

一船人A−B−Aブロック共重合体と一船人A’−B′
ブロック共重合体は、混合して用いてもよく、両者の重
量比は、通常、(A−B−A):  (A′−B′)=
100 : O〜20:80、好ましくは(A−B−A
):  (A′−B′)80 : 20〜40:60で
ある。
One shipman A-B-A block copolymer and one shipman A'-B'
The block copolymers may be used as a mixture, and the weight ratio of the two is usually (A-B-A): (A'-B')=
100:O to 20:80, preferably (A-B-A
): (A'-B') 80:20 to 40:60.

粘着付与樹脂は、特に限定されないが、例えば、脂肪族
炭化水素系樹脂、テルペン系樹脂、クマロン・インデン
樹脂、芳香族炭化水素系樹脂等が好適に使用できる。粘
着付与樹脂の配合割合は、スチレン系熱可塑性ブロック
共重合体100重量部に対して、40〜200重量部が
好ましい。
The tackifying resin is not particularly limited, but for example, aliphatic hydrocarbon resins, terpene resins, coumaron-indene resins, aromatic hydrocarbon resins, etc. can be suitably used. The blending ratio of the tackifier resin is preferably 40 to 200 parts by weight based on 100 parts by weight of the styrenic thermoplastic block copolymer.

軟化剤としては、例えば、ナフテン系オイルが好適に使
用できる。軟化剤の配合割合は、スチレン系熱可塑性ブ
ロック共重合体100重量部に対して、5〜100重量
部が好ましい。
As the softener, for example, naphthenic oil can be suitably used. The blending ratio of the softener is preferably 5 to 100 parts by weight based on 100 parts by weight of the styrenic thermoplastic block copolymer.

基材層と粘着剤層の厚みは、用途により適宜決定されれ
ばよいが、基材層の厚みは、一般に、50〜150μm
程度であり、粘着剤層の厚みは、一般に、10〜60μ
m程度である。
The thickness of the base material layer and the adhesive layer may be appropriately determined depending on the application, but the thickness of the base material layer is generally 50 to 150 μm.
The thickness of the adhesive layer is generally 10 to 60 μm.
It is about m.

なお、基材層、粘着剤層には、光安定剤、紫外線吸収剤
、酸化防止剤などの各種添加剤が必要に応じて添加され
てもよい。
In addition, various additives such as a light stabilizer, an ultraviolet absorber, and an antioxidant may be added to the base material layer and the adhesive layer as necessary.

本発明においては、基材層および粘着剤層を形成する材
料をインフレーション法またはTダイ法などの共押出法
により、一体的に積層する。共押出することにより、粘
着剤層の基材層に対する投錨力が強化され、また、生産
効率が高まる。
In the present invention, materials forming the base layer and the adhesive layer are integrally laminated by a coextrusion method such as an inflation method or a T-die method. By coextruding, the anchoring force of the adhesive layer to the base material layer is strengthened, and production efficiency is also increased.

K五り 以下に、実施例および比較例を挙げて本発明についてさ
らに具体的に説明するが、本発明は、これらの実施例の
みに限定されるものではない。
The present invention will be described in more detail below with reference to Examples and Comparative Examples, but the present invention is not limited only to these Examples.

[実施例1] 基材層には、低密度ポリエチレン(密度0.923、メ
ルトインデックス3.7)、粘着剤層には、スチレン−
イソプレン′−スチレンブロック共重合体(商品名「カ
リフレックスTR−1107」シェル化学社製)100
重量部に対して、粘着付与樹脂(商品名「エスコレツツ
4401J トーネックス社製)100ffi量部、ナ
フテン系オイル(商品名「サンセンオイルJ 5UNO
CO社製)50重量部、酸化防止剤(商品名「ヨシノッ
クス425」吉NH薬社製)1重量部からなる粘着剤組
成物を用いた。
[Example 1] The base layer was made of low density polyethylene (density 0.923, melt index 3.7), and the adhesive layer was made of styrene.
Isoprene'-styrene block copolymer (trade name "Califlex TR-1107" manufactured by Shell Chemical Co., Ltd.) 100
To parts by weight, 100ffi parts of tackifying resin (trade name "Escolets 4401J, manufactured by Tonex Co., Ltd."), naphthenic oil (trade name "Sansen Oil J 5UNO")
A pressure-sensitive adhesive composition containing 50 parts by weight of an antioxidant (trade name: "Yoshinox 425", manufactured by Yoshi NH Pharmaceutical Co., Ltd.) and 1 part by weight of an antioxidant (trade name: "Yoshinox 425", manufactured by Yoshi NH Pharmaceutical Co., Ltd.) was used.

粘着剤成分は、窒素ガス気流下、180℃で混合し、ギ
アポンプで押出機へ供給した。
The adhesive components were mixed at 180° C. under a nitrogen gas stream and fed to an extruder using a gear pump.

2層共押出法にて、基材層の厚み1100tL、粘着剤
層の厚み40μmの粘着テープを得た。
An adhesive tape with a base layer thickness of 1100 tL and an adhesive layer thickness of 40 μm was obtained by a two-layer coextrusion method.

[実施例2] 基材層には、低密度ポリエチレン(密度0.923、メ
ルトインデックス3.7)、粘着剤層には、スチレン−
ブタジェン−スチレンブロック共重合体(商品名[カリ
フレックスTR−1102」シェル化学社製)100重
量部に対して、粘着付与樹脂(商品名「エスコレッツ4
401J トネックス社%)100重量部、ナフテン系
オイル(商品名[サンセンオイルJ 5UNOCO社製
)50重量部、酸化防止剤(商品名「ヨシソックス42
5」吉冨製薬社製)1重量部からなる粘着剤組成物を用
いた。
[Example 2] The base material layer was made of low density polyethylene (density 0.923, melt index 3.7), and the adhesive layer was made of styrene.
To 100 parts by weight of butadiene-styrene block copolymer (trade name [Califlex TR-1102] manufactured by Shell Chemical Co., Ltd.), tackifier resin (trade name [Escolettes 4]
401J Tonex Company%) 100 parts by weight, 50 parts by weight of naphthenic oil (trade name [Sansen Oil J 5 manufactured by UNOCO Company), antioxidant (product name ``Yoshisox 42''),
A pressure-sensitive adhesive composition containing 1 part by weight of ``5'' (manufactured by Yoshitomi Pharmaceutical Co., Ltd.) was used.

粘着剤成分は、窒素ガス気流下、180℃で混合し、ギ
アポンプで押出機へ供給した。
The adhesive components were mixed at 180° C. under a nitrogen gas stream and fed to an extruder using a gear pump.

2層共押出法にて、基材層の厚み100μm、粘着剤層
の厚み40 g mの粘着テープを得た。
An adhesive tape with a base layer thickness of 100 μm and an adhesive layer thickness of 40 gm was obtained by a two-layer coextrusion method.

[比較例1] 基材層には、低密度ポリエチレン(密度0.922、メ
ルトインデックス7.0)、粘着剤層には、エチレン−
酢酸ビニル共重合体(酢酸ビニル含有率45%)100
重量部と水素添加ロジンエステル130重量部よりなる
粘着剤組成物を用いた。
[Comparative Example 1] The base material layer was made of low-density polyethylene (density 0.922, melt index 7.0), and the adhesive layer was made of ethylene-
Vinyl acetate copolymer (vinyl acetate content 45%) 100
A pressure-sensitive adhesive composition consisting of 130 parts by weight of hydrogenated rosin ester and 130 parts by weight of hydrogenated rosin ester was used.

粘着剤は成分は、窒素ガス気流下、180℃で混合し、
ギアポンプで押出機へ供給した。
The components of the adhesive are mixed at 180°C under a nitrogen gas stream.
A gear pump fed the extruder.

2層共押出法にて、基材層の厚み100μm、粘着剤層
の厚み40μmの粘着テープを得た。
An adhesive tape with a base layer thickness of 100 μm and an adhesive layer thickness of 40 μm was obtained by a two-layer coextrusion method.

これらの実施例および比較例で得られた粘着テープの物
性の測定結果を第1表に示す。
Table 1 shows the measurement results of the physical properties of the adhesive tapes obtained in these Examples and Comparative Examples.

なお、物性の測定法は以下のとおりである。The physical properties were measured as follows.

<sp粘着力>:JIS  20237−8〈タック法
>:JIS  20237 (傾斜式ポールタック法1
/32〜32/32インチ径の剛球を使用し、ボールナ
ンバーで表示) 〈保持力>:JIS  20237−11〈紙むしり〉
、粘着テープを23℃で2kgの押圧ロールで押圧し、
段ボール表面に貼付けた。
<sp adhesive strength>: JIS 20237-8 <tack method>: JIS 20237 (inclined pole tack method 1
/32 to 32/32 inch diameter rigid ball is used, indicated by ball number) <Holding force>: JIS 20237-11 <Paper removal>
, press the adhesive tape with a 2 kg press roll at 23°C,
Attached to the cardboard surface.

23℃で30分放置後、300mm/分の速度で180
°の角度で引き剥した。その時に、段ボールをむしりと
るかどうかを観察した。
After leaving it at 23℃ for 30 minutes, it was heated at a speed of 300mm/min.
It was torn off at an angle of °. At that time, we observed whether or not they would tear off the cardboard.

(0:むしる、×;むしらない) (以下余白) 第1表から明らかなように、本発明の粘着テープは、粘
着力、タック、保持力ともに良好であり、かつ、紙むし
すせず、包装用粘着テープとして優れた性能を示してい
る。これに対して、従来技術のように、EVAを粘着剤
成分として用いた場合(比較例1)には、共押出法によ
っては、包装用粘着テープとして不適格なものしか得ら
れない。
(0: Will tear, ×: Will not tear) (Hereafter, blank) As is clear from Table 1, the adhesive tape of the present invention has good adhesive strength, tack, and holding power, and does not tear the paper. It shows excellent performance as an adhesive tape for packaging. On the other hand, when EVA is used as an adhesive component as in the prior art (Comparative Example 1), depending on the coextrusion method, only a product unsuitable for use as a packaging adhesive tape can be obtained.

及薄目と舛釆 本発明によれば、特定の基材と粘着剤とを共押出法によ
り同時に一体化して積層することにより、生産効率、投
錨力に優れ、しかも包装用粘着テープとしての性能に優
れた包装用粘着テープが提供される。
According to the present invention, a specific base material and an adhesive are simultaneously integrated and laminated using a coextrusion method, resulting in excellent production efficiency and anchoring power, and also excellent performance as an adhesive tape for packaging. An excellent packaging adhesive tape is provided.

Claims (1)

【特許請求の範囲】[Claims] (1)ポリオレフィン系樹脂からなる基材層と、スチレ
ン系熱可塑性ブロック共重合体および粘着付与樹脂を必
須成分とする粘着剤層とが共押出法で積層されているこ
とを特徴とする包装用粘着テープ。
(1) For packaging, characterized in that a base material layer made of a polyolefin resin and an adhesive layer whose essential components are a styrene thermoplastic block copolymer and a tackifying resin are laminated by a coextrusion method. Adhesive tape.
JP16230890A 1990-06-20 1990-06-20 Pressure-sensitive tape for packaging Pending JPH0453885A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16230890A JPH0453885A (en) 1990-06-20 1990-06-20 Pressure-sensitive tape for packaging

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16230890A JPH0453885A (en) 1990-06-20 1990-06-20 Pressure-sensitive tape for packaging

Publications (1)

Publication Number Publication Date
JPH0453885A true JPH0453885A (en) 1992-02-21

Family

ID=15752045

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16230890A Pending JPH0453885A (en) 1990-06-20 1990-06-20 Pressure-sensitive tape for packaging

Country Status (1)

Country Link
JP (1) JPH0453885A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2359815B (en) * 2000-02-21 2003-01-15 Plasto Sa Method of fastening external prostheses
US8263713B2 (en) 2009-10-13 2012-09-11 Kraton Polymers U.S. Llc Amine neutralized sulfonated block copolymers and method for making same
US8377514B2 (en) 2008-05-09 2013-02-19 Kraton Polymers Us Llc Sulfonated block copolymer fluid composition for preparing membranes and membrane structures
US9861941B2 (en) 2011-07-12 2018-01-09 Kraton Polymers U.S. Llc Modified sulfonated block copolymers and the preparation thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2359815B (en) * 2000-02-21 2003-01-15 Plasto Sa Method of fastening external prostheses
US8377514B2 (en) 2008-05-09 2013-02-19 Kraton Polymers Us Llc Sulfonated block copolymer fluid composition for preparing membranes and membrane structures
US8377515B2 (en) 2008-05-09 2013-02-19 Kraton Polymers U.S. Llc Process for preparing membranes and membrane structures from a sulfonated block copolymer fluid composition
US8263713B2 (en) 2009-10-13 2012-09-11 Kraton Polymers U.S. Llc Amine neutralized sulfonated block copolymers and method for making same
US9861941B2 (en) 2011-07-12 2018-01-09 Kraton Polymers U.S. Llc Modified sulfonated block copolymers and the preparation thereof

Similar Documents

Publication Publication Date Title
KR100225664B1 (en) Pressure sensitive adhesive composition and pressure sensitive adhesive tape or sheet making use of the same
JP2713519B2 (en) Surface protection film
EP1719809A2 (en) Pressure sensitive adhesive (PSA) laminates
RU2474598C2 (en) Hot-melt pressure-sensitive adhesive composition and adhesive article
JPH1030079A (en) Pressure-sensitive adhesive for radial styrene-isoprene-styrene-based label
JP6892854B2 (en) Hot melt adhesive composition
JP2009532559A (en) Pressure sensitive adhesive (PSA) laminate
JP2003523477A (en) Radiation-curable adhesive composition comprising a block copolymer having a vinyl-functional polydiene block
US20060251888A1 (en) Pressure sensitive adhesive (PSA) laminates
US4361672A (en) Hot melt adhesive compositions
WO2014087815A1 (en) Adhesive composition for protective film of coated surface and method for preparing same
US20060251889A1 (en) Pressure sensitive adhesive (PSA) laminates
US4361663A (en) Pressure sensitive adhesive compositions
JPH0453885A (en) Pressure-sensitive tape for packaging
WO2012128293A1 (en) Pressure sensitive adhesive composition and pressure sensitive adhesive sheet
JPS61103975A (en) Bonding film for surface protection
JPH11106730A (en) Hot melt pressure-sensitive adhesive composition
JP4669194B2 (en) Adhesive tape
WO1983001623A1 (en) Adhesive compositions
TWI408204B (en) Protective films for textured substrates
JP3498970B2 (en) Transfer film
JPS60226579A (en) Pressure-sensitive adhesive composition
JPS60223880A (en) Pressure-sensitive adhesive composition
JPH0860119A (en) Surface protection film and manufacture
KR100225665B1 (en) Pressure sensitive adhesive composition and pressute sensive adhesive tape or sheet making use of the same